Resins Lab

Monday, January 24, 2005

イ Exp. NO: ( U.P 1/7) soft

ロ Study type: {UN SATURATED POLY ESTER { putty
ハ Exp. quantity / kg: 2

Raw Material Charge Weight Y %

EC 100 400 17.66 16.2

EC 101 320 14.128 13.01

EP 106 260 11.479 10.57

EP 105 400 17.66 16.2

ED 307 294.45 13 11.97

ED 306 24 1.059 0.975

EI 503 0.45*7.5=3.390.1 0.02 0.018

EI 501 0.32 *7.5=2.4 0.014 0.013

EI 502 0.63 * 7.5=4.72 0.028 0.026

ED 303 0.11 0.0048 0.045

EV 400 760 33.55 30.93

EI 500 0.11 * 7.5 =0.82 0.0048 0.045

Total Sum 2460 108.607 100.00

Production process :

1) charge EC 101 to flask melting occur at 60 – 70 c with N2 gas.

2) After EC 101 melt , add EP 106 + EP 105 to flask and rise temp to 100 -
110 c , exothermic reaction will start and note increase of temp and note increase
of temperature and don’t allow increase of temp than 140 c.
3) hold T for 1 hr.
4) add ED 307 and hold temp for 1 hr.
5) add EC 100 + ED 306 , raise temp to 165 c ( 5 c /15 min).
6) hold temp 2 hrs at 165 c.
7) raise temp to 215 c ( 10 c /30 min)., at 200 c add half of EI 503.

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8) at 215 c , start to check A.V every hour.

9) at A.V 28 - 30 apply vacuum for 10 min.
10) cool to 180 c , add EI 501 + rest of EI 503.
11) start to check A.V & viscosity ( 66 % in styrene ) , by DIN cup No 4.
12) cool to 100 c , then drop the resin to EV 400 + ED 303 + EI 502 ( temp
shouldn’t exceed 80 c).
13) at temp 40 - 45 c add EI 500.

Processing Results :

Time Temperature Processing Details

10:15 Room Temp Charge EC 101 to flask , raise T to 70 c.

10:40 70 c Add EP 105 + EP 106 , raise T to 100 c.

10:50 110 c Exothermic reaction begin.

11:00 135c Exothermic reaction completed, fix T for 1 hr.

12:00 135 c Add ED 307 , , fix T for 1 hr

1:35 135 c Add ED 306 + EC 100 ,raise to 140 c,fix for 1/4 hr.

1:50 140 c Raise T to 145 c , fix for 1/4 hr.

2:05 145 c Raise T to 150 c , fix for 1/4 hr.

2:20 150 c Raise T to 155 c , fix for 1/4 hr.

2:35 155 c Raise T to 160 c , fix for 1/4 hr.

2:50 160 c Raise T to 165 c , fix for 1hr.

3:50 165 c Raise T to 175 c , fix for 1/2hr.

4:20 175 c Raise T to 185 c , fix for 1/2hr.

4:50 185 c Raise T to 195 c , fix for 1/2hr.

5:20 195 c Add 1/2 EI 503 ,Raise T to 205 c , fix for 1/2hr.

5:50 205 c Raise T to 215 c , fix for 1/2hr.

6:50 215 c A.V = 50.3

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 Resins Lab

8:30 215 c A.V = 31 cool to 180 c.

Add EI 501 + rest of EI 503 , cool to 100 c.
9:15 180 c
Add solvent mixture.
9:40 80 c

9:50 40 c Add EI 500

Final Results

Starting A.V= 50.3

ending A.V= 31
after dilution :
A.V=
Viscosity = 7 min using cup 4
Solid content = %
Color =
Gel time= 45 min.

Special Notes

 all EI’s are diluted to 10% per wt using EP 103 , and using the calculated
quantities multiplied by 7.5 ( i.e : using 3/4 the calculated quantities).
 In 25-1-2004 four samples are sent to ch: Bahaa as follow:

Sample (1) Sample (2) Sample (3) Sample (4)

500 gm resin 500 gm resin 1000 gm resin 500 gm resin

0 5 gm D.B.E 6 gm DR 120 6 gm DR 120

Gel time 45 min 45 min 45 min 38 min

Responsible Chemist General Manager

Ch : Mohammed Said Ch : Mohammed Hussein

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