TUGAS THERMODINAMIKA

Nama : Syamsurizal
NIM : 7780210003

10.26. Assuming the validity of the Dadyburjorcharts, make following VLE Calculations for the ethane(1)/
propane(2)/isobutane(3) system :
(a) BUBL P, given x1=0.10 x2=0.20 x3=0.30 and t=333.15 (60oC)
(b) DEW P, given y1=0.48 y2=0.25 y3=0.15 and t=333.15 (60oC)
(c) BUBL T, given x1=0.14 x2=0.13 x3=0.25 and P= 15 bar
(d) DEW T, given y1=0.42 y2=0.30 y3=0.15 and P= 15 bar

Answer
(a) BUBBLE P
T = 60oC P = 200 Kpa P = 400 Kpa P = 600 Kpa P =700 Kpa P =1000 Kpa P =1500 Kpa P =1100 Kpa
xi Ki Ki.xi Ki Ki.xi Ki Ki.xi Ki Ki.xi Ki Ki.xi Ki Ki.xi Ki Ki.xi
Ethane 0.1 21 2.100 11 1.100 7.4 0.740 6.6 0.660 5 0.500 3.5 0.350 4.6 0.460
Propane 0.2 8 1.600 4.2 0.840 3 0.600 2.6 0.520 1.95 0.390 1.4 0.280 1.8 0.360
Isobutane 0.3 3.8 1.140 2.1 0.630 1.4 0.420 1.25 0.375 0.9 0.270 0.68 0.204 0.86 0.300
4.840 2.570 1.760 1.555 1.160 0.834 1.120

(b) DEW P
T = 60oC P = 150 Kpa P = 400 Kpa P = 2000 Kpa P = 4000 Kpa P = 3000 Kpa P = 3500 Kpa
yi Ki yi/Ki Ki yi/Ki Ki yi/Ki Ki yi/Ki Ki yi/Ki Ki yi/Ki
Ethane 0.48 30 0.016 11 0.043636 2.8 0.171429 1.6 0.3 2.05 0.234146 1.8 0.266667
Propane 0.25 11 0.0227273 4.2 0.059524 1.1 0.227273 0.66 0.378788 0.82 0.304878 0.72 0.347222
Isobutane 0.15 5 0.03 2.1 0.071429 0.54 0.277778 0.34 0.441176 0.42 0.357143 0.38 0.394737
0.0687273 0.174589 0.676479 1.119964 0.896167 1.008626
(c) BUBBLE T
P = 15 Bar = 1500 Kpa T = 80oC
 xi Ki Ki.xi
Ethane 0.14 4.2 0.588
Propane 0.13 1.8 0.234
Isobutane 0.25 0.95 0.2375
1.0595
(d) DEW T
P = 15 Bar = 1500 Kpa T = 80oC
yi Ki yi/Ki
Ethane 0.42 4.2 1.764
Propane 0.3 1.8 0.54
Isobutane 0.15 0.95 0.1425
2.4465
P =1200 Kpa P =1150 Kpa P =1300 Kpa
Ki Ki.xi Ki Ki.xi Ki Ki.xi
4.2 0.420 4.1 0.410 5.2 0.520
1.65 0.330 1.6 0.320 1.55 0.310
0.8 0.240 0.82 0.246 0.74 0.222
0.990 0.976 1.052