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of nearby molecules.
• It is the resistance of the liquid/fluid to
flow. Experiment for viscosity
Viscosity, the resistance to flow, depends on Glycerol – serves as a humectant, solvent, and
molecular shape and decreases with sweetener, and may help preserve foods; is also
temperature. Stronger intermolecular forces used as filler in commercially prepared low-fat
create higher viscosity. foods (e.g., cookies), and as a thickening agent
in liqueurs; Glycerol and water are used to
Some liquids such as water or alcohol flow preserve certain types of plant leaves.
easily. They are fluid. Others such as molasses
or motor oil take a longer time to flow (they are Chemical Formula: Glucose Fructose == Viscous
viscous). yellow liquid. == Honey is primarily fructose and
glucose in that order, with a little sucrose
Nonpolar molecules like benzene (C6H6), (about 1%), and less than 10% other sugars, and
pentane (C5H12), and carbon tetrachloride about 17% water. The low water content is
(CCl4) experience only weak intermolecular important to many of honey's properties. It
forces (dispersion forces) and low viscosities. makes it thick, it prevents spoilage, but is
More polar molecules like glycerol enough to keep it liquid. Because there is so
(C3H5C(OH)3) and aqueous sugar solution little water in honey, microorganisms that
(syrup) have higher viscosities because of H- encounter honey die as the water in them is
bonding among many –OH groups and removed by osmosis. In addition, as honey is
dispersion forces at many points along the diluted with water, a chemical reaction
chain. between glucose, water, and oxygen produces
Viscosity can be measured using a small amounts of hydrogen peroxide and
VISCOMETER. It measures the time it takes for a gluconic acid. The slow release of hydrogen
known volume of liquid to flow through the peroxide makes honey a mild antiseptic. The
small neck. acidity of honey also reduces the number of
organisms that can live in it. Honey is mostly
Benzene – is a widely used industrial chemical; used as a sweetener, but it has been used to
found in crude oil, major part of gasoline; used treat wounds and as a preservative.
to make plastics, resins, synthetic fiber, rubber
lubricants, dyes, detergent, drugs and The bonds in honey are hydrogen bonding,
pesticides; produced naturally by volcanoes and which are one of the strongest bonds, and this
forest fires. causes strong cohesion forces between them
and it causes the flow of the honey to be
slow/viscous.
Cohesion is the attraction in a molecule of liquid constant regardless of changes to the shear
to each other due to intermolecular forces. rate.
The H2O water molecule is polar with He was only partly right. A few fluids, such as
intermolecular dipole-dipole hydrogen bonds. water and honey, do behave this way. We call
As the water molecules attract each other and these fluids Newtonian fluids. Most fluids,
form bonds, water displays properties such as however, have viscosities that fluctuate
high surface tension and a high heat of depending on the shear rate. These are
evaporation. called Non-Newtonian fluids.
The especially strong intermolecular forces in There are five types of non-Newtonian fluids:
ethanol are a result of a special class of dipole- thixotropic, rheopectic, pseudoplastic, dilatant,
dipole forces called hydrogen bonds. and plastic. Different considerations are
required when measuring each of these fluid
Acetone: (CH3)2CO.
types.
The Intermolecular Forces acting on two atoms
TYPES OF VISCOSITY
of Acetone would be London Dispersion Forces
and Dipole-Dipole Forces. This is because the Apparent (shear) viscosity – In Newtonian
atom has only side that is more positively fluids, this value doesn’t change, but with non-
charged than the other causing the Dipole- Newtonian fluids, apparent viscosity is directly
Dipole attraction. affected by shear rate. It can be calculated by
dividing shear stress by shear rate.
The viscosity of a liquid decreases with
increasing temperature because at higher Relative viscosity – is important for non-
temperatures, the average kinetic energy of the Newtonian fluids, specifically polymers. It refers
molecules that overcomes the attractive forces to the relationship between molar mass (the
between molecules is greater. mass of a chemical compound divided by total
amount) and viscosity – higher molar mass
KETCHUP
means higher viscosity in the polymer. It’s
Using the scientific definition, no. ketchup is not calculated by dividing the polymer viscosity of
a liquid. the pure solvent.
Gaussian units constitute a metric system of The higher the poise the greater the viscosity
physical units. This system is the most common
of the several electromagnetic unit systems
based on cgs (centimetre–gram–second) units.
It is also called the Gaussian unit system,
Gaussian-cgs units, or often just cgs units.