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VISCOSITY intermolecular forces to resist the flow

of nearby molecules.
• It is the resistance of the liquid/fluid to
flow. Experiment for viscosity

Difference of Liquid and Fluid Materials:

• Liquid – is a state of matter • 10 pcs. 100-mL Beaker


• Stirring rod
• Fluid – is any substance that flows; the • Honey
molecules themselves are in constant, • Oil
random motion, colliding with each • Water
other and with the walls of any • Alcohol
container. • Acetone
Examples of Viscous Substances Objective:

Liquid:  Observe the viscosity of the liquid


substances used in the experiment to
• Acetone be conducted to day.
• Alcohol
• Blood Questions:
• Blood plasma
• Gasoline 1. Which of the substances used has the
• Glycerine slowest flow?
• Mercury 2. Which of the substances used has the
• Oil
fastest flow?
• Water
Gas: 3. What can you infer from the
experiment conducted?
• NH3
• CO2
• CO
• H2 HONEY IMFA: Hydrogen bonding
• N2
Oil IMFA: London Dispersion Force
• O2
• SO2 Water IMFA: Dipole-dipole Hydrogen
• Helium bonding
• Methane
• Air Alcohol (ethanol) IMFA: Hydrogen bonds

Acetone IMFA: Dipole-dipole attraction


1. It is the resistance of the fluid to flow.
2. Stronger intermolecular forces create
higher viscosity.
3. Liquid viscosities are much higher
because the much higher because the
much shorter distances between their
particles result in many more points for
2 Factors that influence viscosity: KETCHUP

• Effect of temperature • Is a NOT A LIQUID by definition

• Viscosity decreases with • consists of solids in suspension in a


heating liquid

• Faster moving molecules • it’s a “non-Newtonian fluid”


overcome intermolecular forces
Newtonian vs Non-Newtonian
more easily, so the resistance to
flow decreases. • Newtonian fluid – the viscosity of a
fluid would remain constant regardless
• Effect of molecular shape
of changes to the shear rate.
• Small, spherical molecules
• Non-Newtonian fluid – viscosities that
make little contact and pour
fluctuate depending on the shear rate.
easily, like buckshot from a
bowl. 5 Types of Newtonian fluids:

• Long molecules make more 1. Thixotropic


contact and become entangled 2. Rheopectic
and pour slowly. 3. Pseudoplastic
4. Dilatant
• Thus, given the same types of
5. plastic
intermolecular forces, liquids
consisting of longer molecules TYPES of VISCOSITY
have higher viscosities.
• Dynamic (absolute) viscosity – most
often relates to non-Newtonian fluids;
Making of Syrup refers to the fluid’s internal resistance
to flow when force if applied.
Even at room temperature, a concentrated
aqueous sugar solution has a higher viscosity • Kinematic viscosity – is a measure of
than water because of H bonding among the the viscosity of a (usually Newtonian)
many hydroxyl (-OH) groups on the ring-shaped fluid in motion; can be defined as a
sugar molecules. When the solution is slowly ratio of dynamic viscosity to density.
heated to boiling, the sugar molecules react
• Apparent (shear) viscosity – refers to
with each other and link covalently, gradually
the relationship between viscosity and
forming long chains.
shear rate.
Hydrogen bonds and dispersion forces
• Relative viscosity – refers to the
occur at many points along the chains, and
relationship between molar mass and
the resulting syrup is a viscous liquid that
viscosity.
pours slowly and clings to a spoon. When a
viscous syrup is cooled, it may become stiff Dynamic Viscosity
enough to be picked up and stretched – into
taffy candy. • Symbol: P (Poise)

• Jean Loius Marie Poiseuille (1799-1869)


• CGS unit: dyne-second per square • Cosmetics: should be considered when
centimeter designing the feel and flow of cosmetic
products.
• SI Unit: Newton-second per square
meter. (Poiseuille, PI)

• 1P = 0.1 Pa(s); 1PI = 10 P or 1000 cP;


1cP = 1mPa(s)

VISCOSITY is the measure of a substance's


resistance to motion under an applied force. 

• The formula for measuring viscosity is


fairly simple:

viscosity = shear stress / shear rate

• The result is typically expressed


in centipoise (cP), which is the
equivalent of 1 mPa s (millipascal
second). 

• Shear stress is the force per unit area


required to move one layer of fluid in
relation to another.

• Shear rate is the measure of the change


in speed at which intermediate layers
move with respect to one another.

APPLICATIONS IN REAL LIFE

• Food: to maximize production efficiency


and cost effectiveness.

• Adhesives: To choose the right viscosity


for an adhesive, consider how the
adhesive must flow, or not flow, on a
part after the adhesive is applied. 

• Petroleum: project the effectiveness of


lubricating oil and determines design
elements of pipelines.

• Concrete: determines the self-leveling


and pumping behavior of a mix.
It is the resistance of the fluid to flow. Pentane – gives power to cars; helps make
polystyrene foam (those foam peanuts found in
It is related to the movement of the molecules
your favorite package) [styro-foam]
in the liquid, and thus to the molecular forces
present. Carbon Tetrachloride – was widely used as a
cleaning fluid (in industry and dry cleaning
It results from the intermolecular attractions
establishments as degreasing agent, and in
that impede the movement of molecules
households as a spot remover for clothing,
around and past each other.
furniture, and carpeting); was also used in fire
Both gases and liquids flow, but liquid extinguishers and as a fumigant to kill insects in
viscosities are much….. Nearby molecules. grain.

Viscosity, the resistance to flow, depends on Glycerol – serves as a humectant, solvent, and
molecular shape and decreases with sweetener, and may help preserve foods; is also
temperature. Stronger intermolecular forces used as filler in commercially prepared low-fat
create higher viscosity. foods (e.g., cookies), and as a thickening agent
in liqueurs; Glycerol and water are used to
Some liquids such as water or alcohol flow preserve certain types of plant leaves.
easily. They are fluid. Others such as molasses
or motor oil take a longer time to flow (they are Chemical Formula: Glucose Fructose == Viscous
viscous). yellow liquid. == Honey is primarily fructose and
glucose in that order, with a little sucrose
Nonpolar molecules like benzene (C6H6), (about 1%), and less than 10% other sugars, and
pentane (C5H12), and carbon tetrachloride about 17% water. The low water content is
(CCl4) experience only weak intermolecular important to many of honey's properties. It
forces (dispersion forces) and low viscosities. makes it thick, it prevents spoilage, but is
More polar molecules like glycerol enough to keep it liquid. Because there is so
(C3H5C(OH)3) and aqueous sugar solution little water in honey, microorganisms that
(syrup) have higher viscosities because of H- encounter honey die as the water in them is
bonding among many –OH groups and removed by osmosis. In addition, as honey is
dispersion forces at many points along the diluted with water, a chemical reaction
chain. between glucose, water, and oxygen produces
Viscosity can be measured using a small amounts of hydrogen peroxide and
VISCOMETER. It measures the time it takes for a gluconic acid. The slow release of hydrogen
known volume of liquid to flow through the peroxide makes honey a mild antiseptic. The
small neck. acidity of honey also reduces the number of
organisms that can live in it. Honey is mostly
Benzene – is a widely used industrial chemical; used as a sweetener, but it has been used to
found in crude oil, major part of gasoline; used treat wounds and as a preservative.
to make plastics, resins, synthetic fiber, rubber
lubricants, dyes, detergent, drugs and The bonds in honey are hydrogen bonding,
pesticides; produced naturally by volcanoes and which are one of the strongest bonds, and this
forest fires. causes strong cohesion forces between them
and it causes the flow of the honey to be
slow/viscous.
Cohesion is the attraction in a molecule of liquid constant regardless of changes to the shear
to each other due to intermolecular forces. rate. 

The H2O water molecule is polar with He was only partly right. A few fluids, such as
intermolecular dipole-dipole hydrogen bonds. water and honey, do behave this way. We call
As the water molecules attract each other and these fluids Newtonian fluids. Most fluids,
form bonds, water displays properties such as however, have viscosities that fluctuate
high surface tension and a high heat of depending on the shear rate. These are
evaporation. called Non-Newtonian fluids.

The especially strong intermolecular forces in There are five types of non-Newtonian fluids:
ethanol are a result of a special class of dipole- thixotropic, rheopectic, pseudoplastic, dilatant,
dipole forces called hydrogen bonds. and plastic. Different considerations are
required when measuring each of these fluid
Acetone: (CH3)2CO.
types.
The Intermolecular Forces acting on two atoms
TYPES OF VISCOSITY
of Acetone would be London Dispersion Forces
and Dipole-Dipole Forces. This is because the Apparent (shear) viscosity – In Newtonian
atom has only side that is more positively fluids, this value doesn’t change, but with non-
charged than the other causing the Dipole- Newtonian fluids, apparent viscosity is directly
Dipole attraction. affected by shear rate. It can be calculated by
dividing shear stress by shear rate.
The viscosity of a liquid decreases with
increasing temperature because at higher Relative viscosity – is important for non-
temperatures, the average kinetic energy of the Newtonian fluids, specifically polymers. It refers
molecules that overcomes the attractive forces to the relationship between molar mass (the
between molecules is greater. mass of a chemical compound divided by total
amount) and viscosity – higher molar mass
KETCHUP
means higher viscosity in the polymer. It’s
Using the scientific definition, no. ketchup is not calculated by dividing the polymer viscosity of
a liquid. the pure solvent.

It consists of solids in suspension in a liquid, and DYNAMIC VISCOSITY


that makes it a “non-Newtonian fluid”
Poise (symbol: P) Named after the French
A suspension is a heterogeneous mixture in physician Jean Louis Marie Poiseuille (1799–
which the solute particles do not dissolve, but 1869), this is the cgs unit of viscosity, equivalent
get suspended throughout the bulk of the to dyne-second per square centimetre. It is the
solvent, left floating around freely in the viscosity of a fluid in which a tangential force of
medium. 1 dyne per square centimetre maintains a
difference in velocity of 1 centimetre per
Newtonian vs. Non-Newtonian second between two parallel planes 1
Isaac Newton, the man to discover this formula, centimetre apart. Even in relation to high-
thought that, at a given temperature and shear viscosity fluids, this unit is most usually
stress, the viscosity of a fluid would remain encountered as the centipoise (cP), which is
0.01 poise. Many everyday fluids have 100 degrees C) and a precise time reading (in
viscosities between 0.5 and 1000 cP (see table). seconds) for the time it takes a fixed amount of
fluid to flow within the tube from one marked
Pascal-second (symbol: Pa·s) This is the SI unit
point to another by suction or through the force
of viscosity, equivalent to newton-second per
of gravity.
square metre (N·s m–2). It is sometimes
referred to as the “poiseuille” (Pl). One poise is This measured time is then multiplied by a
exactly 0.1 Pa·s. One poiseuille is 10 poise or constant (associated to the particular tube) to
1000 cP, while 1 cP = 1 mPa·s (one millipascal- calculate the absolute viscosity (suction) or the
second). kinematic viscosity (force of gravity).

Gaussian units constitute a metric system of The higher the poise the greater the viscosity
physical units. This system is the most common
of the several electromagnetic unit systems
based on cgs (centimetre–gram–second) units.
It is also called the Gaussian unit system,
Gaussian-cgs units, or often just cgs units.

Gathering viscosity data on a material gives


manufacturers the ability to predict how the
material will behave in the real world. For
example, if toothpaste does not have the
correct viscosity, it can either be too difficult to
pump out from the tube, or pump out too
much.

Knowing the viscosity of a material also affects


how the production and transportation
processes are designed. 

CSC Scientific sells Rotational Viscometers that


can adapt to the testing method required for
measuring the viscosity of Newtonian and Non-
Newtonian fluids.

We also sell the new EMS-1000 Viscometer, a


high-tech electromagnetic spinning viscometer
for tricky applications like adhesives, blood, and
expensive perfumes. 

Capillary (Glass) Viscometer Test

The main apparatus used in a capillary


viscometer test is a glass tube in the general
shape of a “U,” which gives it its commonly
associated name, the U-tube. The procedure for
a U-tube requires the tube to be submerged in
a temperature-controlled bath (usually 40 or

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