altolpr

Assianment
5ecTIoN A
O Discuss about Monosszhomide
ophcal ropen ty ocasty pdratesB
oUsually tound in organt Substan to
Theyve Sodfun chlomda, tunpenra. 1
Assummaric Con bbn otom: C whtch fs ottacheol to toun
dstfeurtqroups ov oloms sbduipoe
All rmonosa cchonitde
Con taun One or moye asynm meby'c C
alom enept H kaona and
dthyolhory aotone
Ary Co mp oun d howt'nq one ev more
assmme rc Caom
shows oph'cal acHvi'ty and Stentos omeauam.

Stesaofs omerltm
Comp ounds hoc howe Same strucural tormula but
dIPF e tn Spaha Con h'guroh'on ane knoUun a

Sheveofs omeg. his fs call d as

Stescofsonmassm
h e ro ol possfblo someas aComp
Compound depend on
ho Oassummehn'c C akom ano eguo o 2n.

Gnlucos e Contains 4 assmmahi'e C otom

Aldose- ketose fsomers

lo Rspe somas'm hs huo fs omess howe
Soume shushuro) mula but
off in Conbory C
On Contain oldehy oa roup cnd ohar kotone qroup
ea Glutose- Alodlehyds group ru otose -
ke tose
97o up
 CH, O

HO

OIA

CHo C20H

Epfmuas-
They oFFe In Con h'gurah'on around one C atom

e
oRua han Caybeny Caned benuh'm ote C

Eg aucos e and qlolaciose. hawe soume

Skucuroa fhovmul a Co CHz0 nA

ase2 C-4 epfmeis Glucose and Gialacase
CHO
H-C-01
onbuss .H Ho
HO-C
H-C O o-C
C - OH -C-6H

CHH CH OH
s -2 epfmes
C-2 epfma3 Gilucbse ano
-

mann es e
CHo
H-COH
[Ho-C-H
Ho-C-H Ho-C-H
c0 H-C-0
H C OH
e H-cbH

CH,OH CH0H

DL fs om ers -

onos acchow fole Can el hey tov m to D ov L fovm

n D-Form, Ae hydrexqooup at Hu penutm ate
Cowb en ts on ght stde wk'u tn fu L- enm, ttn
 On He Cet stcle

.6

- Ho C

CHOH CH,OH
DCt) quces al duhyd LC qlyceraldshyds

o-B isomus
Monos acthan Pela fn cyce Shructure an be în d or B
Con'gurahon
Dn fovm hydex qroup atachad fn CanbenyC6on
t sfda and p orm hy oyoryf o u p aHached he

Conbon Cison ot sele M)Cd tokt

Oph'cal Achvity
Abuy o cormpo und to yotake plano polaysed ght lo
dledao

P l a n polow3 ed u'aht The Uaht Hhot lts wawe passe

Plon
in Same plan by ach on Specod ri'sms.

a Compound otake a plan polayi'sel L'ahd to Tight

fss olaxre 7otadery C d or +

IP a Co mp o un dl re tote a
plan pol anrsed Ueyht lo lut
t's loavoYototery CLov-)
angee o otdfun Is muas ured by polaimata and s

o ec d by mar Pactors, Such as Soure o uht

hakuye, Con tenr aht on Subsshaun to an d temperatuu
 Chemu'cal repeales Monosacchorldes
o omatten o an autal
OR
Ht
R-C-H +R-b R--H R-0sRc-H +Hz0
oldahyclu olcohol
OR' OR
Creackant) hemfoceha a ce hale
Inlermadicda

Hernacetd fs oTmed
by addPtron a n alcohal by
breakfng he C 0 corbonyl olouble bend and atochir
eRa group to Car b ony C and Hq dovoqen caybony
Oxygen
OH
CHa-C-H+CH2 6H CH
Chetaldahyda) CMethonel)l o CH3

CHemmoce ho
istntermecl/ate
hen wnstabe hum' cLceral s hen
Conves bed fnto an
acutoal by Hu
Sub Shhuhon onwly ovme dOH qYoup
by a w eRea Porm
a Second al coh ol CR- OH) obo
rodu enq buoouke
OH
CHg-OH oCH3
CHa
CHg-C-H CH3CH+ H20
oCR CHlsrsxdoo
Chcetal)
Por mah'on kehal a

Adel'hr on aalcohel to ke Fona mred utw an uns tablu

bron heme'o toal fnter m cl'oole ha fn uYn pyodu ta ket
9R
- R + R-OH R- OR
R
4,0
Kelone ol co hl hem ceoliote
atpe
OR
keial
 Hemlkelal somed byadolheon Qn ol tohol by
byeakin q Hhe Cr0 Caybenyl doubu bond ond atadksn
Ra eu group to Cobengl Cond hychegen o
Conbeny x

CH-C-CH,+ CH, CH, OA CH-

9
CH C-CHa
ocHCHs
Clnkevmadfoke)
Unstoubla hemKa tal fs Hhen Convent ed to kal by h
Subsh uhon ono wly Porma od0-H q1oup by a rau
ehea om a Se cond al cohol also rod uc'ng waka.
OH
Ht and 1,(,-o OH2 CHs
CHg- C-CH3 CH-C-CHs H2o
ocHCH3 OCH2CHs
Even Pough hemlace tals ond hemiketals ove unsBale
yecad humlacuals Oun c hem k tcus on e Commonly
Pouwndbeccuse hay one more shobl hon open chairs

OH
CH

Shuctur e and roperhes o Disacchonldes-

atTuwo monos ncch on'oles Comb f'ns d fn a Condans ahfon
reachren o om a do tuble sugan

Bond w twe monos o cchamicl fs kn o wn as

gytosfdte
bond
) 3 Common dSs ac chomldes re maltas c lactose anelsuerer
 Dfs occhonfdes shucure
Suor ese is hormad by qucoe Jofn ed lo ruchoie by -
qlyuost'olue 'nkoge. ( h ydro uyad to qu cose by h
en2yma Sucrase

CH,OH CHo

orCH,DH
OH

Calucose Cru ces e

nd a Sucrose

Prucese df'secchoridl o mtk, consisk gelactos e

jolnad alb gucese by P - L4 aycos/el'e nkage. It6
hydroU'zud fnto hese mones accham tols b lacase and
P-golacHdlse
CH204 CH0y
CHOH
OH DH

y Oy oH
PH
oH H

Cralactos e Gn ucose pols

Loctose
M l toe Coma rom yoro lysr's o Coge olosochondau
Such as Shomch and
aytogen. anol fs Pn
u
to aRuces by mal tagge
hyoroyed e

CtLOH CH 0H ChLOH snatoCHH

OH
o
Gilucos e Gilucose tp m odtose