CEM Continuous Stirred Tank Reactor - Run 1 Results

Sample Sample Elapsed Sodium Ethyl Flowrate Flowrate Measured Stirrer

Number Time Time Hydroxide Acetate of Sodium of Ethyl Conductivity Speed
Concentaion Concentraion Hydroxide Acetate
[mol/dm³] [mol/dm³] [cm³/min] [cm³/min] 0 - 20 [mS] [rpm]
1 14:26:02 00:00:00 0.050 0.050 80.0 0.0 19.99 70
2 14:26:32 00:00:30 0.050 0.050 80.0 0.0 19.99 70
3 14:27:02 00:01:00 0.050 0.050 80.0 0.0 19.99 70
4 14:27:32 00:01:30 0.050 0.050 80.0 80.0 19.99 70
5 14:28:02 00:02:00 0.050 0.050 80.0 80.0 19.99 70
6 14:28:32 00:02:30 0.050 0.050 80.0 80.0 19.99 70
7 14:29:02 00:03:00 0.050 0.050 80.0 80.0 19.99 70
8 14:29:32 00:03:30 0.050 0.050 80.0 80.0 19.99 70
9 14:30:02 00:04:00 0.050 0.050 80.0 80.0 19.89 70
10 14:30:32 00:04:30 0.050 0.050 80.0 80.0 19.09 70
11 14:31:02 00:05:00 0.050 0.050 80.0 80.0 18.43 70
12 14:31:32 00:05:30 0.050 0.050 80.0 80.0 18.37 70
13 14:32:02 00:06:00 0.050 0.050 80.0 80.0 18.13 70
14 14:32:32 00:06:30 0.050 0.050 80.0 80.0 17.59 70
15 14:33:02 00:07:00 0.050 0.050 80.0 80.0 17.46 70
16 14:33:32 00:07:30 0.050 0.050 80.0 80.0 17.17 70
17 14:34:02 00:08:00 0.050 0.050 80.0 80.0 16.94 70
18 14:34:32 00:08:30 0.050 0.050 80.0 80.0 16.46 70
19 14:35:02 00:09:00 0.050 0.050 80.0 80.0 16.32 70
20 14:35:32 00:09:30 0.050 0.050 80.0 80.0 15.83 70
21 14:36:02 00:10:00 0.050 0.050 80.0 80.0 15.93 70
22 14:36:32 00:10:30 0.050 0.050 80.0 80.0 15.67 70
23 14:37:02 00:11:00 0.050 0.050 80.0 80.0 15.64 70
24 14:37:32 00:11:30 0.050 0.050 80.0 80.0 15.13 70
25 14:38:02 00:12:00 0.050 0.050 80.0 80.0 15.18 70
26 14:38:32 00:12:30 0.050 0.050 80.0 80.0 14.96 70
27 14:39:02 00:13:00 0.050 0.050 80.0 80.0 14.66 70
28 14:39:32 00:13:30 0.050 0.050 80.0 80.0 14.35 70
29 14:40:02 00:14:00 0.050 0.050 80.0 80.0 13.92 70
30 14:40:32 00:14:30 0.050 0.050 80.0 80.0 13.48 70
31 14:41:02 00:15:00 0.050 0.050 80.0 80.0 12.84 70

Page 1
 CEM Continuous Stirred Tank Reactor - Run 1 Results

32 14:41:32 00:15:30 0.050 0.050 80.0 80.0 13.03 70

33 14:42:02 00:16:00 0.050 0.050 80.0 80.0 12.68 70
34 14:42:32 00:16:30 0.050 0.050 80.0 80.0 12.59 70

Chart Title
29.0

28.0

27.0
Temperatura (°C)

26.0

25.0

24.0

23.0
00:00:00 00:02:52 00:05:45 00:08:38 00:11:31 00:14:24 00:17:16 00:20:09

Tiempo (min)

Page 2
 CEM Continuous Stirred Tank Reactor - Run 1 Results

Reactor Reactor NaOH EtAC Initial Final

Temp. Volume Notes Feed Feed Feed NaOH
Concentration Concentration Conductivity Concentration
[°C] [dm³] [mol/dm³] [mol/dm³] [mS] [mol/dm³]
28.7 1.00 0.05 0.00 11.1 0.05
28.3 1.00 0.05 0.00 11.1 0.05
28.0 1.00 0.05 0.00 11.0 0.05
27.7 1.00 160.0 0.03 0.03 5.5 0.00
27.2 1.00 0.16 0.03 0.03 5.4 0.00
26.8 1.00 0.03 0.03 5.4 0.00
26.4 1.00 0.03 0.03 5.4 0.00
26.1 1.00 0.03 0.03 5.3 0.00
25.8 1.00 0.03 0.03 5.3 0.00
25.4 1.00 0.03 0.03 5.3 0.00
25.9 1.00 0.03 0.03 5.3 0.00
26.6 1.00 0.03 0.03 5.4 0.00
27.0 1.00 0.03 0.03 5.4 0.00
27.2 1.00 0.03 0.03 5.4 0.00
27.2 1.00 0.03 0.03 5.4 0.00
27.2 1.00 0.03 0.03 5.4 0.00
27.2 1.00 0.03 0.03 5.4 0.00
27.2 1.00 0.03 0.03 5.4 0.00
27.6 1.00 0.03 0.03 5.5 0.00
27.9 1.00 0.03 0.03 5.5 0.00
27.9 1.00 0.03 0.03 5.5 0.00
28.0 1.00 0.03 0.03 5.5 0.00
28.0 1.00 0.03 0.03 5.5 0.00
28.0 1.00 0.03 0.03 5.5 0.00
27.8 1.00 0.03 0.03 5.5 0.00
27.8 1.00 0.03 0.03 5.5 0.00
27.9 1.00 0.03 0.03 5.5 0.00
28.1 1.00 0.03 0.03 5.5 0.00
28.0 1.00 0.03 0.03 5.5 0.00
28.0 1.00 0.03 0.03 5.5 0.00
27.9 1.00 0.03 0.03 5.5 0.00

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 CEM Continuous Stirred Tank Reactor - Run 1 Results

27.8 1.00 0.03 0.03 5.5 0.00

27.8 1.00 0.03 0.03 5.5 0.00
28.0 1.00 0.03 0.03 5.5 0.00

Page 4
 CEM Continuous Stirred Tank Reactor - Run 1 Results

Final Calculated Current Current Conversion Production Specific ln ((a - a1)/

NaAC Final NaOH NaAC of of Rate (a - a0))
Concentration Conductivity Concentration Concentration NaOH NaAC Constant
[mol/dm³] [mS] [mol/dm³] [mol/dm³] [%] [%] K
0.00 11.1 #DIV/0! #DIV/0! #DIV/0! 0.00 #DIV/0! 0.000
0.00 11.1 #DIV/0! #DIV/0! #DIV/0! 0.00 #DIV/0! 0.000
0.00 11.0 #DIV/0! #DIV/0! #DIV/0! 0.00 #DIV/0! 0.000
0.03 2.0 0.13 -0.11 -4.22 -4.22 -0.017 1.653
0.03 2.0 0.13 -0.11 -4.26 -4.26 -0.016 1.661
0.03 2.0 0.13 -0.11 -4.30 -4.30 -0.016 1.669
0.03 2.0 0.13 -0.11 -4.34 -4.34 -0.016 1.675
0.03 2.0 0.13 -0.11 -4.36 -4.36 -0.016 1.680
0.03 2.0 0.13 -0.11 -4.36 -4.36 -0.016 1.679
0.03 1.9 0.13 -0.10 -4.15 -4.15 -0.017 1.640
0.03 2.0 0.12 -0.10 -3.91 -3.91 -0.017 1.592
0.03 2.0 0.12 -0.10 -3.84 -3.84 -0.017 1.577
0.03 2.0 0.12 -0.09 -3.74 -3.74 -0.018 1.556
0.03 2.0 0.11 -0.09 -3.56 -3.56 -0.018 1.517
0.03 2.0 0.11 -0.09 -3.52 -3.52 -0.018 1.509
0.03 2.0 0.11 -0.09 -3.44 -3.44 -0.019 1.490
0.03 2.0 0.11 -0.08 -3.37 -3.37 -0.019 1.475
0.03 2.0 0.11 -0.08 -3.23 -3.23 -0.019 1.442
0.03 2.0 0.10 -0.08 -3.16 -3.16 -0.019 1.426
0.03 2.1 0.10 -0.07 -3.00 -3.00 -0.020 1.386
0.03 2.1 0.10 -0.08 -3.03 -3.03 -0.020 1.393
0.03 2.1 0.10 -0.07 -2.95 -2.95 -0.020 1.373
0.03 2.1 0.10 -0.07 -2.94 -2.94 -0.020 1.371
0.03 2.1 0.09 -0.07 -2.79 -2.79 -0.021 1.332
0.03 2.0 0.10 -0.07 -2.82 -2.82 -0.021 1.339
0.03 2.0 0.09 -0.07 -2.75 -2.75 -0.021 1.322
0.03 2.1 0.09 -0.07 -2.66 -2.66 -0.021 1.297
0.03 2.1 0.09 -0.06 -2.56 -2.56 -0.022 1.269
0.03 2.1 0.09 -0.06 -2.44 -2.44 -0.022 1.235
0.03 2.1 0.08 -0.06 -2.31 -2.31 -0.022 1.197
0.03 2.1 0.08 -0.05 -2.13 -2.13 -0.023 1.142

Page 5
 CEM Continuous Stirred Tank Reactor - Run 1 Results

0.03 2.0 0.08 -0.05 -2.19 -2.19 -0.023 1.160

0.03 2.0 0.08 -0.05 -2.09 -2.09 -0.023 1.128
0.03 2.1 0.08 -0.05 -2.05 -2.05 -0.023 1.116

Page 6
 CEM Continuous Stirred Tank Reactor - Run 1 Results

Measured Optional Optional

Conductivity Temperature Temperature
0-5 T2 T3
[mS] [°C] [°C]
0.01 31.4 199.9
0.01 31.4 199.9
0.01 31.4 199.9
0.01 31.4 199.9
0.01 31.4 199.9
0.01 31.4 199.9
0.01 31.4 199.9
0.01 31.5 199.9
0.01 31.4 199.9
0.01 31.3 199.9
0.01 30.8 199.9
0.01 30.2 199.9
0.01 29.7 199.9
0.01 29.4 199.9
0.01 29.1 199.9
0.01 28.9 199.9
0.01 28.8 199.9
0.01 30.1 199.9
0.01 31.3 199.9
0.01 30.5 199.9
0.01 29.9 199.9
0.01 30.0 199.9
0.01 29.8 199.9
0.01 29.5 199.9
0.01 29.4 199.9
0.01 29.8 199.9
0.01 31.0 199.9
0.01 30.3 199.9
0.01 30.2 199.9
0.01 30.1 199.9
0.01 29.6 199.9

Page 7
 CEM Continuous Stirred Tank Reactor - Run 1 Results

0.01 29.6 199.9

0.01 29.7 199.9
0.01 30.3 199.9

Page 8
 CONCENTRACIÓN
NaOH 1 - CSTR*
No.
CONDUCTIVIDAD
M (mol/L)
K (mS/cm)
0 0.0000 0.0100
1 0.010 2.43
2 0.020 4.58
3 0.040 9.06
4 0.059 13.37
5 0.079 17.28
6 0.096 19.04
7 0.117 19.99

* MARCADO

CONDUCTIVIDAD vs [NaOH]
K (mS/cm)

26
24
22
20
18
16
14
12
10
8
6
4
2
0
0.00 0.02 0.04 0.06 0.08 0.10 0.12
1 3 4 NaOH (mol/L)
 CALIBRACIÓN CONDUCTIVÍMETROS
1 - CSTR* 2 - PFR 3 - PORTÁTIL 24*
TEMPERATURA CONDUCTIVIDAD TEMPERATURA CONDUCTIVIDAD TEMPERATURA
T (°C) K (mS/cm) T (°C) K (mS/cm) T (°C)
22.2 0.0200 18.6 0.0030 20.4
21.2 1.86 18.3 2.15 20.6
20.9 4.17 18.3 4.09 20.4
21.2 7.63 18.3 8.32 20.6
21.5 11.23 18.2 12.48 20.5
20.7 15.50 18.3 16.20 20.5
20.9 18.86 18.3 20.20 20.6
20.7 19.99 18.4 24.20 20.6
NaOH (mol/L)

[NaOH] vs CONDUCTIVIDAD
VIDAD vs [NaOH]
0.12

0.10

0.08

0.06

0.04

0.02
0.06 0.08 0.10 0.12
0.00
3 4 NaOH (mol/L) 0 2 4 6 8 10 12 14 16

1 3 4
 4 - PORTÁTIL 23
CONDUCTIVIDAD TEMPERATURA
K (mS/cm) T (°C)
0.0037 21.0
1.75 20.7
3.31 20.7
6.83 20.7
10.24 20.5
13.30 20.4
16.50 20.5
19.87 20.5

IDAD

12 14 16 18 20 22 24 26

4 K (mS/cm)
 NaOH 0.1
AcEt 0.1
Ko 18.43
K 3.75
Q 1.47
TETA 1

Measured Measured
Temp of Temp of
Conductivity Conductivity
Reactor Reactor Time (min) K°
High Range High Range
[°C] [K]
[mS] [microS]

28.7 301.7 00:00:00 19.99 19990.2 22.26668

28.3 301.3 00:00:30 19.99 19990.2 22.12653
28.0 301.0 00:01:00 19.99 19990.2 22.02141
27.7 300.7 00:01:30 19.99 19990.2 21.91629
27.2 300.2 00:02:00 19.99 19990.2 21.74110
26.8 299.8 00:02:30 19.99 19990.2 21.56590
26.4 299.4 00:03:00 19.99 19990.2 21.42575
26.1 299.1 00:03:30 19.99 19990.2 21.32063
25.8 298.8 00:04:00 19.89 19892.6 21.21551
25.4 298.4 00:04:30 19.09 19091.8 21.07536
25.9 298.9 00:05:00 18.43 18427.7 21.25055
26.6 299.6 00:05:30 18.37 18369.1 21.49583
27.0 300.0 00:06:00 18.13 18134.8 21.63598
27.2 300.2 00:06:30 17.59 17587.9 21.74110
27.2 300.2 00:07:00 17.46 17460.9 21.74110
27.2 300.2 00:07:30 17.17 17168.0 21.74110
27.2 300.2 00:08:00 16.94 16943.4 21.74110
27.2 300.2 00:08:30 16.46 16464.8 21.74110
27.6 300.6 00:09:00 16.32 16318.4 21.88125
27.9 300.9 00:09:30 15.83 15830.1 21.98637
27.9 300.9 00:10:00 15.93 15927.7 21.98637
28.0 301.0 00:10:30 15.67 15673.8 22.02141
28.0 301.0 00:11:00 15.64 15644.5 22.02141
28.0 301.0 00:11:30 15.13 15127.0 22.02141
27.8 300.8 00:12:00 15.18 15175.8 21.95133
27.8 300.8 00:12:30 14.96 14960.9 21.95133
27.9 300.9 00:13:00 14.66 14658.2 21.98637
28.1 301.1 00:13:30 14.35 14345.7 22.05645
28.0 301.0 00:14:00 13.92 13916.0 22.02141
28.0 301.0 00:14:30 13.48 13476.6 22.02141
27.9 300.9 00:15:00 12.84 12841.8 21.98637
27.8 300.8 00:15:30 13.03 13027.3 21.95133
27.8 300.8 00:16:00 12.68 12675.8 21.95133
28.0 301.0 00:16:30 12.59 12587.9 22.02141
 Koo CNaOH XNaOH CAcEt XAcEt CNaEt

8.53293 0.08342 0.16576 0.08342 0.16576 0.01658

8.45528 0.08437 0.15626 0.08437 0.15626 0.01563
8.39704 0.08509 0.14908 0.08509 0.14908 0.01491
8.33879 0.08581 0.14186 0.08581 0.14186 0.01419
8.24172 0.08703 0.12970 0.08703 0.12970 0.01297
8.14465 0.08826 0.11740 0.08826 0.11740 0.01174
8.06700 0.08925 0.10746 0.08925 0.10746 0.01075
8.00875 0.09001 0.09994 0.09001 0.09994 0.00999
7.95051 0.09003 0.09973 0.09003 0.09973 0.00997
7.87286 0.08498 0.15024 0.08498 0.15024 0.01502
7.96993 0.07874 0.21255 0.07874 0.21255 0.02126
8.10583 0.07665 0.23351 0.07665 0.23351 0.02335
8.18348 0.07397 0.26027 0.07397 0.26027 0.02603
8.24172 0.06923 0.30766 0.06923 0.30766 0.03077
8.24172 0.06829 0.31706 0.06829 0.31706 0.03171
8.24172 0.06612 0.33877 0.06612 0.33877 0.03388
8.24172 0.06446 0.35540 0.06446 0.35540 0.03554
8.24172 0.06091 0.39085 0.06091 0.39085 0.03909
8.31938 0.05898 0.41019 0.05898 0.41019 0.04102
8.37762 0.05476 0.45238 0.05476 0.45238 0.04524
8.37762 0.05548 0.44520 0.05548 0.44520 0.04452
8.39704 0.05341 0.46590 0.05341 0.46590 0.04659
8.39704 0.05320 0.46805 0.05320 0.46805 0.04680
8.39704 0.04940 0.50604 0.04940 0.50604 0.05060
8.35821 0.05015 0.49845 0.05015 0.49845 0.04985
8.35821 0.04857 0.51426 0.04857 0.51426 0.05143
8.37762 0.04615 0.53849 0.04615 0.53849 0.05385
8.41645 0.04347 0.56530 0.04347 0.56530 0.05653
8.39704 0.04051 0.59492 0.04051 0.59492 0.05949
8.39704 0.03728 0.62717 0.03728 0.62717 0.06272
8.37762 0.03280 0.67196 0.03280 0.67196 0.06720
8.35821 0.03435 0.65651 0.03435 0.65651 0.06565
8.35821 0.03176 0.68237 0.03176 0.68237 0.06824
8.39704 0.03076 0.69240 0.03076 0.69240 0.06924
Diametro (m) 0.15300
Altura (m) 0.10000
Atrans (m2) 0.04807
Q (ml/min) 50.00000
Q (m3/seg) 8.33E-07
A trans. (m2) 0.01839
ρ (kg/m3) 991.00000
µ (kg/m*s) 0.00100
Vel (m/s) 0.00005
Re 6.86969
Cp (j/kg*K) 4186
K (w/m*K) 0.607
Pr 6.89621
Nu 3.26907
h (W/m2*K) 12.96946
1/U 0.24945
U (W/m2*K) 4.00888
 Conversión vs tiempo
0.80000

0.70000

0.60000

0.50000

0.40000

0.30000

0.20000

0.10000

0.00000
00:00:00 00:02:52 00:05:45 00:08:38 00:11:31 00:14:24 00:17:16 00:20:09

[NaOH] vs Conductividad
0.10000 30.0
0.09000
 [NaOH] vs Conductividad
0.10000 30.0
0.09000
0.08000 28.0
Concnetración (M)

0.07000

Temperatura °C
26.0
0.06000
0.05000 24.0
0.04000
0.03000 22.0
0.02000
20.0
0.01000
0.00000 18.0
12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 23:57:07 00:00:00
Conductividad (mS)

Perfiles de concentración vs tiempo

0.18000
0.16000
0.14000
0.12000
0.10000
0.08000
0.06000
0.04000
0.02000
0.00000
23:57:07 00:00:00 00:02:52 00:05:45 00:08:38 00:11:31 00:14:24 00:17:16

NaOH Acetato de sodio Acetato de etilo

Conductividad vs tiempo
25.00

20.00
Conductividad (mS)

15.00

10.00

5.00

0.00
23:57:07 00:00:00 00:02:52 00:05:45 00:08:38 00:11:31 00:14:24 00:17:16
Tiempo (s)
 Temperatura °C
30.0
 Temperatura °C
30.0

28.0
Temperatura °C

26.0

24.0

22.0

20.0

18.0
23:57:07 00:00:00 00:02:52 00:05:45 00:08:38 00:11:31 00:14:24
Tiempo (min)