Professional Documents
Culture Documents
Paper
Slimicides
Chlorine Stabilizers
Defoamers
slide 2
Lonza Water Treatment
slide 3
Lonza Water Treatment – Product range
Biocides
Halohydantoins (Dantobrom®; BCDMH)
Quaternaries
Bardac® (DDAC); Barquat® (ADBAC);
Barquat® PQ & PQ-2
Isothiazolinone (Isocil® RW; Isocil® Ultra)
Preservative system
DMDMH / Isothiazolinone (Dantoserve®)
Dantogard® 2000
Stabilizer
Equinox® Stabilizer 15
Oil Field Corrosion Inhibitors
Carbonate Quat (Carboshield®)
Pyridine Quats (Uniquat®)
Imidazolidines; Imidazolidines quat (Unamine®)
Defoamers
Amides (Acrawax® C; Glycowax®)
PEG and PGE Esters (Pegosperse®; Polyaldo®)
slide 4
Lonza Water Treatment – main products
Equinox® Stabilizer 15 in combination with a Chlorine source
improves paper machine & cooling tower performance and extends run
time by controlling biological deposits on surfaces
Lonza Halohydantoins
Cost effective, fast-acting, broad spectrum bactericide, fungicide and
algicide applicable for many types of water systems
Lonza Quaternary Compounds
Broadly applicable, cost effective, as algaecides, bactericides,
slimicides and molluscicides
Isocil® RW
Broad spectrum biocide, compatible with organics and widely
applicable to many water based systems
Bardac® LF 18 – Non BPD region
cost effective, broad spectrum, easy to use algaecide for cooling water
systems
slide 5
Lonza Biocides
Lonza Halohydantoins
Lonza Halohydantoins – Water Treatment Uses
Existing Potential
Product Cooling Paper Pools/Spas Wastewater Potable
Dantobrom® x x x
BCDMH x x x x x
slide 8
Lonza Halohydantoins - Typical Uses
Industrial Water Treatment
1. Recirculating Cooling Water Systems
2. Once-Through Cooling Water Systems
3. Evaporative Condensers
4. Brewery Pasteurizers
5. Industrial Air Washers
6. Photoprocessing Wash Water
7. Paper And Paperboard Process Water
8. Influent Water Systems
(Lagoons, Flow-Through Filters, Etc.)
9. Sewage Systems (Septic Tanks, Leach Fields, Tank Lines,
Sewers, Lagoons, Sewage Effluent Water)
slide 9
Lonza Halohydantoin Biocides
Major Products:
1. Dantobrom® RW (DMH; MEH; Br; Cl)
2. BCDMH (DMH; Br; Cl)
slide 10
Lonza Halohydantoins – Composition
Dantobrom
60.0% Bromochlorodimethylhydantoin (BCDMH)
27.4% Dichlorodimethylhydantoin (DCDMH)
10.6% Dichloromethylethylhydantoin (DCMEH)
2.0% Inert (Max.)
BCDMH
97.7% Bromochlorodimethylhydantoin (BCDMH)
2.3% Inert (Max.)
slide 11
Lonza Halohydantoins – on-demand hydrolysis
CH3 CH3
O O
H2O R
R
+ HOBr
N N N N
Br Cl H Cl
O O
CH3 CH3
O H2O O
R R
+ HOCl
N N N N
H Cl H H
O O
slide 12
Lonza Halohydantoins – Application Rates
Industrial Water
Continuous Feed
Halogen: 0.5 to 1.5 ppm Cl2 Total Halogen
(0.1 to 0.2 ppm Cl2 Max Free)
Usage: 0.15 to 0.25 lbs/day/1,000 gallons system volume
0.18 to 0.30 kg/day/10M3 system volume
Slug or Shock Feed
Halogen: Max 1 to 2 ppm Cl2 Total Halogen
(Max 0.5 ppm Cl2 Free)
Usage: 3X/Wk 0.10 to 0.20 lbs/slug/1,000 gallons system volume
0.12 to 0.24 kg/slug/10M3 system volume
5-7X/Wk 0.03 to 0.06 lbs/slug/1,000 gallons system volume
0.04 to 0.07 kg/slug/10M3 system volume
Swimming Pools
Halogen: 0.5 to 1.5 ppm Cl2 Total Halogen (1-3 ppm Br2 )
Usage: 0.18 to 0.30 kg//10M3
Spas
Halogen: 1.5 - 3 ppm Cl2 Total Halogen (3 - 6 ppm Br2 )
Usage: 8 - 12 g /1.1 m3/day
slide 13
Dantobrom® and Dantoin® BCDMH Tablets
slide 14
Lonza Quaternaries & Amines
Lonza Quaternaries & Amines
R CH3
+ - R N CH2 Cl
R N CH3 Cl
+ CH3 -
CH3
BARDAC® BARQUAT®
where R = C8-C18
C H2 C H2 CH 2 NH2
N [C 5H11 N O]+ Cl-
H25 C12 C H2 CH 2 C H 2 N H2 n = 4-6
Lonzabac® 12 Barquat® PQ
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Lonza Quaternaries – Application areas
slide 17
Barquat® (ADBAC) - Bardac® (DDAC) comparison
ADBACs - Barquat®
Similar efficacies and performance properties
Foaming tendencies
slide 18
Lonzabac 12
Bis (3-aminopropyl) dodecyl amine (CH2)3NH2
N
(CH2)3NH2
■ Free of halogen
■ Low corrosion (against iron / steel)
■ Compatible with surfactants
■ Complimentary biocidal effect in combination with complexing agents
(e.g. EDTA, NTA)
■ Effective also under neutral conditions (pH 7-9, neutralization with e.g.
lactic acid, glycolic acid, H4 EDTA, H NTA)
■ Little residues on surfaces
■ Tuberculocidal efficacy
■ Easy to defoam
LPC Lonzabac 12 presentation (LMI 1) slide 19
Lonzabac 12 – Compatibility with surfactants
Compatibility
■ Lonzabac® 12 is compatible with cationic surfactants
■ Lonzabac® 12 is compatible with nonionic surfactants
■ Lonzabac® 12 is compatible with many anionic surfactants
(e.g. Fatty alcohol sulfate, Fatty alcohol ether sulfate etc.)
Remarks
■ All combinations must be checked for its chemical / physical stability and
biocidal performance
The efficacy is very much dependent on e.g. pH value and the amine /
surfactant ratio (typically 3 / 1).
■ Amines like Lonzabac® 12 are not compatible with aldehydes (e.g. in perfume)
Increasing Performance
pH 9 pH 14
Polymeric Quats
Barquat® PQ; Barquat® PQ-2
Polymeric Quats
Barquat® PQ and Barquat® PQ-2 are non foaming long chain
polymeric quaternary ammonium compounds which have
excellent performance against sessile and planktonic algae and
are also effective clarifiers
slide 25
Polymeric Quats - Efficacy
University of Barcelona algaecide test
Chlorella vulgaris
Algaecidal at 1.0 ppm
slide 26
Polymeric Quats – Application rates
Swimming Pools – Barquat PQ-2
Initial shock dose of 20-30 ppm
Maintenance dose of 5-10 ppm
10 ppm = 100g Barquat PQ-2/10,000 litres
slide 27
Polymeric Quats – Benefits
Non Foaming
can be used in heavily aerated water systems without the need for anti
foams
slide 28
Isothiazolinones: Isocil® RW; Isocil® Ultra
Isocil® RW & Ultra
N CH N CH
3 3
S S
Cl
5-chloro-2-methyl-4-isothiazolin-3-one 2-methyl-4-isothiazolin-3-one
slide 30
Isocil® RW
Strengths:
- Broad Spectrum Biocide
- pH insensitive up to 9.5
- Compatible with most organics
- Non-foaming liquid
- Easily deactivated with bisulfite
Weaknesses:
- Strong skin sensitizer & corrosive
- Incompatible with 10 and 20 amines and sulfides
- Only fair algaecide
- Slow kill rate
- Commercial Limitation
slide 31
Isocil® RW – Typical Uses
ppm Active
Recirculating Cooling Water 2.25 - 13
Air Washers 2.25 - 13
Pulp and Paper 3.3 - 11.25
Oil Field Applications 2.25 - 13
slide 32
Halogen Stabilizer
Equinox® Stabilizer 15
Equinox Stabilizer 15
Equinox Stabilizer 15
is a patented,
liquid,
Hydantoin programme,
which enhances hypochlorite efficacy
and reduces OBA’s, PAE, PAM, Starch and AKD requirements
in the paper industry
Application
paper industry
Industrial water applications (e.g. cooling towers)
slide 34
Equinox® Stabilizer 15 – Benefits
The Equinox programme (Equinox Stabilizer 15 + active chlorine source)
improves performance via:
Broad microbiological control of planktonic bacteria, fungi and yeasts and
exceptional control and inhibition of biofilms.
Ease of application and control via a simple two pump dosing system and
static T mixer.
Simple monitoring via DPD or Redox.
Cost effectiveness compared to both non- oxidising and oxidising
programmes.
Excellent environmental profile and safety in use.
Unlike Ammonium Bromide it is not pH dependant.
Any molar ratio combination greater than 1:1.5 can be used without risk of
problems.
slide 35
Equinox® Stabilizer 15 – Properties
Physical Characteristics
15% active aqueous solution
pH = 9.8
CH3
O
Stability
Crystallization point < 40oC
CH3
Stable for >1 year at 20oC
Stable for > 1 month at 50oC
DOT hazard Classification N N
Non-hazardous
DMH ingredient
H H
DMH Oral LD 50 (rat) >10,000mg/kg
Eye irritation: mild irritant O
Skin irritation: mild irritant
Registration status
EPA reviewed non-registered stabilizer
TSCA registered
slide 36
Equinox® Stabilizer 15 – Mechanism of Action
demand”. O O
Stabilized intermediate
slide 37
Equinox® Stabilizer 15
Microorganism
Up to six-fold increase in HOCL Efficacy.
Control
Worker Safety Non-Toxic and inert as supplied
slide 38
Halogen Stabilizer
CH3
Carboshield™ benefits:
Chloride free (Didecyl Dimethyl Carbonate Bicarbonate)
Excellent Corrosion Inhibitor through film forming effect in sweet conditions
Good environmental profile (including CEFAS Registration)
slide 40
Oilfield corrosion inhibitors – Carboshield™
Carboshield™ applications:
Completion fluids: wellbore cleaning
slide 41
Oilfield corrosion inhibitors – Uniquat™ 10-80 HQ
Uniquat™ 10-80 HQ is a Benzyl Alkyl Pyridine Quat with high
quaternization degree that offers an excellent cost performance
solution for challenging technical environments
Outstanding corrosion inhibition performance in acid conditions:
Sour gas fields
Sour oil fields
Acid stimulation jobs
High temperature stability (> 250 °C), ideal for:
Down-the-hole injection
Deep drilling applications
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Oilfield corrosion inhibitors – Uniquat™ 10-80 HQ
19% to 42% more quat than other alkyl pyridine Better cost performance
quats available on the market
Protect your assets under severe operating
conditions like sour fields or acid stimulation
jobs
Outstanding corrosion inhibition performance
Reduce Failure Risks
under acid protection
Reduce Operator risk by limiting H2S
leakage
Increase Operability
High water solubility (high quat content) Ideal for applications with high TDS and
Brines
High temperature stability > 250°C Ideal for deep drilling and down-the-hole
injection
Excellent stability over time - Long shelf life Efficacy remains consistent - No storage
issue with our product's shelf-life
Good chemical compatibility Easy to formulate with other quats, non ionic
surfactants and commonly used biocides
High Quality Product and High production batch No quality issue or change in performance
consistency that could impact the final product
performance.
slide 43
Back-up
Dantobrom® RW Typical Properties
Total Available Halogen as %Cl2 62
Available Chlorine, % Cl2 44
Available Bromine, % Br2 41
Total Insolubles, % <1
Water Solubility (g/100g @ 25C) 0.54
Color White
Odor Halogen
Briquette Wt. (grams) 12
Briquette Density (g/cm3) 1.6
Briquette Bulk Density (lb/ft3) 65
Briquette Dimensions, cm (L x W x T) 4 x 2 x 1.5
Stability In Water Stable
Moisture Retention (% @ 25C for 6 hrs.) 7
Melting Range (C) 120-148
Decomposition Temperature (C) 175
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