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Waves
February 7, 2005
Diffraction at Ultrasonic Waves
Contents
1 Introduction 3
2 Production of Ultrasound 3
6 Apparatus 22
6.1 Diffraction from Sonic-Waves . . . . . . . . . . . . . . . . . . 22
6.2 The Striae method . . . . . . . . . . . . . . . . . . . . . . . . 22
7 Problems 23
7.1 Experimental . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
7.2 General Problems . . . . . . . . . . . . . . . . . . . . . . . . . 23
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Diffraction at Ultrasonic Waves
1 Introduction
2 Production of Ultrasound
The oscillating systems used for the production of ultrasound waves should
be suitable for working with high frequencies. This means that all oscillating
systems with spring and mass separated, which are used for the production
of sound in the hearing range, can not be used to produce ultrasound since
we cannot increase their eigen frequencies above a certain value. Instead,
1
sound particles
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Diffraction at Ultrasonic Waves
109
108
105
104
Acoustic In air c = 330m / s
103 range 20 m ≥ Λ ≥ 20 mm
102
101
Earthquake waves
100 Infrasound
Λ ≥ 100m
10-1
For example: the wave length
of green light is λ ≅ 0.5 µm
in the ultrasound range, continua which are able to oscillate are used e.g.
cavities filled with gas or liquid and solid bodies in the form of plates or
bars. In these systems the elasticity of the material plays the role of the
spring, and the density together with the geometric properties play the role
of the mass i.e. the spring and mass are distributed continuously over the
oscillator.
One can simulate ultrasonic oscillation with frequencies up to about 100
kHz with purely mechanic oscillators. Examples of mechanical oscillators
are gas and liquid filled whistles, which work on the same principle as a set
of wind instruments. For the production of non-sinusoidal oscillations the
hole-siren can be used.
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Diffraction at Ultrasonic Waves
• Piezoelectric converters.
• Magnetostrictive converters.
• Electrodynamic converters.
• Electrostatic converters.
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Diffraction at Ultrasonic Waves
U2 = hii · ∆l
where h is the deformation constant (for quartz with low frequencies h11 =
4.9 · 109 V /m). For the same length variation, the voltages U1 and U2 thus
differ. The proportion U U1 for identical ∆l is described by the square of the
2
coupling coefficient k p
kii = dii · hii
In general the coupling coefficient at low frequencies is smaller than 1. How-
ever, with resonance support and low damping the coupling coefficient can
become nearly 1.
All crystals that show the piezoelectric effect have several similar qualities,
◦
they isolate well and have one or more polar axes. A 180 turn of a polar
axis does not result in the same state. The piezoelectric effect now appears
in the directions of the polar axes. Crystals on which the piezoelectric effect
can be observed are for example: lithium sulfate, tourmaline, zinc blende,
Seignette-salt and tartaric acid.
In a quartz crystal, which we want to study as an example, we have three
polar axes. Quartz has the chemical formula SiO2 and it forms hexagonal
crystals. Every Si-atom has four positive elementary charges and every O-
atom two negative elementary charges. Figure 2(a) shows a structural cell
of quartz.
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Diffraction at Ultrasonic Waves
X1
- - - - - -
X2
X3
Si + Si + Staggerd point of
the + and -
O- O- O- charges
O- Dipol moment
Si + Si +
Si + Si + O-
O-
+ + + + + +
(a) (b)
X1 , X2 and X3 are the polar axes. If we now apply, for instance, pressure in
direction of the X1 axis , we reach the situation depicted in figure 2(b) where
we see the resulting shift of the atoms and charges on the surface. Qualita-
tively the same shift can be achieved, if a thrust is applied perpendicularly
to the X1 axis (transverse piezoelectric effect).
Apart from this group of piezoelectric single crystals there is also a series
of ferroelectric substances. With theses substances the dipole moment is
not only produced by applying pressure or tension, but the electric dipoles
already exist within the crystal unit cell, similar to the magnetic moments
exist in e.g. F e. For this reason ferroelectric materials have a very high
dielectric constant. Applying an electric field at a high temperature aligns
these electrical dipole moments in the same way that a magnetic field aligns
the magnetic dipole moments in F e. When a ferromagnetic material in
an electric field is cooled down below a certain temperature, known as the
Currie-temperature, the aligned electric dipole moments “freeze”. The out-
come is a permanent macroscopic electric dipole. This modification remains
to a large extent, as long as the temperature of the sample does not rise
above the Curie-temperature. Above the curie temperature the polarization
disappears irreversibly, i.e. the sample must be polarized again using an
electric field.
In contrast to the example of a quartz piezo-crystal, ferromagnetic sound-
converters are not necessarily single crystals. Poly-crystaline materials are
sufficient, which can be produced in an inexpensive way and in various forms
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Diffraction at Ultrasonic Waves
∆l 1 K
= ·
l E F
where E is the elasticity module, K the applied force and KF is the tension.
For liquids or gases the compressibility H is used instead of E1 . In sys-
tems with static tension the isotermic compressibility is dominating, while
in high-frequency dynamic-tension systems the adiabatic compressibility is
dominating, since there is not enough time for the heat exchange between
the system and its surroundings.
without
strain
x x
K
K(x1 ) KR (x2 ) K (x2 )
with strain
x x2=x1+ x
Figure 3:
2
in the direction of the length
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Diffraction at Ultrasonic Waves
∂K ∂2ξ
K(x1 ) − K(x2 ) = dx = ρ 2 dF dx (2)
∂x ∂t
s r
∂2ξ 2
2∂ ξ E 1
− cs = 0, cs = = (3)
∂t2 ∂x2 ρ Had · ρ
t1>0
t0=0
cs
c st 1
x
x0 x1
This wave equation is valid for sound waves with small amplitudes ξ(x, t).
The most general solution of this equation has the form
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Diffraction at Ultrasonic Waves
Expansion wave
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Diffraction at Ultrasonic Waves
Ω 2π
where K = cs = Λ =wave number.
α1 is the amplitude of the outgoing wave from the converter and α2 is the
amplitude of the wave reflected from l (see figure 6). αα12 is the reflection
factor.
AeiΩt
x
x=0 x=l
We will assume total reflection from the barrier at location l, this would be
the case for an infinitely stiff barrier.
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Diffraction at Ultrasonic Waves
From the two boundary conditions above and equation (5) we obtain a
standing wave
∂ξ ∂ξ1
so ξ(l, t) = ξ1 (l, t), E = E1 (9)
∂x ∂x
In 1932 Debye and Sears discovered in the USA and Lucas and Biquard
discovered in France that transparent media diffract light when an ultra-
sound wave is sent trough them. This effect is a consequence of a periodical
variation of the refractive index, which in turn is a consequence of a local
periodical pressure change caused by the ultrasound wave. Figure 7 shows
the experimental setup which allows the observation of diffraction of light
by an ultrasonic wave.
A thin slit, lit up by the lamp La serves as a source of light. The lens L1
is placed in the distance of its focal length from the gap and thus produces
a broad beam of parallel light. The light then penetrates a transparent
medium (gas, liquid or solid) in which an ultrasonic wave transducer Q, lo-
cated perpendicularly to the direction of the incidence light beam, produces
elastic waves. For experiments with liquids or gases a container with plane-
parallel glass walls is required. The second lens L2 projects a real image S 0
of the gap S on a screen. If the ultrasound wave is excited, several orders of
the spectrum of the lamp La can be seen on both sides of S 0 . By introducing
a filter F into the path of the light beam we produce monochromatic light
and obtain only one interference strip of each order near S 0 .
To understand this phenomenon we must assume that the local periodical
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Diffraction at Ultrasonic Waves
La L S L1 L2
pressure changes of the elastic wave create local changes in the refraction
index of the medium. The surfaces of equal phase S(x, y, z) of the light
wave are then no longer plains (S(x, y, z) = k0 x for light propagation in
the x-direction.) but they become a sine function with the same period as
the ultrasonic wave. This arises from the fact that in an area with a higher
refractive index n the light wave travel slower than in an area with a lower
refractive index (c = cn0 ).
When we describe an elastic wave by the local density ρ(y, t) instead of by
the deflection ξ(y, t) we can easily convince our selfs that we obtain
∂ξ(y, t)
ρ(y, t) = ρ0 + ρ0 · (10)
∂y
The relation between the refractive index, the dielectric constant ε and the
density ρ is described by the well-known Clausius-Mossotti equation from
the theory of the dielectric constants.
1 ε−1 1 NL
· = · · α = const. (12)
ρ ε+2 3ε0 M
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Diffraction at Ultrasonic Waves
3ρ∆ε
∆ρ = (13)
(ε + 2)(ε − 1)
The light wave E(x, y, z, t) (or the field vectors D,H and B) obeys a wave
equation in the same way the ultrasonic wave does. The wave equations for
light can be obtained from Maxwell’s equations,
∂B
∇×E =− (15)
∂t
∂D
∇×H = (16)
∂t
∇·D =0 (17)
B = µ0 µH (18)
D = ε0 εE (19)
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Diffraction at Ultrasonic Waves
à !
∂2D~ ∂H~ 1 ~
∂B
=∇× =∇× · =
∂t2 ∂t µ0 µ ∂t
1 ³ ´ h i
− ∇× ∇×E ~ = − 1 ∆E ~ − ∇(∇ · E)
~
µ0 µ µµ0
~
∂2E 1
⇒ − ~ = 0.
· ∆E (20)
∂t2 εε0 µµ0
Analogously to the sound wave t term (εε0 µµ0 )−1/2 is equivalent to the
propagation speed of the phase c. Thus in vacuum c0 = √ε10 µ0 and in a
√ ~ stands for {E1 , E2 , E3 }.
medium c = cn0 (n = εµ). The abbreviation E
~ = ~u(x, y, z)eiωt leads to a time independent wave
The separation anzatz E
equation.
~
E(x, ~ iωt−kx
y, z, t) = Ae k = k0 n
From placing this result in the time independent wave equation (21) we see,
that in the extreme case of geometrical optics i.e. k0 → ∞, the equation is
satisfied if
µ ¶2 µ ¶2 µ ¶2
∂S ∂S ∂S
+ + = n2 (23)
∂x ∂y ∂z
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Diffraction at Ultrasonic Waves
1 1
∇Aj · ∇S = − · ∆S (24)
Aj 2
S(x, y, z) is called the eikonal. Surfaces that obey the equation S(x, y, z) =
const. are constant phase surfaces of the light wave and grad(S) then indicate
the direction of the light wave.
Under the condition that the temporal and local changes of the refractive
index n(y, t) are small compared to the temporal and local changes of the
source of light, i.e. Ωsound ¿ ωlight and Λsound À λlight we can use an
approximation of a slowly varying function n(y, t) instead of the constant
refractive index
Exact solutions of the eikonal equation (23) for our problem n = n0 +
∆n(y, t) might still be very difficult to calculate. However, the equation tells
us how one can obtain an image of the surfaces of constant phase using a
simple graphical method. If we have one known surface of a constant phase
(e.g. boundary condition) we can use it to construct a group of ”parallel
surfaces“ with constant infinitesimal gaps |∇S| = n(y). The construction
corresponds exactly to Huygen’s principle where each point of the wave
field is a starting point of a spherical wave. Draw such planes, or curves
of constant phase for an ultrasound wave, for a fixed point in time, i.e.
n = n0 + ∆n0 sin(KΛ) with ∆n0 < n0 .
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Diffraction at Ultrasonic Waves
l
2 R
r
∆y
I II III
ϕ x
l
2
x=0 x=a
Figure 8: Diffraction
EI = A0 ei(ωt−k0 x) (26)
1 i(ωt−k0 R)
∆EIII = EII · e · ∆y (28)
R
R∼
= r − y sin(ϕ) (29)
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Diffraction at Ultrasonic Waves
Z + 2l
A0 i(ωt−k0 ·n0 ·a−k0 ·r)
EIII = e e−i(k0 ·∆n0 ·a sin(Ωt−Ky)−k0 ·y sin(ϕ) dy
r − 2l
We can exactly expand the ei·sin −function in the integrand into a Fourier
series. We know
ν=+∞
X
i·a sin(α)
e = Jν (a)eiνα . (31)
ν=−∞
Jν are the Bessel functions of integer order. After exchange between the
integral and the sum, the integral turns into
X Z
ν=+∞ l
2
(−1)ν Jν (k0 ∆na)eiνΩt ei(k0 sin(ϕ)−νK)y dy
ν=−∞ − 2l
The integral is now simple to calculate and we obtain the following for the
light wave of region III
ν=+∞
A0 l −i(ko n0 a+kr) X
EIII = e (−1)ν Jν (k0 ∆n0 a) ·
r ν=−∞
sin[ 2l (k0 sin(ϕ) − νK)]
l
ei(ω+νΩ)t (32)
2 (k0 sin(ϕ) − νK)
Z τ
1
I = lim (E · E ∗ )dt (33)
τ →∞ τ 0
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Diffraction at Ultrasonic Waves
Calculating the last equation with EIII , we obtain a double sum of the form
X Z τ X
1
I∼
= lim Fν Fµ · ei(ν−µ)Ωt dt = Fν Fµ δνµ
τ →∞
νµ
τ 0 νµ
+∞
" #2
A20 l2 X 2 sin[ 2l (k0 sin(ϕ) − νK)]
I= 2 J (k0 ∆n0 a) · (34)
r ν=−∞ ν l
2 (k0 sin(ϕ) − νK)
2
The function sinx2 x (see figure 9) is maximal for x = 0 and drops rapidly
from each side of x = 0. Thus we have strong intensity (interference fringes)
around the angles ϕν in our wave field (r À l).
k0 sin ϕν − νK = 0 (35)
k λ0
ϕν ∼
=ν =ν (36)
k0 Λ
0.5
J1 2
0.3 J2 2
0.1
x
x
0 -0.1 0 1 2 3 4 5
−3π −2π −π +π +2π +3π
Figure 9:
We find that the distance of the interference fringes from each other is the
same as with a diffraction grating with a lattice constant of the length of
the ultrasonic wave.
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Diffraction at Ultrasonic Waves
+∞
X
Jν2 (x) = 1
ν=−∞
this means that the sum of intensities over all orders is a constant, which
corresponds to the intensity of the incident light.
Another special feature resulting from the movement of our phase grating
can be explained by wave equation (32) for EIII . The light observed in the
ν-th order does not have the original frequency ω but is shifted by ν-times
the frequency of the ultrasonic wave, see figure 10.
ων = ω + νΩ
ultrasound Ω
ω + 2Ω υ=2
ω+Ω υ=1
light ω
ω υ=0
ω−Ω υ = −1
ω − 2Ω υ = −2
Figure 10:
We can explain this frequency shift with the Doppler effect or with quantum
mechanics in an easy manner. In quantum mechanic the sound- and light-
(electromagnetic-) fields are quantized, i.e. the energy of a field of frequency
ω can only change between discrete values (~ω). A sonic-field of frequency
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Diffraction at Ultrasonic Waves
p~ = ~~k (38)
k~1 = k~0 + ν K
~ momentum conservation (39)
k1
k
k0
Figure 11:
|k1 | = ωc01 n = 2π
λ0 n =wave number of the incident light in a liquid with
refractive index n. (λ0 und c0 are values in a vacuum)
Here νΩ ¿ ω, which means |k1 | ∼
= |k0 | and thus from equation (41) we
obtain
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Diffraction at Ultrasonic Waves
αν K λ0
2 sin = αν ∼
=ν
2 k1 nΛ
The angle αν is the angle between incident and scattered photons in the
liquid. For perpendicular incidence of the photons on the liquid we observe
the scattered photons in air, nL = 1, at the angle ϕν (refraction law).
sin ϕν ∼ ϕν ∼
= =n
sin αν αν
λ0
so ϕν = ν
Λ
In the ν-th order of the diffraction spectrum we see now the photons that
absorbed ν phonons, or emitted ν phonons for ν < 0 respectively; corre-
spondingly, due to energy conservation, the frequency in the ν-th order is
shifted by νΩ.
6 Apparatus
Today we use red He-Ne laser with a wavelength of 6328 Å as a light source.
Since the laser beam is narrow and can be amid to arrive perpendicularly
to the cuvette the slit S as well as lenses L,L1 are not required (see figure
7). The laser width can thus be referred to as S. The laser beam coming
out of the container should then be focused on the screen using lens L2 till
a sharp image is obtained.
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Diffraction at Ultrasonic Waves
d' f4
d' > f 4
S L 1 L4 B P
7 Problems
7.1 Experimental
ρ1 c1 − ρ2 c2
R=
ρ1 c1 + ρ2 c2
(where ρ is density and c is the sound velocity) .
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Diffraction at Ultrasonic Waves
nxylene = 1.497
gr
ρ = 0.86
cm3
Watt
W = 1
cm2
Hint: calculate the power-density of the sonic wave as a function of
the amplitude A0
ξ(y, t) = A0 sin(Ωt − Ky)
24