→

CO + 2H2 CH3OH

CRCO = 8,314 ×(3,376+ 0,557× 10−3 T )

CRH2 = 8,314 ×(3,249+0,422 ×10−3 T )

CRCH3OH = 8,314 ×(2,21+12,216 ×10−3 T )

 ∆ C = 8,314 × (−7,663+10,815 ×10−3 T ) × 10−3kJ/mol

R

∆ G 0548,15 K −24,79 548,15 T

548,15
=
298 298 298 T
1
− ∫ (−90,13 ) + ∫ ∆ C dT 2 dT
[ R
]
548,15
8,314 ×10,815 ×10−3 ( 2 1
¿
−24,79
298
∫
298
[ −90,13 ×8,314 ×7,663 × ( T −298 ) +
2 ]
× T −2982 ) ×10−3 2 dT
T

 ∆ G 0548,15 K =32,5918kJ/mol¿ 32,5918 ×103J/mol

 ∆ G 0548,15 K =−RTln k f
0
∆ G548,15 K
 8,314 × 548,15
k f =e =7,8366 × 10−4

k y =1

 k f =k=7,8366 × 10−4

⇔
CO + 2H2 CH3OH

200 420 α

α 2α α

200 – α 420 – α α

−2
α 60
7,8366∗10−4 =
( 200−α ) × ( 420−α )2
×
620−2 α ( )
 α =90,919 (mol)
 e quilibriumCO ¿ 109,081 (mol) ; H2 ¿ 238,162 (mol) ; CH3OH ¿ 90,919 (mol)
  ∑ n=438,162 (mol)

109,081
 PCO = × 60=14,937 atm (PC = 3,5 MPa ; TC = 133K)
438,162
14,937 ×101325
 PC = =0,432
CO
3,5 ×106
 T C =4,1214
CO

 γ CO =1
238,162
 PH = × 60=32,607 atm (Pc = 1,3 MPa ; TC = 33,3K)
2
529,081
 PC =2,5414
H2

 T C =16,61
H2

 γ H =1
2

90,919
 PCH OH = ×60=12,45 atm (Pc = 7,95 MPa ; TC = 513,2K)
3
529,081
 PC CH3 OH
=0,189

 TC CH3 OH
=1,068

 γCH 3 OH =0,95

γ C H OH
¿> k γ = 3
=0,95
γ H × γ CO
2

¿> k y =0,95

7,836 × 10−4 −2
α 60
 k p=
0,95
= ×
(200−α )×(420−2 α ) 620−2 α ( )
 α =92,76 (mol)
 CO = 92,76 (mol) ; H2 = 234,48 (mol) ; CH3OH = 92,76 (mol)

 ∑ n=434,48 (mol)
107,24
 PCO = × 60=14,8 atm
434,48
  PC =0,42846
CO

 T C =4,1214
CO

 γ CO =1
 P H2 =32,38 atm
 PC =2,524
H2

 T C =16,61
H2

 γ H =1
2

 PC H OH =12,81 atm
3

 PC C H 3 OH
=0,163

 TC C H3 OH
=1,068

 γCH 3 OH =0,95

¿> k γ =k γ =0,95
old new

¿> ∑ n=434,48 (mol)

92,76 2 × 92,76
¿> X CO = =0,4638 ; X H 2= =0,22
200 420