Reaction A

Rate (x10^5 min/dm3.mol) Concetration (x10^3 dm3/mol) conc ^2 Rate versus concetration (Reaction A
3.8 1.78 703.1684
25.2 4.58 20.9764
60

Rate (x10^5 min/dm3.mol)

45 6.15 37.8225 f(x) = 10.4889889569199 x − 17.7119380300075
62.1 50
7.22 52.1284 R² = 0.971449559771627
40

30
Reaction B
20
Rate (x10^3 min/dm3.mol) Concetration (x10^2 dm3/mol) Conc^2
2 1 10 1
4.2 1.6 0 2.56
1 2 3 4 5 6
7.8 2.5 6.25
17.5 4.4 19.36 Concetration (x10^3 dm3/mol)

Rate Vs concentartion (Reaction B) Rate versus concetration^2

20
18
(Reaction A)
Rate (x10^3 min/dm3.mol)

16 f(x) = 4.60196746121831 x − 3.05467272039349 70

14 R² = 0.994787890429529
60
Rate (x10^5 min/dm3.mol)

12 f(x) = 1.189223782801 x + 0.103670011168063

R² = 0.999981708098301
10 50
8
40
6
4 30
2 20
0
0.5 1 1.5 2 2.5 3 3.5 4 10 4.5 5
Concetration (x10^2 dm3/mol) 0
0 10 20 30 40
Conc ^2
Rate Vs concentartion^2 (Reaction B)
20
18
Rate (x10^3 min/dm3.mol)

16 f(x) = 0.817371392594206 x + 1.91431911950676

R² = 0.991230777988579
14
12
10
8
6
4
2
0
0 5 10 15 20 25
Concetration^2
oncetration (Reaction A)

199 x − 17.7119380300075
627

4 5 6 7 8
ation (x10^3 dm3/mol)

concetration^2

0.103670011168063

30 40 50 60
Conc ^2
Rate (x10^6
min/dm3.mol)
Concetration
(x10^3 dm3/mol) Conc ^2
Rate Vs concentar
5.15 1.25 1.5625 250
72.5 4.76 22.6576
200.8 8.05 64.8025 200

Rate (x10^6 dm3.mol/min)

f(x) = 28.66539500347
R² = 0.9618309904867
150

100
Rate Vs concentartion^2 (Problem 4)
50
250
Rate (x10^6 min/dm3.mol)

200 0
f(x) = 3.08670876999402 x + 1.22105328411011 0 1 2 3 4
R² = 0.999858326666215
150 Concetration (

100

50

0
0 10 20 30 40 50 60 70
Concetratin^2
te Vs concentartion (Problem 4)

f(x) = 28.6653950034734 x − 41.5284845829455

R² = 0.961830990486778

1 2 3 4 5 6 7 8 9
Concetration (x10^3 dm3/mol)
 Reaction A
Concetration (x10^2
Time (1/min) dm3/mol) 1/ conc ln(conc)
0 1 1 0
20 0.84 1.190476 -0.174353
40 0.724 1.381215 -0.322964
100 0.506 1.976285 -0.681219
150 0.39 2.564103 -0.941609
200 0.335 2.985075 -1.093625
350 0.225 4.444444 -1.491655
450 0.18 5.555556 -1.714798 Conc vs tim
600 0.145 6.896552 -1.931022 1.2

Concetration (x10^2 mol/dm3l)

1
Conc vs time (Reaction A) f(x) = − 0.00414976993865 x + 0.9
R² = 0.999928311335328
0.8
1.2
Concetration (x10^2 mol/dm3)

0.6
1
0.4
0.8
f(x) = − 0.001280498211709 x + 0.754527953818159 0.2
0.6 R² = 0.767596526534332
0
0.4 0 50 100

0.2

0
0 100 200 300 400 500 600 700
1/ conc vs tim
Time (min)
7

6
1/ conc vs time (Reaction A) 5
8 f(x) = 0.021766760755306 x + 0.347
4
1/conc

R² = 0.794305141414422
7
f(x) = 0.009913488942127 x + 1.00654903119045 3
6 R² = 0.999474315124837
2
5
1/conc

1
4
3 0
0 50 100
2
1
0
0 100 200 300 400 500 600 700
Time (min)
Ln(conc) vs tim
0
0 50 10
f(x) = − 0.00848084398731
-0.2 R² = 0.944052555425607
-0.4

Ln(conc) vs time (Reaction A) -0.6

-0.8
Ln(conc)

0 -1
0 100 200 300 400 500 600 700
-1.2
f(x) = − 0.003175230646181 x − 0.254061497519715
-0.5 R² = 0.933115883579824 -1.4
-1.6
-1 -1.8
)
 0 50 10
f(x) = − 0.00848084398731
-0.2 R² = 0.944052555425607
-0.4

Ln(conc) vs time (Reaction A) -0.6

-0.8

Ln(conc)
0 -1
0 100 200 300 400 500 600 700
-1.2
f(x) = − 0.003175230646181 x − 0.254061497519715
-0.5 R² = 0.933115883579824 -1.4
-1.6
-1 -1.8
Ln(conc)

-2
-1.5

-2

-2.5
Time (min)
 Reaction B Reaction C
Concetration
Time (1/min) (x10^2 dm3/mol) 1/ conc ln(conc) Time (1/min)
0 1 1 0 0
40 0.835 1.1976047904 -0.1803235541 50
100 0.58 1.724137931 -0.5447271754 100
150 0.375 2.6666666667 -0.980829253 150
200 0.172 5.8139534884 -1.7602608022 200
250
300
Conc vs time (Reaction B) 400
1.2 600
Concetration (x10^2 mol/dm3l)

1
f(x) = − 0.00414976993865 x + 0.99907745398773 Conc vs time (Reacti
R² = 0.999928311335328
0.8 1.2

Concetration (x10^2 mol/dm3)

0.6 1
0.4 0.8
f(x) = − 0.001525049504951 x + 0.79181683168
0.2 0.6 R² = 0.828086774235995

0 0.4
0 50 100 150 200 250
Time (min) 0.2

0
0 100 200 300 40
1/ conc vs time (Reaction B) Time (min)
7

6
1/ conc vs time (Reacti
5
f(x) = 0.021766760755306 x + 0.347330021278501 18
4
1/conc

R² = 0.794305141414422 16
3 14
2 12 f(x) = 0.024452734091429 x − 1.1342275574
R² = 0.86476025498251
10
1/conc

1
8
0
0 50 100 150 200 250 6

Time (min) 4
2
0
0 100 200 300 400
Ln(conc) vs time (Reaction B) Time (min)
0
0 50 100 x + 0.137894553805856
f(x) = − 0.008480843987312 150 200 250
-0.2 R² = 0.944052555425607
-0.4 Ln(conc) vs time (Rea
-0.6
0
-0.8
Ln(conc)

0 f(x) = − 0.004727467111004
100 200 300 40
x − 0.02034693114
-1 -0.5 R² = 0.998200734698075
-1.2
-1.4 -1
(conc)

-1.6
-1.5
-1.8
 0 50 100 x + 0.137894553805856
f(x) = − 0.008480843987312 150 200 250
-0.2 R² = 0.944052555425607
-0.4 Ln(conc) vs time (Rea
-0.6
0
-0.8
Ln(conc)

0 f(x) = − 0.004727467111004
100 200 300 40
x − 0.02034693114
-1 -0.5 R² = 0.998200734698075
-1.2
-1.4 -1

Ln(conc)
-1.6
-1.5
-1.8
-2 -2
Time (min)
-2.5

-3
Time (min)
 Reaction C
Concetration
(x10^2 dm3/mol) 1/ conc ln(conc)
1 1 0
0.81 1.2345679012 -0.2107210313
0.62 1.6129032258 -0.4780358009
0.48 2.0833333333 -0.7339691751
0.37 2.7027027027 -0.9942522733
0.285 3.5087719298 -1.2552660987
0.225 4.4444444444 -1.4916548768
0.15 6.6666666667 -1.8971199849
0.06 16.666666667 -2.8134107168

Conc vs time (Reaction C)

− 0.001525049504951 x + 0.791816831683168
0.828086774235995

100 200 300 400 500 600 700

Time (min)

1/ conc vs time (Reaction C)

) = 0.024452734091429 x − 1.13422755741672
= 0.86476025498251

100 200 300 400 500 600 700

Time (min)

Ln(conc) vs time (Reaction C)

100 200
− 0.004727467111004 300 400
x − 0.020346931140115 500 600 700
0.998200734698075
 Ln(conc) vs time (Reaction C)
100 200
− 0.004727467111004 300 400
x − 0.020346931140115 500 600 700
0.998200734698075

Time (min)
Time (min) Volume CO2 (cm^3) Volume Reactant 1/Volume react LN(Volume react)
0 0 40.04 0.024975024975 3.68987895444702
330 2.25 37.79 0.026462026991 3.6320445173614
1200 8.3 31.74 0.031505986137 3.45757771509826
2400 14.89 25.15 0.039761431412 3.22485789654575
7760 31.14 8.9 0.112359550562 2.18605127673809
99999 40.04 0

Volume of reactant VS time

45
40
Volume of reactant (cm3)

35 f(x) = − 0.003876098387671 x + 37.7863180303757

R² = 0.966076962318287
30
25
20
15
10
5
LN(Volum
0 4
0 1000 2000 3000 4000 5000 6000 7000 8000 9000
3.5 f(x) = − 0.00019410474598
Time (min) R² = 0.999983328268684
3
2.5

LN(Volume)
1/(Volume reactant) VS Time 2
1.5
0.12
1
0.1 f(x) = 1.15510458212802E-05 x + 0.020006458885245
R² = 0.980238975922069 0.5
0.08 0
0 1000 2000 300
1/volume

0.06

0.04

0.02

0
0 1000 2000 3000 4000 5000 6000 7000 8000 9000
time (min)
 LN(Volume reactant) VS time
4
3.5 f(x) = − 0.000194104745982 x + 3.69189896814434
R² = 0.999983328268684
3
2.5
2
1.5
1
0.5
0
0 1000 2000 3000 4000 5000 6000 7000 8000 9000
Time (Min)
 p C2H4O remain
time (Min) p total (mmHg) (mmHg) Ln(pC2H4O) 1/pC2H4O
0 116.5 116.5 4.757891273 0.0085837
9 129.4 103.6 4.64053733 0.0096525
13 134.7 98.3 4.588024027 0.0101729
18 141.3 91.7 4.518522379 0.0109051
50 172.1 60.9 4.109233175 0.0164204
100 201.2 31.8 3.45946629 0.0314465

1/pC
p C2H4O intial 116.5 mmHg 0.035

0.03
f(x) = 0.000229597802
PC2H4O VS time 0.025 R² = 0.9764139980521

1/pC2H4O
140 0.02
120 0.015
100 f(x) = − 0.826955412809371 x + 109.98692140563 0.01
pC2H4O (mmHg)

R² = 0.972552491676763
80 0.005
60 0
0 20
40

20

0
0 20 40 60 80 100 120
time (min)

Ln(pC2H4O) VS time
5
4.5 f(x) = − 0.01296743616184 x + 4.75624789074971
4 R² = 0.999979564725362
3.5
Ln(pC2H4O)

3
2.5
2
1.5
1
0.5
0
0 20 40 60 80 100 120
time (min)
 1/pC2H4O VS timeO
0.035

0.03
f(x) = 0.000229597802209 x + 0.007259597622834
0.025 R² = 0.976413998052126

0.02

0.015

0.01

0.005

0
0 20 40 60 80 100 120
time (min)
time (s) [A]0 (x10^3 mol/dm3) 1/[A]0
590 8.13 0.123001
665 6.44 0.15528 1/[A]0
900 3.1 0.322581 0.6
1140 1.88 0.531915
0.5 f(x) = 0.000750867879
R² = 0.9928230870896
0.4
[A]0 VS time

1/[A]0
9 0.3
8
0.2
7
[A]0 (x10^3 mol/dm3)

f(x) = − 0.011266368196048 x + 14.1681708014946

R² = 0.936531246065933 0.1
6
5
0
4 500 600 700 8
3
2
1
0
500 600 700 800 900 1000 1100 1200
time (min)
 1/[A]0 Vs Time

f(x) = 0.000750867879848 x − 0.335333348050808

R² = 0.992823087089648

600 700 800 900 1000 1100 1200

time (min)
k x 10^4(L/mol.s) T (K) 1/T k ln(k)
0.503 289 0.00346 5030 8.5231753
3.68 305.2 0.003277 36800 10.513253
67.1 332.9 0.003004 671000 13.416524
1190 363.8 0.002749 11900000 16.292049

Ln(k) VS 1/T
18
16
f(x) = − 10891.752298661 x + 46.1941560331852
14 R² = 0.999848168765008
12
10
Ln(k)

8
6
4
2
0
0.0027 0.0028 0.0029 0.003 0.0031 0.0032 0.0033 0.0034 0.0035
1/T