Professional Documents
Culture Documents
MBR Problems
MBR Problems
Lecture 10
Solving Material Balances Problems
Involving Reactive Processes
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
2
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Input = Output
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
3
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Dehydrogenation of Ethane
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
4
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Dehydrogenation of Ethane
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
5
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
6
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
7
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Extent of Reaction
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
8
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
9
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
A =======> 2B
B =======> C
A =======> 2C
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
10
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
11
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Independent 2 (O or N, Cl or C)
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
12
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Sufficient air (21 mole% O2, 79% N2) is fed to provide 35%
excess oxygen and the fractional conversion of HCl is 85%.
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
13
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
14
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
15
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
yi = ni/nt
yHCl = n2/nt
yO2 = n3/nt
yN2 = n4/nt
yCl2 = n5/nt
yH2O = n6/nt
where nt = n2 + n3 + n4 + n5 + n6
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
16
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Unit: Reactor
unknowns (n1,n2,n3,n4,n5,n6) +6
independent chemical reaction +1
independent molecular species –5
other equations:
–2
35% excess O2 & fractional HCl conversion
Degrees of freedom 0
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
17
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
1molair
n1 33.75mol O 2 160.7 molair
0.21mol O 2
160.7 mol air molair
Required air 1.607
100 mol HCl mol HCl
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
18
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
19
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
20
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Component i ni (moles) y
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
21
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Unit: Reactor
unknowns (n1,n2,n3,n4,n5,n6) +6
independent atomic specie(s) –3
independent nonreactive molecular specie(s) –1
other equations:
–2
35% excess O2 & fractional HCl conversion
Degrees of freedom 0
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
22
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
23
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Unit: Reactor
unknowns (n1,n2,n3,n4,n5,n6) +6
independent chemical reaction(s) +1
independent reactive molecular species –4
independent nonreactive molecular species –1
other equations:
–2
35% excess O2 & fractional HCl conversion
Degrees of freedom 0
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
24
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Extent of Reaction:
Cl2: n5 = 0 + (1)
H2O: n6 = 0 + (1)
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
25
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
26
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
27
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Unit: Reactor
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
28
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
C2 H 4
Stoichiometric Ratio : 1.0
HBr S
C2 H 4 x 165mol / s x
Actual Ratio :
HBr A (1 x)(165mol / s) 1 x
C-Balance
H-Balance
Br-Balance
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
29
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
C-Balance:
Br-Balance:
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
30
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
Solving simulateneously,
Solving for the actual ratio of C2H4 and HBr in the feed:
C2 H 4 0.545
1.0
HBr A 1 0.545
Therefore, HBr is limiting.
actual stoichiometric
% excess C 2 H 4 100
actual
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
31
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
89.93 75.08
% excess C2 H 4 100 19.8%
75.08
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
32
LECTURE 10. Solving Material Balance Problems Involving Reactive Processes
SLIDE
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baños
33