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題型拆解 + 終極題庫
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DSE CHEM MASTERY
八大題型全攻略
題型#1 Mole & Avogadro Constant ................................................................. 2
另外每個題型我均附上一個詳細的拆題思路,此部分為整本筆記最有價值的地方,你在落手去嘗試相關
題型前必須先仔細閱讀,然後再去嘗試運用該拆題思路去完成筆記剩餘的練習!筆記的最後部分有詳細
的 Marking Scheme,你完成可以自行核對,有任何其他 CHEM 的問題請隨時 WhatsApp 與我聯絡!
P.S. 停課放大假期間大家要務必繼續努力,不要讓未來的自己後悔!
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題型#2 MOLE & AVOGADRO CONSTANT
Key Concept
§ One mole is the amount of a substance that contains the same number of particles as there are
atoms in 12.0 g of carbon-12.
# 𝐨𝐟 𝐏𝐚𝐫𝐭𝐢𝐜𝐥𝐞𝐬
𝐌𝐨𝐥𝐞 =
𝐋
Question 1
A water bottle contains 1.5 mole of H2O molecules.
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Question 2
Given that a beaker contains 1.204 x 1024 potassium atoms. How many moles of potassium atoms are
there in the beaker?
Question 3
How many molecules and atoms are there in 2.50 moles of carbon dioxide molecules?
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題型#3 找出 PERCENTAGE BY MASS
Key Concept
Question 4
Calculate the percentage by mass of copper in copper(II) oxide (CuO).
Step 1: 搵出主角
題目要求你搵 % by mass of Cu in CuO,所以主角就是 CuO 裡面的 Cu
Step 2: 將相關數值放進公式
R. A. M. of Cu 63.5
% by mass of Cu in CuO = = × 100% = 79.87%
Molar Mass of CuO 63.5 + 16
Question 5
Ammonium nitrate (NH4NO3) is used as a fertilizer due to the high usable nitrogen content. What is the
percentage by mass of nitrogen in ammonium nitrate?
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Question 6
Calculate the percentage by mass of water in hydrated magnesium chloride (MgCl2.6H2O). (Relative
atomic masses: H = 1.0, O = 16.0, Mg = 24.3, Cl = 35.5)
Question 7
Ammonium sulphate, (NH4)2SO4. Is one of the most frequently used substances in a lot of fertilizers.
What is the percentage by mass of nitrogen in the compound?
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題型#4 利用 % BY MASS 找出其他數值
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐚𝐧 𝐄𝐥𝐞𝐦𝐞𝐧𝐭 𝐢𝐧 𝐚 𝐂𝐨𝐦𝐩𝐨𝐮𝐧𝐝
= 𝐦𝐚𝐬𝐬 𝐨𝐟 𝐭𝐡𝐞 𝐜𝐨𝐦𝐩𝐨𝐮𝐧𝐝 × % 𝐛𝐲 𝐦𝐚𝐬𝐬 𝐨𝐟 𝐞𝐥𝐞𝐦𝐞𝐧𝐭 𝐀 𝐢𝐧 𝐭𝐡𝐞 𝐜𝐨𝐦𝐩𝐨𝐮𝐧𝐝
Question 8
Calculate the mass of carbon in 32.0 g of ethanoic acid (CH3COOH).
Step 1: 先拆題
12 × 2
= × 100% = 40%
12 × 2 + 1 × 4 + 16 × 2
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Question 9
The bromine of a metal M has the formula of MBr3 and contains 18.9% by mass of M. Calculate the
relative atomic mass of M. Hence, deduce what M is.
Step 1: 先拆題
R. A. M. of M
% by Mass of M = 18.9% = × 100%
Molar Mass of MBr!
m
18.9% = × 100%
m + 79.9 × 3
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Question 10
A metal oxide M2O3 contains 69.9% by mass of metal M. Find the relative atomic mass of M.
(Relative atomic mass: O = 16.0)
Question 11
What is the mass of nitrogen present in the sample of potassium nitrate which contains 100 g of
potassium?
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Question 12
What is the mass of water of crystallization present in the sample of sodium carbonate-10-water
(Na2CO3.10H2O) which contains 9.2 g of sodium?
Question 13
1.554 g of CuxO is heated in the presence of CO to give 1.242 g of Cu. Calculate the number of x.
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Question 14
Gypsum (CaSO4 . nH2O) contains 20.9% by mass of water. What is the value of n?
(Relative atomic masses: H = 1.0, O = 16.0, S = 32.1, Ca = 40.1)
Question 15
An ionic compound of chemical formula A2O3 contains 68.5% by mass of A. What is the relative atomic
mass of A?
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題型#5 MOLE RATIO & REACTING MASS
§ mole ratio: the stoichiometric coefficients in the equation
Question 16
Consider the following reaction:
Step 1: 先拆題
題⽬需要我們找出 lead oxide, Pb3O4(s) 的質量,所以我們應按以下流程找到答案:
Step 2: 計算 Mole of Pb
這部分不算難,利用題目給予的 mass 除以 R.A.M. of Pb 即可:
89
= 0.42995 mol
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Step 3: 計算 Mole of Pb3O4
Pb : Pb3O4 = 3 : 1
Mole of Pb 0.42995
Mole of Pb! O" = ×1= × 1 = 0.14332 mol
3 3
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Question 17
42.8 g of impure copper was dissolved in concentrated HNO3. The mixture was concentrated by
heating to give copper (II) nitrate. On strong heating 47.7 g of copper (II) oxide was produced. Calculate
the percentage by mass of copper in the sample.
Question 18
Copper(I) sulphide reacts with oxygen according to the following chemical equation:
Cu# S(s) + O# (g) → 2Cu(s) + SO# (g)
Calculate the mass of copper formed when 42.3 g of copper(I) sulphide react completely with oxygen.
(Relative atomic masses: S = 32.1, Cu = 63.5)
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Question 19
Gunpowder is a mixture of potassium nitrate, sulphur powder and charcoal powder. When this
gunpowder is ignited, solid potassium sulphide, nitrogen gas and carbon dioxide gas are formed.
a) Write the balanced equation for the reaction occurs upon the ignition of the gunpowder.
b) What is the mass of carbon required to react with 49.8 g of potassium nitrate?
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Question 20
Sodium azide (NaN3) is used in airbags in cars. When there is a serious collision, the azide will
decompose to give nitrogen. The decomposition can be represented by the equation:
2NaN! (s) → 2Na(s) + 3N# (g)
What is the mass of nitrogen produced when 3.90 g of sodium azide decompose?
Question 21
In an oxide of metal A, the ion of A carries +1 charge. Complete decomposition of 5.22 g of the oxide
gives 4.86 g of metal M. What is the relative atomic mass of M?
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題型#6 LIMITING REAGENT AND EXCESS REAGENT
KEY CONCEPT
Question 22
Calculate the mass of zinc formed when 16.28 g of zinc oxide are heated with 5.23 g of carbon powder.
也就是說明明我們只需 0.1 mol 的 C 去完全反應 0.2 mol 的 ZnO,但現在我們有 0.436 mol 的 C,比所
需的高出四倍有多!
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Question 23
Carbon dioxide and calcium hydroxide reacts according to the following equation:
CO# (g) + Ca(OH)# (aq) → CaCO! (s) + H# O(l)
15 g of carbon dioxide was added to a solution containing 90 g of calcium hydroxide. Calculate the
theoretical mass of calcium carbonate that can be obtained.
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Question 24
Copper reacts with concentrated sulphuric acid according to the following equation:
Cu + 2H# SO" → CuSO" + SO# + 2H# O
38 g of copper was added to 72 g of sulphuric acid. Calculate the theoretical mass of copper(II)
sulphate and water that can be produced.
Question 25
When heated, lithium reacts with nitrogen to form lithium nitride as shown in the equation below:
6Li(s) + N# (g) → 2Li! N(s)
6.32 g of lithium was heated with 7.88 g of nitrogen. Calculate the mass of lithium nitride formed.
(Relative atomic masses: Li = 6.9, N = 14.0)
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Question 26
Titanium can be prepared by the reaction of titanium(IV) chloride with molten magnesium.
TiCl" (g) + 2Mg(l) → Ti(s) + 2MgCl# (l)
Calculate the mass of titanium obtained when 6.32 x 106 g of magnesium were allowed to react with
2.33 x 107 g of titanium(IV) chloride.
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Question 27
76.2 g of zinc was heated with 23.1 g of oxygen in a vessel. Calculate the mass of the product that can
be produced.
Question 28
Iron reacts with concentrated sulphuric acid according to the following equation:
2Fe + 6H# SO" → Fe# (SO" )! + 3SO# + 6H# O
24 g of iron was added to 90 g of sulphuric acid. Calculate the theoretical mass of iron(III) sulphate and
water that can be produced.
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題型#7 利用 % BY MASS 找到 EMPIRICAL FORMULA
乜係 Empirical formula?
Question 29
Compound X was found to contain iron and oxygen only. Experiments showed that it contains 70%
iron and 30% oxygen by mass. Calculate the empirical formula of X.
(Relative atomic masses: Fe = 55.8; O = 16.0)
Step 1: 找出主角
以這題為例,主角們就是 Fe 和 O 兩位了!
Fe O
Mass 70 g 30 g
Mole
Ratio
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Step 3: 分別找出主角的 Mole 數
Fe O
Mass 70 g 30 g
70 30
Mole = 1.254 mol = 1.875 mol
55.8 16
Ratio
Fe O
Mass 70 g 30 g
70 30
Mole = 1.254 mol = 1.875 mol
55.8 16
1.254 1.875
Ratio =1 = 1.49 ≈ 1.5
1.254 1.254
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Question 30
An experiment was performed to determine the empirical formula of an oxide of zinc. The experimental
results are tabulated below. Determine the empirical formula of the oxide of zinc using the above data.
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Question 31
Compound Y contains 39.1% sulphur, 58.5% oxygen and 2.4% hydrogen by mass. Find the empirical
formula of Y.
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題型#8 從 EMPIRICAL FORMULAE 找出
MOLECULAR FORMULAE
首先你要知道 “Empirical Formula” 和 “Molecular Formula” 之間有什麼分別!
Question 32
Compound Y was found to contain carbon and hydrogen only. Experiment showed that it contained
82.8% carbon and 17.2% hydrogen by mass.
(Relative atomic masses: H = 1.0, C = 12.0)
C H
82.8
Mole = 6.9 mol 17.2 mol
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6.9 17.2
Ratio =1 = 2.49 ≈ 2.50
6.9 6.9
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Molar Mass = 58 = n × Molar Mass of C! H"
58 = n × (12 × 2 + 1 × 5)
n=2
由於 n = 2,所以 Y 的 Molecular Formula 就是 C4H10.
Question 33
A compound Z contains 94.2 % of oxygen and 5.8 % of hydrogen by mass. The mass of 10 mol of this
compound is 340 g.
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Question 34
Epsom salts are hydrated salts of magnesium sulphate with formula MgSO4 . nH2O, which can be used
as bath salts to relieve pains and aches. Experiments were carried out to find the formula of the salt. It
was found that it contained 57.37% by mass of water of crystallization. Find the value of n.
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Question 35
Chlorine reacts with sulphur to form a compound with relative molecular mass of 103. The compound
contains 69.0% of chlorine by mass.
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題型#9 利用 COMBUSTION 實驗結果找出
MOLECULAR FORMULA
這 類 題 型 其 實 跟 上 兩 類 的 目 標 都 是 一 樣 , 也 是 要 求 你 去 找 到 一 個 Compound 的 Empirical
Formula/Molecular Formula。
Question 36
Compound Y containing only carbon, hydrogen and oxygen burnt completely in air to form carbon
dioxide and water as the only products. 7.30 g of Y gave 11.87 g of carbon dioxide and 4.04 g of water.
Determining the empirical formula of Y. If its relative molecular mass is 486, determine the molecular
formula of Y.
Step 1: 先拆題,找出我們需要找的重點
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Mass of C = (% by mass of C in CO# ) × (mass of CO# ) = × 11.87 = 3.237 g
12 + 16 × 2
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相同道理,我們可以從 H2O 的 mass 中找出 H 的 mass:
1×2
Mass of H = (% by mass of H in H# O) × (mass of H# O) = × 4.04 = 0.449 g
1 × 2 + 16
C H O
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Question 37
A compound containing only carbon, hydrogen and oxygen. 2.03 g of the compound gave 3.30 g of
carbon dioxide and 1.13 g of water on complete combustion. Find the empirical formula of the
compound. If the relative molecular mass of the compound is 324.0, find its molecular formula.
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