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NETWORKS

HEAT EXCHANGER

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


1
Aim is….

The design of a heat exchanger network for a simple process

with only one or two streams that need heating and cooling is

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


usually straightforward.

When there are multiple hot and cold streams, the design is

more complex, and there may be many possible heat exchange

networks.

2
Aim is….
The design engineer must determine the optimum extent of
heat recovery, while ensuring that the design is flexible to
changes in process conditions and can be started up and

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


operated easily and safely.

3
The word exchanger really applies to all types of equipment in which heat is
exchanged but is often used specifically to denote equipment in which heat is
exchanged between two process streams.

Exchangers in which a process fluid is heated or cooled by a plant service

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


stream are referred to as heaters and coolers.

If the process stream is vaporized, the exchanger is called a vaporizer if the


stream is essentially completely vaporized,
a reboiler if associated with a distillation column,
an evaporator if used to concentrate a solution.
The terms fired exchanger and fired heater are used for exchangers heated
by combustion gases, such as boilers;
other exchangers are referred to as unfired exchangers.

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Heat - transfer Fluids
Water
Critical pressure and temperature values of water are 220 bar and 373.14° C.
Steam is a valuable heating agent below 200° C, where the saturation pressure
is about 24 bar. Superheated steam can be used to enlarge the temperature
range.
Liquid water is excellent for cooling, but also for heating at mild temperatures

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


below 100 ° C. For higher temperatures thermal fluids are more suitable.

Salt Brines
Salt brines are water solutions of inorganic salts. Aqueous CaCl2 solutions of
maximum 25% are recommended down to −20 ° C. Salt brines are low cost but
expensive in operation. Antifreezes described below are preferable.

Glycol Solutions
Ethylene glycol can be used in principle down to −35 °C, but in practice is
limited to −10 °C because of high viscosity. Propylene glycol has the advantage
of being nontoxic. Other antifreeze fluids, such as methanol and ethanol
solutions raise safety and toxicity problems.

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Heat - transfer Fluids
Refrigerants
Refrigerants remove heat from a body or process fluid by vaporization.
Ammonia (R717) seems to be popular again after years of decline in favor of
chlorinated hydrocarbons (CFCs).

Because of damage to the ozone layer, the CFCs

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


are being replaced by refrigerants based on hydrochlorofluorocarbons (HCFC),
although these are not completely inoffensive.

Thermal Fluids

By using thermal fluids


the heat- transfer
operations can be carried
out over a larger
temperature interval but
at reasonable operating
pressures.

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Heat - transfer Fluids
Inorganic Salts
Several formulations are known but the most widely used salt is a molten
mixture of the eutectic NaNO2 (40%)/NaNO3 (7%) /KNO3 (53%), for
operation between 146° C (melting point) and 454° C.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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Heat - Exchangers
Shell - and - tubes Heat Exchangers

Heat-transfer area per unit volume is greatly increased by placing a large


number of small-diameter tubes inside a shell, that is, a pressure vessel.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


Shell-and-tube heat exchanger - 1-1 fixed head

Segmental baffles

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Heat - Exchangers
Shell - and - tubes Heat Exchangers

When employing a shell-and-tube heat exchanger, a decision must be made as to


which fluid passes through the tubes (tube side) and which passes through the
shell outside the tubes (shell side).

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


NOTE:
 The tube side is for corrosive, fouling, scaling, hazardous, high-
temperature, high-pressure, and more expensive fluids.
 The shell side is for more viscous, cleaner, lower-flow rate, evaporating,
and condensing fluids

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Shell - and - tubes Heat Exchangers

Rules for fluid side selection are:


1. Corrosion: most corrosive fluid to the tube side
2. Fouling: fouling fluids in tubes.
3. Fluid temperatures: high- temperature fluid in tubes.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


4. Pressure: high- pressure fluids in tubes.
5. Pressure drop: lower pressure drop can be obtained in one or two passes.
6. Condensing steam and vapor at low pressures: shell side.
7. Condensing gas– liquid mixtures: tube side with vertical position.
8. Stainless and special steels: corresponding fluid in tubes.

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Shell-and-tube heat exchanger - 1-2 fixed head

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


Shell-and-tube heat exchanger - 1-2 floating head

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Shell-and-tube heat exchanger - 1-2 U-tube

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


Shell-and-tube heat exchanger - 2-4 floating head

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Overall heat - transfer coefficients for shell - and - tubes heat exchangers.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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Overall heat - transfer coefficients for shell - and - tubes heat exchangers.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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Overall heat - transfer coefficients for air - cooled heat (bare tube basis).

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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Overall heat - transfer coefficients for jacketed vessels.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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Overall heat - transfer coefficients for immersed coils in agitated vessels.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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Air - cooled Heat Exchangers

When cooling water is scarce, air is used for cooling and condensing liquid
streams in fin-fan heat exchangers.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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Compact Heat Exchangers

When the two fluids


exchanging heat must be kept

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


clean, plate-and-frame heat
exchangers made of stainless
steel are commonly used.

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Plate Heat Exchangers
Gasketed Plate Heat Exchangers
Selection:
The advantages and disadvantages of plate heat exchangers, compared with
conventional shell and tube exchangers, are as follows:

Advantages

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


1. Plates are attractive when material costs are high.
2. Plate heat exchangers are easier to maintain.
3. Low approach temps can be used, as low as 1oC,
compared with 5 to 10oC for
shell and tube exchangers.
4. Plate heat exchangers are more flexible; it is easy
to add extra plates.
5. Plate heat exchangers are more suitable for highly
viscous materials.
6. The temperature correction factor, Ft, will
normally be higher with plate heat
exchangers, as the flow is closer to true counter-
current flow.
7. Fouling tends to be significantly less in plate heat
exchangers; 20
FIRED HEATERS (FURNACES AND BOILERS)

 Furnaces (also called fired heaters) are often used to heat, vaporize, and/or
react process streams at high temperatures and high flow rates.
 Heat duties of commercial units are in the range of 3 to 100 MW
(10,000,000 to 340,000,000 Btu/hr).

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


Typical applications of fired heaters are
1. Process feed-stream heaters, such as the feed heaters for refinery crude
columns (pipe stills), in which up to 60% of the feed may be vaporized;
2. Reboilers for columns, using relatively small-size direct-fired units;
3. Direct-fired reactors, for example, the pyrolysis of dichloroethane to form vinyl
chloride;
4. Reformers for hydrogen production, giving outlet temperatures of 800–900 o C;
5. Steam boilers.

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Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek
22
(HEND)
NETWORK DESIGN
HEAT EXCHANGER

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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Pinch Technology
The development and application of the method can be
illustrated by considering the problem of recovering heat
between four process streams:
two hot streams that require cooling and two cold streams

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


that must be heated.

Each stream starts from a source temperature: Ts

Each stream is to be heated or cooled to a target temperature: Tt

The heat capacity flow rate of each stream is : CP


For streams where the specific heat capacity can be taken as constant, and there is no
phase change :
m = mass flow rate, kg/s;
Cp = average specific heat capacity between Ts and
Tt kJ/ kg C 24
Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek
Some heat is exchanged between the streams in the heat exchanger.

Additional heat, to raise the cold stream to the target temperature, is


provided by the hot utility (usually steam) in the heater.

Additional cooling to bring the hot stream to its target temperature, by


the cold utility (usually cooling water) in the cooler.
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Problem
Heat Capacity
Stream oC oC Heat Load,
Type Flow rate CP Ts Tt
Number kw
kW/oC

1 Hot 3.0 180 60 360

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


2 Hot 1.0 150 30 120
3 Cold 2.0 20 135 230
4 Cold 4.5 80 140 270

The task is to find the best arrangement of heat exchangers to


achieve the target temperatures.

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To find the pinch temperatures and the
minimum utility requirements:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


Two methods:
1. T-H diagrams
2. Problem Table Method
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Temperature-enthalpy (T-H) diagram.
The stream temperatures are
plotted on the y-axis and the
enthalpy
change in each stream on
the x-axis.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


∆Hhot : the heat transferred from the
hot utility
∆Hcold : the heat transferred to the
cold utility

For heat to be exchanged, a minimum temperature difference must be

maintained between the two streams = ∆Tmin


The practical minimum temperature difference will usually be between 5 and 30oC.
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The heats can also be calculated as:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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The same streams
plotted with a lower value
of ∆Tmin.

The amount of heat exchanged ↑↑

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


The utility requirements ↓↓

The temperature driving force for heat transfer ↓ ↓


So the heat exchanger has both a larger duty and a smaller
log-mean temperature difference. 30
This leads to an increase in the heat transfer area required and
in the capital cost of the exchanger.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


The capital-energy trade-off in process heat recovery
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The maximum feasible heat recovery is reached at the point
where the hot and cold curves touch each other on the T-H plot:

At this point, the temperature


driving force at one end of
the heat exchanger is zero

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


and an infinite heat
exchange surface is
required, so the design is not
practical.

The exchanger is said to be pinched at the end where the hot and cold
curves meet. The heat exchanger is pinched at the cold end.

It is not possible for the hot and cold streams to cross each
other, as this would be a violation of the second law of
thermodynamics. 32
This implies that in
any of the
exchangers to be
used in the network,
the temperature
difference between
the streams will not
be less than 10oC

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


In most exchanger
networks the
minimum
temperature
difference will
occur at only one
point. This is
termed the pinch.

The pinch occurs at between 90 o C on the hot stream curve and 80 o


C on the cold stream curve. 33
Pinch point
The pinch divides the system into two distinct thermodynamic
regions.
 The region above the pinch can be considered a heat sink, with
heat flowing into it, from the hot utility, but no heat flowing out of it.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


 Below the pinch the converse is true. Heat flows out of the region
to the cold utility. No heat flows across the pinch.

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2nd Way: Problem Table Method
1st Step: Convert the actual stream temperatures, Tact, into interval
temperatures, Tint, by subtracting half the minimum temperature
difference from the hot stream temperatures and by adding half to the
cold stream temperatures:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


The use of the interval temperature rather than the actual temperatures
allows the minimum temperature difference to be taken into account.
∆ Tmin = 10oC for the problem being considered.
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Problem Table Method
Heat Capacity
Stream Heat Load,
Type Flow rate CP TsoC TtoC
Number kw
kW/oC

1 Hot 3.0 180 60 360


2 Hot 1.0 150 30 120

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


3 Cold 2.0 20 135 230
4 Cold 4.5 80 140 270

1st step: Interval Temperatures for ∆ Tmin = 10oC

2ndStep: Note any duplicated interval temperatures. 36


Problem Table Method
3rd Step: Rank the interval temperatures in order of magnitude,
showing the duplicated temperatures only once in the order:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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Problem Table Method
4th Step: Carry out a heat balance for the streams falling within
each temperature interval. For the nth interval:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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Problem Table Method
5th Step: ‘Cascade’’ the heat surplus from one interval to the
next down the column of interval temperatures;

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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Problem Table Method
6th Step: Introduce just enough heat to the top of the cascade
to eliminate all the negative values

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


137.5 kW

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Summary
For maximum heat recovery and minimum use of utilities:
1. Do not transfer heat across the pinch.
2. Do not use hot utilities below the pinch.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


3. Do not use cold utilities above the pinch

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Heat Exchanger Network Design
Grid Representation

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


Heat exchangers

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Network Design for Maximum Energy
Recovery
Heat Capacity
Stream Heat Load,
Type Flow rate CP TsoC TtoC
Number kw
kW/oC

1 Hot 3.0 180 60 360

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


2 Hot 1.0 150 30 120
3 Cold 2.0 20 135 230
4 Cold 4.5 80 140 270

50 kW of the hot and 30 kW of the cold utility,


the pinch occurs where the cold streams are at 80oC and the hot
streams are at 90 o C.

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Network Design for Maximum Energy
Recovery (minimum utility consumption)

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


Grid for four-stream problem

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Network Design Above the Pinch

1. Stream 1 can be matched with stream 4, but not with 3

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


Matching streams 1 and 4 and transferring the full amount of heat required
to bring stream 1 to the pinch temperature gives

This will also satisfy the heat load required to bring stream 4 to its target
temperature:

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Network Design Above the Pinch
2. Stream 2 can be matched with stream 3
Transferring the full amount to bring stream 2 to the pinch temperature:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


3. The heat required to bring stream 3 to its target temperature, from the
pinch temperature, is

So, a heater will have to be included to provide the remaining heat load:

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Network Design Above the Pinch

The proposed network design above the pinch is shown as:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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Network Design Below the Pinch

1. Stream 4 begins at the pinch temperature, Ts = 80 oC, and so is not

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


available for any matches below the pinch.

2. A match between streams 1 and 3 adjacent to the pinch will satisfy the
heat capacity restriction but not one between streams 2 and 3.
So, 1 is matched with 3, transferring the full amount to bring stream 1 to its
target temperature:

3. Stream 3 requires more heat to bring it to the pinch temperature;


amount needed:

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Network Design Below the Pinch
This can be provided from stream 2, as the match is now away from the
pinch.
The rise in temperature of stream 3 will be given by

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


So transferring 30 kW will raise the temperature from the source
temperature to:

and this gives a stream temperature difference on the outlet side of the
exchanger of

So, the minimum temperature difference condition, 10oC, will not be


violated by this match.
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Network Design Below the Pinch
4. Stream 2 needs further cooling to bring it to its target temperature,
so a cooler must be included; cooling required:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


This is the amount of the cold utility predicted by the problem
table.

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Proposed Heat Exchanger Network
for ∆ Tmin = 10oC

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


Interior heat exchangers Auxiliary heat exchangers 51
Summary for HEND
The guide rules for devising a network for maximum heat recovery are
given below:
1. Divide the problem at the pinch.
2. Design away from the pinch.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


3. Above the pinch match streams adjacent to the pinch, meeting the
restriction:

4. Below the pinch match streams adjacent to the pinch, meeting the
restriction:

5. If the stream matching criteria cannot be satisfied, split a stream.


6. Maximize the exchanger heat loads.
7. Supply external heating only above the pinch and external cooling only
below the pinch.

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EXAMPLE: H.E.N.D.
Determine the pinch temperatures and the minimum utility requirements for the
streams set out in the following table, for a minimum temperature difference
between the streams of 20oC. Devise a heat exchanger network to achieve the
maximum energy recovery.

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


Heat Capacity
Stream Heat Load,
Type Flow rate CP Ts oC Tt oC
Number kW
kW/oC

1 Hot 40.0 180 40 5600


2 Hot 30.0 150 60 1800
3 Cold 60.0 30 180 9000
4 Cold 20.0 80 160 1600

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SOLUTION
For ∆ Tmin = 20oC

Hot streams Tint = Tact - 10oC

Cold streams Tint =Tact + 10oC

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


Stream data

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SOLUTION
Problem table

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


The final column gives a cascade showing only positive values, with zero energy
cascading at the pinch temperature.

The hot utility requirement is 2900 kW


The cold utility requirement, the bottom value in the column, is 600 kW.
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SOLUTION
Problem table

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


So at the pinch;
hot streams will be at 90 + 10 = 100 oC
the cold streams will be at 90 - 10 = 80 oC
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SOLUTION
Above Pinch
1. CPh ≤ CPc

2. Can match stream 1 or 2 with stream 3, but neither stream can match with

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


stream 4. This creates a problem, since if we match stream 1 with 3, then stream
2 will not be able to make a match at the pinch.
Likewise, if we match stream 2 with 3, then stream 1 will not be able to make a
match at the pinch.

3. Check the heat available in bringing the hot streams to the pinch temperature:

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SOLUTION
4. Check the heat required to bring the cold streams from the pinch temperature to
their target temperatures:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


5. If we split stream 3 into two branches with CP of 40.0 and 20.0, then we can
match the larger branch with stream 1 and transfer 3200 kW, which satisfies
(ticks off) stream 1.

6. We now have two cold streams, both with CP of 20.0 and one hot stream (2)
with CP of 30.0. We need to split stream 2 into two branches. As an initial guess,
these can both have CP of 15.0. We can then match one branch of stream 2 with
the smaller branch of 4 and transfer 750 kW, and the other branch with stream
3, also for 750 kW, which then ticks off stream 2.

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SOLUTION
7. Include a heater on the smaller branch of stream 3 to provide the balance of
the heat required:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


8. Include a heater on stream 4 to provide the balance of the heat required

Check sum of heater


duties =
2050 + 850 = 2900 kW = hot
utility target.

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SOLUTION
Above Pinch

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


60
SOLUTION
Below Pinch

1. CPh ≥ CPc

2. Note that stream 4 starts at the pinch temperature so cannot provide any

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


cooling below the pinch.

3. Cannot match stream 1 or 2 with stream 3 at the pinch.

4. Split stream 3 to reduce CP

5. Check the heat available from bringing the hot streams from the pinch
temperature to their target temperatures:

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SOLUTION
Below Pinch
6. Check the heat required to bring the cold streams from their source
temperatures to the pinch temperature:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


stream 4 is at the pinch temperature.

7. Note that stream 1 cannot be brought to its target temperature of 40oC


by full interchange with stream 3, as the source temperature of stream 3
is 30 o C, so ∆Tmin would be violated. So transfer 1800 kW to one leg of
the split stream 3.

8. Check temperature at exit of this exchanger:

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SOLUTION
Below Pinch

9. Provide cooler on stream 1 to bring it to its target temperature, cooling


needed:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


10. Transfer the full heat load from stream 2 to second leg of stream 3; this
satisfies both streams.

63
SOLUTION
Proposed heat exchanger network

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


64
HOMEWORK-1: HEND
Determine the pinch temperature and the minimum utility requirements
for the process set out here. Take the minimum approach temperature
as 15oC. Devise a heat exchanger network to achieve maximum energy
recovery.

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HOMEWORK-2: HEND
To produce a high purity product, two distillation columns are operated in
series. The overhead stream from the first column is the feed to the
second column. The overhead from the second column is the purified
product. Both columns are conventional distillation columns fitted with

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


reboilers and total condensers. The bottom products are passed to other
processing units, which do not form part of this problem. The feed to the
first column passes through a preheater. The condensate from the
second column is passed through a product cooler. The duty for each
stream is summarized as follows:

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HOMEWORK-2: HEND - continued

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


Find the minimum utility requirements for this process, for a minimum
approach temperature of 10oC.

Note: The stream heat capacity is given by dividing the exchanger duty
by the temperature change.

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HOMEWORK-3: HEND
Consider the design of a HEN for the four streams below in a problem:

Process Design Lecture Notes / Assist.Prof.Dr. E.Bilgin Simsek


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