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E Anexo Sm-Series
E Anexo Sm-Series
Sumitomo Metals began manufacturing tubing, casing, drill pipe and line pipe more than thirty years ago. At
that time, well depths were shallow and oil and gas drilling was relatively uncomplicated.
Today, wells are going deeper, and drilling environments are becoming more hostile.
Sweet wells, sour wells, and wells operating in arctic conditions or at extraordinary well depths have become
commonplace. But these new types of wells require tubular products that are much more sophisticated and
more tailored than their predecessors. To meet these new challenges, Sumitomo developed the SM Series,
and a line of specialty tubular products (NEW SM Series) that are made from rugged materials like stainless
steel and high alloys.
In addition to the SM Series, Sumitomo Metals also produces stainless steel and high alloy line pipe, products
that were specially developed to fight H2S and CO2, corrosive compounds that are often found in pipeline-
transported crude oil and gas.
For more than five decades, Sumitomo has been serving the needs of the oil and gas industries. This
brochure provides a quick over-view of the family of quality Sumitomo products available to these vital
enterprises.
FACILITIES AND LOCATIONS
Sumitomo Metals has almost all kinds of steel pipe manufacturing facilities which produce a wide range of
seamless and welded steel pipe and tubes.
The main facilities are composed of our Steel Tube Works, Wakayama Steel Works, and Kashima Steel
Works.
These works are able to produce approximately three million metric tons of steel pipe and tubes annually.
The company also possesses facilities in affiliated companies in Sakai, Kashima and Koga.
Sumitomo's facilities and locations are tabulated on next page together with their available size ranges (O.D.).
1
3 2
4
6
5 7
1 Kashima Steel Works
8
9 2 Kashima Plant (Sumikin Weld Pipe Co.)
10
3 Koga Plant (Sumikin Stainless Steel Pipe Co.)
Chain Drawbench
Cold Finished
Amagasaki 18
Tube Reducing
Kainan
/ 7
Machine
Hydraulic
Amagasaki 2 20
Drawbench
2" Electric- 34
Resistance-Weld
Wakayama / 2
4" Electric-
Wakayama 1 1/2 4 1/2
Resistance-Weld
20" Electric-
Wakayama 7 1/2 24
Resistance-Weld
Welded
UOE
Submerged Kashima (20) 24 60
Arc-Weld
Blast Furnace
CARBON & ALLOYED STEEL MAKING PRESS
Dephosphorization
Vacuum
Decarburization
VOD Ladle
RH-PB IR-UT
Blooming Mill
Slab
Continuous
Casting
Machine
Bar Mill
Hot Strip Mill
Continuous
Casting
Round Billet Bloom Slab Ingot Bloom Machine Billet Hot Coil
Extrusion Forging
Mandrel Mill Process Electric-Resistance Welding Process
Process Process
Extrusion Forging
Mandrel Mill Process Electric-Resistance Welding Process
Process Process
TUBE AND PIPE MAKING PROCESS
Piercer
1200t Vertical Press 3000t Vertical Press Cold Draw Bench Cold Reducing Mill
Mandrel Mill
3 Roll Reducer
Hot Finished Seamless Steel Tubes and Pipe Cold Finished Seamless Tubes and Pipe Electric-resistance Welded Steel Tubes and Pipe
AVAILABLE GRADES
AVAILABLE GRADES
75,000
85,000
90,000 C-90
95,000 C-95
T-95
100,000
105,000
110,000 P-110
125,000 Q-125
130,000
140,000
150,000
155,000
REMARKS
1. Grade SM-S, SB are designed to prevent sulfide stress corrosion cracking (SSCC), but not designed to prevent
general corrosion CO2 or CO2 + H2S environment, so inhibitor usage should be considered.
2. Grades from SM22CR to SMC276 are designed to prevent both SSCC and general corrosion.
3. SM-Series designation stand for
(1) SM-90SB :SUMITOMO-90,000psi minimum yield strength special sour well service.
(2) SM13CR-80 :SUMITOMO 13%Chromium steel-80,000psi minimum yield strength.
(3) SM2550-110 :SUMITOMO 25%Chromium 50%Nickel 6%Molybdenum alloy-110,000psi minimum yield strength.
AVAILABLE GRADES
AVAILABLE GRADES
40,000
55,000
75,000 SM25CR-75
85,000 SM13CR-85
90,000 SM-90S SM-90SS SM-90TS SM13CRS-90
100,000 SM-C100
105,000
110,000 SM-110T SM-110S SM-C110 SM-110TS SM-110L SM13CRS- SM22CR-110 SM2035-110 SM2550-110
SM-110TT SM-110LL 110㶎㪉 SM25CR-110 SM2050-110
SM13CRM- SM2535-110 SM2060-110
110㶎㪉
SM2242-110 SMC276-110
REMARKS
1. Grade SM-S, SB are designed to prevent sulfide stress corrosion cracking (SSCC), but not designed to prevent
general corrosion CO2 or CO2 + H2S environment, so inhibitor usage should be considered.
2. Grades from SM22CR to SMC276 are designed to prevent both SSCC and general corrosion.
3. SM-Series designation stand for
(1) SM-90SB :SUMITOMO-90,000psi minimum yield strength special sour well service.
(2) SM13CR-80 :SUMITOMO 13%Chromium steel-80,000psi minimum yield strength.
(3) SM2550-110 :SUMITOMO 25%Chromium 50%Nickel 6%Molybdenum alloy-110,000psi minimum yield strength.
㶎1 ERW PROCESS
㶎2 These materials are not suitable for H2S condition. Please consult us when a small amount of H2S is existing in your application.
㶎3 Grade SM-TS is available for high collapse & sour service. Please consult us when 100 & 110 grade is necessary.
AVAILABLE GRADES
AVAILABLE GRADES
NEW SM SERIES CO2 CORROSIVE SM13CR-80 80,000䌾㩷㩷95,000 㻢㩷㩷㩷95,000 API FORMULA HRC 㻡㩷23
WELL SERVICE SM13CR-85 85,000䌾100,000 㻢㩷100,000 API FORMULA HRC 㻡㩷24
SM13CR-95 95,000䌾110,000 㻢㩷105,000 API FORMULA HRC 㻡㩷27
SM13CRS-80 80,000䌾㩷㩷95,000 㻢㩷㩷㩷90,000 API FORMULA HRC 㻡㩷27
SM13CRS-90 90,000䌾105,000 㻢㩷100,000 API FORMULA HRC 㻡㩷27
SM13CRS-95 95,000䌾110,000 㻢㩷105,000 API FORMULA HRC 㻡㩷28
SM13CRS-110 110,000䌾125,000 㻢㩷110,000 API FORMULA HRC 㻡㩷32
SM13CRM-80 80,000䌾㩷㩷95,000 㻢㩷㩷㩷90,000 API FORMULA HRC 㻡㩷27
SM13CRM-95 95,000䌾110,000 㻢㩷105,000 API FORMULA HRC 㻡㩷28
SM13CRM-110 110,000䌾125,000 㻢㩷110,000 API FORMULA HRC 㻡㩷32
CO2-LOW H2S SM22CR-65 65,000䌾100,000 㻢㩷㩷㩷93,000 25 HRC 㻡㩷26
CORROSIVE SM22CR-110 110,000䌾140,000 㻢㩷125,000 12 HRC 㻡㩷36
WELL SERVICE SM22CR-125 125,000䌾145,000 㻢㩷130,000 11 HRC 㻡㩷37
SM22CR-140 140,000䌾160,000 㻢㩷145,000 11 HRC 㻡㩷38
SM25CR-75 75,000䌾100,000 㻢㩷㩷㩷95,000 25 HRC 㻡㩷26
SM25CR-110 110,000䌾140,000 㻢㩷125,000 12 HRC 㻡㩷36
SM25CR-125 125,000䌾145,000 㻢㩷130,000 11 HRC 㻡㩷37
SM25CR-140 140,000䌾160,000 㻢㩷145,000 11 HRC 㻡㩷38
SM25CRW-80 㻢80,000䇭䇭䇭䇭 㻢㩷116,000 20 HRC 㻡㩷30
㻢㩷125,000 12 HRC 㻡㩷36
SM25CRW-125 125,000䌾145,000 㻢㩷130,000 11 HRC 㻡㩷37
SM25CRW-140 140,000䌾160,000 㻢㩷145,000 11 HRC 㻡㩷38
AVAILABLE GRADES
AVAILABLE GRADES
SPECIFICATION REMARKS
API 5CT
䋼SSCC TEST䋾
C-90, T-95 : 㱟th 㻢 80%SMYS
䋼COLLAPSE TEST䋾
SEE PERFORMANCE TABLE
䋼SSCC TEST䋾
䊶SM-S, TS : Sc 㻢㩷10 (BENT BEAM)
䊶SM-C100, C110 :㱟th 㻢㩷85%SMYS (NACE)
䊶SM-90SS : Sc 㻢㩷12 (BENT BEAM)
NEW SM SERIES
AVAILABLE GRADES
AVAILABLE GRADES
MECHANICAL PROPERTIES
SPECIFICATION APPLICATION GRADE TENSILE ELONGATION HARDNESS REMARKS
YIELD STRENGTH STRENGTH
(psi) (%) HRC RANGE 䂦HRC
(psi)
-
NEW SM CO2-H2S-CI - SM2035-110 110,000䌾140,000 㻢 115,000 11 HRC 㻡 32
CORROSIVE
SERIES WELL SERVICE SM2035-125 125,000䌾145,000 㻢 130,000 9 HRC 㻡 33
REMARKS
1. Grade SM-S, SB are designed to prevent sulfide stress corrosion cracking (SSCC), but not designed to prevent general corrosion CO2 or
CO2+H2S environment, so inhibitor usage should be considered.
2. Grades from SM22CR to SMC276 are designed to prevent both SSCC and general corrosion.
3. Grades with㶎 are ERW products.
4. Example of SM-Series names
(1) SM-90SB : SUMITOMO-90,000psi minimum yield strength special sour well service.
(2) SM13CR-80 : SUMITOMO 13%Chromium steel-80,000psi minimum yield strength.
(3) SM2550-110 : SUMITOMO 25%Chromium 50%Nickel 6%Molybdenum alloy-110,000psi minimum yield strength.
AVAILABLE GRADES
THE NEW SM-SERIES AND THEIR APPLICATIONS TO CORROSIVE WELLS
Concept of Material Selection according to Gas (CO2) and H2S) Partial Pressure
SM 25CRW-110, 125 SM 25CRW-80 SM 2535-110, 125, 130 SM 2550-110, 125, 130, 140
(㻡250㷄) SM 25CR-75 SM 2035-110, 125 (㻡300㷄)
(㻡250㷄) SM 2242-110, 125
SM 25CR-110, 125 (㻡250㷄)
(㻡250㷄) SM 22CR-65
103
(㻡200㷄) 104
SM 22CR-110, 125
(㻡200㷄)
102
103
SM 13CR-80㶎 SM 13CRS-80
-85㶎 95
(㻡150㷄) (㻡175㷄)
10
Partial Pressure of CO2 (atm)
10-3
10-2
10-4
10-4 10-3 10-2 10-1 1 10 102 103
(Note) 㶎C - content should be less than 50,000ppm for SM 9CR and SM 13CR
AVAILABLE GRADES
Sulfide Stress Corrosion Cr or Cr-Mo Steel SM90SS Higher Yield Strength for
Cracking SM-C100 Sour Service
(High Pressure and High
Temperature) SM-C110
Wet CO2 Corrosion 13Cr (Mod. AISI 420) SM13CR-80 Quench and Tempered
SM13CR-85
SM13CR-95㶎1
25Cr-7Ni-3Mo-2W SM25CRW-80㶎2
SM25CRW-110, -125㶎3
Wet CO2 and H2S Corrosion 25Cr-35Ni-3Mo SM2535-110, -125, -130 As Cold Drawn
Most Corrosive Environment 25Cr-50Ni-6Mo SM2550-110, -125, -130, -140 As Cold Drawn
㶎4
20Cr-50Ni-11Mo SM2050-110, -125, -130, -140㶎4 Environment with Free
Sulphur
㶎4
20Cr-58Ni-13Mo SM2060-110, -125, -130, -140, -150, -155
SM-G meant for general and deep well service are remarkable for their high yield and tensile strengths while
maintaining good ductility and fracture toughness.
SM-95G was developed as an intermediate grade between N-80 and P-110 to provide economical flexibility in
designing casing strings.
SM-125G, SM-140G, SM-150G, and SM-155G offer additional tensile and yield strengths for deep well
services.
Yield Strength
Elongation Impact Properties min Ave Value
Grade Tensile Strength
2
min psi (kg/m ) 2
max psi (kg/m ) min % At-50 F (- 46㷄) ft-lb (kg-m)
CHARACTERISTICS
1. Tensile Strength
The resistance to collapse and the longitudinal high strength requirements of well casing is becoming
increasingly important with the drilling of deeper and deeper wells. SM-125G through SM-155G offer the high
strength properties.
2. Mechanical Properties
Mechanical Properties of SM-G series are shown in above Table. SM-125G through SM-155G offer the
required high strength properties.
3. Toughness
The Toughness of SM-G is equivalent to that of P110, Q125. Typical longitudinal and transverse impact
properties are shown in Fig.
4. Micro Structure
Typical micro structures are shown in Photo. Each photo shows a well quenched and tempered
microstructure.
100
80
60
40
20
Longitudinal
0 10x10x2V
Transverse
SM-150G coupling 100 10x10x2V
Brittle fracture (%)
80
60
40
20
0
-150 -100 -50 0 50
Testing Temperature ( F)
Application of High Strength Grades for Deep Sour Gas & Oil Wells
As wells becomes deeper, high strength steels are needed for effective completion. Sumitomo can offer our
high strength and high toughness steel for such completions, and have supplied plenty of SM-G Grades all
over the world.
The smallest amount of H2S contamination should always be taken into consideration when looking at high
strength material applications.
Fig shows the applicability of high strength steels for sour service integrating the following variables; H2S
concentration, applied stress level and temperature.
Sulfide stress corrosion cracking susceptibility increases with material strength and grades such as SM150G
or SM155G should never be used if H2S is present.
SM90S SM95S P110 SM125G SM150G SM90S SM95S P110 SM125G SM150G
150 300 10
Test temperature ( F)
100 0.1
200 no crack
0.01
no crack
150
0.001
50
SM90S SM125G
crack 100 SM95S P110 SM150G
SM90S SM125G 80 90 100 110 120 130 140 150 160 170 180(ksi)
SM95S P110 SM150G 50
Yield strength
no crack
crack
70 80 90 100 110 120 (kg/mm2)
90 100 110 120 130 140 150 160 170 180(ksi) Influence of H2S partial pressure on SSCC (㱟appl.=㱟y)
Yield strength
Dependency of SSCC susceptibility on test temperature
(㱟appl.=㱟y, PH2S=1atm (25㷄), NACE solution)
P110
SM90S SM95S SM125G SM150G
10
Partial pressure of H2S (atm)
0.1
0.01
0.001
SM90S SM125G
SM95S P110 SM150G
In order to prevent possible sulfide stress corrosion cracking in sour gas and oil wells containing H2S, it is
necessary to use specially manufactured tubing and casing. API 5CT Group 2 grade tubing and casing have
been developed and used widely for this purpose. However these may not be adequate in high concentration
of H2S.
To address this, Sumitomo Metal, after years of research and development, has succeeded in developing
improved materials with higher strength and higher corrosion resistance for casing and tubing.
These are available in our SM-S & SM-SB series as shown below.
Each of these grades is produced with rigid manufacturing controls covering chemical composition, heat
treatment (quenching and tempering), tensile property, hardness and microstructure.
SM-110S 110,000 (77.3) 125,000 (87.9) 115,000 (80.8) API 23䌾30 min NACE Condition
Formula 1100 F (593㩷㷄) H2S=0.1 atm
㻢80% SMYS
SM-C100 100,000 (70.3) 115,000 (80.8) 105,000 (73.8) 19䌾27 min NACE Threshold
1100 F (593㩷㷄) 㻢85% SMYS
SM-C110 110,000 (77.3) 125,000 (87.9) 115,000 (80.8) 23䌾30
min
SM-90SS 90,000 (63.3) 105,000 (73.8) 100,000 (70.3) Max.24 1200 F (649㩷㷄) Sc Value㻢12
CHARACTERISTICS
1. Materials
The chemical compositions have been carefully determined to provide resistance to sulfide stress corrosion
cracking as well as to insure complete throughwall hardening.
2. Heat Treatment
Quenching and tempering is done under rigid temperature control to assure homogeneous physical
properties and metal structures.
New Higher Strength Sour Resistant Grades SM90SB SM-100SB, SM-C100, SM-C110 have been developed.
3. Micro Structure
These grades exhibit fully tempered martensite which is considered to be the most desirable for resistance to
sulfide stress corrosion cracking.
20
: SM90SS
110
100 SM-C110
㱟th; Threshold stress (ksi)
SM-C100
90
SM-90SS
70
Ordinary SM90SS
API grade
60
10
90 100 110 120 130 140
YS (ksi)
Sumitomo High Collapse Casing SM-T grade is a seamless product designed for deep wells where high
collapse pressures are anticipated. In order to meet deep well service requirements, SM-T casing has
improved collapse properties well in excess of API ratings. These properties are achieved by strict mill control
incorporating a unique production technique inclusive of quenching and tempering. SM-T casing shows a very
high resistance to tension load, internal pressure, and collapse. SM-95TS is also highly resistant to sulfide
stress corrosion cracking and can be used for deep and sour gas and oil service.
Yield Strength
Tensile Strength
Grade Elongation min % Collapse Resistance
min psi (kg/mm2)
min psi (kg/mm2) max psi (kg/mm2)
SM- 80T 80,000 (56.2) 110,000 ( 77.3) 100,000 (70.3) API Formula
SM- 95T㶎 95,000 (66.8) 125,000 ( 87.9) 110,000 (77.3) API Formula
SM- 95TT㶎 95,000 (66.8) 125,000 ( 87.9) 110,000 (77.3) API Formula
Refer to Performance Table
SM-110T㶎 110,000 (77.3) 140,000 ( 98.4) 125,000 (87.9) API Formula
䇭㶎㩷Higher collapse casing than SM-95T & SM-110T are available on request.
㶎㶎㩷Maximum ardness (HRC) of SM-95TS is controlled bellow 25.
More narrow restricted yield strength range is available on request.
Sulfide Stress Corrosion Cracking of SM95TS : Sc Value㻢10
As wells are drilled deeper, the external pressures applied to well casings become greater. Thus, a well casing
must have adequate collapse strength to withstand these horizontal pressures without deformation. For
reasons of economy such casings should also be as light-weight as possible while still retaining ample
collapse resistance properties.
With this in mind Sumitomo Metals has developed its SM-T High Collapse Casing. This casing was developed
from experiments in which Sumitomo studied the critical collapse pressure of a well casing under external
pressure in relation to its longitudinal tensile strength and the geometry of its cross section.
CHARACTERISTICS
1. Unique Production Technique
The material for SM-T casing is carefully selected to insure structural homogeneity. Strict control of heat
treatment and dimensional tolerances is adhered to throughout the manufacturing process.
2. Rigid Dimensional Control
Dimensional tolerances, such as roundness,
Specified Minimum Collapse Pressure
straightness, O.D. and wall thickness are strictly 20,000
Example of
controlled. Actual Data
: SM-95T
3. Specified Collapse Value : SM-110T
A collapse test is carried out on each production : SM-125TT
SM
-1
15,000
TT M-1
10,000
AP
AP IP
IC -1
10
-9
5
5,000
12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27
D/t
SM-SERIES GRADE DESCRIPTION
4. CASING AND TUBING FOR ARCTIC SERVICE
Sumitomo SM-L grades are designed for high impact toughness at subzero temperatures, as this is
experienced in arctic regions.
These properties are achieved through tight material chemistry control and specific heat treatment.
The following Tables show tensile and impact toughness properties.
Tensile Properties
Yield Strength
Grade Tensile Strength
min. psi (kg/mm2 ) Elongation min. % in 2 in
min. psi (kg/mm2 ) max. psi (kg/mm2 )
10
70
2. Heat Treatment
60 8
Both casing and coupling are quenched and
50
tempered with special care.
6
40 SM-80L
3. Impact Properties
30 4
(Example of SM-80L & SM-110LL)
20
2
10
0 0
-140 -120 -100 -80 -60 -40 -20 0 20 40(㷄)
1. Inhibitor Treatment Increase of Velocity above Critical Point Destroy Liquid Film
Batch or Continuous
Increase of Temperature above 120 C Vaporizing Liquid Film Corrosion Problem
Cast comparison between CRA completion versus other corrosion mitigation methods.
Option remain the most economical, in spite of the high initial investment when considering costs on a life
cycle basis.
CRA (Corrosion Resistant Alloy) completion is more economical one after well life, in spite of high initial
investment.
Example Case
䊶Economic Comparison of CRA Completion with carbon steel with inhibitor in 13,000 ft highly corrosive well.
Well depth : 13,000 ft
Highly corrosive
CRA : 3-1/2" 9.2# SM 2535-110
Carbon Steel : 4-1/2" 12.6# L-80
䊶In this example CRA becomes the most effective option after 2 years of production.
between the different completions
2
Cum PVNI (Other)䋭Cum PVNI (CRA)<$Millions>
1 CRA
0
-1 Continuous
-2
-3
-4 Batch
-5 No treatment
-6
-7
-8
-9
0 20 40 60 80 100 120
Months Since Completion
CRA (Corrosion Resistant Alloy, without Inhibitor)
Batch (Inhibitor Treatment) Continuous (Continuous Inhibitor Treatment)
No Treat
PVNI : Present Value Net Income
NEW SM-SERIES
2. MECHANICAL AND THERMAL PROPERTIES OF NEW SM-SERIES
1 SM13CRS-95 0 7.69 201 199 192 188 0.27 0.27 0.26 0.26
2 SM22CR-65 0 7.85 203 196 187 187 0.30 0.28 0.28 0.29
3 SM22CR-110 15 7.85 198 194 184 189 0.25 0.24 0.23 0.24
4 SM25CR-75 0 7.85 189 188 180 193 0.29 0.28 0.28 0.28
5 SM25CR-110 10 7.85 191 184 177 193 0.26 0.25 0.24 0.27
6 SM25CRW-80 0 7.85 204 199 191 188 0.33 0.32 0.33 0.33
7 SM25CRW-125 10 7.85 200 198 191 188 0.27 0.27 0.27 0.27
8 SM2035-110 20 8.10 203 194 181 178 0.32 0.30 0.31 0.30
9 SM2535-110 20 8.07 205 194 189 187 0.31 0.29 0.30 0.30
10 SM2242-110 20 8.14 210 197 184 187 0.31 0.29 0.28 0.29
11 SM2550-110 20 8.29 211 195 186 185 0.31 0.29 0.29 0.28
12 SM2550-140 20 8.33 212 202 190 198 0.31 0.30 0.30 0.30
13 SM2050-110 20 8.58 216 201 192 196 0.33 0.31 0.31 0.31
14 SM2060-110 20 8.71 218 205 196 196 0.33 0.31 0.31 0.31
15 SMC276-110 20 8.87 220 207 197 196 0.33 0.31 0.31 0.31
2 SM22CR-65 0 13.4 14.0 14.2 3.81 3.81 3.97 4.08 3.74 4.48 4.94 5.27 14.3 17.1 19.7 21.5 465.3 494.1 524.7 554.4
3 SM22CR-110 15 12.5 12.8 13.3 3.64 3.93 4.01 4.08 3.77 4.12 4.52 4.73 13.7 16.2 18.1 19.3 468.2 495.8 525.5 561.9
4 SM25CR-75 0 12.7 13.2 13.5 3.52 3.64 3.79 3.88 3.82 3.86 4.39 4.73 13.4 15.1 16.7 18.3 464.8 493.3 523.8 559.8
5 SM25CR-110 10 12.5 12.7 13.0 3.38 3.48 3.68 3.82 3.86 4.60 4.98 5.36 13.1 16.0 18.3 20.5 465.3 492.0 523.8 561.5
6 SM25CRW-80 0 13.2 13.6 13.9 3.37 3.73 3.87 3.92 3.92 4.23 4.52 5.02 13.2 15.7 17.5 20.3 498.0 536.0 574.0 636.0
7 SM25CRW-125 10 13.0 13.2 13.5 3.31 3.64 3.83 3.93 3.93 4.25 4.55 5.08 13.0 15.3 17.7 19.9 497.5 536.0 574.2 635.6
8 SM2035-110 20 14.8 14.8 14.8 2.80 3.04 3.36 3.69 3.82 3.93 4.17 4.39 10.7 12.0 14.0 16.3 453.5 468.6 488.3 508.8
9 SM2535-110 20 14.5 14.9 14.9 2.88 3.11 3.48 3.76 3.75 3.99 4.23 4.39 10.8 12.4 14.7 16.6 452.7 470.7 490.8 508.8
10 SM2242-110 20 14.6 14.7 14.9 2.81 3.02 3.42 3.79 3.68 3.96 4.31 4.52 10.4 12.0 14.7 17.1 451.5 467.4 487.4 504.6
11 SM2550-110 20 14.0 14.1 14.2 2.74 2.79 3.27 3.60 3.75 4.18 4.23 4.52 10.3 11.7 13.9 16.3 442.2 459.8 479.5 469.2
12 SM2550-140 20 13.6 13.9 14.1 2.81 3.02 3.29 3.67 3.67 3.86 4.18 4.27 10.3 11.7 13.8 15.6 441.8 458.1 477.8 497.1
13 SM2050-110 20 13.2 13.5 13.6 2.69 2.72 3.25 3.53 3.74 4.00 4.21 4.41 10.1 11.5 13.9 15.6 421.3 442.2 452.4 466.3
14 SM2060-110 20 12.6 12.8 12.8 2.67 2.89 3.24 3.51 3.74 3.96 4.23 4.35 10.0 11.5 13.7 15.3 415.5 432.2 448.1 464.4
15 SMC276-110 20 12.2 12.4 12.5 2.59 2.60 3.19 3.50 3.67 4.09 4.14 4.27 9.5 10.6 13.2 14.9 398.7 412.5 429.7 448.9
-1 -1
Note : 1cal/cm䊶s䊶㷄䋽360kcal/m䊶h䊶㷄䋽419W䊶m 䊶㷄
NEW SM-SERIES
3. Martensitic Stainless Steel and Duplex Stainless Steel (13CR, 13CRM, 13CRS, 22CR)
SM25CR 㻡 0.03 㻡 0.75 㻡 1.00 0.2䌾0.8 5.5䌾7.5 24.0䌾26.0 2.5䌾3.5 0.10䌾0.50 0.10䌾0.30
SM25CRW 㻡 0.03 㻡 0.80 㻡 1.00 0.2䌾0.8 6.0䌾㪏㪅㪇 24.0䌾26.0 2.5䌾3.5 2.01䌾2.50 0.24䌾0.32
Temperature (㩷㪝)
0 100 200 300 400 500 600
15 70
C-steel 2500
500
60 2Cr
Corrosion rate (mm/Y)
5Cr
Corrosion rate (mpy)
10
9Cr-1Mo
50 2000
13Cr
22Cr/25Cr
40
5 1500
30
1000
0 0
0.01 0.05 0.1 0.5 1 5 10 20
Cr content (wt.%)
500
Effect of Cr content of commercial tubular goods on 10
corrosion rate by loop tester
(Synthetic sea water, CO2 partial pressure 0.1 MPa (60㷄㪀㪃
test temperature 60㷄㪃㩷test duration 150h, flow velocity 2.5 m/s,
specific volume : 800 cc/cm2) 0
0
0 100 200 300
Temperature (㷄)
Effect of temperature on corrosion rate by autoclave
(Synthetic sea water, CO2 partial pressure ; 3.0 MPa (R.T.),
test duration 72h, flow velocity 2.5 m/s, specific volume : 42 cc/cm2)
NEW SM-SERIES
10
1
5
0.1
0.5 (B) 25Cr
10
0.2 5
0.1
0.1
50 100 150 200 250 (㷄)
101 101
Solid mark : Cracked Solid mark : Cracked GC
Half Solid : Pitting Half Solid : Pitting 13Cr
GC : General Corrosion GC GC : General Corrosion GC
100 GC 100
13Cr
Corrosion rate (mm/Y)
Corrosion rate (mm/Y)
10 -1 10-1 SM13CRS
SM13CRS
10-2 10-2
22Cr
-3 22Cr 10-3
10
10-4
10-4 0 50 100 150 200
0 50 100 150 200
Temperature (㷄)
Temperature (㷄)
Effect of temperature on corrosion resistance of SM13CRS Effect of temperature on corrosion resistance of SM13CRS
(5%NaCl + 3.0MPa (450psi) CO2 + 0.001MPa (0.15psi) H2S) (25%NaCl + 3.0MPa (450psi) CO2)
NEW SM-SERIES
Temperature ( F)
300 Solid mark : Crack SM25CRW
150
SM22CR 25Cr
100 200 Type 316L 22Cr
105
104
25Cr (Y. S. 553MPa) 25Cr (Y. S. 822MPa)
Temperature ( F)
Temperature㩷㩿㷄㪀
300 103
150
100 200
102
50
100
10-4 10-3 10-2 10-4 10-3 10-2 10-4 10-3 10-2 10-1
PH2S (MPa) PH2S (MPa) H2S (MPa)
Effect of H2S partial pressure and temperature on the susceptibility SSCC. SCC susceptibility of duplex stainless steel
5% NaCl, 3.0MPa CO2 + H2S at 25㷄㩷(77F, test duration 336h, flow velocity in C1- H2S environment.
2.5m/s 1㱟y with notch : No SCC, : SCC
(SSRT method ; 80㷄, strain rate 4.2 x 10-5/s)(annealed)
1.2
13Cr Cr:12-16% Ni:5-7%
120㷄 SM25CRW
SM25CRW SM25CR
0.1
1
0.01 SM25CR
0.001 0.8
L/L0
60㷄
Corrosion rate (mm/y)
0.6
0.1
0.01
0.4
0.001
25㷄 0.2
0.5 1 2 5 10
0.1 Cl- (104ppm)
(5%4-point
NaCl + 3.0MPa (450psi) CO + 0.001MPa (0.15pti) H S
2
bent beam with notch, 1㱟y, 336h, ( 2
NEW SM-SERIES
0.014
0.012
0.01
Corrosion rate (mm/y)
: 13Cr
: 22Cr duplex
0.008
0.006
0.004
0.002
0
0 50 100 150 200 250 300
Gas velocity (m/s)
NaCl 䂦 䂦 䂾 䂦 䂾
CaCl2 䂾 䂦 䂦 㬍 㬍
MgCl2 㬍 䂾 䂦 㬍 䂾
ZnCl2 㬍 㬍 㬍 䂾 䂾
NaBr 䂾 䂾 䂾 䂦 䋭
CaBr2 䂾 䂦 䂦 䂦 䂾
MgBr2 䂦 䂦 䂦 䂦 䋭
ZnBr2 㬍 㬍 㬍 䂾 䂾
㶎1) In 60㷄 㶎2.3) Autoclave test 150㷄, 0.4MPaCO2 㶎4) Pitting potential 㶎5) 䂾㩷: Crack Free
0.1MPaCO2 㶎2) : 䂾㩷: C.R.㻡1g/m2/h 㶎3 : 䂾㩷: C.R㻡0.1 䂾㩷: Vp㻢0.3V 㬍㩷: Crack
䂾㩷: pH㻢4 䂦㩷: 1<C.R._10 䂦㩷: 0.1䋼C.R.㻡1.0 䂦㩷: 0䋼Vp䋼0.3
䂦㩷: 3䋼pll䋼4 㬍㩷: C.R.>10 㬍㩷: C.R.䋾1.0 㬍㩷: Vp㻡0
㬍㩷: pH㻡3
(1g/m2/h=1.1mm/year)
Brine with a corrosion inhibitor, a biocide, and an oxygen scavenger added is acceptable as a completion fluid
but careful investigation is required at selection brine and additives as a packer fluid.
An oil base solids free packer fluid is recommended, either diesel oil with a corrosion inhibitor additive or one
of the proprietary oil base packer (Drilling) fluids.
All fluids pumped into wells equipped with stainless steel materials should be adequately deoxygenized. Any
additives to completion brines and or packer fluids such as corrosion inhibitors, biocide, etc, should be
carefully selected to avoid possible degradation with time and subsequent negative effect on stainless steel
integrity. Generally Oil based solids free packer fluids such as diesel oil are acceptable.
NEW SM-SERIES
5. H2S+CO2+CL- CORROSION (NI BASE ALLOY)
High Alloy Materials become necessary where severe well conditions with high concentrations of H2S, CO2
and CL- brines are encountered.
(1) High Ni corrosion resistant alloys for OCTG feature a single austenitic phase. Strength is developed
through cold working.
Addition of essential alloying elements such as Cr, Ni, Mo determines the corrosion resistance properties.
(2) Resistance to general (weight loss) corrosion and localized (pitting and crevice) corrosion is achieved by
the formation of a stable passivation film on the material surface.
(3) The effect of fundamental elements on corrosion behaviors are shown in the following Figures. These can
be recapped as follows.
㩷䊶Cr is effective for high temperature service.
㩷䊶Mo is effective for low PH condition.
㩷䊶n combined H2S, CO2, CL- media, the basic minimal chemistry of Cr㻢20%, Ni㻢30%, Mo㻢3% is required.
㩷䊶Hydrogen embrittlement susceptibility increases with material chemistries exceeding 60% Ni.
(4) Precipitation hardened alloys (P.H.) are required as base materials for down hole equipment accessories,
to be used in conjunction with CRA OCTG materials.
Our precipitation hardened alloys have superior properties at least comparable to conventional alloys.
3 3 3
6 6 6
0 0 0
10 10 Corrosion- 10
Corrosion-resistant resistant
3 3 region 3
Corrosion-resistant region
region
Mo (%)
6 6
Mo (%)
15 15 15
Mo (%)
6
30 30 30
C
C
SC
C
SC
25 25 25
SC
SC
10 10 10
TG
TG
IG
TG
)
)
20 20 20
(%
(%
(%
Cr
Cr
Cr
15 15 15 15 15 15
60 40 20 0 60 40 20 0 60 40 20 0
Ni (%) Ni (%) Ni (%)
350㷄
3Mo 20Cr
15
30 SM3040
pH0.5
12
Cr (%)
25 SM2535
HE
250㷄 SM2050
Mo (%)
20 9
SM2030
150㷄
pH2.0
15 6
Austenitic single phase
0 10 20 30 40 50 60 70
Ni (%) 3
0
6Mo 30 40 50 60 70
(5Mo) 350㷄
30 Ni (%)
25 300㷄
(2)Environment, SCC : 20% NaCl 䋫0.5% CH3COOH䋭1.0 MPa
SM2035 250㷄 H2S 䋭1.0 MPa CO2 䋭250㷄, HE : NACE TM01-77 solution,
20
Iron coupling/
400㷄㬍1,000h aging)
15 (5Mo) Austenitic single phase
(6Mo)
0 10 20 30 40 50 60 70
Ni (%)
Fig. 29 Corrosion resistant region temperature-alloying
NEW SM-SERIES
422K
Solid mark : 30 6Mo (300 F)
450K
Cr (mass%)
Secondary crack (350 F)
25 477K
(400 F)
505K
SCC 20 No SCC (450 F)
SM C276
SCC
Temperature ( F)
450
SM 2060 Mo 15
400 SM 2050 30 40 50 60 70
Ni (mass%)
(a) SCC
350
SM 2550
300 30 50Ni
SM 2242 No SCC
Cr (mass%)
SM 2535
25
3 6 9 12 15
20
1
Mo+䋭W(%) Localized
2 corrosion
15
Relationship between testing temperature and Mo content of Ni Base Alloys
in H2S-CL- environment in the SSRT tests. 3 6 9 (10) 12 15
(SSRT test condition ; 25% NaCl-0.5% CH3COOH, 7 atm H2S, E=4.0㬍10-6S-1) Mo (mass%)
(b) Localized corrosion
C Si Mn Cu Ni Cr Mo Ti W Fe
Options
Special clearance couplings
Special bevel couplings
䃂㩷Failure Records
䃂㩷Well Condition 䃂㩷Expert System
䃂㩷Well Operation ECONOMICAL EVALUATION
䃂㩷Running Condition
䃂㩷Analysis Profitability of
Selected Material
String Design
STRESS ANALYSIS
䃂㩷Under Anticipated Load Conditions
CAD FEM
MARKING, COLOR IDENTIFICATION AND
INQUIRY AND/OR ORDER DETAIL
MARKING, COLOR IDENTIFICATION
5CT . P DATE OF MFR 9-5/8 53.5 N S 41.5 BUTTRESS THREAD SUMITOMO METALS MADE IN JAPAN NO1
SM SERIES
DIE STAMP SIZE LBS/FT GRADE LENGTH TYPE OF THREAD SHIPPING MARK
MANUFACTURE'S Mark
SUMITOMO METALS. 9-5/8 53.5 SM-95T S 41.5 BUTTRESS THREAD MADE IN JAPAN NO1
COLOR
BAND PROCESS OF MANUFACTURE PIECE NO
COLOR COATING FOR GRADE
IDENTIFICATION
NEW SM SERIES
MANUFACTURE'S Mark SIZE LBS/FT GRADE LENGTH TYPE OF THREAD SHIPPING MARK
COLOR BAND
SUMITOMO METALS 4-1/2 12.6 SM13CRS-95 S 31.5 VAM-ACE MADE IN JAPAN NO1
You are requested to specify your conditions for the following items on your order sheet.
Quantity
Delivery date and shipping instructions Mill inspection by purchaser.
If you have any special requirements, please specify the details accordingly.
ABC CO 1234-90
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Phone: (02)221-7822, (02)221-7824 Fax: (02)233-7996, Telex: AA27439
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