Free Lime Determination

CH2OH CH2
+ CaO Ca(OH)2 + O
CH2OH CH2

Ca(OH)2+2HCl CaCl2 + 2H2O

(74.08)            (72.92)

2 N of 1000 ml of HCl reacts with 74.08 Parts of Ca(OH)2

1 N of 1000 ml of HCl reacts with 37.04 Parts of Ca(OH)2
0.998 N of 1 ml of HCl reacts with 0.0369659 Parts of Ca(OH)2

74.08 Parts of Ca(OH)2 corresponds = 56.08 Parts of CaO

0.036966 Parts of Ca(OH)2 corresponds= 2.798392 Parts of CaO
Weight of Sample 1 grms
Factor 2.7984

Standardisation of 0.1 N of Hcl

Standardisation by Na2B4O7.10H2O
Indicator bromocresol green indicator
Endpoint blue to green

1000 ml of 1 N of Hcl reacts with 190.685 grms of Na2B4O7.10H2O

1 ml of 1 N of Hcl reacts with 0.190685 grms of Na2B4O7.10H2O
1 ml of 0.1 N of Hcl reacts with 0.0190685 grms of Na2B4O7.10H2O
For 0.0190685 grms of Na2B4O7.10H2O 1 ml of 0.1
For 0.35 grms of Na2B4O7.10H2O 18.4 ml of 0.1

Suppose the endpoint will come at 18.53 ml

Then Normality of HCl 0.099 N

Preparation of 0.1N of Hcl

Eq Wt of HCl 36.46

1000 ml of 1 N of Hcl 36.46 ml of Hcl dissolved in 1000ml

1000 ml of 0.1 N of Hcl 3.646 ml of Hcl dissolved in 1000ml
Specific gravity of Hcl 1.18
So volume of 0.1 N of Hcl 3.0898305 ml of Hcl dissolved in 1000ml
Purity of Hcl 38 %
For 1000 ml of 0.1 N of Hcl 8.13 ml of Hcl dissolved in 1000ml
Na2B4O7.10H2O
Na2B4O7.10H2O
Na2B4O7.10H2O
N of Hcl Consumed
N of Hcl Consumed

dissolved in 1000ml
dissolved in 1000ml

dissolved in 1000ml

dissolved in 1000ml