EXCEL 2022

CARBOXYLIC ACID AND DERIVATIVES

Prep & Prop of CARBOXYLIC ACID 08B

Marking Scheme : Single Correct (+3,-1) M M: 96 Time : 1 hr

1.

(a) (b)

(c) (d)

2.

(a) (b)

(c) (d)

3.
(a) (b) (c) (d)

4.

(a) (b)

(c) (d)

5.

(a) (b) (c) (d)

5
Newtown, Kolkata-700 156
: iitianexplains.kol@gmail.com
6.

(a) (b) (c) (d)

7.

(a) (b)

(c) (d)

8.

(a) (b) (c) (d)

9. Find out the nucleophiles

6
Newtown, Kolkata-700 156
: iitianexplains.kol@gmail.com
10. CH3CH2COCl —NaN  X — Y —H O Z
3 2

(a) X is CH3CH2CON3 (b) Y is CH3CH2NCO (c) Z is CH3CH2NH2 (d) Z is CH3CH2CH2NH2

11.

(a) X is (b) Y is (c) Z is (d) Y is

12.

(a) X is (b) X is (c) Y is (d) Y is

13.

(a) X is (b) Y is HCHO (c) Y is (d) X is

O

14.
(a) X is (b) Y is (c) X is (d) Y is

15. An ester (X) of the formula C4H8O2 on acidic hydrolysis gives an acid (Y) which reduces Tollen’s
reagent and an alcohol (Z) which gives iodoform test. Ester (X) can also be converted into alcohol (Z) by
reaction with excess of grignard reagent (W).
(a) X is (b) Y is (c) Z is (d) W is

EtCHCO EtCHCO EtCHCH 2OH EtCH CH2 OH

O X O Y Z
16. CH 2CH CH 2CH CH 2CHOH CH 2 CHO + MeCHO .

MeC CH2 MeCO MeCHOH

(a) X is O3; H2O / Zn (b) Y is LiAlH4 (c) Z is HIO4 (d) Z is HI / RP

17.

(a) X is (b) Y is (c) X is (d) Y is

7
Newtown, Kolkata-700 156
: iitianexplains.kol@gmail.com
18. An organic lactum X on acid hydrolysis produces Y, an amino acid. Y on treatment with nitrous acid gives
Z. Z on heating with, conc. H2SO4 produces a lactone W. X can also be synthesised by the reaction of
cyclopentanone with hydroxylamine followed by treatment of product with conc. H2SO4
O
O
NH 2 O OH
(a) X is N––H
(b) Y is HOOC (c) W is (d) Z is HOC

19. Compound (X) with molecular weight 108 contains C = 88.89% and H = 11.11%. It gives white precipitate
with ammonical silver nitrate. On complete hydrogenation of (X) gave another compound (Y) of molecular
weight 112. (X) upon oxidation gave an acid of equivalent weight 128. The acid upon decarboxylation
gave cyclohexane.
CH 2––CH3 C CH CH 2––CH3

(a) X is (b) Y is (c) X is (d) Y is

8
Newtown, Kolkata-700 156
: iitianexplains.kol@gmail.com
All students are advised to solve DPPs within allowed time only.
All discussions are scheduled in every 4th doubt discussion class
–MKA Sir (Guruji)

20
Newtown, Kolkata-700 156
: iitianexplains.kol@gmail.com