Date: 25-12-2021 Name:K.N.

Rohan Reg No:21BCE7071

Experiment 6

CONDUCTANCE MEASUREMENT OF ELECTROLYTE SOLUTIONS AT

VARIOUS CONCENTRATIONS

OBSERVATION:

Table 1: Conductivity of various electrolytes

Conductivity Temperature
S. No. Concentration (C) M
(Λ) S cm 2 mol−1 (T) K
1 0.1 M HCl 37.52 298
2 0.1 M LiCl 10.75 298
3 0.1 M NaCl 12.28 298
4 0.1 M KCl 14.21 298

Table 2: Conductivity vs Dilution

S. Solution Concentration Conductivity (Λ) Temperature

2 −1
No. volume, mL (C) M S cm mol (T) K
1 100 mL 0.1000 M  12.28 298 
2 100 + 20 mL 0.0833 M  10.27  298
3 120 + 20 mL 0.0714 M 8.89   298
4 140 + 20 mL 0.0625 M 7.86   298
5 160 + 20 mL 0.0556 M 7.01   298
6 180 + 20 mL 0.0500 M 6.38   298

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Registration No:21BCE7071
 Date: 25-12-2021 Name:K.N.Rohan Reg No:21BCE7071

Table 3: Acid – Base Titration

Volume of Total volume

Conductivity
S. No. NaOH added of NaOH added 2 −1
S cm mol
(mL) (mL)
1 0.0 mL 0.0 19.88 
2 1.0 mL 1.0  17.50
3 1.0 mL 2.0  15.26
4 1.0 mL 3.0  13.23
5 1.0 mL 4.0  11.50
6 1.0 mL 5.0  9.79
7 1.0 mL 6.0  8.38
8 1.0 mL 7.0  6.90
9 1.0 mL 8.0  5.67
10 1.0 mL 9.0  4.28
11 1.0 mL 10.  4.06
12 1.0 mL 11.0  4.66
13 1.0 mL 12.0  5.24
14 1.0 mL 13.0  5.80
15 1.0 mL 14.0  6.32
16 1.0 mL 15.0  6.75
17 1.0 mL 16.0 7.01

Graph: Volume of NaOH vs Conductivity

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Registration No:21BCE7071
 Date: 25-12-2021 Name:K.N.Rohan Reg No:21BCE7071

CALCULATIONS:

Volume of HCl = 10 ml
Molarity of HCl = ?
Molarity of NaOH = 0.1 M
Volume of NaOH = 9.6ml (from Conductivity Vs Volume of NaOH graph)

9.6 ×0.1
The strength of given HCl solution, M1 =
10
= 0.096M

The amount of HCl present in 1 L of the given solution = Strength  equivalent weight

:0.096 M  36.45 g / L = 3.49g / L

RESULTS:

The strength of the given HCl solution : 0.096 M

The amount of HCl present in 1 L of the given solution :3.49 g / L

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Registration No:21BCE7071