CHEM 140.

1 QUANTITATIVE INORGANIC CHEMISTRY (LABORATORY)

LABORATORY REPORT

Name Jhasper John O. Diño Date Submitted: November 12, 2021

Lab Schedule: 7:00-10:00 (Wednesday) Date Performed: November 11, 2021

Experiment No. 6
PREPARATION AND STANDARDIZATION OF NaOH AND HCl SOLUTION

OBJECTIVES

To perform standardization of volumetric solution

To determine the molar concentration of the solution obtained by titration

Note: Show computation on a separate sheet.

RESULTS (g)

STANDARDIZATION OF 0.10N NaOH SOLUTION

TRIAL WEIGHT OF KHP (g) VOLUME OF TITRANT (mL) *CONCENTRATION (N)
1 0.1988 9.8 0.0203
2 0.1989 9.8 0.0203
3 0.1952 9.5 0.0205
*Round to 4 decimal places *Average: 0.0204

STANDARDIZATION OF 0.10N HCl SOLUTION

TRIAL WEIGHT OF KHP (g) VOLUME OF TITRANT (mL) **CONCENTRATION (N)
1 10.0 8.7 0.2239
2 10.0 8.6 0.2240
3 10.0 8.6 0.2156
**Round to 4 decimal places **Average: 0.2212

PREPARATION AND CONCENTRATION OF SOLUTIONS

SOLUTION ***INFERENCE
The 100ml of 0.50N NaOH was transferred into a 500ml
volumetric flask using a 100ml graduated cylinder. Then the
500mL of 0.10 N NaOH prepared using 100-mL graduated
flask was filled with distilled water until the meniscus hit the
cylinder
line. Using an analytical balance, weighed 3 trials of 0.200g of
(KPH).

500mL of 0.10 N HCl prepared using usng 10-mL graduated

pipet

***Note: Discuss the effect of the different preparation on the concentration of the solutions.
 0.10 NaOH Solution

mol KPH
Trial 1: NaOH=
NaOH
0.1988
NaOH=
9.8
NaOH=0.02028571429∨0.0203

mol KPH
Trial 2: NaOH=
NaOH
0.1989
NaOH=
9.8
NaOH=0.02029591836∨0.0203

mol KPH
Trial 3: NaOH=
NaOH
0.1952
NaOH=
9.5
NaOH=0.02054736842∨0.0205

0.0203+0.0203+0.0205
¿
3

¿ 0.02036∨0.0204

∑ ( x −σ ) ²
S=
√ n−1

( 0.0203−0.0204 )2 + ( 0.0203−0.0204 )2 +( 0.0205−0.0204) ²

S=
√ 3−1

0.00000001+0.00000001+0.00000001
S=
√ 2

0.00000003
S=
√ 2

S= √ 0.000000015

S=0.00012247449∨0.0001

0.0001
RSD %=
0.0204

RSD %=0.00490196078∨0.49 %

0.10 HCl Solution

 ( NaOH )(mlNaOH )
Trial 1: HCl=
ml HCl
( 0.1988)( 9.8)
HCl=
8.7
HCl=0.22393563218∨0. 2239

( NaOH )(mlNaOH )
Trial 2: HCl=
ml HCl
( 0.1989)( 9.8)
HCl=
8.6
HCl=0.22665348837∨0. 2267

(NaOH )(mlNaOH)
Trial 3: NaOH=
ml HCl
(0.1952)(9.5)
NaOH=
8.6
NaOH=0.21562790698∨0. 2156

0.2239+0.2267+0.2156
¿
3

¿ 0.22206666667∨0.2221

∑ ( x −σ ) ²
S=
√ n−1

( 0.2239−0.2221 )2+ ( 0.2267−0.2 2 21 )2+(0. 2156−0.2221) ²

S=
√ 3−1

0.00000324+ 0.00002116+0.00004225
S=
√ 2

0.00006665
S=
√ 2

S= √ 0.000033325

S=0.00577278096∨0. 0058

0.0058
RSD %=
0.2221

RSD %=0.0261143629∨2.61 %