Fiitjee Aits 2021 Papers

Fl ITJEE
ALL INDIA TEST SERIES

FULL TEST- II
JEE (Advanced)-2021
PAPER-1
TEST DATE: 04-01-2021
Time Allotted: 3 Hours Maximum Marks: 198
General Instructions:
• The test consist s of t ot al 54 questions.
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• Each subject (PCM) has 18 questions.
• This question paper contains Three Parts.
• Part-I is Physics, Part-II is Chemistry and Part-Ill is Mathemat ics.
• Each Part is f urther divided into Tw o Sections: Section-A & Section-C.
Section-A (01 - 06, 19 - 24, 37- 42) cont ains 18 multiple choice quest ions which have ONLY
ONE CORRECT ANSWER. Each question carries +3 marks for correct answer and -1 mark for
w rong answer.
Section-A {07 - 12, 25 - 30, 43 - 48) this sect ion contains 18 multiple choice questions.
Each question has FOUR options. ONE OR MORE THAN ONE of these f our option(s) is (are)
correct answer(s).
For each question, choose the option (s) corresponding to (all) the correct answer(s)
Answer to each question will be evaluated according to the f ollowing marking scheme:
Full Marks : +4 If only (al l) the correct opt ion(s) is (are) chosen:
Partial Marks : +3 If al l t he four option s are correct but ONLY t hree o ptions are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two opt ions are chosen and
both of w hich are correct;
Partial Marks : +1 If t wo or more optio ns are correct but ONLY o ne o ption is chosen and it is
a correct option;
Zero Marks : 0 If none of t he options is chosen (i. e. t he question is unanswered);
Negative Marks : -2 In all other cases.
Section-C {13 - 18, 31- 36, 49 - 54) contains 18 Numerical answer type questions wi th answer
XXXXX.XX and each question carries +4 marks for correct answer and O marks fo r wrong answ er.
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AITS-FT-11 (Paper-1)-PCM-JEE (Advanced)/2021 2
Physics PART - 1
SECTION-A
(One Options Correct Type)
This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of w hich ONLY ONE option is correct.
1. A particle is ejected from the tube at A w ith a velocity v at an

angle 0 w ith the vertical y-axis. A strong horizontal w ind gives the
particle a constant horizontal acceleration a in the x-direction. If
the particle strikes the ground at a point directly under its released
position and the downward y-acceleration is taken as g then
2
(A) h = 2v sin 0cos0
a
2
h = 2v sin 0cos0
(B)
g
2
2
(C) h= ~ sin0 ( cos0 + :sin0)
2
2
(D) h= : sin0 ( cos0 + ~sin0)
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2. Three blocks A , B, C of w eights 40 N, 30N , 80N respectively are at
rest on an inclined plane as shown in figure. Determine the
smallest value of coefficient of limiting friction (µs) for w hich
equilibrium of system is maintained.
(A) 0.1757
(B) 0.2757
(C) 0.5757
(D) 0.8757
3. A particle falls from a height h on a fixed horizontal plane and rebounds. If e is the coefficient of
restitution, the total distance travelled by the particle before it stops rebounding is
h [1- e 2 ]
(A) 2
2[1 + e ]
h[1- e2 ]
(B)
[1 + e 2 ]
2
h[1 + e ]
(C)
2[1- e 2 ]
2
h[1 + e ]
(D)
[1- e 2 ]
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3 AITS-FT-11 (Paper-1)-PCM-JEE (Advanced)/2021
4. Water of density p in a clean aquarium forms a meniscus, as

illustrated in the figure. Calculate the difference in height h
between the centre and the edge of the meniscus. The surface
tension of water is y.
~
h
(A)
..··-··--···············-·················-
········--· . -....-.............................
·········--······--·-····················
..........._____
............. ............ .....................
~
_.
(8)
(C) ;~
(D) 2~
5. Consider the shown diagram where the two chambers separated by piston-spring arrangement
contain equal amounts of certain ideal gas. Initially when the temperatures of the gas in both the
chambers are kept at 300 K the compression in the spring is 1m. The temperature of the left and
the right chambers are now raised to 400 K and 500 K respectively. If the pistons are free to slide,
the compression in the spring is about.
1
111
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~Im~
(A) 1.3 m
(8) 1.5 m
(C) 1.1 m
(D) 1.0 m
6. An object of specific gravity p is hung from a thin steel wire. The fundamental frequency for
transverse standing waves in the wire is 300 Hz. The object is immersed in water so that one half
of its volume is submerged. The new fundamental frequency in Hz is
1/2
2 1
(A) 300 ( ~; )
1/2
(8) 300 ~
(
2p-1 )
(C) 300( ~ )
2p-1
2 1
(D) 300( ~; )
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(One or More than one correct type)

This section contains 06 multiple choice questions. Each question has FOUR options (A), (B), (C) and
(D). ONE OR MORE THAN ONE of these four options is(are) correct.
7. A horizontal disc rotates freely about a vertical axis through it centre. A ring, having the same
mass and radius as the disc, is now gently placed on the disc. After some time, the two rotate
with a common angular velocity. Select the correct statements from the following.
(A) Some friction exists between the disc and the ring
(B) The angular momentum of the 'disc plus ring' is conserved.
(C) The final common angular velocity is (2/3)rd of the initial angular velocity of the disc.
(D) (2/3)rd of the initial kinetic energy changes to heat.
8. Three concentric conducting spherical shells have radii r, 2r and 3r

and charge q1, q2 and q3 respectively as shown in the figure. Select
the correct alternatives
(A) q1 + q3 = -q2
(B) q1 =- ~
(C) q3 = 3
q1
q3 1
(D) =
q2 3
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9. Remote objects are viewed through a converging lens with a focal length F = 9 cm placed at a
distance a = 36 cm in front of the eye. Assume that the radius r of the pupil is approximately 1.5
mm. Choose the correct options.
(A) The minimum radius of the screen that should be placed behind the lens so that the
entire field of view is covered is 0.5 mm.
(B) The minimum radius of the screen that should be placed behind the lens so that the
entire field of view is covered is 1.0 mm.
(C) The screen must be placed in the plane S with its centre at point B.
(D) The screen must be placed perpendicular to the plane S with its centre at point B.
10. Consider an attractive central force of the form F(r) = -~.k is a constant. For a stable circular
r"
orbit to exist
(A) n=2
(B) n<3
(C) n>3
(D) n=-1
11. A rod OA of length / is rotating (about end 0) over a conducting ring X X X X

in crossed magnetic field B with constant angular velocity ro as X X
shown in figure B
2
3Bro£ X
(A) Current flowing through the rod is - - -
4R X X
. . . 3B 2 ro£2 X X
(B) Magnetic force acting on the rod 1s - - -
4R
X X X X
. . . 3B 2 ro£4
(C) Torque due to magnetic force acting on the rod 1s - - -
8R
(D) Magnitude of external force that acts perpendicularly at the end of the rod to maintain the
2
. 3B ro.e4
constant angular speed Is - - -
8R
12. Two point monochromatic and coherent sources of light of wavelength "A
are placed on the dotted line in front of an infinite screen. The source emit
waves in phase with each other. The distance between S1 and S2 is d
while their distance from the screen is much larger. Then
. 3A. . . .
(A) If d Is - , at O minima will be observed
2
. . 11)., . . . 3
(B) If d Is - , then IntensIty at O will be - of maximum intensity
6 4
(C) if d is 3"A, 0 will be a maxima
7)., 3
(D) if dis - , the intensity at O will be - of maximum intensity
6 4
SECTION-C
(Numerical Answer Type)
This section contains 06 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place; e.g. XXXXX.XX).
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13. A free neutron at rest, decays into three particles: a proton, an electron and an anti-neutrino.
1n
0
➔11 p+ 0-1e+v
The rest masses are: mn = 939.5656 MeV/c2
mp = 938.2723 MeV/c2 me= 0.5109 MeV/c2
In a particular decay, the antineutrino was found to have a total energy (including rest mass
energy) of 0.0004 MeV and the momentum of proton was found to be equal to the momentum of
electron. Find the kinetic energy of the electron.
14. A diver Dis still under water (µ=1) at a depth d = 10
m. A bird is diving along line AB at a constant velocity in

air. When the bird is exactly above the diver he sees it at
a height of 50 m from himself and velocity of the bird
appears to be inclined at 45° to the horizontal. At what
distance from the diver the bird actually hits the water
surface.
...---- --- -----
-------
·-..--- -- ----------
.... -...---............. -------------................
---------- -.. ..
----------
---- - ------ - ----
-------------------
- ----- - ------
--
--- --- ..............---------
- - --- ------
-------------- - -- - --
-- - ------
-----
---· ..................
------------ - - ----
-- -- - ---- -- --- -----
15. A wall is inclined to a horizontal surface at an

angle of 120° as shown. A rod AB of length
L = 0.75 m is sliding with its two ends A and Bon
the horizontal surface and on the wall respectively.
At the moment angle 0 = 20° (see figure), the
velocity of end A is VA = 1.5 m/s towards right.
Calculate the angular speed of the rod at this
instant. [Take cos 40° = 0.766]
A
16. A room is in shape of a cube. A heavy ball (B) is suspended at

the centre of the room tied to three inextensible strings as
show n. String BA is horizontal with A being the centre point of
the wall. Find the ratio of tension in the string BA and BC.
-~ -.. -... -.... ..--. -- ..... --. . -
17. A parallel plate capacitor is to be constructed which can store q = 10 µC charge at V = 1000 volt.
The minimum plate area of the capacitor is required to be A1 when space between the plates has
air. If a dielectric of constant K = 3 is used between the plates, the minimum plate area required
to make such a capacitor is Aa. The breakdown field for the dielectric is 8 times that of air. Find
~
A2
18. A 20 mm diameter copper pipe is used to carry heated water. The external surface of the pipe is
at T = 80°C and its surrounding is at To = 20°c . The outer surface of the pipe radiates like a black
body and also loses heat due to convection. The convective heat loss per unit area per unit time
is given by h(T - To) w here h = 6W (m2 Kt1. Calculate the total heat lost by the pipe in unit time
for one meter of its length.
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Chemistry PART- II
SECTION-A
(D), out of which ONLY ONE option is correct.
19. 38
3D
Overall half life of the reaction 15 days. Then calculate the number of mole of C after 45 days if
the raetio of k 1 : k 2 : k 3 is 4 : 2 : 1
(A) 1
(B) 2
(C) 3
(D) 4
20. For a complex (d6 -configuration) having ~o = 25000 cm-1 and P = 15000 cm- 1 , the crystal field
stabilisation energy is:
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(A) 30,000 cm- 1
(B) -60,000 cm-1
(C) -30,000cm-1
(D) -60,000cm-1
21. When H2S is passed in Ba(OH)2 solution:

(A) milkyness is produced due to formation of insoluble salt
(B) no change is observed because H2S does not reaction with Ba(OHh
(C) milkyness is produced due to the formation of BaSQ3
(D) no change is observed due to the formation of water soluble salt
22. A compound has the empirical formula C10H8Fe. A solution of 0.26g of the compound in 11.2 g of
benzene (C6 H6 ) boils at 80.26°C. The boiling point of benzene is 80.10°C; the Kb is
2.53°C/molal. What is the molecular formula of the compound?
(A) C30H24Fe3
(B) C10 H8 Fe
(C) C5H4Fe
(D) C20H16Fe2
23. Two solid compounds X and Y dissociates at a certain temperature as follows

X(s) ~ A(g) + 2B(g);Kp1 = 9 x 10-3 atm 3
Y(s) ~ 2B(g)+ C(g);Kp2 = 4.5x 10-3 atm 3
The total pressure of gases over a mixture of X and Y is:
(A) 4.5 atm
(B) 0.45 atm
(C) 0.6 atm
(D) None of these
24. In the preparation of iron from haematite (Fe2O3) by the reduction with carbon
Fe2O 3 +C ➔ Fe+CO2
How much 80% pure iron may be produced from 120 kg of 90% pure Fe2O3?
(A) 94.5 kg
(B) 60.48 kg
(C) 116.66 kg
(D) 120 kg

This section contains 06 multiple choice questions. Each question has FOUR options (A), (8), (C) and
25. Consider the reactions given below. In which cases will the reaction proceed toward right by
increasing the pressure?
(A) 4HCl(g)+O2(g) ➔ 2Cl2(g) + 2H2O(g)
1
(B) Cl2(g)+ H2O(g) ➔ 2HCl(g)+-O2(g)
2
(C) CO2(g) + 4H2(g) ➔ CH4 (g) + 2H2O(g)
(D) N2(g)+O2(g) ➔ 2NO(g)
0
26. In which pair second ion is more stable than first?
vve 0 0
o® V V
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r"yOH r"yCH3
~ ~
®
® 0 1/ 1/
(i) (ii) -- (iii) -- (iv)
(A) (i) and (ii)
(B) (ii) and (iii)
(C) (ii) and (iv)
(D) (iii) and (iv)
27. Which of the following is/are correct?

(A) ~H = ~U + ~(PV) when P and V both changes
(B) ~H = ~U + P~V when pressure is constant
(C) ~H = ~U + V ~P when volume is constant
(D) ~H = ~U+P~V +~V~P when P and V both changes
28. Ionisation energy order is CORRECT for:

(A) Sc 3 + >Sc2+ > Sc+
(B) Sc 3 + > Ti 4+ > v 5 +
(C) Sc > Y > La
(D) Sc > Ca> K
29. Select which square planar complex(es) can show optical isomerism.
(A) Bis(en)platinum (II) ion
(B) bis (Gly)platinum (II)
(C) di(NH3)(Gly)platinum (II) ion
(D) di(NH3) (N-methyl N-ethylglycinato)platinum (II) ion
30. Reaction of R-2-butanol with p-toluenesulphonyl chloride in pyridine then LiBr gives:
(A) R-2-butyl bromide
(B) S-2-butyl tosylate
(C) R-2-butyl tosylate
(D) S-2-butyl bromide
SECTION-C
31. 32 g of a sample of FeSO4.7H2O were dissolved in dilute sulphuric acid and water and its volume
was made up to 1 litre. 25 ml of this solution required 20 ml of 0.02 M KMnO4 soluton for
complete oxidation. Calculate the mass% of FeSO4.7H2O in the sample.
32. A mixture of nitrogen and water vapours is admitted to a flask at 760 torr which contains a
sufficient solid drying agent. After long time the pressure attained a steady value of 722 torr. If the
experiment is done at 27°C and drying agent increases in mass by 0.9 gm, what is the volume of
the flask? Neglect any possible vapour pressure of drying agent and volume occupied by drying
agent.
33. Stearic acid [CH3 (CH2 ) 16 CO2 H] is a fatty acid, the part of fat that stores most of the energy. 1.0 g
of stearic acid was burned in a bomb calorimeter. The bomb had a heat capacity of 652 J/°C. If
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the temperature of 500g water (c = 4.18 J/g°C) rose from 25.0 to 39.3°C, how much heat was
released when the stearic acid was burned?
[given CP = (H 2 O) = 4.18J / g°C]
34. In neutral or faintly alkaline solution, 8 moles permanganate anion quantitatively oxidise
thiosulphate anions to produce X moles of a sulphur containing product. The magnitude of X is:
35. In the Hall process, aluminum is produced by the electrolysis of molten Al2O3. How many second
would it take to produce enough aluminum by the Hall process to make a case of 24 cans of
aluminum soft-drink, if each can uses 5.0 g of Al, a current of 9650 amp is employed , and the
current efficiency of the cell is 90.0%:
36. A 2.24l cylinder of oxygen at 1 atm and 273 K is found to develop a leakage. When the leakage
was plugged the pressure dropped to 590 mm of Hg. The number of moles of gas that escaped
will be:
Mathematics PART - 111
SECTION-A
37. The results of 10 cricket matches (win, lose or draw) have to be predicted. How many different
forecasting can contain exactly 7 correct results?
(A) 100
(B) 120
(C) 960
(D) None of these
38. The value of J----==---=1= = = X is

½2 ~(2 +3x) 4
~3/X +c
(A)
2v~
..!_3/X +c
(B)
2v~ 2
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1(
(C) 2 X
2+ 3x
)
+c
(D) None of these
where c is integration costant
39. If A(- 1, 2, - 3), 8(5, 0, - 6) and C(0, 4 , - 1) are the vertices oft,;. ABC, then direction ratios of the
external bisector of LBAC are
(A) -11, 20, 23
(B) -11, 20, 20
(C) 11, 20, 21
(D) none of these
40. Number of solutions of lz - 11 + lz + ii = 4 and 12z - 1 + ii = ✓14 is

(A) 2
(B) 3
(C) 4
(D) none of these
Lasin A cos ( B-C )

2 2
41. In MBC, = nR where R is the radius of circumcircle, then n is equal to
LsinA
(A) 1
(B) 2
(C) 3
(D) none of these
42. ABCD is a cyclic quadrilateral with AC_l_BD and O is the centre of its circumcircle, then
OA . OB + OB . OC + OC. OD + OD. OA is equal to
(A) 1
(8) -1
(C) 0
(D) none of these

This section contains 06 multiple choice questions. Each question has FOUR options (A}, (8), (C) and
43. Tangents are draw n from ( -2, 0) to y 2 = Bx, radius of circle(s) that would touch these tangents
and the corresponding chord of contact, can be equal to,
(A) 4 (✓2+1)
(8) 4 (✓2 -1)
(C) 8✓2
(D) 4✓2
44. Let z1, z2 be the roots of az2 + bz + c = 0 with a, b, c complex number and a ct:. 0 and w 1 , w 2 be
roots of(a + c)z + (b + b)z +(a+ c) = D . lfJ z1 I< 1, I z 2
2
I< 1, then
(A) I w 1 I< 1
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(B) I w 1 I= 1
(C) I W2 I< 1
(D) Jw 2 J=1
45. Let [ x] = the greatest integer less than or equal to x. The equation
sin x = [ 1+ sin x] + [ 1 - cos x] has
(A) . .m [ - n ,n ]
no solution
22
(8) no solution in [ i, n]
(C) . .m [ n, 3n ]
no solution
2
(D) no solution for x E R
46. lfin ~ ABC, a 4 + b4 + c 4 = 2a 2 (b 2 + c 2 ), then L A is

(A) 45°
(8) 60°
(C) goo
(D) 135°
47. The solutions of 0 E [O, 2n] satisfying the equation log✓J tans( ✓log1ane 3 + log✓J 3.J3) = -1 are
7t
(A)
6
7t 5n:
(B)
3'3
4n
(C) has sum -
3
(D) None of these
48. A drawer contains red and black balls. When two balls are drawn at random , the probability that
. 1 .
they both are red Is-. The number of balls In the drawer can be
2
(A) 21
(B) 11
(C) 4
(D) 3
SECTION-C
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49. The tangents are drawn from the points of a straight line 3x + 4y = 24 to the curve
2
x2 + L = 1 . Then all the chords of contact passes through a fixed point {a, b}, then 2a + 3b
4
50. Shortest distance between lines x- 6 = y - 2 = 2 - 2 and x+ 4 = y = 2 + 1 is d then

1 -2 2 3 -2 -2
1
100d+- =
2
1 1 1
51. Find the distance of the point P (3, 8, 2) from the line - (x - 1) = - (y - 3) = - (z - 2) measured
2 4 3
parallel to the plane 3x + 2y - 2z + 15 = 0
X 1 1
52. Let f(x) = sin2n:x 2x2 1 . If f(x) be an odd function and its odd values is equal g(x), then find
x3 3x4 1
the value of 11..
lfll.f(1)g(1)=-2
1 -1 1
53. If A =0 2 -3 and B = (adj A) and C = 5A, then find the value of ladj Bl
2 1 0
ia 2ia. ia
54. Let fP(a) = e7l _e7 _______eP p EN (where ; = ~ . then find the value of ]!i~"1(n)j
Fl ITJEE
FULL TEST- II
JEE (Advanced)-2021
PAPER-1
TEST DATE: 04-01-2021
ANSWERS, HINlS & SOLUTIONS
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Physics PART- I
SECTION-A
1. D
Sol. .
Since 0 = ( v sin
. 8 )t + -1 ( -a )t 2 ⇒
2v-
t=- sin-
8
2 a
1
Also, h = (v cos8)t +-gt2
2
2
⇒ h
2v • ( cos8 + asm8
= asm8 g . )
2. A
Sol. For the impending motion, block A must slip up and block C down the inclined plane. Since the
normal force between A and B is less than that between block B and C, the maximum frictional
force (limiting friction) will be reached first between A and B while Band C will stay together.
}C
F,4a
Writing equilibrium equations:
IFy = O;
NA - WACOS3O°=O
NA = WACOS3O°
NA= 20✓3N
AITS-FT-11 (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 2
Also, for impending motion if FAB is frictional force between blocks A and B, then
f AB = µs.NA = 20✓JµsN .. . (1)
L FX=0;
T - WA sin 30° - FAB = 0
T-40!-20✓
2
3µ s
=0
T = 20(1 + ✓3µ.)
From FBD of block Band C combined
X
Writing equilibrium equation

IFy =0·'
Nc -NA -(W8 + Wc)cos30°= 0
N -
C
20✓3 -110 ✓
2
3 =0
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NC =75✓ 3N
Also, for impending motion:
WB
Fs,1
... (3)
For LFx = 0, we have
TA + (FBA + Fc)- (W 8 + Wc)sin30°= 0
r;:; r;:; 110
T + [20-v.J + 75-v3µJ- =0
2
T = (55-95✓ 3µs)
Since tension is same, so from (2) and (4), we get
20(1 + ✓ Jµs ) = (55 - 95✓ Jµs )
Solving for µs we get, 115✓3µs = 35
35
or µ = r;:; = 0.1757
• 115-v3
Minimum µs = 0.1757
3 AITS-FT-11 (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021
3. D
Sol. The velocity of particle after falling through height h
u = ✓2gh ... (i)
v =u
2 2
- 2gh
0 =e u 2 2
- 2gh1
e 2u2
e 22gh
or h1 = 2g = - - = e 2h [From Eq. (i)]
2
O = e4 u2 - 2gh 2
4
or h2 =e h
= h + 2h1+ 2h2 + ··.oo
= h + 2e2 h + 2e2 h + ...oo
= h + 2e2 h(1 + e 2 + e 4 + ...oo)
h h(- 1-
= + 2e2
1-e2
)
= h ( 1+ C: ::)
1
~e~2 ) = h
4. A
Sol.
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·--··
- ----..--------------------- -
··-··-····.......... --------
.............
---·.
Balancing forces in horizontal direction
( Po - pg~} h + yl! = Pl h ⇒ h =~
5. A
Sol. Let 11 and 12 be the final lengths of the two parts, the from gas equation
SOOK
~ "i ___,. ~ "2 ___,.

POACO = PA£1 = PAR2 ...(i)
To T1 T2
P0 A = kx0 and PA= kx
p X
or ... (ii)
x-xo = £1 +£2 -2£0 ... (iii)

From equation (i),
£ = PaRoT1 and £ = Po£o T2
1 2
PT0 PT0
From equation (ii),
xo£0T1 x o£0T2
£ =-and £ =
1
X o
T 2 T
X o
Putting these in equation (iii),
X-Xo = Xlo [T1+ T2]-2£o
xT0
Substituting the values and solving for x, we get
X Rl 1.3 m
6. A
Sol. f= ; £ J!;;
In air :T =mg= pVg
.-. f = 2~ ✓p~g
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In water: T = mg - upthrust
V Vg
= Vpg-2p"g = 2(2p- p,, )
Vg
- 2 (2p-pJ
. f' = _!_
·· 2£ m
=-1 ✓Vgp /2p-pJ

2£ m 2p
~ = ✓2p2~p"
f' = f ( 2p2~P,, r2
2
~~ J'
2
1
300 ( Hz
7. A, B, D
Sol. Let ro1 = the initial angular velocity of the disc.
ro2 = the final common angular velocity of the disc and the ring.
For the disc, 11 = 2mr2

2
For the ring, 12 = mr2
By conservation of angular momentum, r

L = l1ro1- (11 + 12)co2
!I
or ro 2 -
- ~- - ro/
1 3
m -.. .; ;:= ==i===~ii
11+ 12
m ' 1,
Initial kinetic energy= E 1 = !11ro~
2
Final kinetic energy = E2 = ! (11 + 12 )co~

2
Heat produced = loss in kinetic energy = E1 - E2
E1 -E 2 2
Ratio of heat produced to initial kinetic energy = - - - =
E1 3
8. A, B, C
Sol. Potential on innermost shell is zero
-9!_ + q2 + ~ = 0
r 2r 3r
⇒ 6q1+ 3q2 + 2q3 = 0 ... ( 1 )
Potential on outermost shell is zero
~ + ~ + ~ = 0 ⇒ q, + q3 = -q2 ... (2)

3r 3r 3r
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9. A, C
Sol. Let us first neglect the size of pupil, assuming that it is point-like. Obviously, only those of the
beams passing through the lens will get into the eye which have passed through point B before
they fall on the lens (figure). This point is conjugate to the point at which the pupil is located.
s
a b
1 1 1 aF
- = - + - b = --=12cm
F a b' a-F
b
R = -r =: 0.5mm, and the screen must be placed in the plane S with its centre at point B.
a
10. A, B, D
Sol. F(r) = -~
r"
k 1
⇒ U(r)
f
= - F(r)dr =----------:::;-
(n -1) r"
L2 L2
Kinetic energy = - = - - = K(r)
21 2mr2
Since total energy E(r) = U(r) + K(r)
k 1 L2
⇒ E(r)=---.-+-
1 2
(n -1) r"- 2mr
8EI 8EI
2
⇒- =0and-2
> 0,
ar r -1{) or r-lQ
. both condItIons,
Using .. (3 - n ) -L2 > 0
m
11. A, B, C,D
Sol. I= ~ = 3s
2R 2R
3
= ~ x __!_ Bro.e2 = 3Bro.e2
2R 2 4R
. 3Bro£2
Magnetic force F = - - - x £ x B
4R
4R
3B2 ro£3 .e 3B 2 ro£4
T=--- X- = - - -
4R 2 8R
3B2 ro£3
Force to be applied at the end =---
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8R
12. A , B, C, D
Sol. For maxima d = n1c
For minima d = (n + 1/2)1c
. . 34
For IntensIty - th of maximum . d= (n ± -31)"'-2
SECTION-C
13. 00000.78
Sol. From conservation of energy
mnc 2 = mpc 2 + kp + m.c 2 + ke + mVc 2 + k V
939.5656 = 938.2723 + 0.5109 + 0.0004 + (kP + ke)

[·: mvc2 + kv = 0.0004 MeV]
⇒ kP + ke = 0.0004 MeV
p2 p2
⇒ -+-=0.7820MeV
2mp 2m.
⇒ ~[1m.l
2m.
+
mp
= 0.7820
k.= ( mp )x 0.7820=0.7820MeV
mp +m.
14. 00024.62
Sol. happ = µh
happ = 50 - d = 40 m and m = µ = 4/3
h = 30m
Now, happ = µh
Vyapp = µVy
T
h
Vxapp = Vx
a C
V
Given yapp = tan 45° = 1 :=:=:=~========~~==~========~==·Qi~~~======~==~~======~:=:=:=:=:=~~====
:-:-:-:-: : :-:-:-::-:-: :-: J O,m~-_-:-:-:-:-:-:-:-:-:-:-:-:-:-:-:-:-:-:-: ::-
v ..app
-
-_-_-_:.-_-_-----_-:.-_-_-_-_-_-_-_-_-_- { ---_-_-_---_-_-_-_-_-_-_-_-_-_-_-_-_---_-_-_
µVv = 1 ⇒ tan a = _!_ = ~
-:-:-::-::-::-::-::-:-:-::-::-:-:-:-::-:-::-::-ot:-::-::-:-:-:-:-::-::-:-:-::-::-::-:-:-:-:-::-::-:-:
----------
---- -- - ---
- -- ---- ----
----- -------------------------------
- ------
--- -------- -- ------------------- - -- ----
-- ---- -----
------ --
v. µ 4
a = 37°
a is the true angle that the line of motion of the bird makes with horizontal.
OC = htana = 30.~
4
= 22.5 m
DC= -}(22.5}2 + 102
= 24.62 m
15. 00002.26
Sol. Sine Rule
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X y L
----= =---
sin(60-8) sine sin120°
:. x = ~ sin(60 - 8)
dx = ✓
:. dt 2L
3 cos(60 - 8}
( de )
-dt 120°
de X
Note - - = ro =angular speed.
dt
[0 is decreasing, hence a negative sign]
dx
When 8 = 20°,- = 1.5 m / s.
dt
:. w = 1.5 x 1.732 = 2 _26 rad/s
2 x 0.75 x 0.766
16. 00001 .15

Sol. Let tension in BC & BO be T 1 and that in string BA be T 2
The string CB and DB make an angle of a = cos-

1
( ~ Jwith vertical because the diagonal of a
cube makes cos-

1
( ~ Jangle with a side.
Line BM makes 13 = 45° with vertical.
CB = ✓3a CM = !
2 ' 2
. 1
.-.sm0= .J3
Resultant of tension in CB and DB is along BM equal to
2T0 = 2T1 cos 0 = 2T1 JI

Vertical component of To balance Mg and its horizontal component is equal to T 2.
:. T0 cosl3 = Mg
T0 sinl3 = T2
⇒ 2)IT sin 13 = T1 2
⇒ 2)IT, ~ = T 2
T2 2
⇒---
T1 - .J3
17. 00024.00
KE0 A
Sol. C= = a constant
d
For A to be minimum, d must be minimum. The separation between the plates is limited by the
breakdown strength of the dielectric.
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V
For air capacitor -=Eair [Eair = Breakdown field for air]
dmin
Now
C V
⇒ Amin =
E0 E.,
A1 =S!Y.._
Ea Eair
With dielectric, similar calculation gives

A2 = CV
K Ea E dielec
~= KE dielec =3x8=24
A2 Eai,
18. 00051 .70
Sol. qconv= h(T - To)= 6(80 - 20) = 360 Wm-2
For 1 m length of the pipe
Oconv = qconv A = qconv x 2nr
=360 x 2 x 3.14 x 0.01 = 22.6 wm- 1
qrad = a(T4 - To ) = 5.67 X 1o-s (3534 - 2934 ) = 462 wm-2
4
For 1m length of the pipe

Orad = qrad A= 462 x 2 x 3.14 x 0.01 = 29.1 wm-1
Oconv + Orad = 22.6 + 29.1 = 51.7 wm- 1
Chemistry PART- II
SECTION-A
19. B
Sol. Mole of A remain after 45 days
K1/3B
A ,../'"K 2
'----------K3 ► 8C K1 : K2 : K3 = 4 : 2 : 1
~ 3d
"
~=~-1-=_1 =_!_
2n _I_ 245/15 23 8
2i112
Moles of A convert into product Imai

8
7 8 K2
Moles of [C) = x- x- =2
K1 + K 2 + K3 8 1
20. C
Sol. CFSE (In octahedral) = = (-0.4 x n x l'.'1 0 ) + 2PE
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t 1 1 1 1
1L 1L 1L
21. D
Sol. H2 S + Ba(OHb ➔ BaS + 2H 2 O
(Water so luble)
22. D
Sol. Tb= 80.26,
0 26
0.16 = 2.53 x · I M x 1000;M,., 367
11 .20
That is almost molar mass of C20 H16Fe2 .
23. B
Sol. X(s) ~ A(g)+ 2B(g )
X (2x+2y);
Kp, = pA .PJ(total)
Y(s) ~ C(g)+ 2B(g)
y (2y+2x);
Kp2 = Pc .Pg (total)
Kp X
- ' =- ⇒ x=2y
KP2 y
KP, = x(2x + 2y)2
AITS-FT-11 (Paper-1 )-PCM(Sol.)-JEE (Advanced)/2021 10
⇒x = 0.1 atm ;
:. y = 0.05 atm
Total pressure of gases = PA + P 8 + Pc
= 3(x + y)
= 0.45 atm.
24. A
Sol. Balanced reaction is
2F2 O 3 + 3C ➔ 4Fe + 3C02
Number of moles of Fe2O3
= ( 120 x 1000 )x 90
2 x 56 + 48 100
Mass of 80% pure iron produced
120 X 1000 X O.9 2 X 56
------x - -
2 x 56 + 48 0.8
= 94500 gram or 94.5 kg
25. A, C
Sol. Apply Le chatlier principle.
26. B
Sol. (ii) and (iii)
2nd ion is aromatic.
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27.
Sol.
A , B, C
AfI = ~u + P.~V + V.~P
is correct relation.
28. A , C, D
Sol. Factual
29. D
Sol.
30.
11 AITS-FT-11 (Paper-1 )-PCM(Sol.)-JEE (Advanced)/2021
Sol.
~o
s1/'
OH 0/ ~
I l o
H C--C-CH --CH
3 2 3 I l
H C--C-CH --CH
0
3 2 3
H H
!
N
LiBr
H
I
H C--C-CH --CH
3 I 2 3
Br
S - 2 - Butylbrom ide
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SECTION-C
31. 00069.50
Sol. M-eq. Of FeSQ4_7H2O in 1 litre
= 20 X 0.02 X 5 X (
1
= 80 ~~O)
:. .!!___x1 x 1000=80 ⇒ W=22.24
278
Mass & of FeSQ4_7H2O in given sample
22 24
= · X 100 = 69.5
32
32. 00024.63
38 0.9
Sol. PH2O = 760- 722 = ~atm; nH2 O =
760 18
0 9 0 821 300
v = - x · x x 750-v = 24.63L
18 38 '
33. 00039.21
Sol. -qreaction = qbomb + qwater
qreacton = (C(bomb) + (mwater x C ))LH
= (652 + 500 X 4.18)x 14.3
= 39210J or 39.21 kJ
34. 00000.60
+7 +2 -t4 +6
Sol. Mn 0 4+ S 2 o~- ➔ Mn 0 2 + soi-
x
Equivalents of MnO4 = equivalents of soi-
Moles of Mn0:4x n -factor = moles of so~- x n - factor
8 x 3=X x 4
X=6
~=0 .6
10
35. 00148.14
So I. . Ient of aIummIum,
No. of equIva . . W = l x 11 x t
E
9600
24 x 5 x = 9650 x 0.9 x t
3
27 96500
t = 148.14 sec
36. 00000.02
. .. PV
Sol. P ex: n, IrntIal mole n1 = RT = 0.1 mole
£j_ = _rl1__
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Mathematics PART- Ill
SECTION-A
37. C
Sol. Correct prediction can be given in 1 way, and Incorrect prediction can be in 2 ways
.-. Required number of ways = 10C1 (1 )7 (2)3 = 960.
38. A
Sol. J 1 X
½.2 ~(2+3x)4
= J x
2I3
(2 + 3x
1
)4' 3
dx
2+3x -2
Let - - =t ⇒ -2 dx = dt
X X
= -~J-1-dt = ~t-113 = ~ [ - x -] 113 +c -

2 t 4 13 2 2 2+3x
39. A
Sol. If the external bisector of L'.BAC meets BC at E, then E divides BC externally in the ratio of
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AB :AC.
AB= 7, AC= 3 .
5 1
.-. Coordinates of E are ( -: , 7, ~ )
15 23
:. The direction ratio of line AE are -
4
+ 1, 7 - 2
'
!.!
4
+3 = - !.!
4'
5
' 4
= - 11 , 20, 23
40. A
Sol. lz - 11 + lz - iI = 4 represents ellipse with foci ( 1, 0) and (0, -1 ) and length of major axis = 4.
_
Centre of ellipse _ ( 1
1s ,- 1) and ( 1-i)
2 2 2
2a = 4 2ae = -J2 ⇒ e = - 1-
' 2-J2
From b2 = a2 (1 - e 2 ), we get b = ~
Now 12z - 1 + ii = M
⇒ lz-~+~l=l
⇒ lz-(1;i)I = ~ represents a circle having centre at
1-i
2
and radius = 'V
/7 .
2
Since radius of circle = minor axis of ellipse.
Hence number of solution of given equation= 2.
41. A
sinA sinB sinC sinA + sinB + sinC 1
Sol. We know - - = - - = - - = - - - - - - - - -
a b c a+ b+c 2R
LsinA 1 LsinA 1
-------=- ⇒ ----=------=-
La (cosB + cosC ) 2R L 2acos( B; C ) cos( B; C ) 2R
Lsin A cos ( -B-C)

-
⇒
2 ---
--- 2
- =R ⇒ n=1 .
LsinA
42. C
Sol. As OA= OC
so OA + OC will be perpendicular to AC
- -
:. OA + OC = 1.BD
- . .... ( 1)
where "' is the real number.
Similarly, 0
-OB + -OD=µAC .... (2)
B D
where µ is the real number.
Now using (1) and (2), we get
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43.
Sol. y
B
Point 'P' clearly lies on the directrix of y2 = Bx.
Thus slope of PA and PB are 1 and -1 respectively.
Equation of PA: y =x +2, equation of PB : y = -x -2, equation of AB: x = 2.
Let the centre of the circle be ( h, 0) and radius be 'r'
lh + 2I
lh - 2I
⇒ --=--=r
✓2 1
⇒ h + 4 + 4h = 2(h2 +4 - 4h) ⇒ h2 - 12h + 4 = 0
2
1 2±8✓2 ,,; ,,; ,,;

h= -- =6±4 v2 ⇒ I h-21 =4(v 2 -1}, 4(v 2 +1}.
2
44. B, D
Sol. a+c :t: 0
(a + c)w; + (b + b)w 1 + (a + c ) = o
(a + c)w; + (b + b)w 1 + (a + c ) = o
_ 1 - 1 _
·: w1 0 * : . (a + c)-=T+(b + b)-=- + (a + c ) = 0
W1 W1
1 . 1
:. -=- Is also a root but w 2 1c -=-
W1 W1
45. A , B, C, D
3
Sol. At x=-~, n: ; [1 + sinx]=0,[1-cosx]=1
2 2
sin x = 0 + 1 ⇒ -1 = 1 (absurd)
At x = 0, [ 1 + sin x] = 1, [ 1 - cos x] = 0
sin x = 1 + 0 ⇒ 0 =1 (absurd)
At x = ~ , [ 1 + sin x] = 2, [ 1 - cos x] = 1
2
sin x = 2 + 1 = 3 (absurd)
At x = re, [1 + sin x ]= 1, [1 - cos x] = 2
sin x = 1 +2 = 3 (absurd)
In ( -~ ,O} [1 + sinx] = 0, [1-cosx] = 0
sin x = 0 + 0 = 0 (absurd)
In ( 0,~ } [1 + sinx] = 1,[1-cosx] = 0
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sin x = 1 + 0 = 1 (absurd)
In ( ~ , n:} [ 1 + sin x] = 1, [ 1- cos x] = 1
sin x = 1 + 1 = 2 (absurd)
3
In ( re, re } [1 + sin x] = O,[ 1- cos x] = 1
2
sinx = 0 + 1 = 1 (absurd)
46. A, D
Sol. We have a 4 + b 4 + c 4 = 2a 2 (b 2 + c 2 )
a 4 + b4 + c 4 - 2a2 b 2 - 2a 2c 2 + 2b2 c 2 = 2b2c 2
(b 2 + c 2 -a
2
)2 = 2b2 c 2
b2 2 2 1
b2 + c 2 - a2 = ✓2bc or b 2 + c 2 - a2 = -✓2bc +c - a =_
' 2bc ✓ 2
2 2 2
b + c -a 1
or ~~~~=
2bc ✓2
1
cosA = - = cos 45°
✓2
cos A = - ~ = cos ( re - ~ ) = cos 34re
47. A, C
Sol. log../3 tans

log../3 3 + log(✓3fj ___ 1
log../3 tans log.J3
r
⇒ log../J tane [
2
log../3 tan0
+ 3 ] =-1
Let log../3 tan 0 = y
⇒ y
y<O
y y JF
1 2
y y
1
=-1 ⇒ -+3=-- ⇒ -+3= 2 or y 2 (2 + 3y ) =y ⇒ y [3y2 + 2y-1 ] =0
y(3y-1) (Y + 1) = 0
y = -1 ( ·.- y cannot be positive)
⇒ log../3 tan0=-1
1
tan0 = ✓3
n 7n
0=- and -
6 6
There are two value of 0 in [O, 2n]
48. A, C
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Sol. Let the drawer contains p balls of which 'm' are red.
me 2
1
Probability of drawing two red balls at random is - - = -
P C2 2
⇒ 2m(m -1)= p(p-1)
⇒ 2m 2 -2m-p 2 + p=O
⇒ m= 2± ✓4-8(p-p 2 ) = 1± ✓1-2p+2p 2
4 2
⇒ 1- 2 p
2
+ 2p should be an odd perfect square.
i.e. , p = 21, 4 but p 3 *
when 3 balls out of 4 are red.
15 balls out of 21 are red.
SECTION-C
49. 00002.25
Sol. Let the coordinates of a point lying on the straight line 3x + 4y = 24 is t, 244- 3tJ
(
Equation of the chord of contact is tx + _J_ (24 - 3t) = 1

16
⇒ (24 y- 16) + t(16 x- 3y) = 0
⇒ this line always passes through the fixed point which is the point of intersection of the
lines 24y-16 = 0 and 16x- 3y = 0
fixed point = ( ¾,¾J, which lies on 16x - 3y = 0, 9y2 = 32 x and 24 x + 24 y = 19.
50. 00900.50
Sol. 10 2 3
-2 2
3 -2 -2 108
S.D=~------.=====~---9
✓82 + 82 + 42 - 12 -
51. 00007.00
Sol. Let general point of line be A (211, + 1, 411, + 3, 311, + 2). Let this point lies at the same distance as
the point p (3, 8, 2) from the plane 3x + 2y - 2z + 15 = 0
3.3 + 2 .8-2.2 + 15 3(2),, + 1) + 2(4),, + 3)-2(3),, + 2) + 15
Therefore, ~ = ~
v17 v17
⇒ 36 = 811, + 20 ⇒ "- = 2
Therefore, A is (5, 11 , 8)
PA= ✓(5-3)2 + (11-8)2 + (8-2)2 = ✓4+9+36 =7
52. 00000.50
Sol. f(-x) = - f(x) = g(x)
2
1 1 1
f(x).g(x)=-(f(x))2 orf(1)g(1)=-(f(1))2 =- 0 2 1 =-4
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1 3 1
1
⇒ 11,f(1) g(1) = - 2 ⇒ 11,(-4) = - 2 ⇒ 11, = -
2
53. 00125.00
Sol. 3 1 4
Iadj Bl = ladi(adjA)l-IAi - J2 = IAl
·: lnl =5
=125
54. 00001.00
~(1+2 + . + p) !!!:.(1+2)
Sol. fp (a )= eP =e 2 P
!!!:.(1+.!) ~
lim fn (n) = lim e 2 n = e2
n---+oo n ➔oo
Fl ITJEE
FULL TEST- II
PAPER-2
• The test consists of total 54 questions.
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• Part-I is Physics, Part-II is Chemistry and Part-Ill is Mathematics.
• Each Part is further divided into Three Sections: Section-A, Section - B & Section-C.
Section-A (01 - 06, 19 - 24, 37- 42) this section contains 18 multiple choice questions.
Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is (are)
correct answer(s).
For each question, choose the option(s) corresponding to (all) the correct answer(s)
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen:
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is
a correct option;
Zero Marks : 0 If none of the options is chosen (i . e. the question is unanswered);
Negative Marks : - 2 In all other cases
Section-8 (07 - 12, 25 - 30, 43- 48) contains 18 Numerical based questions with Single digit
integer as answer, ranging from O to 9 and each question carries +3 marks for correct answer
and -1 mark for wrong answer.
Section-C (13 - 18, 31 - 36, 49- 54) contains 18 Numerical answer type questions with answer
XXXXX.XX and each question carries +4 marks for correct answer and O marks for wrong answer.
AITS-FT-11 (Paper-2)-PCM-JEE(Advanced)/2021 2
Physics PART - 1
SECTION-A
2 2 2 2
1. A force F= x y f + x y }(N) acts on a particle which moves in XY plane. Choose the correct
option(s)
(A) F is a conservative force
a5
(B) Work done for path ABC is -(J)
3
a5
(C) Work done for path ADC is -(J)
3
5
2a
(D) Work done for path AC is -(J)
3
2. A metal sphere of radius R and specific heat C is rotated about an axis passing through its centre
at a speed n rotation/second. It is suddenly stopped and 50% of its energy is used in increasing
its temperature, then choose the correct statement(s) from the following?
21t2n2 2
(A) Kinetic energy used to raise the temperature of the sphere is --MR
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5
. . . . 51t2n MR
(B) Kinetic energy used to raise the temperature of the sphere 1s - -
3
. . . 4~~~
(C) The rise 1n the temperature of the sphere 1s - - -
?C
21t2n2R 2
(D) The rise in the temperature of the sphere is - - -
SC
3. Choose the correct options for the circuit shown.

, _ . r - - - r - - Earth
4VI
Earth
(A) Potential of the point P is 7V
(B) Current in the 3R resistance is 7/R
(C) Current in the 3R resistance is 7/3 R
(D) Potential of the point P is 3V
4. Two inductors of self-inductances L1 and L2 and of resistances R1

and R2 (not shown here) respectively, are connected in the circuit as
shown in figure. At the instant t = 0, key K is closed. Choose the
correct options for which the galvanometer will show zero deflection
at all times after the key is closed.
(A) .S_ = R3
K
3 AITS-FT-11 (Paper-2)-PCM-JEE(Advanced)/2021
(B)
L1 = R1
L2 R2
(C) ~ = R3
R2 R4
(D) None of these
5. The graph between the stopping potential (Vo) and v0

(~ ) is shown in the figure. <1>1, <1>2 and <j>3 are work Metal I Metal 2 Metal3
functions. Which of the following is/are correct?

(A) <j>1 : <j>2 : <p3 = 1 : 2 : 4
(B) <j>1 : <j>2 : <p3 = 4 : 2 : 1 L-....L.L.-....L.L.-----"'-L---.l(nm-1)
hC 0.001 0.002 0 .004 l
(C) tane oc -
e
(D) ultraviolet can be used to emit photoelectrons from metal 2 and metal 3 only
6. A large plate with uniform surface charge density a is moving o:,.------

with constant speed v as shown in the figure. The magnetic / ~
field at a small distance from plate is ----:
(A) µ 0 crv in magnitude _ _
µ 0 crv . .
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(B) - - in magnitude
2
(C) perpendicular to plate
(D) parallel to plate
SECTION-B
(Single Digit Integer Type)
This section contains 06 questions. The answer to each question is a Single Digit integer ranging from
0 to 9, both inclusive.
7. The densities of two solid spheres A and B of the same radii R vary with radial distance r as
5
p A ( r) = k ( ~ ) and p 8 ( r) = k ( ~ ) , respectively, where k is a constant. The moments of inertia
of the individual spheres about axes passing through their centres are IA and Is, respectively. If
I n
...!!_ = - , the value of n is
IA 10
8. A uniform rod is placed on two spinning w heels as shown in

figure. The axes of the wheels are separated by a distance
50 .. . .
0
-l'. = -1t2 m, the coefficient of friction between the rod and the
wheels is µ = 0.1. The rod performs harmonic oscillations. The

period of these oscillations is 1Ox sec. Find the value of x.
9. A ball of mass of mass 10-2 kg and having a charge+ 3 x 10--6 C is tied at one end of a 1 m long
thread. The other end of the thread is fixed and a charge -3 x 10--6 C is placed at this end. The
ball can move in a circular orbit of radius 1 m in the vertical plane. Initially, the ball is at the
bottom. Find minimum initial horizontal velocity of the ball so that it w ill be able to complete the
full circle.
10. A circular wire loop of radius R is placed in the x-y plane 1 centered
at the origin 0. A square loop of side a(a « R) having two turns is
z
placed with its centre at z = ../3R
along the axis of the circular wire
loop, as shown in figure. The plane of the square loop makes an
angle 45° with respect to the z-axis. If the mutual inductance between
2
the loops is given by ~

2
then the value of p is
2P' R'
11. A laser beam has intensity 2.5 x 1014 - 2

w• If the amplitude of magnetic field in the beam is
m
16k x 1o-2 T. Find the value of k.
12. A thermodynamic system is taken from an initial state I with

internal energy U; = 100 J to the final state f along two different
paths iaf and ibf, as schematically show n in the figure. The w ork p
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done by the system along the paths at, ib and bf are War= 200 J,
W ;b = 50 J and Wbr = 100 J respectively. The heat supplied to the
system along the path iaf, ib and bf are O wa, Q ;b and O bt
respectively. If the internal energy of the system in the state b is V
· Qbf ·
Ub = 200 J and Q ;ar = 500 J, The ratio - Is
Qib
SECTION-C
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the SECOND
DECIMAL PLACE; e.g. XXXXX. XX) .
13. In a sample of radioactive material, the probability that a particular nucleus will decay in next 2
hour is 8 x 10--4_ Find the half-life of the radioactive sample
[Take ln2 = 0.693, ln(0.9992) = - 8 x 10--4]
14. Sunrays pass through a pinhole in the roof of a hut and produce an elliptical spot on the floor. The
minor and major axes of the spot are 6 cm and 12 cm respectively. The angle subtended by the
diameter of the sun at our eye is 0.5°. Calculate the height of the roof.
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15. A spool has the shape shown in figure. Radii of inner and outer cylinders are R and 2 R
respectively. Mass of the spool is 3 m and its moment of inertia about the shown axis is 2mR2.
Light threads are tightly wrapped on both the cylindrical parts. The spool is placed on a rough
surface with two masses m1 = m and m2 = 2m connected to the strings as shown. The string
segment between spool and the pulleys P1 and P2 are horizontal. The centre of mass of the spool
is at its geometrical centre. System is released from rest. What is minimum value of coefficient of
friction between the spool and the_table so that it does not slip?
axis
16. A pendulum has length L = 1.8 m. The bob is released from position shown in the figure. Find the
tension in the string when the bob reaches the lowest position. Mass of the bob is 1 kg.
+---- Bob
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17. A metallic hemisphere is having dust on its surface. The sphere
is rotated about a vertical axis passing through its centre at Oust
angular speed co = 10 rad s-1. Now the dust is visible only on top
20% area of the curved hemispherical surface. Radius of the
hemisphere is R = 0.1 m. Find the coefficient of friction between
the dust particle and the hemisphere [g = 10 ms-2].
18. In the arrangement shown in the figure A is an X
equilateral wedge and the ball B is rolling down the

incline XO. Find the velocity of the wedge (of course,
y
along OY) at the moment velocity of the ball is 10 mis
parallel to the incline XO.
Chemistry PART - 11
SECTION-A
19. Which is/are correct statement?

(A) Packing fraction in 2D-hcp is 0.785
(B) Packing fraction in AAA ..... is 0.52
(C) Packing fraction in ABAB .... is 0.74
(D) Void fraction in ABCABC ..... is 0.26
20. Indicate the correct statement for equal volumes of N2(g) and CO2(g) at 25°C and 1 atm.
(A) The average translational K.E. per molecule is the same for N2 and CO2
(B) The rms speed is same for both N2 and CO2
(C) The density of N2 is less than that of CO2
(D) The total translational K.E. of both N2 and CO2 is the same
21. Select correctly matched.

(A) Cr2o~- ➔ two tetrahedral units are joined by their common corner
(B) S 2o~- ➔ centre of one tetrahedral is the corner of other tetrahedral
(C) S 2F10 ➔ two octahedral joined together
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(D) S 2o~- ➔ two tetrahedral unit joined by their corners
22. Which of the following represent correct similarity between sulphur and chromium?
(A) Both exhibit hexavalency
(B) Sulphate and chromate of Ba 2+ are water insoluble
(C) Trioxide (MO3) both are acidic
(D) Sulphate (Soi-) and chromate (Croi-) have same colouration
23. H2A is a weak diprotic acid. If the pH of 0.1 M H2A solution is 3 and concentration of A 2- is 10-12
at 25°C.
Select correct statement(s)
(A) [H+ltotal ""[H+] from first step of ionization of acid H2A
(B) Concentration of OW in solution is 10-3 M
(C) The value of Ka1 is nearly 10-5
(D) pKa2 -pK1 =9
24. Determine which of the following reactions taking place at constant pressure represents system
that do work on the surrounding environment
I. Ag+(aq)+Cl-(aq) ➔ AgCl(s)
II. NH4 Cl(s) ➔ NH3 (g)+HCl(g)
Ill. 2NH 3 (g) ➔ N2 (g)+3H2 (g)
(A) I
(B) Ill
(C) II and Ill
(D) I and II
SECTION-B
25. If edge fraction unoccupied in ideal anti-fluorite structure is x. Calculate the value of Z. Where
Z=_x_
0.097
26. Consider the following list of reagents:

Acidified K 2 Cr20 7 , alkaline KMn0 4 , CuS04 , H2 0 2 , Cl2 , 0 3 ,FeCl3 ,HN03 and Na2 S2 0 3 . The
total number of reagents that can oxidise aqueous iodide to iodine is:
27. One mole ideal monoatomic gas is heated according to path AB and AC. If temperature of state B
and state C are equal. Calculate qAc x 10.

qAB
------>V
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28. Find number of substance which produce H2 gas when react with cold water.
Ca,CaH2 ,Mg,MgCl2 ,Ba,Ba02 ,NaHC03 ,Ca 3N2 .
29. A molten mixture contain following substance,

Cu, FeO,PbO,CaO,MgO,Ag
Find number of substances which are removed when molten mixture is treated with Si02.
30. X = total number of substitution and elimination product(s). Find the value of X.
3
~CH
V CH30H )?
Br
SECTION-C
DECIMAL PLACE; e.g. XXXXX. XX).
31. The rate of a first order reaction is 0.04 mol L-1 s- 1 at 10 minutes and 0.03 malt's ' at 20 minutes
after initiation. Find the half-life of the reaction
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32. A solution containing 1 M XSQ4(aq) and 1M YSQ4(aq) is electrolysed. If cone. Of x 2+ is 10-2 M

when deposition of yz+ and x 2 + starts simultaneously, calculate the value of Z.
Given:
2.303RT = _
0 06
F
E~2+,x = -0.12V; E~2+,v = -0.24V
33. Given the two concentration of HCN (Ka =10-9 ) are 0.1 M and 0.001 M respectively. What will
be the ratio of degree of dissociation?
34. The degree of hydrolysis of 0.1 M RNH3CI solution is 1.0%. If the concentration of RNH3CI is
made 0.4M, what is the new degree of hydrolysis (in percentage)?
35. Calculate wave number (in cm-1 ) corresponding to shortest wavelength transition in balmer series
of atomic hydrogen.
36. The equilibrium constant for the following reaction in aqueous solution is 0.90.
H3 B0 3 + glycerin ~ (H 3B0 3 - glycerin)
How many moles of glycerin should be added per litre of 0.10 M H3B03 so that 80% of the
H3 B0 3 is converted to the boric-acid-glycerin complex?
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SECTION-A
37. Let (1 + X + x 2 ) n = a o + alx + a 2x 2 ......... + a 2nx 2n, where n is odd integer, if

S1 = a 0 +a 4 +a 8 + ..............
S2 = QI + Q 5 + Q 9 + ..............
s 3 = Q 2 + Q 6 + QIO + ..............
S4 = a 3 + a 7 + a 11 + .......... .... then
(A) SI = S3
(B) S2 =S4
(C) s2 + S4 = o
(D) either S 1 = S2 = S 3 or S 1 = S3 = S4
2
38. Let / 1 (x) = sin - i (cos(sin x)) / 2 (x) = cos - i (sin(cos 2 x))
2 2
(x) = sin - i (cos(cos x)} / 4 (x) = cos - i (sin(sin x)), then choose the correct option(s)
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/
3
4
(A) L f;(x) = 2n - 2
i =l
4
(B) L(-l)'J;(x)=O
i =I
(C) ±(-l)mJ; = 0
i =l
(x) (w here[.] is greater integer function)
39. If the area of a triangle is given l1. and angle C is given and if the value of the side C opposite to
angle C is minimum then
(A) a= ✓ s~nt,,.C
(B) b= ✓s~C
4!1.
(C) a= sinC
4
(D) b= !1.
sinC
40. If the equation xs -1 Oa3 x2 + b4x + cs = 0 has three equal roots, then
(A) 2b2 -10 a 3 b2 +cs = 0
(B) 6as + cs = 0
(C) 2cs -10 a 3 b2 + b4 cs = 0
(D) b4 = 15a4
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41. Which of the follow ing is /are true ?

1 2
(A) Jsin(x 2
+ 2x + 1~x - Jsin x 2dx = 0
0 1
Jesin xdx - I esin(2x+1)dx = 0

1 1
(B)
-1 0
-4 -1
2 2
(C) Jsin(x -3 ~x + Jsin(x + 12x + 33~x = O
-5 -2
4 1
(D) Jcos x 2 dx - f
8 cos 16(2x -1fdx =O
-4 0
42. Let f(x) = sec-1([1+sin2x]) ([.] denotes the greatest integer function). Then set of points, where f(x)
is not continuous is
(A) { nrc , n E 1}
2
(B) { (2n-1)% , n E I}
(C) { (2n + 1) %,n E 1}
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(D) None of these
SECTION-B
43. A pair of tangents is drawn from the point A (23, 3) to the circle whose equation is x2 + y 2 - 2x -
4y + 4 = 0 to touch the circle in B and C. A third tangent intersects the segment AB in P and AC in
Rand touch the circle in Q . If Pis the perim eter of the triangle APR, than IP - 501 = ..... ............ .
44. If z is a complex number and the minimum value of lzl + I z - 11 + 12z -31 is 'A. and if y = 2 [x] + 3 =
3 [x - 'A.], then find the value of [ x + y] (where[.] denotes the greatest integer function}
10
45. John has x childre n by his first w ife. Mary has x + 1 children by her first husband. They marry and
have children their own. In the whole family there are 24 children, Assuming that two children of
the same parents do no fight. If the maximum no. of fights that can take place is 'A. then 382/'A. is.
46.
47. If equation 4x4 - ax3 + bx2 - ex+ 6 = 0 has four distinct real roots say x1 < x2 <x3 < X4 such that
1 2 3 4 X
- +- + - +- =8 a, b, c E R+ then _..i. is equal to
X1 X2 X3 X4 ' X1
48. If a, 13 are the roots of the equation x2 - 2x + 3 = 0, then find the constant term of the equation
w hose roots are a 3 - 3a 2 + 5a - 2 & 133 - 132 + 13 + 5.
SECTION-C
49. 10 IIT & 2 PET students sit in a row. The total number of ways in which exactly 3 IIT students sit
between 2 PET students is K then ~ is
1000
50. The number of integral solution of this equation x + y + z + w < 25 such that x > - 2, y > 1, z ~ 0,
w> 3 is
51. The value of Y1-Y2·Y3 when

(Y1 - X1 )(Y2 - xi)(y3 - X3)
(x;, Y; ), i =1, 2, 3 satisfy both x 3 -3xy 2 = 2005 & y 3 - 3x2 y = 2004 is
1 1.3 1.3.5 . z 2 + 2z + 100.

52. If z = - + - + - - + ........oo then fmd value of - - - - - 1s equal to
3 3.6 3.6.9 10
53. Let f(x) is a quadratic expression with positive integral coefficients such that for every. a f3 E R,
f3 > a.
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~
f f(x)dx > 0 Let g(t) = f'(t) . f(t) and g(0) = 12. If no of quadratics are ab where a and b are
a
a+b . . ..
natural number than - - 1s equal to. (ab 1s 2 d1g1t number)
2
54. Find the integral value of a , for which the quadratic expression ax2 + (a - 2) x - 2 is negative for
exactly two integral values of x.
Fl ITJEE
FULL TEST- II
PAPER-2
ANSWERS, HIN"FS & SOLUTIONS
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Physics PART-I
SECTION-A
1. B, C, D
Sol. If F is conservative, then
F =_ BU F =_ BU
• Bx 'Y oy
BF, il U if U 8Fy
Andso-=-- = - - = -
oy oyox oxoy ox
2 2
W = JF=.ds = (x y2i + x y2J).(dxi + dyJ)
f
= x2 y2dx + x2y2dy f
as
f
a
Woc = a2y2dy = 3
0
as
Thus, WAsc = WAB + Woc = (J)
3
2as
WAc = 2J x dx =-(J)
a
0
4
2. A, D
Sol. Kinetic energy of the sphere
K=__!_lai
2
AITS-FT-11 (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 2
= -1 x -MR
2 2{21tn}2
2 5
= i1t2n2MR2
5
Kinetic energy used to raise, the temperature
= o.s(~ n2n2MR2)
= ~1t2n2mR2
5
~T = 21t2n2R2
SC
3. A, C
Sol. .----r-- Earth
R
4VI
OV Earth 4V
V = 7V- i = 7 - O = _!__
p ' 3R 3R
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4.
Sol.
. .. (1)
. .. (2)
K
From Equation (1) and (2)
di1R = di2 R
dt 3 dt 4
or di1 = R4 di2 and i1= i2 = R4
dt R3 dt R3
( L1: : - L2) ~i; = i2[ R2 - R~:

4
l .... (3)
At t = 0, i2 =0
L1 R3 ... (4)
3 AITS-FT-11 (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021
5. A, C
Sol. <1>1 : <1> 2 : q> 3 = eVo-, : eVo-i. : eVO:J
V
Metal I Metal 2 Metal 3
..._.....,.___.....,_ _.....,.___ 1/A. (nm- I )
= V = Vo-, : V02 : V03 = 0.001: 0.002: 0.004 = 1: 2: 4

Therefore (a) is correct
⇒ V = he
_ __ . .. (1)
eA e
he
m =-=tan8
e
1 1
- = 0.001nm-1 ⇒ Ao-, =--=1000mn
Ao-, 0.001
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1
Also, - = 0.002 nm-1 ⇒ A02 = 500mn and A02 = 250nm
A,02
6. B, D
. . dx
Sol. Current flowing per unit length = cr- = crv
dt
A,
By Ampere's law
µ crv
B.e + B.e = µ 0 crv.e ⇒ B = -0-
2
SECTION-B
7. 6
R
Sol. l=f(dm)r 2
0
R
f 2
I = p x 4nr dr x r
2
0
R
f 2
I = p x 4nr dr x r
0
2
8. 1
Sol.
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F = -(f1 - f2 )
= -(µN1 - µN2)
= -µ(N1 -N2)
N1+N2=mg ... (1)
mg(e/ 2- x)-N/ = 0 ...(2)
mg
N2 = T (R12 - X)
=~g [ i + x]
F= µl
~g ( 1 X) - 1- X) j
+ ~g (
mg
= - µ~(2x)
R
{u
= 1\J µg = 10 sec
9. 7
mv 2
Sol. (TA + F. ) - mg = ~ ... (i)
mv 2
(TA + F. ) - mg = ~
2
mv 8
mg-F = - - . .. (ii)
• R
1 q2
F. - 4n E
0
£2
1 1
-mv! = -mv! + mg(2£) ... (iii)
2 2
VA = 7 m/s
10. 7
B= ~
2
Sol. 21tiR = µ 0i
4n (R 2 + 3R2 ) 312 16R
M = N<j>
i
= I[ µ oi X a2 cos45°]
i 16R
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11.
Sol.
9
The intensity is given by
I=_!_ E 0 E2 C
2
or 2.5 x 1014 = -1 x (8 .86 x 10-12 ) x E~ x (3 x 108 )
2
Eo = 4.3 x 108 V/m
and B0 = Ea = 1.44T
C
12. 2
Sol. Applying first law of thermodynamics to path iaf
O iaf = L).LJiaf + W iaf
500 = L).LJiaf + 200
L).LJiaf = 300 J
Now,
O iaf = L).U ibf + W ib + W bt
= 300 + 50 + 100
O ib + 0bf = 450 J . .. (1)
Also, O ib = L).;b + W ;b
O ib = 100 + 50 = 150 J ... (2)
Q 300
From (1 ) & (2) _____!!_ = - = 2
Q I> 150
SECTION-C
13. 01732.50
Sol. Probability that a particular nucleus w ill decay in next 2 hr is
N0 -N
- - = 8 x 10-4 [N = surviving population after 2 hr]
Na
Na[1 - 8 x 10-4] = N
⇒ 1- 8 X 10-4 = e-J..t
⇒ e-J..l = 0.9992 ⇒ -At= Rn(0.9992)

.en2
- ~ x 2 = .en(0.9992) [·: t = 2hr]
t 1, 2
t
112
= 2£n2 hr
Rn(0 .9992)
2 0 693
= x · = 1732.5 hr
8 x 10-4
14. 00003.44
Sol. The cone of rays passing through the hole at a produce an elliptical spot on the floor.
The circular base having diameter BO w ill get projected on the floor as an ellipse.
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/ \jSun
9 --
CB = major axis = 12 cm
DB= Minor axis= 6 cm
DB:::: AB(0) = ~⇒h= (6cm) sin 

Sln q> q>
. DB 6 1
But sIn <1> = - = - =-
CB 12 2
h = (6 cm )
2x0
=----
3cm x 180
0 .5 X TC
[o .5 0 =0.5
---
180
TC ad"Ian ]
Xr
= 344 cm
= 3.44 m
15. 00000.11
Sol. Let acceleration of COM of the spool be ao towards right, and acceleration of m2 be a2 dow nward
a~d_that of m1 be a1 upward
T, ~ T.
T, a
a,
r m
1
a,
2m
2mg
mg
f = friction , a = acceleration of the spool

2Ra = a0 ... (1)
Ra + a0 =a 2 ... (2)
2Ra + a0 = a1 . . . (3)
T1 -mg=ma 1
2mg- T2 = 2ma2
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2mg- T2 = 2m[a2 +Ra]= 3maa ... (5)
T2 + f - T1 = 3m a0 . .. (6)
T2R - T1 2R -f2R = la
T2 - 2T, - 2f = 2mRa [·: I = 2mR2 ]
T 2 -2T, - 2f = ma 0 ... (7)
Solving, (4), (5), (6) & (7) we get f = - mg

3
·: f ~ µN :. ~g ~ µ3mg :. i- ~ µ
16. 00035.00
Sol. The bob w ill experience free fall for a distance of L = 1.8 m.
Speed of the bob just before the string gets taut is
u=-J2gL = ✓2x10 x 1.8 =6 m/s
L
L cos60"=
2
~ u,
u,
u
V
·--------
_,...
uI = u cos 30° = ✓3u = 3✓3 mi s

2
1 V2 1 2 L
2m = 2mu1 + mg2
V =3✓ 5 m/s
45
T = 10 + = 35N
1.8
17. 00002.45
Sol.
s = nR2 = 2nR2 (1-cos0)

Ifs = (0.2) (2nR2 ) then
0.2 = 1 - cos 0
⇒ COS0=0.8 ⇒ 0=37°
www.jeeneetbooks.in mg
N =mgcos0 - molrsin0
µ(mgcos0-molrsin0) = mgsin0 + molrcos0
. µgsine + olrcose
· · gcose - olr sin 0
2
= 10 x 0.6 + 10 x 0.06 x 0.8 = 0.6 + 0.48 =
2 45
10 x 0.8-10 2 x 0.06 x 0.6 0.8-0.36 ·
18. 00005.77
Sol. Wall AB of the wedge is vertical. For ball to B
remain in contact with the wedge the velocity

component of the ball perpendicular to the
wall AB must be equal to velocity component
of the wedge in horizontal direction (i.e.,
perpendicular to wall AB)
.-.10cos60° = Vcos30°
5 = V ✓3
2
10
V =✓3 m/s
Chemistry PART- II
SECTION-A
19. A, B, C, D
Sol. (A) 2-D-hexagonal packing
nR2
nR2 + 6 x -
Packing efficiency - ✓3 ~
6 x 3 (2R)
4
3
1x i nR
(B) simple cubic = - ~3~ -
a3
a =2R
20. A, C, D
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Sol. 3
KE= -RT(1 mole)Urms = ✓3RT
--
2 Mw
d= PMw
RT
21. A , B, C, D
Sol. (A) 0 0
Cr
II
11
Cr
~ I""-o/ 11 "'-o-
o O 0
(C) F FF F (D)
"" I ""- /
F---s---s---F
F
I \F FI \ F
22. A, B, C
Sol. Factual
23. A, C
x2
Sol. ·: y is very less so x + y R, x :. Ka1 = - -
x- y- x C-X
12
at equilibrium C-X x+y x-y K a = y = 10- -pK a = 12 I
2 2
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HA-1 ~ W + A 2 -
at equilibrium x-y x+y y
pKa2 -pKa, =12-5=7
1
pH= -[PKa -loge]
2 1
1
3 = -[PKa
2 , + 1] pKa, = 5
24. C
Sol. As tiV is positive w is negative
W =-Pt...V
So work is done on the system.
SECTION-B
25. 3
So I. . of e dge unoccupIe
F ractI0n . d =- 2R
a- -
a
a =2✓
2.R
14
X = 0.4 = 0.293
1.414
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Z=_X_ = 0.293 = 3
0.097 0.097
26. 00007.00
Sol. alk. KMnO4 & Na2 S2 O 3 w ill not
React with kl to give '2
27. 8
Sol. Process AC = polytropic process (P = KV)
Molar Heat capacity Cm = cv + R / 2 = 2R
Process AB = Isobaric
cm= cp = 5R / 2
qAC = x 1Q = 0.8 X 10 = 8
qAB
28. 3
Sol. Ca, CaH2 and produce H2 gas with cold w ater.
29. 4
Sol. MO + SiO2 ➔ MSiO3
(Metal oxide basic) (Acedic) (slag)
30. 4
Sol.
Br
SECTION-C
31. 00024.06
k = 2.303 0.04
Sol. 109
10 0.03
t _ 0.693
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112 --K-
32. -0.24
0 0 91
Sol. -0.12- · ; 1og(~) =-0.24
log_!_= 0.12x2 = 4
X 0.06
X = 10--4
33. 00000.10
Sol. a = fc
{Kaea
34. 00000.50
Sol. ~= ~ ⇒ 0.01 = ✓0.4
a2 ~c"; a 2 0.1
a 2 = 0.005 or % a 2 = 0.5
35. 27419.25
Sol. -V = R x [ 1 1]
--;!
22
36. 00004.52
K = [complex]
Sol.
c [H3 803 ][glycerine]
SECTION-A
37. A, D
Sol. (1 + x + x 2 ) " = a 0 + a 1x + a 2 x 2 + ... + a 2 nx 2n ... (1)
3n + 1
⇒ ao +a2 +a4···=--
2
3n -1
a1 +a3 +as···=--
2
Put x = i in equation (1) where i = H
If n =4m+l
⇒ a 1 - a 3 + a 5 ... = I
a0 - a 2 + a 4 •.• = 0
3n + 1
So, a 1 +a 5 +a 9 ... = - - = S2
4
3n -3
a 3 +a1 +au···=---=S4
4
Similarly if n = 4m + 3
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38.
Then,
A, B,e, D
7t 2
Sol. J;_ (x) = ; - sin 2 x, / 2 (x) =- - COS X
2
7t 2 7t . 2
/ 3 (x)=--cos x, /. (x ) =-
2
- sm x
2
4
39. A, B
Sol. c2 = a2 + b2 - 2ab case
= (a - b)2 + 2ab(1 - case)
1 .
11 = -absme
2
411
or2ab = - -
sine
1
here c 2 = (a - b)2 + 411 ( -~ose)
sine
=(a-b) +4!1tan-
2 e
2
4/1tan e is constant so for c2 to be minimum a = b thus 2ab = 2a2 = ~

2 ~ne
⇒ a=b= ✓ sine
211
.
40. B, D
Sol. f(x) = x 5 - 10a3 x2 + b 4 x + c 5
f'(x) = 5x4 - 20a3 x + b4
f" (x) = 20 x 3 - 20a3
If x = a be a root that is repeated three times,
⇒ f"(a) = 0, f'(a ) = 0, f(a) = 0
⇒ a = a, 5a4 - 20 a 4 + b4 = 0, a5 - 10a 5 +ab4 +c5 = 0
⇒ a =a, b4 = 15a4 , c5 +ab4 - 9a5 = 0 ⇒ c5 +15a5 - 9a5 ⇒ 6a5 + c5 = 0.
41. A, D
b 1
Sol. Since Jf(x}:lx = (b-a)J f {(b-a)x + a}dx ,
a 0
2 1 1
f sin x dx f sin(x
2
= + 1f dx = Jsin(x2 + 2x + 1~x
1 0 0
4 1
fcosx 2
dx f
= 8 cos(8x-4f dx
-4 0
0
f
= 8 cos 16(2x -1f dx .
1
42. B, C
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Sol. f(x) = 0
*
If sin x ± 1 (1 s 1 + sin2x < 2, sin2 = 2)
= n/3 If sin x = ± 1
So f(x) is not continuous at the points, w here sin x = ± 1 i.e. x is an odd multiple of n/2
SECTION-B
43. 6
Sol. AB= 22 = AC
Now AP+ PR+ AR= (AP + PQ) + (QR+ AR)
=AB+ AC= 44.
44. 3
Sol. lzl + lz - 11 + I2z - 31 = I z I + I z - 11 + 13 - 2zl ;::,: lz + z - 1 + 3 - 2zl = 2
lzl + lz - 11 + I2z - 31 ;::,: 2
A, = 2
then 2[x] + 3 = 3[x - 11,]
= 3[x - 2]
⇒ 2[x] + 3 = 3 ([x] - 2)
or [x] = 9, then y = 2.9 + 3 = 21
[x + y] = [x + 21] = [x] + 21 = 9 + 21 = 30
45. 2
Sol. No of fights=
·
24 C
2
- xc2 - x+1c 2 _ 23- 2x C 2
f(x) = -3x2 + 45x + 23.
15
f( x )=O ⇒ X =-=7 .5
2
but x can't be a fraction.
Sox= 7 (nearest integer)
: . f(x) = 191 Ans.
46. 2
Sol. k =1
k=2
:. Reg. Sum= ¾+(¾

J+(¾J +....... oo
2
__
3_-2
- 1-~ -
3
47. 4
Sol. equation has four positive real root.
⇒
-+-+-+-
1 2
X1
3 4
X2 X3 X4 >( 24 )
1/4
=2
4 - X1 ,X2 , X3 , X4 .
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1 2 2 4
⇒ -+-=-=-=k
X1 X2 X3 X4
1
⇒ k =2 :. roots are , 1, 3 and 2
2 2
⇒ X4 =4
X1
48. 2
Sol. Since a2 - 2a + 3 = 0 & p2 - 2p + 3 = 0
a3 - 3a2 + 5a - 2 = a3 - 2a2 + 3u - a2 + 2a - 3 + 1
= a(a2 - 2a + 3)- (a2 - 2a + 3) + 1 = 1
And p3 - p2+p+5 =p3- 2p2 + 3p + p2 - 2p + 5 = p (p2 - 2p + 3) + (p2 - 2p + 3) + 2 = 2
So the ref. equation is
X2 - (2 + 1) X + 2.1 = 0
x2- 3x + 2 = 0
SECTION-C
49. 58060.80
Sol. 10 IIT students T 1, T 2,····· T 10 can be arranged in 10 ! ways. Now the number of ways in which
two PET student can be placed will be equal to the number of ways in which 3 consecutive IIT
students can be taken i.e. in 8 ways and can be arranged in two ways I=> (10 !) (8) (2 !).
Alternatively 3 IIT students can be selected in 10c 3 ways. Now each selection of 3 IIT and 2 PET
students in P1 T 1 T 2 T 3 P2 can be arranged in (2 !) (3 !) ways. Call this box X. Now this X and
the remaining IIT students can be arranged in 8 ! ways
⇒ Total ways 10c3 (2 !) (3 !) (8 !) ]
50. 08855.00
Sol. X + y + Z + W < 25
let x + y + z + w + a = 25 such that a > 0 ........ (i)
X = - 1 + t1 t1 ;:,: 0
y = 2 + t2 t2 ;:,: 0
z = t3 t3 ;:,: 0
w=4+t4 t4 ;:,: 0
a= 1 + t5
put in equation (i)
(-1 +t1)+(2+t2)+t3+(4+t4)+(1 +t5)=25
t1 + t2 + t3 + t4 + t5 = 19
by fictitious partition solution 19 5 1
+ - c19 = 23c 19
51. 01002.00
Sol. 3
x -3xy = 2005
2
⇒ [(~ J -3 ( ~ ) =
2
~?5 ]x 2004
y
3
-
2
3X Y = 2004 ⇒ [ 1- 3 ( ~ J =
2
~?4] X 2004 .... (2)
X
Subtract (1) & (2) & put - = t
y
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~t1
2004t 3 + 6015t 2 -6012t - 2005 = 0 --+ t2
......... h
Vi·Y2·Y2 _ 1
(Y1 - x1)(y2 - X2)(y3 - Y3 ) - (1-t, )(1 -t2)(1- t3)
1
=-------------
1 + (t,t2+ t/3+ ti,) - ( t, + t2+ t3) - t,t/3
put values
= 1002
52.
Sol.
⇒ (J )
2
- = J+ (;/~ + (~~3·~ + ..........oo
✓3 -1 = z ⇒ z2 + 2z - 2 = 0
- 2 ± ✓4 + 8
Z= - ---
2
z = - 2 ± ✓3, but z -:t:- -1- ✓3
53. 00003.50
~
Sol. Let f(x) = ax2 + bx + c,

·: ff(x)dx > 0 ~a. 13 ER
a,b,cEJ• f(x) > 0 ⇒ D < 0
⇒ g(t) = 2a(at
2
f"(x) = 2a + bt + c) = 2a 2 t2 + 2abt + 2ac.
g(0) = 2ac = 12 ⇒ ac = 6.
a =6, C= 1
a= 1 C=6
⇒ b < 24;
2
b = 1, 2, 3, 4
a=3 C=2
a=2 C=3
:. 16 quadratic are possible
54. 00001.00
Sol. Let f(x) = ax2 + (a - 2) x - 2
f(0) = -2
and f(-1) = 0
Since the quadratic expression is negative for exactly two integral values
⇒ f(1) < 0 and f(2) ~ 0
⇒ a+a- 2- 2< 0 and 4a + 2a - 4 - 2 ~ 0
⇒ a<2 and
aE[1,2)
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FIITJEE
FULL TEST- I
JEE (Advanced)-2021
PAPER-1
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• Each Part is further divided into Two Sections: Section-A & Section-C.
Section-A {01 - 06, 19 - 24, 37- 42) contains 18 multiple choice questions which have ONLY
wrong answer.
Section-A {07 -12, 25 - 30, 43 - 48} this section contains 18 multiple choice questions.
correct answer(s).
a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : - 2 In all other cases.
Section-C (13 - 18, 31- 36, 49 - 54) contains 18 Numerical answer type questions with answer
XXXXX.XX and each question carries +4 marks for correct answer and -0 marks for wrong
answer.
fllTJH Ltd., FnTJEE Ho=-, 29-A, Kalu Sarai, San,apriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
websit.: www.fiitj,Hl.com
AITS-FT-I (Paper-1 )-PCM-JEE(Advanced)/2021 2
Physics PART - 1
SECTION-A
1. Consider a situation in which a uniform gravitation field is present

below line AB and no gravity above line AB . Then the speed with
which a rod shown in the figure will strikes earth surface when
released from the position shown is: m ,£
(A) .[ii,
(B) 2.jii, 5£
(C) 3.jii, _ea_r_th_s_u_rf_a_ce_ ____,_i_ _
(D) 4.jii,
2. In hydrogen atom spectrum, when an electron de-excites from higher energy level n >> 1 to
lower energy level then first few frequencies of light that is emitted (e. g. n = n to n-1, n to
n - 2 , n to n - 3 etc.) are very nearly:
(A) in AP (Arithmetic progression)
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(B) in GP (Geometric progression)
(C) in HP (Harmonic progression)
(D) in I2 : 22 : 32 ratio
3. Two identical small blocks each of mass 1kg are given

velocity 4 mis towards each other. All collision are
elastic and surface between 1m to 2m is rough 0
tJ j 777777777
lm
j
2m 3m
(µ = 0.7) and rest part is smooth. Then:
(A) Speed of each block after first collision is ✓ 2 mIs

(B) Speed of each block after first collision is 4 m I s
(C) Separation between blocks when they stop is 2 / 7 m
(D) Separation between blocks when they stop is 5 / 7 m
4. A photon of wavelength A is incident on a photoelectric plate and the most energetic electron
from photoelectric plate is incident on a target metal of X-ray tube. If the minimum wavelength of
photon emitted from target material is 2l then work function of photoelectric plate is:
he
(A)
A,
he
(B)
211,
he
(C)
411,
he
(D)
811,
3 AITS-FT-I (Paper-1)-PCM-JEE(Advanced)/2021
5. In a polytropic ( pyx =constant) when the volume of a mono-atomic gas was increased four
times, simultaneously pressure decreases 8 times:
(A) Molar specific capacity of gas is 2R
(B) Molar specific heat capacity of gas if R
R
(C) Molar specific heat capacity of gas is - -
2
5R
(D) Molar specific heat capacity of gas is -
2
6. A moving ball collides a pendulum bob as shown, the coefficient 0

of restitution so that bob performs vertical circular motion about 0
is (g = 10 m/s2) 1
f =-m
(A) 1 2
1kg lOm/s
1 • 2kg
(B)
4
1
(C)
8
1
(D)
2
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7. Six charges of equal magnitude but opposite sign are fixed on +q R

an insulating ring at equal separation. P is a general point on
the axis of ring at large distance from the centre of ring. PR is a -q -q I
1
path perpendicular to the axis of the ring and R is at infinite
separation from P.
.--- I
------------------------,1
p
+q +q
-q
(A) Amount of work done to bring a charge from R to P via RP is zero.
(B) Net dipole moment is zero and electric field is conservative field.
(C) Amount of work done to bring a charge from R to P via RP is zero because net dipole
moment is zero and electric field is conservative field.
(D) Amount of work done to bring a charge from R to P via RP is zero not because of net
dipole moment is zero and electric field is conservative field.
8. A radioactive point source has a decay constant 2 . When this source moves towards small area
counter kept at large distance from source, then counter records counUsecond which turns out to
be constant:
(A) When separation between source and counter becomes half of initial value, number of
3
nuclei left undecayed will be - th of initial value
4
(B) When separation between source and counter becomes half of initial value, number of
1
4
(C) Graph showing variation of separation between source and counter with time is as shown
r (separation)
(D)
L,(time)
Graph showing variation of separation between source and counter with time is as shown
r (separation)
9.
I~ ~t(time)
A diatomic gas is kept in a closed container of constant volume. Due to increase in temperature
some molecules dissociates into atoms. Neglecting vibrational degrees of freedom:
(A) Specific heat capacity of mixture will increase.
(B) Specific heat capacity of mixture will decrease.
(C) Specific heat capacity of mixture can change by a maximum value of 8%
(D) Specific heat capacity of mixture can change by a maximum value of 20%
10. A lens of focal length f=40cm is cut along the diameter
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into two equal halves. In this process, a layer of f =40cm
thickness t = Imm is lost, then halves are put together Screen
to form a composite lens. In between focal plane and
the composite lens a narrow slit is placed very close to ---------+---t---------t 0
s
lul Ill .
the focal plane < The slit is emitting
lul <IJI
monochromatic light of wavelength 0.6 µm. Behind the 0.5m
lens a screen is located at a distance L = 0.5m from it
as shown:
(A) Fringe width is 0.12mm
(B) Fringe width is 0.24mm.
(C) Length of interference pattern is l / 8 cm
(D) Length of interference pattern is 1116cm
11. In an interference experiment as shown in the figure, the source Screen

B•
plane and screen are separated by a distance 1m. At a certain !
position of source, fringe width is 114mm and by moving the source
away from mirror along the line AB by 0.6mm , the fringe width
st :
A 1----- mflllllll//ll ____ __
changed to 116mm:
!
Wavelength of light used is 5000A :
(A)
(B)
(C)
Wavelength of light used is 6000A
Initial distance of source from A is 1.2mm
---------
!
lm
(D) Initial distance of source from A is 0.6mm
12. A particle of mass 6.6 x 10- kg starts

30
(t = 0) moving on a straight line w ith velocity 10mls . Its
velocity decreases with time, however rate of change of de-Broglie wavelength associated with
particle remains constant atl0-4 mis . (take h = 6.6x 10-34 J-s ):
(A) Velocity of particle at t = 0.9 s is lm I s
(B) Velocity of particle at t = 0.9 s is 6 mls
(C) Magnitude of retardation of particle at t==0.9s is 4mls2
(D) Magnitude of retardation of particle at t = 0.9 s is 1mis
SECTION-C
question, enter the correct numerical value (in decimal notation , truncated/rounded-off to the second
13. A particle of mass 0.1 kg moving horizontally w ith velocity 20 m/s

strikes a stationary sedge of mass 0.05 kg near the apex of the w edge
and comes to rest immediately after the collision . The wedge is free to
move on the smooth floor. Second collision of particle w ith wedge
lOK
-
m A
occurs at B. If the length AB of wedge is ✓5 meter, then find K . SI
( 2) . Neglect the toppling of wedge.
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Take 0=coc'
14. Graph show s variation of internal energy U w ith density p of one U(joule)
mole of an ideal monoatomic gas. Process AB is a part of rectangular
hyperbola. Find work done in the process (in Joules) 23 ····-·· B
--+-------p
15. A radioactive nucleus X decays into a nucleus Y w hich itself is radioactive. Y decays into a stable
nucleus Z.
X Half Life ) y Half Life ) Z
=I2 hour =I8 hour
Initially the sample has only nuclei X & number count of Y is zero. Find time (in minutes) w hen
number of count for Y is maximum.
16. Half ring of mass m and radius R is released from the position shown in diagram.
A small point mass of same mass is also fixed at the end as shown in figure. If
the initial acceleration of point mass m is _Jr_ then find the value of /J.
JJ,c
fllTJH Ltd., FnTJEE Ho=-, 29-A, Kalu Sarai, S arvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513 942
17. In YDSE, if sources are incoherent, the intensity on screen is 1310 . When these sources are
coherent then minimum intensity on screen is 10 . If maximum intensity produced by these
coherent sources on screen is nl0 , then find n .
18. A vessel of volume V 0 is evacuated by means of a piston air pump. One piston stroke captures
the volume~V = 0.2 V 0 . If process is assumed to be isothermal then find the minimum number
1
of strokes after which pressure in the vessel becomes ( - -
1.728
) (P. 1. 1 ) .
llllla
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Chemistry PART- II
SECTION-A
19. The following two compound are:
(A) Identical isomers

0 (II)
~
(B) conformational isomers

(C) geometrical isomers
(D) Optical isomers
20. If mercuric iodide is added to an aqueous solution of KI , the:

(A) freezing point increased
(B) freezing point is lowered
(C) boiling point does not change
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(D) Osmotic pressure increased
21. Which of the following is weaker base?

(A) N(SiH3 ) 3
(B) N(CHJ 3
(C) NH(CH3 \
(D) All are equally basic
22. Which of the following ions is expected to be colourless?

(A) Ni 2+
(B) Mn+2
(C) Zn2+
(D) Cu 2+
23. A definite mass of a monoatomic ideal gas at 1 bar and 27°C expands isothermally against
vacuum from 1.2 dm3 to 2.4 dm3 . The change in free energy of the gas, /'),_G, is (R = 0.80 bar -
UK-mol, In 2 = 0.7)
(A) 0
(B) -64 bar-1
(C) +84J
(D) -84J
24. In the system,LaCl3 (s)+H 2 0(g)+heat~LaClO(s)+2HCl(g) , equilibrium is

established. More water vapour is added to disturb the equilibrium. If the pressure of water
vapour at new equilibrium is double of that at initial equilibrium, the factor by which pressure of
HCl is changed is:
(A) 2 times
(B) ✓2 times
1 .
(C) ✓2 times
(D) 4 times

25. Which of the following statemenUstatements is/are correct?

(A) in the NaCl structures, each Na+ ion is surrounded by 6Cr ions as nearest
neighbours and twelve Na+ ions as next nearest neighbours.
(B) the co-ordination number of cation generally increases as the radius ratio increases
(C) packing efficiencies higher than 0.74 are possible only with cation and anion of different
sizes
(D) during a crystal defect electrical neutrality should be maintained.
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26. An optically active alcohol A ( C8 H 16 0) on oxidation gives B. A on acidic heating gives
C ( C 8H 14
) as major product. C on ozonolysis produces D ( C5 H 8 0) and
H3C-rr-CH3 . Don reduction with LiAIH, gave 0--oH ·

0
Identify correct answer:
3 (B) CH 3
(A) o+CH
A is CH2 0H Bis 0-+cooH
H H
(C)
Cis v=< (D)
Dis (>=o
27. Which of the following order for basic strength is/are correct?
0 () 0 UNH,>&NH
(A) (B) 0
> > 2
N N
H H
COH >00 Q 0
(C) (D)
N0NH
> >
N
\d
N
H H
H
28. When 5 ml of a 1.0 M Hel solution is mixed with 5 ml of a O.IM NaOH solution ,
temperature of solution increases by t 0 e. Which of the following(s) can be predicted from this
observation:
(A) If 5 mL of O.IM Hel is mixed with 5 ml 0.1 M NH3 solution, the temperature rise will
be less than t
0
e
(B) If 5 ml 0.1 M eH3 eOOH is mixed with 5 ml 0.1 M NaOH, the temperature rise will
be less than t
0
e
(C) If 10 ml of 1.0 M HCI is mixed with 10 ml of 0.1 M NaOH, the temperature rise will
be 2t
0
e.
(D) If 10 ml of 0.1 M HCI is mixed with 10 ml of 0.1 M NaCl, the temperature rise will
be t
0
e
29. Which of the following is/are can produce H2O2 on hydrolysis?
(A) Ba02
(B) Pb02
(C) Mn02
(D) Na2 0 2
30. The correct statemenUstatements is/are:

(A) The distance between two octahedral voids of a cubic close packing of atoms with radius
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r is 2r
(B) The distance between two tetrahedral voids of a cubic close packing of atoms with radius
r is ✓6xr at the body diagonal axes
(C)J{- The distance between tetrahedral and octahedral void is x r , where is the radius of
atom forming the close packing
(D) The distance between the surfaces of atoms fee arrangement along an edge is
2( ✓2-l)r
SECTION-C
31. One mole of nitrogen gas at 0.8 atm takes 38 seconds on diffuse through a pinhole, whereas one
mole of a compound of xenon with fluorine at 1.6 atm takes 57 seconds to diffuse through the
same hole. Calculate molecular weight of the compound.
32. Calculate ~1 H 0 (magnitude only) for chloride ion (aq.) from the following data: (in kJ)
1 1
-Hz (g)+-e/2 (g) ➔ Hel(g); ~ f H 0 =-92.4kl
2 2
HC!(g )+H2 0(e) ➔ H 30 + ( aq)+ CZ- ( aq ); ~ 0 =-74.8kl
~ 1H 0
of H+ ( aq) = O.Okl
5
33. K sp of PbBr2 (Molar mass= 367 ) is 3 .2 x 10- • If the salt is 80% dissociated in solution , calculate
the solubility of salt in gram per litre. (in litre-1 )
34. At 20°c , the vapour pressure of 0.1 molal aqueous solution of urea is 0.03 mm less than that of
water and the vapour pressure of 0.1 molal solution if KCl is 0.0594 mm less than that of water.
The apparent percentage dissociation of KCl in water at the given temperature is (Neglect the
moles of solute particles in comparison to the moles of water in both solutions).
35. If x and y are total number of electrons which are present in non-axial and axial set of d-orbitals
2x 2
respectively in Ni cation of [ Ni (DMG )i] ,then calculate value of y.
36. Total energy of an atom when electron is in the 1st orbit of hydrogen atom is -13.6eV/atom.
Kinetic energy of electron in the 1st excited state of Li2 + ion in eV is:
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SECTION-A
37. Conditions so that equation (a1x 2 + b1x + c1 )(a 2 x2 + b2 x + c 2 ) = 0, (a1a2>0) have fours real roots if
(i) c1c2>0 (ii) a1c2<0 (iii) a2c1<0
(A) only (i) is sufficient
(B) either of two statements are sufficient
(C) either of two statements are necessary and sufficient
(D) all the three statements are sufficient
38. In a ~ ABC, the incircle touches the sides BC, CA and AB at D, E, F respectively. If radius of
incircle is 4 units and BO , CE and AF are in A.P. with common difference 1, then area of MBC is
(A) 84 sq. units
(B) 42 sq. units
(C) 168 sq. units
(D) data insufficient
39. Let A be the area between co-ordinate axis, y 2=x-1 , x2=y-1 and the line which makes the
shortest distance between two parabolas and A' be the area between x=0, x2=y-1 , x=y and the
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shortest distance between y2=x-1 and x2=y-1 , then
(A) A=A'
(B) A= (A' )½
(C) A= 2A'
(D) can't say anything
40. a,b,c are in G.P. and the equation (a+di)x2+2(b+ei)x+(c+if)=0 have one real root then ~.!>..~ are
d e f
in, (a,b,c,d,e ,f ER)
(A) AP
(B) GP
(C) HP
(D) none of these
41. fsecP' 3
x cos ecq' 3 xdx = (p, q E 1+ and p+q=12)
- p +1
tan 3 x
(A) ---+ c
- p +1
3
- p +1 - p +3
tan 3 x tan 3 x
(B) - - - + c+---+c
- p+3
tan 3 x
(C) ---+c
-p + 3
3
(D) none of these
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42. A square ABCD of a diagonal 2a is folded along the diagonal AC, so that the planes DAC, BAC
are at right angle. The shortest distance between DC and AB is
(A) #a
2a
(B)
✓3
(C) fl
(D) none of these

43. [ ( ex3 +e-x3 )dx is less than

(A) 2
2
(B) 2e+-
e
1
(C) e+-+2
e
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(D) 2e
trX
I 2
44. J Let f(x)=e-x +

2
✓l+sintdt\fxE(0,oo)then-
o
(A) f exists and is continuous \ix E (0, oo)
(B) f' exists \ix E (0,oo)
(C) f is bounded
(D) There exists a> 0 such thatif(x)I > If' (x)!Vx E (a ,oo)
45. Let x, y, z are positive real numbers and f I is the least value of 2x4 + 2 y 4 + 4z4 - 8.xyz and
4 4 4 1
f 2 is the least value of x y + xy +--2 3 + 3 2 + 8 , then-
x y X y
(A) f1 =-1
(B) £2 >-1
(C) £2 = 10
(D) £2 > 10
4 3 2
46. Consider the equation in x , 8x -16x + 16x -8x + a = 0 , then sum of all the non-real roots of
equation can be ( a E R)
(A) 1
(B) 2
1
(C)
2
(D) None of these
. 40 160 200 320 2

47. For the e q u a t i o n - - - - - - - - + - - = 6x -27x
x-1 x-4 x-5 x-8
(A) Number of real solution of above equation is 3
(B) If E denotes the product of non-zero or complex roots of equation, then sum of divisors of
Eis 2904
(C) It S denotes the set of all real roots of equation then, sum of elements of S taken two at a
time is 81
(D) If a 1 , a 2 ER be two roots of equation such that loga2 ( 2 a 1 ) is defined it must be 1.
48. Let a, b, c be the positive integers such that a<b<c. If the two curves
y =Ix-al+ Ix -bl+ Ix -cl and 2x + y = 2003 have exactly one point in common, then-
(A) least possible value of c is 1002
(B) greatest possible value of b is 1001
(C) least possible value of bis 1002
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(D) greatest possible of a is 1000
SECTION-C
49. Mr. A lists all the positive divisors of the number N(2010)2 and selects two divisors from the list
then the probability that exactly one of the selected divisors is perfect squares is:
50. If (H l .(
x-3 ±1
x
✓ x-4
-x -x 2
j( (17-x
2
+x-1 lxl-32
/ <0 then no. of integers x satisfying the inequality is
51. Let f be real function defined on R (the set of real numbers) such that
f'(x) = 100 ( x -1 )(x -2)2 (x-3) 3 .•..•••(x-100)1°0 , for all x ER. If g is a function defined on
f
X X
f
R such that ef (t) dt = g(x- t)dt + 2x + 3 , If some of the all the values of x for which g(x) has a
a O
A,
local extremum be 1 then find -
3
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52. On a normal standard die one of the 21 dots from any one of the six faces is removed at random
with each dot equally likely to be chosen. The die is then rolled. If the probability that the top face
p (p+q)
has an odd number of dots is -where p and q are in their lowest form, find ~-~
q 4
53. A function f is defined on the complex number by f (z) =(a+ bi)z , where 'a' and 'b' are positive
numbers. This function has the property that the image of each point in the complex plane is
equidistant from that point and the origin. Given that la+ bil = 8 and that b 2
=u
V
where u and v
are coprimes. Find the value of (u + v)-250.
54.
2
1
18
1
20071 (n+a)
36 then find the value o f - - .
100
0 0 1
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FIITJEE
FULL TEST- I
JEE (Advanced)-2021
PAPER-1
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wrong answer.
correct answer(s).
a correct option;
Negative Marks : - 2 In all other cases.
Section-C (13 - 18, 31- 36, 49 - 54) contains 18 Numerical answer type questions with answer
XXXXX.XX and each question carries +4 marks for correct answer and -0 marks for wrong
answer.
Physics PART - 1
SECTION-A
1. Consider a situation in which a uniform gravitation field is present

below line AB and no gravity above line AB . Then the speed with
which a rod shown in the figure will strikes earth surface when
released from the position shown is: m ,£
(A) .[ii,
(B) 2.jii, 5£
(C) 3.jii, _ea_r_th_s_u_rf_a_ce_ ____,_i_ _
(D) 4.jii,
2. In hydrogen atom spectrum, when an electron de-excites from higher energy level n >> 1 to
lower energy level then first few frequencies of light that is emitted (e. g. n = n to n-1, n to
n - 2 , n to n - 3 etc.) are very nearly:
(A) in AP (Arithmetic progression)
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(B) in GP (Geometric progression)
(C) in HP (Harmonic progression)
(D) in I2 : 22 : 32 ratio
3. Two identical small blocks each of mass 1kg are given

velocity 4 mis towards each other. All collision are
elastic and surface between 1m to 2m is rough 0
tJ j 777777777
lm
j
2m 3m
(µ = 0.7) and rest part is smooth. Then:
(A) Speed of each block after first collision is ✓ 2 mIs

(B) Speed of each block after first collision is 4 m I s
(C) Separation between blocks when they stop is 2 / 7 m
(D) Separation between blocks when they stop is 5 / 7 m
4. A photon of wavelength A is incident on a photoelectric plate and the most energetic electron
from photoelectric plate is incident on a target metal of X-ray tube. If the minimum wavelength of
photon emitted from target material is 2l then work function of photoelectric plate is:
he
(A)
A,
he
(B)
211,
he
(C)
411,
he
(D)
811,
5. In a polytropic ( pyx =constant) when the volume of a mono-atomic gas was increased four
times, simultaneously pressure decreases 8 times:
(A) Molar specific capacity of gas is 2R
(B) Molar specific heat capacity of gas if R
R
(C) Molar specific heat capacity of gas is - -
2
5R
(D) Molar specific heat capacity of gas is -
2
6. A moving ball collides a pendulum bob as shown, the coefficient 0

of restitution so that bob performs vertical circular motion about 0
is (g = 10 m/s2) 1
f =-m
(A) 1 2
1kg lOm/s
1 • 2kg
(B)
4
1
(C)
8
1
(D)
2
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7. Six charges of equal magnitude but opposite sign are fixed on +q R

an insulating ring at equal separation. P is a general point on
the axis of ring at large distance from the centre of ring. PR is a -q -q I
1
path perpendicular to the axis of the ring and R is at infinite
separation from P.
.--- I
------------------------,1
p
+q +q
-q
(A) Amount of work done to bring a charge from R to P via RP is zero.
(B) Net dipole moment is zero and electric field is conservative field.
(C) Amount of work done to bring a charge from R to P via RP is zero because net dipole
moment is zero and electric field is conservative field.
(D) Amount of work done to bring a charge from R to P via RP is zero not because of net
dipole moment is zero and electric field is conservative field.
8. A radioactive point source has a decay constant 2 . When this source moves towards small area
counter kept at large distance from source, then counter records counUsecond which turns out to
be constant:
(A) When separation between source and counter becomes half of initial value, number of
3
4
(B) When separation between source and counter becomes half of initial value, number of
1
4
(C) Graph showing variation of separation between source and counter with time is as shown
r (separation)
(D)
L,(time)
Graph showing variation of separation between source and counter with time is as shown
r (separation)
9.
I~ ~t(time)
A diatomic gas is kept in a closed container of constant volume. Due to increase in temperature
some molecules dissociates into atoms. Neglecting vibrational degrees of freedom:
(A) Specific heat capacity of mixture will increase.
(B) Specific heat capacity of mixture will decrease.
(C) Specific heat capacity of mixture can change by a maximum value of 8%
(D) Specific heat capacity of mixture can change by a maximum value of 20%
10. A lens of focal length f=40cm is cut along the diameter
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into two equal halves. In this process, a layer of f =40cm
thickness t = Imm is lost, then halves are put together Screen
to form a composite lens. In between focal plane and
the composite lens a narrow slit is placed very close to ---------+---t---------t 0
s
lul Ill .
the focal plane < The slit is emitting
lul <IJI
monochromatic light of wavelength 0.6 µm. Behind the 0.5m
lens a screen is located at a distance L = 0.5m from it
as shown:
(A) Fringe width is 0.12mm
(B) Fringe width is 0.24mm.
(C) Length of interference pattern is l / 8 cm
(D) Length of interference pattern is 1116cm
11. In an interference experiment as shown in the figure, the source Screen

B•
plane and screen are separated by a distance 1m. At a certain !
position of source, fringe width is 114mm and by moving the source
away from mirror along the line AB by 0.6mm , the fringe width
st :
A 1----- mflllllll//ll ____ __
changed to 116mm:
!
Wavelength of light used is 5000A :
(A)
(B)
(C)
Wavelength of light used is 6000A
Initial distance of source from A is 1.2mm
---------
!
lm
(D) Initial distance of source from A is 0.6mm
12. A particle of mass 6.6 x 10- kg starts

30
(t = 0) moving on a straight line w ith velocity 10mls . Its
velocity decreases with time, however rate of change of de-Broglie wavelength associated with
particle remains constant atl0-4 mis . (take h = 6.6x 10-34 J-s ):
(A) Velocity of particle at t = 0.9 s is lm I s
(B) Velocity of particle at t = 0.9 s is 6 mls
(C) Magnitude of retardation of particle at t==0.9s is 4mls2
(D) Magnitude of retardation of particle at t = 0.9 s is 1mis
SECTION-C
13. A particle of mass 0.1 kg moving horizontally w ith velocity 20 m/s

strikes a stationary sedge of mass 0.05 kg near the apex of the w edge
and comes to rest immediately after the collision . The wedge is free to
move on the smooth floor. Second collision of particle w ith wedge
lOK
-
m A
occurs at B. If the length AB of wedge is ✓5 meter, then find K . SI
( 2) . Neglect the toppling of wedge.
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Take 0=coc'
14. Graph show s variation of internal energy U w ith density p of one U(joule)
mole of an ideal monoatomic gas. Process AB is a part of rectangular
hyperbola. Find work done in the process (in Joules) 23 ····-·· B
--+-------p
15. A radioactive nucleus X decays into a nucleus Y w hich itself is radioactive. Y decays into a stable
nucleus Z.
X Half Life ) y Half Life ) Z
=I2 hour =I8 hour
Initially the sample has only nuclei X & number count of Y is zero. Find time (in minutes) w hen
number of count for Y is maximum.
16. Half ring of mass m and radius R is released from the position shown in diagram.
A small point mass of same mass is also fixed at the end as shown in figure. If
the initial acceleration of point mass m is _Jr_ then find the value of /J.
JJ,c
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17. In YDSE, if sources are incoherent, the intensity on screen is 1310 . When these sources are
coherent then minimum intensity on screen is 10 . If maximum intensity produced by these
coherent sources on screen is nl0 , then find n .
18. A vessel of volume V 0 is evacuated by means of a piston air pump. One piston stroke captures
the volume~V = 0.2 V 0 . If process is assumed to be isothermal then find the minimum number
1
of strokes after which pressure in the vessel becomes ( - -
1.728
) (P. 1. 1 ) .
llllla
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Chemistry PART- II
SECTION-A
19. The following two compound are:
(A) Identical isomers

0 (II)
~
(B) conformational isomers

(C) geometrical isomers
(D) Optical isomers
20. If mercuric iodide is added to an aqueous solution of KI , the:

(A) freezing point increased
(B) freezing point is lowered
(C) boiling point does not change
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(D) Osmotic pressure increased
21. Which of the following is weaker base?

(A) N(SiH3 ) 3
(B) N(CHJ 3
(C) NH(CH3 \
(D) All are equally basic
22. Which of the following ions is expected to be colourless?

(A) Ni 2+
(B) Mn+2
(C) Zn2+
(D) Cu 2+
23. A definite mass of a monoatomic ideal gas at 1 bar and 27°C expands isothermally against
vacuum from 1.2 dm3 to 2.4 dm3 . The change in free energy of the gas, /'),_G, is (R = 0.80 bar -
UK-mol, In 2 = 0.7)
(A) 0
(B) -64 bar-1
(C) +84J
(D) -84J
24. In the system,LaCl3 (s)+H 2 0(g)+heat~LaClO(s)+2HCl(g) , equilibrium is

established. More water vapour is added to disturb the equilibrium. If the pressure of water
vapour at new equilibrium is double of that at initial equilibrium, the factor by which pressure of
HCl is changed is:
(A) 2 times
(B) ✓2 times
1 .
(C) ✓2 times
(D) 4 times

25. Which of the following statemenUstatements is/are correct?

(A) in the NaCl structures, each Na+ ion is surrounded by 6Cr ions as nearest
neighbours and twelve Na+ ions as next nearest neighbours.
(B) the co-ordination number of cation generally increases as the radius ratio increases
(C) packing efficiencies higher than 0.74 are possible only with cation and anion of different
sizes
(D) during a crystal defect electrical neutrality should be maintained.
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26. An optically active alcohol A ( C8 H 16 0) on oxidation gives B. A on acidic heating gives
C ( C 8H 14
) as major product. C on ozonolysis produces D ( C5 H 8 0) and
H3C-rr-CH3 . Don reduction with LiAIH, gave 0--oH ·

0
Identify correct answer:
3 (B) CH 3
(A) o+CH
A is CH2 0H Bis 0-+cooH
H H
(C)
Cis v=< (D)
Dis (>=o
27. Which of the following order for basic strength is/are correct?
0 () 0 UNH,>&NH
(A) (B) 0
> > 2
N N
H H
COH >00 Q 0
(C) (D)
N0NH
> >
N
\d
N
H H
H
28. When 5 ml of a 1.0 M Hel solution is mixed with 5 ml of a O.IM NaOH solution ,
temperature of solution increases by t 0 e. Which of the following(s) can be predicted from this
observation:
(A) If 5 mL of O.IM Hel is mixed with 5 ml 0.1 M NH3 solution, the temperature rise will
be less than t
0
e
(B) If 5 ml 0.1 M eH3 eOOH is mixed with 5 ml 0.1 M NaOH, the temperature rise will
be less than t
0
e
(C) If 10 ml of 1.0 M HCI is mixed with 10 ml of 0.1 M NaOH, the temperature rise will
be 2t
0
e.
(D) If 10 ml of 0.1 M HCI is mixed with 10 ml of 0.1 M NaCl, the temperature rise will
be t
0
e
29. Which of the following is/are can produce H2O2 on hydrolysis?
(A) Ba02
(B) Pb02
(C) Mn02
(D) Na2 0 2
30. The correct statemenUstatements is/are:

(A) The distance between two octahedral voids of a cubic close packing of atoms with radius
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r is 2r
(B) The distance between two tetrahedral voids of a cubic close packing of atoms with radius
r is ✓6xr at the body diagonal axes
(C)J{- The distance between tetrahedral and octahedral void is x r , where is the radius of
atom forming the close packing
(D) The distance between the surfaces of atoms fee arrangement along an edge is
2( ✓2-l)r
SECTION-C
31. One mole of nitrogen gas at 0.8 atm takes 38 seconds on diffuse through a pinhole, whereas one
mole of a compound of xenon with fluorine at 1.6 atm takes 57 seconds to diffuse through the
same hole. Calculate molecular weight of the compound.
32. Calculate ~1 H 0 (magnitude only) for chloride ion (aq.) from the following data: (in kJ)
1 1
-Hz (g)+-e/2 (g) ➔ Hel(g); ~ f H 0 =-92.4kl
2 2
HC!(g )+H2 0(e) ➔ H 30 + ( aq)+ CZ- ( aq ); ~ 0 =-74.8kl
~ 1H 0
of H+ ( aq) = O.Okl
5
33. K sp of PbBr2 (Molar mass= 367 ) is 3 .2 x 10- • If the salt is 80% dissociated in solution , calculate
the solubility of salt in gram per litre. (in litre-1 )
34. At 20°c , the vapour pressure of 0.1 molal aqueous solution of urea is 0.03 mm less than that of
water and the vapour pressure of 0.1 molal solution if KCl is 0.0594 mm less than that of water.
The apparent percentage dissociation of KCl in water at the given temperature is (Neglect the
moles of solute particles in comparison to the moles of water in both solutions).
35. If x and y are total number of electrons which are present in non-axial and axial set of d-orbitals
2x 2
respectively in Ni cation of [ Ni (DMG )i] ,then calculate value of y.
36. Total energy of an atom when electron is in the 1st orbit of hydrogen atom is -13.6eV/atom.
Kinetic energy of electron in the 1st excited state of Li2 + ion in eV is:
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SECTION-A
37. Conditions so that equation (a1x 2 + b1x + c1 )(a 2 x2 + b2 x + c 2 ) = 0, (a1a2>0) have fours real roots if
(i) c1c2>0 (ii) a1c2<0 (iii) a2c1<0
(A) only (i) is sufficient
(B) either of two statements are sufficient
(C) either of two statements are necessary and sufficient
(D) all the three statements are sufficient
38. In a ~ ABC, the incircle touches the sides BC, CA and AB at D, E, F respectively. If radius of
incircle is 4 units and BO , CE and AF are in A.P. with common difference 1, then area of MBC is
(A) 84 sq. units
(B) 42 sq. units
(C) 168 sq. units
(D) data insufficient
39. Let A be the area between co-ordinate axis, y 2=x-1 , x2=y-1 and the line which makes the
shortest distance between two parabolas and A' be the area between x=0, x2=y-1 , x=y and the
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shortest distance between y2=x-1 and x2=y-1 , then
(A) A=A'
(B) A= (A' )½
(C) A= 2A'
(D) can't say anything
40. a,b,c are in G.P. and the equation (a+di)x2+2(b+ei)x+(c+if)=0 have one real root then ~.!>..~ are
d e f
in, (a,b,c,d,e ,f ER)
(A) AP
(B) GP
(C) HP
(D) none of these
41. fsecP' 3
x cos ecq' 3 xdx = (p, q E 1+ and p+q=12)
- p +1
tan 3 x
(A) ---+ c
- p +1
3
- p +1 - p +3
tan 3 x tan 3 x
(B) - - - + c+---+c
- p+3
tan 3 x
(C) ---+c
-p + 3
3
(D) none of these
42. A square ABCD of a diagonal 2a is folded along the diagonal AC, so that the planes DAC, BAC
are at right angle. The shortest distance between DC and AB is
(A) #a
2a
(B)
✓3
(C) fl
(D) none of these

43. [ ( ex3 +e-x3 )dx is less than

(A) 2
2
(B) 2e+-
e
1
(C) e+-+2
e
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(D) 2e
trX
I 2
44. J Let f(x)=e-x +

2
✓l+sintdt\fxE(0,oo)then-
o
(A) f exists and is continuous \ix E (0, oo)
(B) f' exists \ix E (0,oo)
(C) f is bounded
(D) There exists a> 0 such thatif(x)I > If' (x)!Vx E (a ,oo)
45. Let x, y, z are positive real numbers and f I is the least value of 2x4 + 2 y 4 + 4z4 - 8.xyz and
4 4 4 1
f 2 is the least value of x y + xy +--2 3 + 3 2 + 8 , then-
x y X y
(A) f1 =-1
(B) £2 >-1
(C) £2 = 10
(D) £2 > 10
4 3 2
46. Consider the equation in x , 8x -16x + 16x -8x + a = 0 , then sum of all the non-real roots of
equation can be ( a E R)
(A) 1
(B) 2
1
(C)
2
(D) None of these
. 40 160 200 320 2

47. For the e q u a t i o n - - - - - - - - + - - = 6x -27x
x-1 x-4 x-5 x-8
(A) Number of real solution of above equation is 3
(B) If E denotes the product of non-zero or complex roots of equation, then sum of divisors of
Eis 2904
(C) It S denotes the set of all real roots of equation then, sum of elements of S taken two at a
time is 81
(D) If a 1 , a 2 ER be two roots of equation such that loga2 ( 2 a 1 ) is defined it must be 1.
48. Let a, b, c be the positive integers such that a<b<c. If the two curves
y =Ix-al+ Ix -bl+ Ix -cl and 2x + y = 2003 have exactly one point in common, then-
(A) least possible value of c is 1002
(B) greatest possible value of b is 1001
(C) least possible value of bis 1002
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(D) greatest possible of a is 1000
SECTION-C
49. Mr. A lists all the positive divisors of the number N(2010)2 and selects two divisors from the list
then the probability that exactly one of the selected divisors is perfect squares is:
50. If (H l .(
x-3 ±1
x
✓ x-4
-x -x 2
j( (17-x
2
+x-1 lxl-32
/ <0 then no. of integers x satisfying the inequality is
51. Let f be real function defined on R (the set of real numbers) such that
f'(x) = 100 ( x -1 )(x -2)2 (x-3) 3 .•..•••(x-100)1°0 , for all x ER. If g is a function defined on
f
X X
f
R such that ef (t) dt = g(x- t)dt + 2x + 3 , If some of the all the values of x for which g(x) has a
a O
A,
local extremum be 1 then find -
3
52. On a normal standard die one of the 21 dots from any one of the six faces is removed at random
with each dot equally likely to be chosen. The die is then rolled. If the probability that the top face
p (p+q)
has an odd number of dots is -where p and q are in their lowest form, find ~-~
q 4
53. A function f is defined on the complex number by f (z) =(a+ bi)z , where 'a' and 'b' are positive
numbers. This function has the property that the image of each point in the complex plane is
equidistant from that point and the origin. Given that la+ bil = 8 and that b 2
=u
V
where u and v
are coprimes. Find the value of (u + v)-250.
54.
2
1
18
1
20071 (n+a)
36 then find the value o f - - .
100
0 0 1
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FIITJEE
FULL TEST- I
JEE (Advanced)-2021
PAPER-1
ANSWERS, HINTS & S0liUTIONS

Physics PART- I
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SECTION-A
1. C
m
i yg gy
Sol. a=-=-
m .f.
A y1I
u £
fvdv= g fy dy
0 .f. 0
u = .fii........ (1)
22
v = u + 2g ( 4.f.)
u = 3.{ii
2. A
Sol.
'F ~ -Re[(n-lm )'
Form= 1, 2, 3
vis in A.P.
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AITS-FT-I (Paper-1 )-PCM(Sol.)-JEE(Advanced)/2021 2
2
v =2
1 1
⇒ -(0.7)(10)x' = 0-- x 2,
I
X =-
2 7
So final separation =2 (12 17 )= -m

--- 5
7
4. B
hC hC hC
Sol. Work function = - - - =-
,1, 2,1, 2,1,
5. C
Sol. PVX = p (4vr

8
8=(4r
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3ln2 = x21n2
3
x=-
2
R R 3R R
C=--+--=--2R=--
~-l 1-I 2 2
3 2
6. D
Sol. v1 + 2v2 = 10
v1 -v2 = -e(lO)
3v2 = lO(l+e)
3 5(10)(½)=lO(l + e) ⇒ e= ~
7. ABC
Sol. ~w=q~V
8. BC
N
Sol. ~=constant
No = N N= N o
r2 r2 ' 4
3 AITS-FT-I (Paper-1 )-PCM(Sol.)-JEE(Advanced)/2021
N e-Jd
Also 0
r2
= constant
9. AD
Sol. 2 ( CV tonoatomic > ( CV ) diatomic
(2)(3R)-(l)(5R)
2 2
Maximum change = = .!_
SR 5
2
% change = 20%
10. BC
11. BC
Sol. Let AS= h
Screen
Bi
s~
A 1····
:: _______
mmmm111 ······
lm
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- - -....... (1).
l_l(l)
4 2h
1 - l(l)
~ -....... (ii)
6 2(h+0.6)
1
4 _ h+0.6
1 h
6
2 = h + 0·6 ⇒ h = 1.2mm
2 h
.!..mm= l(lm) ⇒ A = 6000.A
4 2x(1.2)mm
12. AD
SECTION-C
13. 00000.40
Sol. Apply COM
14. 00002.00
Sol. U.p.=Constant
T
-=constant
V
P=constant
W=nRflT ...... (i)
n(Cv )llT=3
n( 3
: )flT = 3 ⇒ W = 2joule
15. 00060.00
16. 00001.50
Sol. r = 10 a
2R ( 2mR 2+4mR 2)a

mg-=
Jr
a = mg 2 R1 =___.I_· a = 2R x a = 2g
tr6mR 3trR ' m 3,r
17. 00025.00
Sol. I1 +I 2 = 13I0
(-Jr:-Fzf =Io
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I +I -2-Jr:A =I
1 2 0
2-Jr:J!;=l2Io
Imax =13I0 +12I 0 =25I 0 =(5)2 I0
18. 00003.00
V
Sol. Let P1 be density after first stroke VP=(V + llV)J: = ( )P
V+flV
After nth stroke
P,, = ( V )n p , P,, = ( V )n
V+flV P V+flV
Pressure oc density
p ( V )n
; = V+flV
1 [ V0 Jn
1.728 = 1.2V0
(1.2r = (1.2)3
n=3
Chemistry PART- II
SECTION-A
19. C
Sol. (I) is trans and (II) is cis form
20. A
Sol. 2KI+Hgl 2 ~ K 2 [Hgl4 ]
~ ~
Four ions threeions
21. A
Sol. Due to back bonding (A) is a weaker base.
22. C
Sol. Fully filled d-subshell is colourless in nature.
23. D
Sol. t,,.S =nRln V2

v;
Aff =0
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11G=Aff-Tt,,.S
24. C
25. ABCD
26.
o-+cooH
Sol. CH 3
H
(B)
C)=o+
(D)
j LiAIH,
0-0H
27. BC
Sol. A lone pair of N-atom participating in resonance will be less basic
28. AB
Sol. Reaction proceeds by limiting reagent only_ Enthalpy of neutralization decreases, when acid or
base or both are weak:
29. AD
Sol. Ba0 2 and Na 20 2 are peroxides
30. ABCD
SECTION-C
32. 00167.20
Sol. Given,
}_H2 (g )+(Aq) ➔ H +( aq) ; Mf O = 0.---·--·---·---·--·---( i)
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2
}_H2 (g)+}_C/2 (g) ➔ HC!(g) ; MfO = -92_4k.f___________ (ii)

2 2
HC!(g )+ H 20(l) ➔ H3o+ ( aq) +C!- (aq) ; Ml = - 74_8k.f ____________ --(iii)
By inspection method: Eqs_ (ii)+ (iii)- (i) reveals that

1
- C/2 (g )+( Aq) ➔ Cl-( aq ); Afl=-167_2kf
2
i_e_Heat of formation of Cr ( aq) = - l 67.2kJ
33. 00009.17
1
Sol. Let solubility of PbBr2 is S mo! litre-
PbBr2(s) + aq ~ PbBr2(aq ) ~ Pb 2+ + 2Br-
sxso 2Sx80
100 100
Since, PbBr2 ionises to 80% only.
Now K sp = [Pb 2+ ] [ Br- r 2

Or 3 _2 x 10_5 =[ Sx 80][2Sx 80]
100 100
S = 0_025 mol litre-1
= 0.025 x 367 g litre-'
=9_1 75glitre- 1
34. 00098.00
Sol. T = 20°C 0.Im solution of urea ~P=0.03mm
KCl ➔ 0.Im M=0.0594
M
- p = x /J ➔ 0.lmoleinlkg
0.03 0.1
=----
p 0.1+55.5
p = 0.03 X 55.65 = 16 _695
0.1
M
-=iX
p fJ
0 0594
· =i[0.00179]
16.695
i = 1.987
35. 00036.00
36. 00030.60
z2
Sol. KE= 13.6 x -
n2
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32
= 13.6 x 2 = 30.6eV
2
SECTION-A
37. B
38. A
Sol. As s-b, s-c, s-a are in AP w ith common difference =1
⇒ a,c, bare in AP with common difference equal to 1.
a + a + 1+a + 2 3(a + 1)
⇒ c=a+ 1, b=a+2 ⇒ s=-----=---
2 2
Also r = fi/s ⇒ a + 2a-195 = 0 ⇒ (a+15)(a-13)=0
2
A= 13, c=14, b=15 ⇒ t,,,. = 84 sq. units
39. C
Sol.
·s~(
Line of shortest distance will be perpendicular to line x=y. Also both parabolas are symmetric
=y
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A=area OABCDO
A'=area OECDO
y2 =x-1
⇒ A' =A/2
40. C
Sol. Let a be the real root then (aa2 + 2ba + c) + i(da 2 + 2ea + f) = 0 2 -Jc
⇒ aa + 2ba + c = 0 ⇒ a = ✓a
C ✓C d e f
⇒ da 2 + 2ea + f = 0 ⇒ d. - - 2e- + f =0 ⇒ --2.- + -=0
a ✓a a b c
41. B
Sol. f
I= tan-P'3 x.sec 4 xdx f
= tan-P'3 x(1 + tan2 x). sec 2 xdx
42. B
Sol. If equation of line AB is r = 6+ i(✓2a}-D) = i I
then equation of line DC is f = .fi.a f + µ(J2 f J2] + + ak -.fi.af)
-- "'2
r - v La
a
I
( -1 a 1 ~ k·) ⇒ s -D-- (a2 - [61
+ µ .fi. I + .fi. J+
a1).(b1
x b2[
X bi) - 2a
- J3
43. BCD
I
Sol. I= f( ex3 +e-x )dx > 2 3
-1
Graph is concave upwards
⇒ I < f(O)+ f(l)
44. ACD
Sol.
I
f (x)=e
-2
xI
2
.-+- l+sm-
x3
ff
2
Fl . ffX
2
I
-2
e X
lim-3-=0
And x➔o• X
Also lim f(x) = oo

X ➔ «>
f '(x) does not exist for x=3, 7, 11 ....
45. AD
4 4 4
2x + 2y +4z + I
Sol. - - - - - - - ~ 2xyz
4
4 4 4 1
And x y+xy +~+-3- 2 +8~ 5-2
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X y X y
⇒ C2 > IO (equality cannot hold)
46. AB
I
Sol. (Put X =y +- )
2
47. AB
Sol. (-1 +l) - (- 4 +l) - (-5 +l) +(-8 +l) =

x-1 x-4 x -5 x-8
2
6x -27x
40
⇒ x=O
2x-9 2x-9 =~(2x-9)
Also-----
(x-l)(x-8) (x-4)(x-5) 40
And x=9
48. ABO
Sol. Condition is satisfied for (a, b+c-2a)
⇒ b+c=2003
SECTION-C
49. 00000.32
50. 00031.00
-fxf /
(x-3)x v(x-4)2 (17-x)
Sol. -=~-~------<0
✓-r-(-x 2 +x-1)(1xl-32)
ForM to be defined x < 0
⇒ -lxl =1
X
Since .J(x - 4)2 ,h 2

are positive & - x + x - l is always negative
(x-3)(x-17) >
0
x+32
1
x <O ⇒ -- > 0 ⇒ x=31
x+32
51. 00833.33
X X
Sol. Jef(t)dt =fg(x-t)dt + 2x+ 3

a O
X X
⇒ fef(t)dt =fg(t)dt + 2x + 3 (Using King Property)

a 0
Differential both sides, we get
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ef(x) = g(x) + 2
⇒ g(x) = ef(x) -2
⇒ g '(x) = ef(x) .f '(x)
·: ef(x) is always greater than zero.
:. sign of g'(x) is same as sign of / '(x).
:. sign of g'(x)
-1 -2 ···········96 97 98 99 100
Clearly, local extremum (maximum or minimum) will occur at
x=99,97,95, .... ,3,1
50
:. Sum of all the values=1+3+5+ ... +99=-[2 x 1 + (50- l) x 2] = 2500
2
52. 00008.00
Sol. E, : Dot removed from odd face.
P(E,) =_2_
21
E2 : Dot removed from even face.
E: Die shows odd numbers of dots.
53. 00009.00
Sol. IZ( a +bi)-ZI = l(a + bi)ZI
1
⇒ a=-
2
2 2
a +b =64
54. 00002.00
n -1
1 2n na+8Z:k
k=O
Sol. 0 1 4n
0 0 1
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FIITJEE
FULL TEST- I
JEE (Advanced)-2021
PAPER-2
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Section-A {01 - 06, 19 - 24, 37- 41) this section contains 18 multiple choice questions.
correct answer(s).
a correct option;
Negative Marks : -2 In all other cases
Section-8 {07 - 11, 25 - 30, 43- 48) contains 18 Numerical based questions with Single digit
Section-C {13 - 18, 31 - 36, 49- 54) contains 18 Numerical answer type questions with answer
AITS-FT-I (Paper-2)-PCM-JEE(Advanced)/2021 2
Physics PART - 1
SECTION-A
1. A gas of mass 1.5kg undergoes a quasi-static expansion which follows a relationship p=a+bV
3
where a and b are constants. The initial and final pressure are 10 kPa and 200 kPa and
3 3
corresponding volumes are 0.2 m and 1.2 m . The specific internal energy of the gas is given
3
by U=l.5pV-85kJ/kg (where Pis in kPa and Vin m /kg):
(A) Work done by gas during process is 600kJ
(8) Change in internal energy of the gas is 90 kJ
(C) Maximum internal energy during process is approximately 500 kJ
(D) Maximum internal energy during process is approximately 300 kJ
2. A non-conducting solid sphere of radius 30 cm and relative permittivity 1 has the volume charge
density p = (2-µc I m 3
2~
)(1--r-),
30cm
where r (in cm) is the radial distance of any point in the
space from the centre of the sphere. Then choose the correct statement(s):
(A) Density of electric field lines is maximum at r = 25 cm
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(8) Density of electric field line sis maximum at r = 20 cm
(C) Electrical energy stored in the space r = 30 cm to r ➔ oo, is same as that of a solid non
conducting sphere carrying charge of 0.0225 µC and radii 30 cm having uniform volume
charge density in the same space r = 30 cm to r ➔ oo .
(D) Variation of magnitude of electric field due to the sphere with respect to radial distance r
is rectangular hyperbola in the region r = 30 cm to r ➔ oo .
3. A satellite of mass m is orbiting a planet of mass M at a radial distance ro from the centre of the
planet. The satellite expels a small mass in a direction opposite to its orbital velocity. The
immediate recoil velocity of the satellite exceeds the initial orbital velocity by tiv for which the
satellite remains within the gravitational field of the planet is:
(A) f!!Z
(8) ~
(C) ( -J2 -1) tMro
(D) None of the above
4. A real object is kept in front of a lens in air. The object is a linear extended object with its length
perpendicular to the optical axis of lens. With reference to different cases of image formation by
lens, choose the correct options:
(A) If the image has a magnification -2.5 then Image is real and power of lens is positive.
(8) If the magnification of the image is +0.5 then Image is virtual and power of lens is
negative.
(C) If length of image is the same as that of object then Image is real and power of lens is
positive.
(D) If length of image is the same as that of object then Image is virtual and power of lens is
negative.
5. A block of mass 2kg is given velocity 5 mis along the horizontal
surface which is alternatively smooth and rough(µ=½). 0

□-. . .
lm 2m 3m 4m
Consider first 1 meter is smooth. Then:

(A) Speed of block when it crosses 2m point is 3 mis
(B) Speed of block when it crosses 2m point is 2✓5 mis
(C) Total distance travelled by block before it stops is 10 m
(D) Total distance travelled by block before it stops is 20 m
6. A block is given velocity when the spring was in natural

length. Then (g=10 mls2 )
(A) Distance travelled by the block before it stops for the first time is 32 cm
(B) Distance travelled by the block before it stops for the first time is 64 cm
2
(C) Acceleration of block when it stops for the first time is 5 .5 m I s
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2
(D) Speed of block when the spring is in natural length again is ✓6 m I s
5
SECTION-8
~
7. In the given LCR AC circuit, the effective current (in ampere)
flowing through the circuit is:
V=200sin(100t)
8. The side wall of a wide vertical cylindrical vessel of height h=75cm has a narrow vertical slit
running all the way down to the bottom of the vessel. The length of the slit is I = 50cm and the
width b = 1mm. With the slit closed, the vessel is filled with water. The resultant force of reaction
of water flowing out of the vessel immediately after the slit is opened is (in N)
9. A block of mass M = 1kg lies on a smooth horizontal floor. A bullet of mass 0.1 kg is fired
horizontally with a velocity u = 11 0mls and gets embedded in the block. The combined mass is
set into motion and encounters a rough inclined plane of inclination 37°and length /=1.Bm in its
path. It starts moving up the inclined plane ( A = 0.5 ), reaches the topmost point and finally
lands on the horizontal floor. Assuming that the mass is not jerked when it starts up on the
inclined plane, the horizontal distance covered by the combined mass while it is not in contact
with the horizontal floor is (approximately in m)
fllTJH Ltd., FnTJEE Ho=-, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
10. A point moves according to the law x = at, y = at ( 1- a t ) where a and a positive constants are
and tis time. If the moment at which angle between velocity vector and acceleration vector is
:r A A
-is given by- is given by-. Find the value of A .
4 a a
11. A 6 kg block is moving with a speed of 10 m/s over a rough surface
with coefficients of friction A = 0 .6 and A = 0.4 as shown in figure. I 6kg I F=4 t ..
A time varying force F = 4t ( f in newton and t in second) is applied A =0.6
on the block as shown. Find the acceleration of block at!= 5 sec .
2
A = 0.4
(Take g = IO m I s )
12. Two blocks of masses m1 = 5kg and m2 = 2kg are connected by

threads which pass over the pulleys as shown in the figure. The
threads are massless and the pulleys are massless and smooth. The
blocks can move only along the vertical direction. If the acceleration
T,
of m, , if expressed in simplest from, is equal to - 2n- ) m I sec 2 ,

( n -1
calculate' n' . (Take g = 10 m/s2 )
www.jeeneetbooks.in SECTION-C
DECIMAL PLACE; e .g. XXXXX. XX).
13. The diagram shows the PV diagram of a process carried

p
out with a certain quantity of oxygen ( y = ~) . If
2 5
V A =-V0 andV8 = - V 0 , find the volume till the gas
3 12
absorbs heat. If this volume is NV0 , the find N .
14. A string of length 1m fixed at both ends is vibrating in 3 rd overtone. Tension in string is 200 N and
linear mass density is 5 gm/m. Find the frequency of these vibrations in Hz.
15. A curved thick glass surface is silvered at curved

face & not silvered on plane surface. Object is
placed at A as shown in figure. Considering P (pole p
of the silvered surface) as origin. If x - co - A
ordinate of final image is 'n' cm then find n . 4cm 4cm
µ =2
R=l 6cm
16. In young's double slit experiment, the coherent

sources are separated by a small distance and
screen is placed at a large distance. Thin strips are
placed infront of slits S1 and S2 as shown. The
strip which is placed in front of S1 has width 4 mm
and has refractive index 1.5. The strip which is
placed infront of S2 has a variable refractive index
µ = I+ Cx where xis distance from left end of strip
and C = 1mm·1 .
If central maxima is obtained at O {symmetrical with respect to O}, then find width of strip (in
mm) placed in front of S2 .
17. For an equilateral prism, it is observed that when a ray strikes grazingly at one face and it
emerges grazingly at the other. Its refractive index will be:
18. A and Bare two points on horizontal ground separated by a distance of 300 m. A point source of
sound is situated at point A. If velocity of sound in still air is 260 mis and air flows with speed 100
mis horizontally and perpendicular to AB then find time taken (in sec) by sound travel from A to B:
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Chemistry PART - 11
SECTION-A
19. Which of the following information(s) is/are incorrect regarding the voids formed in three
dimensional HCP of identical spheres?
(A) A tetrahedral void is formed when a sphere of the second layer is present above the
triangular void of the first layer.
(B) All the triangular voids are not covered by the spheres of the second layer.
(C) Tetrahedral voids are formed when the triangular voids in the second layer lie above the
triangular voids in the first layer and the triangular voids in the first layer and the
triangular shapes of these voids do not overlap.
(D) Octahedral voids are formed when the triangular voids in the second layer exactly
overlap with similar voids in the first layer.
20. Consider 0.1molal aqueous solutions of two solutes X and Y. The solute X behaves as a
univalent electrolyte, while the solute Y dimerizes in solution. Which of the following statement(s)
is/are correct regarding these solutions?
(A) The boiling point of the solution of X will be higher than that of Y.
(B) The osmotic pressure of the solution of X will be higher than that of Y.
(C) The freezing point of the solution of X will be higher than that of Y.
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(D) The relative lowering of vapour pressure of both the solution will be the same.
21. Select the correct statement:

(A) Chelation effect is maximum for five and six membered rings
(B) Greater the charge on the central metal cation , greater the value of ~ ( CFSE)
(C) In complex ion [ CoF6 t ,p- is a weak field ligand, so that ~ act <P (Pairing energy)
and it is low spin complex.
(D) [ CoC12 (NH3 ) 2 (en) r complex ion will have four different isomers
22. Roasting of copper pyrites is done:

(A) to remove moisture
(B) to oxidise free sulphur
(C) to decompose pyrite into Cu 2 S and FeS
(D) to remove volatile organic impurities
23. Select the incorrect statement(s):

(A) Cs+ is more hydrated than the other alkali metal ions
(B) Among the alkali metals Li, Na, K and Rb, lithium has the highest melting point
(C) Ionic mobility of u+ is maximum among alkali metal cations
(D) Ionisation potential of Li is lower than that of Na.
24. A sunburn prevention agent must be non-toxic, non-staining, non-volatile, reasonably water
soluble. It should filter of the burning rays of sunlight. Given structure is one such compound:
OH 0
HO
which method/s for synthesis of above compound starting from m-dimethoxybenzene:
(A) (i)Ph-COCl, (ii)dil. NaOH
(B) (i)Conc.HI(ii)Ph-COCl, A1Cl3
(C) (i)Ph-COCl, A1Cl3 (ii) cone.HI
(D) All of these
SECTION-8
25. If four atoms of same radius are placed at the alternate corner of a cube touching each other,
than the length of body diagonal of the cube is equal to ✓x x R , where R is the radius of atom.
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Find the value of x?
26. A certain buffer solution contains equal concentration of x- and HX. The Kb for x- is
10
10- . Find the pH of this buffer solution?
27. Co forms dinuclear complex with a sigma bond within two Co atoms. Consider that metal
carbonyls follows EAN rule. The complex can be written as Co 2 ( CO t . Find the value of x?
28. Diethyl f3 , f3 '- dimethyl glutarate (ester) is condensed with diethyl oxalate in presence of
sodium ethoxide and ethanol to form a major product ( P) , w hich on acidic hydrolysis followed by
heating gives another product (Q) . Calculate total number of C=O bonds in ( P) and (Q)
compounds?
1
29. At 298 K, if /J.G; of H Cl(g) is 1.72 kl moZ- , then calculate KPfor the following reversible
reaction: 2HCl(g) ~ H 2 (g) + C/2 (g)

1
(Use: at 298K: 2.303RT = 5700JmoZ- andlog2 = 0.30)
30. Total no of lone pairs in XeO3 F2 is 2x. Find the value of x.
SECTION-C
31. An optically active substance, A, decomposes into optically active substances 'B' and 'C' as:
A K~0.001 min-I ) 2B + C
The specific rotations of A, Band Care +40°, +10° and -30° per mole, respectively. If initially A
and C were present in 4: 3 mole ratio, the time (in min), after which the sample becomes
optically inactive, is (In 2=0.7, In 5=1.6, In 7=2.0, In 13=2.5)
32. A hydrogenation reaction is carried out at 500K. If the same reaction is carried out in the
presence of a catalyst at the same rate, the temperature required is 400 K. The activation energy
of reaction (in kJ/mol), if the catalyst lowers the activation energy by 20 kJ/mol, is:
33. A volume of 100 ml of a liquid contained in an isolated container at a pressure of 1 bar. The
pressure is steeply increases to 100 bar by which the volume of liquid is decreased by 1 ml. The
change in enthalpy, Ml, of the liquid (in bar ml)
34. The boiling point of a solution of 5g sulphur in 100g of CS2 is 0.5 °C above that of pure solvent.
1
If the Kb of CS2 is 2.56 Kg K moZ- • Find the atomicity of sulphur in this solvent.
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35. Which of the following statements is/are correct?
(i) Sulphur solution is an example of macro molecular colloid.
(ii) Adsorbent used in gas masks is activated charcoal
(iii) Agl is used for producing artificial rain by seeding.
(iv) Alums purify muddy water by coagulation of colloidal sized clay & sand.
(v) It occurs because of van der Waals forces. (for physisorption)
(vi) More easily liquefiable gases are adsorbed readily. (for physisorption)
(vii) Under high pressure it results into multimolecular layer on adsorbent surface. (for
physisorption)
(viii) Enthalpy of adsorption ( f..Hadsorption) is low and positive. (for physisorption)
36. Pressure over 1000 ml of a liquid is gradually increased from 1 bar to 1001 bar under adiabatic
conditions. If the final volume of the liquid is 990 ml and there is linear variation of volume with
pressure, the value of !iU of the process is (Answer as 'abed', where a= 1, if !iU is +ve and
a= 2, if !iU is -ve , and 'bed' is the magnitude of !iU, in J):
SECTION-A
37. If in a !';.ABC, a , b, c are in A.P. and P1 , P2, P3 are the altitudes from the vertices A, B and C
respectively, then
(A) P1, P2, P3 are in A.P.
(B) P1 , P2, P3 are in H.P.
3R
(C) P1+ P2 + P3 :.,; -
/';.
1 1 1 3R
(D) - +- + - :.,; -
P1 P2 P3 /';.
38. Given three non - zero, non - coplanar vectors, and a,b and cand G=pa+ qb + cand
~ = a+ pb + qc if the vectors G+ 2G and 2~ + f2 are collinear then (p, q) is
(A) (0, 0)
(B) (1 , -1)
(C) (-1 , 1)
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(D) (1 , 1)
39. Each of 2010 boxes in a line contains one red marble and for 1:::; k :s; 2010, the box is the k th
position also contain k white marbles. A child begins at the fist box and successively drawn a
single marble at random from each box in order. The stops when be fist draw s a red marble. Let
p ( n) be the probability that he stops after drawing exactly n marbles. The possible value(s) of
n for which p(n) <-1- is:

2010
(A) 44
(B) 45
(C) 46
(D) 47
40.
3 2
lf a, j3,y arerootsof x +2x -3x +l=0 , thenvalueof a/3 + ~+ /Jr islessthan
a+ /3 a +r /J +r
(A) 2
(B) 3
(C) 4
(D) 5
dx X . £ n . .
41. The solution of differential equation 3-= - 3 - 1s x = mx y + c , then which of the follow ing
dy X -y
is/are CORRECT? {c is any arbitrary constant}
(A) £+m+n =11
(B) £ +n = 9
(C) £+2m = 10
(D) m +n=4
42. Three are 5 boxes numbered from 1 to 5. There is 1 Red and 2k black balls in eh box,
k = l, 2, 3, 4, 5. From each box either one red ball is taken or one or more than one black balls
are taken. But from each box both coloured balls are never taken (ball of same coloure are all
alike). Now which of the following holds good?
(A) Total number of ways selecting odd number of red balls is 4725
(B) Total number of ways of selecting even number of red balls is 5670
(C) Total number of ways selecting odd number of red balls is 5670
(D) Total number of ways of selecting even number of red balls is 4 725
SECTION-8
4 3 2
43. If the polynomial f (x )=4x -ax +bx -cx+5 where a, b,cE Rhas four positive real roots
t r ½ r
say rl'r2 ,r3 andr4 , such that ..l..+ -2 + -+ ....!. =I.Find the value of (a-10).
2 4 5 8
2
44. All the three vertices of an equilateral triangle lie on the parabola y = x , and one of its sides has
a slope of 2. The x-coordinates of the three vertices have a sum equal to p where p and q are
q
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relatively prime positive integers. Find the value of (q-p)
45. f ( x) = max 12sin y - xi where y ER then minimum value of f ( x) is:
f (t)
46. Let f ( x) ( x > 1) be a differentiable function satisfying f ( X) = ( In X)2 - fe1 ~ t . Then if Area
bounded by tangent line of y=f(x)at (e,f(e)) , then curve y=f(x)andx=1is A then
[A]is ([.)is G. I. F)
47. If the equation on reflection of ( x-

4)2 + (y- 3 )2 = 1 about the line x - y- 2 =0 is
16 9
16x2 + 9y2 + k1x - 36y + k 2 =0 then k1 + k 2 is
22
2
48. A and Bare two square matrices such that A B = BA and if ( AB)1° = Ak B 10 then the value of
k-1020 is ....
SECTION-C
2 2
49. If two points P and Q on 9x -5 y =1 (whose centre is C) be such that CP is perpendicular to
1 1
CQ then value of CP 2 + CQ 2 is .....
50. Letz, ,z and z be complex numbers such that lz I= lz I=lz I=lz, +z +zI=2.
2 3 1 2 3 2 3 If
lz z I= lz, -z Iand z -:I- z Then find the value of lz +z Ilz +z I.

1- 2 3 2 3. 1 2 1 3
. 100 50
51. If lim 100
- - --
50
=SA; find the value of A.
x➔1 I-x 1-x
52.
53. There are 4 bowlers, 4 batsman and 1 all-rounder (who is bowler as well as batsman). Randomly
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a team of 4 players consisting of at least two bowlers and at least two batsman is formed. If the
4
probability that all-rounder has been selected in team is - , then p is equal to:
p
2
1-7cos x g(x)
f
54. Suppose . 7 2
Sill xcos X
dx = -_- -+ C, where C is an arbitrary constant of integration. Then
sm7 X
the value of g '(O) + g "( :).
FIITJEE
FULL TEST- I
JEE (Advanced)-2021
PAPER-2
ANSWERS, HINTS & SOLUTIONS

Physics
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PART-I
SECTION-A
1. AC
2. BC
2
f(2-)(1-~)4.
0 2.1r 30 1rr dr
2
Sol. Einside 4.1rr = --=-----------

&o
dEinside =0
dx
4. ABC
Sol. Positive power lens (convex lens in rare medium) can from enlarged (or of same size) real,
inverted image.
Positive power lens (convex lens in rare medium) can form virtual, erect, diminished image.
AITS-FT-I (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 2
5. BO
1 2 1 2
Sol. -µmgx=-mv --mv
2 2
⇒ __!_(20)(1) =_!_(2)v2 _ _!_(2)5 2
8 2 2
⇒ v='}_ ✓Sm l s
2
1 2
-µmgx= 0--mv
2
x = I Om
Total distance = 20m
6. ACD
2
Sol. _ _!_ x 20 x x- ( _!_50x ) = 0-_!_2( 6 I 5)2
4 2 2
8
⇒ x=-m=32cm
25
a= kx- fs = 16-5 = 5.Sm I s2
m 2
64
) =_!_(2)v2
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& _ _!_(20)(8 / 25)- ( -!so x
4 2 625 2
2✓6
⇒ v2 =24 / 25 ⇒ U =--m l s
5
SECTION-8
7. 2
sol. R = son
X L =wL=SOQ
1
X =-=l00Q
L OJC
⇒ z=.JR 1 +(xL -xc)1

Z=50✓2,Q
I = Vnns = 200 / ✓2 =2 A
ram Z 50✓2,
8. 5
Sol. V=figy
⇒ dF =(l x l0-3 ) { figy dyfigy
dF = 1x10-3 x 2 x 1o x y x 103 dy = 40 ydy
xp) T
f
⇒ F= 20 ydy= 40 ( 0.75 -0.25 ) =20 x 0.5=5
2 2
2 2 -----------
3 AITS-FT-I (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021
9. 9
10. 1
dx =a ⇒ d x =O
2
Sol.
dt dt 2
dy d 2y
- = a-2aat ⇒ --=-2aa
dt dt 2
Velocity vector ~=at+ ( a - 2a at) J
;=-2aa)
1t
v.a = va cos -
4
t=_!_ ⇒ A=l
a
11. 0
Sol. Block start when µ.mg= 4t
t = 9 sec
At t = 5s block was at rest so answer = 0
12. 4
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SECTION-C
13. 00000.58
P 7P
Sol.
~-vx 5 vx
p
P, -,.~ .P)
i . . . .. . . . .....
, _ _ - - - ~ - - - -......- +V
V, V0
5Vx = 7~ -7Vx
V = 7~
X 12
14. 00400.00
Sol. 111 rd overtone
f = 4V = 2V =~ 200
= 2(200)
2L L I (511000)
f =400Hz
15. 00014.00
Sol. u =- ( 4+~)x2 = -12 cm
1 1 1
-+--=- ⇒ v=-24 cm
V -12 -8
For final image (refraction through plane surface) w e can w rite.
24 = 2 ( ; + ; ) ⇒ 24 = 2x + 4
x =lO cm
So distance from P is 14 cm
16. 00002.00
Sol. Let width of second strip is £
(S,0-4)+ 1.5( 4)-(S,O-l)+[ l +; J

(1.5-1)(4)= f_
2
f = 2mm
17. 00002.00
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Sol. µ = sin90° = 2
sin30°
18. 00001 .25

Sol. Speed of sound in direction of A B V .J
= 2602 -1002 = 240 m I s
A~~- l. ""'
<'60~
300
:.t=-=1.25
240
Chemistry PART- II
SECTION-A
19. CD
20. AB
Sol. Solute X will dissociate into the solution so i>1.
21. ABO
Sol. [ CoF6 r is a high spin complex.
22. ABCD
23. ACD
Sol. Due to the more cohesive energy in Li, it has highest melting point among alkali metals.
24. BC
Sol. 0
II
cone. Ill
OH _(J_1c_'c1----agUOHI
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AlCl 3 ~
OH OH
(re,
0
SECTION-8
25. 6
Sol.
B----~
Face diagonal of cube (AB) =2R
2R
Edge length of cube (BE)= ✓2
h 2R
Body diagonal of cube (AD) =-v _, x ✓2
=✓6xR
26. 4
Sol. pKa of HX = 14-10 = 4
1
pH= pK +log-=4
a I
27. 8
Sol. ( CO)x / 2 Co-Co(CO) x / 2
EAN( = 36) = 27 +1+2x x

2
⇒ 28+x=36
x=8
28. 6
Sol. COOC2Hs
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>-cooc2 H5
>-COOC2 H5
+ COOC2H5
I
COOC2H5
diethyl-~,~-dimethyl COOC2H5
glutaric acid (ester) COOH
COOH
29. 4
Sol. l._H2 (g )+!cz2 (g) ~ HCl(g)LiG 0 = 1.72k.Jmor 1
2 2
0
LiG for2HCl(g) ~H2 (g )+C/2 (g) is[ 2x(-1.72)] kJ
LiG0 =-2.303RTlogKP
-3.44xl03 =-5700logKP
log K P = 0.6
KP =4
30. 6
Sol. 0
F~11 Xe=O
F/11 0
SECTION-C
31. 00500.00
32. 00100.00
Sol. K = Ae-Ea!RT
33. 09900.00
Sol. 1'1U =q tw
For adiabatic process q =0
1'1U=w
flU =PflV =-P(~ -Vi)
flU = -100(99-100) = l00barmL
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Now Ml= flU + fl( PV)
Ml = l 00 + [100 x 99 -1 x 100]
Aff = 9900 bar mL
34. 00008.00
35. 00006.00
36. 01501.00
SECTION-A
37. BO
38. D
39. BCD
Sol. p ( n) = Probability that child stops after drawing exactly n marbles
p(n)=.!..}.I ....... (~ )(-1) = ( 1 )

234 n n+l n n+l
40. ABCD
Sol.
x'+2x'-3x+H{i
x 3 -3x2 -2x + 1 = o{~;;
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1/ y
Given expression - -
1 - +--
1 -+ -1-
3--1 3-- 1 3--1
a /J r
L (3-al )(3-/Jl) 27-6L[_!_+_!_+.!..]+-l +-1 +-1
a /J r a/J /Jr ya - ~
(3-!)(3-a3-~J - 7
= -----,--~,--'-- =
(3-!)(3-a3-~J
41. ABC
Sol. 3x2 dx = ~ x3 = t
dy x 3 -y
dt t
⇒ -=-- ⇒ (t-y)dt=tdy
dy t-y
2
! C
⇒ tdt= ydt+tdt ⇒ -=t.y+-
2 2
⇒ x =2x y+c
6 3
42. AD
Sol. Let
x: Total No of ways of selecting even number of red balls
even number of red balls
y: Total No of ways of selecting
odd numbers of red balls

(2-1)(4-1 )(6-1)(8-1)(10-l)=x-y (2+ 1)(4+ 1)(6+ 1)(8+ 1) (10+ l )=x+y
SECTION-B
43. 9
Sol. A.M.=G.M.
.5.. = r2 = r3 = r4 =k
2 4 5 8
44. 8
Sol. t 1+t 2=2
2-m2 -✓3
1+2m2
and m3-2 ✓3
1+2m3
p 3
ti +t2+t3 = - = -
q 11
45. 2
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46. 0
47. 6
48. 3
SECTION-C
49. 00004.00
50. 00008.00
Sol. The triangle has circumcentre at origin and its orthocentre laying on the circumcircle.
51. 00005.00
. 100y1°0 50.y 50
Sol. lim 100 - so-
y➔! y -1 y -1
liml00- 50 - ( lOO 50 )
y➔I 1- YIOO l- y5o
5
L=50-L :. L= 0 = 25
2
52. 00001 .00
Sol.
1
As H -H = -
n+1 n n+ 1
1 1
⇒ T=----
n Hn Hn+l
1 1
T +T + +T = - - - -
' z n H I H n+l
53. 00007.00
Sol. Clearly a team of 4 with two batsman and two bowler can be formed as
Case-I: 2 bowler+2batsman
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4 4
Number of ways= C 2 x C 2 =3 6
Case-II: 2 bowler+1 batsman +1 all-rounder
4
C 2 X 4 C I x 1C I =24
Case-Ill: 1bowler +2 batsman +1 all-rounder
4
C I X 4 C 2 x 1c I =24
24+24 4
:. Probability that all-rounder is selected=-----
36 + 24 + 24 7
:. p=7
54. 00005.00
FIITJEE
FULL TEST - IV
JEE (Advanced)-202[
PAPER-1

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Section-A (01 - 06, 19 - 24, 37- 42) contains 18 multiple choice questions which have ONLY
wrong answer.
Section-A {07 -12, 25 - 30, 43 -48} this section contains 18 multiple choice questions.
correct answer(s).
a correct option;
Negative Marks: - 2 In all other cases.
Section-C {13 - 18, 31- 36, 49 - 54) contains 18 Numerical answer type questions with answer
AITS-FT-IV (Paper-1)-PCM-JEE(Advanced)/2021 2
Physics PART - 1
SECTION-A
1. A trough has two identical inclined segments and a horizontal trough is enlarged four ti
segment. A ball is released on the top of one inclined part and
it oscillates inside the trough. Friction is large enough to poriod of osciUatioR of tb
~
prevent slipping of the ball. Time period of oscillation is T. Now
the liner dimension of each part of the trough is enlarged four
times. Then new time period will be
(A) T
(B) 2T
(C) 3T
(D) 4T
2. A conducting shell having no charge has radius R. A

point charge Q is placed in front of it at a distance ro from
its centre. Potential due to charge induced on the surface
of the shell at a point P inside the shell is (Distance of
point P from charge Q is r) Q
kQ
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(A)
ro
kQ
(B)
r
kQ kQ
(C) ---
ro r
kQ kQ
(D)
r ro
3. A conducting rod (OP) of length L rotates in form of a conical pendulum

0)
with an angular velocity (J) about a fixed vertical axis passing through its
end 0 . There is a uniform magnetic field Bin vertically downward direction.
The rod makes an angle 0 with the direction of the magnetic field. The emf
induced across the ends of the rod is
2 2
BroL sin 0
(A)
2
BroL2 cos2 0
(B)
2
2
2
a
BroL tan 0
(C)
2
2
BroL
(D)
2
3 AITS-FT-IV (Paper-1)-PCM-JEE(Advanced)/2021
4. Nuclei of radioactive element A are being produced at rate t2 at time t. The element A has decay
dN
constant equal to A. If N is the number of active nuclei of element A at any time t then - was
dt
found to be minimum at t = to. N at time t = to is
ta - xt~
(A)
x2
ta - 2At2
(B)
A,2
4ta - xt~
(C)
A,2
2ta - At~
(D)
A,2
5. A manometer has a vertical of cross-sectional area 9A and an

inclined arm having area of cross section A . The density of the
manometer liquid has a specific gravity of 0.74. The scale
attached to the inclined arm can read up to ± 0.5 mm. It is
desired that the manometer shall record pressure difference (P1
- P2) up to an accuracy of ± 0.09 mm of water. To achieve this,
the inclination angle 0 of the inclined arm should be
(A) sin-1 (0.13)
(B) sin-1 (0.03)
sin-1 (0.33)
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(C)
(D) sin-1 (0.23)
6. A disc of mass M = 2m and radius R is pivoted at its centre. The disc is
free to rotate in the vertical plane about its horizontal axis through its
centre 0. A particle of mass m is stuck on the periphery of the disc. The
frequency of small oscillations of the system about its equilibrium position. 0
(A) 1 /9
2nVR R
1 /9
(B) 2n V2R m
(C) 1 /9
nV2R
(D) ~ /9
nVR
7. A student performed the experiment of determination of focal length of a concave mirror by u-v
method using as optical bench of length 1.5 m. The focal length of the mirror used in 24 cm. The
maximum error in the location of the image can be 0.2 cm. The sets of {u, v) values recorded by
the student (in cm) are (42, 56), (48, 48), (60, 40), (66, 33), (78, 39). The data set(s) that cannot
come from experiment and is (are) incorrectly recorded, is (are)
(A) (42, 56)
(B) (48, 48)
(C) (66, 33)
(D) (78, 39)
8. Two coherent monochromatic point source S1 and S2 of

wavelength "- = 600 nm are placed symmetrically on either side
of the centre of the circle as show n in the figure. The sources are
separated by a distanced d = 1.8 mm. This arrangement
produces interference fringes visible as alternate bright and dark
spots on the circumference of the circle.
The angular separation between two consecutive bright spots is 2
~0. Which of the follow ing options is/are correct?
(A) The angular separation between two consecutive bright
spots decreases as we move from P1 to P2 along the first
quadrant
(B) A dark spot will be formed at the point P2
(C) The total number of fringes produced between P1 and P2 in the first quadrant is close to
3000
(D) At P2 the order of the fringe will be maximum
9. The polonium isotope 2: Po is unstable. It emits an a-particle w ith energy of 5.30 MeV. The
2
atomic mass of : Po is 209, 9829u and atomic mass of ~He is 4.0026 u, then choose the
correct options.
2
(A) Daughter nucleus is : Po
(B) Disintegration energy is 5.30 MeV
(C) Disintegration energy is 5.40 MeV
(D) Mass of daughter nucleus is 205.9745 u
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~~I~t~~:~~Ri~~~~~E;~i~~~~~~~~~t~~f~{;f.~ tll!~ll·. . . J
10.
out by a distance x. Ignoring the friction between the piston and

the cylinder, then choose the correct statements.
(A) If V2 = 2V1 and T2 = 3T1, then the energy stored in the spring is 1/4(pN1).
(B) If V2 = 2V1 and T2 = 3T1 , then the change in interval energy is 3pN1
. 7
(C) If V2 = 3V1 and T2 = 4T1, then the w ork done by the gas Is p1 v1
3
(D) . to the gas .IS -1 (
If V2 = 3V1 and T2 = 4T1, then the heat supplied P1V1)
4
11. A few electric field lines for a system of two charges 01 and 02
fixed at two different points on the X-axis are shown in the figure.
These lines suggest that
(A) I01I > I02I
(B) 1011< 1021
(C) at a finite distance to the left of 01, the electric field is zero
(D) at a finite distance to the right of 02, the electric field is zero
12. Specific heats of a gas varies with temperature. Now, choose the correct options, let hydrogen
gas sample is taken in observation.
3
(A) At temperature around 60 K, Cv = -R
2
5
(B) About 250 K, C v R =-
2
5
(C) About 750 K, C v = -R
2
7
(D) About 4000K, Cv =-R
2
SECTION-C
13. A binary star consists of two starts A (mass 2.2 Ms) and B (mass 11 Ms), where Ms is the mass of
the sun . They are separated by distance d and are rotating about their centre of mass, w hich is
stationary. The ratio of the total angular momentum of the binary star to the angular momentum of
star B about the centre of mass is
14. A hydrogen atom is in n = 5 state makes a transition to it's ground state. Assuming, H-atom is
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initially at rest, find the recoil speed of H-atom.
15. A 5 m long cylindrical steel wire with radius 2 x 10-3 m is suspended vertically from a rigid support
and carries a bob of mass 100 kg at the other end. Calculate the energy stored in the wire upto
two decimal places. (For the steel wire: Young's modulus= 2.1 x 1011 Pa , density= 7860 kg-m3 .
16. Degree of freedom for a gas is 6. This gas does 25 J of piston work at constant pressure. Net
heat absorbed by the gas during this process is ..... .... .
17. A thin piano-convex lens of focal length f is split into two halves. One of
the halves is shifted along the optical axis. The separation between
object and image planes is 1.8 m. The magnification of the image formed
by one of the half lens is 2. Find the separation between the halves.
1.Bm
18. A 100 kg gun fires a ball of 1 kg horizontally from a cliff of height 500 m. It falls on the ground at a
distance of 400 m from the bottom of the oliff. If recoil velocity of gun is v, then find the value of v.
(Take, g = 10 ms-2 )
Chemistry PART - 11
SECTION-A
19. Twenty molecules of SO3 will weigh as much as _ _ molecules of oxygen.

(A) 100
(B) 50
(C) 15
(D) 8
2
20. An ideal gas expands according to the law P V = constant. on expansion, the temperature
(A) decreases
(B) increases
(C) remains constant
(D) none of these
21. The enthalpy of neutralization of a strong acid by a strong base is -57.32kJ moI-1 . The enthalpy of
formation of water is -285.84 kJ moI-1 . The enthalpy of formation of equeous hydroxyl ion is
(A) + 228.52 kJ/mol
(B) -114.26kJ/mol
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(C) -228.52 kJ/mol
(D) +114.2 kJ/mol
22. Liquid ammonia ionizes to slight extent.

At-50°C, its self-ionization constant, K = [NH;J(NH2] = 10·30 M2 . How many amide ions are
present per ml of pure liquid ammonia? (NA = 6 x 1023 )
(A) 10-15
(B) 10·19
(C) 6x105
(D) 6x108
23. In the equation: 4M + 8CN" + 2H 2 O + 0 2 ➔ 4[M(CNhr + 4OH"

Identify the metal M:
(A) Iron
(B) Copper
(C) Zinc
(D) Gold
24. Which of the following complex species does not involve d2 sp 3 hybridisation?
(A) [CoF6 ]3 -
(B) [Co(N H3 ) 6 ] 3 +
(C) [Fe(CN)6 ]3 -
(D) [Cr(NH3 ) 6 ] 3+

25. Which of the following are correct methods for the preparation of propanoic acid?
(A) H C-CH = CH HBr Mg CO2
3 2 Ether > ~o >
(B) BH3 .THF KMnO4
H3C-C = CH
~O2 ,-oH
(C) HBr Mg CO 2
H2C = CH2 Ether H; o
(D) H3 C =CH= C-CH3 03
)
Ag20
26. Which of the following statement is/are incorrect?
90 H ••
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(I) (II) (Ill) (IV)
(A) I and II are aromatic and have equal basic strength
(B) I is aromatic and II is anti-aromatic but II is stronger base than I
(C) The order of basicity of the above of the above compounds is IV> Ill > II > I
(D) Ill is non-aromatic
27. Which statement is/are correct in following?

(A) Glucose does not give 2,4-DNP test.
(B) Cane sugar give non-equimolar mixture of D-(+)-glucose and D-(-)-fructose.
(C) Cellulose does not give reaction with Tollens' Reagent.
(D) Fructose is reducing sugar.
28. Which of the following oxy anion(s) contains(s) P-O bond order equal to 1.5?
(A) H2 P2 o~-
(B) H2 PO 3
(C) Hp0 4
(D) H2PO 2
29. Which of the following pairs of cations cannot be separate by using an NaOH solution?
(A) Fe3 +,Al3 +
(B) Cr3 +,Al 3 +
(C) Sn 2+ , Pb2 +
(D) Cu2+,Pb2 +
30. Mercury is a liquid at 0°C because of:

(A) very high ionisation energy
(B) weak metallic bonds
(C) high heat of hydration
(D) high heat of sublimation
SECTION-C
31. The edge length of the unit of LiCI (NaCl-like structure) is 520pm. Assuming that the lithium ion is
small enough that the chloride ions are in contact, the ionic radius of chloride ion (in pm) is
(~ =0.7J .
32. An aqueous solution contains 12% (w/w) MgSO4 and 9.5% (w/w) MgCl2. If the sulphate
dissociates up to 80%and chloride dissociates up to 60%, the boiling point of solution (in Kelvin)
is (Kb of water= 0.785 K-kg/mol)
33. The reaction 2A + B ➔ C + D goes to completion and follows the rate law
- d[A] = K[A]2[B]. The sum of values ofx and yin the following data:
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dt
Set [A 0 ] x 106 M [80 ] x 106 M Half-life(s)
'
1 300 ' I 40 62.5
2. 300 ,.f~ '-..j / 60 X
3. 5 /,·,·> "-.. . . 300 625
4. 10 I. / /1 - 300 y
34. A 5.0g sample of optically pure (+)-2-bromooctane was dissolved in 40 ml of CCl4. The
observed rotation was +2.7°, measured in a 10cm polarimeter tube.
What is the specific rotation of (+2)-2-bromooctane?
35. What is the percentage of tertiary chloride in products of the following reaction?
CH3 CH(CH3 )CH3
Assume relative rates of abstraction of primary, secondary and tertiary hydrogen to be 1:4:6.
36. Find out number of alcohols that can give positive iodoform test.
OH OH
~ OH
~ Q-J'.-cH, C;v
(a) (b) (c)
"O
HO
H3C- CH2-OH 0-CH,-OH 6

(e) (f) (g) (h)
SECTION-A
10
37 . V aueo
I f "1sc
L.i r·
3sc10_r .IS
r-1
(A) 10c
10
(B) soc10 _3sc10

40c
(C) 10
(D) 40c
10
-1
38. Letf(x)= f xsinx(1+xcosxlnx+sinx)dx

And t(%
J=:, Find value of cos(f(n))?
7t
(A)
2
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(B) re
(C) 0
(D) 1
A A A
39. Find unit vector which is orthogonal to vector 3i + 2j + 6k and is coplanar with vectors
2i + j + k and i - j + k is
2I-6}+1<
(A)
✓
41
2i -3j
(B)
✓13
3j-k
(C)
10
(D)
4i + 3}-31<
✓34
" 2r + 1
40. If S 0 =L 2 3 2, then S10 equals
r-1 r + 2r + r
(A) 1
121
(B)
120
120
(C)
121
99
(D)
100
7t
(A)
2
(B) 7[
31t
(C)
2
(D) -2n
1 cos(B-A ) cos(C-A)
42. If A, B, C are real numbers, then find value of cos ( A - B) 1 cos(C - B)
cos(A-C) cos (B-C) 1
(A) cos A+ cosB + case
(B) cosA.cosB.cosC
(C) independent of A, B, C
(D) cosA.cosC + cosBcosC + cosAcosB

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4 3 2
43. If all roots of equation 2 + az + bz + cz + d = 0 {a, b, c, d E R) are of unit modulus, then
(A) ]a] ~4
(B) ]b] ~ 4
(C) ]c] ~4
(D) ]b] ~ 6
1
44. Consider function f ( x) = ( ax+
~+2
)x where a 2
+ b2 cfc 0, then lim f ( x) is
~ m
(A) exists for all values of a and b

(B) zero for O < a b > 0
- 1 - 1
(D) e a ore b for a = b
45. If the length of tangents from A, B, C to the incircle of MBC are 4, 6, 8 then which of the following
is (are) correct ?
(A) Area of MBC is 12Js
(B) Ex-radii of MBC are in HP
(C) Sides of ~ABC are in AP
4
(D) radius of incircle of ~ABC is -Js
3
46. If f ( X) = ( sin X -1
2
r' n E N, then X = %is a point of
(A) Local maximum if n is odd
(B) Local minimum if n is odd
(C) Local maximum if n is even
(D) Local minimum if n is even
47. Let f(x) be a non-negative continuous and bounded function for all x ~ 0. If
cos xf ' ( x) ::; ( sin x - cos x) f ( x) Vx ~ 0 then which of the following is/are correct ?
(A) f(6)+f(5)>0
x - 3x + 2 + f (7) = 0 has two distinct solution
2
(B)
(C) f(5).t(7)-f(6)(5)=0
_ f ( x) - sin ( nx)
(D) hm~~-~~=1
X➔S (x-6)
48. There are 8 different lines, 7 different circles and 6 different equilateral triangles, then maximum
number of points of intersection of
(A) lines only is 28
(B) circles only is 42
(C) triangles only is 90
(D) circles and triangles any is 384
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SECTION-C
2xy - 2 ~ k ( x
2
49. If X + 2y2 - + 2y) Vx, y E R, then find the number of integer values of k ?
2
50. If solution of differential equation x 2 . d ~ + 2x. dy = 12y is y = Axm + Bx-" then find maximum
dx dx
value of Im+ nl
51. Find area of region by two branches of (y- x) 2 =x 3 and straight line x =1 ?
52.
.
Find value of
J 1 1
tan- x
1( ) dx?
0 cot- 1- x + x 2
53. TP and TQ are any two tangents to a parabola and the tangent at a third point R cuts them is
TP' TQ'
P' and Q' , then f i n d - + - - .
TP TQ
54. Rectangle ABCD has area 200 unit2. An ellipse with area 200n unit2 passes through A and C and
has foci at Band D. find perimeter of rectangle ABCD?
FIITJEE
FULL TEST - IV
JEE (Advanced)-202[
PAPER-1
ANSWERS, HINlS & SOLUTIONS
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Physics PART- I
SECTION-A
1. B
Sol. Let acceleration on inclined part (while going up as well as while going down) be a. Length of
inclined part be /1 and that of flat part be h
Total time period is given as
T~ [IF+ J;~f, +!F]x2

If /1 and fa is made 4 times, the time period doubles.
2. C
Sol. Potential at centre Ve= V0 +Vin= K Q + 0 = KQ

ro ro
Potential at centre = potential at all the points of the shell
Vp = KQ
ro
VinP + VPa = KQ ... VPin = KQ - KQ
ro ro r
3. A
Sol. Consider an elemental length dx. Velocity of the element is perpendicular to the plane of the
figure and its magnitude is
AITS-FT-IV (Paper-1 )-PCM(Sol.)-JEE(Advanced)/2021 2
v = ro(xsin8)
CD
Emf induced in the element is
ds = B( dx) sin 8 [8 is angle between dx and B]
2
= Bro sin 8xdx
: . s = Brosin2 ef xdx = ..!.srosin2 8(L2)

0 2
The free electrons experience force towards P. Hence O is positive.
4.
Sol.
For -dN to b e minimum

. . -d2N2 =
0
dt dt
2
⇒ d N = 2t - 11,(t2 - 11,N) = 0
dt2
or,
5. A
Sol. When a pressure difference P1 - P2 = ~ P is applied various height and length are as shown in the
second figure.
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Since volume of manometer liquid is constant, we have
:. 9Ah1 =Ax ⇒ x = 9h 1
h 2 = x sin 8 = 9h1 sin 8
~p = pg(h1 + h 2) [p = density of liquid]
= 0.74pwg [ ~ + xsin 8] = 0.74p,,gx [ i + sine] A P,
It is needed that when ~ P = 0.09 x 10- p.,g, value3
of x is 0.5 x 10-3 m
5 1
:. 9 x 10- x P,,9 =0.74p.,g x 5 x 10- [ i + sin8]
0.9 1 .
- - - = - + Sin 8
0.74 x 5 9
=
sin 8 0.24 - 0.11 =0.13
:. 8 = sin-1 (0.13)
6. B
Sol. In equilibrium the particle is at the lowest position . Consider the system at an angular position 8.
, = mgRsin 8"" mgR8 (for small 8)

la = ,
2 2
[ ~(2m)R + mR ] a= -mgR8
:. a =- ( ~0) :.f=
2 2
~&
fllTJH Ltd., FnTJEE Ho=-, 29-A, Kalu Sarai, San,apriya Vihar, New Delhi -110016, Ph 46106000, 2 6569493, Fax 26513 942
3 AITS-FT-IV (Paper-1 )-PCM(Sol.)-JEE(Advanced)/2021
7. B, D
Sol. Values of options (B) and (D) do not match with the mirror formula.
1 1 1
-+-=-
v u f
8.
Sol.
"- = 600 nm
AtP1 , M=O
At P2, M = 1.8 mm = n ')..,
Number of maxi mas will be
n = L'1x = 1.8 mm= 3000
'A 600 nm
At P2, M = 3000')..,
Hence, bright fringe will be formed
At P2, 300oth maxima is formed
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For option (a),
M = dsin0
dl'1x = dcos0d0
R'A = dcos0Rd0
⇒ Rd0 = RA
dcos0
As, we move from P1 to P2
0 t cos 0 .,1.. Rd0 t
9. A , C, D
Sol.
2
: Po ➔ ~He+ ~:x
So, daughter nucleus is ~ X
Disintegration energy is
Q = ~ X KE
A-4 °
210
=(
210-4
)x
5.30 = 5.40 MeV
Mass equivalence of disintegration energy is

5
M0 = .40 = 0.0058 u
931
So, mass of daughter nucleus is
=mPo -m.,_ -m0
= 209.9829-4.0026 -0.0058 = 205.9745 u
10. A, B
Sol. This question can be solved , if right hand side chamber is assumed open, so that its pressure
remains constant even, if the piston shifts towards right.
Po
I•··~I 2-
Po.P,
p
I«
pV= nRT
T
⇒ poc-
V
Temperature is made three times and volume is doubled,
3
P2 = P1
2
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Energy of spring,
~kx2 = P1V1
2 4
Also, 11U = nCvi1T
= p 1V1 x ~R x (3T1 -T1 )=3p 1V1

RT1 2
11. B, C
Sol. From the behaviour of electric lines, we can say that 01 is positive and 02 is negative
Further, I0 I> I0 I
1 2
At some finite distance to the right of 02, electric field will be zero. Because electric field due to 01
is towards right (away from 01) and due to 02 is towards left (towards 02). But since magnitude of
01 is more, the two fields may cancel each other, because distance of that point from 0 1 will also
be more.
12. A , B,C,D
Sol. At low temperature (60 K), the hydrogen molecule has only translator motion, therefore it has only
3 degrees of freedom.
So, for 1 mole of gas,
U=~N k T=~RT
2 A B 2
3
⇒ Cv = R at 60K
2
At temperatures above 60 K, i.e. between 250 K to 750 K, molecule of hydrogen began to rotate
and behaves like a dumb-bell. It has now 5 degrees of freedom.
So, U=~N k T=~RT

2 A B 2
5
or Cv = -R, at 250 to 750 K
2
At temperature around 4000 K, the molecular collisions are so vigorous that the atoms begins to
vibrate and the molecules now have 7 degrees of freedom.
Cv = ?__ R at 4000K
2
SECTION-C
13. 00006.00
Sol. L1o1a1 - (IA+ Is )w = mAr; + 1 = J_!_ + 1 = 6

L8 18 .W m8 r; 2.2
14. 00004.20
Sol. When an excited atom emits a photon of momentum p, conservation of momentum requires that
atom recoil with same momentum p.
For emitted photon ,
he
~E=-=pe
A
he
-=P
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A
Here, ~E = E5 - E,
= ( - 1i;6 ) - ( -1~.6)
24
=13.6 x x1.6 x 10-19 J
25
Momentum of photon,
13.6 X24 X1.6 X10-19
P=--------
25 x 3 x 100
= 6.96 X 1 o-21 kg ms-1
So, recoil speed of H-atom is
p = 7 X10-27 = 4.20 ms-1
m 1.67 X1 Q-27
15. 00000.95
Sol. U= ~(Mg)(~ 1)(n:r I) = 0.95 J

2
2
2 nr I
16. 00075.00
Sol. Work done at constant pressure is
~w = ( 1-n X~Qtotal
⇒ 25 = ( 1- n ~Qtolal
2 2
But, r=1 + -=1 + -
f 6
4
or r=-
3
So, 25 = ( 1-¾) X ~Q total
or ~Qtotal = 100 J
So, net heat absorbed by the gas = 100 - 25 =75 J
17. 00000.60
Sol. l~I = 2 or lul = 2lul
When u = -x, then v = + 2x and lxl + lvl = 1.8m

⇒ 3x = 1.8m or x = 0.60 m
18. 00000.40
Sol. H = _!_gf
2
1 2
⇒ 500 = -x 10 x t
2
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⇒ t = 10s
Also, R = ut
R
⇒ u =- =40 ms-2
t
I• R •I
If recoil velocity of gun is v, then
m1v = m2 u
or v = 100 x 40 = 0 .4 ms-1
Chemistry PART- II
SECTION-A
19. B
Sol. 80 x 20 = 32 x n
⇒n =50
20. B
2
Sol. P V = constant
p ex: -T
V
T2
⇒- x
2 V = constant
V
T2
⇒- = constant
V
21. C
Sol. W(aq)+ OW(aq) ~ H2 O(aq)
L'1H1 of W(aq) = 0
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22. C
Sol. [NH2] = 10-15
= 10-15 mol/l
=6 x 1023 x 10-15 ions per ml
⇒ 6 x 1023 x 10-15 x 10-3 ions per ml
23. D
Sol. Factual
24. A
Sol. ( F-1 is a weak field ligand)
25. B, C
Sol. Br
HBr ~ Mg
ether
COOH
_/
26. A, B
Sol. Factual
27. A, C, D
Sol. Factual
28. A, B, C, D
Sol. Factual (from structure)
29. B, C
Sol. Factual
30. A, B
Sol. Factual
SECTION-C
31. 00182.00
Sol. 2(rLi + rc 1) = .f2. x 520
and 2rc1 = 520
32. 00377.00
Sol. X = molarity of MgSQ4 = -12 1000
x ---
100 MMgS04
95
Y = Molarity of MgCl2 = · x 1000
100 MMgCl2
Total molarity of ions
= 1.8x + 2.2y
delta Tb = Kd(1 .8x + 2.2y)
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33.
Sol.
00375.00
Reaction is first order w .r.t. B, so half life is constant if B is changed
Reaction is second order w .r.t. A so half life becomes half on double cone. of A
312.5 + 62.5 = 375
34. 00021 .60

Sol. The specific rotation of (+2)-2-bromooctane is
[a ]= 5 2.7 =21_6o
9 - x 1dm
--
40ml
35. 00040.00
Sol. Ratio of 3° : 1° chloride
=6 x 1:9 x 1
o/o Of 3o = 6 X 100 = 40 %
6 +9
36. 00004.00
Sol. (b), (c), (e) and (h)
SECTION-A
37. B
10
Sol. " 1 s c 35c = 1sc 35c + 1sc 35c + + + 1sc 35c
L.J r· 10-r 1· 9 2· 8 10· O
r-1
=soc _35c
10 10
38. B
Sol. f
f(x) = xsinx (1 + x.cosx.lnx + sinx)dx
If f ( X) = xsinx = esinx.lnx' then
f(x) = f(t(x) + xf '(x))dx = x.xsinx + c
t(%) =% -(%} +c ⇒ c=O

f (x) = (x)(xt"x, f ( 1t) = 1t
39. C
Sol. Let a= 3i + 2} + 61<, b = 2i + 1+ k and C= i - 1+ k
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Then by definition, a vector orthogonal to a and coplanar to band c is ax(6 xc)
_ _ ax(b xc) 3}-1<
.-. Required unit vectors =I _ I = -- .
ax (bx c) 1o
41. B
Sol. cos-1 (2x2 - 1) = 2rc -2cos-1 x (x < 0)
.-. cos-1 ( 2x 2 -1)-2sin-1 x = 21t-2cos-1 x -2sin-1 x
= 21t-1t = 7t
42. C
1 cos(B-A) cos(C-A) cosA sinA 0 cosA sin A 0
Sol. cos(A-B) 1 cos(C-B) = cosB sinB 0 X cosB sinB 0 =0
cos(A-C) cos(B-C) 1 cosC sinC 0 cosC sinC 0
AITS-FT-IV (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021 10
43. A, C, D
4 3 2
Sol. az + bz + cz +dz+ e = 0 (a, b, c, d E R)
Let roots of z1 , z2, Z3, Z4
]21] = ]22] = ]23] = ]24] = 1
21 +22 +23 +24 =-a :. ]a] ~4
~~+~~+~~+~~+~~+~~=~
2 12 2 2 3 + 2 12 2 2 4 + 2 12 3 2 4 + 2 22 3 2 4 = -C,
44. B, C, D
. ax + 1 x . x1
a+- ]x (a Jx
Sol. I
x~
( bx + 2
1
J = x~ [ b+~ = b
If O< ~ < 1, then ( ~

:. lim f(x)=O for O< a 
If ~ > 1 then ( ~ = oo
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: . lim f ( x) is non-existent for a > b > 0
X-+«>
lim-=!..
lim ~ x-+oo a+~
If a = b, lim f ( X) = eX➔~ax+ 2 or e x
X ➔«>
1 1
-~ -~
=e 8
Ore b
45. B, C, D
Sol. Sides are 14, 12, 10, AreaofMBC= ✓18.4.6.16
= 24,Js
⇒ sides of ~are in AP
:. ex-radii are in HP
/J. 24,Js 4-Js
r=-=--=--
S 18 3
46. A, D
Sol.
2
f ( X) = ( sin X -1 r, %J f( = 0
i( ~ )=(0 )". 1(r)=(O )"

7t . . ..
Then x = - 1s point of minima
2
If n is odd, f [ %+) and f [ %-) < 0, then x = %is point of maxima

47. B,C
Sol. Let G(x) = ex_cosx.f (x)
G'( x) = ex .cosx.f '( x) + ex ( cosx-sinx)f ( x)
= ex ( cosx.f '(x) + ( cosx-sinx)f (x))::; 0
As given that cos xf ' ( x) ::; ( sin x - cos x) f ( x)
G(x) is non-increasing function
.-. G(6)=e6 cos6f(6):-=:;0
_-_ f(6) :-=:; 0
But it is given that f(x) is non-negative
.-. f(6) = 0, Similarly f(5) = 0, f(7) = 0
Thus x - 3x + 2 + f (7) = 0 has two distinct solutions
2
lim f(x)-sin(rcx) =lim f'(x)-rcsin(rcx) =f'(S)- rc< O

X➔6 X - 6 X➔6 1
48. A, B, C, D
Sol. Line and line = 8 C2 ( 1) = 28
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7
Circle and circle= C2 (2) = 42
Triangle and triangle= 6 C 2 .6 = 90
Circle and circle + triangle and triangle
Circle and triangle= 42 + 90 + 6 C,.7 C1 .6 = 384
SECTION-C
49. 00000.00
Sol. x 2 - ( 2y + k) x + 2y2 - 2ky - 2 ~ 0 \ix E R
D:-::;O
( 2 y + k )2 - 4 ( 2y 2
- 2ky - 2) :-::; 0
⇒ 4y + 4ky + k 2 -8y2 + 2ky + 8 :-::; 0

2
⇒ -4y2+12kxy+k + 8 :-::; 0 'v'y E R

2
⇒ 4y 2 -12kxy-(k 2 +8) ~ 0'v'yER

⇒ D :-::; 0 ⇒ 144k2 + 16 ( k 2 + 8) :-::; 0
kE 
50. 00007.00
Sol. y = Axm + s-n .-. dy = A.m.xm-1 - n.Bx"-1
dx
d2 2 2
dx; =Am(m-1)xm- +n(n+1)Bx"-
2
Put these values in x
2
. ---4
d
dx
d
+ 2x _J_ = 12y
dx
m = 3, - 4, n = 4, - 3
:. max value of (m + n) = 7
51. 00000.80
Sol. ( y - X )2 = X3 , X ~ 0 X + X 312 =y
⇒ y = X ± X3/ 2
Required area
1 4
= f( (x + x 312
)- ( x- x
312
)) dx = - sq.unit
0 5
y =X - X 3/2
52. 00000.50
Sol. 1= f 1
tan- x dx = f 1
tan- x
_ 1( ( 1- x) + x J 1 1
O tan- ( 1- x) + tan- x
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0
tan
1-(1-x)x
1 1
tan- (1-x)
I= f - - - - --dx
tan-1( x) + tan-1( 1- x)
0
1= ! = 0.5
2
53. 00001.00
Sol. Let parabola be y 2 = 4ax and P (at~ , 2at 2 ) and Q (at; , 2at 2 ) , T be the point of intersection of
tangent at t1 and 12
= T(at1t 2 , a(t1 +t2 ))
P' = (at3 t,, a ( t3 + t1))
Q' = ( at2 t 3 ,a (t2 + t 3 ))
= ~ ⇒ A = t3 - t2
1
TP
TP 1 t1 - t 2
. ·1 I TQ' t1 -t3
S1m1ary - = --
TQ t1 -t2
TP' TQ'
.'.-+ -=1
TP TQ
54. 00080.00
Sol. Let sides of rectangle be p and q
pq = 200
2 2
Let an of ellipse be x 2 + ~ = 1 with eccentricity e
a b
rcab = 200rc ⇒ ab = 200
BO= ✓P2 + q2
p2 + q2 = 4a2e2 (distance between foci= 2ae)
22
(p + q)2 -2qp=4 (a b ) ... (1)
Since sum of distance of any point an ellipse from both foci is equal to length of major axis
:. p + q = 29
Equation (1) becomes
4a2 - 2pq = 4a2 - 4b2, : . 4b2 = 400
b = 10
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FIITJEE
FULL TEST - IV
JEE (Advanced)-2021
PAPER-2
TEST DATE: 18-01-2021

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Section-A {01 - 06, 19 - 24, 37- 42) this section contains 18 multiple choice questions.
correct answer(s).
a correct option;
Negative Marks: - 2 In all other cases
Section-8 {07 - 12, 25 - 30, 43- 48) contains 18 Numerical based questions with Single digit
Section-C {13 - 18, 31 - 36, 49- 54) contains 18 Numerical answer type questions with answer
Physics PART - 1
SECTION-A
1. A fine capillary tube of radius r dipped in a beaker containing water. The water
rises in capillary upto height h. Let e = angle of contact and p = density of
water. Now, choose the correct options.
2
(A) Mass of liquid in capillary tube is 1tr hp
(B) Mass of liquid in capillary tube is rcr

2
( h+ i) p
(C)
.
Surface tension of water Is
. T
= -hrpg
--
2 cos 0
(D) Surface tension of water in glass capillary is approximately T =

r h +- pg
3 ( r)
2
2. To study a relation of frequency and length of a given wire under constant tension using a
sonometer, let you are performing an experiment in your school lab.
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Now, choose the correct options.
(A) Tuning fork of known frequency is touched to wire for observing resonance
(B) Vibrations of wire are observed by paper riders
--✓( I
(C) Frequency of vibration of wire is f =
1
LD
T
rep)
(where, L = length of wire between
bridges, D = diameter and p = density of wire)

(D) Frequency of tuning forks remains constant with temperature of lab
3. A cylindrical shaped wooden having mass m is floating inside a liquid with its axis is parallel to the
vertical. The mass in depressed a little by a force and then force is removed, then
(A) mass will execute SHM with time period inversely proportional to radius of cylinder
rcr2 .Jg
(B) mass will execute SHM with time period - -
2m
(C) mass will not execute SHM
. frequency - 1 ✓rcr
- gp
2
(D)
. execute SHM with
mass will -
2rc m
4. For the given figure, two blocks of equal mass m are connected by a light string
that passes over a smooth pulley. The block A is connected by spring constant k.
Initially spring is relaxed. Then, the block A is slowly pulled down a distance x and
released. The magnitude of accelerations of the left and the right blocks
immediately after releasing are a1 and a2, respectively.
(A) a1 = a2
(B) a1 =a2 ,1·t k :-;:;--

2mg
x
k
(C) If a1 = - X, a2 = 0
m
(D) a1 < a 2 , ·t1 k > -

2mg
-
x
5. A block is connected to a spring in an elevator. Elongation in spring is x 1 = 4✓2 mm and
x2 = 3✓2 mm, w hen it moves up and down w ith constant acceleration, respectively. Then,
(A) acceleration of elevator is ~ m/s 2

7
(B) acceleration of elevator is ~ m/s 2
3
(C) if same elevator moves horizontally w ith same acceleration, then elongation w ill be 5 mm
(D) if same elevator moves horizontally w ith same acceleration, then elongation will be
10 mm
6. A partition divides a container having insulated walls into two
compartments I and II. The same gas fills the two compartments, w hose p, V. T 2p, 2V. T
initial parameters are given. The partition is a conduction wall , w hich can I •
move freely w ithout friction. Which of the follow ing stateme nts is/are
correct with reference to the final equilibrium position?
(A) The final pressure in the two compartments are equal
3V
(B) Volume of compartment I is -
5
. 12V
(C) Volume of compartment II 1s - -
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5
(D) Final pressure in compartment I is Sp

3
SECTION-B
7. T wo moles of a monoatomic ideal gas is taken through a cyclic

process show n in p-T diagram. The process CA is represented as
3
pT = constant. If efficiency of cycle is 1- n \ , then find
121 2 15
the value of x.
8. A short semi-circular right cylinder of radius r and weight w put on a

horizontal s urface and is pulled by a horizontal force P applied at the
point B of the front edge. The flat face make angle 8 with the horizontal
plane just before sliding begins and coefficient of friction at the line of
contact w ith surface isµ. Find the value of 7sin8, if µ is 1/n:.
9. A shaft of diameter D is resting on a support as show n in the figure. The

shaft exerts a total axial force F. Assuming the coefficient of friction is µ ,
the twisting moment M necessary to cause rotary motion to impend is µ
FD/N. Find the value of N.
ll
10. A photoelectric plate is initially exposed to a spectrum of hydrogen gas excited to second energy
level. Later when the same photoelectric plate is exposed to radiation from some unknow n
hydrogen like gas, excited to second energy level, it is found that the de-Broglie wavelength of
the photoelectrons, now ejected has decreased ✓ G:i times. For this new gas difference of
energies of first Lyman series and Balmer series, limit is found to be two times, the ionisation
potential of the hydrogen atom. Find the value of Z for unknown gas.
11. In a modified YDSE, the source S of wavelength 5000A oscillates y
about axis of set up according to the equation, y = 0.5 sin ( i}, s d • 1mm
s, · ··--···· ··· · · · · p
IC
where y is in millimetre and t in second. At what time t will the
S2
intensity at P, a point exactly in front of slit S1, be maximum for the l-1m 0 • 2m
first time?
12. A certain quantity of ideal gas takes up 56 J of heat in the process AB

"4A, C
and 360 J in the process AC. What is the number of degree of freedom
of the gas? p ~
Po-~. 8
: I V
Vo 3Vo 4Vo
SECTION-C
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CD
13. A uniformly charged thin spherical shell of radius R carries uniform

surface charge density 6 per unit area. It is made of two hemispherical :
shells, held together by pressing them with force F. The value of F will F- ! -F
be (Take, ncr2 R 2 = 4i;o)
14. A police car B is chasing a culprit's car A. Car A and Bare moving at constant speed V1 = 108
km/hr and V2 = 90 km/hr respectively along a straight line. The police decide to open fire and a
policeman starts firing with his machine gun directly aiming at car A. The bullet has a velocity
u = 305 m/s relative to the gun. The policeman keep firing for an interval of To = 20 s. The Culprit
~xperiences that the time gap between the first and the last hitting his car is L'1t is
B ~v.I A ~v.
.jillap 1
1
15. A light cylindrical tube of length L = 1.5 m and radius r = ✓nm is Block
open at one end . The tube containing air is inverted and pushed
Air
inside water as shown in figure. A block made of material of relative
density 2 has been placed on the flat upper surface of the tube and
the whole system is in equilibrium. Neglect the weight of air inside
the tube the volume of block placed on the tube is
16. A transverse harmonic wave of amplitude 4 mm and wavelength 1.5 mis travelling in positive x
direction and at x = 1.0 m is at y = + 2 mm and is travelling in positive y direction, then x-
coordinate of the nearest particle (x > 1.0 m) which is at its positive extreme at this instant is
17. Find charge supplied by the cell after the switch is closed (in µC)
a
18. Sunray pass through a pinhole in the roof of a hut and produce an elliptical spot the floor. The
minor and major axes of the spot are 6 cm and 12 cm respectively. The angle subtended by the
diameter of the sun at our eye is 0.5°. Height of the roof in meters is
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Chemistry PART - 11
SECTION-A
19. Select correct statements regarding a and n-bonds:

(A) a-bond lies on the line joining the nuclei of bonded atoms
(B) n-electron cloud lies on either side to the line joining the nuclei of bonded atoms
(C) (2pn-3dn) Pi-bond is stronger than (2pn-3pn) Pi-bond
(D) a-bond has primary effect to decide direction of covalent bond, which n-bond has no
primary effect in direction of bond.
20. Complex compound [Co[SCN)z(NH3 )4 )CI exhibits:

(A) Ionization isomerism
(B) Geometrical isomerism
(C) Optical isomerism
(D) Linkage isomerism
21. Which of the following metal(s) is/are commercially extracted by self reduction method from their
corresponding ore?
(A) Cu
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(B) Fe
(C) Pb
(D) Hg
22.
23. Which of the following compounds are formed by the oxidation of

CH3
I
CH3 -C-CH-CH2
I I I
OH OH OH
with HIO4
(A) CH3 -CHO

(B) CH3 COCH3
(C) H-COOH
(D) HCHO
24. C6 H5 - CH2 -1-N-:~

N:i~ Products
Reaction is assumed to involve nitrene as intermediate, then various possible product are:
(A) C 6 H5 CH2 NH2
(B) C 6 H5 N = CH2
(C) C 6 H5 CH = NH2
(D) ~N
HCH5C6____11
N
SECTION-B
25. Calculate sum of bond order between same bonded atoms in Q and R compounds.
Water
P+Q
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0° C
Na2 O 2
~ Water
25° C
P + R t +S
26. Calculate value of Ix + y - zl for the following silicate [SixOy+zlz- anion.
I \
I , \
,' '
27. How many stereoisomers does the following complex have?
[FeF2Cl2Br2]3+
28. A hydrocarbon CxH12 (g) and 0 2(9) w ere taken in a closed flask at 400K. When sparked they
reacted to form CO2(g) and H2O(g) and no reactants left after the reaction. The pressure in the
flask is increased by 20%. The value of 'x' is
29. Among the following the total number of compound w hich give positive iodoform test is:
H3C- r - C H3
OH
H3C- CH2- CH2- 0H H3C-CH2- 0 H. TI
H3c -C - -CH3
. zy
~
0
g -CH3
30. Examine the structural formulas shown below and identify how many compounds will show
coupling reaction with diazonium salts faster than anisole (Ph - 0- CH3 )
..
Cl
SECTION-C
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31. A transition metal X forms an oxide of formula X203. It is found that only 50% of X atoms in this
compound are in the +3+ oxidation state. The only other stable oxidation states of X are +2 and
+5. What percentage of X atoms is in the +2 oxidation state in this compound?
32. One mole of an non-ideal gas undergoes a change of state from (2.0atm, 3.0 L, 95K) to (4.0 atm,
5.0L, 245 K) with a change in internal energy, ~U = 30.0L atm. The enthalpy change (~H) of the
process in L-atm is
33. A container of capacity V L contains an equilibrium mixture that consists of 2 moles each of
PCl5 ,PCl3 and Clz (all as gases) The pressure is 30.3975 kPa and temperature is TK. A certain
amount ('x' mole) of Clz() is now introduced keeping the pressure and temperature constant, until
the equilibrium volume becomes 2V L. the value of '90x' is
34. The specific conductivity of a saturated solution of AgCI is 2.80x 104 mho m-1 at 25°C. If
A.~ • =6.19 x 10-3 mho m 2 moI-1 and A~i- = 7.81 mhom 2 moi-1, the solubility of silver chloride
9
(in order of 10-5 g 1-1) at 25°C, is
35. Vapoure pressure of solution containing 6g of a non-volatile solute in 180g water is 20 torr. If
1 mole of water is further added, vapour pressure increases by 0.02 torr. The molar mass (in
g/mol) of the non-volatile solute is
36. For a gaseous reaction at 300K, ~H - ~U = -49.8kJ, assuming that R = 8.3 JK-1 moI-1 , Mg is
SECTION-A
1</2 1</2 1</2
37. Suppose 11 = f cos ( re sin 2

x )dx, 12 = f cos(2n sin 2
x )dx, 13 = f cos(n sin x) dx then
0 0 0
(A) 11 =0
(B) 11 + 13 =0
(C) 11 + 12 + 13 = 0
(D) 12 = 13
38. The equations of line(s) through (2, 3) from which the circle x2 + y2 = 25 intercept a chord of
length 8 unit is/are?
(A) X= 2
(B) y=3
(C) 9x+ 11y-51 =O
(D) 12x + 5y- 39 = 0
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39. If y = log7 (log7 x), then dy equal
dx
log7 e
(A)
xloge X
1
(B)
X loge X loge 7
1
(C)
40.
(D)
loge (7xf
log7 e.logx e
X
.
A curve y = f(x) has the property that the perpendicular distance of the origin from the normal at
any point P of cone is equal to the distance of point P from x-axis. Then the differential equation
of curve is
(A) Homogenous
(B) Can be converted into linear differential equation with some suitable substitutes
(C) Is the family of circles touching the x-axis at origin
(D) Family of circles touching y-axis at origin
2 2
41. If fxlog(1+x )dx=~(x).1n(1+x )+'1'(x)+c then
(A) <P ( X) = 1+ X2
2
(8) 'l' ( X) = X2 + 1
2
x2 + 1
(C) 'l'(x)=--
2
2
x +1
(D) 'l'(x)=--
3
x2 Y2
42. Equation(s) of tangent(s) to hyperbole - =1 at point(s), where it intersect the parabola,
4 3
9
y2 =- x are
4
(A) x-y + 1 = 0
(B) x-y-1 = 0
{C) X + y-1 = 0
(D) x+y+1=0
SECTION-B
43. If the value of L

5 ( 1 ) , where x2 + x + 1 = 0
xr +,
r-1 X
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44. Number of points, where f(x) = maximum f ( x) {sgn (x), -✓9 - x2 , x3 } is continuous but not
differentiable
· · f . X y z-1 _
45. The distance of point (1, -2, 3) ram plane x -y + z= 5 measured parallel to line - =- = - - Is
2 3 -6
46. If f(x) = [ gx _ 3x + 1] Vx E ( ~ , 1) ([.] denotes the greatest integer function) then number of
elements in range of f(X) are
8 1
47. An artillery target may be either at point I with probability - or at point II with probability -. we
9 9
have 21 shells each of which can be fired either at point I or II. Each shell may hit the target
. . .. 1 . .
independently of the other shell with probability - . If a, shells must be fired at point I to hit the
2
a,
target with maximum probability, than - equals
2
48. The area bounded by curve y = x + sin x and its inverse function between the ordinates x = 0 and
x = 2n is 4a find a ?
SECTION-C
49. If AM, GM, HM of first and last term of series 100, 101 , 102, .... n - 2, n -1 , n are the terms of
series itself (100 < n ~ 500). Find n? (AM, GM, HM indicates Arithmetic mean, Geometric Mean,
Harmonic Mean respectively)
50. How many 4 letter words can be made using letter of word TATTERS ?
-5 3+5i ~-4i
2
51. Find imaginary port of 3-5i 8 4+5i
3 4·I 4-5i
-+ 9
2
52. Iflal = lbl = lei = 2 ard a.b = b.c = c.a = 2

Then [ abc] cos 45° equals
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53. The curve y = ax 3 + bx2 + ex + 5 touches x-axis at point P(-2, 0_) and cuts y-axis at a point Q
w here its gradient is 3 find le - a - bl ?
54. n]If sin30 + cos20 = 0 for 0 = [ 0,

3
2
Number of value of 0 can be
FIITJEE
FULL TEST - IV
JEE (Advanced)-2021
PAPER-2
TEST DATE: 18-01-2021
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Physics
SECTION-A
1. B, C, D
Sol.
,
Volume of liquid upto lower level of meniscus = nr2 h
•..••.......•.•...•••••
-----------········-----
-•·•·••·--------------
···········--··--···---
Volume of liquid above meniscus = Volume of cylinder of radius r and height r - Volume of
. . 2 3 1 3
hemisphere of radius r = 1tr3 - - 1tr = - 1tr
3 3
So, total volume of liquid in capillary = i
nr2h + nr3 = nr2 ( h + f)
For equilibrium, weight of liquid = Upward force of surface tension
= nr
2
( h+ f)
= 2nrT cos 8
Toose Tcose
T
Tsin8
⇒ h = 2T cos 0 _ _!_
rpg 3
If we neglect _!_ in comparison to h, then

3
T = hrpg
2cos0
or
T= r(h +½)pg
2cos0
For water and glass, 0 is very small
0 ~0°
T= r(h +½) pg
2
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2.
Sol.
B, C
For observing resonance paper riders are used and vibrating tuning fork is touched to sonometer
box (not with wire). When temperature increases length of prongs of tuning fork increases and
thus frequency decreases
3. A, D
Sol. Let length I of the cylinder is dipped in liquid, the weight of liquid displaced by the volume of I-part
of cylinder
nr 2 I pg = W ... (i)
where, p = density of the liquid when cylinder is further dipped through a distance x, then volume
of displaced [liquid rcr2(1 + x)]
3 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021
Therefore, vertically upward force, (i.e. force of buoyance) acting on mass equals nt2(1 + x)pg.
At situation of equilibrium, net force on the mass
F=W-nr2 (l + x)pg
= W - nr2 lpg-nr 2 pxg . ..(ii)
From equations (i) and (ii), we get
2
F = -nr pgx = -kx
2
R = nr pg
The time period, T = 2n)¥

= 2nJnr~pg
:. Frequency of oscillations,
v = _!_ = _1 ✓nr gp
2
T m 2n
4. C, D
Sol. If mg ~ kx - mg
When spring is taut, the acceleration of each block are same
If a 2 =0,T =mg
T + kx-mg kx
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.-. a1= =
m m
If mg < kx - mg, string slacks
kx-mg
and a=---
1 m
and a2 = g
5. A, C
Sol. For upward moving elevator,
kx1 -mg =ma . ..(i)
mg
For downward moving elevator,
mg - kx 2 = ma ... (ii)
mg
Dividing Eq. (i) by Eq. (ii), we get
g+a X1 4✓2.
g- a - X: - 3✓2
a=~
7
For horizontal motion of elevator, spring will be inclined at some angle as given in figure.
locscose
me
mg
kx 3 cos 0 = mg ... (iii)

kx 3 sin 0 = ma ... (iv)
Squaring and adding Eqs. (iii) and (iv), we get
(kx3)2 = m2(g2 + a2)
X3 = ~ ✓92 + a2 ... (v)
From Eqs. (i) and (v), we get
~= ✓92 +a2
x1 g+a
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= [✓gg+a
2
+a J
2
X
3
Hence, X3 = 5 mm
6. A, B, C, D
Sol. At final equilibrium, force must be equal from two side, so
P,,A
I
p~A = Pi:,A ⇒ p~ = Pi:,

In final condition, final temperature will also be same, because separator is conducting.
Conservation of moles in I and II components gives

pV = p1 (V1 )
... (i)
RT RT
2p(2V) p1V2
... (ii)
RT RT
V = 4pV ...(iii)
2
Pt
v +v 1 2 =3V
pV + 4pV = 3 V
Pt Pt
pV x 5 = 3V ⇒ p = Sp
Pt t 3
So,
SECTION-8
7. 7
Sol. Find the network done for the process, then find heat supplied. By this you can find the value x
with the help of efficiency formula.
. . Total work done
EffIcIency = - - - - - - -
Total heat supplied
W As = p(~ V)= nR~T (isochoric process)
25
=2 X X 3QQ = 5QQQ J
3
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1
W sc = nRT In ( :, ) = n RT In ( : :) (isothermal process)
as) = 2 x R x 6001n (
2 1
x
1 X 1 Qs
= 1200 R In (2)
j
l
pT = k
W _ nr.~T = -2R x 300
p2 V =K
CA - 2- y 1-..!.
pxv =K
112
2
=-1200 R
W = 600R + 1200R ln(2)-1200R
W = 600R[2In(2) -1]
Heat supplied,
QAB = nC
p
~T = 2 x SR
2
x 300 = 1S00R
Q sc = W sc = 1200Rln(2)
600R[2In(2)-1] 12In(2)-6
11
= 1S00R + 1200Rln(2) = 15 + 12In(2)
-1 - 21
17
- 15 + 12In(2)
=1- 3x7
15 + 12In(2)
:. X =7
8. 3
Sol. In this problem, concept of friction as well as the concept of torque will be used. For the
equilibrium, resultant force w ill be zero. We well also balance the torque for the equilibrium.
IF=O
fa= O
Under equilibrium,
I FH= 0 = P - µN = 0 ⇒ P = µN
I FV= 0 = N - W = 0 ⇒ N = W
p = JJ-W
w
Moment about contact point A,
P(AD) = W(GD)
P(OA- OD) = W (GD)
. p
s1n8 = W ... (ii)
4
P+-
3 n:
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Substituting, P = µw from Eq. (i)
. µW
s1n8 = W
4
µW + -
3n:
3
sin8 = µn
3µn:+ 4
8 = sin-1 3 µn
⇒
3µn:+ 4
7sin8 = 3
9. 3
Sol. Consider a small element of radius r and width dr.
F
F
Normal reaction, dF = - - x 2rcrdr
~D2
4
Frictional force, dF1 = µdF

Frictional moment, dM = rdF1 = rµdF
Total moment,
D/2 4F
M=
f dM = J rµ x -nD- x 2nrdr
o 2
= 4F X µ X 21t X (D / 2)3
nD2 3
M = µFD ⇒N=3
3
10. 2
Sol.
Wo .-
- - - - • K, E,
We t-eveE1 = W0 + KE, ...(I)
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... (iv)
Now, ionisation energy of H-atoms,
= - E1 = 13.6 eV energy of first line in Lyman series= 13.622 (J_f _J_)

2
ev
2
=10.2Z2 ev
1
and energy of series limit of Balmer series = 13.6 x 2 2 ( J_ - - - } eV = 3.4Z 2eV
2 2 r:xl
2 2
Given, 13.6 X 2 = 10.2 Z -3.4 Z
⇒ Z=2 ⇒ He+ ion
11. 1
Sol. For constructive interference, intensity (I) is maximum ,
When COS<p = +1
The path difference at point P,
LlX = (SS2 - ss1) + (S2P - S1P)
dy d(d / 2)
=-+---
D1 D2
For constructive interference,
dy d2
11X = - + - = n11,
D 1 2D2
3 3 3
(1O- )(O.5sinnt) x 10- + (10- )2 =n11,
1 2x2
0.5sin ( ~ } x 10--6 + 0.25 x 10--6
= (5000 x 10-10 )n = 0.5 x 10--6n
. ( n: j t =
Sin -
0.5n-0.25
----
6 0.5
For the minimum value oft, n = 1
sin ( ~ } = ~ ⇒ ( ~} = ~
or t = 1s
12.
Sol.
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11QAC = 11U + 11W
nR 1
=--i1T + - x 3Vo[Po + 4Pol
y -1 2
[16p0V0 - PoV0] 15p0V0
=-- ---- + ---
y -1 2
y
56=2pOVOx - -
y -1
360 = 15p0V0 lY+

1
2(y -1)
j
360 - ~ (y+ 1)
56 - 4. y
7 2
12y = ?y + 7, y = 5 = 1+ f
⇒ t= 5
SECTION-C
13. 00002.00
Sol. For the given area total force will be u dA
When dA is the area, then electrical force per unit area
= ~EoE2 = ~E□[ 2~J2 = 2::0

Projection area = nr 2
⇒ Net electrical force = ( 2sr:l ) (nR 2

)
In equilibrium, this force should be equal to the applied force,

F = a 2R2 = 4so = 2
2s0 2E0
14.
Sol.
00023.33
8
4ililP _.
---+ v•• 25 ""-
X
.v. . . .
Let x = distance between the car at the instant first bullet is fired (sat at time t = 0)
Speed of bullet, relative to ground is
Vb = u + V2 = 305+25 = 330 m/s
Velocity of bullet, relative to car A is
VbA = 330 - 30 = 330 m/s
: . Time w hen the first bullet hits the car a is
t1 = ~ = ~ . .. (i)
VbA 300
Distance between the car w hen the last bullet is fired (at time t =TO =20 s) is
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1
X = X + VABTo = X + 5 X 20 = X + 100
Time when the last bullet hits the car A is
X
t2 =To+ -
VbA
= 2 0 + X + 100 ... (ii)
300
The interval L'1t = h - t1
= 20 + 1 OO = 23.33sec.
30
15. 00000.75
Sol. Consider the tube + liquid inside it + Block as our system.
For equilibrium
Weight = Buoyancy
2 2
2p,,,vg + nr .~p,,,Q = [ v + nr ~ ] P,,,9
Solving, v = 0.75 m3
16. 00002.25
Sol. - y
We have to find x co-ordinate of particle B. Phase difference between A and B is

= 51t ⇒ 21t(.!1X)= 51t
3 11, 3
5 15
A~=
tiA x · =1 .25m·, :. X 8 = 2 .25 m
6
17. 00016.80
Sol. The potential difference across 1 µF and 2 µF (uppermost) capacitor ♦ -
must sum up to
.9_ + q / 2 = 6 ⇒ q = 24 µC
1 2 5
24
Answer is 12 + = 16.8µC
5
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2µf
18. 00003.44
Sol. The cone of rays passing through the hole at A produce an elliptical spot on the floor.
The circular base having diameter BO w ill get projected on the floor as an ellipse.
CB = major axis = 12 cm
DB = Minor axis = 6 cm
DB= AB(0}= ~ ⇒ h = (6 cm ) sin<!>

s1n<1> 0
. DB 6 1
But s1n<1>=- = - = -
CB 12 2
h = (6 cm)
2x0
= cm-X -
3- 180
-
0.5 x n
lo
. 50 =---ra
0.5 X 7[ d'1an
180
l
Chemistry PART- II
SECTION-A
19. A, B, C, D
Sol. Factual
20. A, B, D
Sol. There will be post in each possible geometrical isomer thus no-optical isomers.
21. A, C, D
Sol. Factual
22. B, C
Sol. POS in B
POS in C after even
Interchanges.
23. B, C, D
Sol.
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24.
Sol.
SECTION-B
25. 3
Sol. Q =H 2 O 2
R=02
26. 0
2
Sol. [SiP1+21 -
27. 6
Sol.
Pair of enantiomers
28. 6
Sol. CxH12 + (x + 3)02 ➔ xCO 2 + 6H2 O
At 400 K H2O is gaseous.
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29. 5
Sol. Compound 1, 3, 4, 5, 6.
30. 3
Sol. Compound 2, 4, 5.
SECTION-C
31. 00033.00
Sol. X2O3
x3+x2+xs+
1 a
o
1-a 3
3 +2a + 5(1-a)-6 = 0
[balancing charges)
32. 00044.00
Sol. !1H = !1U + P2 V2 -P1V1
33. 00600.00
Sol. PCl5 ~ PCl3 + Cl 2
2 2 2
After 'x' moles Ci2 is added.
2+y 2-y 2+x-y
2 + x-y+ 2-y+2+ y = 2x(6)
⇒ x-y=6
2+y 2-y 8
2 2
34. 00287.00
K o o
Sol. s= "'Ag• + xd_
Convert mol/1to g/1
35. 00054.00
Sol. Let molar mass = M
6
M x P0 - 20
180 6 -
--+-
18 M
6
6 x P =20 .02
_M_ 0
11 + -
M
36. 00020.00
Sol. ~H - ~u = ~ ng x RT
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SECTION-A
37. A, B, C
n/2 n/2
Sol. 11 = f 2 2
f
cos(rccos x)dx= cos(rcsin x)dx
I
0 0
212 = 2cos ( %) cos ( %cos2x) = O
11 =0
n/2 n/2
12 = f f
cos ( re ( 1 - cos 2x)) dx = - cos ( re cos 2x) dx
0 0
1 1[
=- -
20
f cos ( 1t cost) dt put 2x = t
=-13
⇒ 12 +13 =0
38. B,D
2
(1 2 2
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a + m )- c
Sol. The line y= mx + c mater a chord of length 2 1 -~-~--from circle x 2 + y2 = a 2
1 +m 2
39. A, B,D
dy 1
Sol. y = log7 (log7 x) ⇒ - = x
dx xloge log0 7
40. A, B,D
1
Sol. Y-y=--(X-x) ⇒ X+mY-(x+my)=0
m
x+my
Perpendicular distance from origin = ,.----; = y
2
--.J1+m
2 2 dy y2 - x2
⇒ x + 2xym = y ⇒ - = ---
dx 2xy
Also x.2y. dy - x 2 = y 2
dx
dt 1
Put y2 =t, - - -.t =-X
dx X
41. A, C
x2 x 2
Sol. f 2
I= x.1n(1 + x )dx = 1n(1 + x
2
).- -
2
f--
1+
1
2x.-dx
2
X
2
_-
- Xn
2
I ( 1 +x 2) - f 3d
X .-
- X
2 x2 + 1
42_ B,D
x2 9 1
Sol. - - - x _ - =1 x2 -3x-4 = 0 X= 4, -1
4 4 3
Points (4, ±3)
_-_ Required equation(s) of tangents are x ± y = 1
SECTION-8
43_ 8
2 1
Sol. x +x +1 =0 ⇒ x+-=-1
X
2
_-_ L 5 ( 1 ) =8
x' +r
r-1 X
44_ 5
Sol. Let at A, B , C f(x) is continuous but not differentiable at A, B , c_ Right hand derivative is - CL) and A
+ is left hard derivative is +CXJ_
Y = x3
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1 - + - - ~-----------------Y = sgn(x)
C
2 3
-1 1-
_-_ 5 points
45_ 1
_ _ _ _ _ x-1 y+3 z-3
Sol. Equation of line through P(1 , -2, 3) and parallel to given line Is - - = - - = - - = "'
2 3 -6
1
General point online Q(2A + 1, 3A. -2, -6A. +3) if then point lie on plane, "- = -
7
_-_a(~7 ' _!!7 ' 15)
7
4 9 36
.-_PQ= - + -+-=1
49 49 49
46_ 7
Sol. gx _ 3x + 1 = ( 3
2
- ~J ¾~ !
+
fllTJH Ltd-, FnTJEE Ho=-, 29-A, Kalu Sarai, San,apriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
3
X E ( - 00, 1)- :<::: gx - 3x + 1 :<::: 7
4
Range of f(x) = {O, 1, 2, 3, 4, 5, 6}
47. 6
Sol. If let A denotes the event that target is hit when x shells are fired at point I.
8 1
P(E 1 )=-, P(E 2 )=-
9 9
21
A ) = 1- ( 1
P( ~ )x ard P (EA ) = 1( 1) -X
2 2 2
21
P(A)=g
8 ( 1- ( 1
2
)x J+ 91 [ 1- ( 21) -xJ
d(A)=O ⇒ X=12
dx
:. a= 12
48. 2
Sol. a = J" (x + sin x) dx -J" xdx = 2 square unit
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0 0
SECTION-C
49. 00400.00
Sol. Am= 100 + n Gm=10✓ n Hm= 200n
2 ' ' 100+n
For Am to be integer, n is even
For GM to be integer n should be perfect square
⇒ n = 4k2
2
. H _ 200k
⇒ k = 125,100, 75, 25
2
.. m - 25+ k 2
.-. k2 = 100 only satisfy.
x = 4 kx 2 = 400
50. 00208.00
Sol. TTT, A,E,R,S
· 1 distinct
· · = 4 c x - ' = 16 4
3 like,
1 3!
4!
2 like, 2 distinct = 4c x 1x - = 72
2 2!
All for different = sc. x 4 ! = 120
:. Total number of words= 16 + 72 + 120 = 208
51. 00000.00
-5 3+5i ~-4i
2
Sol. Z= 3-5i 8 4+5i
3 4·I 4-5i
-+ 9
2
z = z :. z E purel, real
:. imaginer part of z = 0
52. 00004.00
a.6
l
a.a
a.CJ
Sol. [a X b b X C CX a] = [ a b Cr = ~-~ b.b ~-~ = 32
c.a c.b c.c
:. ---J121 =4
[abc
53. 00004.25
Sol. An P{2, 0) lie on curve - 89 + 4b - 2c + 5 = 0 ....(1)
0(0, 5) dy = 3ax2 + 2bx + c
dx
At(O, 5) dy = 3 ⇒ c = 3
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... (2)
dx
dy
dx at ( -2, 0) = 0 ⇒ 12a - 4b + 3 = O
1 3
· a = -- b = -- c = 3
.. 2' 4'
]c - a - b] = 3 + 2 + 31
= 17 = 4.25
I 4 4 4
54. 00004.00
Sol. cos20 =-sine= cos ( % + 30)
20 = 2nn ± ( ~ + 30} n E I
for+vesign 0=-( 2nn + ~ )
2nn n
For-vesign 0 = - - -
5 10
. _ 3n 7n 11n 15n
.. 0 -10, 10'10'10
Hence four values
FIITJEE
PART TEST- I
JEE (Advanced)-2021
PAPER-1
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wrong answer.
correct answer(s).
a correct option;
Negative Marks : -2 In all other cases.
Section-C {13 - 18, 31- 36, 49 - 54) contains 18 Numerical answer type questions with answer
AITS-PT-I (Paper-1)-PCM-JEE (Advanced)/2021 2
Physics PART - 1
SECTION-A
(D), out of w hich ONLY ONE option is correct.
1. A mass of 3M moving at a speed v collides w ith a mass of M moving directly towards it, also w ith
a speed v. If the collision is completely elastic, the total kinetic energy after the collision is Ke . If
the masses stick together, the total kinetic energy after the collision is Ks . What is the ratio Ke ?
Ks
1
(A)
4
(B) 4
1
(C)
2
(D) 2
2. A steel ball bearing bounces vertically on a steel plate. If the speed of the ball just before a
bounce is V; , the speed of the ball immediately afterwards is v 1 = av; with a < 1. Which one of
the follow ing graphs best shows the time between s uccessive bounces ('t) as a function of time
(t)?
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't 't
(A) (B)
(C) (D)
3. The pow er output from a certain experimental car design to be shaped like a cube is proportional
to the mass m of the car. The force of air friction is proportional to Av 2 , w here v is the speed of
the car and A is the cross sectional area. On a level surface the car has a maximum speed vmax .
Ass uming that all versions of this design have the same density, then w hich of the follow ing is
true?
(A) vmax cc m213
(B) V cc m117
max
(C) vmax cc m119
(D) Vmax cc m314
3 AITS-PT-I (Paper-1)-PCM-JEE (Advanced)/2021
4. Two particles with mass m1 and m2 are connected by a mass less rigid rod of length Land placed
on a horizontal frictionless table. At time t = 0, the first mass receives an impulse perpendicular to
the rod, giving it speed v. At this moment, the second mass is at rest. The minimum time after
which the second mass will again come to rest is
(A) t = 2rcm1L
{m1 + m2 )v
(B) t = 2rcm1m 2 L
(m1 + m2 )2v
(C)
t = rc(m1 +m2 )L
m2 v
(D)
5. A uniform circular disc is being pulled by a force F through a string attached

to its centre of mass. Assume that the disc is rolling without slipping. At a
certain instant of time, in which region of the disc (if any) is there a point with F
zero acceleration?
(A) Region 11
(B) Region Ill
(C) Region IV
(D) All points on the disc have non zero acceleration .
6. A uniform circular disc of mass m = 12 kg slides
down along a smooth frictionless hill, which ends in
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a horizontal plane without break. The disc is
released from rest at a height of h = 1.25 m with
zero initial velocity and zero angular velocity and
rides on the top of a cart of mass M = 6kg, which
cart
can move on a frictionless surface. The coefficient
of kinetic friction between the cart and the disc is µ
= 0.4. Find the minimum length of the cart so that
the disc begins to roll without slipping before
loosing contact with the cart.
7
(A) -m
8
7
(B) -m
4
21
(C) -m
4
3
(D) -m
8

7. A uniform circular disc of mass m = 10 kg and radius R = 10 cm A uniform disc
e:~~~04
is placed on a rough horizontal surface. A horizontal time
dependent force F = 1ot N starts acting on the centre of the disc
from t = 0 as show n in the figure. The coefficient of friction
F
between the disc and the surface is 0.4. Choose the correct
option(s). (Take g = 10 m/s 2)
p
(A) The disc is performing pure rolling at t = 6 sec.

(B) Friction force acting on the disc at t = 6 sec is 40 N
(C) Friction force acting on the disc at t = 20 sec is 40 N
(D) Angular momentum of the disc about point P is L = t2 kg-m2/sec, where t is time
8. A uniform cylinder of height 10 cm, diameter 5 cm and

mass M is placed on a horizontal smooth table. One
end of a string passing over an ideal pulley is
connected to top point of the cylinder and the other
end is connected to a block of mass mas shown in the
figure. The system is released from rest from the
situation show n. Then
M - -
(A) If m = then I am l=I aM I
3
(B) If m = M then am = aM
(C) If m = 3M then I am l=I aMI
(D) If m = M then the cylinder is at the verge of toppling
9. An L-shaped body is made of two rigid uniform rod each of A

mass m and length £. The two rods are welded together at
m, C
90° at ends. The body is kept horizontally stationary and
movable on a smooth horizontal surface. A particle of mass
2m strikes the body normally with horizontal velocity u at a 2m u
perpendicular distance of £/4 from point 0. The coefficient of
71 m, C
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restitution for the collision is e = 1/2.
0 B
3
(A) Angular impulse acting on the body (AOB) about its centre of mass is muf
8
9
(B) Angular velocity of the body (AOB) after collision is u
16C
(C) The loss in kinetic energy of the (particle+ rod) system during collision is ~mu 2
8
(D) After the collision, the particle keeps on moving in the direction of velocity before the
collision.
10. A wedge of mass M is placed on a horizontal smooth surface. A F

block of mass m is placed on the smooth w edge and it is pulled
by a contact force F w ith the help of a string passing over an ideal
pulley. m is not s liding on the wedge and both m and M are
moving with the same acceleration. (Given M > .fim)
m 2 gsin0
(A) Pseudo force on the m as seen from M is - - - - - -
M + m - m cos 0
. MF
(B) Pseudo force on M as seen from m Is - -
M+ m
(C) Pseudo force on M as seen from m is zero.
. mF
(D) The normal force between M and m for 0 = 45° Is greater than - - .
M+ m
11. A block of mass m moves on a horizontal circle against the inner ~ J( p ~

walls of a fixed cylindrical drum of inner radius R. The floor of the
drum on which the block moves is smooth but the coefficient of _________
friction between the wall and the block is µ. The block is given an
initial velocity vo along the tangent of the drum as shown in the
figure. Then choose the correct option(s).
(A) The time at which velocity of the block reduces to ~ is _B_

2 µV0
(B) The magnitude of average power developed by the resultant forces acting on the block
v µmv30
from v =voto v = _Q_ is - -
2 8R
(C) The magnitude of average power developed by the resultant forces acting on the block
v 3µmv 03
from v = Vo to v = _Q_ is - - -
2 8R
. . . v . µmv03
(D) The instantaneous power developed by the frrct1on force when v = _Q_ Is - - -
2 8R
12. A bead of mass m is threaded by a light elastic string of natural A
length L. Initially the bead is very close to the bottommost point B
of a fixed vertical ring of radius L and the string is slacked initially.
The other end of the string is fixed to B and the bead can slide cl
along the frictionless ring. The elastic constant of the string is ··············t·············· D
4mg . . .
- - . The bead Is proJected from B with speed u. Mark correct
Bl
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L
,_w-1'::::::....➔ u
option(s).
Bead
(A) The smallest value of u = uo for which the bead will be able to complete the circular path
is -.JagL
(B) If bead is projected with 2uo, then normal force on the bead at topmost point is 19mg and
it acts radially inward.
(C) If bead is projected with 2uo, then normal force on the bead at topmost point is 19 mg and
it acts radially outward.
(D) The tangential acceleration of the bead when it passes through point Dis 4g(✓ 2 -1)
SECTION-C
13. A mass M = 1 kg attached to the end of a small flexible rope of

diameter d = 1 cm is raised vertically by winding the rope on a reel. If
the reel is turned uniformly at the angular velocity of 4n rad/sec, what
will be the tension in the rope in newton? Neglect inertia of the rope
and slight lateral motion of the suspended mass. (Take g = 10 m/s2
and n = 3.14)
250
14. Water flows along a horizontal pipe with a curve having a radius of R = m. Find the lateral
9
pressure (in N/m2) of the water (assuming to be uniform in the diameter of the pipe). The pipe
diameter is d = 20 cm and m = ✓ n x 105 kg of water pass through the pipe in t = 1 hour at a
steady rate.
15. A rope with mass M = 2.3 kg and length L = 10 m is held in the position
shown with one end attached to support. Assume that only a negligible length
of the rope hangs below the support. The rope is released at t = 0. Find the
force (in newton) that the support applies to the rope at t = 1 sec. (Take g =
10 m/s2 ) L
Support
16. A brick is thrown (from ground level) at an angle 0 with respect to horizontal with a speed v = 10
mis. Assume that the larger face of the brick remains parallel to the ground at all times and there
is no deformation in the ground or the brick when the brick hits the ground. After hitting the
ground, the brick does not rebound. If the coefficient of friction between the brick and the ground
is µ = 0.4. Angle 0 is chosen so that the brick travels the maximum total horizontal distance
before finally coming to rest. Find the maximum horizontal distance (in meter) covered by the
brick before coming to rest. (Take g = 10 m/s2)
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17. A uniform sphere of mass m = 2kg rolls without slipping on the
inside of cylinder of radius R = 2m. The cylinder spins around its
axis (which points horizontally) with angular acceleration a. What
should a (in rad/s 2) be if it is desired that the centre of the sphere
to remain motionless at an angle 0 = 30° from the vertical (Take g
= 10 m/s2 )
18. The motion of a point like mass can be split into two parts. In the first part its average speed is v1
= 90 km/hr and in the second its average speed is v2 = 40 km/hr. For the whole motion the
average speed is the geometric mean of the speed v1 and v2 that is V3 = 60 km/hr Then the ratio
of the covered distance in the first part and the second part is
Chemistry PART- II
SECTION-A
312
1
19. If an orbital is represented by \j/=~(-- ) (a-1)(a2 -8a+12)ae-"12 cos0belong to which
3 3a0
orbital
(A) 6dX, -y,
(B) 5p,
(C) 5py
(D) 6dz,
20. For an elementry reaction
mA ~ Product, the graph is plotted between log 10 [ - d~~]] vs log10 [A] . It gives straight line
with intercept equal to 0.6 and showing an angle 45° with origin, then
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(A) rate constant= 3.98 time-1 and m = 1
(B) rate constant= 3.98 mole L-1 time-1 and m = 1
(C) rate constant= 1.99 mole L-1 time-1 and m = 1
(D) rate constant= 1.99 mole L-1 time-1 and m = 2
21. In manufacture of Na2 C03 from solvay process the raw material used is
(A) NaOH
(B) Na2 S04
(C) NaCl
(D) NaHC03
22. Which of the following is the correct statement?

(A) T t+3 and Al+3 act as an oxidizing agent in aqueous solution
(B) In TJ!l3 ,TJ! oxidization state is (+3)
(C) Hydrogen bonding in H3 B03 gives a layered structure
(D) B(OC 2 H5 ) 3 burns with blue edge flame
23. The correct order second ionization potential of C , N, 0 and Fis

(A) C>N>0 >F
(B) 0 > N> F> C
(C) 0 >F>N>C
(D) F>0 >N>C
24. In which of the following molecule/ions are all the bond angles not equal
(A) SiF4
(B) ICI~
(C) SF4
(D) PCI;

25. Choose the correct statement(s)

(A) BeCO3 is kept in the atmosphere of CO2 since it is thermally unstable.
(B) Be is dissolved in alkali forming [ Be ( OHt r.

(C) BeF2 form complex ion with NaF in which Be goes with cation.
(D) BeF2 form complex ion with NaF in which Be goes with anion.
26. The orbital angular momentum is ../3 ~, which of the following should not be the permissible value
1t
of orbit angular momentum of this electron revolving in Bohr orbit?
h
(A)
2n
h
(B)
1t
h
(C) 3 x-
2n
2h
(D)
1t
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27. For a reaction A+ B ~ 2C, Kc = 1 . If the initial concentration of A, B and C are 1 M, 1 M and 2
M then at equilibrium
(A) [A] = [B] = [C]
(B) [A]=;M
(C) [B] = 3_M
3
(D) [A]=_![C]
2
28. Which of the following statements are correct?

(A) In CIF3 , the axial Cl - F bond length is larger than equilateral Cl - F bond length.
(B) In CIF3 , all the Cl - F bond angles are 90°.
(C) In SF4, F - S - F equitorial bond angle is not 120° but 102° due to Ip - bp repulsion.
(D) In OBr2, the bond angle is less than OCl2.
29. Identify the correct statement

(A) time of 75% completion of reaction is thrice of half-life in second order reaction.
(B) for a reaction whose equilibrium constant greater than one. Activation energy of forward
reaction is greater than backward reaction
(C) molecularity of slowest step will be zero or fraction.
(D) In zero order reaction half life is directly proportional to initial concentration
30. Which are correct for radio activity?

(A) Half-life is independent of initial amount of radioactive substance
(B) The increasing the temperature half-life will decrease
(C) Half-life of C-14 in CO2 is different from that C-14 in C6 H1P 6
(D) Half-life of U-235 and U-238 are different.
SECTION-C
31. How many ml of 0.1 M NaOH is added to 60 ml of 0.15 M H3 PO 4 ( pKa, ,PKa, and pK8 3 for H3 PO4
are 3, 8 and 13). So, that pH of resulting buffer solution would be 8.3. (log2 = 0.3)
32. In 200 ml solution of 0.1 M NaOH and 0.2 M NH4 OH, 300 ml of 0.1 M HCI is added. Find pH of
solution (pKb of NH4 OH =5). (and given log3 = 0.48).
33. What is the pH after addition of 40 ml of 0.1 M NaOH in the 50 ml of 0.1 M anilinium chloride
(PKa of anilinium ion= 4.6)
34. Hydrogen like species is in some excited state 'P' and on absorbing a photon of wavelength 'a'
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eV reached to a new state 'Q ' on de-excitation back to the ground state a total of 10 different
wave lengths were emitted in which seven have energy greater than 'a' eV. The ionization energy
in the ground state will be "xa" eV .Find the value of x.
35. In a sample of H atoms, electron are de-excited from a level 'n' to ground state. Total number of
Lyman lines emitted are 3. If the electron are ionized from this level 'n' by a photon of 15 eV.
Then kinetic energy of emitted photon is x eV. Find x.
36. For a substance P undergoing parallel reaction

1/Q
p~R
K1 = 0.372min-1 and K2 = 0.321 min-1

What will be concentration of P after 30 sec where initial concentration of P is 1 molar
Mathematics PART - 111

SECTION-A
37. Let R be the region in the first quadrant bounded by the x-axis, the line 2y = x, and the ellipse
2
~ + y2 = 1. Let R' be the region in the first quadrant bounded by the y-axis, the line y = mx, and
9
the ellipse, then the value of m such that R and R' have the same area is
2
(A)
9
3
(B)
11
2
(C)
5
2
(D)
7
3
➔ [-1 , 1] satisfies ff (x) dx = 0 , then the maximum value of r
3
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38. If f(x): [1 , 3] ~x) dx is
1 1
(A) In ( %)
ln (i)(B)
8
(C)
3
(D) In ( ~ )
39. The value(s) of the real parameter 'a' for which the inequality
x6 - 6x5 + 12x4 + ax3 + 12x2 - 6x + 1 ~ 0 is satisfied for all real x
(A) [-12, 37]
(B) [-12, 38]
(C) [-17, 14]
(D) [-17, 35]
40. Let f(x): [-1 , 1] ➔ R is twice differentiable function such that lf(x)I s 1 and lf''(x)I s 1, then choose
the correct option
(A) lf'(x)I s 2 V x E [-1 , 1]
(B) f'(x1) =3forsomex1 E (-1 , 1)
(C) f'(x1)=4forsomex1 E (-1, 1)
(D) none of these
1 1
rtan- (nx)-tan- xd .
"' It
41 . - - - - - - x 1s equa o
o X
(A) 2:inn
2
(B) n Inn
2
(C) -Inn
7t
(D) none of these
4 2
42. The domain of f(x)=4x ( 2.3x_ x:+x+ ) is
X + X+ 1
(A) [-7, 101]
(B) [-9, 103]
(C) [-9, 93 In 2]
(D) (-oo, oo)

43. Which of the following statements are INCORRECT? (w here {.} denotes the fractional part of
function)
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2 1
(A) f ( x ) = { x} cos2 (( x - )n) isdifferentiableforallx E R
2
(B) f(x) = lsin xIcos-1 (cos x) is differentiable 'ef x E (0, 2n )
(C) f(x) = llx - 21- Ix - 611- 3Ixl + 2x + 1 is not differentiable at 3 points
(D) f(x) = {x}lsin nxl is not differentiable at all integers
44. Let f(x) : R ➔ [-1 , 1] be twice differentiable and f2(0) + (f' (0))2 = 4 , then which of the follow ing(s)
is/are TRUE?
(A) There exist a , p E R w here a < p, such that f is one-one on the interval {a, P)
(B) There exists c E (0, 2) such that lf'(c)I ~ 1
(C) lim f(x) = 1
X ➔OO
(D) There exists some xo such that f(xo) + f"(xo) = 0 but f'(xo) *0
, X 2'. 3
45. If f(x) = 2Ix + 11 - Ix - 11 + 3Ix - 21 + 2x + 1 and h ( x ) = { ~x , then choose the correct
X< 3
statements
(A) y= h(f(x)) is continuous 'ef x E R
(B) y= h(f(x)) is discontinuous at 3 points
(C) y= h(f(x)) is not differentiable at 3 points
(D) y= h(f(x)) is not differentiable at 4 points
2 2
46. Let f (x) = x + 4 x + 3 and g ( x ) = x - 5 x + 10 , then
2 2
x + 7x + 14 x + 5x + 20
(A) greatest value of f(x)g(x) is 5
(B) greatest value of (g(x))f<xJ is 9
(C) greatest value of f(x) is 2
(D) greatest value of (g(x))1<xJ is 8
47. Let f: [0, 1] ➔ R be a continuous function, g(x) be a non-increasing function on [0, 1] and
h(x): [O, oo) ➔ [0, oo) be a continuous strictly increasing function with h(0) = 0, then
1 a
(A) f
a g ( x) dx s f g( x ) dx for any a E (0, 1)
0 0
2
(B) n f (t) dtr s [f (t )dt
a b
(C) fh ( x) dx + fh-1 (x) dx;::.: ab
0 0
a b
(D) fh ( x) dx + fh-1 (x) dxs ab
0 0
.
48. Let n ;::,: 0 be an integer and In = frr -
1-cosnx
- - d x , then
0
1-cosx
(A) lo, 11, b , ..... is an A.P.
(B) lo, 11, b ..... is a G.P.
(C) In = nn: ; n ;: ,: 1
(D) absolute value of the integrand is bounded
SECTION-C
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49. Let f(x), g(x) R ➔ R be periodic function with period

3
and ~ respectively such that
2 2
lim f ( x) = 1, lim g (x ) = 2 , then lim

f(~(3+ ✓1r )
2 is equal to
X➔O X X➔O X n➔«> Q
(1(2 +-.f2)" )
50. Let f: (0, oo) ➔ (0, oo) be a differentiable function such that f ' ( ~ ) = ftx ) where a is positive
constant and f'(1 ) = 1, f'(2) = 2, then f(5) is equal to
51. Let f(x) be a differentiable function with f'(0) =2 and f(0) =3 such that f '(x ) = f (x + n) - f (x)
n
f (5) .
v x E Randn E N , then f ( ) Is
1
1
n
52.
n ➔oo
f
lim n2 xx+1dx is equal to
0
fllTJH Ltd., FnTJEE Ho=-, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513 942
53.
.
-
2°1 2°2
-
2°n
If hm - - + --1 + ..... + --1 = -
O➔ao [ n + 1 n + -
2
n+ -
n
1
Ink
-
l .
( -), then k IS
54. Number of solution(s) of the equation sin(sin(sin(sin(sin(x))))) = ~ is/are

3
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FIITJEE
PART TEST- I
JEE (Advanced)-2021
PAPER-1
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P hysics
SECTION-A
1. B
Sol. K = _!_3Mv 2 + _!_Mv 2 = 2Mv 2

e 2 2
2
2
K =_!_ (3M + M) ( Mv ) =_!_ Mv 2
s 2 4M 2
K
So _ e =4
' Ks
2. A
2vn n
Sol. 'n =- ' where Vn = a V;
g
So, 'n = , 0 a n , w here ,0 = -2v;

g
n 1- a" 'o - , n
t = , 0 La = , 0 - - = - -
n 1- a 1- a
So, , 0 = , 0 -(1- a )t0
3. C
Sol. The side of the cube is L ex: m113 (density is constant)
So, A ex: m 2' 3
For constant speed ,
AITS-PT-I (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 2
m cx: P(= Fv)

So, m cx: Av 3 ex: m 2' 3 v 3
So, v cx: m119
4. D
Sol. Relative to COM frame, the rod is undergoing pure
rotatory motion with a constant angular velocity, co='!....
L
m1L
Xe = - - -
m1 +m2
Xe
So t = 2nl
, V
5. C
Sol.
ae
6. A
Sol. (v0 - µgt)- atR = µmg t
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M µmg
)
( )
µmg
Att = 0 F.B.D. of disc F .B.D. of cart
7. A, C
2FR2 2F
Sol. a--- --
2e - 3mR - 3m
2F
So , F-fs =m-
3m
F
So, f5 =
3
f5 s µmg
F
So, - s 40 N
3
So, F s 120 N
So, the disc undergoes pure rolling motion upto t = 12 sec
Torque about point P = (1 ot) (0.1) N-m
t2
So L = - kg-m2/sec
' 2
3 AITS-PT-I (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021
8. A, D
Sol. For moving together, a = ~
M+ m
So T= Mmg
' M+m
. .
For toppling the cylinder (T) (10)
2
> (Mg) (5
2
)
So, Mmg
M+ m
(_!Q)
2
> Mg( ~ )
2
So, M < m
9. C, D
Sol. From conservation of linear momentum
2mu = 2mv1 + 2mv2
1
And fore, -u = v 2 -v1
2
U 3U V1
So, v 1 =- and v 2 = - ~
4 4
Impulse is passing through centre of mass of the body. So
there is no rotation after the collision
Loss in kinetic energy= !2mu2 - !2m(v; + v~) = ~ mu 2
2 2 8
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10. A, B, D
F F
Sol. a=--
M+ m
m is in equilibrium w .r.t to M
So F = (M + m)mgsin0 a
' M + m-mcose ma
mF
So, pseudo force on m w.r.t to M = - -
M+ m
m 2gsin0
=------
M + m-mcose
MF
Pseudo force on M w.r.t. to m = - -
M+ m
Also, F cos e = N sin 0 + ma
⇒ N Sin F --
. 450 = - mF
-
✓2 M+ m
So, N= ~ [M+ m- ✓2.m ]

M+m m
mF
So, N > - -
M+m
11. A, C, D
µmv2 dv
Sol. --=-m-
R dt
Vo
2 dv µ 1
R
So, f-
va V
=--f
2
R O
dt ⇒ t = -
µV o
I Pavg I= I ~ K.E. I = ~ µmv~

t 8 R
2 3
- . . . . µm v v µmv 0
At v = vo/2, instantaneous pow er due to kinetic friction force= __ _Q__Q_ = - - -
R 4 2 BR
12. A, B
Sol. Extension in the spring at highest point A is L. A
4mg
Fstring = -
L - x l=4mg
From conservation of energy at Band A
2mu~ = mg(2L) +
2 2 L
4
!(
mg ) L2
So, u0 = .J8gl
For u = 2uo at B.
~m [ 2.J8gl r 2 4
= ~mv + mg(2L) + ~ ( ~g ) L
2
So, v = .J24gl
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So, N = 19mg (radially inward)
At point D, string is stretched and gravity is also acting on the bead.
SECTION-C
13. 00010.25
Sol. dv = ro~ = ro ~d
dt dt 2n
Where dv = acceleration of the mass and r = radius of the reel at any instant
dt
14. 00013.89
Sol. Centripetal force Fe= Pd.C.d
Where d.e is a small section of pipe
nd2 v2
So, Pd.C.d = p(d.e)R
4
4m
and v=-2-
nd pt
4m 2
So, P = = 13 .89 N/m2
n pRd3t 2
15. 00017.25
Sol. plg - T = -d ( plgt - -

pg2t3)
-
dt 4
So, T = ~pg2t2 L
4
So, at t = 1 sec Support
23 1 t2
T = ~ ( · ) (10)2(1)2 = 17.25 N -g
4 10 4
16. 00014.50
2
Sol. d . = v sin20
air g
Impulse of normal reaction from ground = mV sin 0

So, after collision, Vx = v cos 0 - µv sin 0
v 2(cos0- µ sin0)2
S0 , dground = - - - - - - -
2µg
2
So, dtotai = ~[ 2µsin20 + (cos 0 -µsin e)2 ]
2µg
d
So, - (dto1ai) = 0 So tan e = µ
dt
2
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So dmaximum
, total
= ~(1
µg
+ µ2) = 14 50 m
·
2
17. 00006.25
Sol. fs = mg sin e
Ra
asphere = -r-
SO, 'C = IUsphere
. 2 R
So, mgr sin 0 = -mr 2 - a
5 r
(5)(10)(.!)
2
So a = 59 sin e = 6 .25 rad/s2
' 2R (2 )(2) mg sine
18. 00001 .50
Chemistry PART- II
SECTION-A
19. B
20. A
Sol. _ _!_ dA = k [Ar
m dt
- dA = mk[Ar
dt
10910 [ - ~~ ] = 10910 mk + mlog[ A]
m = 1, log10 mk = 0 .6 = log3.98
k = 3.98, first order reaction.
21. C
Sol. NH3 + Hp + CO 2 ~ N H4 HCO3
NH4 HCO 3 + NaCl~NaHCO3 + NH4 CI
22. C
1
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Sol. Tt\ ~ Tlt + I;
B ( OC2H5 ) 3 Burns with green edge flame.
23. C
24. C
25. A , B, D
26. A , B, C
Sol. £=3
n=4
orbital angular momentum = 4 x ~ = 2h
2n n
27. A, B
Sol. A + B ~ 2C
At equilibrium 1+ x 1+ x 2-2x
(2 - 2x)2
1=~-~-
(1+x)(1+x)
28. A, C
Sol.
> 180°
6=
---r F
F
Bond angle of 0Br2 = 112°
OCl2 = 110°
29. A, D
30. A, D
SECTION-C
31. 00150.00
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[ HPO~- J
Sol. pH = pK8 2 + log [ ]
H2 PO~
[ HPO~- J
8.3 = 8 + log [ ]
H2 PO;
[ HPO~-J =
2
[HpO~]
H3 P04 + Na0H-----)NaH2 P0 4
9 X 0
0 x-9 9
NaH2 P04 + Na0H-----)Na 2 HP04
9 x-9 0
18-x O x-9
x-9
~~=2
18-x
X = 15
15 = V x 0.1, V = 150 ml
32. 00009.48
Sol. NH4 0H + HCl-----)NH4 CI
40 10 0
30 0 10
1
pOH = 5 + log-; pH = 9.48
3
33. 00004.20
Sol. C 6 H5 NH; + NaOH~C6 H5 NH2 + NaCl
5 4 0 0
0 4
1
pOH = pKb + log-
4
= 10.4 - log4 = 10.4 - 0.6 = 9.8
pH= 4.2
34. 00014.06
Sol. aeV=E{ : - : ]
3 5
225
E1 = a eV
16
X = 14.06
35. 00014.50
13 6
Sol. 15eV = · eV + KE
42
KE=14.15eV
36. 00000.71
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Sol. K + K =2.303 10 _1_
1 2 9
0.5 1-x
Hence, (1- x) = 0.71 molar
SECTION-A
37. A
Sol. Stretch the figure by a factor 3 along the y-axis. So that the point (x, y) goes to (x, 3y), then new
line is 2y- 3x
2
So, for R = R', m = -
9
38. B
Sol. 1-tCx), 1+ f (x)~ o V xE[1 , 3]

X X
2 2
r - :( x) dx ~ r-~(x) dx ..... (1)
1 1
r
3
2
+ : ( x) dx ~ r
3
2
+ ~(x) dx
3 3
⇒ -r+:( x) dx ~ - r + ~(x) dx ..... (2)
2 2
Adding equation (1) and (2), we get ln2-ln ( %) ~ r~x)

3
dx
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2
1
Equality holds for f ( x) = {
-1 ; 2 ~ x ~ 3
39. B
Sol. 3 2
f (x) = ( x + x: ) -6(x + x: )+ 12(x+ ~ )+ a ~ O V x > Oand
3 2
f (x) = ( x + x: ) -6 ( x + x: )+ 12(x +~)+ a ~ O V x>O
1
Let x + - = t
X
So, g(t) = t3 - 6t2 + 9t + 12t +a ~ O; t ~ 2
g'(t) = 3(t - 1)(t - 3) ⇒ g(3) ~ 0 and g(t) ~ 0 V t ~ - 2 ⇒ -12 ~ a ~ 38
40. A
Sol. 2[f'(x)[ ~ [f (1)[ +[f (-1)[+ I(1-x)2 f 2t ) l+l (1+ x;f"(k) I ⇒ [f' ( x )[ ~ 3+2x2 ~ 2
41. A
Sol. Let l(a) = f tan- 1ax - tan-1x
o X
l' (a)= __!_ f dx = ..2:...

2
a x2 + _!__ 2a
0
a2
1=2:lna + c
2
1t
So, l(a) =-Ina
2
42. D
~2 ⇒
2
Sol. Case-I: Let x s O then 2_3x s 2 and 4 x2 + x + 2 x s O or x ~
1
. So, x s 0
x + X+ 1 2
2
4x + x + 2
Case-II: Let x > 0, we prove that < 2 _3x
2
X + X+ 1
2
·t . 4x + X + 2 x
A ssume the opposI e 1.e. ~ 2 .3
X2 + X+ 1
2
4x + X + 2 o 1
·:
2
> 2.3 = 2 ⇒ x < 0 or x > -
X + X+ 1 2
+ x + ~ 2_3x > 2✓
x:X +X+ 3 >3
4 2
Since, x > 0. So, x > _!_. Hence,
2 1
⇒ x2 - 2x - 1 > 0 ⇒ x E ( 1+ .fi., Cf.))
Thus, x:X ++Xx++12 ~ 2 _3x > 231+✓2 > 2 · 3 = 18

4 2
But x:
4 2
+ x+ 4 for any x
< we get a contradi ction
> 0,
X + X+ 1
So, domain is R
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43. B, C
Sol. (A) f(x) = {x}sin2 nx differentiable V x E R
(B) not differentiable at x = (2n + 1)n
(C) not differentiable at x = 0, 2, 6, 4
(D) not differentiable at all integers
44. A , B, D
. J lf( 2) -f (O)
Sol. Let k(x) = f(x) 2 + f'(x)2 using MVT, Jf'(a ) = s 1 : a E (0, 2)
2
So, k(a) s 2
Similarly; k(a) s 2, b E (-2, 0)
·: k (0) = 4. So k(x) has a maximum at some interior point of (-2, 2).
Let that point be xo then certainly k(xo) ~ k(O) =4 ⇒ k' (xo) =0
⇒ f'(xo)(f"+ f(xo)) = 0: clearly, f' (xo) -:t: 0
45. A, C
Sol. h(f(x)) is continuous V x E R and not differentiable at x = -1, 1, 2
46. B, C
Sol. f(x) has maximum value 2 when x =-5 and g(x) has maximum value 3 w hen x = -5
47. A, B, C
1 1
Sol. (A) ·: - f
1- aa
g( x) dx s - f g( x ) dx
1
a
a
0
1 a
f f
a g(x) dx s ( 1- a) g(x)dx
a 0
Add ff(x)dx both sides

0
1 a
af f(x)dx ~ f f(x)dx
0 0
(B) Cauchy-schwarz inequality to the functions f(t) and g(t) = 1 V t E [0, 1)
48. A, D
. 1 - cos nx
So.I II m - - - = n2
x➔o 1-cosx
So, absolute value of the integrand is bounded as x ➔ 0 and hence the integral converges
ln+1 +In_1 = J1-cosnx-cosx = r1-cosnx)+cosnx(1-cosx) =In
2 0
1- COS X O
1- COS X
1
So, In =
2(In+l + ln_1 ); n ~ 1
·: lo= 0, 11 = re, ..... , In = nrc
SECTION-C
49. 00000.00
f ( (3 + .fr)" T1 ) f( (3 + ✓7)2 T1 + (3- ✓7)" T2 -(3 -.fr)" T1) f (-(3- ✓7)" TJ

Sol. ~---~ = ~------------~= ~---~ V n>1
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g((2+-.,'2)"T2 ) g((2+-.,'2)" T2 +(2--.,'2)" T2 - (2--.,'2)" TJ g(-(2--.,'2)" TJ -
So lim f(T1 (3+ ✓7)") = T1 lim lt(-(3- ✓?)"TJ _ -(2--/2)"T2 _ (3--ff)"}=O
'n➔"' f(T2 (2+-/2)") T2 n➔"' -(3--ff)"T1 g(-(2--/2)"TJ (2--/2)"
50. 00012.50
Sol.
f'(~)= ftx) ..... (1)
a
X ➔ -
X
f'(x) = (aa)
xf -
..... (2)
f"(x) =
f'(~)
a a
2
..... (3)
x'r(~f x'(r(~))'
2
. . f'(x) (f'(x))
Using equation (1 ), (2) and (3), we get f"(x) = - - - + ( )
X f X
2
f'(x) xf•(x) x(f(x))
⇒ xf(x) f"(x) + f(x) f'(x) = x(f'(x))2 ⇒ -- + - -- --- =0
f(x) f(x) (f(x))2
xf'(x) J' _ S xf'(x) _ f'(x) _ ~

Observe ( ( ) - 0 . o, ( ) - c ⇒ ( )-
fx fx fx x
51. 00002.60
Sol. Put n = 1 ; f'(x) = f(x + 1) - f(x), n = 2 ; f'(x) = f ( x + 2 1- f ( x)
So f '(x) = f (x + 2) -f ( x + 1)+f( x+1) -f ( x) f '(x ) =_!_f'(x + 1)+ _!_f'(x)

' 2 ' 2 2
⇒ f'(x) = f' (x + 1) V x E R ⇒ (f(x + 1) - f(x))' =0 V x E R
⇒ f(x + 1) - f(x) = c for a constant c E R ⇒ f'(x) = c ⇒ f(x) = ex + d
52. 00000.50
Sol. ·: lim xx = 1
Fix E > 0 and choose 8 > 0 such that for 0 < x < 8, Ixx - 11 < E then for n ~ .! , we have
8
n n n n E
f f
n2 (xx+1 -x) dx ~ n2 f k+1 -xldx = n 2 xlx x -1ldx <E n2 xdx = - f
0 0 0 0 2
-
1 1
-
1 1
n
f n
f
So, n2 xx+ 1dx = ~ + n2 xdx = ~ + n2 . - 2 = -
2 2 2n 2
0 0
53. 00002.00
r r (rn-1) _n1 ( '-1) ~
. n in 2" 2 2 2 n e n
= llm L,--
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Sol. Sn = = =a and
n➔ao r=1 1 + -
1 1+ _!_ 1 + _!_ 1+ _!_
m m m m
1 2
r r-1 r 1+ n ] r-1
for· r > 2· 211 > a > 2
' - '
n __ n_ > 2
1
n (··
. ex> 1 + x)
1+ -
rn
1 2 n-1 2 3 n
S0, - - - - - - - < n< - - - - - - . ence, n= 2xdX =1-

2" + 2" + ..... + 2 n S 2" + 2" + ..... + 2" H S
1
J
n n ln2
O
54. 00003.00
Sol. Let f(x) = sin(sin(sin(sin(sin x))))
f'(0) = 1 > _!_. Therefore, f(x) > ~ in some neighbourhood of 0
3 3
So, there are 3 solutions
FIITJEE
PART TEST- I
JEE (Advanced)-2021
PAPER-2
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Section-A {01 - 06, 19 - 24, 37- 42} this section contains 18 multiple choice questions.
correct answer(s).
a correct option;
Negative Marks : - 2 In all other cases
Section-8 (07 - 12, 25 - 30, 43- 48) contains 18 Numerical based questions with Single digit
and
-1 mark/or wrong answer.
Section-C (13 -18, 31 - 36, 49- 54) contains 18 Numerical answer type questions with answer
Physics PART - 1
SECTION-A
1. An object having all of mass concentrated at centre and having six

identical rods of length R. each attached to it symmetrically is
placed on an inclined rough surface of inclination a. Object looks
like a wheel with six equally spaced spokes without rim. Assume
that there is no slipping and collision between the spokes and
plane is perfectly inelastic and wheel always remains in the vertical
plane. Pick correct statement( s) for the motion of wheel.
(A) Average velocity of the centre of object increases and attains a constant value (Assuming
object remains in contact with the plane and initial kick was given to start motion)
(B) Mechanical energy of object remains conserved
(C) Work done by friction is zero
(D) The value of constant average velocity Is

. . ✓8gR. sina
3
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2. A point mass m is attached to an ideal string, which in
turns is wrapped on a vertical pole. Point mass is kept on a
smooth horizontal surface and string is horizontal. A
horizontal velocity is imparted to the point mass
perpendicular to length of string. Vo
fo
(A) Speed of mass will become twice of initial value if length of string between the point mass
and the pole becomes half of the original value.
(B) Kinetic energy of mass increases.
(C) Work done by tension on the point mass is zero.
(D) Energy of the mass remains constant.
3. Three masses are joined using pin joints (can move m

freely). Length of both rods are identical and system
starts from rest. Accelerations of the balls are shown
in figure. Angle between the rods at this moment is
90°. The horizontal surface is smooth. Choose the
correct option(s).
(A) 2a2 = a1 + ax
(B) 2ay= a1 + a2
(C) 2ax = a1 - a2
(D) 3a1 = 5a2 m 2m
4. A particle of mass m is subjected to two forces

- f - -
F; = f(r)lfl and F2 = -av
Where f(r) is a real valued function depends on the distance of particle from origin, f is position
vector of particle and a is positive constant. If at t = 0, v vector is in x-y plane and angular
momentum of the particle about the origin is Lo. Choose the correct option(s).
(A) Plane of motion of particle does not change.

al
(B) Angular momentum of particle about the origin is given by L0 e m
(C) Angular momentum of particle about the origin is remains constant.

(D) The value of angular momentum about the origin will depend on f(r)
5. A uniform massive string of mass m, length .e is fixed between two

rigid supports. Angles made by the tangents on the string at points
of suspension are shown in the figure. The point C is the lower most
point of the string. Then choose the correct option(s).
. . . 16£
(A) Length of string left of the point C Is -
25
12mg
(B) Tension in the string at point C is - -
5
. . . 12 £
(C) Radius of curvature of the string at point C Is - -
25
3mg
(D) Tension in the string at point Bis - -
5
6. An Atwood's machine having infinite number of masses connected with

ideal strings as shown in the figure. All the masses are identical and equal
tom. All the pulleys are ideal. Then choose the correct option(s).
(A) Acceleration of mass-1 is g/2
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(B) Ratio of acceleration of mass-1 and mass-2 is 2 m
(C) Total work done by tension is zero
(D) Acceleration of mass-1 can't be determined
00
SECTION-B
7. Two particles move with same speed v in x-y plane. Particle A

moves on the circle of radius R centered at origin while particle B
moves along the positive y-axis. At t = 0 particle A is at (R, 0)
and B is at the origin. Average angular velocity of B as seen by A
. . . 1tR . av
in the time interval - Is - . Find the value of a .
2v R
8. A particle is projected from the horizontal surface.

Times taken by the particle to pass through two
horizontal lines separated by height h are T1 and T2. If
g~/). h -- ◄ --- T1______ -- -
I
T2 = 3T1 then find the value of [
- -
9. A particle of mass m is rigidly attached to the circumference of m, R

a uniform circular ring of mass m and radius R and placed on a
rough horizontal surface. The ring is released from rest from the \ m
initial position as shown in the figure and it starts rolling without
slipping on the rough horizontal surface. If the frictional force
<
acting on the ring due to horizontal surface when the particle is
getting at the end of the horizontal diameter is ~g) . Find the

·· · · ··· r -/··
value of k.
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10. Inside a freely falling cubical elevator a point mass is to be
projected from the bottom left corner A towards right w all
such that it collides with the wall at B and finally reaches
the point C, top left corner of the elevator. Points A, B and
C lie in the same vertical plane. Coefficient of restitution for
1
the collision between the w all and the ball is e = - . Then
2
find the value of cot 0. (where e = angle made by initial
velocity of the ball with the horizontal x-axis.
11 . Potential energy of a particle moving on a circle in x-y plane

is given by V = Var3 cos0. Where r is the radius of circle and e
is the angle made by the radius vector of the particle with the
positive x-axis. Magnitude of x-component of force, when the
2
r r ) . . aV r .
particle is at ( ✓2, ✓2 Is given by - : - . Then find the
value of a .
12. A droplet of water in uniform fog is formed. It then falls sweeping up the fog lying in its path.
Assume that it retains all the fog in its path, remains spherical and experiences zero drag. Drop
attains a constant value of acceleration after a large time interval. Its acceleration is given by __g.
K
Find the value of K.
SECTION-C
13. Engine of a car can deliver a maximum power of 50 kW. Car starts from rest and experiences a
drag force F=-kV, where k = 5 N-s/m. If mass of the car is 500 Kg, find the maximum velocity
(in m/s) that the car can attain while it moves on a straight horizontal road is
14. While crossing a river of width 10 m a swimmer wants to B

follow path AB, as shown in the figure. Velocity of the river
current is 5 ms-1 . Velocity of the swimmer in still water is also
5 ms-1 . Swimmer starts swimming making an angle 0 with the
direction of the river current. The value of 0 (in degrees) is
15. Length and height of each step is 10 cm. A ball bounces

down the stairs in regular manner, hitting each step at
identical points and then the ball bounces upto same height
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above each step. Coefficient of restitution between the stairs
and the ball is e = 1/3. Find the horizontal component of
velocity of the ball (in ms-1 ). (Assume that this process can
go on for infinite times).
16. A uniform spherical shell of radius 10 cm is divided into eight identical parts. Find the distance (in
cm) between the geometric centre of the complete spherical shell and the centre of mass of one
part. (Take ✓3 = 1. 732 )
17. Five identical bricks of uniform density and length 10 cm each are
placed on the top of each other at the edge of a table such that they
---
-
remain in equilibrium and corner of top most brick is farthest from the
edge of the table. Horizontal projection of the distance between the
18.
farthest corner of top most brick and edge of the table is (in cm).
An inverted cone of height his scooped out of a uniform cone of radius

-
2h and height 2h symmetrically as shown in the figure. If moment of
inertia of the removed portion about the axis shown is I and the moment
of inertia of the remaining portion is A.I. Find the value of A..
Chemistry PART - 11
SECTION-A
19. Select the correct statement with respect to Na2O2

(A) It decolourises acidified KMnO 4
(B) It is obtained along with Na metal when Na2O is heated to a temperature more than
400°C
(C) On heating with oxygen at 450° C and 300 atm it becomes paramagnetic
(D) It gives both H2O 2 and 0 2with water
20. Which of the following disproportionate on heating with NaOH?

(A) P4
(B) S8
(C) Cl2
(D) Boron
21. Which of the following are correct regarding s-Block elements
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(A) The reducing character of the alkali metal hydride follows the order:
CsH > RbH > KH > NaH > LiH
(B) The bicarbonates of alkaline earth metal are only stable in solution
(C) Lil is the most ionic in nature among the alkali metal halides
(D) Magnesium nitrate on heating decomposes to give NO2 and 02
22. Which of the following are correct regarding Si compounds?

(A) Cross link silicones are obtained by hydrolysis of RSiCl3
(B) Linear silicone are obtained by hydrolysis of R2SiCl2
(C) Sc2(Sip7 ) is a example of pyrosilicate
(D) In three dimensional sheet silicates three oxygen atom of SiO:;4 is shared with adjacent
SiO:;4 unit
23. Which of the following statement are correct?

(A) Ionic carbide are formed by highly electropositive metals
(B) Carborundum and boron carbide are covalent compound
(C) Carborundum and boron carbide are used as abrasive
(D) Al 4 C 3 and CaC2on hydrolysis gives C2H2
24. Which of the following are polar?

(A) Xe03
(B) XeOF4
(C) XeF4
(D) BrF;
SECTION-8
25. xU(SO 4 ) 2 + yKMnO4 +zHp~H2 SO4 + K 2 SO4 + MnSO 4 + UO2 SO4

Find the value of x + y + z? (Minimum integral value of x, y, z)
26. 100 ml of sample of tap water contain 0.192 mg of Mg+2 , what is the hardness as parts of
CaCO 3 per million part of water.
27. Two bulb P and Qare emitting monochromatic light of wave length such that P can just ionize
H-atom and Q can just ionize He+ ion. If power of P and Qare 60 Wand 80 W. The ratio of
number of photons emitted per sec by bulb P and Q is:
28. For the following reaction

A+B~C + D
if 0.4 mole of A and 0.4 mole of B, 2 moles of C and 2 moles of D are mixed in container of
volume 80 ml. Then the equilibrium concentration of B will be.
29. During a decay of 952 gram 92 U238 to 82 Pb206 , total 18.066 x 1024 a - particle are emitted, number of
half lives completed in this decays are
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30. What is the concentration ratio of sodium acetate to acetic acid when pH of solution is 5.35.
[pKa of acetic acid= 4.75]
SECTION-C
31. A diatomic molecule has a dipole moment of 1.2 D. if its bond length is equal to 10-10 m then the
percentage ionic character is x%. Find x. (1 D = 3.336 x 10-3 C x metre) °
32. Bromophenol is an acid indicator having dissociation constant 1 o-s, the pH of solution at which
indicator is 80% ionized. [log2 = 0.3]
33. When one mole of K 4 [ Fe(CN)6 ] is heated with cone. H2 SO4 , the evolved gas during reaction is
reacted with excess of 12 0 5 .find how many moles of 12 will be liberated during the reaction
34. A flask is filled with N2 O3 (g)at 2 bar pressure, and following equilibrium is established.
Reaction 1: Np3 (9)~NO2 (9) + NO (g); KP, = 2.5
Reaction 2: 2NO 2 (g)~N2 O4 (g); KP, =?

If at equilibrium partial pressure of NO (g) is 1.5 bar, then find equilibrium constant for second
reaction
K 1 (sec-1 )
35. A---~B
C D
Starting with 1 molar initial cone. of reactant of each reaction, it takes 10 sec. to reach to 0.5
molar in each reaction. Then find the ratio of k1 /k2.
36. In the following reaction started only w ith A

2A ~ 2B + 3C + D
mole fraction of C is found to be 0.36 at a total pressure of 200 atm. The mole fraction of A at
equilibrium is (Note : Reactant and product are gases).
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SECTION-A
13
37. Let 11 = f
512{x ' }
3
r:i dx and 12
2
= f x 2 { x 3 } dx
2
(where{.} denotes fractional part of function), then
o ~x o
(A) 11 = 12
(B) 11 = 912
(C) 11 = 12
(D) 12 = 4
38. Let the functions f: (-1, 1) ➔ Rand g: (-1, 1) ➔ be defined as f(x) = I3x-2I + I3x + 21and
g(x) = x - [x] (where [x] denotes greatest integer less than or equal to x). Let fog : (-1 , 1) ➔ R be
the composite function defined by (fog)(x) = f(g(x)). Suppose c is the number of points in the
interval (-1 , 1) at which fog is NOT continuous and suppose d is the number of points in the
interval (-1 , 1) at which fog is NOT differentiable, then
(A) c= 1
(8) c=2
(C) d=3
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(D) d= 2
39. Which of the follow ing inequalities is/are true?

2
f (A)
1
0
xtanxdx :2-: -
5
1 1
(B) fx 2 cosx :<:: -
o 3
3
(C) fx
1
0
3
sinxdx :?: -
20
(D) f xsinx :?: -103

0
_1
40. If f(x) is a function defined on the set of non negative integers and having co-domain also as set
of non negative integers, given that
(i) x-f(x) = 20[ x ] -so [ f~~) ] and (ii) 1990 < f(2020) < 2050.
20
Then possible values of f(2020) can take (where[.] denote greatest integer function)
(A) 1920
(B) 3960
(C) 2000
(D) 4000
2
6x-5-x x :-;; 3
41. A function f(x) is defined as f ( x ) ={ 2
24x-32-4x x>3
Tangents are made on f(x) in the first quadrant. Let tangents T 1 : y = m1x + b1 and
T2 : y = m2x + b2 have highest and lowest y intercepts of all tangents made in first quadrant then
(A) b1 + b2 = 36
(B) b1 + b2 = 28
(C) m1 + m2 = -4
(D) area made by y axis, T 1 =0 and T2 = 0 is 54 square units
42. Let f: R ➔ R be given by f(x) = (x - 2)(x - 6)(x2 - 7x + 10)(x - 10). Define F ( x ) = ff ( t ) dt, x > 0.
0
Then w hich of the follow ing options is/are correct?
(A) F(x) has a local minimum at x = 5
(B) F(x) has a local maximum at x = 10
(C) F(x) has a local maximum at x = 2
(D) F(x) has, two local minima and one local maxima in (0, oo)
SECTION-B
43. If f(x) is a differentiable function in interval (- oo, oo) such that f(x) = f(16 - x ), then the value
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[l 2 2
f' ( 8 + x) x e x ] is equal of (w here [.] denote greatest integer function )
44. Let f ( x) = { ln( x -[x]) ' x !l: 1 . Area enclosed by the curve y =f(x), y =f(lxl), -2 :-;; x :-;; 0 and y = 0
0 , x El
is k - loge p , then k + p is equal to
2 2 2
1 9
45. For the function f ( x) = lim In([ + x D- 9" ~ " cos ( 9x ) number of points of discontinuity in
n ➔oo 1 + 9"x n
(-3, 3 ) is
f (x)
46. If f(x) = ao + a1 x + a2x2 + a3X2 + a3X3 + ..... anx" + ..... and
- - = bo + b1x + b2x 2 + ..... bnX" + ..... If
1-x
ao = 1, b1 = 3 and b3 = k, then area bounded by the y(1 + x 2) = k, x-axis, y-axis and x = ,,/3 is A ,
then [A] is (where[.] denotes greatest integer function) (Given ao, a1 , a2, ..... are in G.P.)
47. A curve y = f(x) w hose differential equation is given by x dy + 4 In x dx = 2(y + 1)dx passes
through (1, 3), then [ f ( ../2)] is equal to (where [.] denotes greatest integer function)
~2 . 2 . n~ 2
48. Le t I1 -- J Sin . X + Sin X d x and I --
2
J cos X + cos. X d x , then -11 1s
. equa I t o
1 + Sin X + COS X 1 + COS X + Sin X 12
0 0
SECTION-C
rr/2 rr/2 I
49. Let 11 = J 1
(cos x)../2+ dx and 12 = J(cos x)../2- dx, then f (take J2 = 1.41) is equal to
1
0 O 2
50. Let f(x) = ao + a1x + a2x2 + a3x3 + a4x4 + asx5 be a polynomial to degree 5 w hich increases in the
88
interval {----<Xl, 1) and [3, CXl} and decreases in the interval (1 , 3). Given that f(0) = 2, f ( 1) = and
15
f'(2) = 0, then as is equal to
. sin(t3)-t3 cos(t3)+t15 _
51. llm ( ) 1s equal to
t➔O t3 e3t3 -1- 3t3
x+2 1 .
52. If
f ✓x
---;=========
4
+8x +20x2 +16x+4
3
=-lnf (x)+ c , then f(1) 1s equal to
2
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53. Let f(x) be a differentiable function such that f '(x) + f(x) = 4xe-x sin 2x and f(0) = 0.
7
( (4n+1)n ) --"- ( e~krr -1 J
lf~f =e 4 e-rr_ , thenkisequalto
4 1
54. Let f: R ➔ Rand g : R ➔ R be two bijective function such that they are mirror image of each
other about the 4y - 17 = 0. If h(x) =f(x) + g(x}, then h(0) is equal to
FIITJEE
PART TEST- I
JEE (Advanced)-2021
PAPER-2
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Physics PART-I
SECTION-A
1. A, C, D
Sol. When the pivot point is changed the speed of
central point changes suddenly and the kinetic
energy is lost. Velocity component perpendicular
to new spoke survives.
Average velocity becomes constant when the
loss
in K.E. due to changing contact point = gain in
P.E.
-.!mv~( 1-cos2 2:) = mg.e. 2sin2:sina

2 3 6
2. C, D
Sol. The force on the particle is not the central force.
3. A, B,C, D
Sol. ... (i)
ay - ax = a2 ... (ii)
=0
acm(x)
2a2 = a1 + ax ... (iii)
4. A, B
Sol. L= mver ... (i)
dl
- = - U V0r
dt
dl al
⇒ -=-- from (i)
dt m
1
dl a
⇒ f-
LL
L
=--f
mo
dt
0
5. A, C,D
Sol. 3TA = 4TB TA cos 37°
4TA + 3TB =mg ⇒ TB =~mg

5 5 5 TB cos 53°
TB
TB sin 53°
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6. A, B,C
T T
Sol. Ta1 + 2a 2 + 4a3 + ..... = 0
)+i(2: )+¾(4: )+ .... O

( : -g -g - g =
: (1+¾+1~ + ........) = 9(1+; +¾+·······)

T = 3mg
2
SECTION-8
7. 1
Sol. [ < co > = ~~]

8.
Sol. Writing equation of motion in

y-direction
1 (T
y=2g 2
1)
2
g = T2 - T2
2 1
9. 3
Sol. For a pure rolling motion m, R
a= aR
Using conservation of energy
mg =
R 1 2
2 2
1pro
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R 1
mg- =-x4mR2
2 2
ro 2
⇒ ro=f& ... (i) P fs
Tp =1Pa
2m(g + ro R)-R2 = 4mR a
2 2
CM
2m( g+~) R =4mR2 a ⇒ a =~ .. .(ii)

ro2RJ~
4 2 16R aR/2
f5 = 2m ( a - ro:R)
5
f = 2m ( g _ _l;!) f = 3 mg
s 16 8 ' s 8
10. 3
Sol. ... ...

... ... Vy
... ...
... ...
... ...
...
',
', ...
- - - - _..,, ...
LJ
V
2
11. 4
Sol. Tangential component of force = Vor2 sin0
Magnitude of the x-component of force= Vor2sin2 0.
12. 7
Sol. 4
-nRp 3
-dv + v-
d ( -4 nRp
3 ) 4 3
=-nRpg.
1 1 1
3 ' dt dt 3 3
dv dR
R- + 3v-=Rg
dt dt ... (i)
dm2
Also, nR vp2 = -
dt
4p, dR
V=-.- . . . (ii)
P2 dt
After a long time w hen acceleration becomes constant v = at will satisfy our differential equation .
V = at V = 4 P, dR
p2 dt
R = at2p2
8p,
From equation (i) and (ii)
at2p 2a + 3p2 (at)2 = at2p 2g
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8p, 4p, 8p,
a 3a g
- + -=-
8 4 8
a=~
7
SECTION-C
13. 00100.00
Sol. 5V2 = 50 x 103
V = 102 ms-1
14. 00060.00
5 5 5 mis
Sol. ⇒ a = 30°
sin a sin30°
15. 00000.50
1 2 1 2
Sol. -mv 2 =-mv1 + mg.e
2 2
v~Y = v;Y+ 2g.e
... (i)
ev 2Y = v,y
V 1x =V 2 x =
2(1-e)
-gf
1+e -- =0.50 m/s
16. 00008.66
Sol. R✓3 =10x 1 ·732 =8.66 cm
2 2
17. 00011.42
Sol. Centre of mass should not cross the corner
d= -1 + -1 + -1 + -1 + - 1 ) x 10 cm = 11.42 cm
( 2 4 6 8 10
18. 00031 .00

Sol. I oc h5
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Chemistry PART- II
SECTION-A
19.
400°c
Sol.
Na2O2 + 0 2 45o•c NaO2
Na2O2 + H2O-----..+2NaOH + H2O2
20. A, B, C
Sol. NaOH + P4 -----..+PH3 + NaH2PO2
S8 + NaOH-----..+Na2S + Na 2SO3
Cl2 + NaOH-----..+NaCI + NaClO3
B + NaOH-----..+Na3 BO3 + H2
21. A,B,D
22. A, B, C
Sol. (D) four oxygen atoms are shared.
23. A, B, C
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Sol. AI 4 C 3 + H2O-----..+Al(OH)3 +CH4
CaC2 +H2O-----..+Ca(OH)2 +C2H2
24. A, B
SECTION-B
25. 9
Sol. 5U(SO4 ) 2 +2Hp +2KMnO4 -----..+2MnSO4 +5UO2SO 4 +2H2SO4 +K 2SO4
26. 8
Sol. 100 ml water contain = 0.192 mg
1000 ml water contain= 1.92 mg
.. +2 1.92
Milli mole of Mg = - - = 0.08
24
Hence milli mole of CaCO3 = 0.08
Hence mass of CaCO 3 with 1L = 0.08 x 100 = 8 mg
Hardness will be = 8 ppm.
27. 3
Sol. 60 = ::( ~J
28. 6
Sol. A + B ~ C + D
0.4 + x 0.4+ x 2-x 2-x Kc = 16
X = 0.08
[B] eq = (0.40.08
+ 0.08) =
6
29. 4
Sol. u 238 ----+ Pb206 + 8a + 6A
92 82 f-'
23 24
[ 4-4 GJ]x 8 x 6.02 x 10 =18.066 x 10
n=4
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30. 4
[ CH3Coo-·]
Sol. 5.35 = 4.75 + log [CH COOH]
3
[ CH3Coo-,]
----- = 4
[CH3COOH]
SECTION-C
31. 00025.02
30
Sol. % = 1.2 x 3.336 x 10- x 100%
19
1.6 x 10- x 10- 10
3 x 3.336 x 10
= 4
= 25.02%
Hence, x = 25.02
32. 00005.60
80
Sol. pH= 5 + 1og
20
= 5+ 1og4 = 5.6
33. 00001 .20
Sol. K4[ Fe (CN)6] + 6H2SO 4 + 6Hp ~ 2 K 2SO 4 + FeSO 4 + 3 (NH4) 2SO 4 + 6CO t
5CO + 120 5 ---...+5CO2 + 12
34. 00000.48
Sol. Np3 (g)~N02 (g) + NO
2-x x-2y x
2N02 (g)~N2 0 4 (g)
x-2y y
Given x = 1.5
2.5 = (1.5-2y)(1.5)
0.5
35. 00000.69
36. 00000.28
Sol. 2 A ~ 2B + 3C + D
0.24 0.36 0.12
XA = (1-0.72) = 0.28
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SECTION-A
37. B, C
s12 { x 113}
Sol. I1 = f --dx.
"ef;!
Let x 113
=t ⇒ ~ = -.!.x-213
dx 3
0
8 1 1
⇒ 11 =3f {t} dt=3 x 8 x f {t} dt=24 x -=12
0 0 2
2
12 f
= x
2 3
{ x } dx . Let x3 =t ⇒ 3x2 dx = dt
0
8 1
1 1 8 1 4
= - f {t} dt=- x 8 x f { t} dt=- x -=-
30 3 0 3 2 3
38. A, C
2
-6x -1 < X < - -
3
2 2
Sol. f (x) = 4 -- s X S -
3 3
2
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6x - <X<1 -1 -1 /3 2/3 1
3
g(x) = {x}
2
0 s{x}s -
14 :. f(g(x)) =
2
3 :. c = I and d = 3
6 {x} - <{X}< 1
3
39. A, B,C, D
Sol. (A) f1x tan xdx ~ f1x (x + ~33J dx ~ -25
0 0
(B)
1
fx 2
cos x s fx dx s -31
1
2
0 0
(C)
1
fx 3
1
f
sin x ~ x3 ( x - -x 3 ~ -37 J
0 0 3! 210
(D) x sin x is an even function
o
:. fxsinx=fxsinx
1
~ fx ( x-
1
x3 Jdx ~ -3
-1 0 0
13. 10
40. A, C
Sol. 1990 < f (2020) < 2050 ⇒ If (2020)1 = 24 or 25
80 80 80 L 80
Now put x =2020 we get f(2O2O) = 1920 or 2000
41. B,C,D
-(x-1)(x-5)
Sol. f(x) ={
-4(x-2)(x-4)
Lowest y intercept will be of tangent made on (1 , 0) and
highest y intercept will be of tangent made on (4, 0)
tangent at (1 , 0) is y = 4x - 4 .-. m2 = 4, b2 = -4 and
tangent at (4, 0) is y = -8x + 32 .-. m1 = -8, b1 = 32
42. A, D
Sol. F'(x) = f(x) = (x - 2)2(x - 5)(x - 6)(x - 10)
+ +
5 6 10
F'(x) changes sign from negative to positive at 5 and 10
.-. F(x) has local minima at x > 5, 10, F(x) has local maxima at x = 6
SECTION-B
43. 0
Sol. f(8 - x) = f(8 + x) ⇒ f'(8 - x) = -f'(8 + x)
B B
I= f f'(8 + x)x2ex dx = -f f'(8-x)x2ex dx = -I ⇒ I= 0
2 2
-S -8
44. 6
0 y = f(x)
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Sol. Area= 2 x 2 x f ln{x} dx
-1/2
f = 14 x
1/2
(In xdx)I
= l4(xlnx-x)l;,2
= 14( -1- ( ~1n~-~))I
= 4 ( _!_+_!_1n_!_) =2(1-ln2)
2 2 2
= 2 - 2 In 2 = 2 - In 4 .-. k = 2 and p = 4
45. 2
0 Os 9x2 < 1
Sol. f (X) __ In 2 - cos 1 9 x2 __ 1 d.1scont·muous at x = ± -1

2 3
{
-cos9x 2 9x 2 > 1
46. 7
Sol. Comparing the coefficient of x" both sides we get bn - bn - 1 = an
Also, bo = ao and b1 = ao + a1 ⇒ bo = 1, a1 = 2
.-. b3 = ao + a1 + a2 = 1 + 2 + 4 = 7
7
Area bounded by y = - -
1+x2
✓3
. y-axis
x-axis, . and x = -1t w1·11 be
3
f 7 d
--
1+x2
x = -ln
3
0
47. 6
Sol. xdy -2y=2-4Inx ⇒ dy _'l:_Y= 2 - 4 lnx
dx dx x x
2 2
-J3.dx 1 y-1-=J 2-4Inx ⇒ _1__= __1 _ ( 1nxx- + x- J+c
I. F = e x = ~ .-. x2 x3 x2 x2 4 -2 -4
⇒ y = cx2 + 2 In x ·.- it passes through (1 , 3) .-. c = 3 .-. y = 3x2 + 2 In x
48. 1
1t/2
Sol. 11 + 12 = J 1• dx = %
0
I1 - I2 =
1t/2 . 2 2 .
sin x - cos x + sin x - cosx d
. X =
1t/2
f(.
)d
Sin X - COS X X = 0
J 1+smx + cosx
0 0
71:
.-. 11 = 12 = -
4
SECTION-C
49. 00000.59
1t/2 2" 1t/2
Sol. J
11 = ( cosx).,/2cosxdx= (cosx ).,/2sinx +.fi f (cosx).J2- 1 sin 2 xdx
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0 o 0
⇒ 11 = ✓212 - ✓211 ⇒ .!i_ = ✓2,-;:; = 2- ✓2 = 2-1 .41 = 0.59

12 1+v2
50. 00000.20
Sol. f
f'(x) = k(x - 1)(x - 3)(x - 2)2 and k > O ⇒ f(x) = k (x2 - 4x + 3)(x2 -4x + 4)dx
4 2 3 2 4 2 3 2
= kfx + 16x -8x + 7(x -4x)+ 12dx= k ( ~ -2x + ~x -14x +12xJ + c
88 ⇒ -
·: f(0)=2 ⇒ c=2 .-. f (1) = - 88= k ( --2+--14
1 23 + 12) + c
15 15 5 3
58 58 1
⇒ =k x ⇒ k = 1 .-. a 5 =
15 15 5
51. 00000.07
. sinx-xcosx + x 5
Sol. Let t3 = x ⇒
I1m - - - - - - -
X➔D x(e 3x -1-3x)
Now use expansions of sin x, cos x and e 3x
52. 00007.00
x+2 dt dt
Sol.
f
I= -== ======- Let(x+2) 2 =t ⇒ -=2(x + 2) ⇒ -=(x + 2) dx
✓(x + 2) - 4 (x + 2) + 4
4 2
dx 2
⇒ l=..!_J 1
dt ⇒ 1
l=..!_J--dt=..!_1nlt-2l + c
2 .Jt2-4t+4 2 t-2 2
= ~1nlcx + 2/ -2l + c .-. f(x)=x2 +4x+2

2
53. 00008.00
Sol. . .
I.F=ex :.solut1on1sf(x)ex= f .
4 x s1n2xdx ⇒ f
(x)e x
=4 ( -xcos2x + -sin2x
- )
2 4
⇒ f(x) = (-2x cos 2x + sin 2x)e-x, t ( ¾) = e-¾
(5rc) - 5
:. f - =e 4"
4
54. 00008.50
17 17 17
Sol. -t (x) =- + g( x) ⇒ f ( x )+ g(x) = Vx ER
4 4 2
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Fl ITJEE

ALL INDIA TEST SERIES

TEST DATE: 04-01-2021

Time Allotted: 3 Hours Maximum Marks: 198

• The test consist s of t ot al 54 questions.

• This question paper contains Three Parts.

• Part-I is Physics, Part-II is Chemistry and Part-Ill is Mathemat ics.

• Each Part is f urther divided into Tw o Sections: Section-A & Section-C.

1. A particle is ejected from the tube at A w ith a velocity v at an

4. Water of density p in a clean aquarium forms a meniscus, as

(One or More than one correct type)

8. Three concentric conducting spherical shells have radii r, 2r and 3r

11. A rod OA of length / is rotating (about end 0) over a conducting ring X X X X

14. A diver Dis still under water (µ=1) at a depth d = 10

m. A bird is diving along line AB at a constant velocity in

15. A wall is inclined to a horizontal surface at an

16. A room is in shape of a cube. A heavy ball (B) is suspended at

-~ -.. -... -.... ..--. -- ..... --. . -

21. When H2S is passed in Ba(OH)2 solution:

23. Two solid compounds X and Y dissociates at a certain temperature as follows

(One or More than one correct type)

27. Which of the following is/are correct?

28. Ionisation energy order is CORRECT for:

Mathematics PART - 111

38. The value of J----==---=1= = = X is

40. Number of solutions of lz - 11 + lz + ii = 4 and 12z - 1 + ii = ✓14 is

Lasin A cos ( B-C )

(One or More than one correct type)

46. lfin ~ ABC, a 4 + b4 + c 4 = 2a 2 (b 2 + c 2 ), then L A is

50. Shortest distance between lines x- 6 = y - 2 = 2 - 2 and x+ 4 = y = 2 + 1 is d then

TEST DATE: 04-01-2021

ANSWERS, HINlS & SOLUTIONS

Writing equilibrium equation

~ "i ___,. ~ "2 ___,.

x-xo = £1 +£2 -2£0 ... (iii)

=-1 ✓Vgp /2p-pJ

For the disc, 11 = 2mr2

By conservation of angular momentum, r

Final kinetic energy = E2 = ! (11 + 12 )co~

~ + ~ + ~ = 0 ⇒ q, + q3 = -q2 ... (2)

939.5656 = 938.2723 + 0.5109 + 0.0004 + (kP + ke)

16. 00001 .15

The string CB and DB make an angle of a = cos-

cube makes cos-

2T0 = 2T1 cos 0 = 2T1 JI

With dielectric, similar calculation gives

For 1m length of the pipe

Moles of A convert into product Imai

Kp2 = Pc .Pg (total)

Mathematics PART- Ill

= -~J-1-dt = ~t-113 = ~ [ - x -] 113 +c -

La (cosB + cosC ) 2R L 2acos( B; C ) cos( B; C ) 2R

Lsin A cos ( -B-C)

1 2±8✓2 ,,; ,,; ,,;

In ( -~ ,O} [1 + sinx] = 0, [1-cosx] = 0

In ( 0,~ } [1 + sinx] = 1,[1-cosx] = 0

In ( ~ , n:} [ 1 + sin x] = 1, [ 1- cos x] = 1

cos A = - ~ = cos ( re - ~ ) = cos 34re

Sol. log../3 tans

Let log../3 tan 0 = y

Equation of the chord of contact is tx + _J_ (24 - 3t) = 1

fixed point = ( ¾,¾J, which lies on 16x - 3y = 0, 9y2 = 32 x and 24 x + 24 y = 19.

Time Allotted: 3 Hours Maximum Marks: 198

• The test consists of total 54 questions.

~ "i _,. ~ "2 _,.