Alat dan Bahan

Alat :
1. Labu Ukur 250 mL 1 buah 10. Gelas beaker
2. Corong Gelas 11. Kertas saring
3. Bulp Pipet 12. Labu erlenmeyer 250 mL 3 buah
4. Tisu 13. Pipet tetes
5. Botol semprot 14. Pipet volume 25 mL
6. Neraca analitik 15. Gelas ukur
7. Botol timbang 16. Buret
8. Batang pengaduk 17. Statif dan klem
9. Sendok 18. Mortal & pestle
Bahan :
1. Zn(CH 3 COO)2 padat
2. Etilen Diamine Tetra Asetat (EBT) 1% 100 mg
3. NaCl 9900 mg
4. NH 3142 mL
5. Na4 Cl 17,5 gram
6. Aquadest

Data :
 Pembuatan Zn(CH 3 COO)2
Gram 1000
N Zn(CH 3 COO)2 = ×
Bm mL
Gram 1000
0,01N Zn(CH 3 COO)2= ×
219,5 250
2019,5× 0,01
gr Zn(CH 3 COO)2 =
4
gr Zn(CH 3 COO)2 = 0,5487 gram
Maka dibutuhkan padatan Zn(CH 3 COO)2 sebanyak 0,5487 gram untuk
membuat larutan Zn(CH 3 COO)20,01N.

 Penimbangan Zn(CH 3 COO)2

Massa awal = 20,0058 gram
Penambahan ± 10% =
 20,0058 + 0,55 = 20,5558 gram
20,0058 + 0,45 = 20,4558 gram
Massa akhir = 20,5068 gram
Hasil akhir = 20,5068 gram – 20,0058 gram
= 0,501 gram
 Konsentrasi Zn(CH 3 COO)2
gram 1000
N Zn(CH 3 COO)2 = ×
BE mL
0,501 1000
= ×
219,5 250 mL
= 0,0091298405 N
= 0,0091 N
 Volume Titrasi
Percobaan Volume Volume Volume Volume Buffer PH EBT
Zn(CH 3 COO)2 Awal Akhir Titrasi 10
EDTA EDTA
1 25 mL 7,15 mL 30,47 mL 23,32 mL 2 mL 40 mg
2 25 mL 9,43 mL 32,57 mL 23,14 mL 2 mL 40 mg
3 25 mL 9,97 mL 33,15 mL 23,18 mL 2 mL 40 mg

 Normalitas EDTA
Mek EDTA = Mek Zn(CH 3 COO)2
N EDTA × mLEDTA= N Zn(CH 3 COO)2 × mL Zn(CH 3 COO)2
N Zn(CH 3 COO)2 × mL Zn(CH 3 COO)2
N EDTA =
mL EDTA
0,0091 N ×25 mL
 N1 EDTA =
23,32 mL
= 0,0097555746 N
= 0,0097 N
0,0091 N ×25 mL
 N2 HCl =
23,14 mL
= 0,00983146067 N
= 0,0098 N
0,0091 N ×25 mL
 N3 HCl =
23,18 mL
 = 0,00981449525 N
= 0,0098 N

 Rata-rata normalitas EDTA

N 1+ N 2+ N 3
Rata-rata N EDTA =
3
0,0097+0,0098+0,0098
=
3
= 0,0097666667 N
Rata-rata N EDTA = 0,0098 N

 Rata-rata deviasi dan deviasi rata-rata relatif

∑ ⎸ (N−N rata−rata) ⎸
Rata-rata deviasi =
3
=
⎸ (0,0097−0,0098)+(0,0098−0,0098)+(0,0098−0,0098) ⎸
3
⎸ 0,0001+0+ 0 ⎸
=
3
= 0,0000333333
= 0,00003
 Deviasi rata-rata relatif
Rata−rata deviasi
= × 1000
N rata−rata
0,00003
= × 1000
0,0098 N
= 3,0612244898 ppt
= 3,0612 ppt