LAMPIRAN PERHITUNGAN

Konsentrasi N V titrasi 1 V titrasi 2 V rata-rata NaOH

(mL) (mL) (ml)
0.015 2.7 2.7 2.7
0.03 6.3 6.2 6.25
0.06 13.7 14.1 13.9
0.09 21.6 22.6 22.1
0.12 30.2 30.1 30.15
0.15 37.4 38.9 38.15
0.03 (control) 7.2 8.5 7.85

Konsentrasi N Mol Mol CH3COOH Mol CH3COOH

CH3COOH akhir (mol)
awal (mol)
teradsorpsi
(mol)
0.015 0,00123 mol 0,0015 mol 0,00027 mol
0.03 0,002375 mol 0,003 mol 0,000625 mol
0.06 0,00461 mol 0,006 mol 0,00139 mol
0.09 0,00679 mol 0,009 mol 0,00221 mol
0.12 0,008985 mol 0,012 mol 0,003015 mol
0.15 0,011185 mol 0,015 mol 0,003815 mol

Konsentrasi N N CH3COOH N CH3COOH C

setelah di N
akhir
titrasi
0.015 0.00126 mol 0,00123 mol 8,7804878
0.03 0.00247 mol 0,002375 mol 10,5263157
0.06 0.00493 mol 0, 0,00461 mol 12,0607375
0.09 0.00744 mol 0,00679 mol 13,0191458
0.12 0.01013 mol 0,008985 mol 13,4223706
0.15 0.01298 mol 0,011185 mol 13,6432722

1. Perhitungan Pengenceran CH3COOH (Tyara Qisti Aisyah)

a. CH3COOH 0,15 N
V1 . N1 = V2 . N2
V1 . 1 = 100 . 0,15N
 V1 = 15 mL

b. CH3COOH 0,12 N
V1 . N1 = V2 . N2
V1 . 1 = 100 . 0,12N
V1 = 12 mL
c. CH3COOH 0,09 N
V1 . N1 = V2 . N2
V1 . 1 = 100 . 0,09N
V1 = 9 mL
d. CH3COOH 0,06 N
V1 . N1 = V2 . N2
V1 . 1 = 100 . 0,06N
V1 = 6 mL
e. CH3COOH 0,03 N
V1 . N1 = V2 . N2
V1 . 1 = 100 . 0,03 N
V1 = 3 mL
f. CH3COOH 0,015 N
V1 . N1 = V2 . N2
V1 . 1 = 100 . 0,015N
V1 = 1,5 mL

2. Perhitungan Konsentrasi CH3COOH Sebelum dan Sesudah Adsorbsi

a. CH3COOH 0,15 N
V NaOH
N CH COOH = × N NaOH
3
V CH COOH
3

38 , 15 mL
N CH COOH = ×0 , 1 N
3
25 mL
N CH COOH =0,1526 N
3

Mol CH3COOH awal = [CH3COOH] × 0,1 L

= 0,15 N × 0,1 L
= 0,015 mol
Mol CH3COOH akhir = [CH3COOH] × 0,025 L
 = 0,1526 N × 0,025 L
= 0,003815 mol
Mol CH3COOH teradsorbsi = mol awal – mol akhir
= 0,015 mol – 0,003815 mol
= 0,011185 mol
Mol teradsorbsi
N CH COOH akhir =
3
1g

0,011185 mol
N CH COOH akhir =
3
1g

N CH COOH akhir =0,011185mol / g

3

C 0,1526 mol /g
=
N 0,011185 mol /g

C
=13,6432722
N

b. CH3COOH 0,12 N
V NaOH
N CH COOH = × N NaOH
3
V CH COOH
3

30 , 15 mL
N CH COOH = ×0 , 1 N
3
25 mL
N CH COOH =0,1206 N
3

Mol CH3COOH awal = [CH3COOH] × 0,1 L

= 0,12 N × 0,1 L
= 0,012 mol
Mol CH3COOH akhir = [CH3COOH] × 0,025 L
= 0,1206 N × 0,025 L
= 0,003015 mol
Mol CH3COOH teradsorbsi = mol awal – mol akhir
= 0,012 mol – 0,003015 mol
= 0,008985 mol
Mol teradsorbsi
N CH COOH akhir =
3
1g

0,008985 mol
N CH COOH akhir =
3
1g
 N CH COOH akhir =0,008985 mol/ g
3

C 0,1206 mol/ g
=
N 0,008985 mol / g

C
=13,4223706
N

c. CH3COOH 0,09 N
V NaOH
N CH COOH = × N NaOH
3
V CH COOH
3

22 , 1 mL
N CH COOH = × 0 ,1 N
3
25 mL
N CH COOH =0,0884 N
3

Mol CH3COOH awal = [CH3COOH] × 0,1 L

= 0,09 N × 0,1 L
= 0,009 mol
Mol CH3COOH akhir = [CH3COOH] × 0,025 L
= 0,0884 N × 0,025 L
= 0,00221 mol
Mol CH3COOH teradsorbsi = mol awal – mol akhir
= 0,009 mol – 0,00221 mol
= 0,00679 mol
Mol teradsorbsi
N CH COOH akhir =
3
1g

0,00679 mol
N CH COOH akhir =
3
1g

N CH COOH akhir =0,00679 mol/ g

3

C 0,0884 mol/ g
=
N 0,00679 mol / g

C
=13,0191458
N

d. CH3COOH 0,06 N
V NaOH
N CH COOH = × N NaOH
3
V CH COOH
3
 13 , 9 mL
N CH COOH = ×0 , 1 N
3
25 mL
N CH COOH =0,0556 N
3

Mol CH3COOH awal = [CH3COOH] × 0,1 L

= 0,06 N × 0,1 L
= 0,006 mol
Mol CH3COOH akhir = [CH3COOH] × 0,025 L
= 0,0556 N × 0,025 L
= 0,00139 mol
Mol CH3COOH teradsorbsi = mol awal – mol akhir
= 0,006 mol – 0,00139 mol
= 0,00461 mol
Mol teradsorbsi
N CH COOH akhir =
3
1g

0,00461 mol
N CH COOH akhir =
3
1g

N CH COOH akhir =0,00461mol / g

3

C 0,0556 mol / g
=
N 0,00461 mol /g

C
=12,0607375
N

e. CH3COOH 0,03 N
V NaOH
N CH COOH = × N NaOH
3
V CH COOH
3

6 ,25 mL
N CH COOH = ×0 ,1 N
3
25 mL
N CH COOH =0,025 N
3

Mol CH3COOH awal = [CH3COOH] × 0,1 L

= 0,03 N × 0,1 L
= 0,003 mol
Mol CH3COOH akhir = [CH3COOH] × 0,025 L
= 0,025 N × 0,025 L
= 0,000625 mol
 Mol CH3COOH teradsorbsi = mol awal – mol akhir
= 0,003 mol – 0,000625 mol
= 0,002375 mol
Mol teradsorbsi
N CH COOH akhir =
3
1g

0,002375 mol
N CH COOH akhir =
3
1g

N CH COOH akhir =0,002375 mol/ g

3

C 0,025 mol / g
=
N 0,002375 mol / g

C
=10,5263157
N

f. CH3COOH 0,015 N
V NaOH
N CH COOH = × N NaOH
3
V CH COOH
3

2 , 7 mL
N CH COOH = ×0 , 1 N
3
25 mL
N CH COOH =0,0108 N
3

Mol CH3COOH awal = [CH3COOH] × 0,1 L

= 0,015 N × 0,1 L
= 0,0015 mol
Mol CH3COOH akhir = [CH3COOH] × 0,025 L
= 0,0108 N × 0,025 L
= 0,00027 mol
Mol CH3COOH teradsorbsi = mol awal – mol akhir
= 0,0015 mol – 0,00027 mol
= 0,00123 mol
Mol teradsorbsi
N CH COOH akhir =
3
1g

0,00123 mol
N CH COOH akhir =
3
1g

N CH COOH akhir =0,00123 mol/ g

3
 C 0,0108 mol / g
=
N 0,00123 mol / g

C
=8,7804878
N

3. Perhitungan Nm pada berbagai konsentrasi CH3COOH

Rumus :
C
=
C
N Nm k
1
+ ×N
[ ]
No. N akhir C/N C Nm
1 0.01119 13.643272 0.1526 0.01298
2 0.00899 13.422371 0.1206 0.01013
3 0.00679 13.019146 0.0884 0.00744
4 0.00461 12.060738 0.0556 0.00493
5 0.00238 10.526316 0.025 0.00247
6 0.00123 8.7804878 0.0108 0.00126
K = 0.00594
a. CH3COOH 0,15 N
C
=
C
N Nm k
1
+ ×N
[ ]
13.643272=
0.1526
Nm
+
[ 1
0.00594
×0.01119
]
Nm = 0.01298 mol
b. CH3COOH 0,12 N
C
=
C
N Nm k
1
+ ×N
[ ]
13.422371=
0.1206
Nm
+
[ 1
0.00594
×0.00899
]
Nm = 0.01013 mol
c. CH3COOH 0,09 N

13.019146=
0.0884
Nm
+
[ 1
0.00594
× 0.00679
]
Nm = 0.00744 mol
d. CH3COOH 0,06 N

12.060738=
0.0556
Nm
+
[ 1
0.00594
× 0.00461
]
 Nm = 0.00493 mol
e. CH3COOH 0,03 N

10.526316=
0.025
Nm [
+
1
0.00594
× 0.00238
]
Nm = 0.00247 mol
f. CH3COOH 0,015 N

8.7804878=
0.0108
Nm
+
[ 1
0.00594
× 0.00123
]
Nm = 0.00126 mol
Mencari persamaan garis m dan c:

No. N akhir (x) C xy x2

(y)
N
1. 0.011185 13.6432722 0.1525999 1.2510422 x 10-4
2. 0.008985 13.4223706 0.1205999 0.8073022 x 10-4
3. 0.00679 13.0191458 0.0883999 0.461041 x 10-4
4. 0.00461 12.0607375 0.0555999 0.212521 x 10-4
5. 0.002375 10.5263157 0.0249999 0.0564062 x 10-4
6. 0.00123 8.7804878 0.0107999 0.015129 x 10-4
∑ 0.035175 71.4523296 0.4529994 2.8034416 x 10-4
Rata – rata 0.0058625 11.9087216 0.0754999 0.4672402 x 10-4

n ×∑ XY −∑ X ×∑ Y
m= 2 2
n ×∑ X −( ∑ X )

6 ×0.4529994−0.035175× 71.4523296
m= 2
6 ×0.00028034416−( 0.035175 )

m=460.13469404

Maka :

c= y−m . x

c=11.9087216−460. 13469404 ×0.0058625

c=11.9087216−2,6975396438

c=9.2111819562

y=mx+c

y=460. 13469 x +9.2111