A.

Analisis Data
1. Erlenmeyer 1
Diketahui : [CH3COOH] = 0,5000 M
Mr CH3COOH = 60 g/mol = 60 mg/mmol
V CH3COOH = 50 mL
[NaOH] = 0,1 M
1 +2 (19,0+17,7)
V rata-rata NaOH = = = 18,35 mL
2 2

Massa karbon aktif = 0,5 gram

V CH3COOH = 5 mL (filtrat)
x
Ditanyakan : log C dan log m =.....?

Penyelesaian:
mmol CH3COOH = (M V) CH3COOH
= 0,5000 mmol/mL 50 mL
= 25,0000 mmol
mmol NaOH = (M V) NaOH
= 0,1 mmol/mL 18,35 mL
= 1,8350 mmol
Reaksi : CH3COOH + NaOH CH3COONa + H2O
Mula-mula : 25,0000 mmol 1,8350 mmol - -
Bereaksi : 1,8350 mmol 1,8350 mmol 1,8350 mmol 1,8350 mmol
Setimbang : 23,1650 mmol - 1,8350 mmol 1,8350 mmol
mmol CH3COOH yang teradsorpi = mmol CH3COOH mmol NaOH
= 23,1650 mmol 1,8350 mmol
= 21,3300 mmol
Massa CH3COOH yang teradsorpsi = mmol CH3COOH yang teradsorpsi Mr
CH3COOH
= 21,3300 mmol 60 mg/mmol
= 1279,8 mg
= 1,2798 gram
x massa CH3 CCOH yang teradsorpsi
=
m massa karbon aktif
 1,2798 gram
=
0,5 gram

= 2,5596
x
log = log 2,5596
m
= 0,4081
mmol CH3 COOH yang teradsorpsi
C =
V CH3 COOH
21,3300 mmol
=
50 mL
= 0,4266 M
log C = [CH3COOH] yang teradsorpsi
= log 0,4266 M
= -0,3699 M
2. Erlenmeyer 2
Diketahui :[CH3COOH] = 0,250 M
Mr CH3COOH = 60 g/mol = 60 mg/mmol
V CH3COOH = 50 mL
[NaOH] = 0,1 M
1 +2 (2+1,6)
V rata-rata NaOH = = = 1,80 mL
2 2

Massa karbon aktif = 0,5 gram

V CH3COOH = 5 mL (filtrat)
x
Ditanyakan : log C dan log m =.....?

Penyelesaian:
mmol CH3COOH = (M V) CH3COOH
= 0,250 mmol/mL 50 mL
= 12,5000 mmol
mmol NaOH = (M V) NaOH
= 0,1 mmol/mL 1,80 mL
= 0,1800 mmol
Reaksi : CH3COOH + NaOH CH3COONa + H2O
Mula-mula : 12,5000 mmol 0,1800 mmol - -
Bereaksi : 0,1800 mmol 0,1800 mmol 0,1800 mmol 0,1800 mmol
Setimbang : 12,3200 mmol - 0,1800 mmol 0,1800 mmol
mmol CH3COOH yang teradsorpi = mmol CH3COOH mmol NaOH
= 12,3200 mmol 0,1800 mmol
= 12,1400 mmol
Massa CH3COOH yang teradsorpsi = mmol CH3COOH yang teradsorpsi Mr
CH3COOH
= 12,1400 mmol 60 mg/mmol
= 728,40 mg
= 0,7284 gram
x massa CH3 CCOH yang teradsorpsi
=
m massa karbon aktif
0,7284 gram
=
0,5 gram

= 1,4568
x
log = log 1,4568
m
= 0,1633
mmol CH3 COOH yang teradsorpsi
C =
V CH3 COOH
12,1400 mmol
=
50 mL
= 0,2428 M
log C = [CH3COOH] yang teradsorpsi
= log 0,2428 M
= -0,6055 M
3. Erlenmeyer 3
Diketahui :[CH3COOH] = 0,1250 M
Mr CH3COOH = 60 g/mol = 60 mg/mmol
V CH3COOH = 50 mL
[NaOH] = 0,1 M
1 +2 (1,6+4,6)
V rata-rata NaOH = = = 3,10 mL
2 2

Massa karbon aktif = 0,5 gram

 V CH3COOH = 12,5 mL (filtrat)
x
Ditanyakan : log C dan log m =.....?

Penyelesaian:
mmol CH3COOH = (M V) CH3COOH
= 0,1250 mmol/mL 50 mL
= 6,2500 mmol
mmol NaOH = (M V) NaOH
= 0,1 mmol/mL 3,10 mL
= 0,3100 mmol
Reaksi : CH3COOH + NaOH CH3COONa + H2O
Mula-mula : 6,2500 mmol 0,3100 mmol - -
Bereaksi : 0,3100 mmol 0,3100 mmol 0,3100 mmol 0,3100 mmol
Setimbang : 5,9400 mmol - 0,3100 mmol 0,3100 mmol
mmol CH3COOH yang teradsorpi = mmol CH3COOH mmol NaOH
= 5,9400 mmol 0,3100 mmol
= 5,6300 mmol
Massa CH3COOH yang teradsorpsi = mmol CH3COOH yang teradsorpsi Mr
CH3COOH
= 5,6300 mmol 60 mg/mmol
= 337,80 mg
= 0,3378 gram
x massa CH3 CCOH yang teradsorpsi
=
m massa karbon aktif
0,3378 gram
=
0,5 gram

= 0,6756
x
log m = log 0,6756

= -0,1703
mmol CH3 COOH yang teradsorpsi
C =
V CH3 COOH
5,6300 mmol
=
50 mL
 = 0,1126 M
log C = [CH3COOH] yang teradsorpsi
= log 0,1126 M
= -0,9484 M
4. Erlenmeyer 4
Diketahui :[CH3COOH] = 0,0625 M
Mr CH3COOH = 60 g/mol = 60 mg/mmol
V CH3COOH = 50 mL
[NaOH] = 0,1 M
1 +2 (12+10,5)
V rata-rata NaOH = = = 11,25 mL
2 2
Massa karbon aktif = 0,5 gram
V CH3COOH = 25 mL (filtrat)
x
Ditanyakan : log C dan log m =.....?

Penyelesaian:
mmol CH3COOH = (M V) CH3COOH
= 0,0625 mmol/mL 50 mL
= 3,1250 mmol
mmol NaOH = (M V) NaOH
= 0,1 mmol/mL 11,25 mL
= 1,1250 mmol
Reaksi : CH3COOH + NaOH CH3COONa + H2O
Mula-mula : 3,1250 mmol 1,1250 mmol - -
Bereaksi : 1,1250 mmol 1,1250 mmol 1,1250 mmol 1,1250 mmol
Setimbang : 2,0000 mmol - 1,1250 mmol 1,1250 mmol
mmol CH3COOH yang teradsorpi = mmol CH3COOH mmol NaOH
= 2,0000 mmol 1,1250 mmol
= 0,8750 mmol
Massa CH3COOH yang teradsorpsi = mmol CH3COOH yang teradsorpsi Mr
CH3COOH
= 0,8750 mmol 60 mg/mmol
 = 52,50 mg
= 0,0525 gram
x massa CH3 CCOH yang teradsorpsi
=
m massa karbon aktif
0,0525 gram
=
0,5 gram

= 0,1050
x
log = log 0,1050
m
= -0,9788
mmol CH3 COOH yang teradsorpsi
C =
V CH3 COOH
0,8750 mmol
=
50 mL
= 0,0175 M
log C = [CH3COOH] yang teradsorpsi
= log 0,0175 M
= -1,7569 M
5. Erlenmeyer 5
Diketahui : [CH3COOH] = 0,0313 M
Mr CH3COOH = 60 g/mol = 60 mg/mmol
V CH3COOH = 50 mL
[NaOH] = 0,1 M
1 +2 (1,4+0,9)
V rata-rata NaOH = = = 1,15 mL
2 2

Massa karbon aktif = 0,5 gram

V CH3COOH = 25 mL (filtrat)
x
Ditanyakan : log C dan log m =.....?

Penyelesaian:
mmol CH3COOH = (M V) CH3COOH
= 0,0313 mmol/mL 50 mL
= 1,5650 mmol
mmol NaOH = (M V) NaOH
 = 0,1 mmol/mL 1,15 mL
= 0,1150 mmol
Reaksi : CH3COOH + NaOH CH3COONa + H2O
Mula-mula : 1,5650 mmol 0,1150 mmol - -
Bereaksi : 0,1150 mmol 0,1150 mmol 0,1150 mmol 0,1150 mmol
Setimbang : 1,4500 mmol - 0,1150 mmol 0,1150 mmol
mmol CH3COOH yang teradsorpi = mmol CH3COOH mmol NaOH
= 1,4500 mmol 0,1150 mmol
= 1,3350 mmol
Massa CH3COOH yang teradsorpsi = mmol CH3COOH yang teradsorpsi Mr
CH3COOH
= 1,3350 mmol 60 mg/mmol
= 80,10 mg
= 0,0801 gram
x massa CH3 CCOH yang teradsorpsi
=
m massa karbon aktif
0,0801 gram
=
0,5 gram

= 0,1602
x
log m = log 0,1602

= -0,7953
mmol CH3 COOH yang teradsorpsi
C =
V CH3 COOH
1,3350 mmol
=
50 mL
= 0,0267 M
log C = [CH3COOH] yang teradsorpsi
= log 0,0267 M
= -1,5734 M
6. Erlenmeyer 6
Diketahui :[CH3COOH] = 0,0156 M
Mr CH3COOH = 60 g/mol = 60 mg/mmol
 V CH3COOH = 50 mL
[NaOH] = 0,1 M
1 +2 (0,1+0,1)
V rata-rata NaOH = = = 0,10 mL
2 2

Massa karbon aktif = 0,5 gram

V CH3COOH = 25 mL (filtrat)
x
Ditanyakan : log C dan log m =.....?

Penyelesaian:
mmol CH3COOH = (M V) CH3COOH
= 0,0156 mmol/mL 50 mL
= 0,7800 mmol
mmol NaOH = (M V) NaOH
= 0,1 mmol/mL 0,10 mL
= 0,0100 mmol
Reaksi : CH3COOH + NaOH CH3COONa + H2O
Mula-mula : 0,7800 mmol 0,0100 mmol - -
Bereaksi : 0,0100 mmol 0,0100 mmol 0,0100 mmol 0,0100 mmol
Setimbang : 0,7700 mmol - 0,0100 mmol 0,0100 mmol
mmol CH3COOH yang teradsorpi = mmol CH3COOH mmol NaOH
= 0,7700 mmol 0,0100 mmol
= 0,7600 mmol
Massa CH3COOH yang teradsorpsi = mmol CH3COOH yang teradsorpsi Mr
CH3COOH
= 0,7600 mmol 60 mg/mmol
= 45,60 mg
= 0,0456 gram
x massa CH3 CCOH yang teradsorpsi
=
m massa karbon aktif
0,0456 gram
=
0,5 gram

= 0,0912
x
log = log 0,0912
m
 = -1,0400
mmol CH3 COOH yang teradsorpsi
C =
V CH3 COOH
0,7600 mmol
=
50 mL
= 0,0152 M
log C = [CH3COOH] yang teradsorpsi
= log 0,0152 M
= -1,8181 M

m Konsentrasi (M)
No. X (gram) log log C
(gram) Awal Akhir
1. 0,5000 0,5000 0,4266 1,2798 2,5596 0,4081 -0,3699
2. 0,5000 0,2500 0,2428 0,7284 1,4568 0,1633 -0,6055
3. 0,5000 0,1250 0,1126 0,3378 0,6756 -0,1703 -0,9484
4. 0,5000 0,0625 0,0175 0,0525 0,1050 -0,9788 -1,7569
5. 0,5000 0,0313 0,0267 0,0801 0,1602 -0,7953 -1,5734
6. 0,5000 0,0156 0,0152 0,0456 0,0912 -1,0400 -1,8181

Hubungan x/m terhadap C

3

y = 6x + 3E-16
2.5 R = 1

2
x/m

1.5
X/m

1 Linear (X/m)

0.5

0
0 0.1 0.2 0.3 0.4 0.5
C
 Hubungan Log x/m terhadap Log C
0.6
y = 0.9972x + 0.7732 0.4
R = 1
0.2
0
Log x/m

-2 -1.5 -1 -0.5 0
-0.2
Log X/m
-0.4
Linear (Log X/m)
-0.6
-0.8
-1
-1.2
Log C