A.

Lampiran Perhitungan
Diketahui :
- V awal NaOH = 20 mL
- N NaOH = 0,02 N
- V awal CH3COOC2H5 = 25 mL
- N CH3COOC2H5 = 0,02 N
- V HCl = 10 mL
- N HCl = 0,02 N
- V NaOH + CH3COOC2H5 = 45 mL
- V campuran yang diambil = 5 ml
Ditanya : Orde reaksi dan konstanta laju reaksi?
Jawab :
- V NaOH
𝑉 𝑎𝑤𝑎𝑙 𝑁𝑎𝑂𝐻
= x V camp. yang diambil
𝑉 𝑡𝑜𝑡𝑎𝑙
20 𝑚𝐿
= 45 𝑚𝐿 x 5 mL

= 2,22 mL
- V CH3COOC2H5
𝑉 𝑎𝑤𝑎𝑙 CH3COOC2H5
= x V camp. yang diambil
𝑉 𝑡𝑜𝑡𝑎𝑙
25 𝑚𝐿
= 45 𝑚𝐿 x 5 mL

= 2,78 mL
- Molek NaOH awal
= V NaOH x N NaOH
= 2,22 mL x 0,02 N
= 0,0444 mmol
- Molek CH3COOC2H5 awal
= V CH3COOC2H5 x N CH3COOC2H5
= 2,78 mL x 0,02 N
= 0,056 mmol
- Molek HCl awal
= V HCl x N HCl
 = 10 mL x 0,02 N = 0,2 mmol
CH3COOC2H5(aq) + NaOH(aq)  CH3COONa(aq) + C2H5OH(aq)
m: 0,056 mmol 0,044
mmol
r: x x x x
s: (0,056-x) mmol (0,044-x) x mmol x mmol
mmol

NaOH(aq) + HCl(aq)  NaCl(aq) + H2O(l)

m: (0,044-x) 0,2
mmol mmol
r: y y y y
s: - (0,2-y) y mmol y mmol
mmol

Range volume NaOH titrasi secara teori

 Pada saat t = 0
- Mol HCl yang bereaksi
= mol NaOH awal
= 0,044 mmol
- Mol HCl sisa
= mol HCl awal – mol HCl yang bereaksi
= 0,2 mmol – 0,044 mmol
= 0,156 mmol
- Mol NaOH titrasi
= mol HCl sisa
= 0,0156 mmol
𝑀𝑜𝑙 𝑁𝑎𝑂𝐻 𝑡𝑖𝑡𝑟𝑎𝑠𝑖
- V NaOH titrasi = 𝑁 𝑁𝑎𝑂𝐻
0,156 𝑚𝑚𝑜𝑙
= 0,02 𝑁

= 7,8 mL
 Pada saat t = ∞
- Mol HCl yang bereaksi = 0 (karena NaOH habis bereaksi)
- Mol HCl sisa
= mol HCl awal – mol HCl yang bereaksi
= 0,2 mmol – 0 mmol
= 0,2 mmol
- Mol NaOH titrasi
= mol HCl sisa
= 0,0156 mmol
𝑀𝑜𝑙 𝑁𝑎𝑂𝐻 𝑡𝑖𝑡𝑟𝑎𝑠𝑖
- V NaOH titrasi = 𝑁 𝑁𝑎𝑂𝐻
0,2 𝑚𝑚𝑜𝑙
= 0,02 𝑁

= 10 mL
HCl sisa
1. t = 3 menit
Molek HCl sisa = Molek NaOH
= V NaOH titrasi x N NaOH
= 7,8 mL x 0,02 N
= 0,156 mmol
2. t = 8 menit
Molek HCl sisa = Molek NaOH
= V NaOH titrasi x N NaOH
= 8 mL x 0,02 N
= 0,16 mmol
3. t = 15 menit
Molek HCl sisa = Molek NaOH
= V NaOH titrasi x N NaOH
= 8,1 mL x 0,02 N
= 0,162 mmol
4. t = 25 menit
 Molek HCl sisa = Molek NaOH
= V NaOH titrasi x N NaOH
= 8,3 mL x 0,02 N
= 0,166 mmol
5. t = 40 menit
Molek HCl sisa = Molek NaOH
= V NaOH titrasi x N NaOH
= 8,4 mL x 0,02 N
= 0,168 mmol
6. t = 65 menit
Molek HCl sisa = Molek NaOH
= V NaOH titrasi x N NaOH
= 8,5 mL x 0,02 N
= 0,17 mmol
7. t = 2880 menit
Molek HCl sisa = Molek NaOH
= V NaOH titrasi x N NaOH
= 8,7 mL x 0,02 N
= 0,174 mmol
Mol NaOH sisa (b-x)
1. t = 3 menit
Molek NaOH sisa = Molek HCl – Molek HCl sisa
= 0,2 mmol – 0,156 mmol
= 0,044 mmol
2. t = 8 menit
Molek NaOH sisa = Molek HCl – Molek HCl sisa
= 0,2 mmol – 0,160 mmol
= 0,040 mmol
3. t = 15 menit
Molek NaOH sisa = Molek HCl – Molek HCl sisa
= 0,2 mmol – 0,162 mmol
 = 0,038 mmol
4. t = 25 menit
Molek NaOH sisa = Molek HCl – Molek HCl sisa
= 0,2 mmol – 0,166 mmol
= 0,034 mmol
5. t = 40 menit
Molek NaOH sisa = Molek HCl – Molek HCl sisa
= 0,2 mmol – 0,168 mmol
= 0,032 mmol
6. t = 65 menit
Molek NaOH sisa = Molek HCl – Molek HCl sisa
= 0,2 mmol – 0,170 mmol
= 0,030 mmol
7. t = 2880 menit
Molek NaOH sisa = Molek HCl – Molek HCl sisa
= 0,2 mmol – 0,174 mmol
= 0,026 mmol
Mol HCl yang bereaksi (x)
1. t = 3 menit
Mol HCl yg bereaksi = Molek NaOH awal – Molek NaOH sisa
= 0,0444 mmol – 0,044 mmol
= 0,0004 mmol
2. t = 8 menit
Mol HCl yg bereaksi = Molek NaOH awal – Molek NaOH sisa
= 0,0444 mmol – 0,040 mmol
= 0,00044 mmol
3. t = 15 menit
Mol HCl yg bereaksi = Molek NaOH awal – Molek NaOH sisa
= 0,0444 mmol – 0,038 mmol
= 0,0064 mmol
4. t = 25 menit
 Mol HCl yg bereaksi = Molek NaOH awal – Molek NaOH sisa
= 0,0444 mmol – 0,034 mmol
= 0,0104 mmol
5. t = 40 menit
Mol HCl yg bereaksi = Molek NaOH awal – Molek NaOH sisa
= 0,0444 mmol – 0,032 mmol
= 0,0124 mmol
6. t = 65 menit
Mol HCl yg bereaksi = Molek NaOH awal – Molek NaOH sisa
= 0,0444 mmol – 0,030 mmol
= 0,0144 mmol
7. t = 2880 menit
Mol HCl yg bereaksi = Molek NaOH awal – Molek NaOH sisa
= 0,0444 mmol – 0,026 mmol
= 0,0184 mmol
CH3COOC2H5 sisa (a-x)
1. t = 3 menit
Mol CH3COOC2H5 = Molek CH3COOC2H5 – Molek HCl yang bereaksi
= 0,056 mmol – 0,0004 mmol
= 0,0556 mmol
2. t = 8 menit
Mol CH3COOC2H5 = Molek CH3COOC2H5 – Molek HCl yang bereaksi
= 0,056 mmol – 0,0044 mmol
= 0,0516 mmol
3. t = 15 menit
Mol CH3COOC2H5 = Molek CH3COOC2H5 – Molek HCl yang bereaksi
= 0,056 mmol – 0,0064 mmol
= 0,0496 mmol
4. t = 25 menit
Mol CH3COOC2H5 = Molek CH3COOC2H5 – Molek HCl yang bereaksi
= 0,056 mmol – 0,0104 mmol
 = 0,0456 mmol
5. t = 40 menit
Mol CH3COOC2H5 = Molek CH3COOC2H5 – Molek HCl yang bereaksi
= 0,056 mmol – 0,0124 mmol
= 0,0436 mmol
6. t = 65 menit
Mol CH3COOC2H5 = Molek CH3COOC2H5 – Molek HCl yang bereaksi
= 0,056 mmol – 0,0144 mmol
= 0,0416 mmol
7. t = 2880 menit
Mol CH3COOC2H5 = Molek CH3COOC2H5 – Molek HCl yang bereaksi
= 0,056 mmol – 0,0184 mmol
= 0,0376 mmol
Mencari Nilai k
1. t = 3 menit
1 1 𝑏(𝑎−𝑥)
k1 = 𝑡 𝑥 (𝑎−𝑏) 𝑥 ln 𝑎(𝑏−𝑥)
1 1 0,0444 𝑚𝑚𝑜𝑙 (0,0556 𝑚𝑚𝑜𝑙)
= 180 𝑠 𝑥 (0,056 𝑚𝑚𝑜𝑙−0,0444 𝑚𝑚𝑜𝑙) 𝑥 ln 0,056 𝑚𝑚𝑜𝑙 (0,044 𝑚𝑚𝑜𝑙)
1 1
= 180 𝑠 𝑥 0,0116 𝑚𝑚𝑜𝑙 𝑥 ln 1,0018831169
0,0018813461
= 2,088 𝑠 . 𝑚𝑚𝑜𝑙

= 0,0009 s . mmol
2. t = 8 menit
1 1 𝑏(𝑎−𝑥)
k2 = 𝑡 𝑥 (𝑎−𝑏) 𝑥 ln 𝑎(𝑏−𝑥)
1 1 0,0444 𝑚𝑚𝑜𝑙 (0,0516 𝑚𝑚𝑜𝑙)
= 480 𝑠 𝑥 (0,056 𝑚𝑚𝑜𝑙−0,0444 𝑚𝑚𝑜𝑙) 𝑥 ln 0,056 𝑚𝑚𝑜𝑙 (0,040 𝑚𝑚𝑜𝑙)
1 1
= 480 𝑠 𝑥 0,0116 𝑚𝑚𝑜𝑙 𝑥 ln 1,0227857143
0,0225299971
= 5,568 𝑠 . 𝑚𝑚𝑜𝑙

= 0,0040 s . mmol
3. t = 15 menit
 1 1 𝑏(𝑎−𝑥)
k3 = 𝑡 𝑥 (𝑎−𝑏) 𝑥 ln 𝑎(𝑏−𝑥)
1 1 0,0444 𝑚𝑚𝑜𝑙 (0,0496 𝑚𝑚𝑜𝑙)
= 900 𝑠 𝑥 (0,056 𝑚𝑚𝑜𝑙−0,0444 𝑚𝑚𝑜𝑙) 𝑥 ln 0,056 𝑚𝑚𝑜𝑙 (0,038 𝑚𝑚𝑜𝑙)
1 1
= 900 𝑠 𝑥 0,0116 𝑚𝑚𝑜𝑙 𝑥 ln 1,034887218
0,0342924527
= 10,44 𝑠 . 𝑚𝑚𝑜𝑙

= 0,0033 s . mmol

4. t = 25 menit
1 1 𝑏(𝑎−𝑥)
k4 = 𝑡 𝑥 (𝑎−𝑏) 𝑥 ln 𝑎(𝑏−𝑥)
1 1 0,0444 𝑚𝑚𝑜𝑙 (0,0456 𝑚𝑚𝑜𝑙)
= 1500 𝑠 𝑥 (0,056 𝑚𝑚𝑜𝑙−0,0444 𝑚𝑚𝑜𝑙) 𝑥 ln 0,056 𝑚𝑚𝑜𝑙 (0,034 𝑚𝑚𝑜𝑙)
1 1
= 1500 𝑠 𝑥 0,0116 𝑚𝑚𝑜𝑙 𝑥 ln 1, 0633613445
0,0614349706
= 17,4 𝑠 . 𝑚𝑚𝑜𝑙

= 0,0035 s . mmol
5. t = 40 menit
1 1 𝑏(𝑎−𝑥)
k5 = 𝑡 𝑥 (𝑎−𝑏) 𝑥 ln 𝑎(𝑏−𝑥)
1 1 0,0444 𝑚𝑚𝑜𝑙 (0,0436 𝑚𝑚𝑜𝑙)
= 2400 𝑠 𝑥 (0,056 𝑚𝑚𝑜𝑙−0,0444 𝑚𝑚𝑜𝑙) 𝑥 ln 0,056 𝑚𝑚𝑜𝑙 (0,032 𝑚𝑚𝑜𝑙)
1 1
= 2400 𝑠 𝑥 0,0116 𝑚𝑚𝑜𝑙 𝑥 ln 1,0802678571
0,0772090262
= 27,84 𝑠 . 𝑚𝑚𝑜𝑙

= 0,0028 s . mmol
6. t = 65 menit
1 1 𝑏(𝑎−𝑥)
k6 = 𝑡 𝑥 (𝑎−𝑏) 𝑥 ln 𝑎(𝑏−𝑥)
1 1 0,0444 𝑚𝑚𝑜𝑙 (0,0416 𝑚𝑚𝑜𝑙)
= 3900 𝑠 𝑥 (0,056 𝑚𝑚𝑜𝑙−0,0444 𝑚𝑚𝑜𝑙) 𝑥 ln 0,056 𝑚𝑚𝑜𝑙 (0,030 𝑚𝑚𝑜𝑙)
1 1
= 3900 𝑠 𝑥 0,0116 𝑚𝑚𝑜𝑙 𝑥 ln 1,0994285714
0,0947905643
= 45,24 𝑠 . 𝑚𝑚𝑜𝑙

= 0,0021 s . mmol
7. t = 2880 menit
 1 1 𝑏(𝑎−𝑥)
k7 = 𝑡 𝑥 (𝑎−𝑏) 𝑥 ln 𝑎(𝑏−𝑥)
1 1 0,0444 𝑚𝑚𝑜𝑙 (0,0376 𝑚𝑚𝑜𝑙)
= 172800 𝑠 𝑥 (0,056 𝑚𝑚𝑜𝑙−0,0444 𝑚𝑚𝑜𝑙) 𝑥 ln 0,056 𝑚𝑚𝑜𝑙 (0,026 𝑚𝑚𝑜𝑙)
1 1
= 172800 𝑠 𝑥 0,0116 𝑚𝑚𝑜𝑙 𝑥 ln 1,1465934066
0,1367952911
= 2004,48 𝑠 . 𝑚𝑚𝑜𝑙

= 0,00007 s . mmol