Lampiran Perhitungan

Diketahui :
mmol CH3COOC2H5 = N CH3COOC2H5 x V CH3COOC2H5
= 0,02 N x 125 mL
= 2,5 mmol
mmol NaOH = N NaOH x V NaOH
= 0,02 N x 100 mL
= 2 mmol

CH3COOC2H5 (aq) + NaOH (aq) → CH3COONa (aq) + C2H5OH (aq)

m 2,5 mmol 2 mmol - -
r x mmol x mmol x mmol x mmol
s 2,5-x mmol 2-x mmol x mmol x mmol

No. T (menit) Volume NaOH (mL)

1. 3 4,2 mL
2. 8 4,6 mL
3. 15 4,9 mL
4. 25 5 mL
5. 40 5,1 mL
6. 65 5,4 mL

Larutan blanko
N HCl ~ M HCl dan N NaOH ~ M NaOH
M HCl x V HCl = M NaOH x V NaOH
M HCl x 10 mL = 0,02 N x 10,6mL
n HCl = 0,212 mmol

HCl (aq) + NaOH (aq) → NaCl (aq) + H2O (aq)

Perhitungan
m jumlah HCl yang
0,212 mmol 2-xbereaksi
mmol - -
r1. T = 3ymenit
mmol y mmol y mmol y mmol
s mmol mmol
0,212-y HCl = mmol NaOH
0 mmol y mmol y mmol
1. t = 3 menit
0,212-y mmol = V NaOH x M NaOH 2-x mmol – y mmol = 0

0,212-y mmol = 4,2 mL x 0,02 N x mmol = 2-y mmol

0,212-y mmol = 0,084 mmol x mmol = 2 – 0,128 mmol

y = (0,212 – 0,084) mmol x = 1,872 mmol

y = 0,128 mmol

2. t = 8 menit
mmol HCl = mmol NaOH
0,212-y mmol = V NaOH x M NaOH 2-x mmol – y mmol = 0
0,212-y mmol = 4,6 mL x 0,02 N x mmol = 2-y mmol
0,212-y mmol = 0,092 mmol x mmol = 2 - 0,12 mmol
y = (0,212 – 0,092) mmol x = 1,88 mmol
y = 0,12 mmol

3. t = 15 menit
mmol HCl = mmol NaOH
0,212-y mmol = V NaOH x M NaOH 2-x mmol – y mmol = 0
0,212-y mmol = 4,9 mL x 0,02 N x mmol = 2-y mmol
0,212-y mmol = 0,098 mmol x mmol = 2 – 0,144 mmol
y = (0,212 – 0,098) mmol x = 1,886 mmol
y = 0,114 mmol

4. t = 25 menit
mmol HCl = mmol NaOH
0,212-y mmol = V NaOH x M NaOH 2-x mmol – y mmol = 0
0,212-y mmol = 5 mL x 0,02 N x mmol = 2-y mmol
0,212-y mmol = 0,1 mmol x mmol = 2 - 0,112 mmol
y = (0,212 – 0,1) mmol x = 1,888 mmol
y = 0,112 mmol
5. T = 40 menit
mmol HCl = mmol NaOH
0,212-y mmol = V NaOH x M NaOH
0,212-y mmol = 5,1 mL x 0,02 N
0,212-y mmol = 0,102 mmol
y = (0,212 – 0,102) mmol
y = 0,11 mmol
6. T = 65 menit
mmol HCl = mmol NaOH
0,212-y mmol = V NaOH x M NaOH
0,212-y mmol = 5,4 mL x 0,02 N
0,212-y mmol = 0,108 mmol
y = (0,212 – 0,108) mmol
y = 0,104 mmol
Penentuan Orde Reaksi Cara Non Grafik (evaluasi harga k)
1. Orde 1
Satu spesi a (larutan CH3COOC2H5)
 T = 3 menit (180 s)
ln (a-x) = ln a - kt
ln (2,5 – 1,872) = ln 2,5 - 180k
-0,465 = 0,916 - 180k
180k = 0,916 + 0,465
180k = 1,381
k = 7,672 x 10-3
 T = 15 menit (900 s)
ln (a-x) = ln a - kt
ln (2,5 – 1,886) = ln 2,5 - 900k
-0,614 = 0,916 - 900k
900k = 0,916 + 0,614
2-x mmol – y mmol = 0
x mmol = 2-y mmol
x mmol = 2 - 0,11 mmol
x = 1,890 mmol
2-x mmol – y mmol = 0
x mmol = 2-y mmol
x mmol = 2 - 0,104 mmol
x = 1,896 mmol
 T = 8 menit (480 s)
ln (a-x) = ln a - kt
ln (2,5 – 1,880) = ln 2,5 - 480k
-0,478 = 0,916 - 480k
480k = 0,916 + 0,478
480k = 1,394
k = 2,904 x 10-3
 T = 25 menit 1500 s)
ln (a-x) = ln a - kt
ln (2,5 – 1,888) = ln 2,5 - 1500k
-0,491 = 0,916 - 1500k
1500k = 0,916 + 0,491
1500k = 1,407
k = 0,9 x 10-3
 900k = 1,53
k = 1,7 x 10-3
 T = 40 menit (2400 s)  T = 65 menit (3900 s)
ln (a-x) = ln a - kt ln (a-x) = ln a - kt
ln (2,5 – 1,890) = ln 2,5 - 2400k ln (2,5 – 1,896) = ln 2,5 - 3900k
-0,492= 0,916 - 2400k -0,504 = 0,916 - 3900k
2400k = 0,916 + 0,492 3900k = 0,916 + 0,504
2400k = 1,408 3900k = 1,42
k = 0,587 x 10-3 k = 0,364 x 10-3

Satu spesi b (larutan NaOH)

 T = 3 menit (180 s)  T = 8 menit (480 s)
ln (b-x) = ln b - kt ln (b-x) = ln b - kt
ln (2 – 1,872) = ln 2 - 180k ln (2 – 1,880) = ln 2 - 480k
-2,056 = 0,693 - 180k -2,120 = 0,693 - 480k
180k = 0,693 + 2,056 480k = 0,693 + 2,120
180k = 2,749 480k = 2,813
k = 0,0153 k = 0,0058

 T = 15 menit (900 s)  T = 25 menit (1500 s)

ln (b-x) = ln b - kt
ln (2 – 1,886) = ln 2 - 900k
-2,172 = 0,693 - 900k
900k = 0,693 + 2,172
900k = 2,865
k = 3,183 x 10-3
ln (b-x) = ln b - kt
ln (2 – 1,888) = ln 2 - 1500k
-2,189 = 0,693 - 1500k
1500k = 0,693 + 2,189
1500k = 2,882
k = 1,921 x 10-3

 T = 40 menit (2400 s)  T = 65 menit (3900 s)

ln (b-x) = ln b - kt
ln (2 – 1,890) = ln 2 - 2400k
-2,207 = 0,693 - 2400k
2400k = 0,693 + 2,207
ln (b-x) = ln b - kt
ln (2 – 1,896) = ln 2 - 3900k
-2,263 = 0,693 - 3900k
3900k = 0,693 + 2,263
3900k = 2,956
k = 0,757 x 10-3
 2400k = 2,900
k = 1,208 x 10-3

2. Orde 2
Dua spesi a dan b (larutan CH3COOC2H5 dan NaOH)

t x a-x b-x (𝑎 − 𝑥) b(a-x)-a(b-

𝑙𝑛 b(a-x) a(b-x)
(menit) (mmol) (mmol) (mmol) (𝑏 − 𝑥) x)

3 1,872 0,628 0,128 1,591 1,256 0,320 0,936

8 1,880 0,620 0,120 1,642 1,240 0,300 0,940
15 1,886 0,614 0,114 1,684 1,228 0,285 0,943
25 1,888 0,612 0,112 1,698 1,224 0,280 0,944
40 1,890 0,610 0,110 1,716 1,220 0,275 0,945
65 1,896 0,604 0,104 1,759 1,208 0,260 0,948

 T = 3 menit (180 s)  T = 8 menit (480 s)

(𝑎 − 𝑥) 𝑎 (𝑎 − 𝑥) 𝑎
𝑙𝑛 = 𝑘𝑡(𝑏(𝑎 − 𝑥) − 𝑎(𝑏 − 𝑥)) + 𝑙𝑛 𝑙𝑛 = 𝑘𝑡(𝑏(𝑎 − 𝑥) − 𝑎(𝑏 − 𝑥)) + 𝑙𝑛
(𝑏 − 𝑥) 𝑏 (𝑏 − 𝑥) 𝑏
2,5 1,642 = 480k(0,940) + 0,2231
1,591 = 180k(0,936) + 𝑙𝑛 2

1,591 = 168,48k + 0,2231 2,872 = 480k + 0,2231

k = 7,599 x 10-3 k = 5,518 x 10-3

 T = 15 menit (900 s)  T = 25 menit (1500 s)

(𝑎 − 𝑥) 𝑎 (𝑎 − 𝑥) 𝑎
𝑙𝑛 = 𝑘𝑡(𝑏(𝑎 − 𝑥) − 𝑎(𝑏 − 𝑥)) + 𝑙𝑛 𝑙𝑛 = 𝑘𝑡(𝑏(𝑎 − 𝑥) − 𝑎(𝑏 − 𝑥)) + 𝑙𝑛
(𝑏 − 𝑥) 𝑏 (𝑏 − 𝑥) 𝑏
3,083 = 900k(0,943) + 0,2231 3,258 = 1500k(0,944) + 0,2231

3,083 = 848,7k + 0,2231 3,258 = 1416k + 0,2231

k = 3,370 x 10-3 k = 2,143 x 10-3

 T = 40 menit (2400 s)  T = 65 menit (3900 s)

(𝑎 − 𝑥) 𝑎 (𝑎 − 𝑥) 𝑎
𝑙𝑛 = 𝑘𝑡(𝑏(𝑎 − 𝑥) − 𝑎(𝑏 − 𝑥)) + 𝑙𝑛 𝑙𝑛 = 𝑘𝑡(𝑏(𝑎 − 𝑥) − 𝑎(𝑏 − 𝑥)) + 𝑙𝑛
(𝑏 − 𝑥) 𝑏 (𝑏 − 𝑥) 𝑏
3,603 = 2400k(0,945) + 0,2231 3,932 = 3900k x 0,948 + 0,2231
3,603 = 2268k + 0,2231 3,932 = 3697,2k + 0,2231
k = 1,490 x 10-3 k = 1,003 x 10-3
Satu spesi a (larutan CH3COOC2H5)

 T = 3 menit (180 s)  T = 8 menit (480 s)

1 1 1 1
= 𝑎𝑘𝑡 + = 𝑎𝑘𝑡 +
(𝑎 − 𝑥) 𝑎 (𝑎 − 𝑥) 𝑎
1 1 1 1
= 2,5. (180)𝑘 + = 2,5. (480)𝑘 +
(0,628) 2,5 (0,620) 2,5
1,613 = 1200𝑘 + 0,4
1,592 = 450𝑘 + 0,4
1,613 − 0,4 = 1200𝑘
1,592 − 0,4 = 450𝑘 1,613 = 1200𝑘
1,592 = 450𝑘 𝑘 = 1,344 𝑥 10−3
𝑘 = 3,537 𝑥 10−3

 T = 15 menit (900 s)  T = 25 menit (1500 s)

1 1 1 1
= 𝑎𝑘𝑡 + = 𝑎𝑘𝑡 +
(𝑎 − 𝑥) 𝑎 (𝑎 − 𝑥) 𝑎
1 1 1 1
= 2,5.900𝑘 + = 2,5.1500𝑘 +
(0,614) 2,5 (0,612) 2,5
1,628 = 2250𝑘 + 0,4 1,634 = 3750𝑘 + 0,4
1,628 − 0,4 = 2250𝑘 1,634 − 0,4 = 3750𝑘
1,228 = 2250𝑘 1,234 = 3750𝑘
𝑘 = 0,546 𝑥 10−3 𝑘 = 0,330 𝑥 10−3

 T = 40 menit (2400 s)  T = 65 menit (3900 s)

1 1 1 1
= 𝑎𝑘𝑡 + = 𝑎𝑘𝑡 +
(𝑎 − 𝑥) 𝑎 (𝑎 − 𝑥) 𝑎
1 1 1 1
= 2,5.2400𝑘 + = 2,5.3900𝑘 +
(0,610) 2,5 (0,604) 2,5
1,639 = 6000𝑘 + 0,4 1,655 = 9750𝑘 + 0,4
1,239 − 0,4 = 6000𝑘 1,655 − 0,4 = 9750𝑘
0,839 = 6000𝑘 1,255 = 9750𝑘
𝑘 = 0,139 𝑥 10−3 𝑘 = 0,128 𝑥 10−3
 Satu spesi b (larutan NaOH)
 T = 3 menit (180 s)  T = 8 menit (480 s)
1 1 1 1
= 𝑏𝑘𝑡 + = 𝑏𝑘𝑡 +
(𝑏 − 𝑥) 𝑏 (𝑏 − 𝑥) 𝑏
7,812 = 360𝑘 + 0,5 8,333 = 960𝑘 + 0,5
360𝑘 = 7,312 960𝑘 = 7,833
𝑘 = 2,031 𝑥 10−2 𝑘 = 8,159 𝑥 10−3

 T = 15 menit (900 s)  T = 25 menit (1500 s)

1 1 1 1
= 𝑏𝑘𝑡 + = 𝑏𝑘𝑡 +
(𝑏 − 𝑥) 𝑏 (𝑏 − 𝑥) 𝑏
8,772 = 1800𝑘 + 0,5 8,929 = 3000𝑘 + 0,5
1800𝑘 = 8,272 3000𝑘 = 8,429
𝑘 = 4,595 𝑥 10−3 𝑘 = 2,809 𝑥 10−3

 T = 40 menit (2400 s)  T = 65 menit (3900 s)

1 1 1 1
= 𝑏𝑘𝑡 + = 𝑏𝑘𝑡 +
(𝑏 − 𝑥) 𝑏 (𝑏 − 𝑥) 𝑏
9,091 = 4800𝑘 + 0,5 9,615 = 7800𝑘 + 0,5
4800𝑘 = 8,591 𝑘 = 1,168 𝑥 10−3
𝑘 = 1,789 𝑥 10−3

Tabel harga k Orde 1

Jenis 3 menit 8 menit 15 menit 25 menit 40 menit 65 menit
Satu spesi a 7,672 x 10-3 2,904 x 10-3 1,7 x 10-3 0,9 x 10-3 0,587 x 10-3 0,364 x 10-3
Satu spesi b 0,0153 0,0058 3,183 x 10-3 1,921 x 10-3 1,208 x 10-3 0,757 x 10-3

Tabel harga k Orde 2

Jenis 3 menit 8 menit 15 menit 25 menit 40 menit 65 menit
Satu spesi a 3,537 𝑥 10−3 1,344 𝑥 10−3 0,546 𝑥 10−3 0,330 𝑥 10−3 0,139 𝑥 10−3 0,128 𝑥 10−3
Satu spesi b 2,031 𝑥 10−2 8,159 𝑥 10−3 4,595 𝑥 10−3 2,809 𝑥 10−3 1,789 𝑥 10−3 1,168 𝑥 10−3
Dua spesi a dan b 7,599 x 10-3 5,518 x 10-3 3,370 x 10-3 2,143 x 10-3 1,490 x 10-3 1,003 x 10-3
 Penentuan Orde Reaksi Cara Grafik
1. Grafik Orde 1 Satu Spesi a
t (s) ln(a-x)
180 -0.46521511
480 -0.4780358
900 -0.48776035
1500 -0.491023
2400 -0.49429632
3900 -0.50418108

Grafik Orde 1 Satu Spesi a

ln (a-x) vs t
-0.46
-0.465 0 1000 2000 3000 4000 5000
ln(a-x)
-0.47 vs t
-0.475
-0.48 Linear
ln(a-x)

-0.485 (ln(a-x)
-0.49 vs t)
-0.495
y = -9E-06x - 0.473
-0.5 R² = 0.8169
-0.505
-0.51
t (s)

2. Grafik Orde 1 Satu Spesi b

t (s) ln(b-x)
180 -2.05572502
480 -2.12026354
900 -2.17155683
1500 -2.18925641
2400 -2.20727491
3900 -2.26336438
 Grafik Orde 1 Satu Spesi b
ln (b-x) vs t
-2
0 1000 2000 3000 4000 5000
-2.05
ln(b-x) vs t
-2.1
ln(b-x)

-2.15 Linear
(ln(b-x) vs
-2.2 t)

-2.25 y = -5E-05x - 2.094

R² = 0.8366
-2.3
t (s)

3. Grafik Orde 2 Dua spesi a dan b

t t(b(a-x)-a(b- ln (a-x)/
(menit) x)) (b-x)

180 168.48 1.591

480 451.2 1.642
900 848.7 1.684
1500 1416 1.698
2400 2268 1.716
3900 3697.2 1.759

Grafik Orde 2 Dua Spesi a dan b

ln (a-x)/(b-x) vs t(b(a-x) - a(b-x))
1.800
1.780
1.760 Series1
1.740
ln (a-x)/ (b-x)

1.720
1.700 Linear
1.680 (Series1)
1.660
1.640 y = 4E-05x + 1.6215
1.620 R² = 0.8426
1.600
1.580
0 1000 2000 3000 4000
t(b(a-x)-a(b-x))
4. Grafik Orde Dua Satu Spesi a
t (menit) at 1/(a-x)
180 450 1.592
480 1200 1.613
900 2250 1.628
1500 3750 1.634
2400 6000 1.639
3900 9750 1.655

Grafik Orde 2 Satu Spesi a

1/(a-x) vs at
1.67
1.66 1/(a-x)
1.65
1.64 Linear
(1/(a-x))
1/(a-x)

1.63
1.62
y = 6E-06x + 1.6046
1.61
R² = 0.8185
1.6
1.59
1.58
0 2000 4000 6000 8000 10000 12000
at

5. Grafik Orde 2 Satu Spesi b

t (menit) bt 1/(b-x)
180 360 7.812
480 960 8.333
900 1800 8.772
1500 3000 8.929
2400 4800 9.091
3900 7800 9.615
 Grafik Orde 2 Satu Spesi b
1/(b-x) vs bt
12.000
10.000
1/(b-x)
8.000
1/(b-x)

Linear
6.000
(1/(b-x))
4.000
y = 0.0002x + 8.1099
2.000 R² = 0.8593
0.000
0 2000 4000 6000 8000 10000
bt