Name Famu Kalcn

eno ABEB0%
p. . 2
ate: 04-10-2021

Deermii.ion of reaction rate, irder aid

moiecularity of
ethylacetate hydrolysis
CEINETIK 5 F ACID CATALYSED HYDROLYsis OF ETHYL
ACETATE)

ivtrodCtiti

Eserr 2nica. cunpounds that are derive! froni organic or inorganic acids were a
est ielyroxyl rUp is eplaced by an alkoxy group. Esters with low rnolecular weignt
tia' r ahero rinas and esser.tial oils. They are less polar than alcohol and more

ihers ey are characterized ty ome water solubility due to their

F ai hy gen Eonding. In éasy terms, Hydr olysis is a simple reaction with

C taiysed idyd ulysis of Methyl Esters

S . t s u c h a por iucleophiie, the me:ihod of irireasing the rate of nucleophilic
a ttan ese sto ncrease the electrophilicity of the ester. This Can be achieved
way iie most commOn is to use a Lewis acid or Bronsted acid to form a

rg ed itenediate that is far more reactive and even mild nucleophiles such

A tCt.

iitietic d derivation is i kind of salt. At the point when water is added to

1 e t i c ad derivation, the Compouni S:cuities separate, making it isolate
that point, acetic
,

ci articles and ace tic acid secunday particles. At

iotas to make a
ids dar E ticles in the i t e r then jOin vw:th tiydrogen
O : Calle cidic corrosive
mixe iquentiy L.tilize-d ds a part of refrigerants as CFCs
Alyi lides a 6 Synth:lic
cilorouoroc. i'0S). At the
oit whei w a t e i i s acided to alkyl haiides, the
tC i n d orii juoi, iviiin 1S iorthe most part more
ubst stle haiiged ovei

guide us io know how to

C ihe s of Kiietiis, it an reisU atiy
heicai

lil: iiidin reacEon rate, in order to

He r i un O1:tion aild ipr>VE
dilit diso guide us to learn how to
ihe ucuction oi che1ilal profilct>,
iits:
ireCtIons
Cown tihe reaci01 rUte o!
u e orsic
 Date: 04-10-2021
pt. Nu: 2
Deterninatio of Reaction R.te, Order and Molecularity of Ethyl
peri2t a etate Hy rciysis
produce acetic acid and
Acid catalyzed hydrofysis of ethyl acetate to
Probieniafiniti
ethyialcohol
Follewing clienical kinetics of the reaction through acid base
VetihC Y
tii.inetric
Soiutie Hydiolysing etliyl aceta te to get ethyl alcohol and acetic acid
5.udet l aring Fc ilow the lyirolysis thicugB: p%eudo first order kinetics to know the

reaction rat2, orderand molecularity

e eh the rti consi ant of ihe hydrolysis of Ethyi acetate using an acid as catalyst

atouiue stand he ordcr and molecularity of the reaction.

P.incipt

.nvd.l ssof ar esler orCurs according to:th.eequation

COCis tHC CHCOOH +C2HsOH

Tis reatior ollow pseudc first order kinetics sincethe concentration of ethyl acetate
oly chang i t h t Teand he concentration oi waterdoes not change significantly since

it is akeninaagee c s . 1 wo moler uies are invoived in ine reaction but the order is first

ly ancha ate is anputed using iisorder i t e eytation.

He 1oiOV/ ate E Ion S applic l(: LO the above reaction:

Rat 1f ster! h,0

S H 01ain: Catai,
-

Rate kiist}
0 C snsCOeniration ol tho ester at any time t: k' is the specific veiOy

reaction proyresses, the accumulation of acetic acid increases. Drawinga

t
1No nme of the eaction inixture known al reguiar intervais of time and titrating
insstncd.uisodit nihydroide solution.
hy dioiysIS O. t : r s a tirst-o.cder reaction oiiolecular reaction and the reactio
roceeds firs o d e r kineiics. W i the arnount of water is relatively large, ne

irtt.or gorpractic: t, t o cmpletio (ti:e aquilibriim shifts to the right) and the rate is
t i s t order with u s p e r t to the sier. Th hy di olysis tat.es olace slowly with pure water and ts

iydby ic is.

0 S SD ttiois thy. aetate, O.N iIO, .2N NOiH, Phenolphthalein indicator,

bottlee
.ities-Snt, lim, Coiicclf. ski, Wash bottie Reaction

te.

250 mL clean reactioon

ken in a
atiy 100 m 0.3li-vdr ocnloric icid' solution are

when hali the voiume

t I the ester is aCi0 to it. Zero tinme is noted

Aiter thorough mixing,

Lh 2tt is transtredinto.tiie reaction bottle.
int0 a clean conical flask containing ice-
ifd Ln.L of ti1 solution is pipeited out
solution from the burette
ithet t.teu igainst 0. N sodium hydioxide

The e. (0-0nt is he first appearance

of a pale permanent
alei dcai .

intervals, say
itD of the r2 ixure is w'ihdrawn at regular
The reaction is allowed to go
I t i r . t . d a g insi
sdm ny iroxiuiesolutic.n.
90 minutes.
hei2he
eiction MtUie over a hot aler bath for about
C 0.

volume of alkali used

vC.urne
alkali u.C al 2ero tlie i.d Vi. De the
et ihe
when lne reaction is completed.
V betie reici8
er
of
n terms of volume
dl various tune ntev.iis iie cxpressed
ter
i t orti
 IaiCCetrationof este = (Va- V.)
unentration :feierat any tiNe't V Vol-(V- Vo)
V- V -

V, +Vo)
(VV)
Speui te COnsiato: the reaciion1S IS given oy

log
-V,
k Slope x 2.303

ale tantvaes arealculatedat differenttimeintervals which should nearly be

iSan.. 8rapi is drawn between ig{Va Vi) and
-
:he Time't'. From the slope of the
,t n s a.i is Cillated ind it s conmpared with the experimental value.
 Volum Of
33
S.N. NaOi1
-.)
m
min

3 243 Und ened

+ 38 346
3?83 -36 0 00
28-5 23:4 -363 O0016
9 1 2-5 352 601 8B
95 34 0012

51-6 Undine
esuLS:

h t a Cotai.t f thehyaroiysiof aiiesterfm

0 0018
hiC /alie C00
.eCLul rtvfiirca.tion

Cer O1 ti eaiion
nseudo- FixA Oydox ReacAion
5 3 93
S-6 8 282
5A6 2 3 23:3
546 2 5 23:1
=

51-6 -1 25
516 e

q5 2-1
K=Bo3 Joq V-V) oaLJogyV.)

23o3 X 385-1 36+)

308 x 0 oo9
-

Ks
Ka B03. Joq Vao-V
Nos-VJ

303 x 985-\:36- = 0-oo20

B0 XDD.
2303 LS85-136g

303xO:22
02 = 0°O016

a d d Ho min
Ks BoB X 0 3S
O
O00183

o t = So min
K -303 XL385-844
Rare Contac 2
 Calo
35 Kaxi unilo

Lnn)