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Chemical Thermodynamics for Process Simulation

Book · January 2012

DOI: 10.1002/9783527809479

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4 authors:

Juergen Gmehling Baerbel Kolbe

Carl von Ossietzky Universität Oldenburg ThyssenKrupp AG
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Michael Kleiber Jürgen Rarey

thyssenkrupp Industrial Solutions AG Rareytec Co. Ltd.
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 CHEMICAL THERMODYNAMICS

J. Gmehling, Universität Oldenburg, Oldenburg, Germany

B. Kolbe, ThyssenKrupp Uhde GmbH, Dortmund, Germany
M. Kleiber, ThyssenKrupp Uhde GmbH, Bad Soden, Germany
J. Rarey, Universität Oldenburg, Oldenburg, Germany

Chemical Thermodynamics
for Process Simulation

This is the only book to apply For a deeper understanding

thermodynamics to real- additional problems are given
world process engineering at the end of each chapter.
problems, explaining the To solve the complex
thermodynamics behind problems prepared Mathcad
simulations from the view of files, Excel files or the
academic and industrial DDBSP Explorer version can
authors to users of simulation be accessed via the Internet.
programs. It comprises
numerous solved examples,
While written for an
which simplify the
advanced level, the text is
understanding of the often
easy to understand for every
complex calculation
chemical engineer and
procedures, and discusses
chemist with a basic
their advantages and
education in thermodynamics
disadvantages. The text also
2012. XXVI, 736 pages with 301 figures. and phase equilibria,
Hardcover. includes such special models
teaching students the
€ 99.- as for formaldehyde,
ISBN: 978-3-527-31277-1 engineering perspective of
polymers, and associating
thermodynamics but also of
compounds. Estimation
interest to all companies
methods for thermophysical
active in chemistry,
properties and phase
pharmacy, oil and gas
equilibria and
processing, petrochemistry,
thermodynamics of
refinery, food production,
alternative separation
environmental protection and
processes are covered, as
engineering.
are new developments from
recent years.
FROM THE CONTENTS

Introduction Solid-Liquid Equilibria Appendix A: Pure Component

Parameters
PvT Behavior of Pure Osmosis Appendix B: Coefficients for High-
Compounds Polymer Thermodynamics Precision Equations of State
Correlation and Estimation of Appendix C: Useful Derivations
Application of Thermodynamics Appendix D: Standard Potentials for
Pure Component Properties in Separation Technology Electrolyte Components
Properties of Mixtures Appendix E: Regression Technique for
Chemical Reactions
Pure Component Properties
Phase Equilibria in Fluid Phases Special Models Appendix F: Regression Technique for
Caloric Properties Binary Parameters
Practical Applications
Appendix G: Ideal Gas Heat Capacity
Electrolyte Solutions Polynomial Coefficients
Appendix H: UNIFAC parameters
Appendix I: mod. UNIFAC parameters
Appendix J: PSRK parameters
Appendix K: VTPR-parameters

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