Vidyamandir Classes: Innovating For Your Success

Solutions to Mock JEE Main - 4 | JEE - 2022

PHYSICS
SECTION-1
Pitch 1
1.(C) Least count (LC)   mm
Number of divisions on circular scale 100
= 0.01 mm
As zero is not hidden from circular scale when A and B touches each other. Hence, the screw gauge has
positive error.
e   n( LC )  32  0.01  0.32 mm
Linear scale reading = 4 × (1 mm) = 4 mm
Circular scale reading = 16 × (0.01 mm) = 0.16 mm
 Measured reading = (4 + 0.16) mm = 4.16 mm
 Absolute reading = Measured reading – e
= (4.16 – 0.32) mm = 3.84 mm
Therefore, thickness of the glass plate is 3.84 mm
2.(D) The rms speed of a gas molecule is given by
3RT
vrms 
M
The rms speed of helium at –20°C (253 K) is given by
3  R  253
 … (i)
4 103
The rms speed of argon at T is given by
3 R T
 … (ii)
39.9 103
Since when the rms speed of two gas atoms equals (given) i.e., Eq. (i) = Eq. (ii)
3  R  253 3 R  T
 3

4 10 39.9 103
253  39.9
 T  2523.67 K  2.52  103 K
4
3.(D)

Hence, this is NAND gate.

Q U W
4.(C)  
t t t
12000 2.5 103
  100
60 t
t  25 sec
Code A | Page 1 | Solutions Mock JEE Main - 4 | JEE 2022
 Vidyamandir Classes: Innovating For Your Success
5.(B) Let ground state energy (in eV) be El
The from the given condition
E1
E2n  E1  204 eV or  E1  204 eV
4n 2
 1 
 E1  2  1  204 eV
 4n 
and E2n  En  40.8 eV
E1 E1  3 
   E1   2   40.8 eV
4n n2 2
 4n 
1
1 2
From equation (i) and (ii), 4n  5  n  2
3
4n 2
6.(A) When the capillary is inside the liquid, the surface tension force supports the weight of liquid of height
‗h‘

When the capillary is taken out from the liquid similar type of surface tension force acts at the bottom
also, as shown in figure. Hence now it can support weight of a liquid of height 2h.
1 2
7.(D) From E  W0  mvmax
2
1 1 2
 2hv0  hv0  mv12  hv0  mv1
2 2
1 1
and 5hv0  hv0  mv22  4hv0  mv22
2 2
2
v  4
Dividing equation (ii) by (i)  2  
 v1  1
 v2  2v1  2  4  106  8  106 m /s
8.(C) Let v1 be the speed of gun (or mirror) just after the firing of bullet. From conservation of linear
momentum,
m2v0  m1v1
m2v0
or v1 
m1
du
Now, is the rate at which distance between mirror and bullet is increasing  v1  v0
dt
du  v 2  du
  
dt  u 2  dt

Code A | Page 2 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success

v2
Here, 2
 m2  1 (as at the time of firing, bullet is at pole)
u
dv du
  v1  v0
dt dt

du
Here, is the rate at which distance between image (of bullet) and mirror is increasing. So v2 is the
dt
absolute velocity of image (towards right), then,
dv
v2  v1   v1  v0
dt
or v2  2v1  v0
Therefore, speed of separation of bullet and image will be
vr  v2  v0  2v1  v0  v0
or vr  2(v1  v0 )
Substituting value of v2 from equation (i), we have

 m 
vr  2 1  2  v0
 m1 
1 2
9.(D) U Li  32
2
1
 L  82  32
2
L 1
Also, i 2 R  640
R  10
L 1
Time constant    0.1
R 10
1
10.(B) f R 
2 LC
11.(B) Using Biot Savart Law
12.(B) Using symmetry, both 6 resistors will be removed.
13.(A) r < b
Er  0
br c
2kq
Er  2
r
cr d
Er  0
rd

Code A | Page 3 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success
6kq
Er 
r2
14.(B) This is basically a problem of discharging of a capacitor from inside the capacitor. Charge at any time t
is
Here, q0  (area of plates) (surface charge density)

 dq  q0 t / C
And discharging current, i    e  i0et / C
 dt  C
q0 q0
Here, i0  
C CR
K 0 A d
C and R 
d A
K 0
CR 

q q q0
Therefore, i0  0  0  K
K 0 K 0 i00

Substituting the values, we have
(5.0 1014 )()(4.0) 2 (15 106 )
K
(1.0 106 )(8.86 1012 )
1 q02 1 q02
U 
2 C 2 K 0 A
d
2K 0 AU
d
q02
2  4.25  8.86 1012   (4.0 102 ) 2  7500

(15 106   4.0  4.0) 2
 5.0  103 m  5.0 mm
15.(B) F = 0 where 0  r  R1
Because intensity is zero inside the cavity (using gauss law)
16.(D) P0A + hA  g = P1A
P1  P0
h=
g
12 105
= = 30 m
4 103 10
17.(B)

T2  T  8T

 9T
T1  3T

Code A | Page 4 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success

18.(D) In MNO
  
A C  D  0
  
C D   A
In MNP
  
A B  E 0
In MPNO
   
 E  B C  D  0
   
B E  C   D
19.(A) Theory Based
20.(B) L  v x A y F z  L  kv x A y F z
Putting the dimensions in the above relation
[ ML2T 1]  k[ LT 1]x [ LT 2 ] y [MLT 2 ]z
 [ ML2T 1]  k[ M z Lx y  z T  x2 y 2 z ]
Comparing the powers of M, L and T
z 1 … (i)
x yz 2 … (ii)
 x  2 y  2 z  1 … (iii)
On solving (i), (ii) and (iii) x = 3, y = –2, z = 1
So dimension of L in terms of v, A and F
[ L]  [ Fv3 A2 ]

SECTION - 2
1.(0) Let L1 and L2 be the portions (of length) of rope on left and right surface of wedge acceleration =
M
[ L1 sin   L2 sin ]
L 0
M
[ L1 sin   L2 sin ]
2.(3) Let m1 = mass of the square plate of side ‗a‘
and m2 = mass of the square of side ‗a/2‘
2
a
Then m1     and m2  (a) (  being the areal density and) m2  m1  M
2
 
2

m2a 2  a  a 4  a a 

2 2 2
 m1(a /2)2  (a /2)4 
 I   m1          .  
6 
 6 4  6   6 2 4  
 27 
 I  a 4  
12 16 
 1 4M
Also M   1   a 2  
 4 3 a2

Code A | Page 5 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success

 4 M  4  27 
  a  
 3 a2  12 16 
3Ma 2
 I
16
4T T
3.(4) p1  p0   p2  p0 
r1 r2
r2  r1
p2  p1
i.e. pressure inside the smaller bubble will be more. The excess pressure

This excess pressure acts from concave to convex side the interface will be concave towards smaller
bubble and convex towards larger bubble. Let R be the radius of interface then,
4T
p
R
From equation (i) and (ii), we get
r1r2 (0.004)(0.002)
R   0.004 m
r1  r2 (0.004  0.002)
4.(4) At x = 0 the phase difference should be 
 The correct option is (D)
Alternate Method
y2  a cos(t  kx  0 )
 
 y  y1  y2  a cos  t  kx    a cos(t  kx  0 )
 3
    
  0   0  
 2a cos t  3   cos  kx 
3

 2   2 
   

0 
 y = 0 at x = 0 for any t  kx  3   at x  0  0 
4
2 2 3
 4 
Hence y2  a cos  t  kx  
 3 
5.(50) Gain in kinetic energy = loss in potential energy
Thus, KE  Ui  U f
As, U  MB cos 
 
 KE  MB cos    (MB cos0)
2
= MB

Code A | Page 6 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success
Substituting the values, we have
KE  (2.0) (25 106 ) J
 50 J

6.(5) Here, I  1 kW /m2  103 W /m2

Radiation pressure exerted by absorbed light
1 I 
  
2 c 
Radiation pressure exerted by reflected light
1  2I  I
  
2 c  c
Total radiation pressure on the surface
3I 3  103
Prad    5  106 Pa
2c 2  (3  10 )
8

D D
7.(6) x  n  (n  1)
d d
 n 12000  (n  1)10000 … (i)
2000 n = 10000
n=5
5  (12000 1010 )  2
From (i), x  3
 6 103 m  6.0 mm
2 10
8.(3) From the figure

100 20
Vmax   50V , Vmin   10V
2 2
(i) Percentage modulation
Vmax  Vmin  50  10  40
(%)  100    100  100  66.67%
Vmax  Vmin  50  10  60
9.(8) Let both balls meet at point P after time t.

1 2
The distance travelled by ball A, h1  gt
2
1 2
The distance travelled by ball B, h2  ut  gt
2

Code A | Page 7 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success
h1  h2  400 m
400
 ut  400, t   8sec
50
 h1  320 and h2  80 m
 v 
10.(34) f max  f  
 v  vs 
f is the original frequency of source
v the speed of sound
vs the speed of source
 v 
f min  f  
 v  vs 
f max  f min
 2%  1/50
f
f v(2vs ) v(2vs ) 2vs 1
or   
f v 2  vs2 v2 v 50
v
or vs 
100

Code A | Page 8 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success

CHEMISTRY

SECTION-1
1.(D) Interhalogens compound are more reactive than halogens [exception: F2 due to repulsion force
between F – F atoms].
XX  H 2O  HX  HOX
Bigger X forms hypohalite
Smaller X forms X

2.(A) (1, 4 addition)

3.(B) Nitration:

(Poor yield, because NO2 group is deactivating)

4.(D) Z r
n r
n 2h 2
r
42 k m e e 2 Z
5.(A) For adsorption, H  0 is not possible.

6.(B) CaCO3 
 CO2  CaO
(X)

CaO  H 2O 
 Ca(OH) 2
(Y)

Ca(OH)2  2CO2 
 Ca(HCO3 ) 2
(excess) (Z)

Ca(HCO3 )2 
 CaCO3  CO2  H 2O
(Z) (X)

7.(B) CuF2 : Cu 2 , unpaired electron is present therefore coloured

8.(B)

Code A | Page 9 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success
O
9.(B) NH 2 NH 2 ,OH  will not only reduces || but will also bring out
CH3C — to CH3CH 2 —
dehydrobromination of CH 2CH 2Br to CH  CH 2 . Thus, product (A) is.

10.(A) Frenkel defect is shown when there is large difference between size of cation and anion.
11.(C) For appearing violet complex must have absorbed low energy light.
[CoCl(NH 3 )5 ]2 Violet

[Co(NH 3 )6 ]3 Yellow Orange

[Co(CN)6 ]3 Pale Yellow

[Cu(H 2O) 4 ]2 Blue

12.(C) Polyphosphates (sodium hexametaphosphates, sodium tripolyphosphate) form soluble complexes with
Ca 2 and Mg 2 present in hard water.

13.(D)

14.(B) 3Ca 3 (PO4 ) 2  CaF2 is the compound fluoroapatite.

15.(C) Only benzyl halides, i.e., p-iodobenzyl chloride and o-chlorobenzyl iodide undergo hydrolysis on
shaking with an aqueous solution of NaOH. Since yellow ppt. of AgI are obtained, therefore, iodine
must be present in the side chain and not in the nucleus. Therefore, option (C) is correct.

(i) HNO
NaI 
(ii) AgNO
3 AgI
3 Yellow ppt

(i) NaOH

(ii) HNO
 AgCl
3 White ppt
(iii) AgNO3

16.(D) Phenolphthalein  used for titration of weak acid with strong base.
Methyl orange  used for titration of weak base with strong acid.

17.(C)

Code A | Page 10 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success

18.(C) Molar conductivity of only strong electrolytes varies linearly on dilution.

19.(C)

20.(A) The free energy changes all follow a straight line unless the materials melt or vaporize, when there is a
large change in entropy associated with the change of state, which changes the slope of the line
(for example the Hg – HgO line changes slope at 356°C when Hg boils, and similarly Mg – MgO
changes at 1120°C).

SECTION - 2
1.(3) (ii), (iii) and (iv) as ‗i‘ is less than i of Al2 (SO4 )3.

2.(1)

[(CH3 )3 NH  ][OH  ]
3.(4) Kb 
[(CH3 )3 N]
K b [(CH3 )3 N] 6.3 105  0.35
 [OH  ]  
  4.41104 M
[(CH3 )3 NH ] 0.05

Code A | Page 11 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success

4.(788)
By Born-Haber cycle,
1
 f H (NaCl, s)   sub H (Na)   dissoH (Cl 2 )
2
 ionisation H (Na)  eg H (Cl)  latticeH (NaCl)
1
410  109  (244)  496  349   lattice H (NaCl)
2
or  lattice H (NaCl)  788 kJ
This is energy released when gaseous Na  and Cl ions combine to form one mole of NaCl (s).
Hence, energy required for dissociation of one mole of NaCl (s) into gaseous ions  788 kJ mol1.

5.(7) Magnesium sulphate MgSO4  7H 2O is Epsom salt

Glauber‘s salt is Na 2SO 4 10H 2O
7
 0.7  7  101
10
3
6.(20) 64 Gd :1s 2 2s 2 2p6 3s 2 3p6 3d10 4s 2 4p 6 5s 2 4d10 5p6 4f 7

7.(3) In ICl 2 , I has 3 three lone pairs

8.(3)

C, D, E are correct answer

9.(1) Let the density of the solution is d g mL1, then 1L, i.e. 1000 mL of solution has mass = 1000 d g
Thus, 1000 d g of the solution contain H 2SO4  11.5 moles  11.5  98 g  1127 g
 Mass of water = (1000 d – 1127) g
11.5
Molality   1000  94.5 (Given)
1000d  1127
or 11500 = 94.5 × 1000 d – 94.5 × 1127
or 94500 d = 11500 + 106501.5 = 118001.5
118001.5
 d  1.2487 g/mL
94500

R1 1.16  0.15 
10.(1)    ;   1 (order w.r.t., S2O82 )
R 2 1.70  0.22 

Code A | Page 12 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success

MATHEMATICS
SECTION-1
1.(D) Consider the product
 3  1 3 1  3 1 1 3 
  
PP 
T  2 2 2 2  2 2 2 2 
1  3 3  1   3  1 3  1
  
 2 2 2 2  2 2 2 2 
1 0 
 I …(i)
0 1 
Now, Q  PT AP
 Q2  ( PT AP) ( PT AP)  PT A2 P ( PPT  I )
 Q3  ( PT A2 P) ( PT AP)  PT A3P
 Q2010  PT A2010 P
 P  Q 2010 PT  P  PT A2010 P  PT  A2010
i 2010 0   1 0 
 [ PPT  I ]   0  
 i 2010   0 1
2.(A) The equation of normal to the parabola y 2  8 x at Q(2m2 , 4m) is

y  mx  4m  2m3 …(i)
Now, for the minimum distance, the equation of normal [Eq. (i)] is common for both. Thus, the normal
[Eq.(i)] must pass through the centre C(0, –6)
m3  2 m  3  0
 (m  1)(m2  m  3)  0  m 1
Thus, the required point is (2, –4)
2n  3 1
3.(A) tn  
n(n  1) 3n
Therefore,
2n  3 1  2(n  1)  1  1
tn    
n(n  1) 3n  n(n  1)  3n
2 1 1
   n
 n n(n  1)  3
 2 (n  1)  n  1 2 1 1 1
   n   n  n  n 1  n
 n n(n  1)  3  3
3 1  1 1 1 1 1
tn      n   n1  
 n n 1  3 n 3 n  1 3n
1 1
S n   tn  1  
n 1 n  1 3n

Code A | Page 13 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success
4.(D) See figure, the given equation is written as
 3
 , when x  1
arg[ z  (1  i)]   4
  , when x  1
 4

Therefore, the locus is a set of two rays.

5.(C) Let direction cosines of straight line be l, m and n
Therefore,
4l + m + n = 0
l m n l m n
l  2m  n  0      
3 3 9 1 1 3
Therefore equation of straight line is
x  2 y 1 z 1
 
1 1 3
6.(A) Obviously the given point lies on the plane 12x – 3y + 4z = 0, whose minimum distance from Q is 1
unit
7.(B) A tangent to ellipse is
x y
cos   sin   1
3 2
It intersects x = 3 and x = –3 at points
 2(1  cos )   2(1  cos ) 
P  3,  and Q  3, 
 sin    sin  
The circle with PQ as diameter is
 2(1  cos )  2(1  cos ) 
( x  3)( x  3)   y   y  0
 sin   sin  
 4 
 x2  y 2  5   y0
 sin  
It is a family of circles passing through the intersection of the circle x 2  y 2  5  0 and the line y = 0,
which is ( 5, 0).
8.(A) Since E1  E 2  E1  E2 and ( E1  E2 )  ( E1  E2 )  
1
P{( E1  E2 )  ( E1  E 2 )}  P ()  0 
4
( x  x )2 25
9.(A) x  7, N  6,   and x1 and x2 are other two observations, then
N 3
x1  x2  42  5  6  8  9  14 … (i)

Code A | Page 14 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success

 ( x  x )2  50
 (5  7) 2  (6  7) 2  (8  7) 2  (9  7) 2  ( x1  7) 2  ( x2  7) 2  50
 ( x1  7) 2  ( x2  7) 2  40
 ( x1  7) 2  (14  x1  7) 2  40 [From Eq. (i)]

 ( x1  7) 2  (7  x1) 2  40
 ( x1  7) 2  20  x1  7   20  x1  7  20
 x1  7  20
 x2  7  20
Now all the 6 observations arranged in ascending order are 7  20, 5, 6, 8, 9, 7  20
Therefore,
68
Median  7
2
10.(C) 2 x3 y dy  (1  y 2 )( x 2 y 2  y 2  1)dx  0
2y dy y2 1 1
  
(1  y 2 )2 dx 1  y 2 x x3
y2
Put  u.
1 y2
2ydy du
Then, 
(1  y ) dx dx
2 2

1
du u 1  dx
   3  Integrating factor  e x  eln x  x
dx x x
1
Solution is u  x   2 dx  c
x
 x 2 y 2  (cx  1) (1  y 2 )
11.(A) Putting x  tan , we get
/2
 dx  /2 sec2  d  /2 cos   1 
0   d    2
x   (tan   sec )3 (1  sin )  2(1  sin )  0
3 0 0 3
x 1
2

1 1 3
  
8 2 8

12.(A) As the given system of equations has a non-trivial solution,

 ba ca
a b  c b  0
ac bc 
When   0 then determinants become skew-symmetric determinants of odd order, which is equal to
zero. Thus,   0.

Code A | Page 15 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success
13.(A) For the increasing function f ( x )  0

x3  2 x 2  5 x  2cos x … (i)
Let f ( x)  x3  2 x 2  5 x f ( x)  3x 2  4 x  5
Also, f ( x )  0 and so f (x) is always increasing
Curves in equation (i) have no intersection points.
n n
1 1
14.(B) lim Sn  lim
n n
 r  rn
 lim
n
 r r
r 1 r 1
n  
n n
1
Now, lim 0 (lower limit)
n n
r
and lim  1 (upper limit)
n n
1 1
lim Sn   dx
n 0 x (1  x )
 2[ln(1  x )]10  2ln 2
15.(C) Common ratio = 2, a = 1
x1  at12  1  t1  1
x2  x1  r  2  t2  2
x3  x1  r 4  4  t3  4

y1  2at1  2 1
y2  2at2  2 2
y3  2at3  2 4
:
n 1 n 1
n 1
yn  2atn  2 2  2.2 2  2 2
16.(B) Solve using truth table
 1 x 
17.(B) cos  tan 1  x
 x 

f ( x)  sin(2 tan 1 x ), Let tan 1 x  
2 tan  2 x
f ( x)  
1  tan 
2 1 x
1 1
18.(B) P( A  B)  P( A)  P( B)   3K 2  K
3 3
P(exactly one of A, B occurs)  P ( A)  P ( B )  2 P( A  B)
30 30
19.(A) S   r 2  30Cr  30  r 29
Cr 1
r 1 r 1

Code A | Page 16 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success

 30 30 
S  30   (r  1) 29
Cr 1   29 Cr 1 
 r 1 r 1 
 30 
S  30   29  28Cr 2  229 
 r 1 
S  30 [29  228  229 ]
    
20.(C) a  ( b  c )  [ a b c ]   [ b a c ]
     
  b  ( a  c )   b  b   | b |2

SECTION - 2
1.(7) Let moving point be P (h, k )

 (h  1)2  (k  1)2  (h  1)2  (k  1)2  (h  1)2  (k  1) 2  (h  1) 2  ( k  1) 2  36

 4[h2  k 2  2]  36
 h2  k 2  7  x2  y 2  7
10 10
2.(5) S   r 10Cr  10  9Cr 1
r 1 r 1

S  10  29  5  210  5  45
2 2 2 2
 1  1   1  1 
3.(4) Let S   z     z 2  2    z 3  3    z 27  27 
 z  z   z   z 
 1 1 1 
S  z 2  z 4  z 6  z 54   2  4  54   54
z z z 
1 1 
 1  54 
z (1  z ) z  z 
2 54 2
S   54
1 z2 1 2
1
z
z   (where, ‗  ‘ is an imaginary cube root of unity)
S = 54
4.(2) x yz 0 … (i)
x y z
  … (ii)
4 3 2
 (0, 0, 0) lies on both (i) and (ii)
 Foot of perpendicular of (4, 3, 2) on x + y + z = 0 is
x 4 y 3 z 2 (4  3  2)
    3
1 1 1 3
x z
 (1, 0,  1)  Equation of ‗L‘ :  , y0
1 1
 Any point on ‗L‘ : (,0,  )

d  (  2)2  9  (  4) 2 , where   1

Code A | Page 17 | Solutions Mock JEE Main - 4 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success
2 1 1
5.(5)  
x 1 x  2 
 x 2  (3  ) x  2  3  0
D<0
 (3  )2  4(2  3)  0    (3  2 2, 3  2 2)
6.(4) 2 x  y  e2 xy  If x = 0, y = 1
dy  dy  dy
 2  e2 xy  2  y  x   If x = 0, 0
dx  dx  dx
 (2  y)  2(2 x  y )( y  xy)
 y  2 [(2  y)( y  xy)  (2 x  y )( y  y  xy)]
Put x  0, y  1, y  0
y  4
 3 
lim a sin  5 x    a, f (0)  a 
x0  3 2
7.(3)   ab  3
3  tan 3 x 2sin 3 x  3 
lim     
x0 b  3 x 3x  b 
8.(9)

1
Area   (2  x  x
2
) dx
2
9.(2) Let circumference of circle be ‗x‘ and perimeter of square is ―60 – x‖.
Sum of areas ( S )  R 2  a 2
2 2
 x   x
S      15  
 2   4
60
‗S‘ is minimum at x 
4
10.(5)
5 ways 5 ways 3 ways
 = 75 ways
5,7,9

Code A | Page 18 | Solutions Mock JEE Main - 4 | JEE 2022