MM: 25 Class – XI (Chemistry)

Time: 1:30Hr
Topic – Chemical Equilibrium
Q1. The rate constant for three reactions are K1 = 1.0, K2 = 108 and K3 = 10–12. Which reaction
is expected to go for completion? (1)
Q 2 Why the dissociation of PCl5 is less in presence of Cl2? (1)
Q 3 Why gas fizzes out when soda water bottle is opened? (1)
Q4,For an exothermic reaction, what happens to the equilibrium constant if temperature is
increased? (1)
Q5. Ice melts slowly at higher altitude. Why? (1)
Q6 Give reason that acetic acid is less acidic in sodiumacetate solution than in sodium
chloride solution. (1)
Q7. The pka of acetic acid and pkb of ammonium hydroxide are 4.76 and 4.75 respectively.
Calculate the pH of ammonium acetate solution. (1)
Q 8. Justify the statement that water behaves like an acid and also like a base on the basis of
protonic concept. (2)
Q 9. Why the addition of inert gas does does not change the equilibrium? [2]
Q10. The value of Kc for the reaction 2A ⇌B+C is 2x10 -3. At a time, the composition of the
reaction mixture is [A]=[B]=[C] = 3x10 -4 M. In which direction the reaction will proceed? (2)
Q11. The equilibrium constant for the following reaction is 1.6 ×105 at 1024 K.
H2 (g) + Br2 (g) ⇌2HBr (g) , Find the equilibrium pressure of all gases if 10.0 bar of HBr is
introduced into a sealed container at 1024 K. (3)
Q12. The first ionization constant of H2S is 9.1 × 10-8. Calculate the concentration of HS - ion in
its 0.1 M solution. How will this concentration be affected if the solution is 0.1 M in HCl also? If
the second dissociation constant of H2S is 1.2 ×10-13 calculate the concentration of S 2- under
both conditions. (3)
Q13. A sample of HI(g) is placed in flask at a pressure of 0.2 atm. At equilibrium the partial
pressure of HI(g) is 0.04 atm. What is Kp for the given equilibrium ? 2HI (g) ⇌ H2 (g) + I2 (g) (2)
Q14. Define following (i) Common Ion effect (ii) Le Chatlier principle (2)
Q15. One of the reaction that takes place in producing steel from iron ore is the reduction of
iron(II) oxide by carbon monoxide to give iron metal and CO2. FeO (s) + CO (g)  Fe (s) + CO2
(g); Kp = 0.265 atm at 1050K What are the equilibrium partial pressures of CO and CO2 at 1050
K if the initial partial pressures are: PCO= 1.4 atm and CO2 P = 0.80 atm? (2)

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