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INDEX NUMBER:4031040387
TABLE OF CONTENTS
DECLARATION
ACKNOWLEDGEMENTS
DEDICATION
ABSTRACT
ABSTRACT
Asphalt is a mixture of aggregates, binder and filler, used for constructing and maintaining roads,
parking areas, railway tracks, ports, airport runways, bicycle lanes, sidewalks and also play- and
sport areas. Aggregates used for asphalt mixtures could be crushed rock, sand, gravel or slags. This
project has been grouped into six chapters. The threat of a proper disposal of plastic will not be
solved until the practical steps are initiated at the ground level. It is possible to improve
performance of bituminous mixed used in the surfacing of roads. Studies reported in the use of
recycled plastic mainly polythene in the manufacture of blended indicated reduced permanent
deformation and reduced low-temperature creating of the pavement surfacing. The field tests
withstood the stress and proved that plastic waste used after proper processing as an additive would
enhance the life of the roads and also solve environmental problems. Plastic is such a versatile
material due to its industrial resolution and its large scale production. Plastic seemed to be a cheaper
and effective raw material. Chapter one comprises an introduction in which asphalting plastics is
stated how it was arrived at. Also in this chapter we have problem statement and main objective and
specific objectives.Chapter two comprises of literature review. In chapter three mass balance and
calculation of waste plastic is clearly given in the details.
Chapter four comprises of energy and material balance of the plant. Chapter five consists of
equipment design and finally the conclusions and references are clearly given.
DECLARATION
I hereby declare this project to be my original work through my extreme effort and great effort from
teacher Mr. Oyaro. This work has never been presented for any examination purpose for award of
marks and is subjected to KNEC as fulfillment of a diploma certificate in Chemical Engineering.
STUDENT NAME:
Signature __________________________________________
Date ____________________________________________
Signature __________________________________________
Date ____________________________________________
DEDICATION
I dedicate this work to family and friends for their pieces of advice they gave me throughout for
making the research of this project successful and also my supervisor Mr. David Oyaro for the
advice and supervision and proper attention paid to ensure successive completion for this project.
ACKNOWLEDGEMENT
Many thanks and gratitude goes to the almighty God for his sufficient grace and good health
throughout the completion of my course.
I would also acknowledge my loving parents, brothers and sisters for their moral and financial
support making life a success in college. I also acknowledge my classmates for their continued
support.
CHAPTER 1
INTRODUCTION
The threat of a proper disposal of plastic will not be solved until the practical steps are initiated at
the ground level. It is possible to improve performance of bituminous mixed used in the surfacing
of roads. Studies reported in the use of recycled plastic mainly polythene in the manufacture of
blended indicated reduced permanent deformation and reduced low-temperature creating of the
pavement surfacing. The field tests withstood the stress and proved that plastic waste used after
proper processing as an additive would enhance the life of the roads and also solve environmental
problems. Plastic is such a versatile material due to its industrial resolution and its large scale
production. Plastic seemed to be a cheaper and effective raw material.
Today every important sector in the economy starting from agriculture to packaging to automobile,
electronics, electrical building, construction, communication centers have all been revolutionized by
the applications of plastic. Plastic is a non-biodegradable material and researchers found that the
material can remain on earth for 4500 years without degradation. Several studies have proven that
health hazards caused by improper disposal of plastic waste. In current world we cannot ban the use
of plastic but we can re-use, recycle plastic waste.
The plastic waste could not be used in road construction and the field tests withstood the stress and
provided that plastic waste used after proper processing as an additive would enhance the life of
roads and also solve environmental problems. The rapid rate of urbanization and development has
led to increasing plastic waste generation. As plastic is non-biodegradable in nature it remains in
the environment for several years and disposing plastic waste in landfills is are unsafe since toxic
chemicals reach out into the soil and underground water and pollute the water bodies. Scarcity of
bitumen in future needs for deeper thinking to ensure fast road construction.
Due to littering habits, inadequate waste management systems, infrastructure, plastic waste disposal
continues to be a major problem for the civic authorities especially in urban areas. As stated above,
plastic disposal continues to be a major problem for developing countries like Kenya. At the same
time Kenya needs a large network of roads for smooth economic and social development.
1.3 Justification
The quality of plastic waste in municipal solid waste is increasing due to increase in population and
urbanization development activities. Also changes in lifestyle thus continued littering all around the
town hence disposal of plastic has become a nuisance and a serious problem not only on Kenya but
globally due to their non-degradable since they are not disposable scientifically hence their
possibility to ground and water pollution is very high.
Due to their non-biodegradable they can then be used to partially replace the conventional materials
to improved desired mechanical characteristics for particular roads.
In the present people have developed techniques to use plastic waste for construction purpose of
roads and flexible pavements. In conventional road making process bitumen is used as a binder. The
bitumen can be modified with waste plastic and bitumen can be used as a top later coat of flexible
pavement. This waste plastic modified bitumen mix show better binding, proper stability, density
and more resistance to water.
Objective means the main goal or purpose of using plastic in asphalting of roads
CHAPTER 2
LITERATURE REVIEW
The concept of utilization of waste plastics in construction of flexible road pavement had been done
since 2000. In the construction of flexible pavements , bitumen plays the role of binding the
aggregate together by coating over the aggregate. It also helps to improve the strength and life of
road pavement but its resistance to water is poor. A common method to improve the quality of
bitumen is by modifying the properties of bitumen by binding with synthetic polymers like rubber
and plastics.
Use of plastic waste in the bitumen is similar to polymer modified bitumen. The binding of
recycled plastics to asphalt mixture required no modified bitumen to existing plant facilities or
technology. Polymers modified bitumen has better resistance to temperature and water. This
modified bitumen is one of the important construction materials for flexible road pavements
since90’s.
Considerable research has been carried out to determine the suitability of plastic waste. Modified in
construction of bituminous mixes. The researcher reported the use of recycled plastics composed
predominantly of polypropylene and low density polythene in plain bituminous concrete mixtures.
With increased durability and improved fatigue life, dense bituminous macadam with recycled
plastics mainly low density polyethylene (IDPE) replacing 30% aggregation reduced the mix
density by 16% and showed 250% increase in stability.
Plastic content is recommended for improvement of performance. The mixture was subjected to
performance tests including material stability, tensile strength and comprehensive strength tests.
Stabilizing additives are needed in the mixture to prevent the binder from draining down the mix.
The refuse collection and disposal systems in Nairobi city are inadequate. As a result plastic wastes
are commonly dealt with in several ways. Terminal* disposal, disposed into streams, drainage
channels and rivers each having serious consequences. Plastic bags, juice and waste bottles are
discarded onto the grounds. Be it streets, fields, unused areas, when the consumers have finished
with them. These plastics are not biodegradable and remain at their point of disposal until moved by
wind or the rain.
In this case of latter plastics wash downhill and are eventually deposited into rivers and eventually
into the sea. Other plastic mingle* with other plastic materials in drainage pathways. These form
miniature dams and water flow obstructions disrupts sewage run-offs system and cause serious
urban flooding and mosquito breeding grounds.
CHAPTER THREE
MASS BALANCE
Introduction
Mass balance provides a principle tool for analyzing a process according to its reference input and
their output hence creating an environment for maximum utilization of material. The law of
conversion of matter cannot be destroyed and thus the material entering any system must either
leave or accumulate within it. Any material may change physically or chemically but their masses
of their output of the system must be equilibrium with the quantity entering the same system.
This chapter describes mass balance of the solid recovered* fuel production process produced from
various types of waste stream through mechanical treatment. The stream of municipal solid waste
used here as input waste material to produce solid recovered fuel is energy waste collected from
households of municipality. These balances are based on proximate as well as the ultimate analysis
and the composition determination of various streams of material produced in solid recovered fuel
production plant. All the process streams are sampled and treated according to CEN standard
method for solid recovered fuels.
Screening
Primary ShreddingMetal
/ Separator
Weighing
Treatment
Fuel Storing
Water
Mixed Plastic
Calculations of Plastic
2.78
LDPE
3.5 Treatment
Chemical Additive
HDPE Plastic
IDPE
The amount of chemical added per second is too small hence neglected in mass balance
100
100
3.6 Sorting
15 x 349.9Kgs = 52.485Kgs
100
70 x 349.9Kgs = 244.93Kgs
100
Solids in Plastic
349.9Kgs – (244.93 + 52.485)
= 52.485Kgs
96 x 52.485Kgs = 50.3856Kgs
100
Vapour
Overall Balance
Material Balance
50.3856 = 10.852Kgs
50.3856 = 10.852 + Y
Y = 39.5336Kgs
HDPE = 10.852Kgs
3.8 Cooler
Cooler
Mass in HDPE Mass Out
3.29416Kgs 3.29416Kgs
3.29416Kgs
CHAPTER FOUR
ENERGY BALANCE
4.0 Introduction
Assumption : Accumulation = 0
Temperature = 293 K
4.1 Milling
Water ( CP = 4.187Kgs/KgK-1
CP = 0.301 Kg/KgK-1
CP = 0.32 Kg/KgK-1
Waste Plastic
7 = 310K
Energy generated = Energy leaving with force + Energy leaving with waste plastic -
Energy entering with feed and water
=(853.28 + 13.853) – 0
= 867.14Kgs
4.2 Treatment
7 = 310 Kg
7310K
Vapour = 398K
Steam 390K
4.4 Sorting
Steam Condensate
10.852 Kgs HDPE 7 = 380K
Treated Plastic
7 = 365K
Energy given out by steam = Energy leaving with HDPE – Energy entering with feed
9807.657 Kgs
CHAPTER FIVE
5.0 Introduction
The design of on evaporate or evaporation unit for a pyrolysis plant requires practical application of
date or heat transfer to the boiling liquid with a realization of what happens to the liquid during
condensation.
Evaporation is achieved by adding heat to the solution to vaporize the solvent. Heat is supplied
principally to provide latent heat of evaporation.
Q* = uADT where
Q = Heat transferred per unit time
u = The overall heat transfer coefficient
DT = Temperature difference
The prime objective in design is to determine the surface area required for the rate of transfer of
heat using temperature difference. Overall co-efficent is the reciprocal of overal resistance of heat
transfer which is the sum of all several individual substances* due to scalling of the relationship
between overall coefficient where coefficients is H’F, XW, K, u where
The evaporator design can be drawn from the design equations of the shell and tube heater
exchanger.
An evaporator consists of a bundle of tubes enclosed in a cylindrical shell. The ends of the tube are
fitted into the tube sheets which separates the shell sides and tube side fluid.
Overall heat transfer coefficient between steam and solutions (HDPE) allowing for cooling lies
between 1000 – 1500 w/mk2k (chemical engineering volume 6 design)
Taking the heat highest overall heat transfer coefficient = 1500 w/m2k
= 0.42m2
Total number of tubes = Total heating surface area / heating surface for one tube
= 103/0.42
245 tubes.
245 tubes arranged in a rotated square of 16 by 16 tubes allowances between the tubes =
6.4mm
d2 = 4A/Pie*
d2 = 4 x 4.95/Pie*
d2 = 0.3
d = 2.3m
The height of the shell of the short tube vertical evaporator ranges between 3.6 to 4m and a
maximum height of 4m volume of the shell
Pie*d2
4
=22.08m3
The main products obtained in the waste recycling process are liquid pyrolysis product produce
(pyrolysis oil) carbon acoustic residue (pyrocarbon) metal cord (in the case of used tyres) and
pyrolysis gas. The quantity of products obtained depends in the type of recycled waste.
Furnace 5.2
Voltage Y 380
Name Number
Module of Pyrolysis 1
Retort and Lid Assembly 2
Fridge exchanger 1
Collector Separator 1
Maintenance Area 1
Transporting Stand for furnace 1
Control panel 1
Pipeline and cheque valves Set
Is done on two modules – The excess gas from the first furnace can be used to heat up the second.
In each period of time the furnaces are at different stages of process. The phase shift of the process
between the two furnaces is chosen by in such a way that the second furnace passes the maximum
gas generation stage at the time when the first furnaces experiences the greatest demand for fuel.
Thus there is no need for additional solid fuel emissions to the atmosphere are significantly reduced
and there is no need to install a gas holder for temporary storage of pyrolysis gas and a large
number of pyrolysis modules completely reduces the problem of ignition.
Water are recycled without additional preparation.
CHAPTER 6
6.0 Conclusion
This review intended to find the effective ways to re-utilize the hard plastics waste particles as
bitumen modified for flexible pavements.
The use of recycled waste plastic in pavement asphalt represents a valuable outlet for such
materials. The use of modified bitumen with addition of processed waste plastic of about 5-10% by
weight of bitumen helps in substantially improving the material stability, strength fatigue life and
other desirable properties of bituminous concrete mix resulting which improves the longevity abd
pavement performance with marginal saving ub bitumen usage. The process is environmentally
friendly. The use of plastics in the manufacture of roads and laminated roofing also helps to
consume a large quantity of waste plastics. Thus the processes are socially highly relevant giving
better infrastructure.
With the latest ban on plastics in Kenya, this review provides perfect timing and economical way of
the disposal of waste plastics which is also Eco-friendly to both people and environments.
6.1 Recommendation
I recommend that for the industry to employ the design of pyrolysis plant which is designed in
mobile version and this does not require lasting arrangement. It also working with any
carbonaceous waste. It also be able to get rid of waste without unnecessary assistance and ensures
minimum deadlines and absolute confidentiality in work.
6.3 References