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The Product Makers (Australia) Pty Ltd Chemwatch Hazard Alert Code: 2
Version No: 1.1 Issue Date: 16/09/2020
Safety Data Sheet according to WHS and ADG requirements Print Date: 16/09/2020
S.GHS.AUS.EN
Product Identifier
Product name: 004058 TUNA FLAVOUR
Other means of identification: Not Available
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses:
Pyridines are heterocyclic six-membered aromatic compounds containing a single nitrogen atom.
INTEGRITY CHECK: Product contains BOTH an alcohol and an acid as ingredients.
Details of the supplier of the safety data sheet Emergency telephone number
Registered company name The Product Makers (Australia) Pty Ltd Association / Organisation The Product Makers (Australia) Pty Ltd
Address 50 - 60 Popes Road Keysborough 3173 Australia Emergency telephone numbers 61 3 9771 0300
Telephone 61 3 9771 0300 Other emergency telephone numbers Not Available
Fax 61 3 9771 0301
Website www.theproductmakers.com
Email Not Available
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
COMBUSTIBLE LIQUID, regulated for storage purposes only
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI
Label elements
Hazard pictogram(s)
Hazard statement(s)
H319: Causes serious eye irritation.
H227: Combustible liquid.
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004058 TUNA FLAVOUR
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
102-76-1 90-99 glyceryl triacetate
112-80-1 1-10 oleic acid
8006-77-7 <1 pimento oil
110-86-1 <1 pyridine
57-55-6 1-10 propylene glycol
Skin Contact
Inhalation
– If fumes, aerosols or combustion products are inhaled remove from contaminated area.
– Other measures are usually unnecessary.
Ingestion
Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or unless instructed otherwise:
– INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean patient forward or place on left side (head-down position, if possible) to maintain open
airway and prevent aspiration.
NOTE: Wear a protective glove when inducing vomiting by mechanical means.
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– Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred.
– Positive-pressure ventilation using a bag-valve mask might be of use.
– Monitor and treat, where necessary, for arrhythmias.
– Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications.
– Drug therapy should be considered for pulmonary oedema.
– Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Fluid overload might create complications.
– Treat seizures with diazepam.
– Proparacaine hydrochloride should be used to assist eye irrigation.
BRONSTEIN, A.C. and CURRANCE, P.L.
EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994
Treat symptomatically.
Extinguishing media
– Foam.
– Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result
– Alert Fire Brigade and tell them location and nature of hazard.
Fire/Explosion Hazard
– Combustible.
Combustion products include:
carbon dioxide (CO2)
acrolein
other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
CARE: Water in contact with hot liquid may cause foaming and a steam explosion with wide scattering of hot oil and possible severe burns.
HAZCHEM
Not Applicable
Environmental precautions
See section 12
Major Spills
Moderate hazard.
Rags wet / soaked with unsaturated hydrocarbons / drying oils may auto-oxidise; generate heat and, in-time, smoulder and ignite.
– Avoid all personal contact, including inhalation.
– DO NOT allow clothing wet with material to stay in contact with skin
Other information
Store tightly closed under cool dry conditions in an approved storage area.
Avoid exposure to light
Shelf life 12 months
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004058 TUNA FLAVOUR
Storage incompatibility
Control parameters
Occupational Exposure Limits (OEL)
INGREDIENT DATA
Exposure controls
Appropriate engineering controls
Care: Atmospheres in bulk storages and even apparently empty tanks may be hazardous by oxygen depletion.
Requirements of State Authorities concerning conditions for tank entry must be met.
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.
Personal protection
Skin protection
See Hand protection below
Hands/feet protection
Body protection
See Other protection below
Other protection
– Overalls.
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004058 TUNA FLAVOUR
Reactivity:
See section 7
Chemical stability:
See section 7
Conditions to avoid:
See section 7
Incompatible materials:
See section 7
See section 5
The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation (as classified by EC Directives using animal models).
Inhalation hazard is increased at higher temperatures.
Fine mists generated from plant/ vegetable (or more rarely from animal) oils may be hazardous.
Ingestion
Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce serious damage to the health of the
individual.
Ingestion of propylene glycol produced reversible central nervous system depression in humans following ingestion of 60 ml.
Skin Contact
There is some evidence to suggest that this material can cause inflammation of the skin on contact in some persons.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.
Eye
This material can cause eye irritation and damage in some persons.
Chronic
There has been concern that this material can cause cancer or mutations, but there is not enough data to make an assessment.
Inhaling this product is more likely to cause a sensitisation reaction in some persons compared to the general population.
Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.
Glyceryl triesters (triglycerides) undergo metabolism to become free fatty acids and glycerol.
Data from experimental studies indicate that pyridines represent a potential cause of cancer in man.
TOXICITY IRRITATION
004058 TUNA FLAVOUR
Not Available Not Available
TOXICITY IRRITATION
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004058 TUNA FLAVOUR
TOXICITY IRRITATION
oleic acid Oral (rat) LD50: 25000 mg/kg[2] Skin (human):15 mg/3d-I- moderate
TOXICITY IRRITATION
pimento oil Dermal (rabbit) LD50: 2820 mg/kg[2] Skin (rabbit): 500 mg/24h - SEVERE
TOXICITY IRRITATION
pyridine Dermal (rabbit) LD50: 1121 mg/kg[2] Skin (rabbit): 10 mg/24 h (open)mild
TOXICITY IRRITATION
Inhalation (rat) LC50: >44.9 mg/l/4H[2] Eye (rabbit): 500 mg/24h - mild
Oral (dog) LD50: =20000 mg/kg[2] Eye: no adverse effect observed (not irritating)[1]
propylene glycol Oral (mouse) LD50: =22000 mg/kg[2] Skin(human):104 mg/3d Intermit Mod
Oral (rabbit) LD50: =18000-19000 mg/kg[2] Skin: no adverse effect observed (not irritating)[1]
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted
from RTECS - Register of Toxic Effect of chemical Substances
OLEIC ACID
Polyunsaturated fats (PUFAs) protect against heart disease by providing more membrane fluidity than monounsaturated fats (MUFAs), but they are more vulnerable to being oxidized
and therefore rancid.
Foods containing monounsaturated fats reduce low-density lipoprotein (LDL) cholesterol, while possibly increasing high-density lipoprotein (HDL) cholesterol.
The material may be irritating to the eye, with prolonged contact causing inflammation.
PIMENTO OIL
Asthma-like symptoms may continue for months or even years after exposure to the material ends.
Epoxidation of double bonds is a common bioactivation pathway for alkenes.
For eugenol:
The acute toxicity of eugenol is low.
Fragrance allergens act as haptens, which are small molecules that cause an immune reaction only when attached to a carrier protein.
The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and
thickening of the skin.
PYRIDINE
The material may produce severe irritation to the eye causing pronounced inflammation.
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Flaccid paralysis, ptosis, general anaesthesia, sleep, somnolence, tremor, ataxia, coma, dyspnae, respiratory depression recorded.
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004058 TUNA FLAVOUR
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification
Toxicity
Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic
Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7.
METI (Japan) - Bioconcentration Data 8. Vendor Data
For aliphatic fatty acids and alcohols:
Environmental fate:
Saturated fatty acids are very stable in air, whereas unsaturated (C=C bonds) fatty acids are susceptible to oxidation.
For Pyridine and its Derivatives:
Environmental Fate: As molecular weight/substitution increase in the pyridine category, greater distribution to water and soil, and less to air, is predicted.
For Acetic Acid: Acetic acid and its salts (the acetates) can be grouped together because of their close structural relationships, their natural occurrence in plants and animals, and their
fundamental role in cell metabolism.
DO NOT discharge into sewer or waterways.
Bioaccumulative potential
Ingredient Bioaccumulation
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004058 TUNA FLAVOUR
Ingredient Bioaccumulation
glyceryl triacetate LOW (BCF = 1.3)
oleic acid LOW (LogKOW = 7.7294)
pyridine LOW (LogKOW = 0.65)
propylene glycol LOW (BCF = 1)
Mobility in soil
Ingredient Mobility
glyceryl triacetate LOW (KOC = 48.06)
oleic acid LOW (KOC = 11670)
pyridine LOW (KOC = 33.01)
propylene glycol HIGH (KOC = 1)
Labels Required
COMBUSTIBLE LIQUID
COMBUSTIBLE LIQUID, regulated for storage purposes only
Marine Pollutant
NO
HAZCHEM
Not Applicable
Land transport (ADG): NOT Air transport (ICAO-IATA / DGR): NOT Sea transport (IMDG-Code / GGVSee): NOT
REGULATED FOR TRANSPORT OF REGULATED FOR TRANSPORT OF REGULATED FOR TRANSPORT OF
DANGEROUS GOODS DANGEROUS GOODS DANGEROUS GOODS
UN number:
Not Applicable
UN proper
shipping name:
Not Applicable
Transport hazard
class(es):
Not Applicable
Subrisk:
Not Applicable
Packing group:
Not Applicable
Safety, health and environmental regulations / legislation specific for the substance or mixture
glyceryl triacetate is found on the following regulatory lists
– Australian Inventory of Industrial Chemicals (AIIC)
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004058 TUNA FLAVOUR
– Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - – Australian Inventory of Industrial Chemicals (AIIC)
Schedule 5
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment.
end of SDS