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  • Multi 3

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    Pravin Kale
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    This document contains calculations for fractional distillation of a mixture containing pentane, hexane, and octane. Key details include: - The feed contains 0.8 fraction of pentane, 0.1 fraction of hexane, and 0.1 fraction of octane - Calculations are done to determine vapor pressures and fractionation factors at different temperatures - The goal is to distill out 90% of the mixture, leaving compositions of the final liquid and distillate

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    multi3 (2)

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    This document contains calculations for fractional distillation of a mixture containing pentane, hexane, and octane. Key details include: - The feed contains 0.8 fraction of pentane, 0.1 fraction of hexane, and 0.1 fraction of octane - Calculations are done to determine vapor pressures and fractionation factors at different temperatures - The goal is to distill out 90% of the mixture, leaving compositions of the final liquid and distillate

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    9 views6 pages

    Multi 3

    Uploaded by

    Pravin Kale
    This document contains calculations for fractional distillation of a mixture containing pentane, hexane, and octane. Key details include: - The feed contains 0.8 fraction of pentane, 0.1 fraction of hexane, and 0.1 fraction of octane - Calculations are done to determine vapor pressures and fractionation factors at different temperatures - The goal is to distill out 90% of the mixture, leaving compositions of the final liquid and distillate

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 6

    p 760

    ANTONI CONSTANT

    bp FEED fraction mol.wt


    36 PENTANE 0.8 46 PENTANE
    68 HEXANE 0.1 18 HEXANE
    125 OCTANE 0.1 63 OCTANE

    Mavg 44.9

    TAKING HEXANE REFRENCE

    T 970.078971832

    SIMILARLY FOR PENTANE


    LN P1
    P1
    P2
    SIMMILARLY FOR OCTANE

    LN P3 6.37766490737
    P3 588.551778901

    α12 1.15875743252
    P2 α21 1
    α32 0.7744102354
    Kr 0.90543052547
    Kr P2 p2v 0.90543052547

    recalculating for hexane p2v

    WE HAVE 90% REMOVED FROM FEED

    PENTANE REMOVED
    L1f
    NOW NEW TEMP Pressure
    pentane

    octane
    K1 1.16661615626
    K3 0.75132215884
    k2 0.90543052547

    α12 1.158757
    α21 0.85718
    α32 0.77441
    α23 1.330987

    Sum(KiXi) 1.098968

    Assume BP 95Oc Assume on Graph

    k1 1.4349 K2 0.7949

    α21 0.553976 k2/k1

    α23 5.302869

    Average α α21 0.705578

    α23 3.316928

    L2f 25.95587
    s

    L3f 0.043628
    101.0101
    1.223056
    l3f 0.081762

    total number of moles in liquid


    #VALUE! #VALUE!
    x1 #VALUE! #VALUE!
    x2 #VALUE! #VALUE!
    x3 #VALUE! #VALUE!

    kx #VALUE!

    so taking revised k value


    k2 #VALUE!

    corresponding temprature 91
    k1 4.4
    k3 0.39

    α21 #VALUE!

    α23 #VALUE!
    alfa average
    α21 #VALUE!
    α23 #VALUE!

    l2f 0.00385269327
    l3f #VALUE!
    #VALUE!
    #VALUE!

    total moles of its final liquid


    #VALUE!
    x1 #VALUE!
    x2 #VALUE!
    x3 #VALUE!

    sum k1x1 #VALUE!


    the estimate of the final tem

    number of moles in distillate


    #VALUE!
    composition
    x1d
    x2d
    x3d
    B C
    8.1122 1592.864 226.184
    8.07131 1730.63 233.426
    8.21211 2161.91 208.43

    6.780667 use antoine equation


    880.6556 mmhg 1.158757 bar
    1 bar

    mmhg 0.77441 bar

    P1/P2

    p3/p2
    1/(Fraction 1 *alpha1)+(fraction 2 * alpha 2)+(fraction 3*alpha 3)
    BAR 688.1272 mmhg

    r hexane p2v

    892.3069

    0.99

    0.792 KMOL fraction*purity


    0.00792 MOL

    Ln(p1v) 6.688081
    p1v 802.7803 mmhg 1.05629 bar

    Ln(p3V) 6.248053
    p3v 517.0052 mmhg 0.68027 bar

    p1v/p2v
    p3v/p2v

    K3 0.1499
    #VALUE!
    #VALUE!
    #VALUE!

    assume

    kmol

    ts final liquid total moles in distillate

    x1 #VALUE!
    x2 #VALUE!
    x3 #VALUE!

    1
    estimate of the final temprature is good

    ber of moles in distillate

    #VALUE!
    #VALUE!
    #VALUE!

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