Certified Reference Material

▪ Certificate of Analysis ▪
Product: WatR™ Pollution PCBs in Oil
Catalog Number: 729S
Lot No. P297-729S Product use instructions are included as part of
the certification packet and are paginated
Certificate Issue Date: December 16, 2019 separately from this Certificate of Analysis. Please
reference the product use instructions for catalog
Expiration Date: August 22, 2022 #729S revision 090119.
Revision Number: Original

CERTIFICATION
Certified QC Performance PT Performance
Parameter Value¹ Uncertainty² Acceptance Limits³ Acceptance Limits⁴
mg/kg % mg/kg mg/kg

Aroclor 1016 <0.860 - - -

Aroclor 1221 <1.25 - - -
Aroclor 1232 <1.25 - - -
Aroclor 1242 30.9 3.50 10.0 - 39.9 4.94 - 44.9
Aroclor 1248 <1.25 - - -
Aroclor 1254 <0.860 - - -
Aroclor 1260 <0.860 - - -

ANALYTICAL VERIFICATION
Certified
Parameter Value¹ Proficiency Testing Study NIST Traceability
Mean Recovery⁵ n SRM Number⁶ Recovery
mg/kg mg/kg % %
Aroclor 1016 <0.860 - - - - -
Aroclor 1221 <1.25 - - - - -
Aroclor 1232 <1.25 - - - - -
Aroclor 1242 30.9 25.9 83.7 32 3077 107
Aroclor 1248 <1.25 - - - - -
Aroclor 1254 <0.860 - - - - -
Aroclor 1260 <0.860 - - - - -

Page 1 of 2 Lot: P297-729S

16341 Table Mountain Pkwy ▪ Golden, CO 80403 ▪ T: 800.372.0122 ▪ 303.431.8454 ▪ www.eraqc.com

 Certified Reference Material

▪ Certificate of Analysis ▪
1. The Certified Values are the actual gravimetric/volumetric "made-to" concentrations confirmed by ERA analytical verification. The certified values are
monitored and purchasers will be notified of any significant changes resulting in recertification or withdrawal of this certified reference material during the
period of validity of this certificate.
2. The Uncertainty represents an expanded uncertainty and approximates a 95% confidence interval. The uncertainty is based on the characterization,
homogeneity and stability characteristics of the product, multiplied by a coverage factor (k=2). The uncertainty applies to the product as supplied and does
not take into account any required or optional dilution and/or preparations the laboratory may perform while using this product. The formula used to calculate
the expanded uncertainty is:
Uexpanded = k * SQRT((Uchar²) + (Uhomogen²) + (ULTS²) + (USTS²) + (URSS²))

Where:

Uexpanded = Expanded uncertainty.

k = Coverage factor.
Uchar = Combined standard uncertainty of the manufacturing and/or analytical verification assessment.
Uhomogen = Standard uncertainty of the homogeneity assessment.
ULTS = Standard uncertainty associated with long-term stability.
USTS = Standard uncertainty associated with short-term (transport) stability.
URSS = Standard uncertainty associated with repeated sampling of the product (where permitted by product use instructions).
3. The QC Performance Acceptance Limits (QC PALs™) are based on actual historical data collected in ERA's Proficiency Testing program. The QC
PALs™ reflect any inherent biases in the methods used to establish the limits and closely approximate a 95% confidence interval of the performance that
experienced laboratories should achieve using accepted environmental methods. Use the QC PALs™ to realistically evaluate your performance against your
peers.
4. The PT Performance Acceptance Limits (PT PALs™) are calculated using the regression equations and fixed acceptance criteria specified in the
NELAC proficiency testing requirements. Use the PT PALs™ when analyzing this certified reference material alongside USEPA and NELAC compliant PT
study materials. Please note that many PT study acceptance limits are concentration dependent (some non-linearly) and therefore, the acceptance limits of
this certified reference material and any PT study material may differ relative to their difference in concentrations.
5. The PT Performance Data include the mean value, percent recovery and number of data points reported by laboratories in our Proficiency Testing study
compared to the Certified Values. In the event this lot was not used in a proficiency testing scheme, the data displayed was generated internally by ERA.
6. Where NIST Standard Reference Materials (SRMs) are available, each analyte has been analytically traced to the NIST SRM listed. Analytical
Traceability Recovery (%) = [(% recovery ERA certified reference material)/(% recovery NIST SRM)]*100
The traceability data shown were compiled by analyzing this ERA certified reference material and/or it’s associated stock solution(s) against the applicable
NIST SRMs.
7. Metrological Traceability. This certified reference material is metrologically traceable to NIST mass reference materials through an unbroken chain of
comparisons.
8. For additional information on this product such as intended use, storage information, instructions for use, minimum sample size, and safety information,
please refer to the Product Use Instructions provided.

If you have any questions or need technical assistance, please call ERA technical assistance
at 1-800-372-0122 or send an email to info@eraqc.com.

Certifying Officer Quality Officer

Brian Miller Matthew Seebeck

Page 2 of 2 Lot: P297-729S

16341 Table Mountain Pkwy ▪ Golden, CO 80403 ▪ T: 800.372.0122 ▪ 303.431.8454 ▪ www.eraqc.com

 Instructions for Catalog # 729S
WatR™ Pollution PCBs in Oil
Revision 090119

Description:
• This standard is packaged in a 10 mL flame-sealed ampule containing approximately 5 grams of standard.
• The standard is not preserved.
• The solvent for this standard is transformer oil.
• The standard can be stored at room temperature.
• This product is intended to be used as a quality control check of the entire analytical process for the
analytes/matrix included in the standard.
• The dilution instructions below represent the minimum suggested sample size for this product. Using a
smaller sample size may invalidate the assigned value and/or uncertainty shown on the certificate of analysis.
• The certified values apply to the diluted sample after following the stated dilution instructions.

Helpful Hints:
• This standard has been prepared as a whole volume standard and is ready to analyze as received.
• This standard should be analyzed as soon as possible after the concentrate is diluted.
• The dilution scheme given below is simply a suggestion and you may use other dilutions as you require.

Instructions:
1. Carefully snap the top off of the PCBs in Oil ampule.
2. Tare a clean, dry 10 mL class A volumetric flask.
3. Transfer approximately 1.0 g of the PCBs in Oil standard to the flask and record the weight.
4. Dilute the flask to the line with pesticide grade hexane and mix well.
5. Cap the flask and mix by inverting two or three times.
6. Immediately analyze the diluted sample by your normal procedures.

Safety:
ERA products may be hazardous and are intended for use by professional laboratory personnel trained in the
competent handling of such materials. Responsibility for the safe use of these products rests entirely with the
buyer and/or user. Safety Data Sheets (SDS) for all ERA products are available through our website
www.eraqc.com.

Page 1 of 1