Open Test Series - Paper-1 - (21-09-2021)

JEE ADVANCED PATTERN
TEST-09 (21-09-2021)
Time: 3 Hours OPEN TEST SERIES Maximum Marks: 180
PAPER-1 WITH SOLUTION

READ THE INSTRUCTIONS CAREFULLY
GENERAL
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54 questions along with the options are legible. If not, contact the invigilator for replacement of the
booklet.
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OPTICAL RESPONSE SHEET
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Y.
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CHOOSE WISE TO RISE

Some Useful Data
Quantity Values
Constant of gravitation 6.67259 × 10–11 N-m2 kg–2
Speed of light in vacuum 2.99792458 × 108 m s –1
Avogadro constant 6.0221367 × 1023 mol–1
Gas constant 8.314510 JK–1-mol–1
Boltzmann constant 1.380658 × 10–23 JK–1
8.617385 × 10–5 eV K–1
Stefan-Boltzmann constant 5.67051 × 10–8 W m–2 - K–4
Wien’s displacement law constant 2.897756 × 10–3 m -K
Charge of proton 1.60217733 × 10–19 C
Mass of electron 9.1093897 × 10–31 kg
5.48579903 × 10–4 u
Mass of proton 1.6726231 × 10–27 kg
1.007276470 u
Permeability of vacuum 4 × 10–7 NA–2
Permittivity of vacuum 8.854187817 × 10–12 C2 N–1 m–2
Faraday constant 96485.3029 C mol–1
Planck constant 6.6260755 × 10–34 J-s
4.1356692 × 10–15 eV-s
PAPER-1
PART-I : PHYSICS
SECTION-I : One or More Options Correct Type
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE THAN ONE may be correct. You will be awarded 4 marks if all the
correct option(s) is/are chosen and zero mark if none of the option is chosen. For each correct answer
+1 mark will be awarded if no incorrect option is chosen. In all other cases minus two (–2) mark will be
awarded.
1. Charge is sprayed onto a large non conducting belt above the left hand roller. The belt carries
charge with a uniform surface charge density , as it moves with a speed v between the rollers as
shown. The charge is removed by a wiper at right hand roller. For a point just above the sheet
mark the correct option.
0 v
(A) magnetic field is , out of the plane of the page, parallel to axis of roller.
2
(B) Magnetic field is 0, out of the plane of the page, perpendicular to axis
0
(C) Eclectic field is perpendicular to the plane of sheet
2
(D) If an electron moves parallel to V just above the sheet it will experience an upward magnetic force.
2. In cyclotron (particle accelerator) an ion is made to travel successively along semicircles of

increasing radii under the action of a magnetic field. The angular velocity of this ion is
independent of
(A) speed of the ion. (B) radius of the circle. (C) mass of the ion. (D) charge of the ion.
3. A current passes through an ohmic conductor of nonuniform cross section. Which of the following
quantities are independent of the cross-section?
Nucleus_PAPER-1_21092021
(A) the charge crossing in a given time interval. (B) drift speed
(C) current density (D) free-electron density
4. For the given circuit, select the correct alternative(s)

C C
2 3 4
C C C
1 5
6
C C
NUCLEUS-92, Rajeev Gandhi Nagar, Kota (Raj.) India 324005, Mob. 9358006181, 97831-97831 1
PAPER-1
15C
(A) The equivalent capacitance between points 1 & 2 is
11
5C
(B) The equivalent capacitance between points 3 & 6 is
3
15C
(C) The equivalent capacitance between points 1 & 3 is
14
14C
(D) The equivalent capacitance between points 3 & 5 is
15
5. The electrostatic potential (r ) of a spherical symmetric system, kept at origin, is shown in the
adjacent figure, and given as
q q
r = ( r  R0 ) r = ( r  R0 )
4 0 r 4 0 R 0
Which of the following option(s) is/are correct?
(A) For spherical region r  Ro, total electrostatic energy stored is zero.
(B) Within r = 2Ro, total charge is q.
(C) There will be no charge anywhere except at r = Ro.
(D) Electric field is discontinuous at r = Ro.
6. Two point charges Q and – Q/4 are separated by a distance x. Then
(A) potential is zero at a point on the axis which is x/3 on the right side of the charge – Q/4
(B) potential is zero at a point on the axis which is x/5 on the left side of the charge – Q/4
(C) electric field is zero at a point on the axis which is at a distance x on the right side of the
charge – Q/4
(D) there exist two points on the axis where electric field is zero.
SECTION-II : Integer Value Correct Type

This section contains 8 questions. For each question, enter the correct numerical value (in decimal
notation, truncated / rounded off to the second decimal place; e.g. 6.25, 7.00, –0.33, –0.30, 30.27,
–127.30) using the mouse and the on screen virtual numeric keypad in the place designated to enter the
answer. You will be awarded 3 marks if correct numerical value is entered as answer. No negative
marks will be awarded for incorrect answers in this section.
PAPER-1
7. A bullet of mass 0.01 kg strikes a block of mass 0.09 kg and gets embedded in it. The block then
slide along the surface and comes to rest at point B. The coefficient of friction varies as (x)=0.1x
along the surface where AB = 1 m and x is measured from point A. Find the velocity with which
the bullet hits the block.
8. A 20 kg block is initially at rest on a horizontal surface for which the coefficient of friction is 0.6.
If a horizontal force F is applied such that it varies with time as shown in figure. Determine the
speed of the block (in m/s) after 10 s. ( g = 10 m/s2)
y
200
Force (N)
0 x
5 10
time (s)
9. A block of mass 1 kg is kept on smooth inclined surface of an elevator moving up with a constant
velocity of 5 m/s. The work done by normal reaction (as seen from ground) on the block is 10 sec
is __________.
10. A glass vessel is partially filled with mercury and when both are heated together, the volume of
the unfilled part of vessel remain constant at all temperature. Find the initial volume of mercury if
the empty part measures 34 cm3.(in cm3) [Given : vessel = 9 x 10–6/°C;  Hg = 18 × 10–5/°C]
11. The wavelength (in Å) of the K line for the uranium atom (Z = 92) is (R =107 m–1)
12. If the half lives of a radioactive element for  and  decay are 4 year and 12 years respectively,
then the percentage of the element that remains after 12 year will be -
13. The diagram shows a modified meter bridge, which is used for measuring two unknown resistance
at the same time. When the first galvanometer is used for obtaining the balance point, it is found at
point C. Now the first galvanometer is removed and the second galvanometer is used, which gives
balance point at D. Using the details given in the diagram, the value of R1+R2 .is NR where ‘N’
is an integer then the value of 300N is ( AB = L; AC = L/4 and AD = 2L/3 )
PAPER-1
14. A wooden cube (density 0.5 gm/cc) of side 10 cm is floating in water kept in a cylindrical beaker
of base area 1500 cm2. When a unknown mass is kept on wooden block the level of water rises in
the beaker by 2mm. If the unknown mass is m (in GRAM) then the value of m.
SECTION-III: Paragraph Type

This section contains 2 Paragraphs each describing theory, experiment and data etc. Four questions
relate to two paragraphs with two questions on each paragraph. Each question of a paragraph has
ONLY ONE is correct answer among the four choices (A), (B), (C) and (D). You will be awarded
3 marks if only the correct option is chosen and zero mark if none of the option is chosen. (–1) marks
will be awarded for incorrect answers in this section.
Paragraph for question nos. 15 & 16
50
In a series LCR circuit with an ideal ac source of peak voltage E0 = 50V, frequency = Hz and

R = 300 . The average electric field energy stored in the capacitor and average magnetic energy
stored in the coil are 25 mJ and 5 mJ respectively. The value of RMS current in the circuit is 0.1 A.
Then find 
15. Capacitance (C) of capacitor -
(A) 10µF (B) 15µF (C) 20µF (D) None of these
16. Inductance (L) of inductor -

(A) 0.25 Henry (B) 0.5 Henry (C) 1 Henry (D) 2 Henry

In YDSE apparatus shown in figure wavelength of light used is . The screen is moved away from
the source with a constant speed v. Initial distance between screen and plane of slits was D.
Screen
P
d
O
S
D v
17. At a point P on the screen the order of fringe will -

(A) increase (B) decrease
(C) remain constant (D) first increase then decrease
18. Suppose P is the point where 5th order maxima was lying at t = 0. Then after how much time third
order minima will lie at this point -
2D D 3D 3D
(A) (B) (C) (D)
v v 2v v
PAPER-1
PART-II : MATHEMATICS
awarded.
19. Let ƒ be a real valued differentiable function defined on [1,) with ƒ(1) = 1. Suppose
1
ƒ'(x) = 2 , then
x  ƒ2 (x)
(A)ƒ(x) is increasing on [1, ) (B) ƒ(x) is decreasing on [1, )

(C)ƒ(x) 1 + for every x  [1, ) (D) ƒ(x) 1 for every x )
4
20. For any two events of same sample space,

A 1 B 3 7
if P    , P    and P (exactly one of A or B occurred) = , then -
B 3 A 4 12
(A) A & B are equally likely events (B) A & B are independent events
(C) A & B are dependent events 
(D) P  A  B  B 
5
6

21. If the ellipse x2 + 2y2 = 4 and the hyperbola S = 0 have same end points of the latus rectum, then
the eccentricity of the hyperbola can be -
     
(A) cos ec (B) cos ec (C) 2sin  sin (D) 2 sin  sin
4 3 3 4 3 4
3 4 (n  2) L
22. Let L = 2C0  C1  C2  ......  .Cn (where Cr = nCr). If S  lim n then which of the
2 3 (n  1) n  2
following is/are incorrect ?

(A) S is prime (B) S is composite (C) S is even (D) S is odd

x
cos t
23. Which of the following statement(s) is(are) true for the function ƒ(x) = 
0
t
dt (x > 0)
  
(A) ƒ(x) is monotonically increasing in  (4n  1) , (4n  1)  for all n N.
 2 2

(B) ƒ(x) has a local minima at x = (4n – 1) , n N.
2
(C) The points of inflection of the curve y = ƒ(x) lie on the curve x tan x + 1 = 0.
(D) Number of critical points of y = ƒ(x) in (0, 10) are 19.
PAPER-1
24. The value of  for which the system of equations
(1 – )x + 3y – 4z = 0
x – (3 + )y + 5z = 0
3x + y – z = 0
possesses non-trivial solutions is(are)
(A) –1 (B) 0 (C) 1 (D) 2

      
25. Three vectors ,,  having magnitude 2, 3 and 51/3 respectively satisfying   ((   )   )   . If
  p
sin( ^  )  , (where p and q are co-prime), then (q – p) is-
q
26. The point of contact of the tangent to the curve x2017y1033 = K divides the portion of the tangent
between the co-ordinate axes in the ratio of a : b (a from x-axis), then sum of the digits of (a + b) is
/2
dx
27. If (
0
4
sin x  4 cos x )8
  , then 140 is
28. Let a, b, c, d be real numbers such that a + b + c + d = 10 then the minimum value of
a2 cot 9º + b2 cot 27º + c2 cot 63º + d2 cot 81º is n (n  N). Then 'n' is equal to
1
29. If ƒ() = 64 sec + 27 cosec when  lies in (0, /2) then min ƒ() is equal to
25
30. A sportsman’s chance of shooting an animal at a distance r > a (“a” is constant) is given to be
a2/r2. he fires at r = 2a and if he misses, then again fires at r = 3a. He repeats the same process at
r = 4a, 5a and 6a. When he misses at r = 6a, then animal escapes into the jungle. If the odds
against the sportsman are p : q, then q – p is equal to
x 1 y  3 z  4
31. Let image of the line   in the plane 2x – y + z + 3 = 0 be L. A plane 7x + py +
3 5 2
qz + r = 0 is such that it contains the line L and perpendicular to the plane 2x – y + z + 3 = 0 then
value of p is equal to
32. Suppose ƒ is twice differentiable function satisfying ƒ"(x) = –ƒ(x). Define two functions g(x) and
h(x) by g(x) = ƒ'(x) and h(x) = (ƒ(x))2 + (g(x))2. If h(5) = 5, then h(10) is equal to
PAPER-1
Paragraph for questions no. 33 & 34
1
Let f be a continuous function such that g(x) =  f (t) |x – t| dt where x [–1, 1].
1
1
g"(x)
33. The value of 
0
f (x)
dx , (ƒ(x) is equal to
(A) 0 (B) 1 (C) 2 (D) 3
34. If f(x) = x2, then the value of g'(1) is equal to

1 2 4
(A) 1 (B) (C) (D)
3 3 3

Let A be a variable point on locus of feet of perpendicular drawn from focus upon any tangent to
the curve |z – 2| + |z + 2| = 6 and B be a variable point on (1 – i)z + (1 + i) z = 10 2 , then
35. Minimum value of AB is
(A) 1 (B) 2 (C) 3 (D) 4
36. If a variable circle touches the loci of A externally and also the locus of B, then latus rectum of
locus of centre of variable circle is
(A) 2 (B) 4 (C) 8 (D) 16
PAPER-1
PART-III :CHEMISTRY
awarded.
37. Which of the following element is present in mischmetal :-

(A) S (B) C (C) Ni (D) Al
38. Among the following, choose the correct statements:

(i) HC  CH + CH3MgBr  (P) + CH4

(ii) (P) + CO2 (Q) 
H
(R) 
H2O,HgO4 ,H2SO4 
 S(C3H4O3)   CO2
(iii) S + KMnO4 T
(C3H 4O4 )
(A) T on gentle heating produces acetic acid.

(B) All P, Q, R, S and T are soluble in aqueous NaHCO3.
(C) (T) on reaction with SOCl2 followed by urea forms barbituric acid.
(D) All carbon atoms of R in same plane with all conformations possible.
39. The statement that is/are correct for both electrochemical (galvanic) cells and electrolytic cells is
(A) G = –nFE
(B) Free energy decreases in both cells
(C) The cell potentials are temperature independent
(D) Chemical energy is converted into electrical energy in both cells
40. Select the incorrect statement(s) among the following :

(A) KCl is more soluble than LiCl in water.
(B) The oxidation state of Fe in FeS2 is +4.
(C) Zirconium is refined by zone-refining method.

(D) The electrical conductivity of pure metal is greater than that of their alloy.
41. Which of the following statements are correct for given reaction sequence:
2CH2=CH–CO2Et + Me–NH2 (P)   (Q)   (R)
EtONa H3O

(A) R on reaction with hinsberg reagent produces base insoluble sulphonamide.

(B) P on hydrolysis followed by strong heating produces R.
(C) Q can have four stereoisomers possible.
(D) R on reaction with NaCN/HCN produces diastereomeric cyanohydrin.
PAPER-1
42. The Maxwell-Boltzmann distribution for molecular speeds is shown in the following figure
f(v)
W
H
L v
In the figure, H is the height of the peak, L is the location of the maximum and W is the width at
half height. As the temperature is decreased.
(A) H increases, L decreases and W increases
(B) H increases, L decreases and W decreases
(C) H decreases, L decreases and W increases
(D) H decreases, L decreases and W decreases

43. The reaction to convert iron (II) oxide to iron (III) oxide is as follows
4FeO(s) + O2(g) 2Fe2O3(s) Hrxn = –564 kJ mol–1
 
If the enthalpy of formation H 0f of rust (Fe2O3(s)) is –826 kJ mol–1, what is the enthalpy of
–1
formation of FeO in kJ mol ?
44. NH4NO3   ‘X’ + H2O

Oxidation state of N in compound ‘X’ is –
x
45. Graph between log   and log p is a straight line at angle 45° with intercept OA as shown.
m
x
Hence,   at a pressure of 0.2 atmis :
m
45°
x A
log
m 0.3010
O logp
PAPER-1
46. Which of following pairs can’t be differentiate with given reagent.
(1) Glucose & Fructose  Br2 water
(2) Sucrose &-glucose  Tollen’s reagent
NH2 NH–CH3
(3) &  NaNO2 + HCl

O NH2
NH2 C
(4) &  CHCl3 + KOH, 

O
(5) Ph–C–CH3&Ph–CHO  Fehling solution
&
(6) OH  Victor mayer test
OH
CH2–Cl Cl
(7) &  Ag. AgNO3

(8) Phenol & Picric acid  Na metal
47. A sample of hard water contains 244 ppm of HCO3 ions. What is the minimum mass
(in gm) of CaO required to remove HCO3 ions completely from 1 kg of such water sample ?
48. How many anions will give colourless acid vapour / gas with conc. H2SO4 on reaction with
following given anions ?
CH3COO– , Cl– , Br– , S2– , SO32–, BO33– , NO2–, C2O42– , I–
49. Hg5(IO6)2 oxidizes KI to I2 in acid medium and the other product containing iodine is K2HgI4. If
the I2 liberated in the reaction requires 4 mole of Na2S2O3, what are the number of milimolesof
Hg5(IO6)2 that have reacted is
50. In the given reaction sequence:


(i) Fe/HCl (i) H3PO2 (i) Ag/powder (i) OH/
NO2 (ii) NaNO2/HCl
X (ii) CH3COCl/AlCl3
Y+Z X (ii) (CH3)2CuLi
W
yellow (ii) Hg(OAc)2/H2O

ppt (iii) NaBH /OH 
(iii) NaOH/I2 (iii) N2H4/OH, 
4
(i) H+(Slight)
(ii) SOCl2
V
(iii) Benzene/AlCl3
(iv) Zn-Hg/HCl
(i) Total number of mono-chloro product in ‘W’ is ‘P’

(ii) Total number of possible mono-bromo derivative in product ‘V’ is ‘Q’
Find P/Q ?
PAPER-1
Paragraph for questions no. 51&52

Copper is extracted from copper pyrites. After roasting, the ore is smelted in presence of silica and
coke in a blast furnace. The molten matte obtained from blast furnace is taken into Bessemer
converter. Some silica is also added and a hot air blast is blown into the mixture to obtain blister
copper which is purified by electrorefining.
51. During roasting, copper pyrites are converted into a mixture of
(A) CuS + Fe2S3 (B) Cu2S + FeS (C) CuSO4 + FeS (D) Cu2S + FeSO4
52. Matte, the material obtained from blast furnace during metallurgy of copper, is a mixture of
(A) Cu2S + sand + coke (B) FeS + sand + coke
(C) Cu2S + FeS + coke (D) Cu2S + FeS + coke + sand.
Paragraph for questions no. 53 & 54

For the given reaction sequence :
Catechol + CHCl3 + NaOH  P(C7H6O3)
(P) + CH2I2 + NaOH  Q(C8H6O3)
(Q) + CH3–CHO + NaOH,   R
 
(R) + (CH3CO)2O + CH3COO Na  S , Piperic acid
(S) + LiAlH4  T
53. Which of the following statement is correct for given reaction sequence:
(A) P and Q gives violet color with neutral 1% FeCl3.
(B) Degree of unsaturation of S is 7.
(C) R gives positive Br2/H2O test and silver mirror test.
(D) T can decolorize cold KMnO4 and gives hydrogen gas with Na metal.
54. Piperic acid in the following conversion is:

O O
O O
H OH
(A) (B)
O O
OH OH
OH HOH2C OH
(C) (D)
CH=CH–CH=CH–COOH CH=CH–CH=CH–COOH
PAPER-1
ANSWER KEY & SOLUTION
PART-I : PHYSICS
1. AD 2. AB 3. AD 4. ABC 5. ABCD 6. ABC 7. 10.00
8. 24.00 9. 320.00 10. 6.00 11. 0.16 12. 6.25 13. 900.00
14. 300.00 15. C 16. C 17. B 18. B
19. ACD 20. BD 21. AD 22. ABC 23. ABC 24. AB 25. 7.00
26. 8.00 27. 4.00 28. 125.00 29. 5.00 30. 5.00 31. 1.00 32. 5.00
33. C 34. C 35. B 36. D
PART-III : CHEMISTRY
37. ABD 38. ABCD 39. A 40. ABC 41. BCD 42. B 43. –290.00
44. 1.00 45. 0.40 46. 2.00 47. 0.112 48. 6.00 49. 250.0050. 0.75
51. B 52. D 53. C 54. B
SOLUTION | PART-I : PHYSICS | ADVANCED PAPER

1. (A,D)
0 K
Sol. (A) hence K = V
2
 
(D) F = qu  B hence upwards.
2. (A,B)
mv
Sol. r=
qB
v qB

r m
3. (A,D)
4. (A,B,C)
C
1 3 3
3
C 4C/3 C/2 4C/3

C/3 C C/3
Sol. (A) (B) (C)
2 6 1 6
C 6 C
PAPER-1
5. (A,B,C,D)
Sol. consider Hollow sphare
6. (A,B,C)
7. (10.00)
Sol. µ(x) = 0.1x
Mtotal = 0.01Kg + 0.09 Kg = 0.1 kg
x 1
frtotal =  (0.1x)·(0.1)·g·dx
x 0
1
 x2  0.1
frtotal = 0.1   =
 2 0 2
1 2 0.1
mv =  v = 1 m/s
2 2
Applying momentum conservation.
0.01 V = 0.1 × 1
(V)bullet = 10 m/s
8 24.00
Sol.
frmax = 0.6 mg = 120N y
In the figure acting friction force shown by OAB 200 C D
Force (N)
Net change in momentum of body = Area of ACDB A

120 B
mv 
1
7  5  80 x
2 0 3 5 10
v = 24 m/s time (s)
9. (320.00)
4
Sol. N = mg cos  = 1 × 10 × =8N
5
W = f.ds = fs cos 
4
= 5 × (10 × 8) ×
5
= 320 J
PAPER-1
10. (6.00)
Sol. v–vm = 34 cm3 ....(i)
V(1 + 3T) – vm(1 + T) = 34 cm 3
....(ii)
(V–Vm) + v × 3 × 9 × 10 × T – vm × 18 × 10–5 × T = 34 cm–3
–6
v m ·18 105 20
v= = vm
3.9 106 3
20
vm  v m  34
3
17
v m  34
3
vm = 6 cm3
11. (0.16)
1  1 1 
Sol.  R( Z  1) 2  2  2 
  n2 n1 
 = 0.16Å
12 (6.25)
Sol. We Know that,
ln 2

half life
ln 2
so decay constant for -decay =
4
ln 2
and decay constant for -decay =
12
ln 2 ln 2
So, total decay constant = 
4 12
ln 2

3
Also we know that,

R = Roe–t
after 12 years,
ln 2
R  12
e 3
Ro
R 1
 
R o 16
for converting in percentage multiply by 100 both side,
1
%R = × 100 = 6.25%
16
PAPER-1
13. (900.00)
5R 4R
Sol. ,
3 3
14. (300.00)
Sol. Let the cube dips further by y cm and water level rises by 2 mm.
Then equating the volumes (/// volume = \\\ volume in figure)  volume of water raised
= volume of extra depth of wood
2 2
 100 y = (1500 – 100) = 1400 × = 280
10 10
 y = 2.8 cm  Extra upthrust water × (2.8 + 0.2) × 100 g = mg  m = 300 gm.
15. (C)
1 1
Sol. UE = CVrms2 = C (irms × Xc)2
2 2
1 1 i 2rms
UE = Ci 2rms . ,C =
2 4 2 f 2 C 2 2U E  42f 2
(0.1) 2
= 2
= 20µF
 50 
2  25 10  4   
–3 2
 
16. (C)
1 2
Sol. UB = Li rms = 5× 10–3
2
17. (B)
18. (B)
PAPER-1
19. [A, C, D ]
1
Sol. ƒ'(x) =
x  ƒ 2 (x)
2
ƒ(x)  [1 ,)  ƒ'(x) > 0  ƒ(x) is an increasing function  ƒ(x)  1

1 1
ƒ'(x) =  2  ƒ(x)  tan–1x + c
x  ƒ (x) x  1
22

ƒ(1) = 1  ƒ(x)  + 1
4
20. [B, D]
P  A  B 1 P  A  B 3
Sol.  , 
P(B) 3 P(A) 4
7
& = P(A) + P(B) – 2P(A  B)
12
7 4 
   3  2  P(A  B)
12  3 
1 1 3
P(A  B) = , P(A) = & P(B) =
4 3 4
P(A) . P(B) = P(A B) (independent events)
 
Also P  A  B  B = P(A B)
5
= P(A) + P(B) – P(A B) =
6
21. [A, D]
x 2 y2
Sol. Let hyperbola  1
A 2 B2
B2
Ae= 2, 1
A
B2
 e = 1
A2
PAPER-1
2 1
 2
 1   A2 + A – 2 = 0  A = 1  e = 2
A A
y2 x 2
Let hyperbola 2  2  1
B A
2
A
Be = 1,  2
B
A2 1 2  2 6
 e = 1 2  2  1  B2 = 2B 1  0  =
B B B 2
e=
2 2  3 1= 3 1

 
=
2 3 1 2 2
22. [A,B,C]
Sol. (1 + t)n = C0 + C1t + C2t2 + ...... + Cntn
x x
 (1  t) dt =  (C0  C1t  C2 t  .......  Cn t )dt

n 2 n
0 0
n 1
(1  x)  1 C1x 2 C2 x 3 Cn x n 1
 = C0x +   ...... 
n 1 2 3 n 1
n 1
x(1  x)  x 3
Cx C x 4
C x n 2
  = C0x2 + 1  2  ......  n
n 1 2 3 n 1
Differentiating w.r.t.x
(1  x)n 1  (n  1) x(1  x)n  1
n 1
3C1x 2 4 (n  2)
= 2C0x +  C2 x3  ....  Cn xn 1
2 3 (n  1)
Put x = 1
2n 1  (n  1).2n  1
L=
n 1
2  n 1
 S = lim 1
n  n 1
23. [A,B,C]
cos x  cos x
Sol. ƒ'(x) = ; ƒ"(x) = (x tanx + 1).
x x2
Now, verify alternatives.
24. [A,B]
(1  ) 3 4
Sol. Put 1 (3  ) 5 =0
3 1 
 ( + 1)2 = 0
   = –1, 0
PAPER-1
25. [7.00]
1
3
Sol. || = 2, || = 3, || = 5
    
  (( )  )  
   
  (  )   , take magnitude
51/3|( × ) × | = 3
 
( )  
| × | · 52/3 = 3
 
2.52/3.51/3. sin( ^ )  3
  3 p
sin( ^  )  
10 q
q–p=7
26. [8.00]
Sol. x2017 y1033 = K
dy 2017y

dx 1033x
equation of tangent
2017 y
Y–y= (X – x)
1033 x
 3050x   3050y 
A ,0  ;B  0, 
 2017   1033 
a
Let    ration  : 1
b
 3050x 3050y 
P , 
 2017(  1) 1033(  1) 
3050x 1033
x 
2017(  1) 2017
a 1033
   a + b = 3050
b 2017
sum of digits = 8
27. [4.00]
/2
dx
Sol. 
0
1
 1 8
 sin x  cos x 
4 4
 
 /2 2
sec xdx

0
1

8
1  tan x 
4
 
PAPER-1
tanx = t

dt
 (1  t
0
1/4 8
)
1 + t1/4 = 

4

1
8
(  1)3 dx

 1 1 3 3 
4  5  8  6  7  d
1
    
4
=  140 = 4
140
28. [125.00]
Sol. If a1, a2,....., an and b1, b2,....., bn are 2n real numbers, then
(a1b1 + a2b2 + ..... + anbn)2 (a1  a 2  ....  a n ) (b1  b2  ....  bn )
2 2 2 2 2 2
...(i)
Let a1 = a cot 9º , a2 = b cot 27º , a3 = c cot 63º , a4 = d cot 81º
and b1 = tan 9º , b2 = tan 27º , b3 = tan 63º , b4 = tan81º
Now using (i), we get
(a + b + c + d)2 (a2 cot 9º + b2 cot 27º + c2 cot 63º + d2 cot 81º)
(tan 9º + tan 27º + tan 63º + tan 81º) ....(2)
But a + b + c + d = 10 (Given)
and (tan9º + tan81º) + (tan27º + tan63º)
1 1 2 2 2 2
= + = + = 
sin 9º cos9º sin 27º cos 27º sin18º sin 54º 5 1 5 1
4 4
 ( 5  1)  ( 5 1) 
= 8 4 5
 4 
 From (2), we get
100  4 5 (a2 cot 9º + b2 cot 27º + c2 cot 63º + d2 cot 81º)

 a2 cot 9º + b2 cot 27º + c2 cot 63º + d2 cot 81º  25  5 5  125  n
5
Hence n = 125
29. [5.00]
Sol. Let ƒ() = 64 sec + 27 cosec
ƒ'() = 64 sec tan – 27 cosec cot
sin  cos 
 ƒ'() = 0  64  27 2
cos 
2
sin 
PAPER-1
 tan  = 27/64,
3
i.e., tan = 3/4
ƒ"() = 64 sec  + 64sec tan2 + 27cosec3 + 27 cosec cot2> 0
3
if  (0, /2)

 ƒ has minimum value when tan = 3/4,
i.e., sin = 3/5 and cos = 4/5
minƒ() = 64 × (5/4) + 27 × (5/3) = 125.
30. [5.00]
Sol. The sportsman’s change of missing when r = ja is
a2 1
1 2 2
 1  2 (j = 2, 3, 4, 5, 6)
ja j
The animal escapes when the sportsman misses in all the five shots. Therefore the probability of
animal escaping to jungle is
6
 1  1  1  1  1  1
 1  j 2 
 1  2 1  2 1  2 1  2 1  2 
j 2    2  3  4  5  6 
 1  1  1  1  1    1  1  1  1  1  
= 1  1  1  1  1    × 1  1  1  1  1   
 2  3  4  5  6    2  3  4  5  6  
 1 2 3 4 5  3 4 5 6 7 
=           
 2 3 4 5 6  2 3 4 5 6 
1 7 7 p
  
=
6 2 12 q
Therefore
q – p = 12 – 7 = 5
31. [1.00]
Sol. Point A lie on plane 2x – y + z + 3 = 0
2(3 + 1) – (5 + 3) + (2 + 4) + 3 = 0
3 + 6 = 0
=–2
A(–5, –7, 0)
Image of P(1, 3, 4) in 2x – y + z + 3 = 0 is
x  1 y  3 z  4 2(2  3  4  3)
    2
2 1 1 4 11
Image of Q(–3, 5, 2)
DRs of AQ is 2, 12, 2
x 5 y7 z0
equation of plane is 2 12 2 0
2 1 1
PAPER-1
14(x + 5) – (y + 7) (–2) + z(26) = 0  14x + 2y – 26z + 84 = 0
 7x + y – 13z + 42 = 0
p = 1, q = – 13, r = 42
32. [5.00]
Sol. h'(x) = 2ƒ(x)ƒ'(x) + 2g(x)g'(x)
= –2ƒ"(x)ƒ'(x) + 2ƒ'(x)ƒ"(x) = 0  x
Therefore h(x) is a constant function. Hence
h(5) = 5  h(10) = 5
33. [C]
34. [C]
Sol. For x (–1, 1)
x 1
g(x) =  f (t)(x  t) dt +  f (t)(t  x) dt
1 x
x x 1 1
= x  f (t) dt –  t f (t) dt +  t f (t) dt – x  f (t) dt
1 1 x x
Now, differentiate
x x x 1 1 1
d d d d
g'(x) = 
1
f (t) dt + x 
dx 1
f (t) dt – 
dx 1
t f (t) dt + 
dx x
t f (t) dt –  f (t) dt – x  f (t)
x
dx x
x 1
g'(x) =  f (t) dt + xf(x) – f(x) x – f(x) x – f(x)x –  f (t) dt
1 x
x 1
g'(x) =  f (t) dt –  f (t) dt
1 x
.....(1)
Again differentiate
x 1
d d
g"(x) =  f (t) dt –
dx x
f (t) dt
dx 1
= f(x) + f(x) = 2f(x) .....(2)
Now, verify alternatives
35. [B]
36. [D]
Sol. (I) |z – 2| + |z + 2| = 6 represents an ellipse with major axis 6 and focus (2, 0) and (–2, 0)
 A lies on its auxiliary circle i.e. x2 + y2 = 9
and (1 – i)z + (1 + i) z = 10 2
PAPER-1
  z  z  – i  z  z  = 10 2
 2x – i (2iy) = 10 2  x + y = 5 2
 B lies on straight line x + y = 5 2

ABmin = perpendicular distance
OB – radius OA = 5 –3 = 2
(II) If a variable circle touches line and circle then locus will be Parabola with focus at centre
(0, 0) of given circle and directrix at a line parallel to given line at a distance of 3 units,
equal to radius of circle
 Distance between focus and directrix = 5 + 3 = 8
Latus rectum = 16.
PAPER-1
PART-III : CHEMISTRY
37. (A,B,D)
38. (ABCD)
Sol.
 
(i) HC CH + CH3MgBr HC CMgBr + CH4
(P)
 
O
 
(ii) HC CMgBr + CO2 HC C– C – OMgBr
(P) (Q)
H 
O O O
H2O, HgSO4
H –C– CH2 – C–OH HC C– C – OH
H2SO4
(S) (R)

O
CH3 –C– H + CO2 ()
O O O O
KMnO4
(iii) H –C– CH2 – C – OH HO –C– CH2 – C – OH
(T) malonic acid

O
CH3 –C– OH + CO2 ()

(Acetic acid)
39. (A)
40. (A,B,C)
41. (BCD)
Sol.
PAPER-1
O O
CH2 =CH– C – OEt + MeNH2 Me –NH– CH2 – CH2 –C– OEt
O
CH2= CH – C – OEt
O O
CH2 – CH2 – C – OEt CH2 – CH2 – C – OEt
Me – N EtONa
 Me – N
CH2 – CH – C – OEt CH2 – CH2 – C – OEt
O O
(P)
O O O O
O
H3O 
OEt OH
N N
N
(Q) (R)
R is tert amine and will not react with Hinsberg reagent.
O O
CH2 – CH2 – C – OEt CH2 – CH2 – C – OH
H3O
Me – N Me – N
CH2 – CH – C – OEt
CH2 – CH2 – C – OH
O
O

CH2 – CH2
Me – N C=O
CH2 – CH2
O O
(S)
* OEt
*
N
4 stereo isomers
O HO CN
NaCN/HCN
N N
(Two G.I are possible)
PAPER-1
42. (B)
43. (–290.00)
Sol. Hrxn = H fp – HfR
–564 = 2(–826) – 4× HfFeO
HfFeO = –290
44. (1.00)
45. (0.40)
x
Sol. From Graph : log = logP + 0.3010
m
x
log = log(0.2) + 0.3010
m
= log(0.2) + log2
= log(0.4)
x
 = 0.4
m
46. (2.00)
Sol. Aromatic aldehydes will not give fehling's reagent test.
Phenol and picric acid cannot be differentiated by Na metal as both will react with Na to
produce H2 gas.
47. (0.112)
Sol. Mass of HCO3 on 1 kg or 106 mg water = 244 mg
244
Millimoles of HCO3 = =4
61
2 HCO3 + CaO  CaCO3 + H2O + CO2 + 2e–
Millimoles of CaO = 2
Mass of CaO = 56 × 2 = 112 mg = 0.112 g
48. (6.00)
49. (250.00)
Sol. Eq. of Hg5 (IO6)2 = Eq. of I2 = Eq. of Na2S2O3
moles of Hg5 (IO6)2 × 16 = 4 × 1
moles of Hg5 (IO6)2 = 0.25 moles = 250 milimoles.
PAPER-1
50. (0.75)
Sol.
(i) Fe/HCl NaNO2  
NO2 NH2 HCl
N2Cl
H3PO2
CHI3 NaOH CH3COCl

+ + N2 + HCl
(Z) I2 AlCl3
(yellow ppt)

O O O
H Ag / powder
O
(i) Hg(OAc)2/H2O
H – C C – H 
CH3 – C – H
(ii) NaBH4/OH
NaOH
C – OH
O
O O
SOCl2 CH3
(CH3)2CuLi
CH–CH2–C–H CH3–CH=CH–C–H
CH3

N2H4/OH
C – Cl
CH3
O CH–CH2–CH3
CH3
(W)
O
Zn – Hg
HCl
 Total no. of monochloro product for W = 6
PAPER-1
CH3 – CH – CH2 – CH3

CH3
(w)
 Total no. of mono bromo product for V = 8
51. (B)
52. (D)
53. (C)
54. (B)
Sol. (53 & 54)
PAPER-1
OH OH
OH OH
+ CHCl3 + NaOH
C
H O
(P)
OH O
OH
O C–H
+ CH2I2 + NaOH
O
C
H O (Q)
(P)
O O
O O
H H
+ CH3–CHO + NaOH
O O
(Q) (R)
O
O
O O
H
OH
+ (CH3CO)2O + CH3–COONa
O O
(R) (S)
Piperic acid
O
O LiAlH4 O
OH OH
O O
(S) (T)
DOU = 8
 'T' cannot decolorise KMnO4 as there no alkene present in 'T'.
 P & Q will not give violet colour with neutral 1% FeCl3 because only phenol can give violet
colour.
QUESTION PAPER FORMAT AND MARKING SCHEME
19. The question paper has three parts: Physics, Mathematics and Chemistry.
20. Each part has three sections as detailed in the following table:
NAME OF THE CANDIDATE :_____________________________________________
ROLL NO. :_______________________
I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.
_______________________ ____________________________
Signature of the Candidate Signature of the invigilator

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JEE ADVANCED PATTERN

PAPER-1 WITH SOLUTION

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR.

Name of the Candidate Form Number

I have verified all the information filled in by the Candidate.

Signature of the Candidate Signature of the invigilator

CHOOSE WISE TO RISE

2. In cyclotron (particle accelerator) an ion is made to travel successively along semicircles of

4. For the given circuit, select the correct alternative(s)

6. Two point charges Q and – Q/4 are separated by a distance x. Then

SECTION-II : Integer Value Correct Type

SECTION-III: Paragraph Type

16. Inductance (L) of inductor -

Paragraph for question nos. 17 & 18

17. At a point P on the screen the order of fringe will -

20. For any two events of same sample space,

following is/are incorrect ?

(A) S is prime (B) S is composite (C) S is even (D) S is odd

SECTION-II : Integer Value Correct Type

(A) 0 (B) 1 (C) 2 (D) 3

34. If f(x) = x2, then the value of g'(1) is equal to

Paragraph for question nos. 35 & 36

37. Which of the following element is present in mischmetal :-

38. Among the following, choose the correct statements:

(A) T on gentle heating produces acetic acid.

40. Select the incorrect statement(s) among the following :

(C) Zirconium is refined by zone-refining method.

(A) R on reaction with hinsberg reagent produces base insoluble sulphonamide.

SECTION-II : Integer Value Correct Type

44. NH4NO3   ‘X’ + H2O

(3) &  NaNO2 + HCl

(4) &  CHCl3 + KOH, 

(7) &  Ag. AgNO3

50. In the given reaction sequence:

(i) Total number of mono-chloro product in ‘W’ is ‘P’

Paragraph for questions no. 51&52

Paragraph for questions no. 53 & 54

54. Piperic acid in the following conversion is:

SOLUTION | PART-I : PHYSICS | ADVANCED PAPER

C 4C/3 C/2 4C/3

Net change in momentum of body = Area of ACDB A

Also we know that,

ƒ(x)  [1 ,)  ƒ'(x) > 0  ƒ(x) is an increasing function  ƒ(x)  1

 (1  t) dt =  (C0  C1t  C2 t  .......  Cn t )dt

100  4 5 (a2 cot 9º + b2 cot 27º + c2 cot 63º + d2 cot 81º)

if  (0, /2)

 B lies on straight line x + y = 5 2

CH3 –C– OH + CO2 ()

–564 = 2(–826) – 4× HfFeO

Mass of CaO = 56 × 2 = 112 mg = 0.112 g

CHI3 NaOH CH3COCl

 Total no. of monochloro product for W = 6

CH3 – CH – CH2 – CH3

 Total no. of mono bromo product for V = 8

NAME OF THE CANDIDATE :_____________________________________________

ROLL NO. :_______________________

and shall abide by them of the candidate.

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