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2. Use the Optical Response sheet (ORS) provided separately for answering the questions.
3. Blank spaces are provided within this booklet for rough work.
4. Write your name, form number and sign in the space provided on the back cover of this
booklet.
5. After breaking the seal of the booklet, verify that the booklet contains 30 pages and that all
the 18 questions in each subject and along with the options are legible. If not, contact the
invigilator for replacement of the booklet.
6. You are allowed to take away the Question Paper at the end of the examination.
7. The ORS will be collected by the invigilator at the end of the examination.
8. Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9. Write your name, form number and sign with pen in the space provided for this purpose on
the ORS. Do not write any of these details anywhere else on the ORS. Darken the
appropriate bubble under each digit of your form number.
10. Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
13. The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
14. Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or "un-
darken" a darkened bubble.
Please see th e last page of this booklet for rest of the instructions
यश TG~ @bohring_bot
SOME USEFUL CONSTANTS
Atomic No. : H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
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2. A beam of light of uniform intensity and of a single wavelength strikes a screen in which there is a small
circular hole of area A. Some of the light passes through, and then spreads by diffraction, as shown
below. At the centre of the diffracted wave which reaches the centre of the screen, the intensity of the
light is I0 (intensity is the power per unit area). When the hole is made narrower, then the angular width
of the beam increases, in such a way that for the diffracted beam, half the diameter of the hole will result
in twice the width of the beam. If the diameter of the hole is halved, then what will be the new intensity
at the centre of the diffracted beam?
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4. In the photoelectric experiment, fastest electron has speed v if wavelength used is » . If wavelength used
is 3 » , the speed of fastest electron will be :-
4
1 1
(3) v (4) v
2 2
(A) (B)
4 3
1 1
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5. In the figure shown consider the first reflection at the plane mirror and second at the convex mirror. AB
is object.
(A) the second image is real, inverted of 1/5 th magnification w.r.t AB.
(B) the second image is virtual and erect with magnification 1/5 w.r.t AB.
(C) the second image moves towards the convex mirror.
(D) the second image moves away from the convex mirror.
6. A glass slab is of thickness d = a/2 is shown in figure. The refractive index of the slab varies according
to relation ¼ = a . Value of θ 0 tends to π /2, then choose the CORRECT statement (s):-
a−x
(A) The path of the light ray inside medium is a circle given by (x – a)2 + y2 = a2
(B) The path of the light ray inside medium is a parabola given by (x – a)2 = y
(C) The deviation of ray from its initial direction is δ = π /3
(D) Ray emerges grazing at the surface.
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7. A wide slab consisting of two media of refractive indices n1 and n2 is placed in air as shown in the
figure. A ray of light is incident from medium n1 to n2 at an angle θ , where sin θ is slightly larger than
1/n1. Take refractive index of air as 1. Which of the following statement(s) is(are) correct?
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9. The collector of the photocell (in photoelectric experiment) is made of tungsten while the emitter is of
Platinum having work function of 10 eV. Monochromatic radiation of wavelength 124 Å & power 100
watt is incident on emitter which emits photo electrons with a quantum efficiency of 1%. The
accelerating voltage across the photocell is of 10,000 volts. (Use : hc = 12400eV Å)
(A) The power supplied by the accelerating voltage source is 100 watt
(B) The minimum wavelength of radiation coming from the tungsten target (collector) is 1.23 Å
(C) The power supplied by the accelerating voltage source is 10 watt
(D) The minimum wavelength of radiation coming from the tungsten target (collector) is 2.23 Å
10. In an X-ray tube, electrons emitted from a filament (cathode) carrying current I hit a target (anode) at a
distance d from the cathode. The target is kept at a potential V higher than the cathode resulting in
I
emission of continuous and characteristic X-rays. If the filament current I is decreased to , the
2
potential difference V is increased to 2V and the separation distance d is reduced to d , then :-
2
(A) the cut-off wavelength will reduce to half and the wavelengths of the characteristic X-rays will
remain the same.
(B) the cut-off wavelength as well as the wavelengths of the characteristic X-rays will remain the
same.
(C) the cut-off wavelength will reduce to half and the intensities of all the X-rays will decrease.
(D) the cut-off wavelength will become two times larger, and the intensity of all the X-rays will
decrease.
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A ray of light is incident normally on one face 30° – 60° – 90° prism of refractive index µP = 5/3
immersed in water of refractive index µm = 4/3 as shown in the figure.
1. x
The exit angle θ 2 of the ray is sin−1 ( ), find the value of x.
16
2. The minimum refractive index of surrounding medium so that total internal reflection at point P ceases is
n
, find the value of n.
√3
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A narrow slit S transmitting light of wavelength » is placed a distance d above a large plane mirrors as
shown in the figure. The light coming directly form the slit and that coming after reflection from the
plane mirror interfere on a screen Σ placed at a distance D from the slit. Assume that the mirror is
100% reflecting. (Given D = 1m, d = 0.5 mm and » = 500 nm)
3. Find the fringe width (in mm) of the interference pattern formed on the screen.
4. Find the distance (in mm) of closest point to O on the screen where waves interfere with a phase
difference of π .
2
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The collector of the photocell (in photoelectric experiment) is made of tungsten while the emitter is of
Platinum having work function of 10 eV. Monochromatic radiation of wavelength 124 Å & power 100
watt is incident on emitter which emits photo electrons with a quantum efficiency of 1%. The
accelerating voltage across the photocell is of 10,000 volts (Use : hc = 12400eV Å)
5. What is the power supplied by the accelerating voltage source (In watt)?
6. The minimum wavelength of radiation coming from the tungsten target (collector) is (Considering
kinetic energy of striking electron is converted into energy photon when it collide with collector) (in Å)
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8. A biconvex thin lens is prepared from glass (m = 1.5), the two bounding surfaces having equal radii of
25 cm each. One of the surfaces is silvered from outside to make it reflecting. An object is placed before
2ℓ
this lens at distance ℓ cm so that the image is formed on the object itself. The value of is. Lens is
5
placed in air (µ = 1)
9. A concave mirror of focal length 20 cm and a convex lens of focal length 10 cm are kept with their optic
axis parallel but separated by 0.5 mm as shown in figure. The distance between lens and mirror is 10 cm.
An object of height 3 mm is placed on the optic axis of lens at distance 15 cm from the lens. Find height
of image formed by mirror after refraction from lens (in mm).
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PART-II CHEMISTRY
SECTION-I (i) : (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme :
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered)
Negative Marks : 31 In all other cases
1. Which of the following is an outer orbital complex ?
(A) [Fe(CN)6]4– (B) [Mn(CN)6]4–
(C) [Cr(NH3)6]3+ (D) [Ni(NH3)6]2+
2. Total number of geometrical isomers for square planar shape complex ion [M(A) (B) (C) (D)]+x where,
A, B, C and D are monodentate ligand.
(A) 2 (B) 3
(C) 4 (D) 6
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3.
Choose the most appropriate answer from the options given below :
(A) (a) – (iv), (b) – (i), (c) – (ii), (d) – (iii)
(B) (a) – (iii), (b) – (iv), (c) – (ii), (d) – (i)
(C) (a) – (iii), (b) – (ii), (c) – (iv), (d) – (i)
(D) (a) – (iv), (b) – (ii), (c) – (i), (d) – (iii)
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5. O−(g) + e− → O−2
(g) Δ H1
O(g) + e− → O−(g) Δ H2
O2(g) → O+2(g) + e− Δ H3
O(g) → O+(g) + e− Δ H4
+
H2(g) → H2(g) + e− Δ H5
+
H(g) → H(g) + e− Δ H6
O(g) + 2e− → O−2
(g) Δ H7
Which of the following option(s) is/are correct?
(A) | Δ H1 | > | Δ H2 | (B) | Δ H4 | > | Δ H3 |
(C) | Δ H5 | < | Δ H6 | (D) Δ H7 is +ve
6. Choose the correct steps involved in extraction of Zinc from zinc blende:
(A) Concentration of the ore by froth floatation process, using NaCN as depressant
(B) Roasting of concentrated ore to convert it into ZnO
(C) Reduction of ZnO by excess carbon above boiling point of zinc
(D) Refining of the metal by vacuum distillation to obtain pure metal.
7. Which of the following is coloured d0 ion tetrahedral and d3s hydridisation ?
(A) CrO2−
4 (B) MnO−4
(C) MnO2−
4
(D) [Zn(NH3)4]2+
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8. In which of the following option(s) all species contains X 4 O 4 X bond(s) in structure ( X = central
atom)
(A) (B)
(C) (D)
9. Select the correct orders according to their indicated property -
(A) Na2CO3 < K2CO3 < Rb2CO3 < Cs2CO3 (solubility in water)
(B) NaF < MgO < ScN < TiC (lattice energy)
(C) PbF2 < PbCl2 < PbBr2 < PbI2 (covalent character)
(D) Cl3 – < Br3 – < I3 – (stability order)
10. The complex is oxidised to K2[Zn(CN)4(O2)2], then. Which of the following is/are
corect ?
(A) Zn(II) is oxidised to Zn(IV)
(B) O – O bond length decreases
(C) Magnetic moment increases
(D) Magnetic behaviour does not change
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Imagine a universe in which the four quantum numbers can have the same possible values as in our
universe except the angular momentum quantum number ' ℓ ' can have integral values of 0, 1, 2.......,n
instead of 0, 1, 2,......(n – 1) and magnetic quantum number 'm' can have integral values of – ( ℓ + 1) to 0
to ( ℓ + 1) instead of – ℓ to 0 to + ℓ .
1. Based on above assumption if magnetic moment of the element with atomic number_18, is √x B.M.
Find out the value of ( x ).
4
2. Based on above assumption in the electronic configuration of the element with atomic number 25, find
out the number of electrons present in the subshell having ℓ = 1.
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Experimental enthalpy of hydration of Cr2+ is – 460 k cal mol –1. In the absence of crystal field splitting
the value of enthalpy of hydration of Cr2+ is – 436 k cal mol –1.
(Use 1k cal mol –1 = 350 cm –1)
5. Δ
The value of ( ) for [Cr(H2O)6]2+ in cm –1 is :
1000
6. Number of unpaired electron in eg set of the complex [Cr(H2O)6]2+ is :-
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PART-III MATHEMATICS
SECTION-I (i) : (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme :
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered)
Negative Marks : 31 In all other cases
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equal to
(A) 2 (B) 4
(C) 0 (D) 8
4.
1
(A) In (B) in 6 +
2
(C) (D)
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(C) If the two curves y = ax3 – 6ax2 + (12a + 12)x – (8a + 16) a ∈ R and y = x3 touches each
other at some point, then one of the possible value of 'a' is √2
3
+ √3
3
(D) Let f(x) = a0 + a1x + a2x2 + a3x3 + a4x4 + a5x5 be a polynomial of degree 5 which increases in
the interval (− ∞ , 1] and [3, ∞ ) and decreases in the interval (1,3). Given that
88
f(0) = 2, f(1) = and f '(2) = 0 , then a5 is equal to 1/5.
15
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7. Let f(x) be a non-constant, thrice differentiable function defined on R such that y = f(x) is symmetric
1
about line x = 1 and f(−1) = f ′ ( ) = f ′ ( 1 ) = 0, then which of following is/are correct
4 2
statement(s) ?
(A) f" (x) = 0 has atleast four real roots in the interval (0,2)
(B) f" (x) = 0 has atleast 3 real roots in the interval (0,2)
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Let f be a real valued continuous function on R (the set of all real numbers) and satisfying
1. π /2
If h(t) = f( – t) – f(t) for every t ∈ R, then the value of definite integral ∫ h (t) sin t dt is equal to
0
2. If the range of function g(x) = 3f(x) + b + 4 for every real x is [0, ∞ ), then 'b' equals
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π /2
Let a real valued function f defined on real number satisfies ∫ t2 f(2x − t)dt = 2e2x − 4x2 + 2x − 2 2 and
20
[Note: [k] denotes greatest integer function less than or equal to k.]
5. The value of (a + b) is equal to
6. Number of integral value of » so that the equation bx 2 – b 2 x + » = 0 has roots α , β such
that 1 < α < 2 and 2 < β < 3 is
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x ∈ (a,b) – {c,d,e} then the value of a + b + c + d + e, where [ ] is GIF and { } is fractional part of x.
8.
9. equal to
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