Question Report

Paper Code : 1001CT103516013
ENGLISH
CLASSROOM CONTACT PROGRAMME

(Academic Session : 2016 - 2017)
JEE (Main + Advanced) : LEADER COURSE

PHASE : III, IV & V
Test Type : MINOR Test Pattern : JEE-Advanced
TEST DATE : 14 - 01 - 2017
Time : 3 Hours PAPER – 1 Maximum Marks : 210
READ THE INSTRUCTIONS CAREFULLY
GENERAL :
1. This sealed booklet is your Question Paper. Do not break the seal till you are told
to do so.
2. Use the Optical Response sheet (ORS) provided separately for answering the questions.
DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

3. Blank spaces are provided within this booklet for rough work.
4. Write your name, form number and sign in the space provided on the back cover of this
booklet.
5. After breaking the seal of the booklet, verify that the booklet contains 28 pages and that
all the 20 questions in each subject and along with the options are legible. If not, contact
the invigilator for replacement of the booklet.
6. You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET :
7. The ORS will be collected by the invigilator at the end of the examination.
8. Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9. Write your name, form number and sign with pen in the space provided for this purpose on
the ORS. Do not write any of these details anywhere else on the ORS. Darken the
appropriate bubble under each digit of your form number.
DARKENING THE BUBBLES ON THE ORS :

10. Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11. Darken the bubble COMPLETELY.
12. The correct way of darkening a bubble is as :
13. The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct
way.
14. Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase
or "un-darken" a darkened bubble.
15. Take g = 10 m/s2 unless otherwise stated.
Please see the last page of this booklet for rest of the instructions
Target : JEE (Main + Advanced) 2017/14-01-2017/Paper-1
SOME USEFUL CONSTANTS

Atomic No. H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58,
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
 Boltzmann constant k = 1.38 × 10–23 JK–1

1
 Coulomb's law constant = 9 ×10 9
4 0
 Universal gravitational constant G = 6.67259 × 10–11 N–m2 kg–2
 Speed of light in vacuum c = 3 × 108 ms–1
 Stefan–Boltzmann constant  = 5.67 × 10–8 Wm–2 –K–4
 Wien's displacement law constant b = 2.89 × 10–3 m–K
 Permeability of vacuum µ0 = 4 × 10–7 NA–2
1
 Permittivity of vacuum 0 =
0 c2
 Planck constant h = 6.63 × 10–34 J–s
Space for Rough Work
E-2/28 1001CT103516013
Leader Course/Phase-III, IV & V/14-01-2017/Paper-1
HAVE CONTROL  HAVE PATIENCE  HAVE CONFIDENCE  100% SUCCESS
PHYSICS
BEWARE OF NEGATIVE MARKING
PART-1 : PHYSICS
SECTION–I(i) : (Maximum Marks : 30)
 This section contains TEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.
 For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 In all other cases
1. A block of mass m is placed very gently on a wedge of mass M connected with initially relaxed
spring as shown in the figure. Inclined face of wedge is rough and ground is smooth. What is
compression of spring if system remains in equilibrium?
µ0
m k
M

µ=0
mg sin  cos  1  M2 mg sin  1  M2

(A) (B)
R R
mg cos  1  M2
(C) (D) Spring is not compressed
R
1001CT103516013 E-3/28
2. A point P moves along a circle of radius r with constant speed v. Its angular velocity about any
PHYSICS
fixed point on the circle will be :
v v v v
(A) (B) (C) (D)
r 2r r2 2r 2
3. A sports car accelerates from zero to a certain speed in t seconds. How long does it take for it to
accelerate to twice that speed starting from rest, assuming the power of the engine to be constant
(independent of velocity) and neglecting any resistance to motion?
(A) 2 t sec. (B) 2t sec. (C) 3t sec. (D) 4t sec.
4. Two pendulums of time periods 3 s and 7s respectively start oscillating simultaneously from
two opposite extreme positions. After how much minimum time they will be in phase :-
21 21 21 21
(A) s (B) s (C) s (D) s
8 4 2 10
E-4/28 1001CT103516013

5. Two small electric dioples, one of dipole moment p 1 at point A and the other of dipole moment
PHYSICS
 
p 2 at point B, are as shown in the figure. The torque experienced by the dipole p 2 is :-
p1 p2
x
(A) Zero (B) 

(C) Can't determined (D) None of these
6. Power transfer by a non-ideal cell to an external resistor can be same for two different values.
Out of which one value (R1) is less than internal resistance of cell and another (R2) is greater
than internal resistance of cell then :
(A) R1 will give less internal loss (B) R1 will give more battery life
(C) R2 will give less efficiency (D) R2 will give more battery life
1001CT103516013 E-5/28
7. For the circuit shown in figure the ratio of energy stored in capacitor (1) to that of in capacitor
PHYSICS
(2) is :-
C2
R1
R2
C1
R1C1 R1C2 R12C1 R1C12

(A) R C (B) R C (C) 2 (D)
2 2 2 1 R 2C 2 R2C22
8. A string is under tension and stationary vibrations are produced in it. A, B, C, D are positions
of consecutive nodes. Choose the INCORRECT option.

(A) The distance AB 
2
(B) The phase difference between a vibrating point on AB and another on BC is zero.
(C) The amplitudes of vibration of different points between A and the midpoint of A and B
are different.
(D) When every point of AB is having maximum displacement then every point of BC is
having maximum displacement in opposite direction.
E-6/28 1001CT103516013
9. Three rings each having equal radius R, are placed mutually perpendicular to each other and
PHYSICS
each having its centre at the origin of coordinate system. If current I is flowing through each
ring then the magnitude of the magnetic field at the common centre is :-
3I
(A)
2R
(B)
30I
2R
(C) 0 (D)  3 1  2RI
0
10. In figure shown, wire P1Q1 and P2Q2, both are moving towards right with speed 5 cm/sec.
Resistance of each wire is 2 . Then current through 19 resistor is :
P1 P2
4 cm 19
Q1 Q2 B = 1 Tesla
(A) 0 (B) 0.1 mA (C) 0.2 mA (D) 0.3 mA

1001CT103516013 E-7/28
SECTION–I(ii) : (Maximum Marks : 20)
PHYSICS
 This section contains FIVE questions.

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of
these four option(s) is (are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the
ORS
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is (are)
darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases.
11. A particle is moving in x-y plane with constant speed in anticlockwise direction such that
sum of distances from the two fixed point A (–a, 0) and B (a, 0) is always constant = 3a. At any
instant it has equal distance from A and B at that instant :
(A) vy  0 (B) vx  0 (C) ax  0 (D) ay  0
12. Two particles A & B of masses m and 2m respectively are connected through a spring in its
natural length. They are projected directly away from each other along spring with the same
speed. Mark the correct statement(s) :
(A) At the moment of maximum distance between them, the particles are moving with same
speed in same direction
(B) At the moment of maximum distance between them, the particles are moving with same
speed in opposite direction
(C) Minimum individual speed of the particles A & B are both zero
(D) Minimum individual speed of the particles A & B are both non-zero
E-8/28 1001CT103516013
13. Two parallel resistanceless rails are connected by an inductor of inductance L at one end as
PHYSICS
shown in the figure. A magnetic field B exists in the space which is perpendicular to the
plane of the rails. Now a conductor of length  and mass m is placed transverse on the rails
and given an impulse J towards the rightward direction. Then choose the CORRECT
option(s).
(A) Velocity of the conductor is half of the initial velocity after a displacement of the conductor
3J 2 L
d=
4B2  2 m
(B) Current flowing through the inductor at the instant when velocity of the conductor is half
3J 2
of the initial velocity is i =
4Lm
(C) Velocity of the conductor is half of the initial velocity after a displacement of the conductor
3J 2 L
d=
B2 2 m
(D) Current flowing through the inductor at the instant when velocity of the conductor is half
3J 2
of the initial velocity is i =
mL
1001CT103516013 E-9/28
14. Initially key was placed on (1) till the capacitor got fully charged. Key is placed on (2) at t = 0.
PHYSICS
The time when the energy in both capacitor and inductor will be same-
(1) (2)
L
E
C
 LC  LC 5 LC 5 LC
(A) (B) (C) (D)
4 2 4 2
15. The switch is closed at t = 0 in the adjoining circuit. Which of the following is/are CORRECT?
R L
R R
X Z
Y
s
E
(A) The potential difference across YZ at t = 0 is 2E/3
(B) The potential difference across XY at t =  is E/2
(C) The potential difference across YZ at t = 0 is E/2
(D) The potential difference across XY at t =  is 2E/3
SECTION –II : Matrix-Match Type & SECTION –III : Integer Value Correct Type
No question will be asked in section II and III
E-10/28 1001CT103516013
SECTION–IV : (Maximum Marks : 20)
PHYSICS
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both
inclusive.
 For each question, darken the bubble corresponding to the correct integer in the ORS.
Full Marks : +4 If only the bubble corresponding to the correct answer is darkened.
1. What minimum force (in N) should be applied to the end of the lever of a double pulley
system to hold a load P = 10 kg ? The length of the lever is  = 1m, the radius of the larger
pulley of the system r1 = 20 cm, the radius of the smaller pulley r2 = 10 cm (figure).
(Axle of the double pulley is fixed.)

lever
r2
r1
P
2. A free particle of mass 'm' is confined to a region of length L. The de-Broglie wave associated
with the particle is sinusoidal in nature as given in figure. The kinetic energy of the particle
n 2 h2
is then find the value of n.
8mL2
y
x
L/3 2L/3 L
1001CT103516013 E-11/28
3. A radioactive sample contains two radio nucleoids A and B having decay constant  hr–1 and
PHYSICS
2 hr–1. Initially 25% of total decay comes from A. How long (in hr) will it take before 75% of total
decay comes from A. [Take  = n 3]
4. The time period of Jupiter is (125)1/2 years. The distance of Jupiter from Sun in terms of
astronomical unit is given by  AU. Find the value of . (Astronomical unit is defined as the
average distance of Earth from the Sun).
5. Activity of radioactive material sample A and B at t = 0 is in ratio n2 : 1 and at t = n2T days,

ratio of their activities is  : 1, the half life of A is T days and half life of B is nT days. The
value of '' for n = 2.
E-12/28 1001CT103516013
PART-2 : CHEMISTRY
CHEMISTRY
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options
is correct.
1. A sample of 100 ml of a solution of a weak monoprotic acid of unknown concentration is titrated
with 0.500 M NaOH to give the titration curve shown
14
12
10
8
6
4
2
0
5 10 15 20 25
All of the statements are correct except -
(A) Phenolphthalein would be a suitable indicator for this titration
(B) A buffer solution is formed when 15 ml of NaOH is added
(C) The pKa of the acid is 4
(D) The initial concentration of the acid is 0.1M
2. It takes 126.5 minutes using a current of 5.15 A to deposit all of the nickel from 225 ml of
a solution containing Ni2+. What was the original concentration of Ni2+ in the solution-
(A) 3.6 M (B) 1.8 M (C) 0.9 M (D) 1.5 × 10–2 M
3. For which reaction (s) is the
H value close to the E value ?
I CH4(g) + 2O2(g)  CO(g) + 2H2O(l).
II C2H4(g) + 3O2(g)  2CO(g) + 2H2O(g)
(A) I only (B) II only (C) Both I & II (D) Neither I & II
1001CT103516013 E-13/28
4. Which of the following statement is CORRECT for the conversion given below :-
CHEMISTRY
–x –y
 I  Zn –4 air  III 
 Mn(CN)6    Mn(CN)6 
    M n (CN)6 
   
(I) (II)
(A) (I) is paramagnetic and (II) is diamagnetic
(B) High Spin complex (I) is formed by reduction with Zn

(C) 0 : (I) > (II)
(D) (II) acts as oxidizing agent
5. Which of the following will not give any coloured compound on heating ?
(A) Zn(NO3)2 (B) Hg(NO3)2 (C) (NH4)2Cr2O7 (D) NH4NO2
6. Which of the following option is INCORRECT ?
(A) (AlH3)n contain 3c–2e banana bond and it is nonplanar
(B) Bond order : CO < CO+
(C) Solubility order in water  BeF2 > MgF2 > CaF2
(D) Stability order : Br3 > Cl3
7. Which of the following complex show geometrical isomerism and structural isomerism but
does not show optical isomerism :-
(A) [Pd(NH2 –CH(CH3)–CO2–)2]0 (B) [Pd2Cl4(PPh3)2]
(C) [Pt(bn)2]2+ (D) [Zn(gly)2]0
E-14/28 1001CT103516013
8. The conversion
CHEMISTRY
O OH
H3C— C —CH2CH 2CO 2CH 3  H 3C— CH —CH 2CH2CH 2OH
can be effected using :
(A) LiAlH4 and then H+ (B) B2H6(THF) ; H2O / H+
(C) Na + EtOH (excess) (D) All
9. The final major product (Q) is :
dil. NaOH NaBH4

(P) (Q)
CH3OH
HO
O
OH OH O
(A) (B) (C) (D)
OH
10. For the given reaction
H2SO4 (i) m-CPBA Red P + HI

(P) +
(Q) (R)
OH (ii) H3O
Incorrect statement is :
(A) Number of monohalogenated product for (R) is 6
(B) (P) show positive bromine water test
(C) (Q) gives methane with CH3MgBr
(D) (Q) does not show the reaction with Na
1001CT103516013 E-15/28
CHEMISTRY

ORS
darkened.
11. What occurs when an aqueous solution of Na2SO4 containing several drops of phenolphthalein
is electrolyzed between Pt electrodes
(A) The colourless solution turns pink at the cathode
(B) The pink solution becomes colourless at the cathode
(C) The colourless solution remains colourless at the anode
(D) The colourless solution remains colourless at cathode
12. Which of the following statement(s) is/are correct about the triple point of water-
(A) The triple point for a substance varies with the pressure
(B) The three phases (solid, liquid, gas) have the same density
(C) The three phases ( solid, liquid, gas) are in equilibrium
(D) The three phases (solid, liquid and gas) are distinguishable in appearance.
13. Which of the following change(s) takes place during smelting in the blast furnace for extraction
of Fe ?
(A) CaCO3 — CaO + CO2 (B) Fe2O3 + 3CO — 2Fe + 3CO2
(C) Mn + CO — C + MnO (D) 2P2O5 + 10C — P4 + 10CO
E-16/28 1001CT103516013
14. Which of the given sequences are correctly matched with their final major product :
CHEMISTRY
O
CH2–NH2
(A) HCl + NaNO2
OH
+ + –
H3O [Ag(NH3)2] OH –
(B) O (P) CH3COO
SeO2 CrO3 N2H4 O

(C) (L) (M)
N H2O2
H3C H H3C H
(D) Na in
Liq. NH3
15. Which of the following give pair of diastereomers on reaction with CH3MgBr followed
by H2O :
O O
O
(A) (B) (C) (D)

O
1001CT103516013 E-17/28
CHEMISTRY

inclusive.
1. K2Cr2O7 is the powerful oxidising agent in acidic medium. In the same medium if oxidising
power of Cr2O72– decreases by 'x' volts, when pH of the solution increases from 0 to 5 at
2.303RT
298 K , then the value of '10x' will be. [Take :  0.06 ]
F
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.
2. Among the following total number of complexes which are low spin complex :-
K2[PtCl6] , [CrO4]2– , [Co(H2O)6]3+ , Na2[Zn(CN)4] , [IrF6]3– , [Cr(en)3]Cl3 , [Fe(NH3)6]2+
3. Find the total number of alloy which contain Cu :-
Solder , Brass , Bronze , German silver , Gun metal
E-18/28 1001CT103516013
4. How many of following reactions are correctly match with their major product :
CHEMISTRY
O
H2 ZnHg / HCl
(i) Pd-BaSO4
(ii)
COOH CH2OH
OH O
(iii) (t-BuO)3Al /
O
OH O Ph
HIO4 HBr
(iv) (v)
OH O OH Br
Ph
O
OEt OH
(i) O3
(vi)
(ii) Zn / EtO
(iii) NaBH4
COOH CH3 PCl3

(vii) (viii)
OH Cl
Aq. NaOH
(ix) CH3–CH2Cl CH3–CH2OH
1001CT103516013 E-19/28
5. How many of the given show positive Iodoform test :

CHEMISTRY
O O
O O
(i) CH3–C–OH (ii) (iii) (iv) CH 3–C–H
O
OH OH OH O
(v) (vi) (vii) O (viii)
OCH3
OH
O
OH
(ix) (x)
O
E-20/28 1001CT103516013
MATHEMATICS
PART-3 : MATHEMATICS
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options
is correct.
1. Area bounded by x  y  1  y  x  2 & y < 0 is equal to -
3 9 3 9
(A) (B) (C) (D)
8 8 4 4
2.
x 0

lim sgn cot 1 x  cot 1 x 2  (where sgn(x) is signum function), then -
(A) LHL = RHL = 1 (B) LHL = RHL = –1

(C) LHL = 1, RHL = –1 (D) LHL = –1, RHL = 1
x

x
2  2x 2 cos2
 
3. If  
0
 dx   , then
1  sin x   (1  sin x)22 dx is -
0
(A)  (B)  + 2 – 2 (C)  (D)  + 4 + 2
x y z x  2 y 1 z  2
4. Equation of the line of shortest distance between the lines   and  
2 3 1 3 5 2
is -
(A) 3(x – 21) = (3y – 92) = (3z – 32) (B) 3x – 62 = 3y – 93 = 3z + 31
 92   32 
y z  3 
(x  21)  3    62  31 
(C)   (D) x   y  31   z 
3 3 3 3  3 
1001CT103516013 E-21/28

MATHEMATICS

5. Let a, b, c  R0 and distinct such that   aiˆ  bjˆ  ckˆ and   (b  c)iˆ  (c  a)jˆ  (a  b)kˆ are

||
parallel then  is -
||
1 1
(A) 3 (B) (C) 2 (D)
3 2
6. Let z1, z2, z3 are roots of the equation z3 + z2(i – 1) + z(2 – i) – 2 = 0, then Re(z1) + Re(z2) + Re(z3)
is -
(A) –1 (B) 0 (C) 1 (D) 2
7. Number of points of intersection of |z – (1 + i)| = 1 and z  z  4 is -
(A) 0 (B) 1 (C) 2 (D) 3
8. Let the equation x4 – x3 – x2 – x –  = 0, where  N and >>>then number
of integral roots of the equation is -
(A) 0 (B) 2 (C) 4 (D) 3
x2 y2
9. Let P(x1, y1) & Q(x2, y2) are points lying on hyperbola 2  2  1 . If tangents drawn at the
a b
x1x2
points P & Q are perpendicular, then is -
y1 y2
a2 a2 a4 a4
(A)  (B) (C)  (D)
b2 b2 b4 b4
 
10. Let x, y are non zero and non collinear vectors such that
   
(a2  b  c)x  (a2  b  c)y  (a 2  b  c)(x  y)  0 , then (a + b + c) is (where a,b,c  R)
(A) –2 (B) –1 (C) 0 (D) 4
E-22/28 1001CT103516013
MATHEMATICS
ORS
darkened.
          
11. Let a,b,c are three non coplanar vectors such that   a  2b  3c,   a  3b  4c and
           
  a  b  c and   21a  41b  54c . If   x1  x 2  x 3  , then
(A) x3 > x2 > x1 (B) x1, x2, x3 are in A.P.
(C) H.C.F. of x1 & x3 is 2 (D) x1, x2, x3 are in H.P.
12. Consider a variable plane x + my + nz = k (k > 0) and , m, n are direction cosines of normal
of the plane. Let the given plane intersects co-ordinate axis at A, B, C, then area of ABC
may be -
3 3k 2 3 3k 2
(A) (B) (C) 3 3k2 (D) 12 3k2
2 4
13. For the parabola y2 – 4y + 8 = 4x which of the following is(are) false -
(A) Distance between focus and vertex is 2 unit.
(B) Equation of directrix is x = 2.
(C) Circle (x – 1)2 + (y – 2)2 = 4 cuts the given parabola at 4 points.
(D) Number of common tangents between the parabola and y2 – 4y + 4x = 0 is one.
1001CT103516013 E-23/28
MATHEMATICS
14. Let tangents PA & PB are drawn from variable point P on the parabola y2 = 4x to the circle
x2 + y2 + 10x – 4y + 25 = 0, then locus of circumcentre of PAB
 5 
(A) is a parabola (B) is satisfied by point   , 1 
 2 
(C) never cuts y-axis (D) intersect x-axis.
15. Let ƒ(x)ƒ'(x)ƒ''(x) > 0  x  R, then which of the following is(are) graph of ƒ(x)
ƒ(x)
ƒ(x)
(A) (B)
x x
ƒ(x) ƒ(x)
x x
(C) (D)
E-24/28 1001CT103516013
MATHEMATICS
inclusive.
1. Let (x, y, z) is three dimensional point which satisfies xyz4 = 16 where (x, y, z > 0) its minimum
distance from origin is , then  2 is
 y(3x  1) 
2. Let S = (x,y);  0  and S' = {(x, y)  A × B; –1 < A < 1 and –1 < B < 1}. Then area
 x(3x  2) 
of S  S' is
3. If ax2 + 2hxy + by2 + 2gx + 2ƒy + c = 0 and ax2 + 2hxy + by2 – 2gx – 2ƒy + c = 0 each represent pair
 |c|
of straight lines and area of parallelogram enclosed by them is , then || is
h2  ab
1001CT103516013 E-25/28
MATHEMATICS
4. If the parabola y = ax2 + bx + c has vertex at (4, 2) and a  [1,3] such that difference between

extreme values of abc is , then is
1728
x2 y2
5. Let chord of contact is drawn from every point lying on circle x2 + y2 = 100 to the ellipse  1
4 9
such that all the lines touches an standard ellipse whose eccentricity is e,
81e2
then is
13
E-26/28 1001CT103516013
1001CT103516013 E-27/28
QUESTION PAPER FORMAT AND MARKING SCHEME :
16. The question paper has three parts : Physics, Chemistry and Mathematics.
17. Each part has two sections as detailed in the following table.
Que. No. Category-wise Marks for Each Question Maximum
Section Type of Full Partial Zero Negative Marks of the
Que. Marks Marks Marks Marks section
+3 0
I(i) Single If only the bubble In all
correct option 10 corresponding to — other — 30
the correct option cases
is darkened
+4 0 –1
One or more If only the bubble(s) If none In all
I(ii) correct corresponding of the other
option(s) 5 to all the correct — bubbles is cases 20
option(s) is(are) darkened
darkened
+4 0 –1
Single digit If only the bubble If none In all
IV Integer 5 corresponding — of the other 20
(0-9) to correct answer bubbles is cases
is darkened darkened
NAME OF THE CANDIDATE ................................................................................................
FORM NO. .............................................
I have read all the instructions I have verified the identity, name and Form
and shall abide by them. number of the candidate, and that question
paper and ORS codes are the same.
____________________________ ____________________________
Signature of the Candidate Signature of the invigilator
Corporate Office :  CAREER INSTITUTE, “SANKALP”, CP-6, Indra Vihar, Kota (Rajasthan)-324005
+91-744-5156100 info@allen.ac.in www.allen.ac.in
E-28/28 Your Target is to secure Good Rank in JEE 2017 1001CT103516013
Paper Code : 1001CT103516013
CLASSROOM CONTACT PROGRAMME

HINDI
(Academic Session : 2016 - 2017)
JEE (Main + Advanced) : LEADER COURSE

PHASE : III, IV & V
Test Type : MINOR Test Pattern : JEE-Advanced
TEST DATE : 14 - 01 - 2017
Time : 3 Hours PAPER – 1 Maximum Marks : 210


1. 
2. 
(ORS) 
3. 
4. 
5. 
28 
20 



6. 


7. 
8. 

9. 



:
10. 


11.  


12. 

:
13. 
14. 

15. g = 10 m/s2 
           
SOME USEFUL CONSTANTS

Atomic No. H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58,
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
 Boltzmann constant k = 1.38 × 10–23 JK–1

1
 Coulomb's law constant = 9 ×10 9
4 0
 Universal gravitational constant G = 6.67259 × 10–11 N–m2 kg–2
 Speed of light in vacuum c = 3 × 108 ms–1
 Stefan–Boltzmann constant  = 5.67 × 10–8 Wm–2–K–4
 Wien's displacement law constant b = 2.89 × 10–3 m–K
 Permeability of vacuum µ0 = 4 × 10–7 NA–2
1
 Permittivity of vacuum 0 =
0 c2
 Planck constant h = 6.63 × 10–34 J–s

H-2/28 1001CT103516013
HAVE CONTROL  HAVE PATIENCE  HAVE CONFIDENCE  100% SUCCESS
PHYSICS
BEWARE OF NEGATIVE MARKING

-1 :  
–I(i) : ( : 30)
   
  
  

  (A), (B), (C) 
(D)  
    
               
       
 


   
  : +3           
 : 0    
1.  m
M  
(relaxed) 

µ0
m k
M

µ=0
mg sin  cos  1  M2 mg sin  1  M2

(A) (B)
R R
mg cos  1  M2
(C) (D) 
R

1001CT103516013 H-3/28
2. 
P v 
r 
PHYSICS

v v v v
(A) (B) (C) (D)
r 2r r2 2r 2
3. 
t


(A) 2 t sec. (B) 2t sec. (C) 3t sec. (D) 4t sec.
4. 
3 s 
7s 

21 21 21 21
(A) s (B) s (C) s (D) s
8 4 2 10

H-4/28 1001CT103516013
 
5. 
p 1 
A 
p 2 
B 
PHYSICS


p 2 
p1 p2
x
(A) (B) 
(C)  (D) 
6. 
(R1) 
(R2) 
(A) R1  (B) R1 
(C) R2  (D) R2 

1001CT103516013 H-5/28
7. 
(1)
(2)
PHYSICS
C2
R1
R2
C1
R1C1 R1C2 R12C1 R1C12

(A) R C (B) R C (C) 2 (D)
2 2 2 1 R 2C 2 R2C22
8. 
A, B, C, D 



(A) 
AB  
2
(B) AB 
BC 
(C) A 
A  B 
(D)  AB 
BC 


H-6/28 1001CT103516013
9. 
R 
PHYSICS

I 
y
3I
(A)
2R
(B)
30I
2R
(C) 0 (D)  3 1  2RI
0
10. 
P1Q1 
P2Q2 
5 cm/sec 
2 
19 
P1 P2
4 cm 19
Q1 Q2 B = 1 Tesla
(A) 0 (B) 0.1 mA (C) 0.2 mA (D) 0.3 mA

1001CT103516013 H-7/28
–I(ii) : ( : 20)

PHYSICS
   

 
   
  
(A), (B), (C)  (D)  

      
               
       
 

   
 : +4            
 : 0         
  : –1    
11.  x-y 
A (–a, 0) 
B (a, 0)

3a 
A 
B 
(A) vy  0 (B) vx  0 (C) ax  0 (D) ay  0
12. 
A B 
m 2m 


(A) 
(B) 
(C) A B 
(D) A B 

H-8/28 1001CT103516013
13. 
L 
PHYSICS

B 
 
m 

J 

B
3J 2 L
(A) 
d= 
4B2  2 m
3J 2
(B) 
i= 
4Lm
3J 2 L
(C) 
d= 
B2 2 m
3J 2
(D) 
i= 
mL

1001CT103516013 H-9/28
14. 
(1)
t = 0
(2)
PHYSICS

(1) (2)
L
E
C
 LC  LC 5 LC 5 LC
(A) (B) (C) (D)
4 2 4 2
15. 
t = 0 

R L
R R
X Z
Y
s
E
(A) t = 0  YZ 

2E/3 (B) t =   XY 
E/2
(C) t = 0  YZ 
E/2 (D) t =   XY 
2E/3

–II :  & –III : 

II III 
H-10/28 1001CT103516013
–IV : ( : 20)
PHYSICS
   
  
    
0 9      

 
 
             
       
 

   
 : +4           
 : 0         
  : –1    
1.           
(N 

)  
   
P = 10kg 
 = 1m, r1 = 20 cm 

r2 = 10 cm (
)

lever
r2
r1
2. 
'm' 
L 
n 2 h2


n 
8mL2
y
x
L/3 2L/3 L

1001CT103516013 H-11/28
3.  
A 
B  
 hr–1 
PHYSICS
2 hr–1 
25%, A 
75%A 

[
 = n 3]
4. 
(125)1/2 
 AU 

(
)
5. 
A  B t = 0  n2 : 1 
t = n2T 

 : 1 
A 
T 
B 
nT 
n = 2  '' 

H-12/28 1001CT103516013

-2 :  
CHEMISTRY
–I(i) : ( : 30)
   
  
   
  
(A), (B), (C) (D)  
    
               
       
 

   
 : +3           
 : 0    
1.      
100 ml

       
0.500 M NaOH      
14
12
10
8
6
4
2
0
5 10 15 20 25
      
-  
(A)         
(B)  15 ml NaOH          
(C)  pKa 4 
(D)    
0.1M 
2. 5.15 A    Ni

2+
 225 ml           
126.5       
Ni2+
   - 
(A) 3.6 M (B) 1.8 M (C) 0.9 M (D) 1.5 × 10–2 M

1001CT103516013 H-13/28
3.   H


 
E    
? 
CHEMISTRY
I CH4(g) + 2O 2(g)  CO(g) + 2H2O(l).

II C2H4(g) + 3O 2(g)  2CO(g) + 2H2O(g)
(A) I (B) II (C) I 
II  (D)  
I 
II
4. 
:-
–x –y
 I  Zn –4  III
air 
 Mn(CN)6    Mn(CN)6 
   M n (CN)6 

   
(I) (II)
(A) (I) 
(II) 
(B) Zn 
(I) 
(C) 0 : (I) > (II)
(D) (II) 
5. 
?
(A) Zn(NO3)2 (B) Hg(NO3)2 (C) (NH4)2Cr2O7 (D) NH4NO2
6. 
 ?
(A) (AlH3)n 
3c–2e 
banana bond) 
(B) : CO < CO+
(C) 
 BeF2 > MgF2 > CaF2
(D) 
: Br3 > Cl3
7. 

:-
(A) [Pd(NH2 –CH(CH3)–CO2–)2]0 (B) [Pd2Cl4(PPh3)2]
(C) [Pt(bn)2]2+ (D) [Zn(gly)2]0

H-14/28 1001CT103516013
8. 
CHEMISTRY
O OH
H3C— C —CH2CH 2CO 2CH 3  H 3C— CH —CH 2CH2CH 2OH
     

(A) LiAlH4 
H+ (B) B2H6(THF) ; H2O / H+
(C) Na + EtOH  (D) 

9.   
(Q) 
dil. NaOH NaBH4

(P) (Q)
CH3OH
HO
O
OH OH O
(A) (B) (C) (D)
OH
10.     
H2SO4 (i) m-CPBA Red P + HI

(P) +
(Q) (R)
OH (ii) H3O
  

(A) (R)    6 
 
(B) (P)       
(C) (Q) , CH3MgBr     
(D) (Q) , Na       

1001CT103516013 H-15/28
–I(ii) : ( : 20)
CHEMISTRY
   

 
   
  
(A), (B), (C)  (D)   
      
               
        

   
 : +4            
 : 0         
  : –1    
11.     
Na2SO4  
   Pt     
       
(A)          
(B)        
(C)       
(D)       
12.           
-   
(A)           
(B)         
. 
(C)     
.   
(D)   



     
13. Fe 
?
(A) CaCO3 — CaO + CO2 (B) Fe2O3 + 3CO — 2Fe + 3CO2
(C) Mn + CO — C + MnO (D) 2P2O5 + 10C — P4 + 10CO

H-16/28 1001CT103516013
14.                  
CHEMISTRY
O
CH2–NH2
(A) HCl + NaNO2
OH
+ + –
H3O [Ag(NH3)2] OH –
(B) O (P) CH3COO
SeO2 CrO3 N2H4 O

(C) (L) (M)
N H2O2
H3C H H3C H
(D) Na in
Liq. NH3
15.    CH 

3
MgBr
    
H2O     
     
O O
O
(A) (B) (C) (D)

O

–II :  & –III : 

II III 
1001CT103516013 H-17/28
–IV : ( : 20)
CHEMISTRY
   

  
    
0 9      

 
 
             
       
 

   
 : +4           
 : 0         
  : –1    
1.   
K2Cr2O7       pH
298K 0 5     
2.303RT
Cr2O72– 
 'x' 
'10x' 
[:  0.06 ]
F
   
(
   
)          
  
2. 
:-
K2[PtCl6] , [CrO4]2– , [Co(H2O)6]3+ , Na2[Zn(CN)4] , [IrF6]3– , [Cr(en)3]Cl3 , [Fe(NH3)6]2+
3. 
alloy
Cu 
:-

Solder ,  (Brass) , 
(Bronze) , , 
(Gun metal)

H-18/28 1001CT103516013
4.               
CHEMISTRY
O
H2 ZnHg / HCl
(i) Pd-BaSO4
(ii)
COOH CH2OH
OH O
(iii) (t-BuO)3Al /
O
OH O Ph
HIO4 HBr
(iv) (v)
OH O OH Br
Ph
O
OEt OH
(i) O3
(vi)
(ii) Zn / EtO
(iii) NaBH4
COOH CH3 PCl3

(vii) (viii)
OH Cl
Aq. NaOH
(ix) CH3–CH2Cl CH3–CH2OH

1001CT103516013 H-19/28
5.         

CHEMISTRY
O O
O O
(i) CH3–C–OH (ii) (iii) (iv) CH 3–C–H
OH OH OH O
(v) (vi) (vii) O (viii)
OCH3
OH
O
OH
(ix) (x)
O

H-20/28 1001CT103516013

-3 : 
MATHEMATICS
–I(i) : ( : 30)
   
  
  

 
(A), (B), (C) (D)  
    
               
       
 


   
  : +3           
  : 0    
1. x  y 1  y  x  2 
y < 0 
-
3 9 3 9
(A) (B) (C) (D)
8 8 4 4
2. lim sgn cot 1 x  cot 1 x 2 (sgn(x) 

  ),  -
x 0
(A) LHL = RHL = 1 (B) LHL = RHL = –1

(C) LHL = 1, RHL = –1 (D) LHL = –1, RHL = 1
x
 2  2x 2 cos2
x
3.    
 dx   
 (1  sin x)22 dx 
-
0
1  sin x  0
(A)  (B)  + 2 – 2 (C)  (D)  + 4 + 2
x y z x  2 y 1 z  2
4.       
-
2 3 1 3 5 2
(A) 3(x – 21) = (3y – 92) = (3z – 32) (B) 3x – 62 = 3y – 93 = 3z + 31
 92   32 
 y   z
(x  21)  3   3  62  31 
(C)   (D) x   y  31   z 
3 3 3 3  3 

1001CT103516013 H-21/28
 
MATHEMATICS
5. 
a, b, c  R0 
  aiˆ  bjˆ  ckˆ 
  (b  c)iˆ  (c  a)jˆ  (a  b)kˆ 

||
 
-
||
1 1
(A) 3 (B) (C) 2 (D)
3 2
6. z1, z2, z3 z3 + z2(i – 1) + z(2 – i) – 2 = 0 

Re(z1) + Re(z2) + Re(z3) 
-
(A) –1 (B) 0 (C) 1 (D) 2
7. |z – (1 + i)| = 1 
zz4 
-
(A) 0 (B) 1 (C) 2 (D) 3
8.  –
x4 x3 – x2 – x –  = 0, 
 N 
>>>

-
(A) 0 (B) 2 (C) 4 (D) 3
x2 y2
9. 
P(x1, y1) 
Q(x2, y2),   1 
P 
Q 
a 2 b2
xx

1 2

-
y1 y2
a2 a2 a4 a4
(A)  (B) (C)  (D)
b2 b2 b4 b4
 
10. 
x, y 
   
(a2  b  c)x  (a2  b  c)y  (a 2  b  c)(x  y)  0 
(a + b + c) 
(
a,b,c  R)
(A) –2 (B) –1 (C) 0 (D) 4

H-22/28 1001CT103516013
–I(ii) : ( :
MATHEMATICS
20)
   
 
   
  
(A), (B), (C) (D)  

      
               
       
 


   
  : +4            
  : 0         
  : –1    
              
11. a,b,c       
  a  2b  3c,   a  3b  4c   a  b  c 
       
  21a  41b  54c 
  x1  x2  x3  
(A) x3 > x2 > x1 (B) x1, x2, x3 
(C) x1 
x3 2  (D) x1, x2, x3 
12.  x + my + nz = k (k > 0) 
, m, n 

A, B, C 
ABC 
-
3 3k 2 3 3k 2
(A) (B) (C) 3 3k2 (D) 12 3k2
2 4
13.  y2 – 4y + 8 = 4x 

-
(A) 
2 
(B)  x = 2 
(C) 
(x – 1)2 + (y – 2)2 = 4, 4 
(D) y2 – 4y + 4x = 0 

1001CT103516013 H-23/28
y2 = 4x 
P 
PA 
PB, 
x2 + y2 + 10x – 4y + 25 = 0 
MATHEMATICS
14.

PAB 
 5 
(A)  (B) 
  2 , 1 
 
(C) y- (D) x-

15. 
ƒ(x)ƒ'(x)ƒ''(x) > 0  x  R 
ƒ(x) 
ƒ(x)
ƒ(x)
(A) (B)
x x
ƒ(x) ƒ(x)
x x
(C) (D)

–II :  & –III : 

II III 
H-24/28 1001CT103516013
–IV : ( :
MATHEMATICS
20)
   
  
    
0 9      

 
 
             
       
 


   
  : +4           
  : 0         
  : –1    
1. 
(x, y, z)
xyz4 = 16 (x, y, z > 0) 

 
2 
 y(3x  1) 
2. 
S = (x,y);  0 
S' = {(x, y)  A × B; –1 < A < 1 
–1 < B < 1} 
S  S'
 x(3x  2) 

3. ax2 + 2hxy + by2 + 2gx + 2ƒy + c = 0 
ax2 + 2hxy + by2 – 2gx – 2ƒy + c = 0 
 |c|


|| 
h2  ab

1001CT103516013 H-25/28
 
(4, 2) 
a  [1,3] 
abc 
 
MATHEMATICS
4. y = ax2 + bx + c

1728 
x2 y2
5. 
x2 + y2 = 100 
  1 
4 9
81e2
e  

13

H-26/28 1001CT103516013
1001CT103516013 H-27/28

16. 
17. 
    
       
 
I(i)  +3 0
 10
 —
 — 30
 
 
 +4 0 –1
I(ii)    
 5  —  
20
  
 
 +4 0 –1
IV    
5 — 20
(0-9)   
  

  

................................................................................................
 
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       

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H-28/28 Your Target is to secure Good Rank in JEE 2017 1001CT103516013

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Paper Code : 1001CT103516013

CLASSROOM CONTACT PROGRAMME

JEE (Main + Advanced) : LEADER COURSE

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

DARKENING THE BUBBLES ON THE ORS :

11. Darken the bubble COMPLETELY.

12. The correct way of darkening a bubble is as :

SOME USEFUL CONSTANTS

 Boltzmann constant k = 1.38 × 10–23 JK–1

mg sin  cos  1  M2 mg sin  1  M2

fixed point on the circle will be :

Space for Rough Work

(A) Zero (B) 

R1C1 R1C2 R12C1 R1C12

(A) 0 (B) 0.1 mA (C) 0.2 mA (D) 0.3 mA

 This section contains FIVE questions.

Space for Rough Work

5. Activity of radioactive material sample A and B at t = 0 is in ratio n2 : 1 and at t = n2T days,

(A) (I) is paramagnetic and (II) is diamagnetic

(B) High Spin complex (I) is formed by reduction with Zn

Space for Rough Work

can be effected using :

(A) LiAlH4 and then H+ (B) B2H6(THF) ; H2O / H+

(C) Na + EtOH (excess) (D) All

9. The final major product (Q) is :

dil. NaOH NaBH4

(A) (B) (C) (D)

10. For the given reaction

H2SO4 (i) m-CPBA Red P + HI

(A) Number of monohalogenated product for (R) is 6

(B) (P) show positive bromine water test

(C) (Q) gives methane with CH3MgBr

(D) (Q) does not show the reaction with Na

Space for Rough Work

 This section contains FIVE questions.

SeO2 CrO3 N2H4 O

(A) (B) (C) (D)

Space for Rough Work

 This section contains FIVE questions.

K2[PtCl6] , [CrO4]2– , [Co(H2O)6]3+ , Na2[Zn(CN)4] , [IrF6]3– , [Cr(en)3]Cl3 , [Fe(NH3)6]2+

3. Find the total number of alloy which contain Cu :-

Solder , Brass , Bronze , German silver , Gun metal

Space for Rough Work

COOH CH3 PCl3

Space for Rough Work

5. How many of the given show positive Iodoform test :

1. Area bounded by x  y  1  y  x  2 & y < 0 is equal to -

(A) LHL = RHL = 1 (B) LHL = RHL = –1

(A)  (B)  + 2 – 2 (C)  (D)  + 4 + 2

Space for Rough Work

Space for Rough Work

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NAME OF THE CANDIDATE ................................................................................................

FORM NO. .............................................

CLASSROOM CONTACT PROGRAMME

(Academic Session : 2016 - 2017)

JEE (Main + Advanced) : LEADER COURSE

SOME USEFUL CONSTANTS

 Boltzmann constant k = 1.38 × 10–23 JK–1

mg sin  cos  1  M2 mg sin  1  M2

R1C1 R1C2 R12C1 R1C12

(A) 0 (B) 0.1 mA (C) 0.2 mA (D) 0.3 mA