Aits FT-3 Jee Adv Paper-2 18.01.2022 Solution+qp

FIITJEE
ALL INDIA TEST SERIES

JEE (Advanced)-2022
FULL TEST – III
PAPER –2
TEST DATE: 18-01-2022
Time Allotted: 3 Hours Maximum Marks: 180
General Instructions:
 The test consists of total 57 questions.
 Each subject (PCM) has 19 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Three Sections: Section-A, Section-B & Section-C.
Section – A (01 –06, 20 – 25, 39 – 44): This section contains EIGHTEEN (18) questions. Each question has
FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Section – A (07 –10, 26 – 29, 45 – 48): This section contains SIX (06) paragraphs. Based on each
paragraph, there are TWO (02) questions. Each question has FOUR options (A), (B), (C) and (D). ONLY ONE
of these four options is the correct answer.
Section – B (11 – 13, 30 – 32, 49 – 51): This section contains NINE (09) questions. The answer to each
question is a NON-NEGATIVE INTEGER.
Section – C (14 – 19, 33 – 38, 52 – 57): This section contains NINE (09) question stems. There are TWO
(02) questions corresponding to each question stem. The answer to each question is a NUMERICAL
VALUE. If the numerical value has more than two decimal places, truncate/round-off the value to TWO
decimal places.
MARKING SCHEME
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both of which
are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
Section – C: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-III (Paper-2)-PCM-JEE(Advanced)/22 2
Physics PART – I
Section – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MOER THAN ONE of these four option(s) is (are) correct answer(s).
1. A wire having a uniform linear charge density  , is bent in the form of a a1

ring of radius R. Point A as shown in the figure, is in the plane of the
ring but not at, the centre. Two elements of the ring of lengths a1 and r1
a2 subtend very small and equal angles at the Point A. They are at A
distances r1 and r2 from the point A respectively.
r2
a2
r1
(A) The ratio of charge on elements a1 and a2 is .
r2
(B) The element a1 produces greater magnitude of electric field at A than element a2.
(C) The element a1 and a2 produce same potential at A.
(D) The elements a1 produces greater potential at A than element a2.
Ans. ABC
Sol. dq1 = a1

dq2  a 2
dq1 a1  r1 r1
  
dq2 a2  r2 r2
kdq1 kdr1 
E1   2 
r12 r1 r1
1
E1 
r1
2. Four particles A, B, C and D of masses m A, mB, mC and mD respectively, follow the paths shown
in the figure, in a uniform magnetic field. Each particle moving with same speed. QA, QB,QC and
QD are the specific charge of particles A,B,C and D respectively :
X X X X X X X X X X
X X X X X X X X X X
X X X X X X X X Constant
X X
magnetic
X X X X X X X X fieldX X
X X X RX X X X X X X
X X X X X X X X X X
X X X AX X X X X X X
2R C
X X X X X X X X X X
B
X X X X X X X X X X
R
X X X X X X X X X X
X X X X X X X X D X X
(A) QA < QB <QC <QD
3 AITS-FT-III (Paper-2)-PCM-JEE(Advanced)/22
(B) QD < QB < QC < QA
(C) Charge on the particle B and particle D is of different nature
(D) Work done by magnetic force on the particle C is minimum as compared to other particle
Ans. B
Sol. Since B & revolve in opposite since, thus they are oppositely charged. From direction of motion of
the charges QA = + ve QB & QD  -ve QC  neutral
3. consider a metal rod of length L that is given a uniform acceleration as shown in figure (a) and an
identical rod rotating with constant angular velocity in figure (b).
B
a l
R
A B
A
l
Stationary conducting
(a) Circular Frame
(b)
(A) If VA and VB are potentials of end A and B respectively, then VA < VB in figure (a)
(B) If VA and VB are potentials of end A and B respectively, then VA > VB in figure (b)
ma
(C) Electric field inside rod has magnitude in figure (a)
e
m 2r
(D) Electric field inside rod has magnitude in figure (b)
e
Ans. ABCD
Sol. Due to psuedo force, electrons move from B to A.

a
A E B VA > VA
-ive +ive
In figure (b) electron moves from A to B
Region I Region II
4. There is a spherical glass ball of refractive index 1 and

another glass ball of refractive index  2 inside it as shown in 1
figure. The radius of the outer ball is R1 and that of inner ball is i2 B
r2 C
R2. A ray is incident on the outer surface of the ball at an A r1 O D
angle i1. Mark the correct options. i1
1
R1 R2 2
-1  sini1 
(A) The Value or r1 is sin  
 1 
 R 
(B) The value of r2 is sin1  1 sini1 
  2R2 
 sini2 
The value of r1 is sin   
-1
(C)
 2 
 R 
(D) The value of r2 is sin1  2 sini1 
 R
 2 1 
Ans. AB
Sol. 1 sinr1  sini1

 sini1 
 r1  sin1  
 1 
1
sini2  sinr2
2
1 R1 sini1
 sinr2
 2 R 2 1
 R 
r2  sin1  1 sini1 
 R
 2 2 
5. A bead is fixed on a rigid ring of radius r and of mass that

negligible as compared to that of the bead. Assembly thus formed
is held motionless on a horizontal floor with the plane of the ring
vertical and the bead on the top. Coefficient of friction between the
ring and the floor is  . Now the assembly is given a slight push so
that the ring starts rolling Acceleration of free fall is g. Choose the
correct statements.
(A) The angle rotated by the ring before it begins to slide tan-1   
(B) The speed of centre of the ring before it begins to slide  gR
-1
(C) The angle rotated by the ring before it begins to slide 2tan  
(D) The speed of the centre of the ring before it begins to slide.  2gR
Ans. BC
Sol. 

V
N
P N
VC is Horizontal only.
  

VP  VPC  VC
VP  0
Mechanical energy conservation,
1 2
mgR 1  cos    mVbead VBead  2v cos  / 2
2
gR  2sin2  / 2  2v 2 cos2  / 2
V = gR tan  / 2

em  Icm  0 As Icm  0
NR sin   N  R  R cos  
tan  / 2  
  2 tan1   
6. An adiabatic container of volume 4 V0 is divided into two equal parts by rigid fixed wall whose
lower half is conducting and upper half in non-conducting. Initially the right portion is divided into
two equal parts by a freely moving massless & non conducting piston. Section A has 2 moles, B
and C each has one mole of an ideal gas with adiabatic exponent    1.5. If the heater in left part
is switched on till the final pressure C becomes (125/27) Po. Mark the correct statements
Non Conducting
Po
B
A Vo
Po
2Vo Po
C
Vo
Conducting
205Po Vo
(A) Final temperature in section A
27R
5Po Vo
(B) Final temperature in section B
3R
205Po Vo
(C) Final temperature in section C
27R
368
(D) Heat supplied by the Heater Po Vo
9
Ans. ABCD
Sol. For piston to be in equilibrium

PB = PC
Process in B is adiabatic,
Process in A is Isochoric
At every instant Temperature of A = Temperature of C
For B
1.5 125 9Vo
P oV o = Po v1.5 V =
27 25
16Vo
Volume of C will increase by
25
41Vo
VC 
25
125 9Vo 5Po Vo
TB  Po 
27 25 3R
205 Po Vo
TC =   TA
27 R
Net work done by gas is zero as there is no pushing of surroundings.
Q Heater =  Usyst
368
Q Heater = Po Vo
9

This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
Paragraph for Question Nos. 07 and 08
A small bead starts sliding down a frictionless rigid helical wire frame. The axis of the R
helix is vertical, radius is R and pitch is h.
A h
Axis
7. In How much time, will the Bead descend a Height H?
2H h2  42R2
(A)
g h
H h2  42R2
(B)
g h
H h2  42R2
(C)
g 2h
(D) None of these
Ans. A
Sol. Motion along Helix = Motion in horizontal plane + Motion along Axis.
a t cos 
at
h a t sin 

2 R
Top view
an
v cos  a t ,cos 
a t  gsin 
A along Axis = a t sin   gsin2 .
1 2H 1 2H h2  42R2
H gsin2 . t=  
2 g sin  g h
8. How much force will the wire frame exert on the bead when the bead has descended a height H?
[Acceleration of free ball g]
h2  42R2  162H2
(A) 2mgR
h 2  4 2 R 2
mgR h2  42R2  162H2

(B)
h2  42R 2
mgR h2  2R 2  42H2

(C)
h2  4 2R 2
(D) None of these
Ans. A
Sol. N2
N1
mg
v cos 
2
2 2
m  v cos  
N= N N
1 2 N1  N2  mgcos 
R
v  2gH
2mgR h2  42R 2  162H2
N=
h2  42R2
A prism shaped Styrofoam of density styrofoam < water is held completely submerged in water. It lies with
its base horizontal. The base of foam is at a depth h0 below water surface and atmospheric pressure is
Po. Surface is open to atmosphere. Styrofoam prism is held in equilibrium by the string attached
symmetrically.
 Take : styrofoam  f ; water    .
l
ho
90o
PL
l 90°
9. Net force exerted by liquid on the Styrofoam is:
(A) 2 gl2L
(B) 2 gl2L
l2L
(C) g
2
(D)  gl2L
Ans. C
10. Magnitude of force on any one of the slant face of Styrofoam is:
(A)
 o  o 
P   g h  2l  Ll
 
  l 
(B) Po   g  ho    Ll
  2 
  l 
(C) Po   g  ho    Ll
  2 
  l 
(D) Po  p g  ho    Ll
  2 2 
Ans. D
l2L
Sol. Net force exerted by liquid on Styrofoam is buoyant force =  g
2
Average pressure on slant surface
 l 
Po  gho    Po  gho  
 2
Pavg 
2
 1 
  Po   gho  
 2 2
Force on any one of the slant surface
  l 
Po  p g  ho    Ll
  2 2 
Section – B (Maximum Marks: 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER.
11. An arrangement consisting of slabs is show in the figure. When system is placed in situation (a)
with temperature difference is maintained between (1) and (2), equivalent thermal conductivity of
system is K and when system in changed to situation (b) and temperature difference is
maintained between (3) and (4) then equivalent thermal conductivity increases by 20%. Find
number of slabs in the arrangement.
d
l d
2l
k
d
(3) 2k
d nl (4)
(1) (2)
k 2k nk
nk
2l nl (b)
l (a)
Ans. 4
Sol. In first case

l  2l  .....  nl l 2l 3l nl
    ...... 
k eq A kA 3kA 3kA nkA
k eq1 
 n  1 k
2
In second case
k eq2 
 k1Ai
 Ai
kA '  2k  2A '   ......   nk  nA ' 

A ' 2A ' .....  nA '

 2n  1 k
2
 2n  1 k
6  n  1 k

3 5 2
9n + 9 = 10n + 5
n=4
12. A small boat is travelling downstream with velocity 5 m/s relative to river
flowing with speed 7/3 m/s. it encounters a log floating in the river at some
distance from itself. It turns by an angle of 37o and just crosses the edge of
the log after 8 sec. Find time taken by boat to just cross the edge of log if
log is kept fixed.
Ans. 6
Sol. Q
Vbr = 5
PQ = 5  8  4 0 m
37o w.r.t Ground
P Boat
  

Vb  Vbr  Vr
Velocity must be along PQ
vbr sin   vr sin37
sin   7 / 25
Vbr Vb Q
Q
P Vr
40
t  6 sec.
v br cos   v r cos 37o
13. A pendulum with massless string of length l and bob of mass m is

attached inside a railway carriage which is moving with speed v 0 as V0 V0
shown. Carriage is brought to rest uniformly by applying brakes.
When carriage comes to rest pendulum string is horizontal. Minimum
magnitude of retardation of carriage such that bob completes vertical
circular motion is (3k-2) ms-2. Find k. (g = 10 ms-2)
Ans. 9
Sol. Acceleration of train = a 

Motion of bob w.r.t. train:

Initially V bob /train  O
From A   B, pseudo force F = ma  acts on bob. Let bob turns through 180o and has
speed v’ at highest position
V’
1800
v
F 
F = ma A
(pseudo) at rest
W/E theorem A  B :
1
FR = mv 2  mgh
2
mv 2
 2  ma  mg …….(i)
R
B   C : Now train has stopped, a = 0,
No pseudo force acts on bob.
Conservation of Energy
1 1
mgR + mv '2  mv 2
2 2
mv '2 mv 2
  2mg
R R
T + mg = 2 (ma – mg) – 2mg [From eq. (i)]
On solving a  25m / s 2
3K – 2 = 25 K=9
Section – C (Maximum Marks: 12)

This section contains THREE (03) questions stems. There are TWO (02) questions corresponding to
each question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has
more than two decimal places, truncate/round-off the value to TWO decimal places.
Question Stem for Question Nos. 14 and 15
Question Stem
Consider two neutral concentric conducting thin spherical shells of radii r and 3r. A particle of positive
charge Q is fixed at a distance 2r from the common center of the shells. The inner shell can be electrically
connected to the outer shell through a resistance R1 with the help of switch S1 and outer shell can be
grounded through a resistance R2 with the help of another switch S2 as shown.
H1 (total heat) is dissipated in the resistance R1 after the switch S1 is closed keeping the switch S2 open
until a steady state is reached:
S2
R1 3r
S1 +Q
r R2
2r
When steady state is reached after closing the switch S1, the other switch S2 is closed. Total Heat
dissipated after the switch S2 is closed until a new steady state is reached is H2.
Q2
(Take  108 SI units]
0 r
14. Then the value of H1 is ___________
Ans. 00000.56
Q2
Sol. H1 =
1920 r
15. Then the value of H2 is ___________
Ans. 00004.33
Q2
Sol. H2 
24 0r

Question Stem
A glass plate is placed above a glass cube of 2 cm edges in such a way that there
remains a thin air layer between them, see figure. Electromagnetic radiation of
d
wavelength between 400 nm and 1150 nm (for which the plate is penetrable) incident
perpendicular to the plate from above is reflected from both air surfaces and h
interferes. In this range only two wavelengths give maximum reinforcements, one of
them is 400 nm.  is the second wavelength. T is change in temp. necessary to warm
up the cube so as it would touch the plate. The coefficient of linear thermal expansion
is   8  106. the refractive index of the air   1 . The distance of the bottom of the
cube from the plate does not change during warming up.
Then,
16. The value of  (in nm) ______
Ans. 00666.67
17. The value of T (in o C) ______
Ans. 00003.10
Sol. 2d   2n  1  / 2 for constructive interference

4d

2n  1
4d 4d 4d
  4d, , , -------
3 5 7
As n   
4d
400   4d  400  2n  1
2n  1
400 31
 1150  30n  31 n> n = 2, 3, -----
2  n  1  1 30
4d 77
 1150  n  n = 0,1,2 ----
2 n  2  1 30
n = 2 (common)
4  1 d
 400 d = 500 nm.
5
d
L  L  T T  3.1o C .
L
 = 666.67 nm
Question Stem
A heavy steel ball held in contact with an extremely light steel ball at height h
= 5 3 m above a hard horizontal floor. The line joining the centres of the balls
makes angle   30o with a vertical. If all the collisions are elastic and sizes of
the balls are negligible as compared to the height h, the horizontal range of the
lighter ball. Is R & speed Just after collision is u.
Then,
h

18. The value of R (in m) is ______
Ans. 00120.00
19. The value of u (in m/s) is _____
Ans. 00034.82
Sol. Y
LOC
 v co s  v s in 
v cos  v
Heavy
Let velocity of light ball along LOC after collision is V1

V1 – v cos   2v cos 
V1  3v cos 
2
Speed u = v12   v sin  
 9v 2 cos2   v 2 sin2 
v 2  2gh
3 1 56gh
u  9  2gh   2 g h 
4 4 4
u  14gH  34.82 m/s
3v cos 
v s in 
Find Range R = 8hsin2  4cos 2   1
3  3 
R = 85 3    4   1  120m.
2  4 
Chemistry PART – II

20. Which of the following statement(s) is correct?
(A) Most four-coordinated complexes of Ni2 ions are square planer rather than tetrahedral.
3 3
(B) The Fe  H2 O  6  ions is more paramagnetic than the Fe  CN 6  ion.
(C) Square planar complexes are more stable than octahedral complexes.
4 3
(D) The Fe  CN 6  ion is paramagnetic but Fe  CN6   ion is diamagnetic.
Ans. ABC
4
Sol. Fe  CN6  has Fe 2 and have no unpaired electron, so it is diamagnetic and
3
Fe  CN6  has Fe 3 and having one unpaired electron, so it is paramagnetic.
21. Regarding the structure of compound, PBr2Cl  CH3 2 , which of the following is incorrect
statement(s)?
(A) Both CH3 occupy axial position

(B) Both Br occupy axial position
(C) One Cl and one Br occupy axial position.
(D) One CH3 and one Br occupy axial position
Ans. ABD
Sol. Cl
H3C
P less electronegative atom occupy equatorial position.

Br CH3
Br
22. Which of the following statement(s) is correct.
(A) In metallic carbonyls the ligand CO molecule acts both as donor and acceptor.
(B) The ligand thiosulphate, S2 O32 can give rise to linkage isomerism.
(C) The complex ferricyanide does not follow effective atomic number (EAN) rule.
(D) The complex Pt Py  NH3  NO2  ClBrI exist in eight geometrical forms.
Ans. ABC
Sol. In complex Pt(Py)(NH3 )(NO2 )ClBrI , 15 geometrical isomers exist.
23. In an oxide ions are placed with FCC unit cell in which B+3 ion occupy x% of octahedral void and
A+2 ion occupy y% of tetrahedral void, then what is incorrect about the unit cell?
(A) Formula is A 3B2 O6 in which x = 50% and y = 12.5%
(B) Formula is A 2B4 O 6 in which x = 50% and y = 50%
(C) Formula is AB2 O 4 in which x = 50% and y = 12.5%
(D) Formula is AB2 O 4 in which x = 12.5% and y = 50%
Ans. ABD
Sol. A1B2 O 4 of x = 50% and y = 12.5%

A 4B2O 4 of x = 50% and y = 50%
AB2 O 4 of x = 50% and y = 12.5%
A 4B1/2 O 4 of x = 12.5% and y = 50%
24. If E0Zn2 /Zn  0.76V,ENi

0
2
/Ni
0
 0.24,EFe 3
/Fe
0
 0.04V,ECd2
/Cd
 0.40V
Which is/are correct statements
(A) Zn2  Cd  Cd2  Zn , spontaneous
(B) Ni2  Cd  Ni  Cd2 , spontaneous
(C) Fe 3  Ni  Ni2  Fe, spontaneous
(D) Cd2  Zn  Zn2  Cd, spontaneous
Ans. BCD
Sol. E0cell is (+) ve, then cell reaction is spontaneous

E0cell  E(R.P) o(R.P)
cathode  E Anode
 0.76  0.40
 0.36 (Nonspontaneous)
25. Each of the following options contains a set of four molecules. Identify the option(s) where all four
molecule possess permanent dipole moment at room temperature.
(A) BeCl2 , CO2 , BCl3 , CHCl3
(B) NO2 , NH3 , POCl3 , CH3 Cl
(C) BF3 , O3 ,SF6 , XeF6
(D) SO 2 , C6H5 Cl, H2 Se, BrF5
Ans. BD
Sol. O Cl
N N H P Cl C H
O O H H Cl Cl H H
angular Pynomidal Tetrahedral but Tetrahedral but
attached atom are attaned atom are
different different
F F
Cl
Br
S Se
O O H H F F
F
angular Angular
square pyramidal

answer.
Imagine a universe in which the four quantum numbers can have the same possible values as in our
universe except the angular momentum quantum number "  " can have integral values of 0, 1, 2, 3
…….n (instead of 0, 1, 2……….(n -1) and magnetic quantum numbers “m” can have integral values of
    1 to 0 to    1 instead of  to 0 to   .
26. Electronic configuration of the element with atomic number 25, based on the above assumption
is.
(A) 1s2 ,1p6 ,2s2 ,1d10 ,2p5
(B) 1s2 ,1p10 ,2s2 ,1d11
(C) 1s3 ,1p9 ,2s3 ,2p9 ,3s1
(D) 1s6 ,1p10 ,2s6 ,2p3
Ans. D
27. Based on above assumption magnetic moment of the element with atomic number 18 is
(A) 24 B.M.
(B) 8 B.M.
(C) Zero B.M.
(D) 15 B. M.
Ans. B
Sol. (26 – 27)

1s6 ,1p10 ,2s6 ,2p3 ,2d
 spin only  n  n  2   2  2  2   8 B.M.
A compound (x) of molecular formula C8H8O is treated with two equivalent of Br2 in ether at 0oC in
presence of a base to give a substituted product (Y) of molecular formula C8H6OBr2. Compound (Y) on
treatment with alkali followed by HCl forms -hydroxy acid (z) of molecular formula C8H8O3. (x) forms an
oxime as well as showing positive iodoform test.
28. Compound (X) is
(A) O (B) OH
HC CH C H
HC CH3
(C) O (D) O CH CH2
C CH3
Ans. C
29. Compound (z) is
(A) OH O (B) OH O
C 6H 5 CH C OH H C C OC 6 H 5
(C) O O (D) OH OH
C 6H 5 C C H C 6H 5 C C H
H H
Ans. A
Sol. (for Q. 28-29)

(X) is likely to be a methyl ketone since it form an oxime as well as shown positive iodoform test.
Further degree of unsaturation of (x) is 5. Therefore (X) would be
C 6H5 C CH3
O O H2 O
2Br2 OH
C 6 H5 C CH3 C 6H 5 C CH (OH )2 C 6H 5 C C H
C 6H 5 C C H Br2
O O O
(X) (Y)
The formed compound undergoes intramolecular Cannizaro reaction.

INTEGER.
3
30. In how many number of molecule/ions central element is sp hybridized state.
ClO 2 , I3 , IF6 , BrF6 , ICl2 , CsBrCl2 , Br  XeO6 ,  CN  2
3 2
Co  NH3 6  , Ni  CN4  , Ni  CO  4 
Ans. 3
Sol. Only in ClO 2 , ICl2 , Ni  CO  4  is sp3 hybridized.
31. A saturated solution of a sparingly soluble salt MCl2 has a vapour pressure of 31.78 mm of Hg at
30oC. While pure water exert a pressure of 31.82 mm of Hg at the same temperature. Calculate
the solubility product of the compound at this temp. is approximately x  10 5 mol3L3 . Find the
value of x.
Ans. 5
Sol. Let the solubility of MCl2 be small/lit


MCl2(s)  2 
 M(aq)  2Cl(aq)
s 2s
Using Roult’s law
P0  Ps n

P0 N
31.82  31.78 3s

31.82 1000
18
On solving s = 0.0232 mol/lit
 Ksp  4s 3
 4.9  10 5  5  10 5
32. What are the number of total plane of symmetry in a cube?
Ans. 9
Sol. Plane of symmetry
Diagonal Plane of symmetric (6) Rectangular plane of symmetric (3)
(12 edge)

Question Stem
OCH 3
Mg HBr / 
 HBr  A 
(1 eq)
 B  C(C18H22 O 2 )
(1eq) (C10H13 OBr ) (C20H26 O2 )
HC CH CH3
33. Degree unsaturation of compound A is ________.
Ans. 00004.00
34. Degree unsaturation of compound B is________.
Ans. 00008.00
Sol. (for Q. 33-34)

In the case H+ from HBr gas to the double bond making it a carbocation that can be stabilized by
delocalization
OCH 3 OCH 3 OCH 3 OH OH
(A) (B) (C)
CH CH2 CH3 CH CH CH CH
Br H 5 C2 C2 H 5 H5 C 2 C 2 H5
Question Stem
Heavy metal compound (A) with a (+2) oxidation state on the central metal on heating produces a gas
(B). The element of gas(B) forms a paramagnetic oxide (C). (A) on treatment with a chromate salt
produces yellow crystalline p.p.t (D). (B) on reaction with water procures two acids (E), (F); (F) on heating
gives (B) {Atomic weight of Pb = 207, Ba = 137}
35. Molecular weight of compound (A) is_________.
Ans. 00331.00
36. Molecular formula of (E) is HNOx, the value of x is _______.
Ans. 00002.00
Sol. (for Q. 35-36)

1 K 2 CrO4
Pb(NO3 )2  PbO  2NO2  O2 , Pb(NO3 )2   PbCrO 4
(A) (B) 2 (D)
Disproportioration
NO2  H2 O  HNO3  HNO 2reaction
(F) (E)
1
2HNO3  2NO2  H2 O  O2
(F) 2
(C) is NO
Question Stem
An organic compound undergo number of parallel reaction can give product P1, P2, P3 ……….Pn. The rate
constant of these parallel reaction are K, 2K, 3K …….. nK and activation energy for each parallel reaction
is E, 2E, 3E ……….nE respectively.
E  2n  1
37. The overall activation energy of reaction is given by . The value of x is_______.
x
Ans. 00003.00
38. A reaction follow two parallel path have activation energies 100 and 200 kJ/mol respectively. Rate
constant of these parallel path are respectively 2  102 & 3  102 min1 . The overall activation
energy reaction in (kJ) is_____.
Ans. 00160.00
Sol. (for Q. 37-38)

P1
E
K,
2K, 2E
A 3K, 3 P2
E
nK, n
P3
E
Pn
Let rate cont. K 0  K  2K  3K  ........nE

E
 0
RT
K 0  Ae
E
dK 0  0  E 
 Ae RT  0 2 
dT  RT 
dK 0 E0
 K0
dT RT 2
1 dK 0 E
 02
K 0 dT RT
1  d E
 K  2K  3K  ........nK   02
K 0  dT  RT
1  K.E 2K.2K 3K.3E nk.nE  E0
K0  RT 2  RT 2  RT 2  ......... RT 2   RT 2
 
K.E 2 E
1  22  32  ...........n2   0 2
RT 2  RT
K.E     1
n n  1 2n
 E0
K 1  2  3  .....n  6
n  n  1  2n  1
 E0
n  n  1 6
2
 2n  1
E0  E
3
Overall activation anergy of two parallel path is given by
K E  K 2 E2
E 1 1
K1  K 2
E
100  2  10 2
 200  3  102 
2 2
2  10  3  10
800  102

5  102
 160
Mathematics PART – III

39. If D1, D2, D3,……...D1000 are 1000 doors and P1,P2P3 ............P1000 are 1000 persons. Initially all
doors are closed. Changing the status of doors means closing the door if it is open or opening it if
it is closed. P1 changes the status of all doors. Then P2 change s the status of D2, D4, D6,........
D1000 (Doors having number which are multiples of 2). Then P3 changes the status of D3, D6, D9 .
.......D999 (doors having number which are multiples of 3) and this process is continued till
P1000 changes the status to D1000, then the doors which are finally open is/are
(A) D961
(B) D269
(C) D413
(D) D729
Ans. AD
Sol. Dm will be open finally if m is the perfect square
40. f(x) = cos( |x| +[x] ), then
(A) f is continuous at x = 1/2
(B) f is continuous at x = 0
(C) f is differentiable in ( -1, 0)
(D) f is differentiable in (0, 1) .
Ans. ACD
Sol. f(x) = cos( |x| +[x])

f(0) =1, f(0 – 0) = cos( -1) = –1
 1 1   1
f(1/2) = cos   = 0 , f   0   cos    = 0,
 2 2  2
1  
f   0   cos  0
 2  2
for x  (0, 1) f(x) = cosx
for x  (-1, 0) f(x) = cos ( -x- 1) = - cos x .
41. If z1,z2 ,z3 ,z4 are complex numbers in an Argand plane satisfying z1  z3  z2  z4 . A complex
 z  z2   z3  z2 
number ‘z’ lies on the line joining z1and z4 such that Arg    Arg   . It is given that
 z1  z2   z  z2 
z  z4  5, z  z 2  z  z 3  6 then
(A) area of the triangle formed by z,z1z2 is 3 7 sq. units
15 7
(B) area of triangle formed by z,z3 ,z 4 is sq. units
4
27 7
(C) area of the quadrilateral formed by the points z1,z2 ,z3 ,z4 taken is order is sq. units
2
47 7
(D) area of the quadrilateral formed by the points z1,z2 ,z3 ,z4 taken is order is sq. units
3
Ans. ABC
42. Which of the following is/are correct?
(A) If A is a n  n matrix such that aij   i2  j2  5ij    j  i  I and j then trace  A   0
(B) If A is a n  n matrix such that aij   i2  j2  5ij    j  i  I and j then trace  A   0
(C) If P is a 3  3 orthogonal matrix, , ,  are the angle made by a straight line with OX, OY,
 sin2  sin   sin  sin   sin  
 
OZ and A   sin   sin  sin2  sin   sin   and Q  PT AP, then PQ6P T  32A
 sin   sin  sin   sin  sin2  

(D) Id matrix A  aij  33 and matrix B  bij  33 where aij  a ji  0 and bij  b ji  0  i and j
then A 6B7 is a singular matrix
Ans. ACD
Sol. (A) aij  a ji  aij  a ji  0  A is skew symmetric matrix

(B) A 2  2A  A 3  22 A  A 6  25 A
(D) A 6B7 is a skew symmetric matrix of odd order
43. If three normals can be drawn from the point (h, 0) to the parabola y 2  4x , then h can be
(A) any real number in the interval  , 3 
(B) any real number in the interval  4, 3 
(C) any real number in the interval ( , 4)
(D) any real number
Ans. ABC
Sol. (h, 0) satisfy the equation of the normal y  mx  2am  am3
dy x 2  y 2  1
44. The solution of  satisfying y(1) = 1 is given by :
dx 2xy
(A) a system of hyperbola

(B) a system of circles
(C) y2 = x(1 + x) – 1
2 2
(D) (x – 2) + (y – 3) = 5
Ans. AC
Sol. Put y2 = u
du u 1
We get  =  x , which is in linear form.
dx x x

answer.
Let y = f(x) is a curve and P(x, y) be any point on it. The tangent and the normal drawn at P meets x-axis
at T and N respectively PT and PN are called length of tangent and length of normal at P. If M is the foot
of perpendicular drawn from P on x-axis, then MT and MN are called length of sub-tangent and length of
sub-normal at P. Answer the following questions.
45. The equation of the curves passing through (0, 1), if the length of sub-normal at any point of the
curve remains unity is
(A) y2 =  x + 1
x
(B) y2 =  1
2
(C) y2 =  2 x + 1
(D) y2 =  3x + 1
Ans. C
dy
Sol. y  1  y2 = 2x + 1
dx
46. The equation of the curve passing through (1, 2), if the intercepts of normal on x-axis is equal to
thrice of the abscissa of point P is
(A) 3x2 – y2 + 1 = 0
(B) x2 – 2y2 + 7 = 0
2 2
(C) 2x – y + 2 = 0
(D) x 2 – y2 + 3 = 0
Ans. C
dy 2 2
Sol. x+y = 3x; solving we get 2x – y + 2 = 0.
dx

1
m 1
If m  0, n  0, the definite integral I =
x (1  x)n1 dx depends upon the values of m and n and is
0
denoted by  (m, n), called the beta function.
1 1
e.g.  x 4 (1  x)5 dx  x
5 1
(1  x)6 1 dx   (5, 6) and
0 0
1 1
5/2  7 1
x (1  x)1/ 2 dx  x
7 / 2 1
(1  x)1/ 2 1 dx    ,  . Obviously,  (n, m) =  (m, n).
0 0
2 2
/2
2m
47. The integral
 cos  sin2n  d is equal to
0
1  1 1
(A)  m , n 
2  2 2
(B) 2 (2m, 2n)
(C)  (2m + 1, 2n + 1)
(D) None of these
Ans. A
Sol. Writing sin2  = x, we get 2 sin  cos  d = dx, and hence the given integral is equal to
/2
1 2m 1
 cos sin2n 1  (2 sin  cos ) d
2
0
1 2m 1 2n 1 1
1 1 m 1/ 2 n 1/ 2 1  1 1
  cos    sin  
2 2
=
2
0
2 2 dx 
2  1  x 
0
x dx   m  , n   .
2  2 2
 
x m 1 x n1
48. If  (1  x)
0
mn
dx  k  (1  x)
0
m n
dx , then k is equal to
m
(A)
n
(B) 1
n
(C)
m
(D) None of these
Ans. B
x z 1 dz
Sol. Writing  z, we get x = ,1+x= and dx = .
1 x 1 z 1 z (1  z)2
1 1
zm 1 dz
L.H.S. =  (1  z) m 1
1  z m n 2
 z
m 1
(1  z)n1 dz =  (m, n)
0
(1  z) 0
 n 1
x
=  (1  x)
0
m n
dx .

INTEGER.
49. If the least value of the area bounded by the line y = mx +1 and the parabola y  x 2  2x  3 is 
6
where m is a parameter then the value of is ________
32
Ans. 2
Sol. A    y1  y 2  dx where ,  are the


roots of x 2  2x  3  mx  1, on solving we will get
 ,0 
,0 
1 2 3/2 32
6

m  4m  20  : Hence  
3
6
 2
32
2 2 2 1
50. The shortest distance between 1  x    x  y    y  z   z 2  and 4x+2y+4z+7=0 in 3 -
4
dimensional coordinates system is equal to _________
Ans. 2
Sol. Let a  1  x
b xy
c  yz
dz
1
then a+b+c+d=1 and a2  b2  c 2  d2 
4
2 2 2 2 2 2
  a  b    a  c    a  d  b  c   b  d   c  d  0
abcd
3 1 1
x  , y  ,z 
4 2 4
 3 1 1
So the distance from the point  , , 
4 2 4
3  1 1 7
From the plane 4x  2y  4z  7  0 is 2
6
51. The equation of the plane passing through the intersection of the planes 2x  5y  z  3 and
x  y  4z  5 and parallel to the plane x  3y  6z  1 is x+3y+6z=k, where k is
Ans. 7
Sol. Equation of plane passing through the intersection of the planes 2x  5y  z  3 and x+y+4z=5 is
 2x  5y  z  3     x  y  4z  5   0
  2    x   5    y  1  4   3  5  0 .... i 
Which is parallel to the plane x  3y  6z  1.
2   5   1  4
Then  
1 3 6
2   5   1  4
Then,  
1 3 6
11
 
2
from eq. (i)
7 21 49
   y  21z  0
2 2 2
 x  3y  6z  7
Hence, k = 7


Question Stem
Experiment -1: Let ‘S’ be the sample space obtained when two different coloured unbiased coins are
tossed. Two subsets P and Q (of two elements each) are randomly chosen from S one after another with
replacement.
Element obtained in P and Q are recorded.
Experiment -2: The same two coins used in the previous experiment are tossed. The outcomes are
recorded.
If the outcomes obtained in experiment 2 matches with nay of the outcomes of experiment 1, then both
the experiments are declared ‘successful’.
(Note that experiment ‘2’ is conducted after experiment 1)
52. Probability that ‘success’ is from ‘P’ but not from ‘Q’
Ans. 00000.25
Sol. Case  1: n P  Q   0
Let SP denote ‘success’ from P, then
4
1  E1  1 C2

P SP  SQ   P   

  .
 n  P  Q   0  2  C2 
2
2 4
Case  2 : n P  Q   1  n P  Q   3
1  E1  1 4 C3 3 C1  2

P SP  SQ   4
P  
 n P  Q   1  4 2
.
 
4
C2  
Case  3 : n P  Q   2

P SP  SQ  0 
P S P  SQ   122  121  41 .
53. Probability that there is no ‘success’ if experiment 1 is conducted after experiment 2
Ans. 00000.25
Sol. Case  2 : n P  Q   0
 n P  Q   4

 P SP  SQ  0 
Case  2 : n P  Q   1  n P  Q   3
3
C1  2 1

P SP  SQ   2

6
.
 4
C2 
Case  3 : n P  Q   2  n P  Q   2
3
C2 1

P SP  S Q   2

12
.
 4
C2 
2 1 1

P SP  SQ     .
12 12 4

Question Stem
 
Let r is a position vector of a variable point in Cartesian OXY plane such that r  10ˆj  8iˆ  rˆ  40 and  
2 2
      8
p1  max  r  2iˆ  3ˆj  ,p2  min  r  2iˆ  3ˆj  . A tangent line is drawn to the curve y  2 at the point A
    x
with abscissa 2. The drawn line cuts x-axis at a point B.
54. p2 is equal to
Ans. 00003.40
 2
Sol. p2  min r  2i  3j


where r  10ˆj  8iˆ  rˆ  40 

take r  xiˆ  yjˆ
 xiˆ  yjˆ   10  y  ˆj  8  x  ˆi 
 x  8  x   y 10  y   40
x 2  y 2  8x  10y  40  0
2 2
 x  4   y  5  1 (i)
2
xiˆ  yjˆ  2iˆ  3ˆj
2
  x  2  ˆi   y  3  ˆj
2 2 2
  x  2    y  3   minimum distance of  x, y  from  2,3  
C
(-4,5)
Q
(-2,3)
P
2
= PQ 
2
= PC  1
2

= 2 2 1 
=8+1-4 2  9  4 2
 
55. AB OB is
Ans. 00003.00
Question Stem
Let   0 and  C denotes the determinant of cofactors, then  C   n 1, where n (>0) is the order of  .
56. If a, b, c are the roots of the equation x 3  px 2  r  0, then the value of

bc  a 2 ca  b2 ab  c 2
ca  b2 ab  c 2 bc  a2 is (if p = 0.9)
ab  c 2 bc  a2 ca  b2
Ans. 00000.53
2
Sol.  a  b  c  p,ab  bc  ca  0,  a2  b2  c 2   a  b  c   2  ab  bc  ca   p2
a b c bc  a2 ca  b2 ab  c 2
If = b c a then  C  ca  b2 ab  c 2 bc  a2   3 1   2
c a b ab  c 2 bc  a2 ca  b2
2
a b c a b c a b c
 C  b c a  b c a b c a
c a b c a b c a b
a2  b2  c 2 ab  bc  ca ab  bc  ca p2 0 0
2 2 2
 ab  bc  ca a  b  c ab  bc  ca  0 p2 0
ab  bc  ca ab  bc  ca a2  b2  c 2 0 0 p2
57. If a, b, c are the roots of the equation x 3  3x 2  3x  7  0, then the value of

2bc  a2 c2 b2
c2 2ac  b2 a2 is
2 2 2
b a 2ab  c
Ans. 00000.00
3
Sol.  x  1  8  x  1  2, 2, 22
 x  1,1  2,1  22
 a  1,b  1  2,c  1  22
a b c2 a b c a c b 2bc  a2 c2 b2
 b c c  b c a b a c  c2 2ac  b2 a2
c a b c a b c b a b2 a2 2ab  c 2

Aits FT-3 Jee Adv Paper-2 18.01.2022 Solution+qp

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Aits FT-3 Jee Adv Paper-2 18.01.2022 Solution+qp

Uploaded by

Copyright:

Available Formats

FIITJEE

ALL INDIA TEST SERIES

Section – A (Maximum Marks: 24)

1. A wire having a uniform linear charge density  , is bent in the form of a a1

(C) The element a1 and a2 produce same potential at A.

(D) The elements a1 produces greater potential at A than element a2.

Sol. dq1 = a1

(A) QA < QB <QC <QD

(B) QD < QB < QC < QA

(C) Charge on the particle B and particle D is of different nature

Sol. Due to psuedo force, electrons move from B to A.

4. There is a spherical glass ball of refractive index 1 and

Sol. 1 sinr1  sini1

5. A bead is fixed on a rigid ring of radius r and of mass that

(B) The speed of centre of the ring before it begins to slide  gR

  

Sol. For piston to be in equilibrium

Section – A (Maximum Marks: 12)

Paragraph for Question Nos. 07 and 08

7. In How much time, will the Bead descend a Height H?

(D) None of these

mgR h2  42R2  162H2

mgR h2  2R 2  42H2

(D) None of these

Paragraph for Question Nos. 09 and 10

9. Net force exerted by liquid on the Styrofoam is:

(A) 2 gl2L

(B) 2 gl2L

Section – B (Maximum Marks: 12)

Sol. In first case

  

13. A pendulum with massless string of length l and bob of mass m is

Sol. Acceleration of train = a 

Section – C (Maximum Marks: 12)

Question Stem for Question Nos. 14 and 15

14. Then the value of H1 is ___________

15. Then the value of H2 is ___________

Question Stem for Question Nos. 16 and 17

16. The value of  (in nm) ______

17. The value of T (in o C) ______

Sol. 2d   2n  1  / 2 for constructive interference

Question Stem for Question Nos. 18 and 19

18. The value of R (in m) is ______

19. The value of u (in m/s) is _____

Let velocity of light ball along LOC after collision is V1

Section – A (Maximum Marks: 24)

20. Which of the following statement(s) is correct?

(A) Both CH3 occupy axial position

P less electronegative atom occupy equatorial position.

22. Which of the following statement(s) is correct.

Sol. In complex Pt(Py)(NH3 )(NO2 )ClBrI , 15 geometrical isomers exist.

(A) Formula is A 3B2 O6 in which x = 50% and y = 12.5%

(B) Formula is A 2B4 O 6 in which x = 50% and y = 50%

(C) Formula is AB2 O 4 in which x = 50% and y = 12.5%

(D) Formula is AB2 O 4 in which x = 12.5% and y = 50%

Sol. A1B2 O 4 of x = 50% and y = 12.5%

24. If E0Zn2 /Zn  0.76V,ENi

(A) Zn2  Cd  Cd2  Zn , spontaneous

(B) Ni2  Cd  Ni  Cd2 , spontaneous

(C) Fe 3  Ni  Ni2  Fe, spontaneous

(D) Cd2  Zn  Zn2  Cd, spontaneous

Sol. E0cell is (+) ve, then cell reaction is spontaneous