Aits 2122 Ot I Jeea Paper 1 PDF

ALL INDIA TEST SERIES
JEE (Advanced)-2022
OPEN TEST – I
PAPER –1
TEST DATE: 23-01-2022
Time Allotted: 3 Hours Maximum Marks: 180
General Instructions:
 The test consists of total 57 questions.
 Each subject (PCM) has 19 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Three Sections: Section-A, Section-B & Section-C.
Section – A (01 – 04, 20 – 23, 39 – 42): This section contains TWELVE (12) questions. Each question has
FOUR options. ONLY ONE of these four options is the correct answer.
Section – A (05 –10, 24 – 29, 43 – 48): This section contains EIGHTEEN (18) questions. Each question has
FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Section – B (11 – 13, 30 – 32, 49 – 51): This section contains NINE (09) questions. The answer to each
question is a NON-NEGATIVE INTEGER.
Section – C (14 – 19, 33 – 38, 52 – 57): This section contains NINE (09) question stems. There are TWO
(02) questions corresponding to each question stem. The answer to each question is a NUMERICAL
VALUE. If the numerical value has more than two decimal places, truncate/round-off the value to TWO
decimal places.
MARKING SCHEME
Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
Section – C: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-OT-I (Paper-1)-PCM-JEE(Advanced)/22 2
Physics PART – I
Section – A (Maximum Marks: 12)

This section contains FOUR (04) questions. Each question has FOUR options. ONLY ONE of these four
options is the correct answer.
1. In the shown figure, a plank P of mass 25 kg 1m 3m

is placed over a cylinder C of mass 10 kg.
P A
The cylinder is placed over a block B of mass
5 kg. All the surfaces are rough and
coefficeint of friction between all the surfaces
is  = 0.3. What is the minimum horizontal C
force F needed to pull the block. Plank is
hinged at A so that it is free to move in F
vertical plane without friction. B
(A) 120 N
(B) 95 N
(C) 15 N
(D) 175 N
Ans. B
Sol.
N1
1m
3m
C
P
F
B
25g 2m
N2 N1
15g
N2
50 3N1  2  25g
N2  15g  g
3 50g
 N1 
F  N2  95N 3
2. A cube of side length 1 m and mass 10 kg is placed on 2 kg

a smooth horizontal surface. A small block of mass 2 kg
and negligible size is placed on the front corner of the
cube. Coefficient of friction between the cube and the
block is  = 0.2. The cube is pulled with a constant 10 kg
horizontal force F = 36 N. The kinetic energy of the
F = 36 N
block just before it reaches the ground is
3 AITS-OT-I (Paper-1)-PCM-JEE(Advanced)/22
90
(A) J
3
80
(B) J
3
20
(C) J
3
7.2
(D) J
3
Ans. B
36  0.2  2g
Sol. aC   3.2 m/s2
10
0.2  2g
aB   2 m/s2
2
 relative acceleration ar  3.2  2  1.2 m/s2
1 2 2
r  ar t1  t1 
2 1.2
For block vx = 2t1
1 1
Also for vertical motion 1   10t 22  t 2 
2 5
vy=10t2, KE=m(vx2+vy2)/2
3. In the shown figure two uniformly charged rings A and B of B

radius R and R 3 having charges Q1 and Q2 respectively are Q2
concentric with center C and coplanar. A point P is on the axis A
of the rings at a distance CP = R. At point P electric field is R3
Q1 R
zero. The ratio is
Q2 C P
Q1
(A) 2
1
(B)
3
1
(C)
2 2
(D) 3
Ans. C
kQ1R kQ2R
Sol. E  0
   
3 3
R2  R2 R2  3R2
Q1 1
 
Q2 2 2
4. An insulating long cylinder is uniformly charged on its lateral surface

with surface charge density . On its flat surface, a circular and
conducting loop of radius r is placed coaxially as shown in the figure.
There is no friction between the cylinder and the loop. The cylinder is
being rotated with a uniform angular acceleration  about its axis. The
relationship between the compressive force F in the loop and time t
and surface charge density is best represented by
(A) F (B) F
time time
(C) F (D) F
Surface Radius of
charge loop
density ()
Ans. B
Sol. Let Rs is resistance of the loop

Field through loop B = (0R)/2 = (0Rt)/2
Induced emf in the loop e = (r20R)/2
e r 20 R
Current in the loop i  
Rs 2Rs
r 2 0 R
F = iBr = 0 Rtr
4Rs
 2 2 2R2r 3 
F 0 t
 4Rs 
 

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MOER THAN ONE of these four option(s) is (are) correct answer(s).
5. A cube of mass m and side length 4R has a groove made inside

it in a vertical plane. The groove is a circle having radius R. A
particle of mass m is moving down with a velocity v  2gR .
R
Assume all surfaces are smooth. The correct statement(s) at this
instant.
(A) Normal reaction on particle is mg

(B) Normal reaction on cube by the ground is mg
(C) Acceleration of block w.r.t ground is g
(D) Acceleration of particle with respect to ground is g 2
Ans. A, B, C, D
Sol. N2  mg = 0
 N2 = mg
N1 = ma
R
 v2  N1
N1 + ma = m  
R
 
N1 + ma = m2g a
 N1 = mg
and a = g
N2
mg
F.B.D. of cube
  
aP,g  aP,C  aC,g
N1 ma
g
 = g 2 v2
ar 
R
g
v
F.B.D. of particle w.r.t.

cube
6. A black body at temperature T = 400 K is emitting radiations at rate 200 W/m2. Another body of
surface area 2 m2 coefficeint of reflectivity (r) = 0.3 and zero coefficeint of transmission is at
temperature 800 K. The correct statement(s) about the another body is
(A) Emissive power is 2240 W/m2

(B) Power emitted is 2240 W
(C) Power emitted is 4480 W
(D) emissivity is 0.7
Ans. A, C, D
Sol. 200 = .1.(400)4 …(i)

Power emitted by the other body
P    0.7  2  (800)4 …(ii)
P
  0.7  2  24
200
 P = 200  0.7  2  24
7. A thin cube of side length  = 1m is heated with the help of

electric heater which maintains inner temperature of cube
at 100C. The outer surface of cube emits 500 W power
and absorbs 100 W radiation incident over it in steady
state. After heater is switched off, it cools down according
to Newton’s law of cooling. When its temperature becomes
40C at outer surface, it emits 300Watt power. Temperature
of surrounding is constant at 0C.

(A) Power of heater is 500 W
(B) Temperature of the outer surface is steady state 53.3C
(C) Temperature of outer surface in steady state 80C
(D) Power of heater is 400 W
Ans. C, D
Sol. Power given = power loss

P = 500  100 = 400 W
dQ
 k(T  0)
dt
400 = k (T0) …(i)
Also 300  100 = k(40 0) …(ii)
 T = 80C
8. Capacitor of capacitance C = 10 F was connected with a  = 10 V

soruce of emf  = 10V for long time. At time t = 0 switch S is
shifted from point A to B, which connects a solenoid of self
1
inductance L = 10H length  = m , and number of turns 10000. A C = 10 F
2 S
A charge particle of charge q = 10 C, mass 1106 kg is
B t=0
10
released from rest on the axis of solenoid at time t = ms. At
3
this instant
L = 10 H
(A) acceleration of the charged particle is zero
(B) acceleration of the charged particle is 100 m/s 2
(C) magnetic field inside the solenoid is nearly 700 mT
(D) magnetic field inside the solenoid is nearly 218 T
Ans. B, D
Sol. V = 0 cos t is voltage across capacitor

10
 103
t 3 
t   
LC 10  10  10  6 3

 V  0 cos  
3
10
 V  5 Volt
2
V
Field E   10 V/m

qE 10  10 6  10
a   100 m/s2
m 1 106
2
1 2 1  0  1
C0  C    LI2
2 2  2  2
 I  8.7  10 3 A
B = 0nI
= 4  107  20000  8.7  103 = 218  106 T
9. In the shown figure, two parallel rails in a vertical plane            

of negligible resistance are connected by a resistance R            
= 1 at one end. A uniform horizontal magnetic field is            
present (B = 0.5 T). A thin ring of mass m1 = 1kg, radius            
r = 25 cm is fitted over a wooden disc of mass m2 = 1kg. 1 F = 2N
           
Resistance of ring is R = 4 and there is no friction            
between the ring and the disc, ring and upper rail. r=25cm
           
Friction between ring and lower rail is sufficient to            
support pure rolling of the ring. Horizontal force F = 2N is
     B= 0.5T
     
applied at centre of the disc. When the terminal velocity
is reached
(A) Terminal velocity of disc is 64 m/s
(B) Terminal velocity of disc is 96 m/s
(C) Current flowing in the rails is 8 2 A
(D) Current flowing in the rails is 8 A
Ans. A, D
Sol. at v  v 
Power given =power loss

 4
Fv   I2  1   …(i)
 4
Bv  (2r)
I …(ii)
 4
1  4 
 
By solving v = 64 m/s
and I = 8A
10. A conducting wire of mass m is pulled with a uniform x

velocity v0 on two parallel rails lying in horizontal
           
plane and separated by distance . Ends of rails is
           
connected by a coil of self inductance L. At time t = 0,  L          
x = x0(0) and uniform vertical magnetic field B is         F   
present in space. When the conducting wire is at            
distance x from the initial position.            
           
       B
    
           
(A) Force F is directly proportional to x
(B) Force F is directly proportional to x2
(C) Energy stored in coil is directly proportional to x
(D) Energy stored in coil is directly proportional to x2
Ans. A, D
dI dx
Sol. L  B
dt dt
I x
B
 
0
dI 
L 
dx
0
B
I x
L
1
U  LI2  U  x 2
2
F = IB
B2  2
F x
L
Fx
Section – B (Maximum Marks: 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER.
11. Two converging lenses L1 and L2 of focal f1 = 20 cm

lengths f1 = 20 cm and f2 = 30 cm respectively f3 = 30 cm
are placed such that their principal axes
coincide. An object is first placed at a distance L1 L2
25 cm from lens L1. Object is oscillating along
principal axis with amplitude 5 cm. Find the ratio
of maximum to minimum magnification of its A
image.
20 cm 50 cm
Ans. 1
Sol. Magnification is independent of object distance from lens L1.

Since separation between lenses d = f1 + f2
12. Two blocks of equal masses are placed one over the other as shown in the figures. Friction
between all the contact surfaces is  = 0.8. Minimum values of the forces required to pull the
blocks are F1 and F2 respectively. Force F1 is horizontal and F2 is parallel to the inclined plane.
F
Find the ratio 1 .
F2
m
m
F1
m
Figure-A m
F2
60
Figure-B
Ans. 2
Sol. F = T + 2mg + mg

And T = mg
 F1 = 4 mg
F2 + mg sin 60 = T + 3mg cos 60
FT = mg sin 60 + mg cos 60
 F2 = 4mg cos60
F1 1
 2
F2 cos 60
13. In the shown circuit all the sources of emf are ideal. I1 5 2V 5V
Current through 5 resistance is I1 and thorugh 10 
I 
resistance is I2. Find the ratio  1  . 20
 I2  3V
5V 15
20
10
I2
5V 5V
10V
Ans. 4
Sol. Using Kirchoff’s law

3  5I1  2  5  10  0  I1  4 A
and 5  10I2  5  10  0  I2  1 A
I1
 =4
I2
Section – C (Maximum Marks: 12)

This section contains THREE (03) question stems. There are TWO (02) questions corresponding to each
question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places.
Question Stem for Question Nos. 14 and 15
Question Stem
A block of ice at 0C and mass M is kept inside isolated container of negligible heat capacity. Steam of
mass m at temperature 100C is kept inside the container. The ice melted and its tempeature becomes
20C. The steam of mass 0.2 kg at 100C is again let inside the container, due to which temperature
inside the container becomes 30C in steady state. Latent heat of ice and steam are 80 kcal/kg and 540
kcal/kg respectively. Specific heat capacity of water is Sw = 1 kcal/kg-C.
14. The value of m (in kg) is ………..
Ans. 1.69
15. The value of M (in kg) is ………..
Ans. 10.48
Sol. (for Q.14-15)

Using conservation of energy
(m  540) + m  1  (100 20) = (M  80) + M  1  (20  0)
 M = 6.2 m …(i)
(0.2  540) + 0.2  1  (100  30) = (M + m)  1  (30  20)
 M +m = 12.2
Solving equations
m = 1.69 kg
M = 10.48 kg
Question Stem
An insulating cylinder of volume 20 liter is divided into two equal

parts by a movable piston made of insulating material. Monoatomic
ideal gas is filled at temperature 300 K and pressure 105 N/m2 in
each part. Left part is given heat Q joule by using an electric heater
such that temperature in the right part becomes (300 + 2)K and in
3/2
 300 
the left part becomes (300 + T)K. (Take    0.99 )
 302 
16. The value of T is …………..
Ans. 8.10
17. The value of Q is …………..
Ans. 50.50
Sol. (for Q. 16-17)

In right part using adiabatic equation
300  102/3  (300  2) V22/3
 V2  9.9 liter
Pressure is same in left part also temperature in left part T2
Volume in left part V2  20  9.9  10.1 liter
 10.1 302 
T2     308.10 ,
 9.9 
By solving T2  308.10
 T = 308.10  300 = 8.10
Q = nCv T1  nCv T2
nCv ( T1  T2 )
P1V1 3 3 P1V1
 R( T1  T2 )  ( T1  T2 )
RT1 2 2 T1
3 105  (10  10 3 )
  (2  8.10)  50.50 J
2 300

Question Stem
A converging lens of power P1 = +5D and a concave mirror of

power P2 = +16D are placed at a separation 80 cm such that their
principal axis coincide. A point object is placed left side of the lens
on its principal axes at a distance X1 from the lens such that image
of the object coincides with the object itself. When the mirror is
further shifted right side by a distance X2, the image of the object O
further coincides with the object.
18. The value of X1(in cm) is ……………
Ans. 26.67
19. The value of X2(in cm) is ………..
Ans. 12.50
Sol. (for Q.18-19)

1 1 1 80 cm
  x1
80  x1 20
1 1 1
   x1 = 26.67 cm
x1 20 80
O
f1 = 20 cm
x2 = R = 12.50 cm x1 80 cm x2 = R
f1 = 20 cm
Chemistry PART – II

20. The correct relation between the following compounds is:

CH3
Cl H HO H
C C C and C C C
H CH3 H Cl
HO
(A) Enantiomers
(B) Diastereomers
(C) Homomers (identical)
(D) Constitutional isomers
Ans. C
Sol. Since, the absolute configuration about the chiral carbon is (S) in each compound. Also,
configuration of Cl and H about double bond carbon is also same in each compound. So, both
compounds are identical.
21. The correct order of the rate constants for the following series of reactions  Z  CF3 ,CH3 ,OCH3  :
Br N
NO2 NO2
 
N
Z H Z
(A) CF3  CH3  OCH3
(B) CF3  OCH3  CH3
(C) OCH3  CF3  CH3
(D) CH3  OCH3  CF3
Ans. A
Sol. Rate of ArSN 2  magnitude of positive charge on   carbon atom.
CF CH OCH
3
 3 3
Decreasing electron withdrawing nature and hence decreasing rate of ArSN 2 .
22. The left half-cell of the electrochemical cell consists of an iron electrode (in excess) that is
oxidized during the action and an aqueous solution of iron (III) nitrate. The right half-cell consists
of graphite electrode and a mixture of iron (II) and (III) nitrates. Using the information on ion
 
mobility o , select the most suitable ionic compound (s) for the salt bridge:
Cation o ,m2 V 1 s1.109 , 25o C Anion o ,m2 V 1 s1.109 , 25o C

Ca2aq 61.6 Faq 51.5

K aq 73.5 CO32   aq  70.3
NH4  aq 76.1 NO3  aq  74.1
Haq 205 Br   aq  81.8
(A) Calcium carbonate
(B) Ammonium nitrate
(C) Potassium carbonate
(D) Ammonium bromide
Ans. B
Sol. For the salt bridges, the most advantageous is to use salts in which the cation and the anion have
the same mobility which assure the absence of so called diffusion potential in the half-cell
boundary. Thus, the most suitable salts are KNO3 and NH4NO3 .
23. 50 mL of 0.10 M HX has been mixed with 100 mL of 0.05 M NaOH, then the concentration of the
conjugate base of HX in the resultant solution can’t be
(A) 0.032 M
(B) 0.028 M
(C) 0.036 M
(D) Both (A) and (B)
Ans. C
Sol. If HX is a strong acid then maximum concentration of conjugate base is 0.033 M. Therefore, any
value higher than this is not possible.

24. Which systematic diagram represents the “INCORRECT” chemical relations between iron and its
compounds?
(A) Fe Conc. HCl

  FeCl2
Ag HCl
Fe2  SO4 3
Conc. H SO

2 4
 FeCl3
(B) Fe HCl gas

  FeCl2

Cl2 / 
Mg
Fe2  SO4 3
Conc. H SO

2 4
 FeCl3
(C) Fe HCl gas

  FeCl2

Air / 
Cu
Fe2  SO4 3
dil. H SO

2 4
 FeCl3
(D) Fe HCl gas

  FeCl3

Air / 
Mg
Fe2  SO4 3
Conc. H SO

2 4
 FeCl2
Ans. A, C, D
Sol. Iron reacts with dry HCl gas to give FeCl2 . FeCl2 on heating with chlorine gas (dry) oxidises to
FeCl3 . Conc. H2SO4 being less volatile substitute more volatile HCl from FeCl3 , converting
FeCl3 into Fe2  SO 4 3 . Mg being more electropositive than iron reduces Fe2  SO 4 3 into Fe.
25. The major product in the following reaction is (X).
i NBS/H O
 2
 ii K 2 CO3  aq  X
 iii BF3 .Et 2O
Identify the correct statement(s) about (X):
(A) ‘X’ gives positive Brady’s test

(B) ‘X’ gives positive Bromine-water test
(C) ‘X’ on reduction with N2H4 / KOH / , gives a bicyclic compound
(D) ‘X’ is a bicyclic compound and both rings in ‘X’ are of same size
Ans. A, C, D
Sol. Br
   2 3 
ii K CO aq
i NBS/H O

2
  O
OH
BF3 .Et 2 O
N2H4 , KOH

 X

26. On adding potassium iodide to an aqueous solution containing complex ion  Ag NH3 2  , yellow
coloured precipitate of AgI is formed. Similarly, when hydroiodic acid was added to the complex

ion,  Ag NH3 2  again yellow precipitate of AgI is formed. The correct statement(s) for these
observations is/are:

(A)  Ag NH3   is less stable than AgI.
 2

(B)  Ag NH3   ionizes less than AgI.
 2
(C) HI neutralizes NH3 ligands and precipitates AgI.

(D) IUPAC name of  Ag NH3 2  is “Diamminesilver (I) ion”.
Ans. A, C, D

Sol. AgI is more stable than  Ag NH3 2  . HI neutralises NH3 for ming NH4 ion, thus it cannot act as
ligand.
27. Which of the following statement(s) is/are correct?
(A) Cu2  salts form soluble complex with excess KCN.
(B) Cu2  salts form soluble complex with aqueous ammonia.
(C) Cu2  salts form soluble complex with KI.
(D) A piece of iron or zinc when placed in Cu2  salts solution, precipitates copper.
Ans. A, B, D
Sol. (A) 2Cu2  10KCN  2K 3 Cu  CN4    CN2  4K 

soluble complex
(B) 2
Cu2   4NH3  aq   Cu NH3 4 
 soluble blue complex 
(C) 2Cu 2
 4KI  2CuI   I2  4K 
ppt.
(D) In electrochemical series, Fe and Zn both are above Cu. So, both Fe and Zn can displace
Cu2  from its salt into Cu.
28. The apparatus shown was used to investigate the electrolysis of aqueous sodium sulphate
solution to which a few drops of universal indicator solution had been added. The solution was
initially pale green in colour. Colour of universal indicator at different pH values is given below:
pH range Colour
<3 Red
3–6 Orange-yellow
7 Green
8 – 11 Blue
> 11 Violet
Electrode (B)
Electrode (A)
Na2SO4 (aq) solution
Now, select the correct statement(s) among the following:
(A) Current conducted through the electrolyte is due to the movement of ions.
(B) Oxidation occurs at electrode ‘B’.
(C) When a current was passed through the electrolyte for 15 minutes, 8.5 cm3 of gas was
collected above the positive electrode, then the volume of the gas collected above the
negative electrode at same pressure and temperature and in the same duration is
25 cm3 .
(D) Blue colour appears near the electrode ‘A’.
Ans. A, B, D
Sol. Milli-equivalent of H2 gas produced at cathode are same as milli-equivalents of O2 produced at

anode. As the solution around electrode ‘A’ is slightly basic, colour changes to blue.
29. The graph below shows the change in the mass as copper (II) sulphate pentahydrate
 CuSO4 .5H2O  when heated. Decomposition takes place where the gradient is steepest leaving
various decomposition products indicated by ‘A’ to ‘E’ in the diagram shown below: (Atomic mass:
Cu = 63.5 u, S = 32 u, O = 16 u, H = 1 u)
10
A
20
B
30
C
40
50
Percentage mass loss
60
D
70
E
80
90
100
200oC 400oC 600oC 800oC 1000oC
Temperature (oC)
Select the correct statement (s) among the following:
(A) Conversion of (D) to (E) is a redox reaction with n-factor of one of the product as 4.
(B) (C) is a white compound.
(C) Ratio of oxygen atoms per formula unit in (A) to (B) is 3.
(D) Copper (II) sulphate decomposes above 800o C .
Ans. A, B, D
Sol. From the graph, it can be concluded that

A  CuSO4 .3H2O D  CuO
B  CuSO 4 .H2O E  Cu2 O
C  CuSO 4
1
2CuO  s   Cu2O  s   O2  g
2
O2 has n-factor 4.
About 35% loss in mass corresponds to loss of all water molecules.

INTEGER.
30. Consider the following reaction
 ii PhMgBr 1 eqv.  Major product P 

 3
i O / Zn/H O
Me 3C  2
 iii CH3MgBr 1 eqv.

Me 3C  iv  H3 O
Let, degree of unsaturation of (P) = x.

Possible number of stereoisomers of (P) = y
So, the value of (x + y) is_____
Ans. 20
Sol. Major product (P) is
OH
Ph
Me 3C
Me 3C
CH3
OH
So, x = 12, and y = 8.
31. How many of the following statement(s) regarding oxides (M2O), peroxides (M2O2) and
superoxide (MO2) of alkali metals are correct?
(i) Order of size of oxide, peroxide and superoxide ions is O2  O22   O2 .
(ii) Thermal stability order is O2  O22   O2 .
(iii) Thermal stability order with a particular alkali metal is : superoxide < peroxide < oxide.
(iv) Lattice energy of oxides, peroxides and superoxides decreases down the group for alkali
Metals.
(v) In the formation of oxides, peroxides and superoxides, the entropy decreases in the order :
oxide  peroxide  superoxide .
(vi) Heat of formation is in the order : oxide > peroxide > superoxide.
(vii) Heat of formation decreases down the group for oxides, peroxides and superoxides.
(viii) Compared to the difference in lattice energies between monoxides and peroxides is less
than between monoxides and superoxides.
(ix) Compared to the difference in lattice energies between monoxides and peroxides is less than
between peroxides and superoxides.
(x) All oxides, peroxides and superoxides form basic solutions when dissolved in water.
(xi) Thermal stability of oxides and peroxides decreases down the group while those of
superoxides increases down the group.
(xii) The difference between the lattice enthalpies of monoxides and peroxides decreases down
the group.
Ans. 8
Sol. Correct statements are :

(iii); (iv); (v); (viii); (ix); (x); (xi) and (xii).
Important data for support:

 Lattice energies kJ mol1 
M2 O M2 O2 MO2
Li 2907 2592 878
Na 2518 2309 799
K 2229 2114 741
Rb 2146 2025 706
Cs 2016 1948 679

 Standard enthalpies of formation Hof in kJ mol1 : 
M2 O M2 O2 MO2
Li 596 640 
Na 416 505 270
K 362 494 280
Rb 330 426 310
Cs 318 402 315
32. In a solution of 0.010 M barium nitrate and 0.010 M lead (II) nitrate, when the more soluble
fluoride (other than NaF) begins to precipitate, the concentration of the cation for the less soluble
fluoride that remains in solution, when NaF is added, is a  10b M. So, the value of 10  a  b 
is………
K sp of PbF2  4  10 8 and K sp BaF2   1.44  10 6 
 
(Round off the answer to the nearest integer)
Ans. 32
Sol. For PbF2 ,

PbF2  s   Pb2  aq  2F  aq
2
4  108   0.01  F 
 F   2  103 M
For BaF2 :
BaF2  s   Ba2  aq  2F  aq
2
1.44  10 6   0.01  F 
F   1.2  10 2 M
 
The PbF2 will precipitate first because a lower value for the concentration of fluoride ion is
needed for its precipitation.
BaF2 starts precipitating when the conc. Of F  reaches to 1.2  102 M .
Since, PbF2  s  is present then
PbF2  s   Pb2  aq  2F  aq
   
2
4  108  Pb2   1.2  102
8
 10
Pb   1.2 4 1.2
2
 10 4
 2.77  10 4  2.8  10 4
 a  2.8, b  4


Question Stem
When titanium (III) chloride is heated, it undergoes the following reaction:
2TiCl3  s   TiCl2  s   TiCl4  g
A graph showing how 'K eq ' varies with temperature for this reaction is plotted below
-1
0.00135
0.00140 1/T (K ) 0.00145 0.00150 0.00155 0.00160
-8
(0.001412 (0.001572)
-9
B
-10
(a graph of lnKeq
against 1/T)
- 11
lnKeq
- 12
Graph not to scale
Assume standard enthalpy change Ho   and standard entropy change  S  o

are temperature
independent in the temperature range given in the graph. R  8.314 J mol1 K 1 
 
Let, the Ho of the reaction be ‘x’ kJ and standard free energy change Go of the reaction at 
689.65 K be ‘y’ (kJ).
33. The value of ‘x’ is_______
Ans. Range (155.85 – 155.90)
Ho 1 So
Sol. nK eq    … (1)
R T R
o
 1 H
So, the slope of nK eq against     from the graph.
T
  R
Ho 12   9 
Slope     18750
R 0.001572  0.001412
Ho
  18750
R
18750  8.314
or Ho   155.88 kJ
1000
34. The value of ‘y’ is_______
Ans. Range (55.65 – 55.70)
 Ho  1 So
Sol. nK eq    
 R T R
S o
12  18750  0.001572 
R
S o
So,  17.475
R
 So  17.475  8.314  145.28 JK 1
So, Go  Ho  TSo
 155.88  103  689.65  145.28
Go  155880  100192.35
 55,687.65 J
Go  55.68 kJ

Question Stem
NO2
1 eqvt    A  
 excess    B    C
NH4 SH Br2 /H2 O NaNO2
 dil. HCl
 273 K  278 K 
NO2 CuBr / HBr
Br2 / H2 O Sn / HCl
F  E  D
 excess 
 excess   G  
 273 K  278 K    H

NaNO /HCl excess 

NH4 SH 2
H3PO2 1 eqvt 
H3 O CuCN
K   J I 
HCN
[Atomic masses : C = 12; N = 14; Br = 80; H = 1; Cl = 35.5]
Ratio of the number of halogen atoms present in a molecule of (B) to that of the number of
halogen atoms present in a molecule of (F) is ‘x’ and the ratio of molecular weights of ‘D’ to that of
(K) is ‘y’.
35. The value of ‘x’ is______
Ans. 0.40
Sol. +
NH2 NH2 N2 Cl Br
Br Br Br Br Br Br
; ; ; ;
NO2 NO2 NO2 NO2

(A) (B) (C) (D)
+
Br Br NH2 N2 Cl
Br Br Br Br
; ; ; ;
Br Br
+
NH2 NH2 NH2 N2 Cl
(E) (F) (G) (H)
H
; ;
+ CN COOH
N2 Cl
(I) (J) (K)
36. The value of ‘y’ is________
Ans. 2.95
Range (2.94 – 2.96)
Sol. Molar mass of (D) = 360

Molar mass of (K) = 122
360
So, ratio of molar mass of (D) to that of (K)   2.95
122

Question Stem
Consider the given plot of KEmax against frequency    of incident light.
(Graph not to scale)
19.86
K.Emax(Joules)
13.24
6.62
1.0 2.0 3.0 4.0

Frequency ' ' (in Hz)
Here, frequency '  ' is to be multiplied by 1015 and maximum kinetic energy (KEmax) to be
19
multiplied by 10 .
The work function of the metal be ‘x’ eV.
Planck’s constant  h   6.62  1034 J.s and speed of light (c) = 3  108 m / sec .
Let, electronic charge  e   1.6  10 19 Coulamb .
If a light radiation of wavelength 100 nm is allowed to strike surface of the metal (taken in the
experiment for which above graph has been plotted), then, maximum speed of photoelectron
ejected is found to be y  106 m / s .
37. The value of ‘x’ is________
Ans. Range (4.11 – 4.15)
Sol.   h o
 6.62  10 34  1 1015 J
 6.62  10 19 J
6.62  10 19

  4.1375 eV
1.6  10 19
38. The value of ‘y’ is_______
Ans. Range (1.70 – 1.72)
hc 6.62  10 34  3  108

Sol. Energy of photon  10
 3  6.62  10 19 J
 1000  10
Work function     6.62  10 19 J
 KEmax  3  6.62  10 19  6.62  1019
1
KEmax  2  6.62  10 19 J  2
 m  Vmax
2
2  2  6.62  1019
Vmax   1.7  106 m / s
9.1 10 31
Mathematics PART – III

39. Let PQR be equilateral with side length a. On side PQ produced a point A is taken such that P
lies in between A and Q. If r1 is in radius of APR and r2 be ex-radius of AQR with respect to
r r
side QR, then 1 2 is equal to
a
3
(A)
2
(B) 2
(C) 2
1
(D)
2
Ans. A
Sol. As M1M2 = m1m2 m2

r1 r2 R
M1M2 = M1P + PQ + QM2 = a
3 3 m1
m1m2  m1R  Rm2 ….. (1) r1 N1 r2
60º N2
= N1 R + N2 R A
M1 P Q M2
r1 r2
= a a ….. (2)
3 3
r1  r2 r r 
From equation (1) and (2), we get a   2a   1 2 
3  3 
r r 
2 1 2 a
 3 
40. A person has 6 cards A, K, 2, Q, 10, 9. The person randomly draws the cards one by one with
replacement till he gets 3 consecutive A. If Pn represents the probability that atleast n cards are
drawn, then 216Pn  5Pn 3  30Pn 2  180Pn 1 is (For n > 3)
(A) 0
(B) 1
(C) 2
(D) 3
Ans. A
1 5 1 5  5
Sol. Pn     Pn 3   Pn 2   Pn1 
6 6 6 6  6
216Pn  5Pn 3  30Pn 2  180Pn1  0
1 0 0
tr  A n  PBnP 
41. Let A and B be 3  3 matrices and P  0 0 1 , B = PAP, then lim is equal to
n  tr  An 
0 1 0 
(where |A |  0, tr represents trace of square matrix)
n
(A) 1
(B) 2
(C) 3
(D) 4
Ans. B
Sol. Bn = PAnP (P2 = I)

 PBnP = P(PAnP)P = An
1
42. Let f  x   , x  [0, 1] and a  [2, 3], then which of the following is correct?
sin x   x  a 
2 2
(A) f(x) always increases in (0, 1)
(B) f(x) always decreases in interval (0, 1)
(C) there exists a point of local minima in (0, 1)
(D) there exists a point of local maxima in (0, 1)
Ans. B
1
Sol. f x   sin2x  2  x  a  < 0  x  (0, 1)
 sin2 x   x  a 2 
2

43. Let the value of log2 

  
 2015 2015 2 iab
1  e 2015   is N, then which of the following is/are TRUE?
 a 1 b1 
(A) N is divisible by 5
(B) N is divisible by 3
(C) N > 13000
(D) N is divisible by 61
Ans. A, B, C, D
 1  e  = 2
n 2 iab
gcd a,n 
Sol. N = 13725 if n is odd, then n
b 1
x2 y2
44. Chords at right angles are drawn through P() lying on ellipse   1 and chords joining
4 1
extremities meets normal at Q, then which of the following is/are correct?
(A) Q is same for all such chords drawn through P()
(B) y = 0 is angle bisector of PCQ, (where C is centre of ellipse)
(C) Locus of Q is ellipse for different position of P
(D) Q is not same for all such chords drawn from P
Ans. A, B, C
6cos  3 sin 
Sol. Coordinate of Q are, ,
5 5
1
45. Let f : [1, )  R is a differentiable function such that f   x   and f(1) = 1, then which
x  f2 x
2
of the following is/are correct?
(A) f(x) is strictly increasing in (1, )
(B) lim f  x   2
x 
(C) The number of solution of f(x) = 1 + 2x is 0
(D) f(3) < 2
Ans. A, B, C, D
Sol. f(x) > 0  x  (1, ) so f(x) is strictly increasing

1
So, f(x)  f(1)  x  (1, )  f   x   2
x 1
x x
1 x 
So, f  x   1   f   t  dt  1   2
dt  1  tan1 t 1  1  tan1 x 
1 1 t 1 4

x  , f(x)  1 
4
1
46. If all roots of the equation x8 – 4x7 + b6x6 + b5x5 + b4x4 + b3x3 + b2x2 + b1x +  0 are positive
28
and real, then which of the following is/are correct?
b 2b 6
(A)  0.7
b4
b 2b 6
(B)  0.5
b4
b3b5 14
(C) 
b4 5
b2
(D)  7
b1
Ans. A, C, D
Sol. Let i for i = 1, 2, 3, 4, 5, 6, 7, 8 are positive real roots

1
 i  4 ,  i  28 using AM  GM
1
 i  1 8
  8  as AM = GM  all roots are equal to
1
8 2  2
6 2
8  1  1
C6    8 C2  
b 2b 6 2 2
 4
b4 8  1
C6  
2
cos x
47. Let g  x   , then which of the following is/are correct?
x 1  x 
 1
(A) g    0
2
1
(B)  g  x  dx  0
0
 1 1
(C) g   = 
2 2
1 
(D) g(x) < 0  x   , 1
2 
Ans. A, B, D
1  1  1  1   1
Sol. g   x   g   x   g   x   g   x   g    0
2  2  2  2  2
10
48. The value of  20r C20  20 r C10 is equal to
r 0
39
(A) C9
41
(B) C10
41
(C) C31
39
(D) C30
Ans. B, C
Sol. Coefficient of x10 in (1 – x)–32

INTEGER.
49. The area bounded by region {(x, y) : |x + ay + a2|  1  a  [0, 1]} is A, then [A] is
(where [.] denotes greatest integer function)
Ans. 3
0 1 1
 2 1  x  dx    x  2 1  x  dx    2 1  x  2  x  dx
1
Sol. Required area = 
2
1 0 0
1 4 23
=  2 =
2 3 6
50. Two circles with radius r1 and r2 touches each other

externally and touch a semicircle of radius 1 internally as
shown in figure. If maximum value of r1 + r2 is k, then
3k
is
2 1
Ans. 6
Sol. A1A 2   r1  r2 2  r1  r2 2  2 r1r2
and A1A2 = A1O + OA2 = 1  r1 2  r12  1  r2 2  r22 O2

O1
= 1  2r1  1  2r2
 1  2r1  1  2r2  2 r1r2 A1 O A2
 r1  r2  2 r1r2  
2  r1r2   r1  r2   2  r1r2 
r1r2  2  1  r1  r2  2  2  1
51. Let P(x) ad Q(x) be polynomials with real coefficients such that P(x) (x 2 – 3x + 2) = Q(x) (x2 + 3x +
2). Then minimum number of real roots of the equation P(x)·Q(x) + x 4 – 5x2 + 4 = 0 is
Ans. 4
Sol. Let g(x) = P(x)·Q(x) + x4 – 5x2 + y, the g(–2) = 0, g(2) = 0, g(–1) = 0, g(1) = 0

Question Stem
Let P(1, s, t) be a point and L1 : x + y = 1, z + 2y = 2, L2 : x + y = 1, z – 3y = 2 be straight lines, then
52. If there exist infinite number of lines passing through P and intersecting both the lines, then the
value of s is
Ans. 0.00
53. If there exist unique line passing through P and intersecting both the lines L1 and L2, then number
of values of s such that P lies on the plane x + y = 1 is
Ans. 0.00
Sol. (for Q. 52-53)

Lines L1 and L2 are coplanar and lies on plane x + y = 1
Question Stem
Let P(–1, ), Q(2, ) be focii of the ellipse which touches y = x at (1, 1). If length of major axis of ellipse is
3
17 , then
2
54. The value of (> 0) is
Ans. 0.50
55. The value of ordinate of centre of ellipse if ( > 0) is
Ans. 2.75
Sol. (for Q. 54-55)

Image of one focus about tangent, point of contact of tangent and other focus are collinear

Question Stem
Let y = f(x) satisfy the differential equation (x + 2)(x + y + 2)dy = y 2dx, for x > 0 and f(1) = 6, then
56. Number of points of intersection of y = f(x) and y = x + 2 is
Ans. 1.00
57. Number of points of intersection of y = f(x) and y = (x + 2) 2 is
Ans. 0.00
Sol. (x + 2)2dy + (x + 2)y dy = y2 dx

1 1 y
dy  dy  dx  0
y  x  2  x  2 2
1  y  y
dy  d    0  ln y  c
y  x 2 x2

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ALL INDIA TEST SERIES

Section – A (Maximum Marks: 12)

1. In the shown figure, a plank P of mass 25 kg 1m 3m

2. A cube of side length 1 m and mass 10 kg is placed on 2 kg

3. In the shown figure two uniformly charged rings A and B of B

4. An insulating long cylinder is uniformly charged on its lateral surface

Sol. Let Rs is resistance of the loop

Section – A (Maximum Marks: 24)

5. A cube of mass m and side length 4R has a groove made inside

(A) Normal reaction on particle is mg

F.B.D. of particle w.r.t.

(A) Emissive power is 2240 W/m2

Sol. 200 = .1.(400)4 …(i)

7. A thin cube of side length  = 1m is heated with the help of

(A) Power of heater is 500 W

(B) Temperature of the outer surface is steady state 53.3C

(C) Temperature of outer surface in steady state 80C

(D) Power of heater is 400 W

Sol. Power given = power loss

8. Capacitor of capacitance C = 10 F was connected with a  = 10 V

(A) acceleration of the charged particle is zero

(B) acceleration of the charged particle is 100 m/s 2

(C) magnetic field inside the solenoid is nearly 700 mT

(D) magnetic field inside the solenoid is nearly 218 T

Sol. V = 0 cos t is voltage across capacitor

9. In the shown figure, two parallel rails in a vertical plane            

(A) Terminal velocity of disc is 64 m/s

(B) Terminal velocity of disc is 96 m/s

(C) Current flowing in the rails is 8 2 A

(D) Current flowing in the rails is 8 A

Power given =power loss

10. A conducting wire of mass m is pulled with a uniform x

(A) Force F is directly proportional to x

(B) Force F is directly proportional to x2

(C) Energy stored in coil is directly proportional to x

(D) Energy stored in coil is directly proportional to x2

Section – B (Maximum Marks: 12)

11. Two converging lenses L1 and L2 of focal f1 = 20 cm

Sol. Magnification is independent of object distance from lens L1.

Sol. F = T + 2mg + mg

Sol. Using Kirchoff’s law

Section – C (Maximum Marks: 12)

Question Stem for Question Nos. 14 and 15

14. The value of m (in kg) is ………..

15. The value of M (in kg) is ………..

Sol. (for Q.14-15)

Question Stem for Question Nos. 16 and 17

An insulating cylinder of volume 20 liter is divided into two equal

16. The value of T is …………..

17. The value of Q is …………..

Sol. (for Q. 16-17)

Question Stem for Question Nos. 18 and 19

A converging lens of power P1 = +5D and a concave mirror of

18. The value of X1(in cm) is ……………

19. The value of X2(in cm) is ………..

Sol. (for Q.18-19)

Section – A (Maximum Marks: 12)

20. The correct relation between the following compounds is:

(C) Homomers (identical)

(D) Constitutional isomers

(A) CF3  CH3  OCH3

(B) CF3  OCH3  CH3