Page 1/10

Safety Data Sheet

acc.to ISO/DIS 11014
Printing date 12/18/2012 Version : 5 Reviewed on 12/18/2012

* 1 Identification of the substance/mixture and of the company/undertaking

· Product identifier
· Trade name: RAZEEN LR 1100, LR 1110, LR 1120, LR 1130, LR 1140, LR
1150, LR 1160, LR 1170, LR 1200, LR 2280
· CAS Number:
25068-38-6
· NLP Number:
500-033-5
· Index number:
603-074-00-8
· Relevant identified uses of the substance or mixture and uses advised against
Manufacture
Formulation - (Industrial)
Formulation - Professional
Coating Application - Industrial
Coating Application (Professional Use)
Tooling and Casting (Industrial)
Tooling and Casting (Professional Use)
Consumer Use Exposure from Use of Two-Component Epoxy Paints and Adhesives
· Sector of Use
SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
SU8 Manufacture of bulk, large scale chemicals (including petroleum products)
· Product category PC19 Intermediate
· Process category
PROC15 Use as laboratory reagent
PROC2 Use in closed, continuous process with occasional controlled exposure
PROC8b Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at
dedicated facilities
· Environmental release category ERC1 Manufacture of substances
· Application of the substance / the preparation Epoxy Resin
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Jubail Chemical Industries Company
P.O. Box -10661
Jubail Chemical City - 31961
Kinddom of Saudi Arabia
phone no: 00966-3-3585002
· Information department: safety: e-mail: safety@nama.com.sa
· Emergency telephone number:
Swiss Toxicological Information Centre
Freiestrasse 16 CH- Zurich
Emergency phone number (from outside Switzerland): 0041 44 251 51 51 (24h)

* 2 Hazards identification
· Classification of the substance or mixture

GHS07

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2 H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Irritant
Irritating to eyes and skin. May cause sensitisation by skin contact.
(Contd. on page 2)
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 Page 2/10
Safety Data Sheet
acc.to ISO/DIS 11014
Printing date 12/18/2012 Version : 5 Reviewed on 12/18/2012

Trade name: RAZEEN LR 1100, LR 1110, LR 1120, LR 1130, LR 1140, LR 1150,

LR 1160, LR 1170, LR 1200, LR 2280
(Contd. of page 1)

Dangerous for the environment

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
· Information concerning particular hazards for human and environment: Not applicable.
· Label elements
· GHS label elements
The substance is classified and labelled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS07

· Signal word Warning

· Hazard-determining components of labelling:
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight  700)
· Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
· Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
P362 Take off contaminated clothing and wash before reuse.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· NFPA ratings (scale 0 - 4)
Health = 1
1 Fire = 1
1 0 Reactivity = 0
· HMIS-ratings (scale 0 - 4)
HEALTH 1 Health = 1
FIRE 1 Fire = 1
REACTIVITY 0 Reactivity = 0
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterization: Substances
· CAS No. Description
25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin
(number average molecular weight  700)
· Identification number(s)
· NLP Number: 500-033-5
(Contd. on page 3)
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 Page 3/10
Safety Data Sheet
acc.to ISO/DIS 11014
Printing date 12/18/2012 Version : 5 Reviewed on 12/18/2012

Trade name: RAZEEN LR 1100, LR 1110, LR 1120, LR 1130, LR 1140, LR 1150,

LR 1160, LR 1170, LR 1200, LR 2280
(Contd. of page 2)
· Index number: 603-074-00-8

* 4 First aid measures

· Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact:
Seek medical treatment.
Immediately wash with water and soap and rinse thoroughly.
Clean with detergents. Avoid solvents.
· After eye contact:
Call a doctor immediately.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: Administer medicinal carbon
· Information for doctor:
· Most important symptoms and effects both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

* 5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents: Use fire fighting measures that suit the environment.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
In certain fire conditions, traces of other toxic gases cannot be excluded.
Can form explosive gas-air mixtures.
Carbon oxides. Burning produces obnoxious and toxic fumes.
· Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

* 6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures Wear protective clothing.
· Environmental precautions:
Keep contaminated washing water and dispose of appropriately.
Do not allow to penetrate the ground/soil.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Residual products may be removed using steam or hot soapy water.
Residual can also be removed with solvent. Solvent are not recommended for cleanup, unless guidelines and
safe handling practices for the specific solvent are followed.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
(Contd. on page 4)
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 Page 4/10
Safety Data Sheet
acc.to ISO/DIS 11014
Printing date 12/18/2012 Version : 5 Reviewed on 12/18/2012

Trade name: RAZEEN LR 1100, LR 1110, LR 1120, LR 1130, LR 1140, LR 1150,

LR 1160, LR 1170, LR 1200, LR 2280
(Contd. of page 3)
See Section 13 for disposal information.

* 7 Handling and storage

· Precautions for safe handling No special precautions are necessary if used correctly.
· Information about protection against explosions and fires: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Keep at temperatures between 2 and 40 °C (35 - 104 °F)
· Specific end use(s) No further relevant information available.

* 8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Use of barrier cream recommended.
· Breathing equipment: Not necessary if room is well-ventilated.
· Protection of hands:
Chemical resistant gloves (EN 374)

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
Natural rubber, NR
Chloroprene rubber, CR
Nitrile rubber, NBR
Fluorocarbon rubber (Viton)
Butyl rubber, BR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 5)
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 Page 5/10
Safety Data Sheet
acc.to ISO/DIS 11014
Printing date 12/18/2012 Version : 5 Reviewed on 12/18/2012

Trade name: RAZEEN LR 1100, LR 1110, LR 1120, LR 1130, LR 1140, LR 1150,

LR 1160, LR 1170, LR 1200, LR 2280
(Contd. of page 4)
· Eye protection:

Tightly sealed goggles

· Body protection: Protective work clothing

* 9 Physical and chemical properties

· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Color: Various colors
· Odor: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: > 200 °C (> 392 °F) (DIN 51751)
· Flash point: > 200 °C (> 392 °F) (DIN 51755)
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature:
Decomposition temperature: >200 °C (>392 °F)
· Auto igniting: Not determined.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapor pressure: Not determined.
· Density at 20 °C (68 °F): 1.1 g/cm³ (9.18 lbs/gal)
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic at 25 °C (77 °F): 8000-24000 mPas
Kinematic: Not determined.
Organic solvents: 0.0 %
· Other information No further relevant information available.
USA
(Contd. on page 6)

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 Page 6/10
Safety Data Sheet
acc.to ISO/DIS 11014
Printing date 12/18/2012 Version : 5 Reviewed on 12/18/2012

Trade name: RAZEEN LR 1100, LR 1110, LR 1120, LR 1130, LR 1140, LR 1150,

LR 1160, LR 1170, LR 1200, LR 2280
(Contd. of page 5)

* 10 Stability and reactivity

· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Take necessary action to avoid static electricity discharge.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials:
Strong acids or strong bases.
Strong oxidizing agents.
· Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Aldehyde
Carbon oxides. Burning produces obnoxious and toxic fumes.

* 11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular
weight  700)
Oral LD50 15000 mg/kg (rat)
Dermal LD50 23000 mg/kg (rat)
· Primary irritant effect:
· on the skin: Irritant to skin and mucous membranes.
· on the eye: Irritating effect.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information: Irritant
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
Substance is not listed.
· NTP (National Toxicology Program)
Substance is not listed.

* 12 Ecological information
· Toxicity
· Aquatic toxicity:
25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular
weight  700)
Oral ErC50 (72h ) >11 mg/l (Algen/Algues)
NOEC 21 d (OECD 203) 0.3 mg/l (daphnia magna)
EC50 (48h) 1.8 mg/l (daphnia magna)
LC50 (96h) 2.0 mg/l (Oncorhynchus mykiss)
· Persistence and degradability
Not easily biodegradable
Biological degradation: 12 % OECD 301 B (mod.Sturm)
(Contd. on page 7)
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 Page 7/10
Safety Data Sheet
acc.to ISO/DIS 11014
Printing date 12/18/2012 Version : 5 Reviewed on 12/18/2012

Trade name: RAZEEN LR 1100, LR 1110, LR 1120, LR 1130, LR 1140, LR 1150,

LR 1160, LR 1170, LR 1200, LR 2280
(Contd. of page 6)
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Toxic for fish
· Additional ecological information:
· General notes:
Water hazard class 2 (Assessment by list): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation:
Hand over to hazardous waste disposers.
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

* 14 Transport information
· UN-Number
· DOT, ADR, IMDG, IATA UN3082
· UN proper shipping name
· DOT, IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (reaction product: bisphenol-A-(epichlorhydrin) epoxy
resin (number average molecular weight  700))
· ADR 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (reaction product: bisphenol-A-
(epichlorhydrin) epoxy resin (number average molecular weight
 700))
· IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (reaction product: bisphenol-A-(epichlorhydrin) epoxy
resin (number average molecular weight  700)), MARINE
POLLUTANT
· Transport hazard class(es)
· DOT

· Class 9 Miscellaneous dangerous substances and articles.

(Contd. on page 8)
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 Page 8/10
Safety Data Sheet
acc.to ISO/DIS 11014
Printing date 12/18/2012 Version : 5 Reviewed on 12/18/2012

Trade name: RAZEEN LR 1100, LR 1110, LR 1120, LR 1130, LR 1140, LR 1150,

LR 1160, LR 1170, LR 1200, LR 2280
(Contd. of page 7)

· Label 9
· ADR, IMDG, IATA

· Class 9 Miscellaneous dangerous substances and articles

· Label 9
· Packing group
· DOT, ADR, IMDG, IATA III
· Environmental hazards:
· Marine pollutant: Yes
Symbol (fish and tree)
· Special marking (ADR): Symbol (fish and tree)
· Special marking (IATA): Symbol (fish and tree)
· Special precautions for user Warning: Miscellaneous dangerous substances and articles
· Danger code (Kemler): 90
· EMS Number: F-A,S-F
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· UN "Model Regulation": UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (reaction product: bisphenol-A-
(epichlorhydrin) epoxy resin (number average molecular weight
 700)), 9, III

* 15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
Substance is not listed.
· Section 313 (Specific toxic chemical listings):
Substance is not listed.
· TSCA (Toxic Substances Control Act):
Substance is listed.
· Proposition 65
· Chemicals known to cause cancer:
Substance is not listed.
· Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
· Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
· Chemicals known to cause developmental toxicity:
Substance is not listed.
(Contd. on page 9)
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 Page 9/10
Safety Data Sheet
acc.to ISO/DIS 11014
Printing date 12/18/2012 Version : 5 Reviewed on 12/18/2012

Trade name: RAZEEN LR 1100, LR 1110, LR 1120, LR 1130, LR 1140, LR 1150,

LR 1160, LR 1170, LR 1200, LR 2280
(Contd. of page 8)

· Cancerogenity categories
· EPA (Environmental Protection Agency)
Substance is not listed.
· TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
· OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.
· GHS label elements
The substance is classified and labelled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS07

· Signal word Warning

· Hazard-determining components of labelling:
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight  700)
· Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
· Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
P362 Take off contaminated clothing and wash before reuse.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Chemical safety assessment: A Chemical Safety Assessment has been carried out.

* 16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Department issuing MSDS: product safety departement
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organization
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
(Contd. on page 10)
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Safety Data Sheet
acc.to ISO/DIS 11014
Printing date 12/18/2012 Version : 5 Reviewed on 12/18/2012

Trade name: RAZEEN LR 1100, LR 1110, LR 1120, LR 1130, LR 1140, LR 1150,

LR 1160, LR 1170, LR 1200, LR 2280
(Contd. of page 9)
LD50: Lethal dose, 50 percent
· * Data compared to the previous version altered.
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