Solutions 3

Concentration Terms
Anupam Gupta
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 Solutions 3
Concentration Terms
 Concentration Terms

The following concentration terms are used to expressed the concentration of

a solution.

● Molarity (M)
● Molality (m)
● Mole fraction (x)
● % calculation
● ppm
 Molarity

Molarity (M) : The number of moles of a solute dissolved in 1 L (1000 ml) of the
solution is known as the molarity of the solution.
500 mL of a glucose solution contains 6.02 x 1022 molecules. The
concentration of the solution is

A. 0.1 M
B. 1.0 M
C. 0.2 M
D. 2.0 M
 Molarity

Millimoles

Number of Millimoles = Molarity of solution x Vml

Molarity = Number of millimole of solute

Total volume of solution in ml
What volume of a 0.8 M solution contains 100 milli moles of the solute?

A. 100 mL
B. 125 mL
C. 500 mL
D. 62.5 mL
 Molarity

Dilution

If a particular solution having volume V1 and molarity = M1 is diluted upto volume V2 mL than
M1 V1 = M2 V2

M2 : Resultant molarity
 Molarity

Mixing

If a solution having volume V1 and molarity M1 is mixed with another solution of same solute
having
volume V2 mL & molarity M2 then M1 V1 + M2 V2 = MR (V1 + V2)
M1 V1 + M2 V2
M2 : Resultant molarity
V1 + V2
If 500 ml of 1 M solution of glucose is mixed with 500 ml of 1 M solution of
glucose final molarity of solution will be :
A. 1 M
B. 0.5 M
C. 2 M
D. 1.5 M
The volume of water that must be added to a mixture of 250 ml of 0.6 M
HCl and 750 ml of 0.2 M HCl to obtain 0.25 M solution of HCl is :

A. 750 ml
B. 100 ml
C. 200 ml
D. 300 ml
Which of the following is correct-

A. mole = molarity x Vin l =

B. Milli mole = molarity x Vin mL =

C. Moles and millimoles of reactants react according to stoichiometric

ratio of balanced chemical equation

D. All
 Molarity

Molarity α 1 α 1
temperature volume

Molarity is a unit that depends upon temperature. It varies inversely with temperature.

Mathematically: Molarity decreases as temperature increases.

 Molality

Molality (m)
The number of moles of solute dissolved in 1000g (1kg) of a solvent is known as the
molality of the solution.
If 18 gram of glucose (C6H12O6) is present in 1000 gram of an aqueous solution of
glucose it is said to be

A. 39.2 molal
B. 1.1 molal
C. 0.5 molal
D. 0.1 molal
Equal moles of H2O and NaCl are present in a solution. Hence, molality of
NaCl solution is :

A. 0.55
B. 55.5
C. 1.00
D. 0.18
 Molality

Molality is independent of temperature changes.

 Mole Fraction(x)

Let number of moles of solute in solution = n

Number of moles of solvent in solution = N

Mole fraction of solute (x1) = n

n+N

Mole fraction of solute (x2) = N

n+N

also x1 + x2 = 1
 Mole Fraction(x)

Mole fraction is pure number. It will remain independent of temperature changes.

Mole fraction of A in H2O is 0.2. The molality of A in H2O is :

A. 13.9
B. 15.5
C. 14.5
D. 16.8
5.85 g of NaCl are dissolved in 90 g of water. The mole fraction of NaCl is

A. 0.1
B. 0.01
C. 0.2
D. 0.0196
 %w/w
% weight by weight (ww): It is given as mass of solute present in per 100g of solution.

mass of solute in gm
i.e. %w/w = x 100
mass of solution in gm
 %w/v
% weight by volume (w/v) : It is given as mass of solute present in per 100 ml of solution.
mass of solute in gm
mass of solute in gm
i.e. %w/v = x 100
mass of solution in ml
 %v/v
% volume by volume (v/v) : It is given as volume of solute present in per 100 ml solution.
volume of solute in ml
volume of solute in ml
i.e. %v/v = x 100
volume of solution in ml
What is the molarity of H2SO4 solution that has a density of 1.84 g/cc and
contains 98% by mass of H2SO4? (Given atomic mass of S = 32)

A. 4.18 M
B. 8.14 M
C. 18.4 M
D. 18 M
The molarity of the solution containing 2.8% (mass/volume) solution of
KOH is : Given atomic mass of K = 39) is :

A. 70.1 M
B. 0.5 M
C. 0.2 M
D. 1M
Decreasing order of mass of pure NaOH in each of the aqueous solution.
I. 50 g of 40% (W/W) NaOH
II. 50 ml of 50% (W/V) NaOH
III.50 g of 15 M NaOH (dsol = 1 g/ml).
A. I, II, III
B. III, II, I
C. II, III, I
D. III = II = I.
 Parts Per Million (ppm)
mass of A
ppmA = x 106 = mass fraction x 106
Total mass
1000 gram aqueous solution of CaCO3 contains 10 gram of carbonate.
Concentration of solution is -
A. 10 ppm
B. 100 ppm
C. 1000 ppm
D. 10,000 ppm
2M of 100 ml Na2SO4 is mixed with 3M of 100 ml NaCl solution and 1M of 200 ml
CaCl2 solution. Then the ratio of the concentration of cation and anion.

A. 1/2
B. 2
C. 1 .5
D. 1
Density of water is 1g/mL. The concentration of water in mol/litre is

A. 1000
B. 18
C. 0.018
D. 55.5
How many grams of NaOH will be needed to prepare 250mL of 0.1 M solution

A. 1g
B. 10g
C. 4g
D. 6g
How many grams of glucose should be dissolved to make one litre solution of
10%(w/v) glucose.
A. 10g
B. 180g
C. 100 g
D. 1.8 g
The molality of 15% (wt./vol.) solution of H2SO4 of density 1.1 g/cm3 is
approximately-
A. 1.2
B. 1.4
C. 1.8
D. 1.6
Equal volumes of 0.1 M AgNO3 and 0.2 M NaCl are mixed. The concentration of NO3-
ions in the mixture will be
A. 0.1 M
B. 0.05 M
C. 0.2 M
D. 0.15 M
All of the water in a 0.20 M solution of NaCl was evaporated and 0.150 mol of NaCl
was obtained. What was the original volume of the sample ?
A. 30 mL
B. 333 mL
C. 750 mL
D. 1000 mL
25 mL of 3.0 M HNO3 are mixed with 75 mL of 4.0M HNO3. If the volumes are
additive, the molarity of the final mixture would be
A. 3.25 M
B. 4.0 M
C. 3.75 M
D. 3.50 M
10 gram of glucose are dissolved in 150 gram of water. The mass % of glucose os

A. 5%
B. 6.25%
C. 93.75%
D. 15%
If 100 ml of M NaOH solution is diluted to 1.0 L, the resulting solution contains-

A. 1 mole of NaOH
B. 0.1 mole of NaOH
C. 10.0 mole of NaOH
D. 0.05 mole of NaOH
The molarity of a solution obtained by mixing 750 mL of 0.5(M) HCl with 250 mL of
2(M) HCl will be :

A. 0.875 M
[2013]
B. 1.00 M
C. 1.75 M
D. 0.975 M
The density of a solution prepared by dissolving 120 g of urea (mol. mass = 60 u) in
1000 g of water is 1.15 g/mL. The molarity of this solution is

A. 0.50 M
[2012]
B. 1.78 M
C. 1.02 M
D. 2.05 M
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