Chemical Data Guide For Bulk Shipment by Water

SCANNED BY MKP & BARIS A.
2004
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rl COMI'IANDANT INSTRUCTION M16616. 6A

COMDINST M16616.6A
08 Nov1990
1-t SubJ:
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Chemical Data
PURPOSE. This manual has

cuide for Bulk Shipment
been prepared
By Water
to assist Coast
Guard personnel and others involved in
1-l
bulk chemical
shipment by water.
2. DIRECTIVES AFFECTED. The Chemical Data cuide for Bulk

Shipment by water, dated January 28, 1982, j.s cancelled.
t_l 3. CHANGE.
suggestions
Recommendations,
for lmproving
Commandant (G-MTH-1).
comments,
this guide
additional data
are requested
and
by the
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rI Rear Adnlral,
Chlef, office
U.S. Coast Guard
of Marine Safety,
rw Securlty and Envlronmental Protectlon
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For d. by th. 8uFrinbnd6s! ol freumGtrb, U.8. Oovcmncnt Printi{ Ofiaa

Wr.hi|t|rn. D.C. toao,
PREFACE TO THE SEVENTH EDITION CIIEMICAL DATA GUIDE
FOR
The firrst edition of this Guide was issued on I June 1965. It con- BULK SHIPMENT BY WATER
tained data on 127 cargoes. This edition contains data on over 300 car-
goes. A number of new cargo data sheets have been added, and several Table of Contents
Page
obsolete cargo data sheets have been dropped.
CommandantInstruction M I 66I 6.64, i
Most of the data for the new cargoes were obtained from complet-
ed CG-4355 forms. This form, Characteristics of Liquid Chemicals pro- Table of Contents iii
posed for Bulk Water Movement, or the International Maritime Organi-
Prefaceto the Seventh Edition v
zation's equivalent form, BCH/Circ.26, Characteristics of Liquid
Chemicals Proposed for Marine Transport in Bulk, or other equivalent Introduction vii
data source is required prior to the classification of a bulk cargo.
Explanation of Data viii
On 6 April 1987, Annex II of the 1978 Protocol to the Internation-
Chemical HazardsResponseInformation System(CHRIS) xviii
al Convention for the Prevention of Pollution from Ships, 1973
(MARPOL 73/78) came into force. This Convention controls oper- National ResponseCenter (NRC). xxi
ational discharges from chemical tankers and provides additional pro-
Guide Sheet. I
tection from accidental spills. With the advent of the MARpOL Con-
vention, carriage requirements for chemical cargoes are now deter- Data Sheets 2
mined by evaluation of both their safety and pollution characteristics.
SynonymIndex........... 313
This edition of the Guide includes the International Maritime organiza-
tion (IMO) Pollution Category, and for domestic carriage, the U.S. En- Appendixes:
vironmental Protection Agency (EPA) Category.
A. Compatibility Information, 46 CFR 15G-Subpart A......... 360
All data have been updated where new data were available includ-
B. Medical Kit Information-Cyanide-like cargoes;
ing the Threshold Limit Values (TLVs) adopted in the 1989-1990 edi-
Carcinogenslisted in the Guide... ,lo8
tion by the American Conference of Governmental Industrial Hygien-
ists (ACGIH). Included with this edition for the first time are the per-
c. List of Oils-Appendix I, MARPOL 73/78:
Composition of Common Petroleum Products..... 410
missible Exposure Limits (PELs) adopted by the U.S. Occupational
D. ConversionFactors....... 412
Safety and Health Administration (OSHA) in Table Z-l-A,29 CFR E. TemperatureConversion.................. 417
l9 10.1000.
The information in this book was collected from various sources
believed to be reliable. However, the coast Guard makesno claim that
these data are either correct or suffrcient and assumesno liability for
any consequencesarising from their use.
The courses of action described in this guide are meant as sugges.
tions only. This guide carries no force of law or regulation except for
46 CFR 150.
SCANNED BY MKP & BARIS A. 2004
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SCANNED BY MKP & BARIS A. 2004 {
r INTRODUCIION
The U.S. Coast Guard is vitally concerned with safety at sea. In
r the interest of safety, the coast Guard reviews all chemicals proposed
for bulk shipment by water. All cargoes classiflred as dangerous are reg-
ulated.
t* The number and variety of unconventional liquid cargoes being

transported in bulk by water continues to steadily increase. Although
the transportation hazards of common petroleum products are generally
f- well understood, newer commodities often have unusual fire and explo-
sive properties such as wide flammable range, low ignition temperature
r and foam incompatibility in addition to other hazards such as toxicity

and'dangerous reactivity. It became increasingly evident that a conven-
ient reference guide listing properties and emergency procedures for
bulk liquid cargoes was needed by coast Guard personnel concerned
r
I
with the various aspects of safe transportation (marine inspection, port
safety and security, marine environmental response and rescue coordi-
nation) and by civilian personnel with similar safety interests. The result
f i of these concerns was this Chemical Data Guide.
This manual was prepared by the Marine Technical and Hazardous

Materials Division staff at Headquarters in connection with the regula-
[; tions governing bulk chemical transportation. The data in this guide
were compiled from a number of sources. Too often contradictory data
were found, and for many commodities desired data were simpiy non-
[-l existant. However, as additional data become available, appropriate cor-
rections and additions will be made to update and continuously im-
prove this guide.
[-i Although this chemicalData Guide is intended to be helpful in the
initial stages of emergencies and casualties, users should seek more de-
f-l
tailed, specific and competent emergency medical services as soon as
l l possible.
f-- rl This chemical Data Guide was developed in the interest of safe
t
t , water movement of bulk chemicals. Hopefully, by providing key chem-
ical information in an easy to use form, this guide can help prevent or
at least minimize the harmful effects of chemical accidents on the
t-t waterwavs.
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SCANNED BY MKP & BARIS A. 2004 r-
EXPLANATION OF DATA
I Chemical Family:
This is a general chemical category which facilitates the use of
r*
Format the compatibility chart for predicting the type of reactions
which can be expected.
Data sheets are arranged alphabetically by the most commonly-
used chemical name. Following the data pages is a synonym index Pollution Category...USEPA IMO -:
In the blanks are indicated the category assignedby the U.S. En-
which shows other names for the products.
A standard form is used for each product to permit rapid reference

t- vironmental Protection Agency (USEPA), for domestic user in-
formation, and the Noxious Liquid Substance (NLS) Pollution
and to group data in a logical manner. General information on identifi- Category (Pol. Cat.) assigned by the International Maritime Or-
cation and physical properties is given at the top of the page. Data per-
taining to the three basic types of hazard (fire, health and reactivity)
t* ganization (IMO) for international shipment on oceangoing ves-
sels.
are given in separate blocks below. Suggested action in the event of a
USEPA
spill or leak is given in the bottom block. Regulatory classiltcations are I X, A, B, C, D-Category associated with reportable quantities
included in the top section, while special information is given at the of l, 10, 100, 1,000, and 5,000 pounds, respectively. See 40 CFR
"Remarks."
bottom of the page under Table 302.4-List of Hazardous Substances and Reportable
This book will be used by personnel with varying degrees of I Quantities.
chemical training and experience. For this reason, non-technical terms IMO
are used whenever possible.
The guide sheet preceding the data sheets is intended to help inter-
t- A, B, C, D-NLS
Ill-Appendix
Category of Annex II of MARPOL 73/78.
III of Annex II (non-NLS cargoes) of MARPOL
73/78.
pret and identify the information on the data sheets.
Explanation of Terms
T-
I
I-Considered an oil under Annex I of MARPOL 73178. See
page 410 of the Data Guide for the complete list.
Synonyms:
Alternate and common names are listed. In general, proprietary
and trade names are not used.
r #-No determination of NLS status. For shipping on oceango-
ing vessels,see 46 CFR 153.900(c).
@-The NLS category has been assigned by the U.S. Coast
Formula:
The constituent elements and a simplified structural formula are
r Guard, in absence of one assigned by the IMO. The category is
based upon a GESAMP Hazard Profile or by analogy to a close-
ly related product having an NLS assigned.
r
"gas"-The
shown. IMO generally does not assign Pol. Cats to gases as
these cargoes present little to no hazard to the aquatic environ-
Appearance-Odor: ment.
A brief descriptive statement of these properties is given.
r- Applicable Bulk Regulation 46 CFR Subchapter
Specific Gravity: I In the blank is indicated the CFR reference for the carriage of
This is the ratio of the weight of a volume of the cargo to the the commodity.
weight of an equal volume of water. In the case of liquids of lim-
ited solubility, the specifrc gravity will predict whether the prod-
uct will sink or float on water; for example, if the specific gravi-
r United Nations Number:
The number assigned to a particular
Nations.
cargo by the United
ty is greater than 1, the product will sink, and if the specific

gravity is less than l, the product will float. t- CHRIS Code:
The three letter designation assigned to every entry in the
Chemical Hazard Response Information System.
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Boiling Point: Fire & Explosion Hazard Data
The temperature at which the liquid boils, given in "C and 'F at
a pressure of 760 mm Hg, one atmosphere or 14.7 psia. Thus, the
l-l Grade:
boiling point is the temperature at which the vapor pressure is The classiflrcation assigned by the Coast Guard to flammable or
760 mm Hg, one atmosphere or 14.7 psia
Freezing Point:
f*' combustible liquids is defined as follows:
Grade A Flammable liquid with a Reid vapor pressure of 14

The temperature in 'C and in 'F at which the liquid solidifies. pounds per square inch absolute (psia) or more.
{-
Vapor Pressure: Grade B Flammable liquid with a Reid vapor pressure of more
The equilibrium pressure of the saturated vapor above the liquid, than 8Yz psia but less than 14 psia.
measured in millimeters of mercury (760 mm Hg : 14.7 psia) at
20'C (68"F) unless another temperature is specified. Conversion
l-- Grade C Flammable liquid with a Reid vapor pressure of 8yz
psia or less and a flash point of 8O"F or below.
is done as follows:
psi = mm Hg x A.7 t- Grade D Combustible liquid with a flash point above 80"F, but
below 150'F.
r
760
Grade E, Combustible liquid with a flash point of 150.F or
Reid Vapor Pressure:
above.
Equilibrium pressure exerted by vapor over the liquid at 100'F,
expressed as pounds per square inch absolute (pisa), defrned in 46 Electrical Group:
cFR 30.10-59. f* The electrical group is based on the explosive characteristics of
air mixtures of gases or vapors. The 1986 edition of Manual for
r
Vapor Density:
Classification of Gases, Vapors, and Dusts for Electrical Equip-
This is actually a specific gravity rather than a true density be-
ment in Hazardous (Classified) Locations, NFPA 497M, or the
cause it equals the ratio of the weight of a vapor or gas (with no
1982 edition of Classification of Gases, Liquids, and Volatile
air present) compared to the weight of an equal volume of air at
the same temperature and pressure. Values less than I indicate r1 Solids Relative to Explosion-Proof Electrical Equipment,
that the vapor or gas tends to rise and values greater than I indi- l l NMAB 353-5. These publications provide details and list the
cate that it tends to settle. However, temperature effects must be chemicals by Group. (Both publications were current as of press
time of the Data Guide.)
considered. For example, although methane at 68'F has a vapor
density of 0.55, it becomes denser at lower temperatures. At
-259"F, the boiling point, the vapor is heavier than air. Vapors
f: Flash Point:
The lowest temperature at which the vapors of a liquid may be
from an open container of boiling methane fall rather than rise.
Solubility in Water:
t-r ignited momentarily. Values given in the data sheets are open
cup except where designated "(cc)," which indicates the closed
The following terms are used to describe the solubility of the
product by weight in cold water:
Negligible less than 0.17o
rr cup value. In general the open cup value is about l0' to l5'F
higher than the closed cup value.
Flammable Limits:
Slight
Moderate
O.lVo-lVo
lVo-lOVo tl The range of gas or vapor concentrations (percent by volume in
air) which will burn or explode if an ignition source is present.
Limiting concentrations are commonly called the "lower explo-
The Vo by weight will be given when the solubility is of particu-
lar importance; for example, a highly toxic material which is
only slightly soluble.
n sive limit" (LEL) and the "upper explosive limit', (UEL). Below
the LEL the mixture is too lean to burn, and above the UEL it
n
is too rich to burn.
r- ---
SCANNED BY MKP & BARIS A. 2004 t '
t ,
Autoignition Temperature:
The minimum temperature required to ignite gas or vapor with-
out a spark or flame being present. Values given are only ap-
t- violently with water. Precautions should always be observed be-
cause of the hazardous properties of many cargoes in a fire. Ex-
proximate and may change substantially with changes in geome-
try, gas, or vapor concentrations, presence of catalysts, or other
factors.
r amples include the formation of toxic combustion products, the
reactivity with extinguishing media and the need for protective
clothing and breathing apparatus.
Extinguishing Media:
A list of firefighting materials suitable for use on the burning ma- I General Fire Fighting Procedures:
For flammable liquids and volatile solids having flash points be-
terial. For certain speciftc chemicals special formulations are
tween approximately 100' and 212"F, water fog may be used.
available for extinguishing fires in addition to the standard
agents. No mention of these can be made here because of the I For liquids with flash points below IOO"F, water may not extin-
guish, but possibly will control the fire.
large number of such media available under various trade names.
The firefrghting agents listed here are as follows:
Water fog-a finely divided mist produced by either a high or
low velocity fog nozzle. It is used for knocking down
r Flammable liquids having specific gravities greater than that of
water (sp.gr. - l), and not water soluble, may be extinguished
by gentle application of water to blanket the surface.
flames and cooling hot surfaces.
Water foam-either mechanical or chemical, produced by a
l , For flammable liquids with flash points above 2lZ"F, and also
special foam nozzle or by a fixed system. It is used to for some very viscous materials, the use of water may cause
form a blanket over the surface of burning liquids. It
is effective only with liquids which are not apprecia-
[---i frothing of the burning liquid. Water spray, if carefully applied,
however, may be effective.
bly soluble in water.
Alcohol foam-this material blankets fires in the same manner
as conventional foam, but is intended for use with liq-
uids which are soluble in water, such as alcohol and
r Generally, foam is a good extinguishing agent for frres in flam-
mable liquids, except for those that are more than slightly solu-
ble in water. These require the use of "alcohol" foam.
acetone. It must be applied more carefully than regu-
lar foam because the mechanical strength of the bub-
I Health Hazard Data
bles is less.
Health Hazard Data Ratings are given in the same consecutive
C0z-Carbon dioxide gas stored in cylinders. It may be ap-
[; order as those given in columns II, III and IV of Table II of the Na-
plied through a fixed or semi-fixed system, or from a
tional Academy of Sciences (NAS) Publication 1465 (1973 Revision).
portable extinguisher. It is useful for inerting a com-
partment or for putting out small local fires.
Dry chemical-Sodium or potassium bicarbonate or monosodi-
fl The first rating deals with the hazard presented by ..irritating
vapors" to the skin or to the mucous membranes of the eyes, nose,
um phosphate powder, usually available from a semi- throat, and lungs. These ratings have the following meanings:
flrxed or portable extinguisher.
[; 0 Chemicals that are nonvolatile, or the vapors from which are
r
ln case of a large-scale chemical hre aboard a vessel, it is proba- nonirritating to the eyes and throat.
ble that water will be the medium used because of its availabil- I Chemicals that cause a slight smarting of the eyes or respiratory
ity. Other agents may by more effective, but their supply is nec- system if present in high concentrations. This effect is tempo-
essarily limited. During such a frre, water should also be used to rary.
cool tanks of chemicals which are not burning in order to pre-
vent explosion or tank rupture. The only case in which water l*r 2 Chemical vapors that cause moderate irritation, such that
would not be used is that of a burning chemical which reacts personnel will find high concentrations unpleasant. The effect is
xll
t-l temporary.
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SCANNED BY MKP & BARIS A. 2004 rt
3 Moderately irritating volatile chemicals, such that personnel will
not usually tolerate moderate or high vapor concentrations.
n National Technical Information Service (NTIS)
Telephone: 703-487 -46m
n
4 Severe eye or throat irritants, vapors are capable of causing eye U.S. Department of Commerce
or lung injury, and cannot be tolerated even at low concentra- 5285 Port Royal Road
tions. Springfreld, VA 22161
The second rating deals with the hazard of "irritation from liquids Odor Threshold:
or solids" with regard to a chemical's tendency to burn or irritate {*' The smallest concentration, expressed in parts per million (ppm)
human skin from contact. Ratings have the following meanings: by volume in air that can be detected by smell by most people.
This is not an absolute value. It will vary among individuals and
0 No appreciable hazard. These chemicals are practically harmless [-*r
l l will vary from day to day for any one person. The odor of a
to the skin. Included are certain very volatile compounds that
potentially dangerous vapor may be hidden by another odor. In
evaporate quickly from the skin.
r addition, certain vapors are likely to produce olfactory fatigue,
I Minimum hazard. Usually includes chemicals which, if spilled on l r which is deadening of the sense of smell. For these reasons, the
clothing and allowed to remain, will cause smarting and redden- sense of smell alone is not a reliable indicator of the presence or
ing of the skin. absence of a dangerous vapor.
2 Chemicals that cause smarting of the skin and first-degree burns

I , Permissible Exposure Limits (PEL); Threshold Limit Val. (TLV):
on long exposure. The Permissible Exposure Limit and the Threshold Limit Value
refer to an airborne concentration of a product expressed in parts
3 Fairly severe skin irritants, usually causing pain and second- I per million (pp-) by volume in air. These are the Time-Weight-
degree burns after a few minutes' contact. ed Average (TWA) concentrations believed to be safe for the
average person during an 8-hour workday and 4O-hour work-
4 Severe skin irritants, causing second and third-degree burns on
short contact and very injurious to the eyes.
I week for prolonged periods. The susceptibility of individuals will
vary.
The third rating deals with the hazard presented due to "chemical
poisons" entering the body through inhalation, oral ingestion, or skin
r
t ' The values listed are those assigned by the Occupational Safety
penetration causing bodily harm. Ratings have the following meanings: and Health Administration (OSHA) in Title 29 of the Code of
I
Federal Regulations Part 1910.1000,et. al. (29 CFR 1910.1000),
0 No likelihood of producing injury. I and those accepted by the American Conference of Governmen-
I Minimum hazard. Includes most chemicals having threshold tal Industrial Hygienists (ACGIH) as published in Threshold
limits above 500 ppm. Limit Values and Biological Exposure Indices for 1989-1990. In all
I cases, these values should NOT be used to compare the relative
2 Some hazard, typically having threshold limits of 100 to 500 toxicities of different materials.
ppm.
3 Moderately hazardous chemicals. I The equilibrium concentration of a gas which can be produced
by a liquid can be calculated as follows:
4 Severely hazardous chemicals usually having threshold limits
below l0 ppm. r conc. (ppm) : vapor pressure in mm Hg X 1300.
NAS Publication 1465 (1973 Revision) may be consulted for more
detailed information on the guidelines employed in rating each class of
hazard. This publication may be obtained as AD 775756:
r* "Skin"-the
notation used to indicate that the product can be ab-
sorbed through the skin, including mucous membranes and eyes.
Prevent or reduce exposure to the extent necessary in the cir-
xiv
r
SCANNED BY MKP & BARIS A. 2004 il;
Spill or Leak
cumstances through the use of gloves, coveralls, goggles, or I-l
I t The information given is intended to be used only as
other appropriate personal protective equipment, engineering
controls or work practices. Many factors must be considered before deciding on a course r
in a particular case'
Short Exposure Tolerance: I-:
Vapor concentration, expressed as parts per million (ppm) by Remarks
volume in air, which should not be exceeded for the expo-sure Some special regulations which apply are listed. Other infi
[l
times specified. Other exposure information obtained from I i of particulai importance is also listed.
sources believed to be reliable is included. In many cases little or
no data on human exposureare available
tJ
Exposure Procedures:
First aid procedures recommended by manufacturers and safety ft
organizations. These are emergency procedures only. The victim I I
should be examined by a physician as soon as possible.
Poisons: t-i
Some products are classifiedfor regulatory purposesas poison-
ous liquids. Definitions are given in 49 CFR Part 173, Subpart
D I
l l
Reactivity Data
Stability: ' '

[*-li
The susceptibility of the products to dangerous reactions when
exposed to conditions such as high temperature and shock.
[--'--t,
Compatibility: l l t
Structural materials compatible with the cargo are listed; also,
structural materials, contaminants and other cargoes which react I i
I l' :
dangerously with the commodity are given. This list is by no
means complete or all inclusive. In some cases a very small
quantity of material can act as a catalyst and produce violent re- |I [Ir
actions such as polymerization, dissociation and condensation.
These catalysts, when known, are also listed.
l--,
The accidental mixing of one chemical group with another |
|
can in some casesbe expected to result in a vigorous and hazard n'
ous chemical reaction. The generation of toxic gases, the heating, I'
'l
overflow, and rupture of cargo tanks, and frre explosion are pos- ]
I
sible consequencesof such reactions.
The purpose of the Compatibility Chart, which is fully ex- l-rr
plained the 46 CFR 150 is to show chemical combinations be- I f
lieved to be dangerously reactive in the case of accidental
mixing.
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CHRIS
CHEMICAL HAZARDS RESPONSE INFORMATION SYSTEM t-l MANUAL 1 COMDTINST MI6465.IIA A CONDENSED GUIDE
TO CHEMICAL HAZARDS
CONTENTS order number: O5O-O12-00224-O
The Chemical Hazards Response lnformation System (CHRIS) it rT 5l-l
BINDER order number:050-012-001
an officirrl publication of the U.S. Coast Guard. It consists of the fol'
I I
MANUAL 2 COMDTINST MI6465.12A HAZARDOUS CHEMICAL
lowing manuals: DATA
MANUAL I COMDTINST M16465.IIA A CONDENSED GUIDE
TO CHEMICAL HAZARDS
t-l CONTENTS order number:050-012-00215-l
Intentled for use by response personnel who may be the ftrst tc T-l
arrive at the site of an accidental discharge or hre to assesstht l l
dangers and consider the appropriate large-scale response neces
sary to safeguard life and property (contains I100 chemicals).
MANUAL 2 COMDTINST M16465.12A HAZARDOUS CHEMICAI t-l

DATA
This manual is the cornerstone of CHRIS. It lists the specifi< nl
chemical, physical and biological data for about 1100 chemicalr l
needed for the preparation and use of other components of thr
system. It is intended for use primarily by the On-Scene Coordi
nator (OSC) and by regional and National Response Centers fo. t-l
devising, evaluating and carrying out responseplans.
NOTE: Coast Guard offices can obtain CHRIS manuals at no cos

t'-t
l {
through the directives system. All others must purchase the manual
from the Government Printing Office. Please confirm availability ant
price with GPO before placing your order. (Use order numbers to iden
tify Manuals to GPO).
n
ORDER FROM: Superintendent Of Documents
Government Printing Office l--l
Washington, DC. 20402
(2O2) 783-3238
l {
ADDITIONALINFORMATION: Commandant(G-MER-2)
U.S. CoastGuard
21002nd Street.S.W.
Washington,DC. 20593-0001
(202) 267-O44O
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SCANNED BY MKP & BARIS A. 2004 t-t
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I CtrcmlcelDrtr Sheetr t-t
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n LOCATION
NATIONAL RESPONSECENTER
f--r U.S. Coast Guard Headquarters, Washington, D.C. 20593.

t l HOURS OF OPERATION
n
24 hours a day:7 days a week.
PERSONNEL
Staffed by Coast Guard Ofhcers trained in the methods and pro-
cedures of Pollution Response.
f1 FUNCTION
n
To received notification of actural or potential oil hazardous
chemical incidents and relay these reports to proper authorities
for responseactions.
CAPABILITIES
t-l A toll free number (800-424-3802) for receiving reports of pollu-
tion incidents within the Continential U.S. from any phone in the
n Continential U.S. (In Washington, D.C. area call (202) 426-

2675.)
ri Continuously manned Communications Center.
Access to environmental and safety information on chemicals.
n Contact points with other Government Agencies for access to

responseto pollution emergencies.
t-t xxi
I
SCANNED BY MKP & BARIS A. 2004 t- MOST COII'MONLY USED CHEMICAL NAME
Synonymr- Other chemical names by which known
Fornula-Simolitied structural lormula

Boiling Polrt....... at 14.7 psi -'C _'F
ADp€arance.Odd- _'F -'c
_'F
F r e e z i n gP o l n t - . . . . . . . . . . . . . . , . . . . . . .
Specific Gmvity-Waler:1.0 _'F
VaporPressure 20'C (68'F)(mhHO..........
C'hemical Fsmily-
Reid vspor Prsure (psia).
Valnr Pressure46"C (115'F) (Dsis)
Pollution CateSory-USEPA - IMO - VaporDensity(Air : 1.0)..............
Applicrble Bulk Reg. 46 CFR Subchspter
FIRE & EXPLOSION HAZARD DATA

Grade-The classificationassigned to liquids which burn, as shown in 46 CFR 30.10-15 and 46 CFR 30.'10-22.
Elctrical Group-Assigned by Elsctrical Hazards Pan€l; NA means "not applicable" if the flash point is above
150'F
Generrl-Unusual tire or explosion hazards andlor special conditionsgoverning the hazard will be mentioned
here.
FlashPoint CFr.............................
Open cup unlessothemise noted.
Fhmmrbl€Limits..........................
LEL and UEL.
AutoignitiorTemp.('F)................The temperatureat whichthe vapor will catch fire.
ExtirguishinSAgenis.....................
Suitableagentsare lisled.
SDecialFire Prcedurs................ lf water is unsuitableor dangerouslo us€, or it special protectiveequipment is
nseded. m€nlion will b€ made here.
r-
I HEALTH HAZARD DATA
Health Hu.d RqtirSr Odoi Thr6hold (ppm) PEL,/TWA (ppn) TLV^WA Opn)
Getrersl-General and specific statemenls about the hazards to health from exposure lo the chemical.
Symptomc-The mosl common snstions felt by the appeararce ol a p€rson €xposed to the producl.
{-
I Short Erlbsure Tolerrnce-The vapor concentration and exposuretimes known o. reported to cause etfects in
humanbeingswill be givenif available.
ExposurePreedures-First aid measures to be taken immediately.THIS DOES NOT REPLACEMEDICAL

ATTENTION BY A PHYSICIAN!Any time a person has experiencedrespiratorydistress or has come into
contact wilh a co(rosiveor blisteringagent, proper medical attenlion must be given.
REACTIVITY DATA
Strbility-The stabilityol the product and its likelihood ol undergoingdangerous reactions under special
condilions.
Comprtibility-Msterial: In general,the substanceswith which the product could react dangerously.This

includes materialsof construction,impuritiesand other cargoes.
t-
I Crrgo: The group number assigned by the compatibilitychart is indicated here.
SPILL OR LEAK PROCEDURE

Oescriptionol the immediatesteps to b€ taken should the material be released inlo the air, onto the vessel's
slruclure or into the water.
If a spill mcurs, call the National ResDons C€nter, E00-424-8t02.
Remarks: Any special factors and/or qualiiying information will be mentioned here.
'760
mm: 14.7 psi
KEy NOTES
V. Low : Very low : Greater than
V. High : Vsry high = Less than
NP : Not pertinent = Approximate(ly)
Synonyms-Acelic
ACETALDEHYDE
ald€hydei Aldehyde; Ethanal; Ethyl United NrtioN Nunbcr.......................,.,,,,,
g
n SyronyeAcetic
ACETICACID(Glaclall
acid glacial; Elhanoc aod; GlacLl Urltrd Nrtloor tf16bc1. .10%-80%
Glacial, >80%
3!EI-
jA99-
r']
aldehyde
acatic acid; Methane carboxylic acid; Vinagar rcid
_lap_
FomuII-CHTCOOH
r
Fornula-CHTCHO
21'C 70't BoffhjPolrt.-,.,.................,..
-119'C 245'F
Boiling Point..........................
ADperrance-Odor-Colodessliquid;pungent suflocating liqukJ; Fr{oil vinagar.lltc -t
odori fruity odor when diluted. FrezirsPoitrt.........-121:E :ti ooor h,rrr por.r...........
.. ...... z:3 -r-:F
SpecificGrrvity-0.78 SpecitlcGnvlty-'1.05 _'c _'F
a)'C (6c'D (nnHr).......... lljl-
r
Vapor Pressure 20'C (68'F) (nnHg) 7,55 Vrpr Pmn
Chedicsl Family-Aldehyde Ctcrlcrl Fully-Organic add Rcld Vr;r Puure (pdr),,...................... 0.60
Reid Vrpor Pressure (psir)................ 15.!- VrDorhnrc a5'C (llS'D (gch)............. 0.92
VaporPressure 46'C (ff5'F) (poie)............. -l9O- Pollutlon CracSory-USEPA D tUO D
PollutionCstegory-USnPl G IMO C V i l n r D e n s i t y( A i r : 1 , 0 ) . . . . . . . . . . . . . . . . . . . . .1. . 5
. .2.
VOr'DorD.rlty (Alr = 1.0)...,................,......
2.O7
ApplicsbleBulk Reg.,16CFR Subchapter...... O Comoleto Appllcrble Bulk Rca rl5 CFR SubchrDtcr..... O So|lblllty In Wrter Comol€le
Solubility in Water
cr.dFA: Flammabl€liquit
Elstrical GroulFC
Ger€nl-Produces irritatingvapor when heated. lf pressure is used to unload tank, nitrogen or other inert gas
r Grrde-O: Combustibl€ liquil
Elsdcd Group-D
Crnerd-lgnited
by h€ai and by som€ oxidizing agents. Vapo{ may explode if ignited in an €nclos€d area.
must b€ used. Air pressure may cause explosiveperoxidss to form. Flashbackalong vapor trail may occur.
Vapor may explode il igniled in an anclosed area.
l l s h P o i n t( ' F ) . . . . . . . . . . . . . . . . . . . . .-.3. .6. . .(.c. c )
Ffsmmsble Limits...............-...... ... 4.Oto 57o/.
1-l Flsh Polot ('F).............................
110
Flmnrble Linits..........................
5.4 to 16'h al 212"F
AutoiSnition tenp. ('F)................1050
AutoigDition Tenp. ('n................365
ll
Ertir8uisbinS A8ents.....................
CO,, dry chemical, alcohol toam, water fog
ExtinSuishingAgerts COr, dry chemical,alcohol foam, water fog
Sp€cirl Fire Prftedur6................ Use personal protective equipmeni when coniact wilh liquid is likely. Skin or
Sp€cislFire Pr@edures................ Avoid exposure to vapors. Wear self-conlainedbreathing apparatus.U3o
cloihing contact can cause s€rious burns. Wear sell-coniainedbrsathing apparatus.Cool expGed tanks
wator tog on large firss. Use hose sireams at mdimum range to cool exposed tanks. Fight fire from a late
wilh walsr.
distance or trom a Drotectedlocation.
Heilth H.ed Rraings

3, 1,2
Odor Tf,reshold (ppm)
2.3
HEALTH HAZARD DATA
PEL,/TWA (ppm)
100
TLV,/TWA (pDn)
100
r: Hedth H@rd Rrtingr
2, 3, 2
HEALTH HAZARD DATA
Odor Thredold (ppn)
1.0
PELAWA (Dpd
10
TLV/TWA (pDr)
10
Ger€rrl-Suspected carcinogen.Vapor irritating;liquid caus€s skin and eye burns.
SymDtonFBurning ol syes, noss and ttuoal; headache,rapkl heartbeat possiblo drowsiress with prolonged
exposure.
1l Gacrd-Vapor extremelyirritating.Liquid causes s€vgre burns.
of skin in contacl with liquid. lrilation of eyes and respiratorysystam.
Short ExposureTolenncF1100 ppm for 2 hours is severly irritatingto mucous membranes; 'l'1,OOO
hours has been reported as tatal.
ppm lor l-2
t-l Erlcurc Tolcme-4o
ErposEr€Prccdur6-Vapor-rsmov€
ppm tor 5 minules,
victim to fresh air; if breathing stops, apply artificial respiration.Skin or
n
Ex!6ure Pr@edur6-Vapor-remove victim to lresh air; it br€athingstops, apply artilicial respiration.Skin or
eye contact-rsmove conlaminatedclothing and gontly flush affected areas wilh water tor 15 minut6s. G6l
eye contact-remove conlaminatodclothing and gently llush alfecled areas with water lor 15 minut$. Gel
medical attention. Wash contaminatgdclothing, includingshoes, belore reuse.
medical advice or attention.
REACTIVITY DATA
Stsbility-Highly reactive.Can form explosiveperoxidesunder air pr€ssure.Slowly polymerizesto paraldehyde.
Can react vigorouslywith oxidizingmaterials.Explodeswhsn mixod with iodine. n potash) and sodium hydroxide(caustic soda).
REACTIVITY DATA
Strbllity-Can reacl vigorouslywith oxidizingmaterials.Reacts violenlty with potassium hydroxida(caustic
CrmDrtibility-Materid: Highly corrosiv€ to metals when dilule. 316 and 318 siainless steels and aluminum are
n
Compatibllity-Mrtcrldr Negligiblecorrosionto mild steel. May dissolvs rubb€r.
satislactory conslruction materials.
Crrgo: Group 4 ot compaiibilitychart. S€€ also Appendix l.Exceptionsto the Chart.

C$8o: Group 19 of compatibilitychart
SPILL OR LEAX PROCEDURE

ll possibls, w€ar rubber gloves. solf-containedbreathing epparatus and protectivs clothing. Covor |'|lll wrth
n SPILL OR LEAK PROCEDURE
S€cure ignition sources. lf possibls, wear rubb€r glov€s, face shaeld,and protective clolhing. Body shield and
self-contained brsathing apparaius should b€ available. Cover spill with soda ash or sodium bicarbonate. Mix.
r
mdrum brsulfilo(NaHSG). Add small amounl of water and mix. Scoop up. Wesh oite with rorp rolutbn s.crr. and add wat€r it ns€ssary lor mixing. Sc@p up slurry. Wash site with soda ash solution. Flush spills with large
lonilronsourcc!. quanliliss ot wetsr. Usuelly a spill into a navigable wat€ryay would quickly diluts to a harmlessconcontralion lor
numano. If r cpill ccurl cll thc Nrttonrl R6rc Center,&Xt-a2!tt02.
lf I rDlll c.un. c.ll thc N.aldl
Rrub! Below 62'F th€ rcid may lrszo md expend €nough to burst it8 conteinel
r
lcarr|l
-tr:-,
fll*-, --:,jb&il&;
SCANNED BY MKP & BARIS A. 2004 .a*-aid!c.t*r-'*,-". ".,--liirr^*rr&tc,:
ACETICANHYDRIDE
symnyru: Acetic acid anhydrid€; Ac6tb orkte; Acelyl
oxide; Elhanoic anhydrids
Uritcd Nrttor Nunb.r -Jfll-,
-I
11 Synonync- Dimethyl k€tona; Ketone propan€:
betakeio-Propan€:Propenone;2-Propanona;
ACETONE
1090
Urlt d N.t|ou Numbcr................................
Fmulr-(CHTCO)rO
cHRrscodc...........
BoilingPoirt.......................... 140'C
. ac
2la.'l
-
t
n, Pyroacelic sth€l
Fomuh-CHsCOCHT
CHnIS Codc.......... ..... ACT
B o l f l n g P o i n t . . . . . . . . . . . - - . . . , - . . .5. 7. .' .C. ' 1 3 4 " F

App€mce-odor-Colod6s liquid; pur|g€nr, highly --t3:3
iritating odor
Speific GnYlty-1.08
c'hcmlql Fmlly-Add anhydrid€

pot!t.........
Frezins .....
VaDorPresure 20'C (6S'F, (nnHO.......... --LO-
-'c
:m:l
- 'F tl SDcltlc Gnrlty-o.79
liquid; 9w9€ll8hodor
Frszin8 Point
Vrtor Prsure 20"C (5S'F) (nnHS)..........

_'c
............ -95"C
_'c
180
_"F
_'F
-'139'F
Reid Vapor Pressure(pdr).........
rr
Chcnlcd Frnlly-K€lona 7.25
ReidVrpor Presure (Dsis)....................-...-.-
Vapor Pressureil5"C (U5'F) (Fta).......,.,.. 0.4
D O vrpor Pressure 46'C (115'F)OEir)............. 10.0
Pollution Cetcgory-USEPA nVO V a p o r D e n s i t y ( A i r : 1 . 0 ) . . . . . . . . . , . . . . . . . . . . .3. ...5. . . Pollutlon Crtcaory-UsEP^ D ttrtO lll 2.O
VrDorDeEity (Ail : 1.0)...........................
ADDlicsbleBull Reg.4'6CFR Subchapter........ O SolubilityiD wrter......................... l2oloAootecilHa
ADpllc.blcBull Rc8.a6 CfR SubchrDt€r........ D Solubilityin wrter......................... Comol€te
crudFD: Combustibleliouid
Electricel GrouD-D
c€ner8l-Reacls violenlly with water gsneratingdangerous heal and prosgurEin confined spaces. lgnilod by
rt, Grrde-C; Flammabls liquid
Elctrlcel Grout+O
Gene.rl-Highly llammabla. Flashback along vapor trail may occur. Ksp away trom hsat, sparks, and op€n
heat. Vapor may explode if ignited in an enclos€d space.
tl
flame. Vapor may explodo if igniled in an enclosed ar€a.
121 (cc)
Flllh Poilt CD............................. Fl$h Point ('n.............................
15
2.7 lo 1O"h
Flrmmrblc Lfnitt.......................--. Flrnhrble l.lnftr.....-.......--.-.....2.5 lo 12.8"/"
AltoigDitionTenp. CF)................ 734 AutolgrltionTilD. CD,............... 1040
rl
ExtinguisbidgAgent! COr, alcohol foam, watgr fog' or dry chemical. E(lngulshing Agcltt.....................COr, dry chemb!|, alcohol loam, wat€r log
slEirl Fire Prcedurd................ Cool outside ol tanks with water spray. Apply water cautiously.DO NOT SDccl.l Flre Precdus................ Water may be inetloclivs on fire. Cool expoS€dtankg wilh walor. lf waisr is
contaminateanhydridesystem wilh water. Use slt-conlained respiratoryproteclion and prolactive clolhing. used, largo quantiiios must b€ applisd in order to prevent r€-ignition.A solution ot 4oloacetone and 96%
water has 6 llash poinl ol 129'F.
H6lth Hr8d RatirS.

3.3.3 0.14
HEALTH HAZARD DATA
Odor Threhold (ppm)
Gcrenl-Vapor extrsmev iritating. Liquidcauses *vere bums.

PEL/TWA (Dpm)
5
TLVlTlvA
5
(DDr) n Heslth Hsard RrtlDt
1. 0. 0
HEALTH HAZARD DATA
Odor Threshold (ppm)
200 to 4OO
PELlTlryA (ppn)
750
[,V,/TWA (ppm)
75O
Symptons-Coughing; burning sensationin nose and ihroat. S€vere eye and skin burns. Warning ptop€rt€3 aro
good because compound is highly irritating.
tt, Generrl-lrilant lo eyes, nose and throat. Anaesthetic etfects after high concentrationexposures.Prolongedor
rep€ated skin contacl may caus defatting ot the skin and may produce dermatitastrom frequenl daily
contact.
Symptoms-Drowsinossand throat irritation.
Short EtDosureTolerucFLes than 40 ppm lor 5 minutes.
ErD6ure Prcedures-Vapor-remove victim to fresh air; il breathing stops, apply artificial respiraiion.Skin of
eye contacl-remove contaminatsdclothing and gently tlush aflected ar€as with water lor 15 minut$. Gsl
t l ErD6ure Toleme-10,00o
ExposnrePrcedurFvapor-remove
ppm has been roported as sndurable tor 30-60 minutes without symploms.
victim to tresh air; il breathing stops, apply artificialrespiration.Skin ol

eye contact-remove contaminatedclothing and gently flush atlectsd areas with watsr for 15 minutes. Get
medical atlention. medical advice oi attention.
REACTIVITY DATA REACTIVITY DATA

strbillty-Reacts wilh waler to lorm acetic acid and produces considerableheat. Reacis violsntly with
potassiumhydroxide(caustic potash) and sodium hydroxids (causiic soda).
CanDotibluty-Materid: Highly corrosive to iron and stesl whgn moist. Softons many plaslica. Usually stor€d in Will dissolve many plastics and rubb€r.
aluminumor stainless steel tanks.
Cr4o: Group 11 of compatibililychart. Cugo: Group 18 of compatibilitychart. See also Appondix l-Exc€ptions to the Charl.

Wear full-protetive clothing. Body shisld and sslf-coniain€d broaihing apparatus should b€ lvdhblc. S€cuto
sources. It possible covsr spill wilh soda esh or sodium bicarbonale. Mh and rdd walet It nacarssry lo
€fiect good mixing. Scoop up slurry and wash site wiih goda ash solution. Ulullly a lpill Inlo r navlg||blc
t-- SPILL OR LEAK PROCEDURE
lf possible: Wsar rubbsr gloves, lace shiald and protectiveclothing. Have all-purposecanisler mask availabls.
Secure ignition sourcss. Flush spilled acetom away with water. Do not flush inlo conlined spaca such as a
8€wer because ol th6 dangor ot €xplosion.
wataMay would quickly dilule lo a point whera il would pressnt littl€ danger lo humenr.
lf t Dlll ccur, qll lhe N.tlord Ramnr Ccnlcr, UII-a2a-02. Ilr Dflf ccrn, cll thc Nrddl nOC C.!t r, |I'&4,2/-l!'0i2.
l.|rlr: ' AvoL, grtting wds into aoatc lnhydrid. t|'*r. ncn[tr:

ACETONECYANOHYDRIN
Synonymr- alpha-Hydroxyisobutronitrile;
alpha-Hydroryisobutyronitrile;
Usltrd Nd!o- NuD.r...........,..,.,.,..,......,..,
J!tl- r tt-t*
ACETONITRILE
r
llethyl cyanid€
2-Hydroxy-2-methylpropanenitrile;
2-Methylacetonilrile;Propananitrile,
2-hydroxy-2-methyl CHRIS Code........... .,., --ACI-
Fornule-(CHr)zC(OH)CN '"
r
Fmuh-CHTCN
Boiffns poilt..p.esqmpe.eoo..jl30 1',
178'F
8o11hsPoht.......................,..
-el'C
Appeeruce-odor-Colorless to straw colored liquid; -'c -'F
-2'F lhuid: aronlalic odor
almond color Frezins Point...................... -10'C
Speilic GraYity-o.93
't h..dnrPotrt........................--lo:3--:F
SDcnc Gnvlty{.78 _'c _'E
vapor Presure 20'c (68'D,-^"arl-" *
ChemicalFamily-Cyanohydrin 09 VrFr Prsm 110'C(6t'D (DaHO.......... O.5l
ReidVaporPrs[e (Dsir)........................... Ctenlcl Frnlly-Nitile
t-
ReldVrpr Pmc O.02
Orh)...........................
VsporPressure,l6"C (f fs'F) (Dsh)............. 0.4
A 2.9 Vrpor Prow rl6'C (rrS'F) (Fh)............. O.03
Pollutior Crtegory-uSfpl ----A- IMO VtporDensity(Air: 1.0)........................... PolludoD Cdesory-USEPA D lll
IMO l.4l
Vrpor Deldty (AIr : f.0)...........................
ApDlicrbl€Bulk Reg.,15CFR SubchrDter..... Solubilityin watei......................... Comolete ApD||oblc Bu[. ncS. 16 CIIR Subchrpter........ ----Q- Solublllty|nW.tcr......................... Comol€te
GrcdFE: Combustibleliouid
Eletricd GrouD-D
c.nerrl-Gives off llammable and poisonouscyanids gas when h€ated. Vapor may explod€ it ignil€d in an
r Eletrlql
Flmmable liqrid
Greop-D
crd-B€acb
wilh sieam and acids to produco lo)dc and llammable vapors. lgnitod by heat, sparks, or op€n
enclosed area. Dilutionwith waler causes decompositionwith the lormation ol hydrogen cyanide.
F l s h P o i n tC F ) . . . . . . . . . . . . . . . . . . . . . . . . .(. c. .c. ')1 6 5

Flammable Linits....................... ... 2.25 lo 11
t- flam€. Flashback along vapor lrail may 6cur. Vapor may sxplods if ignitsd in en 6nclo$d area.
Fbi Potrt CD.............................

Flumble L|n|tr..........................
42
4./t to 16.0%
r
Autoignition Temp.('F)................ 1270 Autolgildo! TcnD. ('F)................ 975
Extinguishing Agents..................... CO2,alcoholtoam,water fog" Ertiogdrhtrg Asotr CO,, dry chsmical, alcohol toam
Specill Fire Pr@edur6 ................DO NOT USE SODA-ACIDEXTINGUISHER!Cool exposed tanks with walor SD€dd nrc Ppc.drE................ Walsr may b€ in€ft$live. C@l oxposed tanks with water spray. Car€ must b€
Apply water cautiously.D0 NOT contaminatecargo with water. Respiratoryprotection requiredfor taken nol lo oxpos€ fir€ fight€rs to ih€ tum6s of this rnat6rial. Any who must €nter a contaminated
tirefightingpersonnel.Wear tull protective,airtight clothing. atmosphore must b€ provired with r€sparatory proteclion.
Health H@rd Rstirgr

HEALTH HAZARD DATA
Odor Threshold (ppm) PEL,/TWA (ppn) TLVITWA (pDn)
r Haltl Hrand nrdrg
HEALTH HAZARD DATA
Odor Thrqhold OtE) PEVTWA (Dpn) TLV,/TIVA (DpD)
r
1. 2. 4 Unavailable Unavailable Unavailable
t, 1,3 40' 40 4o/skin
ceneol-Vapor very poisonousby inhalation-Liquid poisonousby absorptionthrough the skin. Grade B poison ml-Highly toxic. Can b€ abso.b€d through skin and respiratory tract. Vapor iritaling to eyes, nos6 and
throat. Liquid initating to skin and syss.
synptorHeadache, diziness, nausea;blueness of lips and fingernails.
h€adach€, naus€a, and blu€ne3o ol lips and ling€rneils. Inhalafon will caus€ ditficult
r
breathing
Short Erlqm TolreUnavailable ErDcre TolreBrief o)eosur€ to 5OOppm has producod som€ nos and throat iritalidt.
Exposure Prcedurevapor-remove victim lo fresh air: it breathing stops, apply artificial respiralion. Skin or Etpqrre PnccdeBemov€ victim to lrssh air. Apply artificial rsspiration if h€ stops brea$ing. G€t medical
r
eye conlacl-remove contaminatedclothing and gently tlush alfected areas wilh water fo|ls minuts3.K@p attention. ll lhuid contacts skin, wash oft with plenty ot water..
victim at resl. Get prompt medical attention tor liquid or vapor exposure.Wash contaminatedclothing,
includingshoes, belore reuse
see Medical Kit Intormation,Appendix B
S€€ Medical Kit Inlomlion. ADoondix B

st.bility-Whan heated, decomposeslo lorm cyanide gas. Must be kept slightly aciditied.Dilulion wilh walet
causes decomposiiionwith formation of hydrogen cyanide.
Conp.tibility-M.terirl: Aluminum and stainles sieel are satisfaclory, rubbd will swell.
l- Mild steol and stainlsss st€€l aro comDatible.
Cugo: Group O of compatibilitychart. See also App€ndix l-Exc€ption to ih€ Chatt

r c|180: G;oup 37 of compatibility chart

lf possible,wear long rubber glov6s, self-containedbreathing apparatus,and proletive clolhing. Eliminrto rll
sources of ignition. Evacuat€ p€rsonnel not equippod wilh respiratory protoclion. Do not lluah |Ptll wbta
t- SPILL OR LEAK PROCEDURE
ll po3siu€, w€ar long rubb€r glovss, s€ll-@ntain€d breathing rpperStus, and prol€cdva ob|hhg. Avold
liacl wilh lQuirl. Secure ignilion sourcss. Small spills may b€ walh€d ewey with wlter. May add .roaaa ol
humans or animals may contac.l. litong calcium lrypochlorite soluiion lo spill and $oop up slurry. Walh lito with rcap rctulbn oottbhlne aoma
hypochlorite.
lf I .Dll crn, cll ffc Ndfood npr Ortc' lll.42/Lor.
[" Il I tDil Glr|' oll the Ndlaal ROoc Catr. O.altl{|2.
lcrulr: ' D€compo8€r rt lho boiling poinl. ' NOTE: Odo. ttr.ahold
" Avoid gstllng wtlor inlo cargo lanl, frb b not conab€r.d daqua!. uarnhg of pffid dangrqt W,
onoffa0ona. Hgfi Yqn. aonoanorlc| c.uaa rTld daatr.
.- '- 4- ;;..J1ftt&-*-
SCANNED BY MKP & -,,*..
BARIS A. 2004
*rls..irer;.--;-
ACRYLAMIDESOLUTION,5006
Syronynr- Acrylamidemonomer;Acrylicacid amide: ieu-,
UnitedNrtionr Numbc..................,......,..,.
t"l; Symnym-Acrol€ic acid; Ethylenecarborylic acid:
ACRYLICACID
n
Acrylic amide; Propenamide;2-Propenamide 2-Propenicacid; 2-Prop€noicacid: propenoic ad4
Vinyl formic acid
*r, f,
Fomule-CHz : CHCONH,
n
Formule-GHTCOOH
102'C
BolllngPotrt.......................... 2t3'F 't4 t'c 286"F
Bollltr8 Po|trt.........................
ADDerrrnce-Odor-Colorles liquid;odorl€ss -g:3 ApperrrnccOdor-Colorlsss lhuid; acrid o(b? _'c _'F
Frezingpotnt............... *:F FEzltrg Polnt....................... 8.C 46.F
SpeciticGnrity-l.05 _'c _'F SpcclflcGrarity-1.05 _'c _'F
VaporPrwure20'C(58'D(hmHO,....,.,.. -l V.!pr Prilurc 20'C (6E'F) (nnH3).......... ---3J--
C'hemicalFmlly-Amidee Reid\'aDorPrsure {psia)...................... t C'henlel FMily-Organic acid R e l d V s D o r P r w u r e ( D r i r ) . . . . . . . . . . . . , . , , , . , .O
, . ., 2
. ,'. ,
valDr Prcsure{6'C (115'n (pcir).....,.,..... ---l- V.!or Prwure 45'C (1f5'D (p6ir)............. 0.4
D D
Pollution Cstegory-USEPA IMO
O
Vrpor Denrity(Air : 1.0).............. [-[ Pollution CttGgory-USEPA - fl|lO D VrDorDenrfty(Atr : 1.0)........................... 2.44
ApDlieble Bulk Reg.,t5 CFR Subcbrytcr........ SolubilityinW|tcr......................... Solubl€ ApplicableBulk R€g. 45 CFR Subchsptcr........ O so|ubthtyinwater.....................C . . .o.m o l e l e
G.sdFNon-flammabl6
ElectricalGreup-NA Note: Acrylamid€is not flammable or combustible.lt is shipped dissolvsd in waler (5Ot5
by weight).Acrylamidewill polymerizein lh€ wat€r solulion if h€at€d.
G€nord-Toxic oxides ol nitrogen may be tormed in fire.
n crrd€-D: Combustibloliquid
Eletrical Grou!-O
G€nerrl-Presenls no special tire or explosion huard because of its relatively high flash point and low vapor
Flsh Point('F)...... Non-tlammable

FlmmsbleLimitE..........................
Non-flammable
ft pressure. Poisonousgases may be produced in a tire.
Flsb Poirt CF).............................

Flammsble
130
Linttt..........................
Unavailable
Autoiglition TemD.('F)................ Non-tlammable
ErtlnguirhingA8ents.......,.............
SDeld fire Preedurs................ Wear lull protectiveclothing, selt-contain€dbreathing apparatus.
r AutoignitionTemp.
Extinguishin8Agerts
('D....,..,.,......
835
Water, dry chemical, alcohol foam, CO,
Fire Procedurs................Use ol CO, where it could blanket ihe vaDor sDace of a conlainer is not
recommended.A tire involvinga spill outsid€ of tanks could be extinguishedwith dry chemical.Wear lull
protetive clothing, eye prolection and selt-containedbreathing apparatus.
H6lth H.ed Rrting

0, 1, 3 Unavailable
HEALTH HAZARD DATA
Odor Threshold (pDm) PELITWA (pDn)
0.3 mg/m3/Skin
TLVITIVA (Dta)
0.3 mg/mvskln
n Health Hud
3,3,2
Ratint
HEALTH HAZARD DATA
Odor Thrqhold (ppm)
Unavailable
PEL,/TWA (ppm)
1o/Skin
TLV,/TwA (pDE)
10'
Generd-Vapor irritatingto eyes, nose and throat. Liquid will burn skin and ey€8.
Synpt@Muscular weakmsa, ataxia, inclordinalion, temors, hallucinatons. Attacks cenlral n€r\rous syslom.
fr G€oerd-Acrylic acid, when in contacl with skin or oyes, may result in a burn upon short contact. Vapors may
present an inhalation hazard trom single exposures;irritatingto eyes, nose and throat.
Symptomr-Vapors are capabls of causing definiie skin or eye irritation,nasal irritationand lachrymation.
ErDqure Toleme-Unavailable Short ErpGure Toleruce-o.s ppm
n
Exlnsure Prcedurs-Remove to lresh air. Administerartiticialrespirationor orygen as necessry. Flush 6yaa Exlnsure Prceduro-lf contact with skin or eye occurs, immediatelyflush with plenty ot water for at least 15
with plenty of waler. Remove conlaminatedclothing and sho€s and llush with water. lf swalloyed and minutes. Gel medical anen$on promplly. lmmediatelyramovs contaminat€dclothing and shoes.
conscious,give waler or milk, induce vomiting,

Strbility-Slable with inhibitor (orygen). May polymerizs violently on m€lling. -Polym€rizes readily.Should be inhibited lo insure safety and stability during storage or handling.
ConFtibility-lnc(mpatible with oxidizing agents, r€ducing agenis, acids, bases, and vinyl potymartrton Compstibl[ty-Mrterirl: Severely corrodes iron and stel. Glass, low carbon content stainless stg€l and high
Ir
initialoF. purity aluminumare recomm€ndedlor conlainment in order staled.
Crrgo: Group 10 of compatibilitychart. C$go: Group 4 of compatibilitychart. See also App€ndix l-Exceplions to the Chart.

Cover with inert absorbent or llush with waler. Oo not allow lpill to dry. Werr tull protstlva clothrng.
fl SPILL OR LEAK PROCEDURE
lf possibl€, wear rubb€r gloves, lace shield, protective clolhing. Body shield and self-containod brsathing
86lt-conlain€dbrgathing appa.atus,rubb€r gloves. apparatus should be available. lf possible, cover contaminatod surtaces and spill with largo quaniities ol soda
ash or sodium bicarbonai€. Mix and add water it needed for good mixing. Scoop up slurry. Wash sit€ with 8ods
ash solution.
I rolll 6.uri, ..ll thc Ndoral ItCa. C.nar, lFa|tllilf lf . lDlll acurq cdl the Nrilold Rq!rc Center,
' Vtpor Pr.aarrai 19 mmHg ' Propolod
l-arLr rt 25'C, Rcouk: chanOain TLV to 2 99m, with "Skin" notetion.
I Umv||hbL
SCANNED BY MKP & BARIS A. 2004 jli J;-d -,&r;*;r$ll&r.

gymyeAn; 6)ano€thylene; Prop€nenitilo:
ACRYLONITRILE
tfl
Utr|tedNrdouNuDe.....,..........................
r Synonyr
ADIPONITRILE
1,4-Dicyanobulane:Tetramethylenecyanide ............ 2?96
UDitcdNrtiors Nunber....................
r
2-Propenenitrile;Vinyl cyanide
CfiRIS cod............ .,.. -6!il-
Fomuh-CFLGHCN
r
Fomule-NC(CHr)rCN
BoilfrsPoht..........." " "" -rzr', BoillngPoht.......................... 295"C 563'F
ApgoreOdor-Cdod€s liquid; res€mbl€3 lhat ot :.a liquid; praclically odorloss
o€ach $ed FredlgPotrt........................ -85'C -ljll'F FreezinsPoint.........
.............. 2"3 *'F
Spenc Gmvlty--O.8l _'c - 'e SDelfic Gr.vlty-O.gs _'c _"F
Vepor Prow AfC (6S'D (DDHS)..........-03- Vrpor Prsure 2O'C (5t'F) (nnHs)...,...... Low
Ctcnicd F.Dily-Nitil€ R"ldvrporPreOdr)........................... 3'3 Ctemical Fmily-Nitrile
t-
Low
ReidVaporPrwure (psia)...........,...............
vrpor Prruc l5'C (lfS'D (0fi)............. -L0- Vlpor Pressure '16'C(fl5"D (pdr)............. Low
Pouudoo otrSory-USEPA B IMO B vrDor tcrdty (AL : --L9-
f.0).......................... Pollution Crtegory-USEPA - IMO D Vrpor D€6ity (Air : 1.0)...........................
3.79
Appllcble BulI Rcl ,|6 CFR $bchqtcr........ O Solub||ityhWrter......................... Mod€rate ApDlicrbleBull Re8.{6 CFR Subchrpter...... O Solubilityir W.t€r.... Sliohl
Grrdec: Flammabls lkrui,

Elcctrlql GunD
r Grrde-E: CombustiblElhuid
Electricd CreuD-D
ccrcnl-whon hsatgd lhb matefhl may e\rolve toxic cyanid€ gas, or eplod€, or boih. Flashback aloargYtPor
trail may occur. Firs may caB€ viol€ni rupturs ol tank.
Fluh Potrt CD.............................

Ft@ble Lhtn..........................
32
3.0 to 17.0%
r Gcnerd-On being heated to its flash poinl this material can decompos lo form highly poisonoG cyenide gas.
Vapor may explode il ignited in an enclosed area.
Fluh Point Cn.............................

FlmDrble Linta..........................
199
LEL: 1.0"/.at 200'C
r
Artol8rldotr Tml. CD ................
898 Autoigrition Tenp. ('F)................ Unavailable
Etth8uLutrg Ag6t! @?, dry ch€mical, alcohol foam ErtiD8uirhingA8cntr.....................
COr, dry chemical,alcohol foam or waier tog.
Sletd Flre Pruccdm ................ DO NOT us€ dry ch€mical tor a largo, confined fire. Walal or l@m mly c!1180 Speld Fire ProceduH................Kegp iank cool with a waler spray. Combustionmay produce cyanide gas, so
frothing. Fir6 parlies musl wear respiratory protstion and tull protectivo clothing including rubb€r bootl. tire parties should woar s€ll-coniained breathing apparatus and protective clothing.
Ksp tank cool with water spray.
Halth Hrad Rrdlgr

HEALTH HAZARD DATA
(Xor Thrghold Opr) PELAWA (ppn) TLVAWA (ppn)
r Haltf, Hrdd Rrtint
HEALTH HAZARD DATA
Odor Thr6hold (Dpm) PEL,/TWA (ppn) .ILVITWA (DDn)
r
3. 1. 3 21.6' 29 CFR 1910.1045 2/Skin 1. 1. 3 Unavailable Unavailable Unavailabl€
ccerrl-Suspected carcinogen. Harmful by inhalation and skin absorption. Psnstrat€s l€ather, liquid in thoos G€rerd-Harmful by skin contaci. Gas from fir€ is poisonous if inhalad. Liquid or solid is irilaling to skin arid
mu$s dolayed burm. Contaminatod lsathor sho€s and glovss should bo deslroyed. syss.
symptorEye iribton, hoadache, naus€a, blu€n€ss ol lips ard fngodips. Contacl wilh skin mey al8o cauag SyEptou-Hsadache, nausea; blueness of lips and fingertips.
r
d€rmatrus.
Short ErDow Tolre4oo ppm for 30 minutas. Short Expcure TolemcFunavailabl€
Ertnrue PraedueRsmo!/e victim to tresh air. ll h€ is nol breathing, apply arlificial respiration. Remo\r€ Erl6ure Prc€duG-R€move victim to fresh air. Remove conlaminated clothing. lf brsathing stops, give
contaminat€d clothing and wash ch€mical lrom skin with a gentle llow ol wat€r. G€t medical attan0oal lf
pati€nt is uncon$ioG, administsrvapor ot amyl nitrito.'
Se€ Medical Kit Information.App€ndh B r arlificial respiration.Wash spill trom skin with gentle llow ot water. Get medical attention.
Ses Msdical Kit Informaiion.ADo€ndixB
REACTIVITY DATA
Strbtlty-Vsry reactiv€; may polymsrize explosivsly in ih€ pras€nce ol strong bar€g. Musl b€ inhlbliad to
prwenl polymerizatbn. Polym€rizaton could b€ initiated by visible light.
CmD.dbiltty-Mrterldr Copper and coppsr alloys ar€ attacked and should nof bo u!€d. Altack! dudnum h
r ConFtlblllty-Mrtcrti!
REACTIVITY DATA
Strbllity-Stable up lo temp€raturss n€ar ths tlash point.
Compatiblewith st@|, wood, most rubb€6.

high @ncentrations.
c$Bo: Group 15 of @mpatbility chart. S€€ also App€ndix l-Excaptions to lll. Or.ti
r Crrjo: Group 37 ol compatibilitychart.

It possiblo, woar long rubb€r glovos, s€lt.contained br€athing rppa'ltur, protac{rra dothlrlg. Avold cq||-t
with lhuid. S€cure ignilion sources. Mey add oxco!| ol strong calclrn ttlrpocl||ot|.. rob0on. Sooop up *rry.
l- SPILL OR LEAK PR(rcEDURE
ll pootlbb, werr long tubbd glovor rnd protectivs clothlng. Add an exceaa ol rlrong crlcrum hypochbrto
b tha |plll. Scoop |.p tlutry. W!.h dts of lpill with sorp lolution contrining rom. hypochlo.lla,
Walh Ctr of lpill wtlh loep loluibn cont ining rorn hypochlo.lb.
frrt
lt . .plll aclrr, oll tb Nrtlord
' NOI€: Oabclbb odo. L gr..b. th.n th. TtV. Eryaut b pil.r!.fy (l.rgrq. vft
l- lnrlr:
lf . iplll ftcun, cdl tb Nrtlul n'n C.rt.r, t(X) a:a ir0l
oqut!*.r an sr bftr ha YS. b &boad.
l-:
tl
t - - i r
Synonyrdeylbenzenesulfonic
ACID
ALKYLBENZENESULFONIC
acid; Un-, Do-, Tri-, United Nstiors Number....................
l'; SynonymF Propenol; 1-Propenol-3:1-ProFEn-3-ol;
ALLYL ALCOHOL
1098
r
T€tra-, Penta- or H€xa-; Dodecylbenzenesulfonb +g UnltcdNotlw Nunbcr.........,.............,.......,
lco 2-Propenol;z-Propen-l -ol; Prop€nyl rlcohol; Vint
I carbinol
cHRIs co&........... .... IEILF
c|InIS Cod...........
r
Fomuh-C"Hr,+QHrS031,=16-16y 'C
BolllnS Poht........... -'F Fomuh-GHr : CHCHTOH
BolllngPolnt.......................... 97"C 206'F
ADDcrnnce-Odor-Whiteto yellow liquid;odorlesg -'c 'C - 'F liquid; prmgenl odor --
FrerlnaPoirt,.,...... -'F
SpectftcGrrvity-1.0 to 1.4
't tz9:3 -aoo'F
pornr.,......................
Frezrtrs
vaDorPresure,o'" (*'t, ,t *a) ---i. - Spcclllc Grrvlty-0.85 _'c _'F
VrDor Pmrc 20'C (68'F, (mnHg).......... --lJQ-
t-
Ctcnicrl Fmily-Ackk R e i d V r p o r P r e $ u r e ( p s i s ) . . . . . . . . . . . . . . . . . . . .t . . . . . . . C'hcmicdFully-Substiluted allyl R e l d v q o r h c u c ( F t r ) . . . . . . . . . . . . . . . . . . . . . . . . . . .1 . 0
vaDorPresrure46'C (U5'D (Fh)............. I
Polhtlor Crtegory-USfPl C ruO C VsporDeNity (Air : 1.0)........................... I Vrpor Prcurc rl5'C (tl!'D (061.)............. 1.8
Pouution CrteSory-USEPA B IMO B Vrpor Dculty (Alr : 1.0)........................... 2.0
Applleble Bulk Reg.45 CFR Subcbrpte......... D. O' Solubilityinwrt€r......................... Solublo
ADplicrbleBult Reg 46 CFR Subchrpter........ O Solubi||ty|nWrt3r.........................Comol€le
Crade-E: Combustibleliquid
Electricrl GrouD-NA
r Grade-C: Flammableliouid
Electricd GrouD-C
Generel-Slightly llammable when exposed to heat or llame. lrritatingsuafuricsckl misl may form in lire.
Flammabl€hydrogen gas may be producedon contact with m€tals.
Flsb Point("F).............................
395
F'lmmble Limiis..........................
Autoi8nitionTemp.
Unavailable
('tr)................
Unavailable
r Gcnerrl-Poisonous gases may be produced in a fire. Readily ignit€d by heat, sparks, or op€n flame. Flashback
along vapor trail may occur. Vapor may explode il ignited in an enclosed area.
90 (oc); 70 (cc)
Flsh Point CF).............................
Flammbfc LiEits.,........................
2.5 lo 18"h
AutoignltlonTemp.("D................
l=
ExtirSutuhingAgeDts Alcohol foam, dry chemical, CO, 713
Slrcid Fire Prced|m................ Water may be inetfectiveon fire, ExtinguishingASeDts COz, dry chemical, alcohol foam, waler tog
Sn$isl Fire Prceduc................ Use respiratory,body and eye prolective equipment and clothing. Wat6r may
be insffsctive. Cool oxDosed lanks with wat€r.
Heslth H.ard Rrtin8r

HEALTH HAZARD DATA
Odor Thr6hold (ppm) PELAWA (ppm) TLvAwA (DPD)
r HEALTH HAZARD DATA
r
Unavailable Unavailable Unavailable Unavailabl€ Health Hurd Rrtlr8s Odor Threshold (ppm) PELITIVA Opd TLVITWA (ppm)
3.2.3 2 to 5 2/Skin 2/Skin
Gercrsl-Liquid is irritating to skin and eyos, corrosive.
Genenl-Vapor poienous it inhaled or if skin is exposd. Liquid is poisonous il swallowedor it skin is expos€d,
Vapor extremsly irritating.Lung and eye iniury may be delayed. Liquid causes severe bums. Grade B
symptorlnilation ot eyes and skin. Ingestlon caus€s iritalbn of mouth and slomach, naus€a. Doison.
SymptonFvapor exposure-irritation lo respiratorylracl. Liquid splashed on the skin causes "dop bone
ache" il not remov€d promptly. Disablingirritationand corneal injury to eyes may be delay€d.
Short ErpGure TolcmcFunavailabla
ExposurePrccdreEyes-llush with water lor at least 15 minutes.Skin-llush wiih soap and walor.
l- Short Extpsure Tolerue-1000
toleraled tor 30 minutes.
ppm has been reported as fatal (sxposure time not reported);5 ppm can be
Ingestion-givg largs amount of water.
r ErDosurePrcedurFvapor-Remove victim to tresh air; it breathing stops, apply artificialrespiration.Skin or

eye contact-immediately flmd affected areas gently with water for al least 15 minules; remov€
contaminatsd clothing and shoes at onc€. Keep patienl at rest and under obs€rvationtor 24-48 hrs; eftecls
may be d€layed.Wash contaminatedclothing before reuse, desfoy sho6s. Get medical help.
stlbility-stabb.
REACTIVITY DATA
r Strbility-Chemically stablo
REACTIVITY DATA
r
Attacks metals and giv€s ott tlammabl€ hydrogsn gas.
Swells rubb€r. Nc1 corosive lo steel.
Cargo: Unassignedin compatibilitychart. See also Appendix l-Exceptions to the Chett

Crrgo: Group 15 of compatibilitychart. Se6 d$ Appendix l-Exceptionsto the Chart.
SPILL OR LEAN PROCEDURE

Avoid contact with liouid. Flush with wat€r. rinse with dilut€ sodium ticarbonat€ or soda aah 8olution.Wosr
goggl€s or facs ehi€ld and rubber gloves. S€curo ignilion sourcas.
r SPILL OR LEAK PROCEDURE
lf fnssibls, wear rubb€r gloves, tace shield 8nd protsctivs clothing. Sscurs ignition sources. Us€ respiratory
protection. K€sp unprolectsd p€rsonn€l upwind ol contaminatsd area. Flush spill with wat€r. May absorb very
Cenler. t{10-rl2l-01.
' a'li or le$ is ragulrled by Subclrrpler O; orar 4% is rogulatad by Subcluptl O.
l- small spills wilh absorbent matsrial (sand, elc.).
It r |lilll ccur, c.ll lhc Nrtiond RtDoI Cerler, 8u}-42i4-8t02.
r
llrrlr:
I Unrvtlrbla lrhr
I Urraaalgnad.
t2
SCANNED BY MKP & BARIS A. 2004 It
ALLYL CHLORIDE
A MI NOETHYLETHANOLAM INE
stutl- Chlqsllylsno; 1-Chloro-2-prop€ne; Unltcd Nrtiou Nubcr................................
l1g0-
3-Chloropropono;3.Chloro-1-prop€ne; lltut*- .' ll. 'r,'i,','tl,yl)amhol.rlhrnol,
3.chloropro9yl.no; elpha-chloropropylan€ N {Amil , ,ilrno.
Fomule--GHz = CHCHTCI
45'C 113'F
t- N (? Ail
llvtforr
r{mrnc,
rlno.
N B l l y ( ! r , . r , , r f, y , l r i y , n r ( r t l m t m :
N Hydforyotltyl 1,? rrlhylonodtrmina
BollirgPoltrt.......................... lm0L-NH'(;H'CH'NHCH'CHTOH
Atcume-odor-Clear to strawberry colored liquit; BoillngPoint...............-.-.-....-. 243'C 469'F
swegtish odor
SDcfic Grrvlty-O.94
s o 1 n t . . . ...........
FrezinP 134'3
_'c _'F
vrpor Prcure 20'c (68"F)(mmHg)..........-394.3-
-r*:F
l-l A;rrmo-(xlrr-Claar,
tmmonrcal odot
Sr(tnc (;..vlty-1.03
cddLa lrquid with mild
Frcezin8Point..............
_'c
-78'C
_'F
-f Og'f
CAcnlol Fully-Substituled allyl Reid Vapor Prsure (Diir)......................... Vapor Pressure20"C (68"D (nmHg).......... ---tQ!L-
O-1..1 lully-Amlna (psis)....................,...... Low
vtpor Prsurc 46'C (115"F)1p6i4............. l0.6 Reid VsDorPressure
Polluttor CrteSory-USEPA C nUO
ADplloble Bulk Re8.,t6 CFR Subchapter........
B
O Solubilityirwster.................--.... O.sv"
2'U
VaporD€nsity(Alr : 1.0).....,.,.,.................
I-l Pollutlon qt
Artllc.bt.
afy-USEPA - IUO ---Q-
Brll RGf; a6 CFR SubchrDter. . . O
Vapor Prwure 46"C (1f5'F) (psis).............---t@-
V a p o r D c n s i t y ( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .3. . 5
SolubilityinWat€r........,................Comolele
. .9. .
Grrde-B: Flammableliouid
Electriol GrouD-D
Generd-Corrosive hydrogen chloride gas lormed upon combusiion.Becomes morg reactive and corosive
r Grrdc-E; Combusliblelhuid
ElcHcd Grcup-C
when wet. lgnited by heat, sparks or op€n flame. Flashbackalong vapor trail may @cur. Vapor may explode Gcn.rd-No smoking or open lights.
if ignited in an enclos€d area.
-20 (cc)
Flsh PoiDtCF).............................
FlammrbleLimit!..........................
3.3 to 11.9%
l- Flrh Polnt ('D.............................
275
Flrnnrblc Lfnltr..........................
15.Olo 27.O"/"
Autoignition Tenp. ('F)................
737
ExtinguirhingAgent!....-.......-......CO,, dry chemical,alcohol foam. AutolgtrltlorToDD.('F)................ 695
Fire Pr4cd|E.......,........ Water may be inetf€ctiv€on tire. Cool expos€d tanks with waier spray ExtltrgulrhbS A8crtr.....................
Carbon dioxide, dry chemical or alcohol toam
Firefightingp€rsonnelshould be protected against hydrochloricacid tumes by wearing sell-containod
breathingapparatusand full protectiveclothing.
[-l Stecld Flre Prcedw....---..-.. Cml exposed tanks with watsr. Walor or loam may cause frothing,
Health Hsard Rrtitrgr

3. 2. 3
HEALTH HAZARD DATA
(Xor Thrghold (DDm)
above 1
PELAWA (ppD)
'l
TLvlTwA (Dpm)
1
l-: Hedti Hr4d Rrtlrg
HEALTH HAZARD DATA
Odor Thr6hold (ppn) PEL,/TWA (ppn) TLV,/TWA (pDD)
1.3. I Unavailable Unavailable Unavailable
t-
cenerll-Suspected carcinogen.Poisnous if inhaled, if swallowed,or if skin is expo*d. Vapor extremely
irritating.Liquid causes burns. Grade B poison. Gctrcrd-Caus€s s€vsrs gye iritation.
symptorvapors are irritatingto eyes and respiratorytract. The liquid irritales lhe skin.
SymptomFLiquid caus€s skin irritationwilh possibilityof burns or prolongod contact. Vapor causss mild
respiratoryirrilation.
f-r
short E{m Tolcmelnhalation of 100 ppm lor 60 minulss has b€€n reported as fal..
Short Erluure Toleruce-Unavailablo
ExDorrrePrccdurvapor-removs viclim to tresh air. ll br€athingis ditficult, administoroxygen; it breathing

stops, apply artificialrespiration.Skin or eye contact-remove contaminatedclothing and gently flush ExDorurePrcedure-ln cas ol eye coniact, immediatelytlush €yes with plenty ot low-prsssur€water for 15
t-
affected areas with waler lor 15 minules. Get medical helo. minutes. lf discomtortp€rsists or r€appears,s a physician.
REACTIVITY DATA
REACTIVITY DATA
l-'
Strbil|ty-Chemi€lly stable.
conDatibillty-Msterid: Highly corosive to stsl and aluminum. Nickel and monal ar€ $itabl€ matetials of
construction. Incompatibl€ with copp€r, copper alloys, aluminum and zlnc,
crrSo: Group 15 of campalibilitychart.

[- Cslor Group 8 ot compatibilitychart.

Waat rubbor glost, s€ll-coniained br€athing apparatus and prolsctivs clothing. Avoid contact wilh liquid
Saoiaa lgnltlon surco!. Do not llush spill into continsd spac€s wh€re flammablevapors can accumulat€.
rl Avodconrrctw,rhriqud, *":",.:t;:;t"#rl*T:1rt"::"- pror.criy. coy.r.Fil
crorhhg,
r
frt aodlm ba|tjfna. Sp.ay wllh walj and wrah away with hrla arcerr ol wlter.
llr olll Gn 6ll $. N.tlod Rru Crntc. nF42SO2.

lf r Jll ,rcurr. cdl rh( Ndcd n .rc ( .nt!r. flt-a,|-lttt.
l-dx
' l-ir I tn-F.d
la a
l-
It
".,-SCANNED BY MKP & BARIS A. 2004
t
*- .s^ *itBa*.*rr4i[ &JiI&*a-,$.iIla
AMMONIA,ANHYDROUS ll Synonyms-Ammonia, aqueous; Ammonia watsr;
AMMONIASOLUTIONS
UBftcd Nrtions l\q6[s1. 10-35o/o 2672
n
Synonyms-Ammonia; Ammonia gas; ruN; Liquid Unlted Nrtlo[ Number..,,..,..,...,.,.,,.,,...,...,..l0Ol Ammonium hydroxide;Aqua ammonia; Household 35-500/0 2073
ammonia ammonia: SDiritol Hartshorn 5ooloor more 1005
CHRIS Cod...........
Formuh-NHTOH
rl
Fomub-Nfb Bolllrs Polnt.......................... -y.g[igg'C Varies"F
BoilingPoint.......................... -33'C 28'F
AppeerueOdor-Colorless liquid; pungont odof -vartes:3
App€.r.nce-Odor-Colorlessliquid ot gas; pungent, Frcztns potnt.......... ............. "**:F
highly irritatingodor Frezir8Polnt.......... -7s"3 ::F
SpecificGr!rlty-o.88 at 20'C (liquid) _'c _'E
SD€citicGrsvity-0.77 al 0"C _'c _'F
n
Vrpor Presurem'C (6t'D (mmHd.......... Vari€s
Vtpor Piessure20'C (6E'D (nnHd.......... 6477 Cl|emicsl Fsmily-Amine ReldVaporPruurc (pdr)........................... Vari€s
ChemicrlFamily-Ammonia ReidVsporPresure(psi8)...........................21 1.9
Vilpr Prcasu.e 46'C (lf5'n (psh).........,.,.Vari€s
vapor Presure 46'C (lfs'D (psta)............. -2€8,0- Pollution Crtegory-USEPA C IMO C V q p r D e n s i t y ( A l r = 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .1. ...2. 1
B 0.588 ..
Pollution Cstegory-USnpt IMo ----gilg- VsDorDensity(Air : 1.0)........................... ApplicableBulk Reg.,16CFR SubchsDtcr....... O Solubllliyinwster......................... Comolet€
ApplicableBulk Reg.116CFR SubchaDter........ O Solubilityin wrter.........................Aotreciabls

crrde-Liouetied ComDressedGas (LCG)
Electricd GrouD-O
tl Electrical GrouF-D
Vapors are capabls of lorming an explosivemixture in air.

Generd-Fire hazard when in high concentrationsand at high temperature.Oil or other combusliblevapors
increasethe fire hazard.
Ftsh Point ('F).............................
conditionslikely to be encounlered.
Indefinite,below32'F (sometimesditficultto ignite).Nol flammableunder
l-l Flsh Point ('F)............................. Varies
n
F l a m m r b l e L i n t t s . . . . . . . . . . . . . . . . . . . . . . . . . .t' ol 6 2 5 %
16 to 25%
Flmmrble Limits.......................... Autoignition Temp. ('D...,............ 1204
AuloignitionTcmp.('F)...,.,..........'l204 Extinguishing Agerts.....................Water log
Stop the flow ot gas (lighter than air); cool tanks wilh water spGy.
ExtinguishingA8ents..................... Fire Prcedure8................Due to the toxic and irritating nature of ammonia vapors, tull respiratory
Speiol Fire Prcedurc,...,........... Use respiratoryand body protection whan approaching protection must be provided for tirolighiers. Cool exposed ianks with wat€r. Water tog will reduc€ vapor
ammonia-contaminatedalmosphere.Lib€ral use ot water tog, where possible,will reduce vapor concenlraiion.
concentration.
Heslth Hrryd Rrtings

HEALTH HAZARD DATA
Odor Threshold (ppm) PELITWA (ppE) TLVAWA (ppn)
n Hedth Hrard nrtings
2,2,2
Odor Thrahold (ppn)
approx.50
HEALTH HAZARD DATA
PEL,/TWA (ppn)
Unavailable
TLVAwA (Dpm)
Unavailable
4,2,2 approx.50 Unavailabl€
Vapor extrem€ly irritating.Liquid causes burns; will caus frostbite.
25
Ti eliremoly irritating.Liquid causes burns.
varies from mild d€rmatitisto s€vere burns and skin destruclion_Vapor: buming ol the €yes,
SynDtoms-Coughing;burning sensation,eye irrilation or pain. Frozen areas turn whilo.
Short ExD6ure Toleruce-A 2500 ppm (0.25%) concentrationot ammonia in air may b€ latal within 30 minutes.
ExposurePr@edur6-Remove victim to fresh air. Call a physicianat once. ll not breathing, apply artilicial
respiration,orygen. lf breathing is ditficull,administerorygen. Flush aflected areas ol body wilh plenty of
n skin irrilation,swellingol eyelids and lips, coughing.
rt ExposureTolerucF4oo ppm causes throat irritation& 700 ppm causes eye irritation,both with no
serious results for exposure less than one hour; 1720 ppm causes convulsivecoughing for oxposur€ l€ss
than half an hour.
n
ExposurePrcedurc-lnhalation: remove victim to tresh air; il br€athing stops apply artiticial rsspiration;
water tor 15 minutes.DO NOT FLUSH FROZEN AREAS. lf the liquid has spilled onto the skin, points ot administer 100o/oOr. Skin contacl: remove contaminaledclolhing; wash with cool H:O followed by l6mon
contact may be frostbitten;handle gently and protect lrom mschanicaldamage. DO NOT RUB. Removs juice, vinegar, ot 25"/oacelic acid; follow with more water.
contaminatedclothing and shoes. Get prompi medical atlenlion. Low-velocitylog is effective tor
decontaminatingthe atmosphere-
REACTIVITY DATA
REACTIVITY DATA Ammonia,anhydroul
Stsbility-Normally stable. Reacts with acidic materials.
r Corroalva lo gtrlvanlrad lJrLoar, coppar, copp.r alloyr and alunrlnjm rlbya.

Crnpstibility-Mrterial: Corrosiveto galvanizedsurtaces,copper and copper alloys. lron and steel at€ guitable
for the constructionof coniainers,fittings and piping. Forms sxplosivs compounds wilh mercury.
('rF: Grilp 6 ol cong.ttrltty chr.l,
Corgo: Group 6 ol compatibilitychart.
sPlr.r.on t,l:Ar Pn(x']:trt,ta],

Saa. Ammon|., anhtdoi,t
Evacuate area in cas6 ol laJgo leaks or tank ruptur€. Shut otf l€ak il withoul ri8k. Worr sll-conlrln d
brsathing apparatus.ll necessary to ent€r spill erea, weSJlull proteliv€ clothangincluding boot8. Wttor rptry rl
sxtremsly €tloctive in absorbing ammonia gas and should b€ uaod around loaks ol gar only, OO NOI PUI
WATERON LIOUIDAMMONIA.
lt | .Dlll ccun. cdl ibc Nralond naDn. (tntc.. e)ar.-lrl.
tl lrub
lf . iall E.rr. r.ll tL \dH l* EaraaL
lrulr:
l l
rt
SCANNED BY MKP & BARIS A. 2004 dxt iffi; i'!!&r44itu.dii-:
AMMONIUMSULFIDESOLUTION,45olo
SynonyhhAmmonium monosullidesoluiion;
Diammoniumsulfids solution
2683
UnitedNationsNrmb€r................................
I tyn,'a1*
leo-AMYLACETATE
Anll aoaLlal aac.Amy' rcotale: Amylacslic
r,,r, Binrn! ol; laoanv rcal,ate; lsoamyl
llllt-
United Nrtlons Nunbcr...............................
"il,im!.. ltopanM aca||L; 3.Mothyl-1-buianol

rc.trlat 2 Mothylbutylolhrnoll€; P€ar oil
CHRIS Cod€........... .... ASS ___lat_
CHRIS Coda..........
Fomuh-(NHr)zS FaI|._CH,@O(CF'LhCH(CHJ),
BoilingPoirt'........................
-39:LOO'" roO*rr',
BolllnsPollt.......................... 149'C -3gq'F
Apperuce-Odor-Greenish to reddishyellow solution; -'c - 'F AtF uc.-(Xo.-Colodaaa lhuid; pleasanl fruiv,
slrong ammonia, hydrogen sullide (rotten eggs) FreeringPoint........................ -18'C 0'F
banrne-lika odof FreziDg Point........................ --.:Z,q'C -=-94'F
odor -'F tt-{lt Gnrlt'{.88 -'c -'F
SD€clficGrrrity-0.993 ai 60'F vr'or pr*sure 20.c (68'D ,r*--" VaDorPresure 20"C (68"F)(nnHg).......... -1,!--
r
Ctcnicsl Fuily-Caustics 22.7
ReidVaporPre$uc (p6ir)........................... (l-lc.l F.dly-Eslor R e i d V r p o r P r e s u r e ( F i r ) . . . . . . . . . . . . . . . . . . . . .0. ...1. .
VrporPrasure,l6"C(115'F)(Isir).............26.5 vrDor Pr6sure 46'C (f15"F)(p.h)............. 0.3/t
PollutionCrtego.y-USEPA B IMO B r
Vrpor D€Nity (Air : 1.0)........................... Pollutla Crt aory-USEPA D rUO C 4.5
VlDorDensity(Air : 1.0)............,..............
ADplicrbleBdl( Reg.45 CFR SrbchrDter........ O Solubllltyinwoter......................... Comolets Appllc.blc Bult RcA.r|6 CFR Subchrpter........ D. O SolubilityinWrter......................... Slioht
FIRE & EXPLOSION HAZARD DATA FIRE & EXPLOSION HAZARD DATA
Grrde-A: Flammableliquid Gnd+D: Combustiblsliquid
Electricd CrouF-D Eletrlql GruD-D
cenerd-Toxic sullur oxides produced in the. Liquid solution gives olt ammonia and/or hydrogen sultide gas C€ncr.l-No smoking or open llames. Flashback along vapor trail may occur. Vapor may explode if ignited in
dop€ndingon ths pH; vapor evolutionrate increaseswhen heated. Flashback along vapor trial may oecur. an enclosed space. Precautions should be taken to prsvonl th€ accumulation ol static slectricity.
Vapor may explode in an enclos€d area.
71.6 (cc)
Flsh PointCF)............................. Fl$b Polnt Ctr).............................
100
FlMmble Limib..........................
4.3 to 46% as hydrogensulfide Ilmn.ble Linit3..........................
1.1 lo 7.5%
ArtoiSDitionTemp.('F)................
Unavailable Autol8nitionTemD.('F)................714
Ertin8utuhingA8eDts......--...........
Water spray, foam, dry chemical,catbon dioxide ExtlnguirhingAg€nti CO,, dry chsmical, alcohol loam, waler tog
SDecirlFire Prmeduro................Wear eye protection,prolective clolhing and self{onisined brealhing Specld Flre Praedrc................ Wat€r may b€ inetfectiv€.
appararus.
HEALTH HAZARD DATA HEALTH HAZARD DATA

Hedth Hred Rsting Odor Thrdbold (ppm) PELAWA (Dpm) TLVITWA (pln) Hcdth H.ad Rltl'gr Odor Threshold (Dpn) PEL/TWA (Dpn) TLVITIVA ODn)
Unavailable Unavailable Unavailable 10, as hydrogensulfide 1.0. 1 7 to 10 100 l0O
Gcncrd-Mildly alkaline and evolves toxic hydrogensulfide and/or ammonia depending on pH. C€lqd-Liltle hazard trom inhalationbelow 500 ppm. ll may dry and defat skin.
SymptorEyes: irriiation,conjunctivitis.Skin: irritation,conosion, dermatitis,chemical buins. Ingsslion: naus€a, dizinoss, nausea; irritalion of mucous membran€s ot ey€s and r$Firatory lracl,
iritation and corrosion ot mucous membranesand stomach. Inhalation:irritation,pulmonaryedema, coughing.
pneumonia,bronchitis,trach€itis,respiraloryproblems
Short ErDGue TolGmrsoo to 1000 ppm tor 30 to 60 minut€s will produce d6tinite irritation ot syss, lhroat,
Short Erposure TolerucF and trachea.
ErlDsure Pr@edures-Call physician.Inhilation:Remove to fresh air; give oxygen or artiticial respirationas ErDcre Prccdurevapor-remove victim to lresh airi if breaihing stops, apply artiticial respiration.Skin or
needed. lngestion:ll concious,give large amounts ol water or milk, but do not induce vomiling. Eyes: Hold oye conlacl-rsmov€ contamimted clothing and gently flush atfoctsd areas wilh water for'15 minules. Gel
€yelids open, llush with water lor 15 minut€s.Skin: Flush with large amounts ol water for 15 minutss. medical advico or attgnlion.
REACIIVITY DATA REACTIVITY DATA

strblllty-When healed, toxic hydrogensulfide and/or ammonia evolve. Reacts wilh acids to form hydrog€n sr.ullt'{h.mh.lly tt blo.
sulfide. Reacts with basss to lorm ammonia.
Compatibillty-Mrtcridr Compatiblewith mild and stainl€sssteel, neoprene,polypropy'€re. lncompatiblewith (btdlll'-M.tdd! Tlrlr cornpound wlll loti€n, th€n dbsolve, a grsat many pla3tlc materbl!, and rubb€r
aluminum,brass, bronze, copper, tin, zinc Altac-ta ubaolor.
Crgo: Group 5 of the compatibilitychart qrro: Group 34 ol compatibility chlrt

Slop rele63€ lf possible. Wear neoprsne apron, gloves, boots, and gogglos or lull shield, plus sell-contain€d
broathing apparalu8. Ssure ignition sourcss. Oikg large spills, pr€vent spill trom ent€ring sewers and drains,
rccor/ot liquid, lrsal ground with dilutsd hydrogen peroxide. Absorb small spills with earth, sand, or oth€r inart
Wo., rubb.r glovos, l.ca JLld, p.olectiv€ clothing. Hav6 all-purpos€canialor mask availablo.Avoid contacl
||th llquld. g.cua lgnition |oqot. Fluah minor spills away with wator.
abtooanl end prop€rly dilpos€.
borrh: ' Al toO'F,

ll | .Dlll crn. crll the Nrtlo.d
bubbbr ol hydloean sullide gas tom.

RaFu cctrter. E00{2AElr2,
t- f-fr
ll t rrlll ecun. oll |l Ndal r,{'za1r,}..l.
t UnrvdhbL
It r9'
^-n.r.i.^rfu-,- "*L*,.; SCANNED BY MKP & BARIS A. 2004 -..j:.*-.*-
-,,sil,-..;-,,e&a;;.,r*, -,iir-Lr*-,,
Synoi[FAlcohol
n-AMYLALCOHOL
C-5; l-Amyl alcchol; primary-n. tl06
UnitcdNrdru Numbcr................................
r SynonyeAminob€nzeno; Amirbphon; Anilin€ oil;
Ben€namine;Ben2snamino;Blue oil; Phenylaminr
ANILINE
Urlt d Ndou Nunbcr................................
-l-82-
r
Amyl alcohol;n-Butylcarbinol;1-
Pantanol;P€nlyl alcohol
CHRIS Cod............ .... AAN CHRIS Codc..........
Fomulr-CHr(CHz)rOH Fornula-GHsN|'lr
Appeerrnce-Odor-Golorlessliquid;mild odot
Specific Grrvity-0.82
po............................
Botting
. ......
FczinsPotnt..........
--llu'"
--zg'3
_'c
l',
- t r:F
_'F
Lil
r Apperance-Odor-Oily colorle$-to-brown liqukJ;odor
not unolaasanl
SDemc Gnvtty-1.02
8o111nsPo|nt..........................
Frezlr8 Polnt .
Vapor Prwure 20'C (68"F)(n8HO..........
-194'C
--l-o'c
_'c
2.4
-
_"F
364"F
a"e
r
Vapor Pressure 20'C (68'D (DnHd..........
Chcnicd Fmlly-Alcohol Ctemlcd Fmlly-Amin€ ReidVaporPressure 0.02
(Dcir)..................,.,......
Reid Vapor Pre$ure (psia).........
Vapor Presure il6'C (U5'D (Dcir),........... 0.3 Vrpor Presure 46'C (ffs'F) (Ddr)............. 0.04
PollutionCrtegory-USEPA - IMO D 3.04 Pollutlon CrteSory-usfPt D IMO C VrDorDeNity (Air : 1.0)..............-............
3,2L-
VaporDemity (Alr : 1.0).........................
ApplicableBulk Reg.,|6 CFR Subchepter........
-JL- S o l u b i l i t y i n W s t e r . . . . . . . . . . . . . . . . . . . . . . .S. .l i o h t ApDliqble Bulk Reg.45 CFR Subchrpter........ O SofubifityinWrt€r......................... g-O%
crdc-D: Combuslibleliouid
Eledql Group-D
r Grlde-E: Combuslibleliquid
Elstricrl GrouIFD
r
Genersl-Moderate fire haard wh€n exposed to heat or llame. Flashbackalong vapor irail may mcur. Vapo. Gerc..l-Poisonous gas is prodrced wh€n heat€d. Vapor may explode it ignited in an enclosed arga.
may explode it ignited in an enclosed area. When heated, it emits acrid tumes; can react wilh oxidizing
materials.
trlsh Point('F).............................
l l8 Flsh Polnt ('F).........-.-..--.........158 (cc)
nsnrble Linltt..........................
1.2 to 10.0% FlemmrblcL|nitr..................--.... LEL:1.3%; UEL: l106
AutoiSritionTenD. ('F)................572 AutolgnltlonTemD.('F)................ 1 143
Ertir8utuhingA8ents.....................
Carbon dioxids, dry chsmical or alcohol toam.
Speid Fire PrceduG................ Waier may b€ inettectiveon fire. Cool exposed tanks wilh water spray. Wear
sll-contained breathingapparatus. t- Ertingulshlnt 48ertr.....................CO,, dry chemical, alcohol loam, water spray
Sp€ctd Ftre Prqedurs.........,...... Prolecl personnel against exposure to either the vapor or liquid;wear full
protsctiv€ clothing and sltcontained breathing apparatus.
H6lth Hred Ratin$

1, O,2
HEALTH HAZARD DATA
Odor Thrsbold (Dpn)
O.12
PEL,/TWA (pDn)
Unavailabls
TLV,/TWA (DDm)
Unavailabls
r Hedth Hurd RltlnBB
1, 1, 3 0.5
HEALTH HAZARD DATA
Odor Thrqhold (Dpm)
-
PEL,/TwA (ppD)
2/Skin
TLV,/TWA (ppE)
2/Skin
General-Vapor may b€ irritant to th€ eyes and the upper respiratory tract. General-Suspscted carcinogen.Poisonougby inhalationor skin absorption. lt will cause cyanosis,a serious
blood condition. Class B Doien.
[;
Symptom!-Vapor inhalalion causss psychic stimulalion, in$mnia, paldtation ot heart, headache, and verligo. SymptocHeadacha, woakn€ss, irritabilily,dizinsss, bluish discolorationol lips and tingornails,drowsiness,
and unconsciousnesg.
Short ErDcre Tdcrurlso ppm fo( 30 minutes. Erpcure Tolemeso-loo ppm probabt can be tolerated lor 60 minutes.
[-;
ErposurePrcedevapor-remov€ victim to lresh air; if breathingslops or is very weak, apply artiticial ExpocurcPrccrdueFlgmove victim to fresh air. Apply artificialrespirationif needed. Remove any cloihing wet
r
respiration.Skin or aye coniacl-remove contaminatedclothing and genlly flush atfsci€d areas with walsr with aniline. Flu3h oxtpsed skin area thoroughlywith water. Get medical attention as soon as possible.
for 15 minutes.Get medical advics or attenlion. Admaniste.oxygen it svailable. Keep pati€nl at rest. Wash clothing thoroughlywith strong soap solution
b€fore reuse, or destroy.
REAC:TIVITY DATA REACTIVITY DATA

Strbility-Very -Stable. Fl€actsdangerouslywith oxidizingagenis and inorganicacids
stabl6.
[*l Crnp.tlbillty-M.terldr Corrosive to copp€r and copper alloys. Not corrosiv€ to iron or stesl.
CoED.tibtllty-Mdeddr Can be slored in copper, aluminum, or plain slsl tank3.
Cargo: Group 20 of compatibilitychart.

r, Cargo: Group 9 of compatibilitychart.
SPILL OR LEAK PROCEDURE SPILL OR LEAK PROCEDURE

Waat rubbor gloves, lac€ shiold, protoctiv€ clothing. Havs all-purpos€canister mask availablo.Avoid contact
[; Avoid contact with liquid. Wear butyl rubber gloves, plastic protactive apron and soll-contained breathing
with lhuid. Socuto ignition soutcos. apparatus. Secure ignition sources. May mix with sand and soda ash mixtur€ (90-10), scoop up into cardboard
n.slr
lf r rdll mun, oll rh. Nrdol nm.. C.tra-. Ga&lllt. r boxes and pack wilh excess crumpl€d paper. Then burn in open pit.
R.Etr
lf s sDill @cur|' cdl the N.tloml ReDo!re Cenier, ClFa2a.lto2.
't
f- 2l
SCANNED BY MKP & BARIS A. 2004 !lGirrfi-a
'*r
SyMyFAsphelt bitumen;A8phalt cement;
ASPHALT (typical)
In
UnltcdNilloil Nrnbcr.....,,.,..,,..,....,,....,.,...
lrl BENZENE
Asphallum;Bilumon; Judsan pitch; Mineral pitch; Syronyns- Benzol; B€nzoletCoal naphtha; Coal iar Ulltcd Nrtloil NuDbcr.. 1114
Petrol€umasphalt; Pstrolsum pitch; Tars liquid naphtha; Cyclohexatri€n€;Phens; Phenyl hydrid€
CIIRIS Code........... .... -AI-

ACU
l-l CflRIS Codc......,... BNZ
r
Fornuh-Mixtura of elid or ssmielid hydrocarbons
---21'C
BoilinsPolnt.......................... Jll'f FomuleQlt
Appernnce-odor-Thick brown to black s€mEolid; tarry 8ot1tn8Po|rt.......................... 80"C -120'F
ooor FrezingPolrt..................... v.,l*:3 f:i ADpcsmce-Odor-Cl€ar colode$ lhuid wtth ! typicel, -o'c _'F
SDcdncGnYity-O.g io 1.1 -.C JE pleasant aromatic odol FrezlnS Po1nt......... 12.F
_'c _'F
r
Vlpor Pressure20'C (6S'F) (mHO.......... Vetiil Speclltc Grrvlty-O.88
Ctemic.l Fmily-Miscellaneous hydrocarbonmixture ReidvsDorPr€$ure(psia)........................... Vati€3 v|DorPruw at'C (6s'n (mHr).......... 75
VaDorPr$ure 46"C (f 15"n (Fh)............. Vad'e' C't€nlcd Fmlly-Aromatic hydrocarton Rcid VrDor PHure (D6h)..
Pollotion crtegory-UsEPA - nfO I Vrpoi Dersity (Air : 1.0)...........................Vati6 V|Dor PEuc {6'C (r15'F) (Fh)............. 4.5
'
Applioble Bulk RGg.,16CFR Subcirpter....... ----Q- sotolitity io water.........................
----I99!iglblg- Pollutlon Crtcgory-USEPA A IIUO G vrDor DcElty (Alr : 1.0)........................... 2.8
r
ApplicableEulk Reg. a5 CFR Srbchrpter........ O solubility in w.ter.........................
-N99!9ibl9--

crd€-Vari€s with the composition of th€ producl. FIRE & EXPLOSION HAZARD DATA
Elstricd CreuD-D Grrde-C: Flammable liquid.
r
Eletricd Group-D
c€rcr8|-There are many grades of asphalt,sach with ditf€rsnt prop€rties.For sxample, the flash pdnt may
vary lrom 50"F to over 400'F. Gererd-Extremely tlammable. lgnited by heat, sparks, op€n ffame. Flashback along vapor trail may occur.
Vapor may €xplod€ il igniled in an enclosd area. Prtrautions must be taksn to prsvsnt static eleclricity
50 to 400 dependingon gradeof asphall
FlEh Point CD............................. builduo.
12 (Benzeneis solid at 12'F)
FlEh Polnt CD.............................
r
Varies
Flmmsble Limiis..........................
Autoignitior Temp.('F)..,....,........905 Flmnrble Limits..................-......
1.4 to 8.0olo
CO,, dry chemical,toam, water fog
ExtinguishirgAgents..................... AutoignltlonTemp. ('F)................
1076
specialFtre Prcedufes................water spray or foam may be insiftrtive because of frothing; apply cautiousv. Ertingulrhl4 Agertr.........-..-......CO2,dry chemical, foam, water fog
DO NOT direct a solid stream ol water into hot asphalt. SDecidFtre Prc€duu,............... Water may be in€ttactiveon a fire. Fire parties must wear respiralory
prot€clion and rubber boots. In other respects, fighl like a gasoline fire. Explosion haard is great if ignition
has not already occurred and hence civil defense authoritiesshould also be alerted. Cool exposed tanks
with water.
HEALTH HAZARD DATA I

[;
Hedth Hrud Rrtiqs ()dor Thrqhold (ppm) PEL,/TWA (ppn) TLVITWA (Dpr) I HEALTH HAZARD DATA
1, 2, 1 Unavailable Unavailable 5 mg/m3 I Heslth Hurd Rttltrgr Odor Threshold (pDm) PELAWA (Dpm) TLV,/TWA (ppn)
cr!€rrt-When hsated to a liquid siat6 it will cause severe burns. lt is not conosive. There is a posstbilityof
skin poisoningor dermalitis by contact.
I
l-l 1, t,3 4.68 29 CFR t910.1028 10
Generd-Benzene is a known carcinogen. Benzene vapors are sev€rely toxic by inhalation.Benzene has a
pleasni odor and narcotic elf*t and lhus has poor warning properties.
SyDptorFumss ol hoi asphalt can cause nausa and dizin€33.
SymDtoroiziness, headach€,and drowsina€a.
Short Erp6ure Tolerme-Unavailablg
Sbort ErDaw Tolemce-Vapor concentrations:3000 ppm is endurable lor 30-60 minutes (single exposure);
7500 ppm is dangerous in 30-60 minutes (single exposure);20,000 ppm has been latal in 5-10 minutes.
ExDosw Prmedurs-ll spilled onto skin, flood with watsr. Do not bind up, and do not try to scrub otl adhering
materials.Get medi€l attention. ExDorw Prccdur6-Vapor-remove victim to fresh air; il breathing is ditficutt, administeroxygen. lf breathing
sfoI,3, apply artificialrespiration.Skin or eye contacl-remove contaminat€d clothing and gently llush
atfocted areas with waler for 15 minutes. Get medical helD.
REACTIVITY DATA
r, Strblllty-Stabls under normal conditions.
REACTIVITY DATA
c&go: Group 33 of compatibilitychart. r CoDDrdbility-Msterid: Rubber on prolonged expo$re to b€nz€n€ first sw€lls, then $tten8.
C.rgo: Group 32 ot compatibilitychart.

Avold contricl with hot liquid.Woar haavy woat glovss, sale9 goggles or fac€ shi€ld, prolectivo clolhinC lot
r
hot lhuid. ll lrphalt heat.d abovo 212'F is lpllLd Inio walar, pafsons n€arby risk b€ing scaldod by lho tlsam ol Wear rubb€r glw6s, faca shield, plastic coatsd clothing. Wear slt-contained brcething apparatus. Approach
hot watar loflnad. Mort g.raba ol rlphall will gadont linle ot no problem if spilled. from upwind sids. Avoid contact with liquid. Secure ignilion sources. Small spills may b€ tlushed away with
waler.
m{2+tto2.
It r rDlll €cun, cdl the Nrtlon.l
22
r lrfr
* *.-*i-". SCANNED
'ii* BY MKP & BARIS A. 2004 - ;4,!!^, :r*ri*&Ae ;*:i
BENZENE,
TOLUENE,
XYLENEMIXTURES
Synonyms- Eenzens concentrate;BTX mixtures;Coal
n BENZYLALCOHOL
Synonyms- B€nz€ns carbinol;elpha-Hydroxyioluaata; T
Unlttd Nrdo[ Nmbcr................,....,.....,....
t:
tar light oil; Coks oven light oil; Dipolene; Lighl oit;
Phenyl carbinol; Phenyl m€thyl alcohol
Sscondary light dl
CHnIS Codc...,.........:.,...,.............................
-EAl-
Formuh-Benzenes, toluenes,rylenes and othsr
I'
Fomule4HrCHrOH
aromalic hydr@arbons BolllngPolrt.......................... t'C -'F
205'C
Bolll!3Po|nt.......................... 401'F
Appe.rmce.Odor-Yellow to amber liquid;characlslistic -- ----:F
"gasoline" point.......... ApDe|roce-Odor-Colorle3s lhuld: mild pleesenl
odor Frezins . . ..... ... zs:3
Sp€cific Grsvity-approx. 0.84
aromatc odor F * d l r P o t n t . . . . . . . . . . . . . . . . . . .-.1. .5.:.3 t'F
_'c _'F SDecificGnvlty-1.05 at 15'C _'c _'F
Vapor Presure 20'C (68'F) (nnHf!.......... ---25-
Ctemical Fmily-Aromatic
Polhtior Crtegory-USEPA -
hydrocarbon
IMO
ADplioble Bulk Re& rl5 CFR Subchrpter........
@C
O
R€idVsDorPrsure
valnr Presure 46'C (f15"F) (pcid............. 7.3
VaporDeDity (Air : 1.0)...........................
5.8
(Doir)...........................
2.4
solubility tn wrtq.........................---NggliCihh--
l- Chenicrl Frrdly-Aromatic
Pollution Crtegory-USEPA -
alcohob
fUO C
Vrlnr Pwure 20'C(68'D (nnHg..........-si.Q,J-
Rcld Vepr Ptwure (gdr).....................,...,.
-I-
Vrlnr Prwure {6"C (lf 5'D (Flr).,,.......... -I-
VaDorDencity(Alr : 1.0)...........................
-3.Zil-
r
ApplicableBulk Re& 46 CFR SubchrDter........ O Solubilityinwster.............--..-..,. 1.4
Gnd*C: Flammableliquid.
Grade-E: Combustibleliquid
Elctrical Group-Unassigned (B€nzsn€,D; Tolusne, D; Xyl€ne, D)
r
Eletrical GrouI-O
General-Extremelyllammable. lgnitsd by h€at, sparks, open flame. Flashbackalong vapor trail may occur. giv€ olf toxic combustion products in a lke.
Generd-Can
Vapor may explode if igniled in an snclosed area. Precautionsmust be taken to prevenl static eltrtricity
buildup.
Flsb Point ('D.............................
80
r
220 (oc); 2.3 (cc)
Ilah Poirt CF).............................
FlMmrble Limits..................--....
2.2 lo 1'l.O"A FlmMble Limitr...............--....... Unavailable
AutoiSnitionTenD. ('F)................approximately1076 ('F)
AutoignitionTemp. ................817
ErtinguisbingA8ent8.....................
Contined-Co,, dry chemical.Open-water, loam. Ertlnguishirg Agents Alcohol foam, dry chemical, carbon dioxide
SFcid Fire Prc€d|rc ................Fire parties must wear r€spiratoryproteclion and rubb€r boots. In oths SDeld Fire Prsedurg................ Water and foam may cause frothing. Wear slf-contain€d breathing apparatus,
rsspects, tight like gasoline fire. Explosionhazard is great. prottrtiv€ clothing. U$ water to keep ianks cool.
Hcdth Hred Rltirsr

HEALTH HAZARD DATA
()dor Th.6bold (Dpm) PEL,/TwA (DpD) TLVITIYA (rF)
rl,
' Hedtt Hrard Rrtirg Odor Thr6hold (pDm) PEL,/TIVA (ppn) TLVAWA (Dpn)
1, 1, 3 0.0'l see benzeno Unavailabls 5.5 Unavailable Unavailable
Gerc.d-B€nzene is a known carcinogen.Mild irritant in contact wilh skin; avoid rep€ated or prolonged
Gcrerd-Avoid direct contacl wilh liquid and prolonged exposuro to vapor-absorbedthrough skin.
exposur€.Minor iniury lrom ingestionor inhalation-repeated contact may b€ more haardous.
Syhptomr-Watsring eyes, mild skin irritalion,diziness, headache and drowsiness.

SymDto||tFlrritation to eyes, skin. Vapor irritates uppsr respiratorytract and produces headachs, dizziness,
nausea. Ingestioncauses abdominal pain, vomiling, diarrhea.
Shori Ex!trure TolemeSome evidence ol carcinogsnicbehavior to animals has been obseruedlor Short Erporue Tolemce-Must have adequate veniilation or use respiratoryprotection.
prolongedskin contact.
ErDcure PrmedueFlush skin and eye coniact at orce with pl€nty ot water. ll inhaled, removs to frssh ai.
No specilic antidote is known. Call a doctor.
'Benzone:29 CFR 1910.1028. r ExposurePrcedrrFEye contact: Flush with water lor al least 15 minutss; call physician.Skin contact Wash
wilh soap and water tor 15 minutes. Inhalation:Remove the lresh air, give orygen it necessary:call
physician.Ingeslion: lf conscious,give waler, induce vomiting, contact physician.
Strbility-Stablo.
REACTIVITY DATA
II REACTIVITY DATA
strbtlity-Generally stable. Slwly oxidizes in air and orygen. R€acts wilh mineral acids generating heaq r€acts
with sirong oxidizsrs.
Conpdibility-Mrterld:
t:
Steel and other metals completely resistantbut not copper alloy. All elasiomers af€ Conpotiblltty-Caried in stainlsss steel or phenolic r€sin lined mild stsel ianks. Noncorrosiveto stsl and mosl
attack€d and any coatings €xcept baked phenolic are stripped. Most plastics are s€versly attacked. metals but corrodes aluminumat high temp€rature.Will attack some non-flourinatodplastics,will not attack
polypropylene.
CuSor Group 32 of compatibility chart. Csgo: Group 21 ol compatibilitychart.

Wear rubb€r gloves, fac€ shi€ld, plastic coatad cloihing. Wsar self-containodbfeathing applratu!. Appro.ch
from upwind sids. Avoid conlect with liquid. S€cure igniiion lourcss. Srnall lpills may b€ lluthcd rwry Ntlh
W€ar goggle8, lace shi€ld. Covar small spills with absorb€nt (snd, swdust); dispo!6. Dk6 lr|igp sFilb tor
pumping to sio.ag€ tank; dispose or rsclaim.
It.
[-l
la . ttlll H.1 c.ll lhc Nrtlood nrDor C4ntcr, 0{H2/a-ttlrt,
lrulr: I Umvdl.bL
t un t|lgn d r_l l-&ra t Unadal|. rtt
l l
I
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-t.=
-Ef---
2' SCANNED
=. ,.. BY
* I-I MKP & BARIS A. 2004 It
BENZYLCHLORIDE BUNKERC
r
Synonynr- Bonzene,chloromelhyl-;(Chloromethyl) UnltcdNrtionr Number................................
lZiU- t;n;eFtj.l ol m. C: H.!W industriallusl oili
bonzsn€: alpha-Chlorotoluene: na.ldu.l lu.l oll no. t
ofirega-Chlorotolusne
CHRIS Code........... .... BCL

CHRIS Codr................... osx
,.............
I
Fmrlr-QHsCHrCl
8oi1in8P6int..........................
---lZg'C 355'F
BolltngPoht.......................... \24"C >75"F
Apperrrnce.Odor-{olod$s to slightly yellowish liquid; -'c -'F
AttonF-()dor-V€ry viscous, dark colored liquid:
-39"C -39"F -t'! -'r
pungenl, aromatic,iritating odor FreezingPoint.........,.............. t;agrlnt odor. poiri.........
Fr@zin8 ........
SD€cilicGrsYity-'|.1 al25" /25"C -'F
SDcl|lc Gntlty--O.g2 to 1.07 _'c _'F
v.por presure il'c (68'F) ,.r",
I
--:.
Chenicsl Fmily-Halogenated hydrocarbor V.por Prwure 20'C (68"D (mnHg).......... O-O42
ReidVrpor Prsure ........... 0 07
(!cir)............... Clillol Frolly-Misc. hydrocarbon mixlure R e i dV t p o r P r e $ u r e { p s i ! ) . . . . . . . . . . . . . . . . . . . .L. .o.w
....
Vapor Prwure {6'C (f f5'F) (pir)............. 0.09
B B Vrpor Prwure ,16'C(115"F)(Fir)............. 0.149
Pollutiotr Crtegory-USEPA tVO VaporDensity(Air : 1.0)............,.............- 4.36 Pollutlor Criegory-USEPA - IMO --l- Vrpor D€nsity (Air : 1.0)..............
r
---!-
ApplicableBulk Reg.46 CFR Subchapter........ Solubilityirwster......................... Neolioible Appllcrblt Bulk Reg.rl5 CFR Srbchapter........ O Solubilityitr W.ter............--......... Neolioible
Gnde-E: Combustibleliquid Ulu_E: Combustibleliouid
WmOUSI
Elctrical GrouD-D ElccHol Greup-D
cercrsl-Modsrate tire haard. Kep away lrom open tlame or ignitionsources. lritating gses ar€ produced
when heated. Decomposeswith water to produce hydrog€n chloride fumes. I b€ healod io sustain combuslion.
165 (cc)
nsh Point CF)................-........... Flsb Polrt ('F).............,-.--....... 150 to 430 (ccl
t ;
Flmble Limits..........................
LEL:1.1%: Flumrble Ltm|tr...........,...,..,.......1 to 5%
Autoignitior TenD. CF)................1085 AutoignldorTcmp. ('F)....,........... 765
CO,, dry chemical,water fog
ExtlnguishingA8eDtr..................... Ertir8ubhltr8 ^8etrtt.......-............Foam, CO2,dry ch€micalg
Fire Preedur6 ................Use complele personal protectiveclothing. Wear self-containedbreathing Flrc Preedrq ................Waler mav b6 inottmtiva on tif€3.
apparatusIor indoor fires. Water mist may be used, but in large quantityto hold down hydrogenchloride
lumes and flush away acid.

Hedth Hrad Rrtirgs Odor Thr6bold (ppm) PELlTtryA Opm) TLv,/TtryA (Dpn) Holth Hrad R.th3r Odor Thrabold (ppn) PELITWA (ppo) TLVAWA (ppn)
4.2.4 0.01 1
Generd-Suspected carcinogen.Vapor eldremelyirritating.Liquid causes burns.
1
I Unavailable
brsaihing v8por.
Unavailable Unavailable Unavailable
t
Symptoms-Vaporsare irritaiingto eyes and respiratorytract, causs tears and coughing,possible loss ol sight. SymptGH€adacho, nau$a, dizinsss, v€rtigo, unconscio$n€8s.
Liquid causes skin irritationresultingin burns on prolonged conlact.
Short Erysue Tolerme-1o ppm lor 30 minutes Shfil Erfaorc Tolrc-Unavailable
ErDqrre ProccdureVapq-remove victim to tresh air immediately, il breathing stops apply artificial
respiration.Skin or eye conlacl-remove contaminatedclothing and llush with large amounts ol water for 15
minules. Get medical advice or attention. l r Erlcurc Preeduro-lnhalalion: Remove viclim lo tresh air, prevsnt chitling,and appty artificial respirationif
br€alhing has stopp€d. Get immediab attention if viclim is overcomo by vapors.
REACTIVITY DATA
strbi[ty-Unstabilization results in rapid condensationreaclion in prssence of particularmetals. Liberat€a
hydrogen chloride lrom decompositionreaction with water.
l-r Strblllty-V€ry stablo.
REACTIVITY DATA
Comlntibility-Mrt€rid: Avoid mpper, aluminum, iron, zinc, magn€sium and tin; viol€nt polymsrizatbn wil
resull. Nickel is recommended.
Cugo: Group 36 of compatibility chert

t- CdFdbntty-Mlcrld: Compatibls with mosl materials ot c$slruction.
Cr4o: Group 33 ol compatibilitychart

I-t SPILL OR LEAK PROCEDURE
Woar full protetivo clolhing, rubb€r bootg, lace shi€ld, ey€ protoction, sslt-contain€d br6alhing apparaius. Waat tubbar gloves, tac€ shield, proloctive clothing. Have all-purpos€canister mask availabls.Can eak up
lmm€diatelytlush wilh larg€ quantitiesol cold watsr. Fre€ly vsntilate to rgmove odors. Sodium carbonste or lime
can bo used it wator is unavailable.Remwe ell contaminat€dclothing and thoroughly clean.
lt. tlc Nrdorl tm C*. m-ar..|l|2.

[-r apl $$ papa., rardurt, rag!, otc.
llrdlmndlrf.Ndill
lrlr: l-||t I t,uvl..bb
I rrrrr5r-
-.-b.i SCANNED BY MKP & BARIS

- -.&;A. 2004 .rAn4d4*, ".-*{-' ;;r--*:*-
BUTADIENE
1010
tl Synonynr-Butane; Oiothyl;Msthylsthylmothana
N.BUTANE
Unllrd Nrdu 1011
Nubcr................................
Symyn.- Eiethylene;
Bivinyl;1,3-Butadiene;alpha, Unit€dNrtioru Nuber................................
gamma-Butadiene;Divinyl;Erythrene;Pyrrolylsne: f-l
vlnyr ethyrene
| |
BDI
CHRIS Codc................................................. CHI|S Codc.......... ..... BUT
"(iso-' n')"
Fmuh-crlle, or cHr : cHcH = cfL t-l Fonulr-c1H16
'C 24'F 8o||l!a Pohi . ... . ................ -0'5'C 31'F
BoiliDsPoint........... I |
Appearuce-Odor-Colorlessgas or liquid;mitd, -'C -'F | | Appemce-odor-Colorloss; odorlorr gaa -'(
aromaticodor -1Og"C
Frezlng Po1rt........................ -164'F FndS Poha...........,............
.-L!19'(
SpecificGrrvity-O.62 at 20'C (a liquid) -'C -"F SpeclflcGravity-O.s8 at O'C (a liquid) -'(
l3?g- -l
.hcnrorFm'y-unsaturarsd
hydrocarbon Hil'"ffilff.:l$"?llill-..::..::.: t ctemrcel
Fenrry-satuiatsd
hydrocarbo" If"ffi;:3;?1'111-::::::::
vrDorPrnrc
vrDor Prnrc a6'C (rl3'D (rh).............
a6'C(rl3'D trtr1.............--00.Q-
!!9

Grede-Liquefied FlammableGas (LFG)
Electricsl Gloup-B
n Grrde-Liquelbd Flammabl€Gas (LFG)
Electricsl GrcuD-D
cene.d-Unless llow ol gas can be slopp€d, eninguishing a butadienefire may permit accumulationol an
explosiveconcentrationof vapor, and subsequentsxplosion or re-tlash.Fire may cause violent rupturo of
tenk.
-105
Flsh Polnt CF).............................
ri G€nerd-Unl€ss the flow of gas can b€ stopp€d, oxtinguishinga butans fire will p€rmit accumulationof an
explosive concenlrationof vapor, and 8ub8€quentexplogionor ro.tlagh,
- 76
FlEb Poht ('F).............................
FlanmrbleLinitr..........................
2.0 to 11.5% FhmmrbleLlntt!..........................
1.9 to 8.5%
AutoiSnitionTenp. ('F) ................842
Extinguichin8ASenb Stop flow of gas; COr, dry chemical,waler log
SDecidFire PrEedur6 ................Keep burningtank and adjacsnt tanks cool with a wal6r spray. W€ar tull
protscliv€ clothing and s€lf-contained brealhing apparau8.
l AutoignidonTenp. CD................
ExtinguishinSASents
761
Stop llow of gas; CG, dry chsmical, water fog.
Sp€cid Flrc ProccdrE................ Keep burning iank and adjacsnt tanks cool with a waler spray. Stop flow ol
gas.

Heslth H@rd Rrtilgr Odor Threshold (ppn) PEL,/TWA (pDn) TLV,/TwA ODn) Hedth Hr4d Rrtings Odor Threshold (ppn) PELITIVA (Dpm) TLV,/TWA (ppm)
1.1.1 above 1000 unavailable 1000 0.0. 0 5000 800 800
G€nerd-Susp€cted carcinogen.Liquid or cold gas may caus€ skin or eye injury similar to troslbite. Geoerd-Produces drowsiness.Simple asphyxiant.Liquid or cold gas may cause trostbilo.
SyEDtorlnhalation: dizziness,headache.Skin contact lrostbitlen ar6as will appear white. lrritatingto eys SymDtorDiziness and drowsiness.
and respiralorytract.
Short ErposureToleruce-8,oo0 ppm was lound endurablefor I hours wilh only slighl irtiiation ot the eyes and
upp€r respiratorytract.
I i Short Expsure Toleranc+10,000 ppm (1"6) tor'lO minutes will cause drowsiness.
Expocure Prcedurc-Vapor-rsmove victim lo tresh air; if breathing stops, apply artificial rsspiration. Skin o{ ExDocurePrcedureFlemove victim to lresh air. lf breathing has stopped, give arlilicial respiration.ll the liquid
eye contact-remove contaminaledclothing and gently tlush atf€cted areas with water for 15 minutes. has spilled onto the skin, points ol contacl may be lrostbitten; handle gently and protect trom mechanical
Protect trostbittenareas from abrasionsand mechanicaldamag€.DO NOT RUB. Get medical advice d damage. DO NOT RUB. Get medical atlention.
attenlion.
REAC'TIVITY DATA REACTIVITY DATA

Strblllty-Must be inhibitedlo prevent polymerizaiion.Forris unstable peroxidesin presnce ot orygen and/or Strbility-Slable product.
iron rusl.
ComD.tibility-Mrterld: Unsat€ in conlact with acetylide-fdming mterials such as mon€|, coppor or copp€. CoDDrtibility-Mrtsld: Non.corosive lo most materials of construclion.
allovs.
Crrgo: Group 30 of compatibility chari- Cu3or Group 3l ol compatibility charl

Wear rubber gloves, tace shisld, proi€ctive clothing, and selt-containedbresthing apparalus. S€cute ignition
Woar rubbor gloves, faca shield, proteciive clothing. Hav€ all-purpos€canistsr mask available.Secure ignilion
sources. The spilled liquid will boil away rapidly, leaving no resid(r€.
t-
8ourcas.Th€ spilled liquid will boil away leaving no residus.
lt I trlll Gril cdl tic Nrtlord nm ('atr. Ul.a'.-tdr2. lfr
lrrfu
lrlrb:
r
i l l
-
. -.r!'n.
It ,.
.''"-*- SCANNED
!r BY MKP & BARIS A. 2004
*.ta**-g.lfg-i
29
ii-*-i.i-,.aiae-.Ji-j;
SynoryrAcelic
lsobutyl acatat€; 2-Msihylpropylacstate;
iso.BUTYLACETATE
acid, iso-butyl€ster; Butyl acetate; UnitedNrtionsNunbcr.......................,........
-l.?LlL
r, SynonyrAc€tic
n-BUTYLACETATE
acid; butyl ester; Butyl rcolate; Uniled Nrtlons Numbcr................................ 11
2-Methyl l -propyl acetate; beta-M€lhylpropy' normal-Butylacelale; Butyl sthanoele
6thanoat6
CIIRIS Code........... .... IBA
"(iso-, n-)" BAX Calnls . . . . . . . . . . . . . . . . . . . .B. .C. N
Cod...........................
"(iso-, n-)"
r
Formuh-CHsCOOCH,CH(CHs), BAX
BoilinsPoirt.......................... 1 18'C 241'F Fmuh-CHsCOOCTI'lr
Appearue-Odor-Colorl$s lhuid; pleasant, lruity odor Bolllnj Polnt.......................... 127'C 260'F
-1oo:3
Fre'irsPotrt........................ -t*:F lhuld; dealeni, tnXtyo&, _'c _'F
Frt dlt Poha........................ -77.C - 107'F
SD€cificGnvity-o.87 _'a -'g
SDemc Gnvlty-O.88
'c _'F
Vrpor Prwure 20"C (68"F)(nnHg).......... :
ClhemicslFmily-Estei ReidVaporPrmure (!6ia)...........................
-0.tt-
Clenlcd Fmlly-Ester
Vrpor Prruure 46'C (Us'F) (pdr)............._0.9-
Pollution crtegory-uSfPl D tUO C VsporDensity(Air: 1.0).........................,. 4.0
Pollution crteBory-USEPA D IMO ----Q-
ApplicableBulk Reg.il6 CFn Subchapter........ D. O SolubilityinWater......................S . . l. i o h t
ApDtlc.bleBulk R€& {6 CFR Subchr9tcr........ O- O
Elect.icd
Combustibl€ lhuid
GrouD-D
T Grade-D: Combwiible liquid
Eletricd GreuFD
FIRD & EXPLOSION HAZARD DATA
along vapor trail may occur. May explode if ignited in an enclosed area.
Gercrd-Volatile, wilh a low llash point. Flashback along vepor trail may occur. Vspor m8y explode if ignited in
an onclosed sDace.
Flsh Polrt fF).............................
88
Flsh Point CFr.............................
90
r
2 to 15% (approx.)
Flmuble L|nits........,.................
Autoignldon Temp,CF)................ 793 Flrmmble Lin|ts..................-...... 1.4 lo 7.6"h
ExtinguishingA8ent5.....................
Co,, dry chemical, alcohol loam, water tog AutolgDitionTemD. ('F) ................790
Fire Prsedug................ Use of dry chemical where il can get into a tank of butyl acetate is nol ErtirSutuhinSA8entr.....................COr, dry chemical, alcohol foam, water tog
rocommended.Fire involvingspills outside of tanks can be extinguish€dwith dry chemical. Waisr may b€ Specld Fire PrceduG................ Use of dry chemical where il can get into a tank ot n-butyl acelale is not
inoftsctivs. Cool adjacent tanks with water spray. recommended.Fires involvingspills outside ot tanks can be extinguishedwith dry chemicals.Water may be
Hedth Haad R.tilgs

HEALTH HAZARD DATA
Odor Thrghold (ppn) PELAwA (Dpn) TLVITwA (DF)
r ineltective. Cool sxposed tanks with water spray.
HEALTH HAZARD DATA

1.1.2 r0 150
irritatingto syes, no$ and throat. Liquid irritatingfo skin and eys3.
Inhalation of vapors will caus€ headache, iritation ot rospiralory passages and eyes, dizzins3s, and
nausea.
150
r Hedtt Hrud Rltings

1,1,2
Odor Thrshold (ppn)
10
PELAWA (DpD)
150
TLVITWA (Dpo)
150
Ccnerd-Low level ot toxicity. Vapor irritaling to syes, nos€ and throat. Liquid irritating to skin and €yos
SymptorH€adach6, iritation of r€spiralorypasage and eyes, diziness, and nausea.

ExposureTolemce-200-300 ppm produces some nose and eye irrltationupon briel exposurg.
ft Short Exposure Tolemr200-300 ppm produces some nose and eye irritation upon brief exposure.
Exl8ur€ PrcedurFvapor-remove victim to tresh air; if breathingstops, apply artificialrsspiration.Skin or

eye conlact-remove coniaminatodclothing and gently flush atfected areas with water lo|15 minutes.Gsl Ertdue Prced@Vapot-remove victim lo fresh air; il brsathing stops, apply artiticial respiration. Skin or
medical advic€ or attention. sye conlact-remove contaminatedclothing and gently flush allectod areas with water lor 15 minules. Get
m€dical advice or attention.
REACTIVITY DATA
Strbility-Generally slable, however,will slilly d€composs on standingto form acetic acid and isbutyl
alcohol. r, REACTIVITY DATA
Stability-Stable, howsver, will hydrolfz€ (rsacl with water) on standing to form acelic acid and n-butyl alcohol
r
ComDstibili8-Mrtertd: Sottens and dissolved rubb€r and many plaslica.
ConDrtibility-Mrterisl: Sottens and dissolvss rubb€r and many plastics.
Crrso: Group 34 ot compatibility chart.

c|r8or Group 34 of compatibility chart.

W€ar rubb€r gloves, face shield, protectiveclothing. Have all-purpolo clnistor maska lvdltuo. Avoid conbct
liquid. Securs ignition sources. For a gas leak from a tauliy bnk, kaap concantatbn of gar balow th.
Wear rubb€r gloves, ta€ shisld, protective clothing. Have all-purpose canist€r mask availabl€.Avoid contact
exploSivemixtur€ rang€ by venlilalion. with liquid. Secuis ignition sourcas.
ll t rtlll ccurg.
' Vapor ftatrure: 10 mmHg t2.8'C.
cell tbc Nttlul l-l ll r rplll ccun, qll thc Nrdold Rdpotre Ccnt.r, t{XL424-EE02.
nrb rl
bfr

l0
il
grrgtt& {{EL-! ii-
SEC-BUTYLACETATE II ISo.BUTYLACRYLATE
acid, soc-butyl ester;2-Butanol acetate; I I acrylat€; tsobutyl-2-propenoale;2-Methyl-1-propyl

1-Methylpropylaceta," acrylate
| |
cHRls codc........... .... -SIA- cHRts cod€.......... ..... BAI
"(iso-' n-)"
Fomulr-cHscoocH(cHs)c,H! 1-l Formulr-CHz:CHCOOCH,CH(CHlh
BoilingPo1nt.......................... 112'C -----23i4'l | | 8otlttr3Po1n........................... 137"C 271'F
ADpesrarce-odor-Colorlessliquid; mild, pleasant odor -'C -'l | | Aplrarance-Odor-Colorlsss liquid; sharp, tragrsnt odoa -'C
FreeringPoilt........................ -73'C - 10O'F FczhS Po1trt........................-61'C -78'F
SpeciticGravity-o.89 -'C -'F SpecificGnvity-o.88 -'C
c.hemicsr
Fsn'y-Esrer Hil!ff;l"jl.: ,t$"?1""3....::.:.
fil I| I| chemic.r
Frn'y-Acryraro [il'r:ffifjl;: lff l.1lll-?-::::::.:.
p
porutioncltesory-usEpA ruo p J:il:ilffil",f;t:"r1t,"1*'-"]...... + porurioncaresory-usEpA-rMo B l:il:flf,"J,f;t-tLtl..l*::::::::::.:
Combustiblsliquid
FIRE & EXPLOSION HAZARD DATA n Grrd+D; Combustibleliquid
n
Electrical Group-D Electriel Group-D
Volatil€ with low tlash pdnt. Flashbackalong vapor fail may occut. Vapor may oxplodo il ignited in an Genergl-The main hazard is its very easy polymsrization. lgnit€d by heat and op€n tlame. Fire may caus€
€nclo$d aroa. violent ruoturs ot tank.
Ilsh PoitrtCF).............................
88 Flsh Point CD.............................
86
1.7 to 9.8%
FhmmableLinits.......................... FlammrbleLiEits..........................
1.9 to 8.00%
AutoignitiotrTemp.CI)................ 750 to 800
ExtingukhingAgents Co,, dry chemical, alcohol loam, water fog
SpeciatFire Prceduu................ Use ol dry chemical where il can get into a tank ot butyl acetale is nol
recommended.Fires involvingspills outside ol tanks can be extinguishedwith dry chemical.Wal6r may b€
I_l Autoigrition Tenp. ('F)................644
ExtinguishingAgetrt!.....................
COr, water fog, dry chemical,loam
Firc Preedu€ ................Provide fire fighters with breathing apparatus. Kesp tank cool with wats
spray.
inetlective.Cool exposed tanks with water spray.
HEALTH HAZARD DATA

n HEALTH HAZARD DATA
Hedth Hrand Ratings
1.1.2
OdG Thrdhold (Dpm)
b e l o w2 0 0
PELAWA (ppm)
200
GeDenl-Vapor irritatingto oyes, nos€ and lhroat. Liquid irritatingto skin and eyes.
TLVITWA (ppm)
200
n Hesllh Hurd R.titrg.
1, 1, 1
Odor Thr€shold (ppm)
Unavailable
irritating.Avoid skin contact with liqui4
PEL,/TWA (Dpn)
10
TLVAWA (pDm)
Unavailabls
sympton!-Headache, irritationol respiratorypassages and eyes, diziness, and nausea. redness lrom skin contact with lhuid
Short Ex!trure Tolemce-300 ppm I_l ExDorureTolemeunavailable.
ExposurePreedurevapor-rsmove victim to fresh air; it breathingstops, apply artificial respiration.Skin or

eye contact-remove coniaminatedclothing and gently flush affected areas with wat€r lor 15 minutes.Gal
medical advice or attenlion. n Expcure Prcedure-Skin or 6ye contact-llush immediatelywith large quantities of water for at least 15
minutes. lf any irritationor injury dsv€lops after washing, prompt medical attention should be obtained.
Vapor inhalation-remove viciim to uncontaminatedarea and obtain prompt medical attention il any illness
is observed-
REACTIVITY DATA
Stsbllity-Stable, however,will hydrol}/ze(react with waier) on standingto form acetic acid and sec-butyl
alcohol.
t REACTIVITY DATA
Stability-Polymsrizes readily on heating. Must be inhibited.
Comlotibility-Msterld: Softens and dissohr€c rubb€r and many plastc€.
Crrgo: Group 34 ol compatibilily chart.

t Con!trtibility-Mstcrirl Compatible wilh mosf matsials ot constructon.
er4o: Group 14 ol compatibilitychart.

W€ar rubb€r gloves, laco shi€ld, protectiveclothing. Hav€ all-purposecanists mask evallabl€.Avold contact W€er rubb€r glovos, tace shi€ld, lull proieciive clothing. Have all-purpos€ canistgr mask availablo. Sacure
ignition $urces. Small spills may be fl$hsd away with water.
I
lhuid. S€cure ignition sources.
ll r rdll mun, cdl thc Nrrlorl nrDoix Crrir. 0{ltl-tgll. It N.alod nrnr C6td, D{if-I8.
r-b lsu
n
t l
i l l l
I
- .r;1,.a.lzi+r.,o;r.u-*,;* ll ' SCANNED
'.,'- BY MKP
I - ^ L ; . - . *&- . f f .BARIS A. 2004
N.BUWL ACRYLATE fi ISo.BUTYLALCOHOL
_2W
r
Synonyr Acrylic acid, n-bulyl ost€r; United Nrtiors Nunber.....................,......
1212
SynonyFAlcohol C-4; Fermontationbutyl alcohol; unftedNdfom Number.....
..........................
n-Butyl-2-prop€noate; 2-Plop€ndc acid, butyl ester 'l-Hydroxymsthylpropane;
IBA; lsobutanol; lsobutyl
alcohol; lsopropylcarbinol;2-M€thyl-1-propanol {
CHRIS Code............., BTC
"(iso-, n)" CHRIS Code..........
_eAB_
Fomrh-CHz: CHCOOCTI-b
ADDanncc-Odor-Colorless
o8tsr-likeodor.
SDcclttcCrrrlty-O.go
liquid; shae, biting,
BoilitrgPoirt.......................... 149'C
Freezins point......... ...-

--ol'3
_'c
VrDor PrNurc 20"C (68'D (nmHg) ..........--31-
-.-:F
_'F
30O'F
r Fomulr-(CHrhCHCl.LOll
SpectncGnYity-O.8'l at 15"C
liquid; sweel odor
BoilingPoin1...........-.-............ 1O7"C
Freziog p o i n t . . . . . . . . .....
--toe'3
_'c
- t
_'F
* - ' F
225"F
Ctemlcrl Fmily-Acrylals
Pollution Crte8ory-USEPA - IMO

ApDlicrbleBulk Reg.il6 CFR Subchrpter........
B
O
Reidvrpor Presure
VrporPresure,|6'C(115'F)(psir)........,.... 0.4
vrpor DeEity (Air : 1.0)..............
sohbinty h wrier. ---NggJEblg-
0.2
(pcir)...........................
I- Ctemlcd Fuily-Alcohol
Pollution CxteSory-USEPA - IMO lll

Vrpor Prssure 20"C (68'D (nnHg).......... ---9€-
ReidVsporPrsure (lris).........
vspor Presue 46'C (115'F) (Isi8)............. 0.9
Vspor De$ity (Air : 1.0)........................... 2.6
r
ApplicsbleBulk Reg.46 CFR Subch.pt€r........ D Solubilityin wster...................-.... Moderate
GndeD: Combustibleliouid
Combustibleliouid
Electricll Group-D
r
Eletrlcd Group-D
General-The main hazard is its vsry easy polymerization.lgnited by h€at and open flame. Fira may caus€
by h3at or op€n flamo. Flashback along vapor trail may occur. Vapor may oxplode il ignitgd in
violent ruDtureol tank.
an gndo$d ar€a.
F l s h P o i n tC n . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ' l 2 0
FlEh Polnt Cn.............................
1(x)
Fl.mmlbleLimits.................-....... 1.5to 9.9',6
Flmnrbfe Lfnftr..........................
1.7 to 10.gohal 212'F
Autoignition T€mp.('F)................ 567
ExtinguishingAgentr.......---........Carbon dioxid€, dry chsmical, alcohol foam, waler spray.
SDecirlFire Proc€dB................ Providefire lightsrs with breathingapparatus.Kep tank cool with wait
spray.
l- AutolSnitionTenp. ('F)................825
Ettirguishing Agertr Co,, dry ch€mical, alcohol foam, wator toe
Firc Prcedu................ Water mav b€ inettectiv€.
HEALTH HAZARD DATA

G€nqd-Vapor and liquid are irriialing.
irriiation;walering ot eyes and salivationwhen inhaled.

r Hedtb Hrud Rati4s
'1,0, 1
Odor Threbold (ppm)
Unavailable
PELAWA (ppn)
50
TLV,/TwA (pDn)
50
erd-Not highly loxic. Eye conlaci should be pr€vented, and prolonged or r€pealed exposure to lhe vapors
should be avoided. Prolongedor repeated skin contact may cause defatling ol the skin and may produce
dermatitisfrom daily contacl.
ymptoms-Headache and diziness.
lT Short ExDosureTolermce-1so ppm
Expcure Prcedur+Skin contacl should be washed thoroughly with soap and water. In case ol eys contact,
llush wilh water lor 15 minutss. Gst msdical attention or advice.
r Erpoure PrcedeVapor-remove victim to lrssh air; il breathing stops, apply artificial respiration.Skin or
eye contacl-remove contaminalsd clothing and gently flush atfected areas with water tor 15 minutes. Get
strbility-Potymsrizssreadityon heating.MREACTIVITY
ConDdbllty-Msterid! Compaliblo
withsleel,stainlossst6€lor aluminum.
DATA
r strbilty-stable.
REACTIVITY DATA
ConFtibility-Mrtedd: Compatible with plain sto€|. Wat3r-tree isobutanol rsacts with aluminum at
CrrSo: Group 14 ol compatibilitychart.

l- lemDeraluresabove 120'F.
Crgor Group 20 ot compatibilitychart. Ss€ also Appendix l-Exceptions to ths Chart.

W6ar rubbsr glovss, lace shield, lull prol&tiv€ clothing. Hav€ all-purpos€ canist€r mrrk lvailabL. AvoE
r
Weet rubb€r gloves, face shi€ld, prolstive clothing. Have all-purposecanistsr mask available.Avoid contact
contacl with liquid.Securs ignition sourcoa.
with liquid. Socure ignition sourcss.
lt a Lll Nr, crll tL Nrdord
r lllf, t Unrv.LbL
J'
SCANNED BY MKP & BARIS A. 2004 rt *tf i*-:
n-BUTYLALCOHOL l-l tOC.BUTYLALCOHOL
SynonyneAlcohol C-4; Butanol;1-Butanol; n-Butanol; ll2lL
Urit€d NrtionsNunber.....,................,....... Synonyms- Alcohol C-4: 2-Butanol;le-Bulanol; 1120
UnltcdNillor Numbcr................................
Butyl llcohol; Butyric alcohol; 1-Hydrorybutane: Butyl€n€ hydrat€: Elhyl methyl cattinol:
NBA; Propyl carbinol;n-Propylcarbinol 2-Hydroxybutsn€;Melhyl ethyl carbinol; SBA
[;
Fomuh-CHr(CHr)sOll Fomulr-CHsCHTCHOHCHT
App€rrrncc-odor-Colorless liquid;pungenl alcohol

ooor
Boi|itrgPoht........................-. 117'C
-'c
FreezirgPoht........................ 84'C
243'F
'F
-120'F I Appeemce-odor-Colorl6s
oool
SDccmcGnvlty-o.81
liquid; slton€, p|iat.nt
8 o 1 1 1 n 8 P o | i l , . . . . . . . . . . . . . . -. .- .1. 9
Frertng Potnr.......... ......

--tog:3
-'c
. .'.C. . . .
-'F
211'F
-t*:F
r'
SDecitlcGnvity-o.81
Vrpor Prwurc 20'C (6E'D,.."r*-" v.Dc h{urc afc (6t'R (mmH$..........---l-
Chemicrl Fully-Alcohol ReidvrDor Pressure 0'3
(D6h)..............,.,...,...... C'hcnlcrl Fmlly-Alcohol Rcld Vlpor Prilrrc (p.h)........................... -0.2-
vapor Prwure {6'C (U5'F) (Dsil)...'........ 0'5 Vrpor Piourc ff'C (lls"n (pc1d............. Jl-
Pollution Crte8ory-USfpt D 619 lll Vrpor Dersity(Air : 1.0)....................... 2'6 Pollutlon CrteSory-USEPA - IMO lll vrDor Dcnrlty(Alr = 1.0)...........-.............. -?,S--
D Modetate Appltoble Bulk Res.tl6 CFR Subchrptr...,.... -JL- So|ubl||ty|nWrtr.,....................M . . .o d t r t l e
r
ApplicrbleBulk Re&,16 CFR Subch8Dta....... solubilityinwrtGr......-----.........
FIRE & EXPLOSION HAZARD DATA FIRE E EXPLOSION HAZARD DATA

Gnde-D: Combustibleliquid crsde-C: Flammabl€liouid
Elfftric8l GrcuF-D El6tricrl GrouFD
cen€rrt-lgnited by h€at, sparks, or opon llame. Flashback along vapor trail may occur. Vapor may explod€ it cenerd-Dangerous when exposed to hsat or llame. Flashbackalong vapor tail may rccur. Vapor may
€xplode if ignit€d in an enclosed area.
igniied in an enclosed area. [-:
103 Flsh Poirt ('n.............................
74
r
Ftrrh PointCn.............................
1.4io 11.2t4
nmmrble Limits.......................... FlammrbleLinit8..........................1.7to 9-g al 212'F.
AutoignitiorTenD. CD................ 690 AutoigDitionTenD.('F)........,....... 763
Dry chemical,COz,foam, water fog
ExtinguishinSA8ent8..................... Extinguishing4gentr.....................CO,, dry chemical,alcoholtoam, water fog
specistFire Pmcd|E................ Wat€r and alcohol foam may be inetfectiveon fire. SDeid Fire Predw ................Water may b€ inettectiveon fire.
HEALTH HAZARD DATA

l-' HEALTH HAZARD DATA
r,
Herltb Hled Rltitrgr Odor Thr6hold (pDm) PEL,/TWA (ppm) TLv,/TwA (DDn) Heslth Hurd Rriirgr Odol Thresbold Opn) PEL,4WA (Dpm) TLVAWA (ipm)
1.1.2 25 so/Skin so/Skin 1. 0. 1 Unavailable 100 100
c€rersl-Causes significantiniury lo the surlace ot the 6ye. Flepeatedskin contacl may haw a delatting actbn inhalationol high vapor concentrations.Prolongedor repeatod skin contact may cause defatting
on the skin and may produc€ dermatitislrom daily conlact. Avoid prolonged and repeated breathingol of the skin and may produce dermatitisfrom daily contact.
vaDors.
synptons-Headache, dizzinessand respiratoryirritation.
Short Erporuc Tolerre1sO PPm r Short ExD$ure Tol€mce-1s0

and diziness
ppm for 30 minutgs.
ErDoure Prcedurs-Vapor-remove victim to lresh air; il breathing stops, apply artificial respiration.Skin or
eye contact-remove contaminatedclothing and gently llush aflected areas with water lor 15 minutos.Gol
medical advice or attenlion. r ExpocurePruedurs-Vapor-remove victim to fresh air. Give artilicial respirationif breathingslops. Skin or eye
conlact-remove contaminatodclothing and gantly llush atlocted areas wiih water lor 15 min. Get medical
helD.
Strbility-Stable.
REACTIVITY DATA
t- Strbilitv-Stable.
REACTIVITY DATA
ConDdlbtllty-Mrterhl Rscommend carbon sleel lanks, valves, and piping. Water-frs€ n-butanol rsacts wilh
aluminumat tsmoeraturssabove 120'F.
csso: Group 20 ot compatibility chan. See also App€ndix l-Exceptions lo th€ Chart.
r CooDrdbility-Mrterid: Usual materials o; conslruction are suitabl€.
Crrro: Group 20 ol compatibility charl. See also Appendix l-Excsptions to the Chart.
SPILL OR LEAN PROCEDURE

Waa. rubbar glovor, lrca rhield, prot€ctive clothing. Hlve all-purpo6€ csnister mark |vrlhble.
w'lh lhukt. Socure hnition lourcos.
Avoid conLcl
r with liquid. Socure ignaiionsourcoa.
Wsar rubb€r gloves, tace shield, protectiv€ clolhing. Have all-purposs canistd mask availabl€.Ayoid conlacl
lt I trlll acu, cil th. Nraloul ROor. (tDa.., tlH2a-tt t.

l- lt I t lll acun, cdl aic
lrrtr:
tc SCANNED BY MKP & BARIS A. 2004 It ! , .,'

.rl*.,-**..
tert-BUTYLALCOHOL
I I iso-BUTYLAMINE
syMyr Alcohol C-4; lerl-Butanol;
TBA; Trimslhyl carbinol
2-M€thyl-2-propanol;
cHRts code .........

. .. 1120
UDittdN.dou Nmber..................'........
BAT
n Syronyms- 1-Amino-2-Methylpropane;lsobutylamine;
mono-lsobutylamine:2-Methylpropylemine
Unliad Nrtions Numbcr..........
CHRIS Codc..........
_1211_
IAM
r
"all isomers" BTY
--J',
Fmrb-(CHs)sCOH Fmulr-(CH:)rCl|Cl'LNHr
Boilin8Poinl.......................... 83'" BoilinsPoint.......................... 66"C 151'F
Appernnce-odor-Colorles liquid or crystallinesolid; _'c _'F Apperrme-Odor-Colorless liquid wilh ammonia.lik€ --go:3
pungent,camphorlike odor ........ 26'C 7A'F mot. Frezins Point......... ... -t*-:F
Fredrg Point.........
SDecilicGr8rity-0.78 at 26'C (a liquid) _'c _'F Spctftc Gnrlty-O.73 _'c _'F
C'hemicrl F.mily-Alcohol
Pollution c.tegory-USEPA - IMO lll

Vepor Preure 20'C (68'F) (mHt)..........
Reidv.por Pr6ue (FirI..........................| 8
Vrpor Prwure ,16'C (f 15'F) (Ddr)............-
Vrpor D€Nity (Air : 1.0)...........................
30.6
2.4
2.6
l-r Ctemlcd Fmlly-Alkyl
Pollution Cstc8ory-USEPA
aming
C fUO C
Valnr Prsue m'C (6S'F) (mmHg)..........--2.1.€-
Reid vaDor Presure
VrpoiDensity(Air: 1.0).....................2
2.4
(psia)...........................
VaporPrwure 46'C (115'F)(DEir)............. 3.2
. ...5. . .
ADpltcrbleBulk Reg.,16CFR Subchapter........ D Solubility itr Wrter . Comolele ADplicrbleBult Reg.,15CFR Subchapter........ O SotubilityinWater.......................,.Comolet€
Gnde-C: Flammableliquid
FIRE & EXPLOSION HAZARD DATA fi Gnde-C: Flammableliquid
r
El€ctricd GrouF-D Electricd GrouF-D
Cere.d-Dangerous when exposed to heat or tlame. Flashbackalong vapor ttail may occur. Vapor may Gene.rl-Toxic oxidss ol nitrogen may b€ lormod in fir€. Flammabl€,high lir€ risk. Flashbackalong vapor trail
explod€ if igniled in an enclosed area. may occur. Vapo. may explode il igniled in an onclosed area
Flsh Point ('F)...... 52 (cc) (tert-Burylalcohol is elid at 52'F) Fhsh Point ('F).............................
10
Fhomble Lintts..............-.--..... 1.7 to 9.8%
l ,
Ffammable 2.4 lo 8.Oy"
Limits..........................
AutoigDitiorTenp. CD ................892 AutolgnitionTenp. ('D........,.......712
ErtinSuirhlngAgents @r, dry chemical,alcohol loam, wat€r fog ErthSuirhing Agert!.........-.-.......Dry chemical, alcohol toam or carbon dioxid€.
SpecislFtre Prcedu6................ Water may be inetlective on lire. Spodrt Ftre Preedro................ Walgr may b€ in€fisclive, hjt should b€ ussd lo ke€p contain€rscool.
ll
Hqlth Haard Rating Odor Thrshold (DDE) PELAWA (DpE) TLV,/TWA (ppm) Hedth Haad Rrdryr Odor Thr€shold (ppm) PEL,/TWA (ppn) TLVAWA (pDm)
1. 0. 1 Unavailable 100 100
General-Avoid breathinghigh vapor concentrations.Prolongedor repeated skin contact may caus defatting of
the skin and may produce dermatilisfrom daily contact.
fi 2.3. 0 Unavailable
Gencrd-Moderately toxic, eye, skin and r€spiratoryiritart
s/Skin' s/Skin'
symDtorHeadach€ and dizziness. SynDtorLoss of con$iousnsss may occur. lf iaken intgrnally,convulsions may also @cur.
Short Erposm TolermcFunayailabls

l-l Shorl ExporureToleruce-10-15 ppm is highly irritaling.
ExporurePrcedureVapor-remve victim to fresh air. Give artilicialrespirationif breathing stops. Skin or aye Erpcure ProcedeR€move clothing and shoes. Flush aftected areas with plenty ot water. lf in eyes flush
'l eyes thoroughlywith waler. lf taken internally,and viclim is conscious, have him drink watgr. ll victim is
conlacl-remove contaminatedclothing and gently llush attected areas with water tor 5 minutes.Get
medical advice or attention. unconscious,do nolhing except keep him warm. Call a doctor.
stlbiltty-slabl€.
REACTIVITY DATA r REACTIVITY DATA
-Stable. Keep separat€dlrom heat and oxidants.
-Meterid: Usual malsrials of constrstion are suitabl€. Conprtibillty-Mderi8t Stor€ in carbon steel, aluminum, stainl€ss steel tor purity. Copp€r and its alloys should
NOT b€ us€d.
c|rjo: Group 20 ol compatibility chart. S€€ also App€ndix l-Exc€plions to lho Chart Crr8o: Group 7 of compatibility chart.
SPILL OR LEAK PR(rcEDURE SPILL OR LEAK PROCEDURE

Wary rubb€r gloves, fac€ shield, protoctive clothir€. Hlve all-purpooa canisler orad( |YalbbL. Avold con||cl Woar butyl rubb€r gloves, prolective clothing and self.contained breathing apparalus. Avoid conlact with
wl0t l$rd. Securo ionition sourc€s. liquid. S€cure ignilion sources. Cover spills with sodium bisullate and spray with large amounts ol water.
ll r rdll eun, c.ll thc N.tlad nm.. Crlr. lll{l}llt lt I slll m. c.ll th. Nrtlond R6Du Cctricr. flX'..42,a-EAD"
lryb;
"-- - &L;ild -;- r/&adr .i.,

ry
!l t)
Synonymr-1-Aminobutane; l-Butanamine;
Butylamine;
N.BUTYLAMINE
ll25
UnitedN.tions Number..................,......,....,.
rl 8EG.BUTYLAMINE
n
Mono-n-butylamine;Norualamine Synonyms- 2-Aminobutan€;2-Butsnamin€;1-Methyl
propylamin€
CHR1SCode........... .... BAM

"all ismers" BTL
llM- cHRls codt "
"all isomors" BTY
Fomula-CHsCHzCHTCH'NH,
t-l
EofltnSPoftrt.......................... 78"C 172'F Fomulr-CHTCH(NHr)Gft
ADDe$anceodor-Colorless liquid with a pungent, -- 8o1||nsPohl..........................
------€l'C 146"F
ammonialike odor Frezitrs pobt......... . .. . . so'3 :.-:: Aplnrucc-odc-Colorl€8s liqukt; ammonilJike odd.
SpecificGr8vity-o.74 _'c _'F r.rcthrportr.....,...................
---=r!li! :,i
Vrpor Presure 20'C (68'D (nnH$.......... --.92- SpeclficGrevlty-0.73
Ctemicd Flmily-Alkyl amine (psis)........................... 1.39 v.tnr Pre 20'C (60'F) (nnHg.......... --J-4Q-
l-l
ReidVrpor Pressure
veDorPr6sure46'C (f15'D (Dcit)............. 2.7 Chemlql Frnlly-Alkyl aminog R c t d V | D o r P u u r c ( p h ) . . . . . . . . . . . . . . . . . . . . . . . .6. ...1
Pollution Crtegory-USnPl C IUO C V a D o r D e n s i t y ( A:i r 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . 2. ...5. . . VryorPuurc4S'C(ll5'F)(F||)............. 8.O
Pollulton Crt€8ory-USBPt C fUO C VrDorDcElty (Alr = t.0)................-.........- 2.52
ApplicsbleBulk Reg.{6 CFR Subchlpter........ O Solubilityinwrter......................... ComolelE
n
ADpltsble Bull Rq. l|6 CFR Subchrlric........--9- solublllty In wd6.....-.--..---..... ---Co!n!gle-

Gndec: Flammableliquid FIRE & EXPLOSION HAZARD DATA
Electricrl CrouFD Grade-C: Flammable liouid
n
Eletrical GrouP-D
General-Toxic oxides ot nilrogen may bo formed in lire. Flammable,dang€rousfire risk. Flashbackalong vepol
lrail may occur. Vapor may explode il ignited in an erclosed area. Toxic oxid€s ot niirog€n may b€ form€d in fire. Flammabl€,dangarous lirs risk. Flashbackalong vapol
trail may occur. Vapoi may explod€ il ignit€d in an anclosed arsa.
Fbsh Point CFr.............................
10
F|rmfrsbleLinits..........................
1.7 to 9.8"6 f l s h P o i r t ( ' F ) . . . . . . . . . . . . . . . . . . . . .1. .5. . . . . .
AutoignitionTenp. ("F) ................
594 Flumrble Linits.......................... Unavailable
Confined-drypowder, CO2.Open-water,polar solvent foam.
ExtirguishingA9erts.....................
SD€cialFire Pruednr6................ Ke€p tanks cool ith water spray. Providefire fightors with proteciive clothing
and solf-containedbrsathing apparalusagainst toxic tumes.
l-l Autolgtritlon Temp.('f)................712
ExtinguichingAgentr............--.....Contin€d-drypowder, COz. Open-polarsolvent loam, water.
Speial Fire Pr@edur6................Keep tanks cool with water spray. Provide tire lighters with protecliv€ clothing
and slt-contained brsathing apparalus.
Health Hsard RstitrSr

HEALTH HAZARD DATA
Odor Threshold (ppn) PEL,/TWA (pDn) TLvlTwA (pDD)
4.4.4 1 to 2 s/Skin s/Skin
General-Poisonous if inhaled or if skin is exposed to the vapor. Irritationot eyes and rospiratorytract, sovtrs
damage atter conlact of short to moderate periods.
Symptoms-Severedamage to skin or eyes by liquid,iritation ol upper respiratorytract and eyss, mild

n Hedth Haad Ratingr
3.2.3
GcDml-Moderat€ly toxic.
(Xor Threshold (ppm)
Unavailable
PELAWA (ppm)
s/Skin'
TLV,/TWA (pDn)
s/Skin'
headachesand tlushing of skin ol face, cumulativeetfects have not been obs€ryed.

Short ExposureTolelurTen to 15 ppm is highly iritating during short exposure;3'100ppm killsd 3 out ol 3
rats in 50 min.; whereas rats suryiveda single 4-hour exposureof 2000 ppm. Hazards unknown loJ humans. n SyDDtoro-Coughing, irritationof eyes and mucous m€mbranes,redness or irritationol skin.
Short Expcure Toleruce-Unavailabl€
n
ExDGor€Preedur€FFlush skin or eyes immediatelywith large amounls ol water for approximately15 minulss.
Remove all contaminatedclothing and flush underlyingareas with waler. ln case ol eye contacl or ExDGurePr@€durFFlush skin and eyos immediatelywith large amounts ol water for 15 minutes. In case ot
inhalationof high concentrationsof vapor, viclim should be immediatelyplaced under physician'scars. sys contacl, inhalationol high conc€ntrations,or ingestion,victim should be placed und6r physician'scar€.
REACTIVITY DATA
Strbility-Stable, but readily combines wiih acids, aldehydes,chlorohydrins,and organic aullur compounds. REAC:TIVITY DATA
Strbility-Stablo.
rD.dbllity-Mrterid: Store in carbon steel containersor aluminumor stainless stssl for purity. Copp€r and
ConFtlblllty-Mrtcrlrl: Carbon dd.
l'
its alloys should not be used.
Cugo: Group 7 of compatibilitychett.

Cupr Group 7 ol compttiull9 ahd

s t D i l . l .( ) R l , l : A x l ) R t x ' 1 , ' t )rtR ] :
Wxt butyl rubbs glovss, protoctive clothing, seltcontained broathing apparalu!. Avoid conLcl wilh liqu(l
S.cqa lenition sources. Covar spill with sodium bisultal€. Spray with llrga amountr ol wabr. Eurn in op€n prl Waat buiyl rubbar b@la, glovcr, l'olqrtryo (:krlh!{r. sll i iill.rEl |ro.lt*n argartt|,| AyO.d mtrcl itth
rttf, (laolving in wesl€ elcohols or in an incin€rstorwilh atl€rburn€rErnd rcrubbd. liquld Socu,e Onrlon nrcar Oovd $th nrhrm ttrull.lo.rrl f.rh nlh tt nly d falr-o. tLolv. h wtrta
tlcoholr rnd bi/rn gurn h ofrn lrl q h rn rmrErk, -th .ltr lrrrr rtt r,rlir
lf . rDlll {Kcrc crll the Nrtiond RrDu Ctltar. reata-tto:.

lt . |'lll d.rn, ..ll rL N|.lql
lr!la '
ltorrlr. l'l I drtl l l V l[nr{t r4xrr ,r llulyl.rtl|t
I U.rart.e,rJ
, f SCANNED BY MKP & BARIS A. 2004

tert-BUTYLAMINE BUTYLBENZYLPHTHALATE
United Nrtions Number Synonyns- BBP; Bonryl n-butyl phthalat€; Phthalic Unlt€dNrtloN Nunber....................
Synonymr- 2-Aminoisobutane;
acid, b€nzyl buM 6lh€r; Santicizer 'l0O
2-Amino-2-methylpropane;
1,1-Oimsthyl€thylamine;
Trimethylaminomolhana
Dimeihyl ethylamine;
2-Methyl-2-propanamin€;
CHRIS Cod............ .... BUA

"all isomers"
-E;ry-
t- CHRIS Cod........... ...... BPH
Fomrh-CTHoCOOQH.COOCHTC.H., or CrrHrOr
Fomule-(CHs)rCNHr
ApDearsnc€-Odor-Watetwhite liquid;ammoniacalodor
SpecificGrevity-O.70
BolllngPoint.......................... 45'C
-'c
FreezinsPoint........................ -67'C
-'F
_'c
113'F
-88'F
-'F
I charact€nstacodor.
Sp€cilicGnrlty-1.'12
oily liguid; slighl,
Bollla3Po|nt.......................... 370'C
Fcd!8 Polnt........................ -35:3

_'c _'F
698'F
-t:F
Vrpor Prwure 20'C (68'D {nnHg).......... -30- Vrlnr Prwurc al'C (60'D (nnH$
1l
C'hemicrlFmlly-Ester Rcld Vrpor Ptwsrc (Fh).......... ............. Ld
C'hemicalFanily-Alkyl amino Reid Vapor Presure (Dcia).........
Vepor Pwure 46'C (ffs'D (Doir)............. 15 Velor Pruurc l6'C (lt5'D (Flr).............--Igd-
C 2'5 Pollution Crtegory-USEPA B IMO A 1O.8
VrgorDculty(Atr : 1.0)...........................
Pollution category-UsEP^ IMO ----8- VrtorDersity(Air : 1.0)...................'.......
O Sol$ilityhwrt€r.................-...... Comolst€ ADpllcsblcBult Re8.46 CFR SubchrDter........ D. O Solubllltyinwrter......................... Neolioibl€
ApDliqble Bulk Reg.46 CFR Subchail.r........
crrde-B: Flammableliauid
FIRE & EXPLOSION HAZARD DATA Il Combustibleliouid
Electricd Group-D
n
Eletricd Croup-D
haard slight when exposod to heat or llame. Carbon monoxids, carbon dioxide,and wat€;
cenenl-Toxic oxides of nitrogon may lorm in firo. Vapors lorm explosivemixtureswith ai]. Flashbackalong produced by combustion.
vapor trail may occur. Vapor may explode if ignitsd in an enclosed area.
Flsb Poirt CD.............................
390
about50
Flsh Point CD.............................
Flmmrble Limits..........................
LEL:0.26"/. (calculatsd) UEL-Unavailable
1.7 to 9.0%
Fl.mmableLimits..........................
AutoignitionTemp.("F) ...--......... Unavailable
AutoignitionTenp. ('F)........,.......
612
ExtinSuishingA9erts.....................
Confined-Cq, dry chemical.Open-water, toam.
ExtirSubbitrgAgenb Dry chemical,alcohol foam or @,
SDecidFire Prcedurd................ Water or loam may cause €xtsnsive lrothing.
Specid Fire Pr@edur6................Keep tanks cool with waler spray. Providelire lightsrs with prottrtive clolhing
and slf-contained breathing apparatus.

PELAWA (ppn) Hedth Hezrd Rrtings Odor Thrshold Qpn) PELITWA (DDd TLVITWA (DpD)
H6lth Hrard Rrtingr Odor Threshold (Dpm) TLvlfWA ODr)
1, 1, 0 Unavailabls Unavailable Unavailable
2,2, g Unavailable s/Skin' s/Skin'
G.Hl-No apparsnt hazards-low loxicity.
c4neirl-Causes irrwersible damage to eye tissue. Moderat€lytoxic by oral intake. lritating lo eyes, skin,
lungs. Not absorbed through skin.
toxicily.
Symptoms-Red or irritatedsyes or skin, coughing,irritationof mucous membrane,nausoa
Erposure TderucFwill not caus iritalion to skin.

sbort Erporurc Toleruce-Animal lest for liquid eye irritation producsd destruclion ol corneal tissus with 2-3
min. Vapor inhalationtor 5 minuteswas fatal to test animals-
Expoeure Praedueskin coniacl-wash atfected areas with wat€r. Vapo. inhalation-remove victim to fr€sh
ErDGure PrftedureFlush skin and eyes immediat€tywith large amounts of water for 15 minutes.Rsmove all
air. Call a doclor.
contaminatedclothing and flush underlyingareas wilh waler. In cas ol ey€ contact or inhalalionol high
concentrationsol vapor, victim should be imm€dialelyplaced under physician'scare.
Strbiltty-Stablo.
ComDstibility-Materid:
REACTIVITY DATA
D@sn't react with stoel, wood, cloth: softens rubber and paint
r REACTIVITY DATA
strbility-Stable at modarale temporatures;no spontan€ousdecomposition.Can reacl with oxidizingmaterials
Oestructivs to rubb€r and paint. No etf€cts on steel, wood, or cloth. Fo@man€nd

conl,ainersol steel.

cr8o: Group 7 ol compatibility chart.
SPILL OR LEAK PROCEDURE SPILL OR LEAX PR(X'}:DI'R}:

woar rubbor glove!, laca thaald. conlim .nd rb|o(b on ertrbb matf,r.t rFh r| rafir||1. oLt, o, ilL,oal
Wear butyl rubber protective clothing, sell-containsd br€athing apparatus. Avoid conLact with lkluid. SacuTa
May bc inclrrjricd.
ignition sourcss. Covsr with sodium bisultale and wash with planty ot watsr. Do not llush spill inlo conimd
spacg8 whora ttammable vapors can accumulate. Eurn in an op€n pit or an incine.ator with stiafbgam and
rcrubb€r.
ll r d0 tcun. (rll lL N.thd
lf r tDlll ccun, crll thc N.alold nOOx Canl.r, llX)-afCt02'
lrll ' V.po. Pr.ru.
' PEL 0 tC mmHg.t t!o.C,
lcnrrl.: and TLV blrd upon n-Butylamina
I Un0..grn
t Una.dgn d
i l l
. i *
{ ! . a 2 , i l
at
4&$aq;" --t*i&.
BUTYLENE BUTYLENE
MIXTURES'
Symlym- No common gynonym8.
syrot[- Butenoi l-Butgno; alpha-Butyleno;
Elhyloihylsnc
I
Fornule-Grl{
Fomula-CFh : CHCHzCHT
Appemce-odor-Colorless gas; sweelish odor

Boilin8Poirt..........................----=-A"C
. ......
Frtrzir8Poht..........
--tae'3 -:r*:F
21'F
fi Appearrncc-Odor-Gaswithgasoline-likeodot.
SpecillcGrrvlty-Unavailable
:
SD€clRc
Gnrlty-0.60 at 20'C (a liquid) _'c _'F
Ctemicd Frmlly-Olefin
Pollution Crtegory-USEPA - IMO ----ggii-

v.por Prsure 20'C (66'F) (nnHg).......... J9!lQ-
Reid Vspor Prsure (pEir)..........................
vrDor Ptwure 46'c (rrs'D (Dsid............. 76
VaporDeBity(Air : 1.0)...........................l'94
l-l C'hemlcdFrnlly-Ol€tins
Pollution Crt€gory-USEPA - IMO ---.9S9-

ADplieble Bult ReS.a6 CFR Subchapter........ D. O
Applioble Bulk Re& ,16CFR Subchrpter........ D. O Solubilityin Wster......................... lnsoluble

FlammableGas (LFG)
rl FIRE & EXPLOSION HAZARD DATA
LiquetiedFlammableGas (LFG)
r
Eletrical Group-Unassigned
Eletricrl Group-D
the flow ol gas can b€ stopped, extinguishinga fire will p€rmit lhs accumulationol an
the flow of gas can bs stopped, exlingubhing a butene fire will permil accumulationol an explosive concenlralionot vapor, and subsequenlgxplosion or re-flash.
sxplosiveconcenlrationol vapor, and subsquent explosionor rejlash,
-24 approximately
Flsh Poirt Cn.............................
Ftsh point ("F).............................
110 (cc)
Fhmnrble Limits..........................
1.0 to 10.Oolo(approx.)
t-
1.6 to 9.3%
Flmmrble Limits.......................... Temp.('D...-...........615 to 725 (approx.)
Atrtoignition
ArtoignltionTemp.('F)................723
ExtinSuishingAgent! Stop flow ol gas; COi, dry chemical, water spray
EttinguishitrSASents Stop tlow ot gas; Coz, dry chemical,waler log.
cid Fire Prcedrr6................ Use water lo cool conlainers in order to reduce possibilityof rupturing tank.
SDsld Firc Prcedus................ Ke€p burningtank and adjacent ianks cool with a water spray' Try to seal the gas leak. Use water spray to knock down water vapors. Flash back along vapor trail may
occur

Herlth Hryd Rsdl8| Odor Thr6hold (ppm) PELAWA (ppn) TLVAWA (ppn)
H6lth Hred RstinSr Odor Thrghold (Dpn) PEL,/TWA (pPm) TLV^WA (p0!)
1. 4, 0 Unavailable Unavailable Unavailabl€
Unavailable Unavailable Unavailable Unavailable
non-toxic at low concentralions. At higher concentrations, it can acl as an anesthelic.
Generrl-May produce an€stheticetttrts on €xposure lo high vapor concentrations.Contact with liquid may
produce a trostbite.
Syrptorcauses diziness and ditficull breathing.Liquid will cause lroslbit€.
t-
Symptom-Breathing high concentrationsof gas for some time may cause dizziness.Coniact with liquidmay
cause skin and eye injury similar to lrostbite.
Short Exposure Tolemce-Unavailabl€
Short Exp6ure Tolerurunavailabls
ErDGrre PrftedureFRemove lo lrssh air. ll brsathing has stopp€d, give artiticial repiration. ll the liquid hag
spilled onto the skin, points of conlact may be frostbitten;handle gently and protect from mechanical
damage.DO NOT RUB. Get medical atlsntion. r ExposurePrcedurg-Remove victim Jp lresh air. lf breathing has stopped, administerartificial respiration.ll
br€athing is difficult,give oxygen. ll the liquid has spilled onto the skin, points ot contacl may b€ trostbitten;
handle genlly and protect trom mechanical damago. DO NOT RUB. Get medical attention.
REACTIVITY DATA
Strbiltty-Stable. Can reacl with oxidizingmaterials. r Strbility-Will react with acids and alkyl halidss.
REACTIVITY DATA
Conpatibiltty-Md€rirl: Noncorrosive to most malerials ot construction.
crSor Group 30 ol compatibilitychart.

r Comprtibility-Mrt€rtd: Usual mat€rials of constructionare suitable.
CrBo: Group 30 of compatibilitychart.

Wear rubb€r glov$, lac6 shield, proieciiv€ clothing. Hav€ all-purpos€canistor mask eveilable.Securo lgniton
Wear rubber gloves, faco shield and proteclivo clothing. Have all purposs cenisler maak availeble. Kcap
concentralion of leaking gas bolow explosivs mixture range by v€ntilation. S€cure lgnition sourc€8. Oo not llush
sources.The spilled liquid will boil away rapidly,leaving no r€sidue.
ltrr0lGnolltL
t- spill into confinod spaces wher€ flammabl€ vapors can accumulalo.
' Soms drL

lf . eplll acu6, cdl thc Nrtloml Rdril Ccrtrr, gH2a-1t02.
Rruh: !16 undolorminabL baclu!€ lhb cllegory conlidorr mifirt Ol britylf,tl,
lJtr
l- * Unarlignad
.
SCANNED BY MKPo L&, n BARIS A. 2004 ,.-fS i.il1d4L,rrl4;E-
4t
it -.-t-;--.".**".**.-r5rl . -..1",
l,3.BUTYLENEGLYCOL t 1,2.BUTYLENEOXIDE
symyr- Eutans-1,3-diol;
1,3-Butanediol; Syronyr 1,2-Bulyl€n€oxide, stabilized;
bab-Butyl€neglycol;1,3-Dihydroxybutans;
Malhyltrimethylen€glycol
t alpha-Buvten€ oride; 1,2-Eporybutane
Fmulr-CH:OHCH,CH(OH)CH!
ADDcmnce-Odor-Practically colorle$; odorlsss liquid.

BoilingPoint.......................... 2O7'C ----..1lQQ'F
Frezins Pofrt...................
-zg "3 ^:i
r Fomuh-HzCOCHCI'lzCHs
ADD€soce.odor-Colorl$s liquid: sharp, pungenl odor

-----6?'C
BolllngPolnl..........................
-'c
---:54'C
FrezhsPolnt........................
_'c
-'F
_'F
146'F
-58"F
n
Spelftc Grrvity-l.01 -'c -'F Spccilic Gnvtty-O.83
VrDor Prsure 20'C (5t"F) (mnHg).......... --9.0€- Vfpor Prsuc 20'C (68'n (nHd .......'.' 2O7
Ctcmical Family-Glycol R e i d V e p o r P r * u r e ( p s i 8 ) . . . . . . . . . . . . . . . . . . . .L. o w Ctemicd Fully-Alkylene oxid,o ReidVrpor Prwure (ph)......................,....5.8
VaporPresure,l6'C(U5'F) (Dsir).............Low Vspor Prwur€ a5'C (f 15'D (Flr)............. 7 '2
Pollulion CrteSory-USEPA - IMO D V8porDensity(Air : 1.0)........................... -jlQ- Pollution CrtoSory-USEPA - fUO C
n
Applieble Bulk Reg.,15CFR Subchrpter........ D Sototititvin Watcr.........................Comolet€ AppliccbleBulk R€g.il6 CFR Subchspter........ O Solubtlity in Wilq....
cndFE: Combustibleliquid GrrdeC: Flammablolhuid
n
Elctrlcd GrouP-D Eletricd GrouF-B
censd-Slight fire haard wh€n sxpog€d to h€at or tlam€. cercr8l-Very flammable and vapoG ar6 highly llammable, ev6n €xplosive. Fir€ or contaminationmay caus
violenl rupture of tanks. Flashback along vapor trail may @cur.
250
Flch Poirt CF)............................. lsss than -20
FlEh Point CF .............................
Unavailable
Ilmmsble Lintts.......................... 1.5 to 25.1%
Ftumble Limits..........................
AutoienitionTenD.('F)................
ExtinguishinSASanb
7't0
Waler, carbon dioxide or dry chemical,alcohol toam.
Specid Fire Prcedurg,............... Cool exposed tanks with water,
l--l AutoignitiotrTenp. CD................ 959
Confined-Co2. Op€n-Water, foam.
Extinsui8hingAgentr.....................
Speid Flrc Prcedrc ................Cool tanks with wat6t spray. Us€ water spray to
"knock down" vapot'
HEALTH HAZARD DATA

Health H@rd Rrtiryr
0.0.0
cercld-Not
Odor Thrchold (ppn)
Unavailable
PEL,/TwA (DpE)
Unavailable
consideredtoxic under ordinarycondiiions of handling.
ILVITWA (ppn)
Unavailabla
r, Hedth Hrud Rrtingr
Noi Listed
Odor Thr6bold (ppm)
Unavailable
PEL,/TWA (ppm)
Unavailable
TLVITWA (ppn)
400'
Cenersl-lritation of eyes and respiralorytract. Oversxposurewill cause serious injury.Contact with eyes will
cause burn. Contact wilh uncovgred skin produces frostbite. Ingeslion will caus $rious illness or dealh-
Symptom!-Unavailabl€ Synptoms-Coughing, watering eyes, sickness of stomach, frostbitten skin.
Shorl ErDosure Toleruce-Unavailabl€ l- short ErDosw TolemrProlonged coniact with skin caus€s frostbite burn.
Erp6w Pmedures-Vapor-remove
with water lor 15 minules.
victim to tresh ak. bkin or eye conlact-gently flush contaminaled areas
r ErDqw ProedueVapor-remove victim to lresh air; if breathing has stopp€d, use orygen inhalation. lf
ingssted, make victim vomit, at least 2-3 times, and then give victim a tablespooGol Epsom salt in glass ol
wat€r. Flush eyes immediatelyfor approximately15 minutes. Remove contaminated clothing or other
wearing apparel immediately.Clothing can seldom be d€coniaminatsd.Wash skin with soap and water.
REACTIVITY DATA
st.blltty-Stable. Can react with oxidizingmalerials. r REACTIVITY DATA
Stlbility-Thermodynamically unstabl€;d€composition is rapid. Polymerizalionwill occur in presence of acids,
bases. and certain salts.
ConDrtlb[lty-Mrtcrld: Usual matorials of conslruction are suitabl€.
c|rgo: Group 20 of compatiulity chart. S@ al$ App€ndh l-Excaptons to lh€ Chart.

r Mild steel or siainless steel is unattected.Storage tanks and olher equipment should
b€ absolut€lydry and free lrom air, ammonia, acetylene, hydrogen sulfide, rusi, and other contaminanls.
Corgo: Group 16 of compatibilitychart.
Avoid contlct with llquid.

r SPITJLOR LEAK PROCEDURE
Evacual€ area, w€ar respiratory proteciive d€vices as wsll as imp€ruious clothing (boots, gloves, olc.). Use
large amounta ol wat€r to dilute to at l€ast 22 parts H,O to I part ol oxid€. Leaking conlaingra should be
lf r olll ccrn, cdl lb ildill Oar.r.

l- imm€rsod into largo amounts ol waler il possible. Sscurs ignition sourc€s.
It r &lll @il crll tL Nralonrl RqDu Crtrlcr. 8l{24-tt02,
r.-b lnrtl ur In furd 96! lo dlrplace lhe air In itl. storrgo ol butylem oxkf.
l-r
I Unaragmd ' Vd,. obLlned irom I CG-4355 lorm: hosavf,. lhi| valtx war nol conltrtiad.
'6 SCANNED BY MKP & BARIS A. 2004 a1 .J_.*

N.BUTYL ETHER
il BUTYLMETHACRYLATE
Synonyns-1-Buloxybutane:Butylether;Dibulylether;
D-n-butyl sther: n-Oibutylether; Oibutylethers;
Oibutyloxide; 1,1'-Orybis[butane]
CHRISCod............
1149
UtritedNstionsNumber........................,.-....
DBE
.................
n Sytronyro- Butyl 2-m€thacrylat€;n-Butyl m€thacrylatet
n-Butyl alpha-mslhacrylalo;Butyl
2-msthyl2-p.op€noate;Meihecrylic acid, butyl oat-
Udt.d Nrtlor
cHRls codc..........
Nub.r...... ..........................
-WI-
....,-EUlt-
Fomulr-(CrHe)zO
AppcerrnceOdor-Colorless liquid;mild, Pleasant,

ethetrlikeodor Frecrins ..........
142'" l',
8ot1tn8po.nt..........................
----:-95t8:jE
Poilt.............
tl Formulr-CHz = C(CHs)COOC.Fb
AgD€srncc-Odor-Clear, colodess liqukl wilh ! lypical

acrylate odor
Bolllq Polnl...............,.,........
..
FElnB Po1trt..........
-1t5'C
-t"F -g3:3
311'F
Spcinc Grsvity-O.767 SpecificGr.vity-O.88 _'c _"F
Ctenicrl FMily-Etherg
PollutionCrte8ory-USEPA - tvO C
Vapor Prmure 20'C (68'D (nnHg).......... ---4'9.-
Reidvspor Pre$ure(psia)...........................
VlDor Pressure
vuor Density (
il5"C (115'n (psia)....... ---gI-
A i r : t . 0 ) . . . . . . . . . . . . . . . . . .
----l-
. . . .4. .5. . .
I I Ctenlcd Frnily-Acrylate
Pollution CrteSory-USEPA -
(monomer)
IMO -Q-
v.!pr Prwure 2O'C(6t'D (nnHd..........---31-
Rcld Vrpor Presure (!dr)......................,....
VeporPrwure i5"C (lls'D (psh)............. 0.29
--!9!{-
V a p o r D e n s i t y ( A t r : 1 , 0 ) . . . . . . . . . . . , . . . . . , . . .4
. ...9. . .
O solubilityin watei......................... Neolioible Appllqble Bulk Re& 46 CFR Subch$ter ........ O Solubility ir Wster o.4vo
ADplicrble Bulk Reg. ,16CFR Subchapter........
Combustibleliouid
tl Grade-D: Combuslible liouid
rl
ElectricalGroup-C Eletricd Greup-D
cererrl-Flammable, iritating vapors are produced. Flashbackalong vapor trail may occur. Vapor may €xplodo Generd-H€at will increas€ goneration ol toxic lum€s.
if ignited in an enclosed area. Ground all equipment and personnel!
92
Flsh Poirt Cn............................. Flsh Polnt CF).............................
105
AutoiSritiorTemp.CD................
1.5to 7.6%
Flmmrble Linits..........................
382
Dry chemical,alcohol loam, CO,
ExtinguishitrgAgerts.....................
SpecialFire Pr@edur6................Containersmay explode in fire. Water may be inettective.Cool exposed
I I Flunrble LiDits..........................
AutoignitiorTeDD.("D.,.,,...........
2 lo 8"h (estimaled)
562
Extirguisbhg Ag€nts.....................
Carbon dioxid€, dry chemical or foam
SDccialFlre Pruedus................ Use water spray to cool fire expos€d lanks.
rl
containerswilh wats. S€curs ignition sourc€s.Wear gogglos or face shield, rubber glovos.

Herlth Haard Ratitrgt
Unavailable
Odor Threrhold (ppm)
Unavailable
PEI-.,/TWA (Ppm)
Unavailable
cerent-Vapor irritatingto eyes, nose, and throat. Liquid irritatingto skin and eyes.
TLV/TWA (PDr)
Unavailabla
rl Hedth Hr8d R.dng.
1.1.2
Odor Thrchold (ppn)
less than 50
PEL,/TWA (Dpm)
Unavailable
TLVAWA (ppm)
Unavailable
Gcneral-Mild skin irritanl. Can be absorbed through skin and lungs. Ingestion may cause serious p€rman€nl
damage or death.
SymDtorlnhalation
contact.
Shorl ExposureTolemrData
causes iritation ol nos€ and throai. Liquid iritatss syss and iritates skin or prolongsd
nol available.
t1 SymptomFskin-mild
respiratorytract.
Short Expcure Tolrel10O
initalion and reddsning ot skin. lnhalation-iritation of mucous msmbranes and
ppm for on6 hour.
ExposurePr@edur#Remove to fresh air, administ€rartificialrespiralionor orygen as necgssary.Flemove

contaminatedclothing. Ftush areas with large amounts of watsr. It conscious, induce vomiting. G8l modical
atlenlion. SPEEO IS OF PRIMARYIMPORTANCE.
n Erpoiure Prcedurg-Skin-wash atfecled ar€as with plenty of water. Eyes-wash with cool wat6r to|ls
minutes. Inhalation-remove viclim to frosh air. Administsr artiticialrespirationit necessary,and th€n
orygen. In all cases call a doctor.
REACTIVITY DATA
Strbility-Stable. However,when anhydrous(dry),tends to lorm explosive poroxidesin air.
n REACTIVITY DATA
stability-Butyl melhacrylats is r€latively stable if properly inhibit€d. Exposure to oxidizers will initiato
polym€rization.
-Mrterirl: lron, aluminum,stainlessste€l, tin, polysthylene,porcelain,glass and enamel ar€

suiiable for conlain€rs. l"l Siainless ste€l is acceptable.
Csgo: Group 14 of compalibiliiy chart.
n
Cr4o: Group 41 ol compatibilitychart.

Mshanically contain matsrial and remove. Stay upwind. Wear lace shiald and rubbat glov.t, proleclrv(, Wsar rubber glovss, lac€ shield, protsctive clothing, Have all-purpose canisisr mask available. S@ure all
clothing. geware ot tlsrhbsck along vapor lrail. S€cur€ ignition surces. Ground dl cqtlgmanl and p.(rcnnall
l l ignilbn 8ourcss. Cl€an up liquid with pap€r towgls and burn und6r hood.
n
lf a tDlll m6, crll thc Nadnl nodx ( .nh. ll r plll acrn, cdl tb Nrdcd lcoou Ccatrr,8l{21-tdl2.
lnrlr: t Unrvrihda brrh
-i.
SCANNED BY MKP & BARIS A. 2004 - --','.-,-,.r":,.h"
iso-BUTYRALDEHYDE
lt; N.BUTYRALDEHYDE
Synonyms- Buiald€hyde;Butanal; n-Butanal;Butyl 1129
Urtt.d N.tlou Nunber.,..............................
rI
stronynr- iso-8u91aldehyde;lsobutanal; 2045
UnitedNrtiorr Numbcr............,................... aldehyd€;n-BuV alcl€hydo;Butyraldohyde;Eutydc
lsobutylald€hyde;lsobutyraldehyde;lsobutyric ald€hyd€
rld€hyde; 2-Methylpropanal
CHnIS Codr.......... ..... BTR
CHRIS Codc........... .... BAD
Fomuh-(CH:)zCHCHO
ApDe.rrnce-Odor-Colorlessliquid;pungent odol
SDe.ificG.svity-o.79
------€4'C
BoiliDsPotlt..........................
-'c
FrezingPoirt....................... -66'C
\47'F
- 'F
---=-QZ'F
-'F
n Fomu|.-CHsCHTCHTCHO
ADD.rmceodor-Colodes
Spectfic Gnvtty-0.82
liquid; pungonl odo(.
BolllngPo|rt.......................... 76'C
Frertn8potnr......... .........
--gg:3
-'c - 'F
169'F
-t*:F
vrDor Pisurc m'C (6S'n (DtHs).......... 91.5

C'hemicslFmily-Ald€hyde
PollutionclteSory-UsEPA- M C
vapor prwure 20"c (6s'rr) ,.."o
VsporDeNity (Air :
--:
5,0
ReidVsDorPresrure(prir).................,........,
vrDorPresrure,l6'C(115"F)(Dsis)............. 8.0
2.44
1.0)..................-........
ll C-tenlal Frmlly-Aldehyde
Pollutloo CrteSory-USEPA - tMO

ApDllqble Bull Reg. 15 CFR SobchrDtcr........
B
O
ReldVrpor Prsurc (Ddr)...........................
Vtpor Pressure 45'C (115'D (ndr).............
Vrpor D€n8ity(Air : 1.0).......,...................
Lg-
-0.0-
S o l u b i | i t y i n W s t e . . . . . . . . . . . . . . . . . . . . . . . .6. .' 5 %
2-14
Solubtlityin Wrter.........................
-10.0%-
rl
AppltcrbleBulk Reg 46 CFR Subchepter........
----Q-

FIRE & EXPLOSION HAZARD DATA Gndeo: Flammabl€liquid
Gndec: Flammableliquid Eletrical GrouD-C
Electricsl GrorD-C
Gererd-Fires are ditficult to conlrol because ot the ease with which the vapors reignite.These vapors are
Gcneral-Fires are ditficull to conlrol b€cause ol the sase with which ths vapors reignits. These vaPors arg readily ignited by static sparks of relativelylow energy. Flashback along vapor trail may mcur. Vapor may
readily ignited by static sparks ot relativelylow €nergy. Flashbackalong vapor trail may occur. Vapor may explode il ignited in an anclos€d arsa.
€xplode if ignited in an enclosed area. 20 (cc)
Flsh Point Cn.............................
-40
FlDh Point CF)............................. Flmnlble Limits..........................
2.47 to 10.6%
Autoignition
1.6 to 10.6%
FlrmmableLimits..........................
433
T€mD.CF)................
ErtinSuishingAg€nts Co,, dry chemical,water fog, alcohol toam'
SDecialFire Procedurc................Keep tanks adiacent to lire cool with a watel spray. Wear eye protsction and
l-l Artoignitiontenp. ('F)................
Extinguisbing Agetrts
446
COr, dry chemical, water tog, alcohol toam
SDecirlFtrc Pruedurs................ Fire parties should wear body and respiratoryprotection to guard againsi both
inhalationand liquid conlact. Keep iank cool with waler spray. Fight fire trom a sate distance,or lrom a
self-conlainedbrealhingapparalus. Drotsct€d localion.
tl HEALTH HAZARD DATA

HEALTH HAZARD DATA Odor Thr6hold (ppm) PEL,/TWA (pDn) TLVAWA (Dpd)
ri
Halth Hrand Rrthgs
Health Hurd Ratlnga Odor Thrdhold (Dpm) PELAWA (ppm) TLV,/TWA (pDm) 2,1,2 0.0046 Unavailable Unavailable
2, 1,2 0.047 Unavailable Unavailable
Ccrerd-lritalion and burns of th€ skin and eves follow contacl of short duration.
cenerd-lrritation and burns of the skin and eyes tollow contact of short duralion.
Synptoms-Coughing, waiering of eyes, and burning sensation in throat and nose.

synDtorcoughing, watering ol eyes, and burning sensalion in throat and nose. Drowsiness,incoordination,
headache.
Sbort ExposureToleruce-Animal experimentshave shown thal large doses produce depressionof the central
Sbort Exposure TolemcFAnimal experimenls have shown that large dosos produce d€Plsssion of the central ngryous system and anesthesia
neryous syslem and anesthesia.
ExposurePrcedurFvapor-remove victim to lresh air; if breathing stops, apply artificialrespiration.Orygen,
ExposureProcedures-Vapor-remove victim to tresh air; if breathingstops, apply artificialrespiration.Orygon, when administeredby trainsd psrsonnel, is helplul. Skin or eye contact-r€move contaminatedclolhing and
when administeredby irained personnel,is helplul. Skin or eye contact-remove conlaminatedclothing and gently flush atlsct€d area with water tor 15 minutes. Get medical advice or attention.
gently tlush alfected areas wiih water tor 15 minutes.Got medical advice or attonlion.
REACTIVITY DATA
Stsbilty-Underqoes rapid oxidalion to butyric acid in air.
I Strbillty--Oxidizes to butyric acid readily.
REACTIVITY DATA
t-
ComDrtibllity-Mrterid: Mild slsl is cotroded by butyric acid formed in presencs ol dr.
ConDdlbility-M.t€rld: Mild st6l is unsatisfactory b€cause ol corosive action of butydc acid.
c|rto: Group 19 ol compatibility chart.

Cugo: Group 19 ol compatibilitychart.

SPILL OR LEAK PROCEDURE Woar rubbsr gloves, ssll-conlain€d brsathing apparaius, prolective clothing. S€cure ignition sourc68. ll
Wear rubb€r glovgs, loll€ontained br€athing apparatus, proteciive clothing. Avoid contlcl wlth liquid. Sst'a possibl€, covsr spill with sodium bisultite. Add small amount ol water and mix. Scoop up. Wash th€ site with
lgnrtDn source!. It pollible, covsr spill with sodium bisulfite.Add small amount ot wsler and mix. Scoop up en<l aoap sluiion. Rags u$d to wipe up small spills should b€ immersed in watsr or removed to a sl€ area withoul
rmh away with r latla oxc€ss of walor, atter one hour. Wash tho silo with 8oap solution. delay oth€ili86 they may ignite spontaneously.
ll I rDlll ccun, cdl th. N.tlord ncrorx Crracr, tlXI-424-tC0l.
lt | .rlll Gu. sll lh. Nrtloul
lruh:
frcte

i
il
*L--t..:,- _--/.)t:.4lrl_.-
N-BUTYRICACID [-l CAMPHOR
OIL
............ 28?o
United NrtioN Number.................... Synoryro-Gum camphof;lmpurecamphor;Light 1130
Unttrd Nrtlons Numbcr................................
r
Syndynr- Bulanic acid; Butanoicacid; Butyricacid;
Elhylaceticacid; Propanecarborylicacid; camphor dl; Liquid camphor; White camphor oil
Propylformicacid
Fornuh-CHsCHzCHzCOOH Fomule-CroHreO
BoilingPofnt.......................... 164'C 327F 8o111tr8Potna..........................
-449'C -392'F
Appeamce-odor-Colorless liquid;pungent,putrid odor Appesrnce.Odor-Oily liquid,colorloss, brown or blue; -trpl! -"r
poht........................
Frezr's ------=tE :ii penotratingcamphor odor. pornr............
Frezrns ..........
SDecificGrsvity-0.96 SDecillcGrrrity-o.87 to 1.04 _'c _'F
-*-
crenicrrFmiry-Keron€ -+
creniorFamiry-orsanic
acid Hfi'rff".T::"11.:l$,"?.1::"-?-.:.:.'.'..
(r15"F)(Dci!)......... 0'07
I . . nfl"ffffi;:..f;r1.11111-...:.:.:.:
VqDr Pr{urc a6'C (lts"D (0dd.............
- valpr Pressure'15'C |I _ ----l-
PollutionCrteSory-USEPA D flfO D 3.04
vrlnr Density(Air : r.0)........................... PollrtionCotegory-USEPA- IMO B VrDorDendty (Atr f,lp
L01...........................
ADDlicibleBulk R€g.,16CFR Subchapter
..... Solubilityiu wrter......................... Comol€te Applicable Bulk Re8. {5 CFR Subchapter ...... O Solublllty in w..er....................... Slioht
crrdFE: Combustibleliouid
Electric.l Gloup-D
r Grade-D: Combustibleliouid
Electdcal Group-D
ceneral-Moderale lire haard whon exposed to heai or flame. Yi€lds tlammablevapors which lorm explosiyg
mixtures.
Flsh Point CF).............................

Flammable
175
Linits.......................-..
2 lo 1O"h
r Generrl-Moderate lirc hazad when exposed to heat. The solid otten evaporates withoul lirst melting.
1 17 (cc)
Flch Poirt CID.............................
Flmm.ble Lintt!..........................
Unavailable
("F)................ Autoi8nitionTenp. ("F)................
466'C
l"
AutoignitionTemp, 846
Dry chemical,alcohol loam or carbon dioxide
ExtinguishingA8ents..................... Extirguishing A8enG.....................
Foam, carbon dioxide or dry chemical
Sp€cielFire Prsedur6................ Water may be inelfectiv€.Wear eye protectionand protective clolhing. SpecialFlre Pr@edrr6...,............ Cool exposed tanks with water.
HEALTH HAZARD DATA

r
Herlth Haad Rrtingr Odor Threshold (ppm) PEL,/TWA (Dpm) TLV,/TWA (pDm) Herlth Haard Rrtings Odor Thr6hold (ppm) PEL,/TWA (ppn) TLV,/TIVA (ppn.)
2.3. 0 0.001 Unavailable Unavailable 0, I, 1 Unavailable Unavailable Unavailable
General-Skin contact may b€ sevorelyinitating or may cause moderate burns. Eyes are s€riouslyiniured by C€neral-Vapors are noniritating to the ey€s and throat. ll spilled on clothing and allored to remain, smarting
liouid contact. and reddening ol the skin may result.
synDtoms-Vapor: eye, throal, skin ifiitalion. Liquid contact; sverely iritating with moderale burns. SynDtoms-Atter swallowing,nausga and vomiling; headache,confusion;j€rky movemenB.
sho.t Exposue Tolcruce-Eyes are seriouslyiniured by a live p€rcenl solution of the acid.
l- Short ExposureTolennce-Reliable data unavailable.
ExposurePrcedureoontact with skin or eyes: immedialelyllush with plenty of clear running water, wash eyes
lor 15 minutes and get medical care; remove conlaminatedclothing. Inhalation:move to fresh air; il
br€athingis ditficult,give oxygen. Get medical attention.
r ExposurePrtrednrFln cas of contact, llush skin or eyes with plenty of low-presgurewater. Get medicd
attention for eye contact.
Strbility-Can r6act wathoxidizingmaterial.

REACTIVITY DATA
r REACTIVITY DATA
Stability-Stable. Can react with oxidizingmaterials.
Comprtibility-Msteri8l: Storage tanks and piping can be ol stainlsss steel or aluminum.
Cargo: Group 4 ol compatibilitychstt. r Comprtibility-Mlterld:
Cugo: Group 18 of compatibilitychart.

Woar rubb€r gloves, tace shield, proieclive clothing. Body shbld and self-contained brsathing apparalu3
slrould be avsilable. Eliminataall sources ol ignition. It possibl€,cover spill with larg€ quanlilies ol lodr ath or
r woar
rubbe' race
sroves, ".",T"*rt":*,ffi^J",::?":#ilr"0.
Shut€tl leak. Flush aroa wiih watet.
.*,," isnirion
$urces.
sodium bica.bonale Mix and add watsr it nsed€d tor good mixing. Scmp up slurry. Wa8h silo wth todt r$
$olulion.
If r rolll rrccur|. oll tie Nralooal nrDo. ( cnaq.
t- lf | 3Dill @cun, cdl the
Rair.ltr ncnrrk.r t Unavailrble
flr
'2 SCANNED
'
1
IBY MKP & BARIS A. 2004. ; :
rt
E& i ;tf-
--i!rg_-a-
L_ ''
!lti'nyil-Aminmaproic
CAPROLACTAMSOLUTION,80"/O
lactam; spsilon-Caprolactam; r
UritedNstionsNumbcr,...............................
l- CARBON DISULFIDE
Synonyms- Carbon bisulfide;Carbon bFulphidoi 1131
UnliedNralonrNumber................,.,.............
2-Katolrdamothylenimine; 2-Oxohexamsthylenimino Carbon disulphid€; Dilhiocarbonic anhydride
CHRI5cod€........... .... CLS

,........ cBB
Fmuh-CrHrrNO
ADFurneOdor-Clear
Spelflc Gnvity-1.06
light yellow, liquid;odorbss
Boiling
Po'rt..........................
..
FrezinsPoirt...............
--l1g'"
-'c
13'3
1',
---=:F
-'F
VaDorPrsure 20'C (6S"F)(nnHg).......... ---l-Q--
r Fmuh-CSr
Aplrcaruce-Odor-Coldl$s
ooor
SpecificGnvity-1.26
liquid; strong disagrosable
BoilinS
Frezin8Pottrt......... . .
46"C
Polnt..........................
_'c
11 1"3
_"E
115"F
- *t:F
I-
C'hemicalFuily-Cyclic amide 0.45 Vrlnr Prwsure 20'C (6E'D (nnHg).......... --292-
ReidVrpor Pr*ure (pdir)........................... Ctemicrl Fmily-Sulf id6 R e i d v r p o r P r s u r e ( 0 . 1 d . . . . . . . . . . . . . . . , . . . . . .1. .0...3.
Vspor Presure 46'C (ffs'D (pEir)............. 0.70
Polldion Crtegory-USEPA - IUO D : 3.9 Valnr Pressure 45'C (lls'D (Fh)............. 10.5
VsDorDensity(Air 1.0)........................... Pollution Crtegory-USEPA B IMO B
D 90% bv weioht vspor Density(Air : 1.0).............,.,.,......... 2-41
ApplicrbleBulk Reg.46 CFR Subchrpter........ Solubilityin wrter ......................... ApDliqble Bulk Reg il6 CFR Subchsptr........ O SolubilityinWrter......................... O.22
FIRE & EXPLOSION HAZARD DATA FIRE & EXPI,OSION HAZARD DATA
cnde-E: Combustibleliquid Gnde-B: Flammable liouid
Elstric.l Group-NA El€ctricd Croup-No electrical squipment allow€d.
cererd-Toxic oxides ot nitrogen may be form€d in lire. Nsgligiblohazard polymerizationbelow 20O"F. Generd-Highly tlammable liquid with unusuallylow autoignitionlemperature;contacl with steam line or hot,
bare el€lric light bulb can cause ignition. Burning rsl€ases initating and toxic sultur dioxide gas (SO2)
Rsh Point ('F).............................
230 Flsh Point ("D.............................
22 (cc\
LEL: 1.84olo
Ftumble Lin|ts.......................... UEL-Unavailable Flmmsble Linits..........................
1.3to 44%
AutoignitlonTenp. ('F)
ExtinSuishingAgents
................Greater than 284
SDecidFire Prcedud.....,........,.
Walet, dry chemical,toam, COr
t- AutoignitionTenp. ('D..,......,......212
ErtitrguishingA9ents.......,.............
CO, or dry chemical
SpccislFire Pr@€du6........,.,.,... A sell-contained breathing apparatus is recommended.When burning,carbon
disulfide produces sultur dioxide, which is toxic and highly irritating.Wear full protectiv€clothing. Fight fire
from a safe distance or trom a Drol€cted l@ation.
r
Heslth H@rd Rrtings Odor Threshold (ppn) PELAwA (ppn) TLVAWA (DDn)
Heslth Hurd RrtinSr Odor Thrchold (ppr) PEL,/TwA (ppm) TLV,/TWA (DDn)
O ,O ,4 0.3mg/m3 5 5
2,2,3 O.21 4/Skin lolskin
Genenl-Slight haard, however,toxic vapors result from th€rmal decompositionabovs a00'F. Possibilityof Gercrd-Vapor harmful.Avoid skin contact with liquid,
thermal burns lrom hot liquid if carriedat elflated temperature.
symptoms-lnhalation causes @ughing or mild iritation. Symptoro-Light-h€adsdnsss, diziness; prolonged contact with skin may cause burns.
Short ExDosureTolemrNot pertinsnt.

t- Sbort ExposureTdemF1,100 pgmlo( 1/2 hour may caus severe symptoms and unconsiousness;4,915
ppm for t hour has bsn reported as latal.
Exncure Pr@edoelnhalalion-remove patienl to lresh air. Eyes-wash wiih water for 15 minutes.
ErposurePrceduren€move to fresh air. Give artilicial resoiralionit unconscious.Get m€dical attention 6
Skin-wash wilh soao and waler. soon as possibl€. ll breathing is ditficuli, administerorygen.
Stsbltty-Stabl6.
REAC'TIVITY DATA
t- REAC:TIVITY DATA
Strbility-Cargo tanks should be isolated trom high temperaluretluids. Under conditions encouniered on
tankships and barges, carbon disulfide is not dangerouslyreactive. Must be shipped wilh pad ot inert gas.
Non-conosiveto sleel, wood, rubber, paint, cloth, or olher common materiel!. Comprtibility-Msterisl: May be slightly conosive to motals ol construclion due to impurities. Sottens rubb€r
and many plaslics.
Cugo: Group 22 ol compalibililychart.
Crrgo: croup 38 ol compatibility chart

Socurs ignition sourcas. Spills may b€ flush€d with walsr.
r
Wear rubb€r glov$, salsty glasss, protectiv€ cloihing and s€lt.contained breathing apparat$. Have carbon
dioxid€ lire sxtinguisher availablo. Eliminaie flammablss and all sources of igniiion. Nots lho low auloignition
tsmporalwe (212'F).
ltrrallffic||aL
ll . Tilll acun, cdl thc Nrtlod nqre Crtrtrr, EfiL424-88O2,
lcnrrlr: t Unassigngd
I- IT t tryb
t - t
, I I
I
. Il
r, .
) . - -: ': tt
;{'. 9i + l
CARBONTETRACHLORIDE tl Synonync- Brazil wax; Myricycl csrotate
CARNAUBA
WAX
Synonym- Benzinotorm;Carbon tet; Methane, Unlted Nrtions Nunb€r
Il
tekachloro-;Necatorina;Perchloromethanei
Tetrachloromethane
Fomulr-GzH*COOC*Hm
l'l
Fmrh-CClr
Appermce-odor-Colorless liquid; sweelish odor -'c -'F AplrcrrrnceOdor-Hard, amorphous,lighl y€llow to

FreezitrSPoitrt.............. -23'C -9'F greenish brown lumps; slight odol
SpeciflcGrrvlty-1.59 _'c _'F Sp€cificCrsvity-'1.00
Vrpor Prsure 20'C (6S'F) (mmHg)..........JOL
Chemicd Fmily-Halogenated hydrocarbons
Pollution cstegory-uSspl ----A- tUO B

3.8
ReidVrpor Presure(pcia)...........................
VaDorPrsure 46'C (ffs'D (pcia).............---51--
5.49
VrporDensity(Air : 1.0)...........................
I1 C-hemicrlFsmlly-Esler
Pollution C{teSory-USEPA - IUO

ApDlicableBulk Reg.il6 CFR Subchrpt€r........
O
D
ApplicableBulk Reg.45 CFR Subchrptcr....... O Solubilityinwater........,.,-.,.......... lnsluble
crrde-Nonllammable; haardous liquid

FIRE & EXPLOSION HAZARD DATA Il GredeE:
Electrical
Combustible
Group-NA
FIRE E EXPLOSION HAZARD DATA
Electricd Group-NA
Generd-Does not burn. Liquid or vapor in contact with hot metal can lorm poisonous phosgene gas'
Non-flammable
nsh PoitrtCF).............................
l.l cenerrl-Combustibb.
Flsh Point CD.............................54O (cc)

Non-tlammable
F'lmmableLimits.......................... Flamm.ble Linits.................--..... Unavailable
AutoignitionTemp.('F)................
ExtitrguishinS
Non-flammable
Non-llammable
Agents.....................
SpccialFire Prcedurc................ Wear selt-containedbr€athing apparatus.Cool lanks near lire wilh walor
spray.
I I Autoignition Tenp. ('F) .........,...... Unavailable
Extinguirhing Agents
Speid Firc Pruedus
Ory chemical, foam, or carbon dioxids
................ Wear breathing apparatus. Water or foam may cau$ trothing.
HEALTH HAZARD DATA

il HEALTH HAZARD DATA
Holth Hrard Ratinp Odor Thruhold (Dpm) PEL,/TWA (pDn) TLv,/TwA (pDr) Heslth H@rd Rsting. Odor Threhold (ppn) PEL,/TwA (Dpn) TLVAWA (ppm)
2.1.4 50' 2 s/Skin
G€redl-Suspected carcinogen.Breathingvapor in closed space can cause serious illness. The odor thr€shold
is not consideredadequate warning ol potentiallydangerousvapor concentration.Prolongedor repeated
skin contact may cause delatting ol the skin.
t-ll 0, 1, 0 Unavailable Unavailable
Getrersl-Virtually non-toxic,but possibilityol thermal buins trom hot liquid.
Unavailable
sydptons-Drowsiness lollowed by unconsciousnessand by respiratorylailure il exposure is prolonged. SynptorLow toxicity
Short ErDocre TolerdcFLittle or no injury from single exposurs to 300 ppm tor one hour, 90 ppm for 4 hours,
or 2000 ppm for 6 minutes.
l l ShoraExtGure Toleruce-Low toxicily.
ExDosurePrftedures-Vapor-remove victim to fresh air. lf breathing is difficult adminisler orygen. ll brealhing

stops, apply artiticialrespiration.Skin or eye contacl-remove contaminatedclothing and g€ntly llush
attected areas with water for 15 minutes.Get medical advice or attention. DO NOT give viciim any
preparationcontaining alcohol, because it could be fatal.'
n Expcue PrccdreTreat burns caused by hot liquid.
Strbility-Stable.
REACTIVITY DATA
tl Sbblltty-StaU€.
REACTIVITY DATA
t-
ConD.tibility-Mrterid: Becomes corrosive when in contact with waler. Corrosive to most iron and copp€r ComDrtibllity-Materld: Usual materialsof constructionare suitabls.
baso alloys, aluminumand rubber.
Crrjo: Group 36 of compatibilitychart. Crr8o: Group 34 ot compatibility chart.

Warr rubber gloves, B€lf{onlain€d brsalhing apprratus, and protectiveclothing. Avold conhcl wlth llqulr. Avoid contact with hol liquid.Wear goggles or face shield, proteclivo clothing loa hot lhdd. 8q|a, alE|U.l of
plac€ into package of paper or oth€r flammabls matorial and burn in incinontor
ll r rolll mcun, c.ll th. Ndlond ncFu (tnt.r, tlx)-a!'l-ttll2, It r.tlll Gu, call ilc N.tlill nmx ( dar. nr
'
rr nol conlrdc.od Ol pol€ntElly dangcrour vtpo. conconlrrlpnr &othr Nomllly tttnapdtad at aLvttad Lmporulurer Sor .tO(,1 l( :1oI |rv.trt ld\rrt . ( fura
il
La.ff, Odq throihold adoguata wJn||lg
I Unrvrilaua
I Un.rdettd
t6 ;.,r.i&- SCANNED BY MKPjo-*aer

& BARIS A. 2004
-*,rr&s*
f? oii.s
CASTER OIL
tl CAUSTIC POTASH SOLUTION
tyronym- Neolid; Oil ol Palma Chrisli; Ricinus oil; Urit€d NrtioN ___l__
Number...............,............... Synonynr- Lye; Poia$ium hydroxid€;Poiasdum Uliacd Nrtto[ Nunbcr.,.,.....,............
tanornlangan oil: Turkey-redoil (sulfatedcaster oil)
CHRIS Code ocA

tl hydroxidesoluton
l l
Formuh-Not chemicallydistinguishabls Fornule-KOH
BolllnSPoint.........,................ 312'C 594'F soln. 133'C -22tF
BolflnsPolnt.......45olo
Appcermce-Odor-Pale-yellowishor almost colorless -'c -'F Apperance-Odor-Colorless or lighl yellow syrupy 5Oo/.soln. 145'C 293'F
FrezingPoint........................ -10'C -ll'F -reg:9il"C -MT"F
transparenl,viscous liquid;laint mild odor liquid: odorless Freztr8 Point.... 45% soln.
SDecilicGrrvity-O.94 to 0.97 -;' SpecilicGrrrity-up to 1.54 (solid dissolvsd in wate0 s0% soln. 9/-33"C 4g/-27'F
Cl|emicrl Fsmily-Esters
Pollution Crtegory-USEPA - IIUO D

vrDor Pr*ure 2o'c (5E'D ,..", --:.
neid vepor Prwure (pcir)...........................
VaporPiessure45'C (1f5'!-) Ori.)........... 0'15
VsDorD€rsity(Air : 1.0)........................ 10
0"lo
tl Chenical Fsmlly-Caustic
Pollution Cstegory-USfPA C tMO C

Vapnr Presure 20'C (6t"F) (nnHd.......... ----j-
ReidV$or Prsure (DEir).........
Ialnr Presure,l6'C(tl5'F)(D.lr)............. t
VatDr DeGity (Air : 1.0)...........................
0.62
n
Appliclble Bulk Reg.,15CFR Subchrpt€r........ D solubilityin w8tei .........................Unavailable Applioble Bulk Reg.,15CFR Subchrpter........ O Solubilityin W.ter......................... Comolete
Grade-E: Combuslibleliouid Cr.de-Non"llammabls. Classifiedas a corrosive liouid.
Elmtrical Group-NA Eletricd Group-NA
firs hazard when exposd to heal

tl erd-Oes not burn. lt will r€act with many melals, giving ott highy flammable hydrogen gas. It hydrogen is
trapped in contined spaces, it can lorm explosiv€ mixtureswith air. See data sheet lor hydrogen.
n
445 (cc)
Flsh Point CF)............................. Fl$h Point ('F).............................
None
Fhmmabl€ Limits....,.....................Unavailable Flumrble Limits.................,........None
Autoignition Temp. ('F)................ 840 Autoigrition Tenp. ('F)........-... . None
Extinguishitrg Ag€nts Dry ch€mical, toam, ol carbon dioxids ErtirSuisbinS A8ertr.....................None
Specisl Fire Pr@cdur6................ Water or foam may cause frothing Cool expos€d lanks with water. citl Fire Pru€dur6................ Cannot catch tire. Cool oxposed tanks with watsr. Fire parties r€spondingto a
lire in the vicinity of caustic solulions should wear protectiveclothing includinglull face proteclion and
rubber gloves, boots, and outer clothing.
HEALTH HAZARD DATA

tl
HEALTH HAZARD DATA
rl
He.lth Hurd Rrtlr8s Odor Threshold (ppm) PELITWA (ppD) TLV,/TWA (ppn) Hedtb Hrard RetingE Odor Tbrghold (ppn) pEL,/TtryA (pDd TLV,/TwA (pDn)
Unavailable Unavailabls Unavailabls Unavailabl€ 0,4, 1 No odor 2 mg/ms. 2 mg/mrr.
Gener8l-Non-toxic Gencrrl-Causes severe burns ol eyes, skin and mucous membranes.
SynDtons-Non-toxic Svmptoms-lf solution splashes on skin no pain may be felt, but hair and skin in contact with the liouid will
Sboit Expcure TolmFNon-toxic t l b€gin to dissolvo on contact.

Sbort ExDofure TolemrNo sp€cific data.
ErDGue Prc€durNoGtoxic. Wash thoroughly with soap and water.
n ErIre Prccedurc-Do NOT DELAY! Flush attected part gently with plenty of water lor at least 15 minut€s.
Remove contaminat€dshoes or clothing. Get medical attention. Wash contaminatedclothing, including
sho€s before reuse.
Stsbility-Stable al room temperature.

REACTIVITY DATA
n REAC]TIVITY DATA
Strbilitv-Considerable heat is generated when water is added to caustic potash; boiling and spatteringof hot
caustacsolution may resull.
Comprttbility-Mrteridr Usual materials ol conslruction ar€ suitable.
Crrgo: Group 34 of CompatibilityChart.

tl crmprtiblllty-Mrt€risl: Practicallynoncorrosiveto iron and rubb€r at almospheric temp€ratures.Attacks
clothing and a tew metals, such as aluminum,iin, l€ad, and zinc and alloys containingthese mslals.
C.rgo: Group 5 of compatibilitychart. Se€ also App€ndix l-Exceptions to the Chart.

n SPILL OR LEAK PROCEDURE
r
wear rubb€r glovea, protsctivs clothing and tace shiold. ^ Wear rubber gloves and boots, large tacs shield and rubber protective clothing. Avoid contact with tiquid
sacute ignition lources. Neutralizewith weak acid and mop up or at dock ltush with oxcess watsr.
Il r Dlll cffi, cdl the :{rtloill Ragou Ccntcr, lFlltl'{Il. ll r .9lll (Kn. cll tb. Nrtlood n a2tFt{t2.
Rcmrki: + Unassign€d
n ldr:
' (:ryrt.llrrrlxrr
.. hr tlF l(rm
I trnara-b
ton|p /Soltdtltng lemp
ol a ltm rpray d mltl.
d.rridir. .;--. - -,.- . SCANNED BY MKP & BARIS A. 2004 *- t--*- -..2 r.E---.-.--r
TOTE: THIS CARCO I3 PERTITTED 'O BE SHIPPEDIII BULK OI{ UNilANI{ED BARGES OI{LY.
CAUSTIC SODA SOLUTION CHLORINE
Synonymr- Lye; Soda ly€; Sodium hyrdoxide;Sodium ......
Unii.d Nrtions Numbcr................ 1424 Synonyms- No common synonymg. 1017
Urlted Nrdou Nmber................................
hydroxid€solutbn
cHRIs code........... ... CSS

fi, C'HRISCodc.......... ..... CLX
t-,
FomulFNaOH Fomulr-Clr
Boilinspoirt.......50o/o
soh. 148'c ;'l ' o t ' t n s p o t n t . . . . . . . . . . . . . . . . . . . . . . . -. .3. 4 ' " l',
App€rrarce-Odor-Colodessot gray, syrupy liquid; no 73o/osln. 198'C 388'F AplErr.rce-Odor-Greenish-yollowgas;lntta0n$,
odor FreGzinSPoint.....5070 soln 5'C 41'F bl€ach-lik€choking odor ! ' . e 2 1 r s P o l n t . . . . . . . . , . . . . . . . . . . .-.1. .0 1 : 3 -r*:F
SDecilicGrrvity-up to 1.53(solid dissolvedin waler) 73olosoln. 62'C --14'F SpecillcGr.rfty-1.47 al 32/ 3S'F
r
_'c _'F
vaDoi Prsure 20'C (6s'I") (mn99........!:7-3ll& Vrlnr Prwurc m'C (6t"F) tmmHQ.......... l59Q-
Chemicd Fmily-Caustic ReidVrpor Pressure (psi.)......... C'h€mlcdFully-Halogen Rcld Vrpor Prilurc(prh)...........................155
Vapor Piwure 46"C (rrs'D (Dstr)............. i Vrlnr Pruurc a5'C (lls'F) (rh).............l!0-
Pollutlon CrteSory-USnPt nfAO C D Vrpor Density (Air : NP
1.0)........................... Pollution CrteSory-USEPA - IMO -gll- V r l D r D c n s l i y ( A l r= 1 , 0 ) . . . . . . . . . . , . . . , , , . , , . 2 . ,..1. . .
ApplicrbleBulk Re& 46 CFR Subchrpier-.......----Q- sotolitity in wster.........................
----geEPl9l9- ApDlicrbleBulI Re8.il6 CFR Subcbtpter........ O S o l u b l l l tiyn W r t e r . . . . . . . . . . . . . . . . . . . . 1. ...0. .%a t 6 O ' F
FIRE & EXPLOSION HAZARD DATA [; FIRE & EXPLOSION HAZARD DATA
Classifiedas a corrosiveliquid. Grade-Liquefied Compressd Gas (LCG)
Elstricd GrouD-NA Electricsl Group-NA
It will react with many metals, giving otl highly flammable hydrogen gas. lf hydtogon is Generd-Chlorine is non-explosiveand non-flammabl€.However,most combustibleswill burn in chlorin€,
irapped in conlined spaces, it can form explosive mixtures with air. See data sheet lor hydrogen although gas is nol llammable. Toxic products are genoratsd when combustiblesburn in chlorin€.
[,
F l $ h P o i n t ( ' F ) . . . . . . . . . . . . . . . . . . . . . . . .N. .o. .n. € Flsh Point ('F).............................
Non-fiammable
FhDmrble Limits..........................
Autoigrition Temp. ('F) ................Non€
ExtinSuishing A9ents.........,.,.,.......
Special Fire prceduE................
None
None
Cannol caich lire. Cool exposed tanks with watet. Fire parlies responding lo a
tire in the vicinity of causlic eluiions should wear protective clothing including lull lace protection and
rubber gloves, boots, and outer clolhing.
r FhmmableLimits.................,........
AutoignitionTemp.CF) .....,..........
Extinguishing
Non-flammable
Non-tlammable
A8erts...............,.....
Non-tlammable
SpccialFlre Prcedures................Chlorine lanks exposd io lire should be cooled with a water spray lo
- decrease the buildup of pressure. lt leak seems likely, emergencypersonnel should carry selt-contained
breathing apparatus so that facepiece may b€ donned without delay.

Heslth Hurd Rrtirgs Odor Threhold (Dpn) PELAWA (Dpn) TLVAWA (Dpm) Heslth Hsard RrtirSs Odor Threshold (Dpm) PEL,/TWA (ppn) TLV,zTWA (ppm)
0.4. 1 No odor 2 mg/m3' 2 mg/ms 4, 2, 4 3.5 0.5 0.5
Getrenl-Causes severe damage to lhe eyes. On contact with the skin, severe burns with deep ulceraiionsand
ultimatescarring may result.
[-l G€neral-Gas is primarilya respiratoryirriiant; severe sxposure can be fatal. Liquid or high concentrationsot
gas in contact with skin or eyes will cause local irritaiion or burns.
Synptons-lf the solution splashesonto skin no pain may be lell, but hait and skin in contact with caustic will Symptoms-Vapor: coughing,choking, burning sensation in eyes and throal, and shortness ot breath. Liquid:
begin to dissolveon contact.
Short ExDosureTolersncFunavailable. t* severe iritation or blistering.Frostbite can also resull.
Short Exlmre Tolemce-Exposure to vapor concenlration of 1000 ppm for 10 minutgs has caused death.
Expcure Preedurc-Oo NO DELAY! Ftush attected areas gently with ptenty ol waler for at least 15 minuls.
Remove contaminatedsho€s or clothing. Get medical att€nlion.Wash contaminatedclothing, including
shes betore reuse. r ExposurePrceduro-Remove victim to fresh air. ll breathing stops, apply artificial respiration.Orygen,
adminisleredby trained personnel,is otten helpful. It eyes are eltecled, wash gently with water lor 15
minutes. lf liquid chlorine has spilled onto the skin, remove conlaminated clothing and llood ihe exposd
area genily with water for 15 minut€s.Get medical attention prompfly.
REACTIVITY DATA
Stability-Considerable heat is generatedwhen water is added lo causlic soda; boiling and spatteringol hot
caustic slution may result.
r REACTIVITY DATA
Strbility-Will react wiih many inorganic and organic compounds,usually with an evolution of heat.
Conprtibility-Mrterid: Noncorrosivelo rubber at atmospherictemperatures.Slowly corrosive.to iron, copper

and monel m€tal. Attacks clothing and a lew metals, such as aluminum,tin, lead and zinc, and alloys
containingthese metals.
Cugo: Group 5 ol compatibititycharts. See al$ Appendix l-Exceptions lo the Chart.
r Compstibility-M8t€rial: Below 230 dogres F, copper, iron, lead, nickel, platinum,silver, steel and lantalum are
chemically resistantto dry chlorine gas or liquid.Certain copper and ferrous alloys, includingHastalloy "C",
monel and types 304 and 316 stainless steel also are resislant.
Cugo: Chlorine is unassignedin the compatibilitychart. For assistanc€,call
G-MTH. 1 t202-267- 1577t.

w€ar rubbor glovss and boots, large tace shield, and rubber protectivecloihing. Avoid conlact with lhe lhuid
r
Wear rubbsr glov€s, seltcontained breathing apparatus, and prolsctive clothing. Evecuato all downwind
Sscure igniiion sourc€s. Neutralizewith weak acid and mop, or, at dock, flush wilh axcesg wateJ. p€rsonn€l not equipp€d with respiratoryproteciion.
lf I aDlll ecun. cdl the Nrtlonrl R6Drs C.ntcr. tm-a2a-tdrl. lf r ulll ccun. cdl thc Nrtlonrl Rm Crrr.r. 81H24-tt02.
Rcnrlr ' In lho lorm ot ! fing mi8t or sp.ay
t Unevrihbb
r lrlr:
60
*:a-. - SCANNED
. :
fa*.sftrrr&l|i BY MKP & BARIS A. 2004 6l
CHLOROACETICACID, 8006
Synonynr- Chloroac€ticacid, liquid;MCA; 1750
UniiedNstio6Numbcr..............................
rr Synonyms- Benzene chlorid€; Benzene, chloro-;
CHLOROEENZENE
Unlaed N.tlons Numbcr................,.........,..... 1134
Monochloroa€lic acid Chlorob€nzol;MCB; Monochlorobonzone;Phent
chloride
CttRIs code........... .... -CHII- CHRIS Codc....................., _cBs_

Fmuh-CHzCl
SDGcmc
COOH
ADranncc-Odor-Colorless liquid;acidic odor
Crrvity-1-328
' o r r i n s p o i n t . . . . . . . . . . . . . . . . . . . .1. .8.9. .'." 1 1
poitrt........................
Freezin8 ------lliE :,8 n Formuh-QHrCl
ADp€mncc-Odor--€olorl$s liquid: atmond-likeodot
SpecificGrltity-1 .11
Bolllng Polnt..
Frezlnl Polnt
-'c
_'c
132'C
-/ts'C
-"F
_'F
270"F
-48'F
Vrpor Pressure20'C (68"F) (mnHd.......... -_0i4- Vrpor Pr*urc 20'C (5t'F) (mnHD.......... --lqq--
ClremicdFemily-Organic acid Reidvrpr Pressure (psia).......................,.. 0 99 Ctemicel Fmlly-Halog€nated hydrocarbon R e l d V r D o r P r * u r e ( p . h ) . . . . . . . . . . . . . . . . . . . . . . 0. ...5.
VaporPrsure 45'C (115'n (D€ir)............. -l- VaporPrroure 46'C (tls'F) (pclr)............. ---9€-
PollutionCrtegory-USEPA - mO C vrpor D€nsity(Air : 1.0)........................... 3.26 Pollutloo Cotegory-USfPl B fUO B VsporDe6lty (Air : 1.0)......................... 3.88
ApplicrbleBulk Reg.,16CFR Subchepter........ O ---
sototiuty in wrter......................... te!!!plglg- ADplicrbleBulk Reg.,16CFR Subchrpter........ O Solubilityid Water.........................Neolioible
Grrde-Non-tlammable
Electricd GrouD-D
FIRE & EXPLOSION HAZARD DATA n Grede-D: Combustible
Eletrical Group-D
liouid
Generd-Non-tlammable, but when heated gives oll toxic gases. tlecomposs to chlorine and phosgens when
heated above ils boiling point.
Non-flammable
Flsh PointCD.............................
It; Genersl-Burning releases toxic and iritating gases ot phosgene and hydrogen chloride. lgnit€d by heat or
open flames. Flashback along vapor trail may occur. Vapor may explode in an enclosed area.
90 (cc)
FlGb Poirt CF).............................
Non-tlammable
FkmmrblcLimits.......................... Flmmable Limits..........................1 .3 to 7.1oA
Temp,('F)................
fi
Auioi8DitioD Non-tlammable Autoignition Temp. ("F) ................1 1 80
Ertinguishing Non-flammable
Agents..................... Extinguishing Agents.....................Co2, dry chemical, water fog, loam
SDecislFire Keep containerscool with water spray. Fire tighlers must wear lull protgctive
prsedureE.............,.. SD€cid Fire Praeduro................ Supply respiratory protoction to tire tighting persnnd.
clothing and selt-containedbreathingapparatus.
HEALTH HAZARD DATA

Herlth Hrad Rrttngs Odor Threshold (ppm) PELAWA (ppn) TLv,/TwA (Dpm) Halth H.ed Rrttngo Odor Thrshold (ppm) PELAWA (pDr) TLVATVA (ppm)
4.4.4 Unavailable Unavailable Unavailabls 0, 'l, 2
l-l
Unavailable 75 75'
toxic waier solution, can cause perman€nt iniury or d€ath. Ahrays w€ar protective clothing when Canenl-Vapor irritatinglo skin, eyes and mucous m€mbrams.
handling.
acute syslemic intoxication,vomiting, internal burns and perterations.Skin contact: SynDtom-Drowsiness, lwitching ol extremities,and do€p, rapid rsspiration.
severe, paintul burns and irritation;shock. lnhalation:heated vapor painlul to lungs, pneumonia,brsalhing
oroblems.
Short ExpostrreTolerarce-Mists harmful but vapor not harmful unless liquid hsated.
l-l Sbort Expcure TolemeExposure
to cause death.
for 0.5 hours to 6500 ppm of 1.0 hour to 2OOOppm would not be expected
.l5 minutes,Skin: temove

ExposurePrcedur6-Always call physician.Eyes: llush wilh water for at least Expcure Prcedw-Remove victim to lresh air; il breathing stops, apply artificial respiration.Skin or eye
clothing,tlush with large amounts ol water. Ingeslion: swallil s€veral glasses of waler, do not induce contact-ramove contaminatedclothing and gently tlush atfected area with water lor 15 minules. Get
vomiting. lnhalation:remove to fresh air. medical advice or atlention.
[;
REACTIVITY DATA
Strbility-Reacts with strong bases. Stable at ambient temperature;decomposes,lo toxic gas€s when heated. I-l REAC'TIVITY DATA
Strbility-Rsacts vigorouslywith oxidizers.It heated to decomposition,toxic chlorine compounds will be gvil
otf.
CoDprtibility-Corrodes: mild sle€|, aluminum,copper, zinc, tin, brass, bronze. Compatible:stainlesssto€|, CoDDotibility-Mrterial: Relativ€ly non-corrosive. Attacks rubbsr.
polyethylene(high density)
crrgo: Group 4 ol compatibility chart

l-r C$go: Group 36 of compatibility charl.
SPILL OR LEAK PROCEDURE [, SPILL OR LEAK PROCEDURE

Nsutraliz€ wilh sodium carbonate, dilut€ with water. In case of material b€ing involvod, w€at full-protsclive WoaJ rubb€r glovss, s€ll-containgd br€aihing apparatus, and protscliv€ clolhing. Avoid contact with liquid.
clothing and solf-containedbreathing apparatus. Spray wator on contain€rs to keep thom cool. Fight tire f,'ilh S€cur€ ignition sourc€e
m€dium appropriatsfor lu€|.
Il I sDlll ccun. cdl lhe N.lloml R..rcn* Cmttt. frXH2a-ttll2. lf r rplll mcun, oll ahe Nrtloml R6Dotre Center, 8lXF42AtE02.
Rcnulr: t Unavrlable Irn nrrta ' Propr.<l chlrgr In TLV lo

l0 ppm
l-l
o,
fu.;tarr;@- SCANNED BY MKP & BARIS A. 2004
d* -'-.--:..-.
6l
gir.";.gii
CHLORODIFLUOROMETHANE tl CHLOROFORM
n
Synonyns-Dif luorochloromethane; United Nstions Number.. 1018 Synonyr Formal trichlonde;Methane, trichloro; U r l t d N r t t o m N u n b c r . . . . . . . . . . . , . . , . , . . . , . . . .1
. .8. .8. 8
..
Ditluoromonochloromethane; Fluorocatbon22; Methenyl trichlorido;Trichloromsthane
Frcon 22i,Monochlorodifluoromethane:Propellani
22, Ralngeranl 22
CHRTS Code ........... .... MCF CllRtS Cod........... CRF
.....
tl
Fornulr-CHClFr Formuh-CIGL
8oi1in8Point.......................... -41"" -*', , r,;l
Bofflnr Poftrf..,....................... 61'C 142'F
ADperuce-odor-Colodess gas with a faint ether6al -roo"3 Appearrnce.Odor-Coldle$ lhuldi 8we€l odoa
odor like carbon tetrachloride Free2in8Poirt...................... -*:F l'reela3 potnt.,.,.,.,............ eg:3 -z-:F
SpecificGravity-l.18 _'c _'F SDecific
Gravity-1.48 _'c _'F
t-l
Vspor Presure 20"C (6t'F) (mmHg)..........--0998- Vrpor hrurc 20'C (6t'ts) tmnHO.......... --15!L-
ChemicalFidily-Halogenal€d hydrocarbon ReidVaporPressure (psis)......... ..................212.6 Ch€micrl Frmily-Halog€naled hydroca.bon R.ld v|'or Ptuurc (Fh). .. ....,..,.,.... 6.39
VaporPresure45"C(115'F)(psia)............. --225- Vrlor Prcurc ll6'C (lt5'1) (Fh)............. 9.00
Pollution Category-USEPA - IMO ----gg9- v s p o r D e n s i t y ( A i:r 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .2. . 9. .8. . Pollution Crtcgory-USfPt A tMO B Vepr Dcndty (Alr = 1.0)........................... 4.25
n
Applioble Bulk Reg il6 CFR Subchrpter........ O Solubi|ityinW.ter...........,............ ioht S l ApplicsbleBull Re8. 46 CFR Subchepter........ O S o l u b l l l t y l n W r t € r . . . . . . . . . . . . . . . . . . - . . . .S
. liohl
crrde-Liquefied CompressedGas (LCG) Grade-E: Combustibleliouid
Electricd Greup-NA Electrical Grou!+D
Cencrd-Oecomposition gass are toxic and irritating.Weakly flammablegas.
Flah Point ('F).............................

Non-flammable
tl Gene.d-Will burn only atter prolonged exposure to tlame or high temperatures.Wh€n h€at€d or exposed to a
tlame, chloroform decomposesto form phosgene, which is highly piosonous.
trlNh Poitrt('F).............................
None
Flemmable Limits............--...-.....
Non-flammable Flanmrbl€Limits..........................
None
AutoiSnitiotr
Temp. ('F)................
1170
Water, carbon dioxide, dry powder
ExtinguishinSA8ents.....................
SD€cislFire Prcedurq................ Shut otl supply of gas. Tanks exposd to lire should be kept cml wilh a
continuousspray of water. Firefight€rsshould wear self-containedbreathing apparatus.
Il Autoignitiontemp. ("tr)................
Exlin$ishingA8erts.....................
1155
None
Specid Fire Prmedurq................ Keep lire exposed tanks cool wilh water spray. Wear sye protection,
self-containedbreathing apparatus and protective clothing.
Health Haard Rstings

HEALTH HAZARD DATA
Odor Threshold (ppm) PEL,/TWA (Dpd TLVITWA (DD!)
n Heallh Hrard Ratings
HEALTH HAZARD DATA
Odor Threshold (ppm) PEL,/TWA (Dpn) TLV,/TWA (pDm,
0.0. 'l Unavailable 1000 1000
G€nenl-Suspected carcinogen.Liquid may cause skin or eye injury similar to frostbite. Breathingvapor may
cause uncon$iousness without warning because of lack of orygen.
tl 2,1,2 2 0 0t o 3 0 0 2 10
crnersl-Suspect€d carcinogen. Breathingvapor in enclosed area can cause loss of consciousness.Odor
threshold is higher than the TLV. Exposureto potentiallydangerous vapor concentrationscan occur belore
th€ product can be detected by smell.
Syfrptoms-lnhalation-asphyxiation causing drowsinesswith or without nausa. Skin contacl-trostkilo. Symptoms-lrritationoI mucous membranes and skin; drowsinesg.
Short ExDcure Toleruce-Unavailable tl Short Exlmure Tolermcelnhalation of 400 lo 600 ppm tor 30 minules or less can prove tatal.
tl
ExDGore Preedurg-Vapor-remove victim to lr€sh air; if breathing stops, apply artiticial respiration. Eye ExpocurePreedures-Remove viclim to fresh air; it breathing stops, apply artificial respiration.Skin or eye
contact-flood eye gently with clean sea or clean fresh water lor at leasl 15 minutes. lf the liquid has contacl-remove contaminatedclothing and gently llush aftecled areas wiih wat€r tor 15 minutes.Get
spilled onto the skin, points of contact may be frostbitten;handle gently and protect lrom mechanical medical advice or attention.
damage. DO NOT RUB. Get medical attention.
REASIIVITY DATA
Stlbility-Very stable. Oecomposesslowly in presence ot rust and moislurs. II REACTIVITY DATA
Stability-Decomposes in the plesence ol excess water or a high temperatureto give phosgene and hydrogen
chloride, which are very toxic; can become explosive in the presence of strong alkalies and water.
t-l
ConFtibillty-Mrterirl: Usual matgrialsot conslructionar€ suitabl€. conpstibility-M8terial: Non-corrosiveat normal almospheric iemperatureswhen fr6e ol moislure-In contact
wilh watsr and at high temperaturesit becomes @nosive. Corrodes iron and csrtain other mstals.
Crrgo; Group 36 of compatibili9 chart C{r8o: Group 36 ol compalibility chart

tl SPILL OR LEAK PROCEDURE
Hrva rll-putporc canirter mask svailabl€. Avoid contact wilh liquid. S€cuc ignition !ourc6. Evlcuala rll Wear rubb€r glov€s, solf-contain€dbreathing apparalus,and proteclivs clothing. Avoid contacl with liquid.
t l
unprolocled p€rtonn€|. Flush spill with larg€ quanlilb8 ol water.
la r rall Gcun. c.ll th. lt I rdll acu, cdl lh. Nrtlord
tl
lrrrtr: lllull
u SCANNED BY MKP & BARIS

:*,.*aa;A. 2004 €- -== *,,-r $d!".-=,t:*
(crude)
CHLOROHYDRINS O.CHLORONITROBENZENE
Synuymr- crude Epichlorohydrin (A 2023
Urited NrtionsNumb€r....................,........... Synonynr- 1-Chloro-2-nitrobenzene; Unltcd N.tlon6 Number................................1574
CHRIS Code.............. ('HRIS (i)de . . . . . . . . . .c N o

|-q
Fornuh-CHTCHCHzCI Fomulr-GHTCINoz
38-260"C 100-500"F
BoilinSPoini.......................... Bollln3 Polnt.. 245'C 473'F
Appemce-Odor-Light yellow turbid liquid;pungent, -. Apgrrrence.Odor-Yellow solid: aromatic odot -'c -"F
gadic odor FreezinsPoint.................. - 16'E -'i l'reezing Polnt 32"C 90'F
SpecificGnvity-1.20 _'c _'F Specific Gnvity-1.4 -'c -"F
Vapor Prwure 20'C (6S'F, (nnH8).......... 5.1 vrlnr Prroure 20'C (66'F) (mmHd.......... -y-!Q!tL
C'hemicalFmily-Epichlotohyddn 0.3
Reidvapor Presure (Dsir)........................... Chenicsl Family-Nilrocompounds Rcld VaporPresure (pch).........
VeporPrerrure,l6'C(115'F)(D!is)............. 0.5 Velnr Pr*ure 46'c (ll5'D (Dsia)............. -!L-tg!tl
PotlutioncrteSory-UsEPA- M D vapor DeNity (Air - 1.0)......................,....
t PollutiorCstegory-USEPA - IMO B VrtDr Denlity (Air = 1.0).............. ............. 5 4
ApplicableBulk Reg.it5 CFR Subchapter........
---.Q- Solubilityinwater......................... 6.004 Applicable Bulk Re& {6 CFR Subch$ter........ O S o l u b i l i t y i n W r t e r . . . . . . . . . . . . . . . . . . . . . .l n
. .s o l u b l e
crade-D: Combustibleliquid Grade-E: Combustibleliquid
Eletricsl Group-D Elet.icsl GroutFUnavailabl€
Geaeral-lgnited by heat and open flame. Burning releases hydrochloricacid tumes. Containersmay explode in hazafd wh€n exposed to heat or flame. Toxic vapors ot nitric oxides (NO,), hydrog€n chloride
fire because ol polymerization. (HCl), and carbon dioxide (COz) are given ofl by high temperatures or combustion.
Flsh Point('tr.)....... 90 to 100 F l $ h P o i t r t C n . . . . . . . . . . . . . . . . . . . . . . . . .2. .6. 1.

3.8 to 21%
FlmmsbleLimits.......................,.. Fbnmble LiDits..........................Unavailable
AutoignitiorT€mp.('F)................804 Autoignitlon Tenp. ('F) ................greater than 300
Water, CO,, alcohol loam and dry chemical
ExtinSuishingAgents..................... Extinguishing A8ents..................... Water spray, COr, dry chemical, foam
Specid Fire Prueduro................ Wear self-containedbreathing apparatusand lull protectiveclothing. Cool specisl Fire Prcedur6................ Water or loam may cause lrothing. Weaf sell-@ntained breathing apparatus,
exoosedtanks with water. Avoid use ot dry chemical it fire mcurs in conlainer with confined vent. eye protection and protective clothing.
HEALT}I HAZARD DATA HEALTH HAZARD DATA

Heslth Hud Rstings Odor Thrghold (pDm) PEL,/TWA (ppn) TLvlTwA (ppm) Ileslth Hsard Rrtir8s Odor Thresholdippd) PEL,/TWA (ppm) TLVAWA (ppn)
3.3.4 2/Skint 2/Skin' 3,2,4 Unavailabre Unavailable 1 mg/m3
l l
<10
G€nersl-'Vapor extremelyirritaling.Lung iniury may be delayed. Liquid causes severe burns. Absorbed by Generrl-Very toxic via inhalalion,ingestion. Possibilityof thermal burns lrom hot liquid.The molten liquid is
leather and causes delayed burns. NOTE: Related cargo, epichlorohydrin,is a suspecied carcanogen. irritatingto ihe skin. Class B poison.
Symptoms-Eye, nos, and throat irritalion;headaches,nausa, vomiting. Symptoms-Headache,weakness,anemia, shallow respiration,convulsions,coma, cyanosrs.
Short ErposureTolerance-1o ppm lor 30 minutes. Short Extpsure Tolerance-2 mg/m3. The ettects of this poison are cumulative.
Exp6ure Precedur6-Vapor-remove victim to fresh air; il breathingstops, apply artiticial respiration.Skin or ExposurePreedures-Remove from exposure. ll indicated give artilicial respiration.Flush eyes with large
eye contact-remove contaminatedclothing and gently tlush affecled areas with water for 15 minul€s. Gel amounts ol water lor al least 15 minutes. Wash skin with soap and waler. It swallowed,give emetic, gastric
medical attention as soon as Dossible. ravage.

Stsbility-Unavailable Stsbility-Stabl€. Toxic vapors ol NOr, HCl, CO2are given otf by high temp€ralursa ol combustion.R€acts with
causlics.
(i)mDrtlbtltty-Materld: Dissolvesmost paints, causes rubber to swell. The wet producl will pit carbon stsel. ComDrtibility-M.terid: Usual matsrials ol constructionare suitablg.
Cr4o: Group 17 of compatibilitychart. cr19o: Group 42 ot compatibilitychart.
SPILL OR LEAK PROCEDURE SPILL OR LEAK PR(X]}.]I)URI.:

Wcl rubb€r glovo!, !€ll-containod brsathing app8ralus, protelivs clothing. Evecuta pdlonml mt aqrbPo(l Soak up with a mixture ol sand end soda ash (9:1). Scmp up ond ptaco In ctrlom Ind br'n Wonr buv
wiih protecliv€ clolhing and respiraloryproteclion.Shul otl all ignilion surces. Flulh ato! wilh wateTaptly. rubb€r gloves, self-containedbreathing apparalus,prolectiva clothlng rnd srloty rhoat
ll | .Dlll acun. ..ll rb. N.llod ngr (i!lT. lf I aDlll 6con. crll lh. N.rloill rua
' P€L iilrr0txr! ilr tha tnOrllr'n$ttla et 4tl (
lrrrlr: rtd TLV bssod qtoar I prclrlorolry(trn Itmrrlr
I Unrvaltbb
tl l t I Umvnrltrl,la
66 SCANNED BY MKP I& BARIS A. 2004

,*;,,
cl
ACID
CHLOROSULFONIC COALTAR
synonynr-Chlorosulturic acid; Chlorsullonicacid; United Nftions Numbcr.........,.................... 1754 Synonyms- Coal tar distillate;Oruds coal lat; High U n l t . dN r a l o u N u m b e r . . . . . . . . . . . . . . ... ..... . . . 1 1 3 6
Chlorrulluricacid; Sulluric chlorohydrin temperaturecoal lar; Tar; Tar, liquid
CHRIS Code................... __esa_

................ ( llRts Codc........... . . . . . . . . . . . . . . .C. .O R
Fomula-HOSOzCl, or Sos.HCl 't52'C Fomuh-Mixture

305'F
BoilinS Point................... Bollht Polna.................. 38-479"C 100-895'F
ADFarrnce-odor-Colorless to lighl liquid;pungenl _'c -'F Appearance-Odor-Oarkviscous liquid; aromatic odor -o'c
Point.................
-80'c -112F o'r
odor Fr*zing l'rczlnr Polnr.
_'c _"F 'c 'F
SDecificGravity-1.79 SDeltlc Grsvlty-1.2
Vrpor Prsure 20'C (6S'F)(mmHg)....... --d-Q- Vlpor Presrure20'C (68'l') (mmllg). .. . 0 2-1.0
ChemicslFamily-lnorganic acid R e i dV a p o rP r s u r e ( p s i a ) . . . . . . . . . . . . . . ... 0 0 3 Ch€mlcalFrmily-Aromatic hydrocarbon Rcid trpor Prilure (Fh,.........
Vrpr Piesure 46'C (1r5'F) (psia)...... . --9Q9- Vrpor Prdcure45'C (lls'Fr tpsirr . .. I
PollutionCatesory-uSnPl C ttUO C v.Dor Density(Air : r.0)........................... , 4'0 Pollutlon C8t€8ory-USEPA - IMO A V r D o r D c n r l t y ( A t -r 1 . 0 ) . . . . . . . . . . . . . . .. . > 1 . 0
ApplicrbleBulk Reg.d5 CFR Subchrpter........ O S o l u b i l i tiyt W a t e r . . . . . . . . . . . . . . . . . . . . . . Appllcrble Bulk Reg.46 CFR Subchrpter . O solubtlltyin wrt€r.................. . Below 0.2%
crode-Non-flammable. Classiliedas corrosiveliquid. Grade-E: Combustiblsliquid
ElectricatGroup-B (based upon possible hydrogengas (H,) generationshould a leak or spill occur) Elect.icsl Group-D
Genenl-Non-llammable, bul it may cause ignition by contaci with combustiblematerials.Dangerouslyreactive

Explosiveconcentrationsof hydrogengas can accumulateinsjde metal tanks containingthis acid. Spill in
conlined space may produce explosiveconcentrationol hydrogen See data sheel for hydrogen
Flsh PoiDt('D.............................
Non-llammable.
II Gerenl-Moderate lire hazard when heated.
250 (variesaccordingto composition)

Flsh Point CF).............................
Non-flammable.
FhmnableLimits.......................... Flmmlble Limib..........................
Unavailable
AutoignitionTenp. ('F) ................
Nonjlammable. AutoignitionTemp.('F)................Unavailable
Extinguishing NonJlammable.
A8entr..................... Extitrguishing Water splay,loam, COr, dry chemical
A8ents.....................
Speciatfire prceduG................ DO NOT USE WATEB. Wear lull protectiveclothing, includings€lf-conlained SDeial Fire Preedures..........,.,...Wear lull protective clothing and self-containedbreathing apparatus.Remove
breathingapparatus.Cml adjacenttanks wilh water spray lrom a dislance. containers lrom fire if possible:il not possible,cool conlainers with water.

Hellth Hurd Rrtingt Odor Thr6hold (ppm) PELITWA (Dpn) TLV,/TWA (ppm) Hedtb Hurd Ratings Odor Thrahold (ppm) PELAWA (ppn) TLVAWA (ppm)
4,4,4 3 Unavailable 1 Unavailable Unavailable Unavailable 0.2 mg/m"
Generel-Vapor inhalationmay cau* loss of consiousnsss with serious damage to lung tissue. Liquidcauses exposure causes cancer in animals. Known carcinogen.
severe irritationand watering ot lhe eyes.
Synptoms-Contact of liquid with the skin can cause severe burns. Breathingthe vapors will cause *vere headache,nausea, vomiting; irritationto respiralorytract. Skin contact: highly irritating,
irritationand wateringol the eyes. dermatitis;sensitizesskin to light. Eyes: vapor exposure irritating.Ingestion:vapor toxic, vomiting, mild
ExposureTol€nnce-3o ppm tor 10 minutes: 10 ppm lor 60 minutes. convulsions,hypolhermia,dizziness
Short ExDosureTolerance-Keep exposures below the TLV/TWA ol O.2 mg/m3.
Erposureprmedurc-Vapor-remove victim to lresh air; if breathingstops, apply artiticialrespiration.Oxygon, ExDosurePrcedur6-Eye contact: flush with water lor at least 15 minutes. Skin contact: remove contaminated
administeredby trained pgrsonnel,is otten helplul. Skin or eye contact-remove contaminatedclolhing and clothing, wash alfected areas with soap and water. Inhalation:remove to lresh air. Orygen or artificial
gently tlush aflected areas with water for 15 minutes.Get medical advice or attention. respirationas needed. lngeslion: induce vomiting, give oxygen il respirationshallow; swallow activated
charcoal.

Stability-Violently reacts with waler torming sulfuric and hydrochloricacids. Strbility-Stable. Incompatiblewith strong oxidizingmaterials.
Compatibility-Mrte.id: Dangerouslyreactive.In addition to attacking many metals, the acid is a strong Comprtibility-Mst€ri8l: Swells and softens rubber.
oxidizingagent and will react with water and organic materialswith evolution of heat and large quantiti€sot
dense fumes.
Cargo: Chlorosullonicacid is unassign€din the compatibilitychart. For compaiibilityassistanco, Crrgo: Group 33 of compatibilitychart
call G-MTH-1 eo2-267-1 5771.
SPILL OR LEAK PROCEDURE SPILL OR LEAK PROCEDUR}:

Wear rubber gloves, ssll-containedbreathing apparatus, protective clothing. Avoid conlact wilh spill€d hqurd
From a distance carelully flush the spill away with water. Greal care must be taken as watsr and chlorosullonrc Wear prolsctive clothing and self-contarnedbroathing apparstus. Removo all Dnrlron sou.coB Vonlrltto sprll
area rl €nclosed.Collectspill€dlrqurdtor proper drsposrtron. Uso absorbantslor smell sprllB,drko sprllaros to.
acid react violently lorming toxic HCI lumes and sulturic acid. Consoquenlly,clean-up personn€l should work
with ths wind at their backs. lf water is not availableor il inversioncondilions prevail, apply dry sand. vermrculrkt
ash€s or 'powdorod clay lo absorb lh3 spill.
lf I rdll ecm' oll thc Nrtlorrl Rctd. ('enldr lxlal/1-tt(l:.
I large spillr.Alter spill rsmoval,wash down sprllsrlo Malo(al rEe sor(rr$ p()lh,l(ilrl)rrri.d
lt | .oill (rcsrr. c.ll ah. Nrllon.l nm ( rnt.r. nll lfa l0l"
Rculr: ' Farcts virLnlly lormrnghydrochloriclnd sullunc sLrds l..rylr: I[.hrdvdrht)lo
l i
6t
--*.-.1
-- --*-44
0
COAL TAR NAPHTHA COTTONSEEDOIL
Synonyms- Crude solveni coal tar naphtha;Hight Unltcd Nrtions Numbcr...,.,. .IATL Synonyu- No common gynonyms. Urited Nrtionr Nunber............. _____{_
solvent napnha; Naphtha
CHRIS Cod€........................ ...,. _NqI_ ( ' l l R I S C o d e . . . .. . . . . . . ocs
Formula-Mixture Forhuls-Mixture of C-14 to C-l6latty acids.

Boiling Point........................ 93-260'C 200-500'F Bollln8 Polnt ......... V. Hioh'C _'F qc
Appearrnce-odor-Colorlessto pale yellow liquidwith a _'c _'F Apperrrnce-Odor-Pale yellow or yellowish-brownto
benzenelike odor Frezing Point..................... 0'c 32"F dark ruby red; odorless liquid when puo FreezhS Polnl.......... -o"c -n'r
SpecificGravity-0.86 to 0.88 _"c _'F SDcclllcGrrvity-O.g2 U I
VoporPrsure 20'C (68'n (mmHd.......... 3 Vrlnr Pressure 20'C (6E'F) (mmHO... 2O

ChemicalFrmily-Petroleum oils C'hemicrlFenily-Ester
R e i dV a p o r P r s u r e ( D s i r ) . . . . . . . . . . . . . . . . . . . .0. . .1. 3. Reid Vapor P|wurc (Fh)............... .. O1
vapor Prsure 46'c (f15"t) (Dsis).............0.20 Vrpnr Pressure ,|6'C (l15'F) (Drir)........... 0.1 5
PollutionCrtegory-USEPA - IMO B Pollution Cstegory-USEPA - IMO D Vrlnr Density (Air : 1.0) ........... t
vapor Density(Air : 1.0)..............
ApplicabteBulk Reg.il6 CFR Subchapter.. . . O S o l u b i | i t y i n W a t e . . . . . . . . . . . . . . . . . . . . .N
. . e. .o. l i o i b l e ADplicrbleButk Reg,,16CFR Subchopter D Solubility in Wrter............ Neolioible
GredeD: Combuslibleliquid Grade-E: Combustibleliquid
Elctrical Group-D Eletricd GrouI+D
ceneral-Flammable, moderatelire risk. Gerenl-Slighi fire haard when exposed to heal or tlame.
FIsh Point CF).............................

100 lo 107 486 (cc)
Flsh PoitrtCF).............................
Flammable Limits..........................
0.8 to 6.0010 Ilanmable Linits..........................
Unavailable
AutoignitionTenp. ('F) ................
above 530 AutoignitionTemp.("F.)................
650
Extinguishing Conlinedarea-Cor, dry chemical.Open area-toam.
Agerls..................... ExtidguisbinSAgent$.....................
Dry chemical,foam, or carbondioxioe.
SD€cialFire Prcedures................Fire parties musl wear respiratoryprotection and rubber b@ts. In olhsr SpecislFire Pruedure................ Water may be inetfectiveon lire. Cool exposedtanks with water.
respects,fighl like gasoline fire. Cool exposed tanks with water spray.

Health Hurd Ratings Odor Threshold (ppm) PELAWA (ppn) TLV,/TWA (9pm) Health Hurd Rstings Odor Thrshold (pDm) PEI"/TIryA (ppm) TLV,/TtryA (ppm)
Unavailable 5 100 100 0, 1,0 None None None
cenerrl-Suspecled carcinogen.Main hazard is vapor inhalation. G€nerrl-Non{oxic
symptom!-Dizziness, headache,drowsiness,vomiting, irritaled skin, wat€ry ey€s. Symptons-Non-toxic
Short ExDcure Tolerurunavailabls Short Exluure Toleluce-Non-toxic
ExposurePrftedur6-Vapor-remove viclim to tresh air; if breathingis difiicult, administoroxygen. It br€athing E$mure PrcedurNon-toxic. lf accid€ntly splashed into eyes, wash eyes thoroughly with copious amounts
stops, apply artilicialrespiration.Skin or eye @ntact-flush attected areas tor 15 minules with watsr. Gst of water.
modical attention.

Stsbility-Stable. srlbility-stable.
CoDDrtibility-Msterid: Compatiblewith steel; certain rubbers and plasticsare incompaliblg. Compatibility-Mrtcrid: Usual maisrials of conslruction are suilable.
Crrgo: Group 33 of compatibilitychart. C.rgo: Group 34 ol compatibilitychan.

Wear rubber gloves, tace shield, plastic coaled proteclive clothing. Wsar self-cotrtalnadbforthing epprrrtus. W€ar rubb€r gloves and tac€ shi€ld. Clean up €xcala amounts and wlsh redd|J. awty wiih wator
Approach lrom up-wind side. Avoid contacl with liquid. S€cur€ ignilion 3ources.Small rpillt mry bo tlulhad rwty
wilh water.
lt I Dlll m oll tlc Nrtlonrl Rm* Ccnlcr. t00-,ar4-lltt. It r dll ccrr, cdl tL N.alill &ara-at{D.
l.nrrll I UmvdLua laaarh: I IJn{vilrl{trlo
lt I Umri|{lnod
l***.*,*b,,*.., SCANNED BY MKP & BARIS A. 2004 ,t

CREOSOTE,COAL TAR
l l (. mlrluia
CRESOLS
of orlho, mata and p.r. cr.aol)
synonymr- Coal tar creosote; Creosote from coal tar; United N.tions NuEb€l
Sytronyms-Cresol(2-, 9-, a-l: Cr€sylicaod: Cr€sylol; tJtrll.d Nrlionr Number ....... 2076
Croosote oil; Oead oil; Heavy oil; Liquid pitch oil;
Tlr oili Wash oil Hydroxymethyl banzgns;Hydroxytoluon€,
Methylphenol(2-, 3-, oi 4-li Oxyloluenos,Tar acrds;
CHRIS Cod€.......... ccT Toluol (o-, m-, p-); TricJelol
CHRIS Co&.. . CRS
l'ormuh-Unavailable
Boiling Point.......... - 392-482'F
...........-2Q9:25Q'C Formula-CHTGHTOH
to dark green-brown; _'c -'F Rollln8 Polnt . . . . . . . . . . . . . .1.4. 6 - 1 9 2 " C 2 9 5 - 3 7 8 ' F
App€rrsnce-odor-Yellowish
Freezing Point........ ........... t'c _'F ADpearanc€-Odor-Colorl€ss-to-brown liquid; smells like _'c _'F
characteristic tarry, aromatic odor "Lysol" disinlectanl, sweet, tarry
_'c _"F l'.ezln8 Polni... .........1 . 2 to 35'C 54 ro 95'F
Specific Grevity-1.07
SpeciflcGravity-l.03 to 1.05 _'c -'F
vipor Pressurc20"c (68'D (mmHg)..........---LQlg-
Chemical f'amily-Hydrocarbon (aromaiic) ph€nol R e i d V a p o r P r e s s u r e ( D s i a ) . . . . . - . . . . . . . . . .L. i.l. . . . vrDor Pr6curc 20'c (6E'n (nnHO.......... 0.52
ch€niol Frnily-Phenol Rcld Vepor Pre$ure (psia).. 0.03
VlDor Pressure 45'C (115'n (Dsia)............ Low
Pollutiotr C8t€8ory-USEPA X IMO --A- VrDorDensity(Air : 1.0)............... . NP VaporPresure 45'C (115'D (psir)............. ---q.-q0-
Pollution Cste8ory-USfPl C IUO A Vrpor Density(Air : 1.0).............. . ... 372
ADplicable Bulk Reg. 46 CFR Subch|pter.. . O S o l u b i l i t y i n W a t e r . . . . . . . . . . . . . . . . . . . .N
. .e o l i o i b l e
ApplicsbleBulk Reg.,|6 CFR Subchapter....... O Solubility in Water 2.50/"

crsdFE: Combustibleliquid
ElectricslGroup-D Grrde-E: Combustible
Electrical Group-O
cercrsl-Moderate fire hazard when exposed to heat or flame
ceneral-Moderate fir€ hazard when exposed to heal or flame. When heated, loxic vapors are given ofl.
F l s h P o i r t( ' F ) . . . . . . . . . . . . .. .. .. . 1 8 0
Flandrble Limits.......................... Unavailable 178 to 187 (varieswith compositionand purity)
Flsh Point CF).............................
Autoignition Temp.('Fl................ 637 LEL: 1.1% UEL-unavailable
FhmmableLimits..........................
('F) ..........
... '1038 to 1 195
Extinguishing A8ents..................... Conlinedaroa-Cor, dry powder.Open area-foam, water spray. AutoignitionTemp.
ExtinSuishing Co2, dry chemical,Ioam, water fog
A8ents.....................
SpecislFire Pitredur6................ Providelire fighters with breathingapparatus.Water or loam may cause
lrothing. Do not direct water directly into a lire. Specirl Fire Prqedures................Full body and respiratoryprotection should be provided. Use water to keep
fire exposed tanks cool. Use water spray to dispersevapors.
HEALTH HAZARD DATA

Herlth Hrard RrtinSs Odor Threshold(pDm) PELAWA (ppn) TLvAwA (ppm) HEALTH HAZARD DATA
Unavailable Hellth Hlard RatinSs Odor Threshold(Dpm) PEL,/TWA (Dpn) TLV,/TWA (ppm)
2, 3,2 Unavailable Unavailable
2,3,2 1 to 5 s/Skin s/Skin
cenerrl-Severe neurologicaldisturbanceswhen tumes are inhaled at high concentrations.Moderatelytoxic,
skin and eye i(itanl. cederrl-Suspected carcinogens.Causes severe burns. Poisonousby skin absorption.Odor lhreshold is aboul
the same as the TLV. Exposureto potentiallydangerous vapor concentration can occur betore the producl
SymDtoms-Difficultyin thinking, sight impairment,difiiculty walking in straight line, stammeringor stuttering can be detected by smell.
Sydptoms-Burning sensation in throal, nose and eyes. Burning senation at the site ot contacl; skin may turn
while.
short Exp6ure Tolemc€-Unavailable.
Short ErposureTolermce-Exlensive skin contact may be latal in a very short time.
l l
Exp6ure Pr@edurelnhalation: lmmediatelyremove victim lrom contaminatedatmosphere. ll breathing i3
interrupted,artilicial respirationshould be applied immediately.A physicianshould be called. ExposurePrmedures-Vapor: Femove victim to lresh air; il breathing stops, apply artiticial respiration.Skin or
eye contact: remove contaminatedclothing and gently tlush atfected area with water lor 15 minutes.Get

Stsbility-Stable.
Stability-Not dangerouslyreactive.
ComDatibility-Mrterial: Nol corrosiveto iron or sle€|.

Not considered corrosive to most of the usual mat€rialsof construclion.
Cargo: Group 21 ol compatibilitychart. See also Appendix l-Exceptions to tho Chari.

Cargo: Group 21 of compalibilitychart

Wear rubb€r glovss, lace shisld, protsciivs clothing. Have all-purpose cgnialer mask evarlablo Socur€ all
rgnationsourcss. Wear rubb€r gloves, lace shield, and protective clothing. Avoid contact with the liquid. Do not llush inlo
navigabla water or wh€r€ it may b€ conlact€d by human bsings or animalg.
lt I Dlll Gr[. olt lhr Ndond tnc Ccrc.Oili]Ftll2 qturr.

lr r llll c.ll tL Nr$u! nm Crnler, tlXLa2/t n2.
I
Rcrulr: I Un|vdhua
nrrbr
I Unrrion d
SCANNED BY MKP & BARIS A. 2004 '^

CRUDEOIL
CROTONALDEHYDE Synonyro-Coal oal; Mineral oil; Petroleum: Peirolsum 1267
Ullacd Nralou Numb€r ..
synotryn.-2-Butenal: trans-2-Butenal; 1143
UnitedN.tionsN[nbcr................................ crud6 oil: Rock oil: S€ns8 oll
Croienaldehyde;Crotonaldehyde,
stabilized;Crotonic aldehyde;beta-
Methylacrolein;Propylonealdehyde CHRIS ('ode ............. . . . . .. . otL
CHRIS code........... .... CTA
Fomulr-C"Hr,+r, or CHnHzn-2
I'ormula-CH"CH: CHCHO B o i l i n r P o l n l . . . . . . . . . . . . . . . .3. .2.-. 4 0 0 " C 9 0 - 7 5 0 ' F
BoilingPoirt.......................... 1O2'C 216'F App€mnce-Odor-Thick, h6avy liquid, ygllow to dark -ls'3
App€orance-odor-Waterwhite to yellow liquid; - -zq'3 reddish-brown or black color; distinct tarry odor. Freczins Potnt......... a'F
suflocatingtarry odor FreezingPotnt......... . . t*'F Specific Grsvity-o-8s to 0.95
SpecificCravity-o.85 -"c -'F Vrlor Presurc 20'C (63'l) (mmllg).......... -L!Ql-
C'henicd Fmily-Hydr@arbon mixture -0 10
Vslnr Presure20'C (68'F)(mmH$.......... 30 Reid Vepor Pr€sur€ (Fis)......... .. ..
ChemicdFmily-Aldehyde ReidVsDorPrsure (Dsia).................. ..... 15 Vapor Prwure il6'C (115'D (psia) ........... ---9J5--
Pollutlon Category-USEPA - IMO I Vapor DeNity (Air : 1.0)........................ above 1
VaporPressure 46'C (115'D (paia)............. ---?!-
PollutionClte8ory-USEPA B IMO B V a p o r D e n s i t y ( A i:r 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .2. . 4 . .1. . Applicrble Bulk Reg. '16 CFR Subchapter........ D SolubilityinWrter......................... Neolioible
ApplicrbleBulk Reg,46 CFR Subchapter........ O S o l u b i l i t y i n w a t e r . . . . . . . . . . . . . . . . . . . . . . .S
. .l i o h t

FIRE & EXPLOSION HAZARD DATA GrrdFC or D depending on flash point
Flammableliouid Eletricd Group-D
Elstricrl Group-C
G€Derd-When heated to decomposition,it emils toxic tumes. Moderate to sgvere.
elevated temperatures,polymerizationoccurs. ll the polymerizationtakes place in a closed
container, violent rupture is possible.
F l s h P o i n tC F ) . . . . . . . . . . . . . . . . . . . . .-.5. .0. . .t .o. + 9 0
Flsh Point CF).............................
55 Flmble Limits.......................... Unavailable
Flrmmable Limits..........................
2.1o/olo 1 5.5o/. AutoiSnitiotr Temp.('F)................ Unavailable
Autoi8nition TcmD. CF)................ 450 ErtinSuishitrgAgent! CO,, dry chemical, foam, waler fog.
Alcohol loam, carbon dioxide or dry chemical.
ExtinSuishing A8ents..................... Spsirl Flre Prmdurq................ Tanks exposed to lire should be kept cool wilh a water spray. Fire lighters
SD€cialFire Pr@edures................Cool hot container surfaces wilh water. should weaf respiratoryprotection.
HEALTH HAZARD DATA

HEALTH HAZARD DATA Helth Hred Rrtirgs Odor Thrahold (ppm) PELAWA (ppn) TLVITIVA (pDn)
Health H@rd Rltings Odor Threshold (ppm) PEL,/TWA (pDm) TLVITWA (ppm) 0, 1, 1 Unavailable Unavailable Unavailable
3 .3 . 3 0.13 2 2 Gercrd-Liquid causes skin irritation.
cenersl-Suspected carcinogen.Vapor extremelyirritating.Liquid causes severe burns. A lachrymator.
SymDtons-Skin contact; skin irritationand burns.

symptoms-Vapor causes eye irritalionand burning skin irritationat high concentrations,and inhalation results
in coughing,watering of eyes and burning ol nose and throat. Liquid causes severe irritationto eyes and Short Exposue Tole@Unavailabte
sKtn.
Short ExpooureToleruce-Unavailabl€.
ExDcure Preedurc-Wipe spilled liquid lrom skin, remove contaminatedclothing, and wash atfected areas
Exposur€Pr@edures-ln case ol skin contact, wash thoroughlywith soap and waler for at least 15 minut$. In with soap and water. For eye contact, llush with water tor 'l5 minutes while obtaining medical attention.
cas ol eye contact flush with water then obtain medical aid.
REACTIVITY DATA
REACTIVITY DATA Stlbility-Chemically stable.
Strbility-May polymerizewhen mixed with acids or bases.
Compstibiltty-Mrterisl: Usual materialsol consiruction are suitable.
C4npdibility-Mrterisl: Compatiblewith aluminumand stainless steel.
Cirgo: Group 33 ol compatibilitychart.

Cargo: Group 19 ol compatibilitychart. See also Appendix l-Exceptions to the Charl.

SPILL OR LEAK PROCEDURE Wear rubb€r gloves, facs shield, prolsctive clothing. Have gll-purpos€canister mask avlilrble. Secura
W€ar rubber gloves, self-containedbreathing apparatus, proteclive clothing. Avoid contact wilh liquid Secuta ignition sources.
ignilion sourc€s. Cover wilh edium bisulfita (NaHSq). Add small amouni ol weter and mlx, Scoop up. W|!h
site wilh soap solution.
It r Dill ccrn. crll tlc Nrtlotrd
ll . rDlll acu6, crll ah. Nrtlond ndm Crtr. m{:!F02. Rcmrrtt
RcnrrlE
llr
_ .dili;,*i,iil,*;,;..,;'*i,:',;....*,:1.. _,. .-.., , * *_ai'_* .."_,.*_,,,., SCANNED BY MKP & BARIS A. 2004
: : ,.- -,,..-lr'.:ublliid&l&hlcn
7l
CUMENE CYCLOHEXANE
SynotrynF Bgnzen€, hexahydride:Banzen€,
Synoryms- Benzene, 1-methylethyl-;Cumol; lsopropyl United Nrtions Number........ 19.19_ hexahydro-;[Hsxahydrob€nzgne:Hoxam€thyleno:
benzene;(1-Methylsthyl)benzene;2-Phenylpropans Hexanaphth€ns
CHRIS Code..
Fomuh-CHr(CHr).CHz
Fornula-GH.CH(CHr)z Bolllng Poin! 8t'c 177'F
Boilin8 Point.. 152'C 306'F
ADpeannce-Odor-Colorl$s mobile liquid; sweetish
'c
liquid;sharp, pengtrating
ADp€arance.Odor-Colorless -go'c odor when highly pur€, pung€nl odor otherui8€. F r e e z i n SP o b t . . . . . . . . . . . . . . . . . . . . . . . . 7'C 44'F
aromaticodor Fr€ezlng Point rare
StEilic Cravity-o.86
'c 'F Sp€cificGraYity-o.78 - U
"
Vlpor Presure 20'C (6S"n (nnHO..........
VaporPressure 20'C (68'n (nnH$.......... 8 Chemicclfrmlly-Saturated hydrocarbon Reld Vapor Prwure (pslr)........................... 3.3
Ctemicrl F.nily-Aromatic hydrocarbon ReidVrpor Pressure (psis)................... 0.5
vrpor Pressure {5'C (115'F) (Dotr)............. 4.5
VaporPressure i5"C (lls'n (psis)............. 0.6 Polludoo Cstegory-USEPA C fn O C' vrpor DeEity (Alr : 1.0)........................... 2.9
Pollutior Crtegory-USEPA D IMO B VaDorDersity(Air : 1.0).....................
.. .. 4.2
ApDliqble Bulk Reg.46 CFR Subchrpter...... D. O Solubi|ityinwiler......................... lnsoluble
ApplicrbleBulk Reg.{6 CFR Subchapter.. .... D. O Solubility in Wrter .. Neolioible

FIRE & EXPLOSION HAZARD DATA crade-C: Flammableliouid
Combustibleliouid Electrical GreuP-D
ElectricslGroup-D
General-When exposed to heat or flame it can reacl with oxidizingmaterials.Flashbackalong vapor lrail may
ldms exolosive mixtureswith air. occur. Vapor may explode it ignited in an enclosed area.
F l s b P o i n t C F ) . . . . . . . . . . . . . . . . . . . . . . .4. . . . . .
102 (cc)
Flsh Point('F)............................. FluDrble Lin1ts.......................... 1.3 to 8.4',6
Flammsble Limits..........................
0.9 to 6.5% AutoignitionTemD,('n................500
AutoiSritionTemp. ('D................795 Ertinguishin8A9ents..................... Foam,carbondioxideor dry chemical
Erti4uishirg A8cnis.....................
CO,, dry chemical,toam,water tog Sp€cialFire Prsedur6................ In unconfined tires, solid hose streams tend to scatter the liquid and spread
Fire Preedure................ Use water to keep fire-exposedcontainerscool the fire. Us water spray or high prsssure fog to cool a burning surface and exclude air to control or
extinguishfire.
HEALTH HAZARD DATA

t, HEALTH HAZARD DATA
Heslth Hsand RdiDSr Odor Thrqhold (ppm) PEL,/TWA (ppm) TLV,/TWA (ppn)
Hedth Haard RatinSs Odor Threhold (ppn) PELAWA (ppm) TLVAWA (ppn)
1, 1,2 300 300 300
1. 1. 1 1.2 so/Skin so/Skin
Geoeral-Undesirable etlects may occur lrom the inhalationof excessive concentrationsot cyclohexanevapor,
and liquid irritalion. prolonged or rep€at6d skin contact with liquid, and from liquid contaminalion of ey€s.
SymptorDizziness, nausga,vomiling, unconsciousness.

lrritalionof nose and throal; drowsiness
Shori ErDocureTolerance-No chronic ettects have been observed to occur in workers exposed to vapor
Short Ex!6ure Toleruce-Occasional short exposure lo concentrationot 400 ppm probably would not be concentrationsin the range of 600-700 ppm.
harmful.
Extpsure Prmedur6-lf cyclohexaneis splashed into the eyes it should be flushed out immediatelywith
ExlDsurePrmedurrvapor-remove victim to fresh air; il breathingstops, apply artificial respiration.Skin ot copious amount ol water. For over-exposureby inhalationto high vapor concentrations,remove patient to
eye contaci-remove contaminatedclothing and ganlly flush atfected areas wilh water for '15 minutes.Gal tresh air, adminisler orygen therapy or artilicial respirationit necessary.
REACTIVITY DATA
REACTIVITY DATA
ll can reacl with oxidizingmaterials. l
Usual materialsof construction are suiiable.
Anacks rubber
Cugo: Group 32 ot compalibilitychart.

I Csrgor Group 31 ol compatibilitychart.

l SPILL OR LEAK PROCEDURE
Wear rubb€r gloves, facs shi€ld, protective clothing. Havg all-purpos€canblsr mask avail8ble.S€curo
Wear rubber glov€s, lace shield, protectiveclothing. Have all-purposocanislsr mask availablo.Avokt contact ignition sourcsg.
with liquid.Secure ignilion sources.Small spills may be washsd away with wal€r.
ll | |'lll acur. cdl aheN.aloml nm C.!acr, tlD{2/a-l01

l lt I elll Gn crll ibe N.tloul Rsme C.!i.r. 6{X}{24-ttll2.
llcnrrb: ' Pollution Cllogory C

oil-liko, 33 CFF 151.49.
llcouh "
T
V.por Protur. 97.6 mmHg at 25'C.

77
CYCLOHEXANOL CYCLOHEXANONE
Synonyro- Cydohoryl alcohol; Hexahydrophenol; ----l-
United Nstions Numbcr................................ SynonyrCyclohsxyl k€lone;Ketohoxamothylene; 1915
UnlaedNrtkrN Numbcr...............................
Hydrorycyclohoxane - Pimolic ketone
cHRIs Code........... .... CHN CHRIS Codr...... . . . . . . . . .c c H

t--t
Fomula-GHr(CHdTCHOH Fmdr-CHdCFlr)r@
BoilingPoint.......................... 161'C 322'F 8 o 1 1 h 3 P o t n t . . . . . . . . . . . . . . . . . . . . . . . ' 1 5 6 '3C1 3 ' F
Appemnce-odor-Coloda$ to pale yellow oily liquid; _'c _'F Appormce-Odor-Water-whilo to pale yelbw lhuid;
camphor-likeodor Fruzins Poirt........................ 24"C 27'F odor reminisc€nlot popptrmlntand acoton€. t'rcrln8 Poht..,.........,........... -31"C -24'F
SpslRc GrsYity-0.94 _'c _'F SDelRc Gnvity-o.gs _'c _'F
-+*- c.henrcd
Fmiry-Ketone -*-
cremicrr
Fmny-Arcohd Hil'r:ffi',""1l;:,t$,J.1'1"-?-.::.:.':.: l;tr'":ff1"J":3n11'-"-1 . .
VrDor Prsure,l6'C (115'F) (psid.............---Q3- -t?-
PollutionCotegory-USEPA - tUO
-
C Vrpor Density(Air : 1.0)........................... 3.5 crtesory-usBpAp
po.utron rMo p l:il: 3:ff,fifi;":tT.'.,"11t"] .
ApplicablGBulk Reg 46 CFR Subchrpter........-9,Q- solubility in wster.........................
----S!gbl- Applleble Eulk Re8. ,16 CFR Subchrpt€r........ O Sotubillty ltr W.ter ......................... Slioht
GndFE: Combustibleliouid GrrdeD: Combustibleliquid.
Electrical Group-D Eleticrl Group-D
c€ncnl-Modsrate tire hazard.when exposed to heat or flame il can react with oxidizingmatsrlal8. G€rerd-Moderate lire hazard,when exposgd to heat or flame.
154 (cc)
Fl$b Point CF)............................. FlNh Point Cn.............................
129
Linits..........................Unavailable 1.1 to 8. 1o/o
I{mmble Limits..........................
AutoiSritionTcnp. ('F)................
572 { AutoignitiotrTenp. ("D................
788
ErtinSuirhiq Ag€nts Alcohol loam, carbon dioxide,dry chemical. ( ErtltrguishingAgents Alcohol loam, dry chemical, CO2
Spcid Ilre Proeduro................ Cool expos€d tanks with wat€r. W€ar self-containedbreathing apparatua. SDe.td Fire Preedure................ Wear full protective clothing, s€ll-containodbreathing apparatus.
HEALTH HAZARD DATA

l l HEALTII HAZARD DATA
Heslth Hred RrtinSs Odor Thrqhold (ppE) PEL,/TWA (ppn) TLvAwA (pDm) H@ltb Hr4d Ratirgs Odor Throhold (ppm) PEL,/TWA (Dpm) TLVAWA (ppn)
1. 2. 1 Unavailable so/Skin so/Skin 3,2.1 O.12 2slskin 2slskin
Generrl-Vapor and liquid iritation. Systemicellects produced. inhalationiritating to mucous membranes.
SyEptoms-Vapor-irritation of mu@us membranes,headache. Liquid-ulceralion, lhickening ot skin. SymptorEye, nose, and throal irritation;narcosis, salivation;depression of body temperature,respiralory
rates. heart rates.
Short ExD6ure Toleronce-3 to 5 minutes exposureto 100 ppm was obiectionable,producing nose, eye, and Erp6ur€ TolemcFso ppm tor 3 lo 5 minuies was uncomtortablyirritating,particularlyto lhe throat.
throal irritalion. Definitg eye, nose and throal irritalion was reported at 75 ppm.
Exposr.ePrmedur6-Vapor-remove victim to tresh air; if breathingstops, apply artiticial respiration.Skin or ErtMure Preedurs-Vapor-remove victim to fresh air; il breathing stops, apply artificial respiration.Skin or
eye contact-remove contaminatedclothing and genlly flush attsted areas with water for 15 minutes;20 to eye contact-rsmove contaminatedclolhing and gently llush allected areas with water lor '15 mintues. Get
30 minuteslor eye contact. G€t medical attention. medical advice or attention.

Strbility-Stable. Stability-Stabl€.
CamDrtibility-Material Usual malerialsof constructionare suitabl€. ConDqtibility-Mrterid: Usual mat€rialsof constructionare suitabl€. Will attack most paints.
Cugo: Group 20 ol compatibilitycharL Cergo: Group'18 ot compatibilitychart.

Wear rubb€r gloves, facs shield, protecliv€ clolhing. Have all-purpos€canistgr maak aveileble.Avoid conlact It possibl€, woar rubb€r gloves, lacs shi6ld, and prolective clothing. Secure ignition sources. Havs all-purpose
with liouid. canider mask availabl€. Keep unproiecl€d persnnol upwind ot contaminatedarea. Flush spill with water,
r rplll mur1 cdl thc Nrdonel Ralou Ccltcr. &X}..l mcurr, oll lic Nralon.l RdDor Crraq. ext{2a-ttlt2.
nJfn I Unassigned fr-
1t SCANNED BY MKP & BARIS A. 2004 19

CYCLOHEXYLAMINE
l l P.CYMENE
Synonyn!- Cymol; Oolcymsne;4-lsopropyl-l-mothyl Unf tcd Nrtioil Number................................2046
syDonym3- Aminocyclohexane; Cychlohexanamine; ............ 2357
UnitedNstio6 Nunber.................... benzens; lsopropyltoluene;4-lsopropyttotuene;
Hexahydroaniline p-lsopropyltolu€ne;M6thylisopropylbenzen€:
1-Melhyl-4-isopropylbsnzene;Msihyl propyl
benzene CHRIS Code.. CMP
CHRISCode........... .... CHA
Formula-CHlQHTCH(CHsh
Fomula-(CH,!CHNHz Boiling Point.. ...... 177'C 351'F
' o i l t r s p o h i . . . . . . . . . . . . . . . . . . . . . .i .3.s. .' " 1 n , Appeuuce-Odor-Colorl€ss liquid; b€mene-like odor _"c _'F
Appeormce-odor-Colorless liquid; strong -ta'3 Fre€zin8 Point ...... - 6 8 " C - 90'F
ammonia-like odot Freezing Point......... .... *:F SDecificGr8vity-0.86 _'c _'F
Specific Gravity-0.865 -'c -'F
Vrpor Pr$ure 20'C (68'F) (mHg).......... Low
VaDorPrwure 20'C(5s"F)(nnHg)..........--01-ZZ- Ct€micd Frnily-Aromalic hydrocaabon ReldVrpor Pressure (pir)...........................
Low
Chemical Fmily-Aliphatic amins Reidl rpor Presurc (06i4,......... Vrpor Prmure 46'C (f15'D (D6ir).............0.46
VsporPrwure 45'C (lfs'F) (pch).............0.619 Pollution Cstegory-USEPA - IMO C' Vqpr DeNity (Air : 1.0)...........................
4.62
Pollution CrteSory-USEPA - ttrlO C 3.42
VaDorDensity(Air : 1.0)...................,....... Applieble Bulk Reg.{6 CFR Subchspter........ D. O SolubilityinWiter........................ Neolioible
ApDlicsble Bulk Reg. 46 CFR Subchapter...... . O SolubilityinWater.....................S..o
. .l u b l e

FIRE & EXPLOSION HAZARD DATA GndeD: Combustibleliquid
Grade-D: Combuslibleliquid Eletricd GrouI+D
Elctrical Group-D
General-Slighl explosion hazard when in th€ lorm of vapor.
Generrl-Dangerous wh€n expossd io h€at or tire; gives ofl toxic fumes. Flashback along vapor trail may occur.
Vapor may explode if ignited in an enclosed space.
F l s h P o l n tC F ) . . . . . . . . . . . . . . . . . . . . .1. 1. .7. . . . .
Flsh PointCn.............................
90 Flmmble Limits.......................... O.7lo 5.6"h
Flmnable LinitE..........................
Unavailable Autoigritiontenp. ("F)................ 817
AutoignitiorTenD.('D................560 ExtinSuishinSAgerts COu,dry chemical, water fog, toam
ErtinguisbingAgeilt.....................Fmm, COz,dry chemical Sp€cid Fire Procedus................ Fight in the same manner as any Grade D p€troleum product fire. Water may
Slecial Fire Prcedue................ Wear goggles and self-containedbreathingapparatus.Cool exposed tanks be inetteclive, The vapors ot cymene are more toxic than those of petroleum products.
with water.
HEALTH HAZARD DATA

HEALTH HAZARD DATA Health Hurd R.tirgs Odor Thr6hold (ppm) PEL^WA (ppn) TLV,/TtryA Opm)
Health Hurd Rstings Odor Thruhold (Dpm) PEL,/TWA (ppn) TLVITWA (ppn) 0, 1, 1 Unavailable Unavailable Unavailable
3,4,2 Unavailable 10 10
Cenersl-High vapor concentrationsare intoxicating.
Gerersl-Strongly caustic.
Symptoms-Oizzin€ss,headache,and naussa. The victim mav act as it drunk.

symptoms-lnhalation of vapors, and skin and eyes contact with liquid will cause severe burns.
Sbort ExposurcToleruceUnavailable
Sholt Exp6ue Tolerance-Unavailable.Acute exposure cau$s nausea,anxiety, apprehension,slurrsd speech,
pupilarydilation.
ExDcue Prcedures-lngestion-do not induce vomiting. Eyes-flush with water lor at leasl l5 minules, get
medical attenlion immediately.Skin-remove contaminatedclothing and llush skin with larg€ amounts ol
waler.
t Expcure Prceduevapor-removs victim to fresh air; if brealhing stops, apply artificial respiration.Skin o.
eye contact-remov€ contaminatedclothing and gently llush attected areas with water lor 15 minutes.Get
medical advice or atlsntion.
REACTIVITY DATA
REACIIVITY DATA stability-stable.
Strblity-Stabl€.
Crmlntibility-Mrterid: Cymene will €us rubb€r to swell and sotten.

ConFtlbthty-Mrtcdd: Conosive lo copper and its alloys.
Cego: Group 32 ot compatibilitychart

Cr4o: Group 7 ol compatibilitychart

s P u . t . ( ) R t . t , l ^ KI ' R ( ) ( ' u t ) u R E Wsar rubbsr glov€s, lace shield, prolective clothing. Have all-purpos canister mask availabl€.Ss{r€ ignition
Avilt co||ci nlh Lqdd Kip FogL .r.y W..r lull p|oloclrv. clolhng, loll-conitinod bretlhing atfra,!fur sourcas.
,rrxl nioar Orarcb0rql l.y lo (:rnbh ls lJgp qillr rLrtrx r.rd llrJrh Sruro |gntlion aoucaa,
lt I rplu ccu, cdl tic Ndior.l Ratre Ccnio., AXI42a-8802.

lf r dl rr:r ,.a lt ., ..1 l.{- ('ntor ill ll..ll
Rruh ' Pollulpn
Crt.gory C orl-Iko. 33 CFR t5t 49
i lffF
h-L'
t
sr, -i -M--.-ju. SCANNED BY MKP & BARIS A. 2004 u
iso.DECYLACRYLATE
iso-DECALDEHYDE
Synonyns- Acrylic acid, isodecyl estsr; lsodocyl
stMynFlsodsaldehyde, mixed isomers; UnitedNrtiotrsNunber.................... acrylate; lsodtryl propenoale
Trim€thylheptanols
CHRIS Cod€..
SHRIS Code........... .... IDA
Fornuh-CHr : CHCOOC,"HI
l'omuh-GHr0CHO, mixture ol isomeB BolllnS Polnt.. 121"C 250'F
Boilirg Point.......................... 197'C 387'F Appeme-Odor-Waler while liquid; pungeni odor --
Apperrrnce-odor-Colorless liquid with a pleasanl fruity FEzlng Point too.c - tag-"f
odor Frezins Poirt......... ... -80:3 -,*'F oa oE
SpecificGrrrlty-O.89
Specific GnYlty-O.83 _'c -"F
vrlpr Pr@wc 20'c (6t'F) (nnHo....... < 0 01
vrDor Pre$urc 20'C (6E"D (nnHg).......... --qza- ChemicalFrnlly-AcMalo R € l dV . p o r P r 6 u r € ( p s i r ) . . . . . . . . . . . . . . . . . . . . . .L.o. .w. .
Ch€nlcd Fmlly-Ald€hyds ReidVrDorPresure(pch)........................... 0'03 VrlDr Presurc 45"C(lfs"n (psia)...... Low
vspor Prcsure {6'C (f15'D (Dsia)............. ---0!0- Pollution Crte8ory-USEPA - IMO A V r D o rD c n d t y( A i r : r . 0 ) . . . . . . . . . ............ . . . . . 7 . 3
PollutiotrCsteSory-USEPA - IMO @C :
VrDorDensitv(Air 1.0)........................... 5.38 ApplicableBulk RGt. 15 CFR Subchrptrr........ O Neolioible
Solubility in Wster
ApDlicabl€Bulk Reg",15CFR Subchapter........
---Q-9- S o l u b i l i t y i n W a t e r . . . . . . . . . . . . . . . . . . . . .l .n.g. .l u b l e

FIRE & EXPLOSION HAZARD DATA Grrde-E: Combustibleliquid
GndeE: Combustibleliouid Eletrlcd Grout+D
Electricd GrouD-C
Gerenl-May polymerizeto gummy solid. Beaction is not violent.
General-This material is more of a health hazard than a fire haard.
F l s h P o i n t( ' n . . . . . . . . . . . . . . . . . . . . . .2. .4. 0. . . .

Flsb Point(.F).............................
185 Fluhible Limits.......................... Unavailablg
Flmmble Limits..........................
Unavailable AutoignitionTemp.('F) ................ Unavailable
AutoiStritioD 375
Temp.CF)................ Ertin8uishingA8ents..................... Foam,dry chemical,Co,
ErtitrSuirhingAgerts Carbon dioxide,foam and dry chemical SDecidFire Pr@cdur6................Water might be ineffective.Cool exposed tanks with waler.
Spetd Flre Preedurs ................Cool coniainer surfaces wilh watsr.
HEALTH HAZARD DATA

HEALTI{ HAZARD DATA Heelth Hr4rd Rrtirgs Odor Tb.eshold (ppm) PEL,zTWA (ppm) TLV,/TWA (ppn)
He8ltb Hurd Rstirgs Odor Thrahold (ppn) PEL,/TWA (ppn) TLV,/TwA (pDn) 1, I, 1 Unavailable Unavailable Unavailable
1. 1. 1 Unavailable Unavailable Umvailable
causes swelling and redness atter about 10 minutes.
irritatingto mucous membranes.
contacl: Swelling and redness.

Symptoms-Coughingand sneezing,burningand tearing ol eyes, salivation.Signs ot initalion of lhe mucous
memDranes.
short ExlDsureTolerrnce-8 hour exposure ol rats to concentratedvapors approachingsaturationin air was not
Short ErDGure TolmFunavailable faial. Inhalationcauses mild irritation of nose and throat; vapor mildly irritates eyes.
ExposurePruedurstrong concentration on the skin will produce bums. Obtain medi€l treatmenl. Wsaker
solutionsmay caus di$oloration, rougheningand htrdening. Spills on skin should be washsd immediaiely
with soaDand waler. r ExDosurePr@edures-Vapor-remove victim to fresh air. Give artificial respirationil breathing stops. Skin or eye
conlact-remove contaminatedclothing and gently flush affected areas with water lor 15 minutes. Ggt
REACTIVITY DATA
REACTIVITY DATA Stability-Stable il inhibitsd.
Shbillty-Stable.
Crnpstibility-M8t€ri.l: Will swell and sotten cerlain rubbers and sotten and remove certain oaints
ComD.tibility-Mrtertd: Compatible with aluminum, steel, stainles steel; not compatible with galvanizsd iron
Csgo: Group 14 of compalibilitychart.


SPILL OR LEAK PROCEDURE lf FDssiblewear rubber gloves, tace shield, and prolective clothing. Have allpuapose canister mask available
Wear rubber glwos, slt-containsd breathing apparatus, prottrtive clolhing. Avold conlrcl wllh lQuU. Cover Socure ignition sources. Flush gway with water. Do not tlush into confin€d space (such as a s€wer) because ol
spill with sodium bisullite (NaHSO!). Add small amounl of wator and mix. Sc@p up. W||h tile wilh totp lhr dangor of explosion.
$lution.
lf r rplll ccun, 6ll thc Nralo[l RerDor* Ccntcr, tflL42,LtE02.
lf . iolll trcrn crll lhc Natlon.l
lffrrlr: I lJnil\qUnIrl
f-f. I Unrlgmd
SCANNED BY MKP & BARIS A. 2004 ;r ,..eidr&i&

IJ
N-DECYLALCOHOL DIACETONEALCOHOL
str.Q|r- Alcohol C-10; Capric alcohol; 1-Decanol; UnitedNrtio8 Numb€r................................
----J- SyronymF Oiacetone;4-Hydroxy-4-methyl-2-pentone; tjnltGd N.tlons Number 114!L
Nonylcartinol 4-Hydroxy-4-methylpsntanon€-2;
2-Methyl-2.petanol-4-one
.... DAN CHRIS Code........... OAA

CHRTSCod€........... "all isomers" oAX
Fcnulr{llr(CHr)rCH:OH Fomuh-CHaCOCH,C(CHr),OH
451'F B o l l l n SP o i n t . . . . . . . . . . . . . . . . 164'C 32A'F
8oi1in8Point..........................233'C
Attcrr.nce-Odo.-Colorless, water white liqukt;sour Appemce-Odor-Colorls$ to light ysllow liquidi lalnt, _'G _"F
pleasant odor . . 50'c -58'F
odor po1nr.........
Freezfn8 . .... 7:3 -rt-:F hoezln8 Point..........
SFclnc Gnvity-o.83 _'c _'F SpeclflcGrrvity-O.94 _"c _'F
vrpor PrNure 20'c (6t'F) (mmHg)..........f,lou- Vrpor Prcurc m'C (68'n (mmHg).......... ---l-.L
Cteblcd F.nily-Alcohol C'hemicrlFmily-Kelon€/Alcohol (exhibits prop€rli€s R c l d V r D o r P r u u r e ( t d i . . . . . . . . . . . . . . . . . . . . . . .0. ...0. 7
ReidVaporPrsure (Dsir)............ V. Low
.............. of both) VeporPresure,l6"C(lfs'l) (pstr)............. 0 1
vrDor Prsure 46'C (f lS"F) (Dci.).............]ll9!1"- D
Pollutlon Crtetory-USEPA - IMO --E-- 53 Pollutlon Crtegory-USEPA - ffrlo v.Dor Dcnsity(Atr : 1.0)........................... 4o
VrDorD€nsity(Air : 1.0)...........................
AppllcrbleBulk Reg.,16CFR Subchapter........ D. O Solubilityin water......................... lnsoluble Applicrble Bulk Reg.46 CFR Subchspter........ D S o l u b i l i t y i n w r t e r . . . . . . . . . . . . . . . . . . . . . .C o m o l e t e
Combustibl€liquid.
UOmOUSII
Grade-E: Combustible liouid
UlloFE:
Elecfidql Group-D
Electrical GrouF-D
haard, whon sxposed to h€al or flame; can react wiih oxidizingmateriab. Gener8l-Moderate hazard, when exposed to heal or flame.
F l s h P o i n t ( ' D . . . . . . . . . . . . . . . . . . . . . . . . .1. 2
. .6. ( c c )
nuh Point CF).............................
180
Flunable Limits..........................1.8 to 6.9olo
Fhmmrble Limib..........................Unavailable
Autoignition Temp. ('F)................ 1 1 18
Auioi8ritioD TGmp. CF)................ 550
Extinguishing A8erts.....................CO,, dry chemical, waler fog, alcohol foam
Exthguirhing A8ents..................... Alcohol loam, carbon dioxide, dry chemical, water spray
Fire Prueduro..........,.,... Nol Frtinenl
specid Fire Prccdurs................ Firg parties should be provided with respiratory protection.

Herlth Hurd Rrtirgs Odor Thr6hold (Dpn) PEL,/TWA (ppD) TLV,/TWA (ppn) Hedtb H8Ad Ratings Odor Threhold (ppm) PEL,/TwA (ppm) TLV,/TWA (pDn)
0. o. 0 Unavailable Unavailable Unavailable 1.2.O 25 50 50
non-toxic.Handle as a detergenl. Main haard is liquid coniact wilh eyes. c4nerd-lrritating to eyes and mucous membranes.Narcotic in high concentration.Experimentallyhas caused
anemia and damage to kidneys and liver.
and eye contact-considerabls pain and irritationto eyes; skin irritation. SymptorBurning of eyes and nasal passages;diziness, drowsine$.
Sbort ExposureTolermcel50 ppm for 30 minutes.

Short ExIGure Tolemrunavailable
Ex!trure Prc€dor6-Eye contact*flood gently wiih clean water for at l€ast | 5 minutes.Skin contact-removs ExposurePr6edur6-Vapor-remove victim to lresh air; il breathing stops, apply artificial respiration.Skin or
conlaminaledclothing and wash atfected areas with plenty of water. eye contact-remove contaminatedclothing and genily flush aftected areas with water for 15 minutes.Get
REA€:TIVITY DATA REACTIVITY DATA

Strbility-Stable. Strbility-Relatively stable. Can react with oxidizingmaterials.
Crrprd$illty-Mrtertsl: Mild sleel is suitabletor tanks, pipes, valves. ComDstibility-Materia} Dissolvesor soft€ns n'any plastics.
Crrgo: Group 20 ol compatibilitychari. See also Appendix l-Exceptions lo the Charl. Cugo: Group 20 of compatibililychart. See also Appendix l-Exceptions to lhe Chart.

W.!r rubb€r glovo8, lace shield, protectivs clolhing. W€ar rubb€r gloves, taco shield, prot€ctive clothing. Havs all-purposecanister mask available.
lt I rDlll ftcurs. crll the NrtloDd Ccrtet

lt . |Dlll 6urr, cdl thc Nralotrd uHza-t0r.
frrff, lcmrrlt
| Utrarlgn d
u SCANNED BY MKP & BARIS A. 2004 lt5

DIBUTYLAMINE
ll Synonynr- No common synonyma.
DI.Sec.BUTYLAMINE
tJnllcd Nrlloil Numbcr....................
synonyr 1-Butanamine,N-butyl-; 2244
Urited Nrtioc Number........,.......................
N-8utyl-l-butanamine;di-n-butylamine;
n-Oibutylamins;di(n-butyl)amine
CHRIS Code ,. DBA

ll ('llRts (ide.. ' ' . ' . ' , ' . ' ' ' . . ' . ' . , ' .1
Fomulr-(CH"CHCH"CH'hNH
ll
Fornula-(CrHs),NH Boiling Polni.. 132-135'C 270-275"F
BoilingPoitrt.......................... 159'C 318'F ADp€mc-Odor-Watgt white liquid; amim odor _'c _'F
Appemce-Odor-Colorless liquid;ammoniacalodor. l'reslng I'olnl 104"C - 155'F
FreezingPoint......... ......... 51'3 -*:F SD€cilicCnvlty-o.75
"c "F
SDecincGnYity-o.77 Vlpor Prwure 20'C (6t'D (mmH$..........---lr-
vrpor Prsue 20'C (5s'F) (mHg).......... 2 C]|temlql Fmlly-Alkyl amines Reid Vepor Pmurc (pdr)....
Ctenicsl Frmily-Alkyl amin€s 0.0
ReidVsporPrcure (psir)........................... Vrprr Pr€$ure46'C (ll5"n (psie)............. ---QJ-
Vrpor Prro 45"C(115'F)(Dcir).............0 18 PolluaionCrtcgory-LSEPA - IMO -----f- Vrpor Denslty(Alr : 1.0) . . ........ 4.5
PollutioD Cstegory-USEPA - fUO C 4 46
Vrpor Deulty (Air : 1.0)........................... ADpllc.bleBull Re8. 46 CFR Subchrpter........ O S o l u b i l i t y i nw r t e . . . . . . . . . . . . . . . . . . . . . . .U
. .n a v a i l a b l e
ApplicableEulk Reg.,|6 CFR Subchapter........ O Solubltlty ln TYater. Aoorsiablo

FIRE & EXPLOSION HAZARD DATA Grade-C: Flammable liquid.
cndFo: Combustibleliquid Eletricd Grorp-C
Electrical Grcup-C
Generrl-Dangerous tire risk.
cererd-Toxic oxid€s of nitrogen may torm in lirss. Flammable, modetate fire risk.
Flsh PoitrtCn.............................
75
Fhsh Poht CF).............................
125 Flmm.ble Linits..........................
Unavailable
Fbmn.ble Linits..........................
LEL: 1.1'l. UEL-unavailable AutoignitionTemp.('F)................Unavailable
AutoiSnition TenD.CD..............iUnavailable Extitrguishing
A8erts.....................
Confinedspace:COr, dry chemical.
Extin8uilhitrgAgcrts.....................
Contined space-Cor, dry chemical SpecialFire Prcedu6 ................Cool exposed tanks with water.
Speid Fire PraeduE................ Use water lo cool fire exposed containers.Waler may be ineltective on lire
Wear goggles and $lf-contain€d breathingapparatus.
HEALTH HAZARD DATA

HEALTH HAZARD DATA Heslth Hurd Ratings Odor Tbrohold (ppm) PELAIVA (Dpm) TLV,/TWA (ppn)
Hedth Ha8d Rltlur Odor Tbr6boli (ppn) PELITWA (ppn) TLv,/TtryA (ppn) 3,3,0 Unavailable Unavailable Unavailable
4. 3. 3 Unavailable Unavailable Unavailable General-lrrilation of ey€s and respiratorylracts, severe to eyes moderate to skin aftsr contact ol short period
G€neral-lrritation of eyes and respiratorytracls, sever€ to eyes and moderate to skin attor contact of short of time.
oeriod of exoosure.
Symptoms-lrritation of syes, skin, and mucous membranes.
SyDDtorwaiering, redness,or burningol eyes, irritationot skin, irritationol mucous m€mbranes.
Short ExposureTolmrunavailable l l Short ErlGure TolersncFunavailable
Exlnsurc Pruedur*Flush eyes and skin with waler lor 15 minutes. Remove contaminaled clothing and flush
ca* of contacl with eyes and skin, immediately flush with plenly of water for at lsast
ll
Erposure PreedueFln underlyingarea with water. Call a doctor as soon as possible.
15 minutes.For eyes get medical attention. Flemoveconiaminatedclothing and shoes at once. Call a
doctor.
REACTIVITY DATA
REACNIVITY DATA Sbbility-Stable.
Strbillty-Stable.
ComDotibility-Material: Cartnn sleel, aluminum,stainlesssteel, nickel, tinned iron, and phenolic-linedste€l

conpstibllity-Mrt€rial: Carbon steel, cast iron, aluminum,siainless steel, phenoliclined stsl, nickel ot linned arE suitable materialsol construclion. Do not use copper or copper alloys, zinc, or galvanizedsteel.
iron are suitable materialsol construclion.Oo not us copper or copper alloys.
Cargo: Group 7 ot compatibilitychart.

SPILL OR LEAK PROCEDURE Wear butyl rubbsr glovss, lace-shield or all-purpose canister rospirator, protective clothing. Struro ignition
Waer butyl rubb€r gloves, facs-shield, all-purpose canister respiralor, proloclivo clolhlng. Saq'| ignltlon gurces. Cover wiih sodium bisullate and cl€an up. Flush spill with large quantities of water.
sources.Cov€r with sodium bisulfat€and clean up. Flush spill wilh larg€ quantiiiss of waler.
It r .DIl m, cdl thc Nrt oul RiDonsc C€ntcr, tln-42a-tt02.

It r .Dlll Gu cdl $c N.llorl Rc Caaor. tlXl{rtl-L0il
llcnrrb: I No Oolormrnrtpn
nryta I Umvrrlibl.
I uila.lgtpd
aa SCANNED BY MKP & BARIS A. 2004 rt

O.DICHLOROBENZENE DICHLORODIFLUOBOIIETHANE
stiorymr- Bsnzsns,1,2-dichloro-; United NatioE Number. __1591- Synonyms- Difluorodichlorom€than€; F I 2; Freon 12; Ulllcd Nrtloo Nrmbcr ........ 1028
'1,2-Dichlorob€nzsne;
o-Oichlorobenzol; Halon | 22; Melhane, dichlorodifluoro-;Prog€ll6nt
Dowtherm E: Orlhodichlorobenzene 12; Relrigerant12; Ucon |2
CHR1S Codc........... .... DBO ('lInIS ('ode .............. . ........

__aaE-_
Formuh-C"H.Clr Fomule-CClrFr
Boili4 Point.......................... 181'" *'"' Eollltrt Potnt ............. 30'c 22' F
Apperrrnce-odor-Colorless liquid;pleasant aromatic -'c -'F odorl€ss ga8 or liquid.
Appearance-Odor-Colorl€8a, _"c _'F
F r e e 2 i n s P o i n t . . . . , . . . . . . . . . . . . . . -. .1. 8. .' C -1'F 158'C - 2 5 2'F
odor 't F r a c z l n gl 1 ) 1 n t . . . . . . . . . . . . . . .
SpeciltcGrrvity-l.30 Sp€cificGrrvlty-l.35 at 15'C (a liquid) _'c _'F
vrgor Pre$urc 2o'c (68'D ,..", -:: t- Vrlnr Proure 2(l'(' (6t'D (nmllg)
Ctenlcsl Fmily-Halogenated compound R e i d V a p o r P r s u r e ( D c i . ) . . . . . . . . . . . . . . . . . . . .0. '.0. .6 C'hemicelFmlly-Hdoggnated hydrmatbon nr[|dV.Dot Pt.sure (td]r)......... ...... 132
vapor Pisure {6'C (f15"F)(Fir)............. 0.1 V r l n r P u u r c 4 6 ( ( t l 5 ' D ( p s l r ) . . . . . . . . . . . .1 6 1
Pollutior Cltegory-USEPA B IUO B V s p o r D e n r i t y ( A i:r 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .5. .. 0
. .7. Potltrtion CileSory-tlSfpt ----Q- tMO ----q$l- V.ror Dcltfty (Alr .. 1.0).............. ......... 4.17
ApplicrbleBulk Reg.{6 CFR Subchapter........ O Solubilityin wster......................... Neolioibl€ ApplicableBull Rq. 1|6CFn Subch$acr ... .. O s o l u b l l l t y l o W r a e r . . . . . . . . . . . . . . . . . . . . .I.n. r c l u b l 6
I'IRE & EXPLOSION HAZARD DATA FIRE & EXPLOSION HAZARD DATA
Grrde-E: Combustibleliquid Grsde-Non-flammable
Eletricrl Group-D Electrical Groul+Unassigned
G€ner8l-Dangerous.When heate- to decomposition,emits highly toxic chloride fumes. Generd-Does nol burn. Toxic fumes emitt€d whon h€at6d to decomposilion.
F l s h P o i n t( ' n . . . . . . . . . . . . . . . . . . . . . .1. .5. 1

.... Flah Poirt ('F).............................
None
trlrmeble Limits...................... .... 2 lo 9"h trlanmble Limits.....................,....None
AutoigritionTemD.('F) ................ 1198 Autoignition Temp. ('F) ................None
ExtingulshitrgASots Water spray, dry chgmical,COr, foam. Extinguishhg 4gertB.....................None
Flre Preccdw................ Wear lull proteciive clothing and sell-contain€dbrsathing apparatus Special Fire Pruedues.........,...... When heated to decomposition temperaiure, it emits highly toxic fumes ol
phosgene and tluorides. Fire lighters musl wear slf-contained brsathing apparatus and tull protective
clothing. C@l tanks exposd to fire with continuous water spray.

Hcrlth Harud Rstitrgt Odor Threhold (ppn) PELITWA (pPm) TLVAWA (IDtrr) Healtb Htard Rrtingr Odor Thr6hold (ppm) PEL,/TWA (ppm) TLV,/TWA (Dpm)
2,'1,1 4 50 so/skin 0,0, 1 Unavailable 1000 1000
Gererd-Vapor inhalationcauses moderate local irritationof nose and airuay. iquid may cause skin or eye injury similar to trosibite. Vapor not toxic but breathing it may €use
unconsciousnesswithout warning because of lack of orygen.
Synptons-Drowsiness, unsteadiness,eye irritation,ditticultyin breathing. wilh or without nausea.
short ErDosureToleratrce-Painlulto some at 60-100 ppm for more than a lew minulss. ErDcure Toleruce-Human exposure to 100,000 ppm fot a lew minutes produces unconsciousn€ss
ExDoErrePruedur6-Vapor-remove victim to fresh air; il breathingstops, apply ariiticial respiration.Skin or ExIGuc Prcedur6-Remove victim to tresh air; it he stops br€athing,apply artificial respiation. lf the liquid
eye contact-remove conlaminatedclothing and gently flush affected areas with water tor 15 minutes. G€t has spilled onlo the skin, points ot contacl may be frostbitten;handle gently and protect from mechanical
medical advice or attention. damage. DO NOT RUB. Get medical attention.

Stlbiltty-Stabl€. Stlbility-Stabl€.
Cooprtlbility-M8terld: Most rubb€rs are not compalible. Conprtibility-Materid: Noncorrosive.
C$go: Group 36 of compatibilitychart. Cugo: Group 36 of compatibilitychart.

ll po$ibl€, wear butyl iubb€r glov€s, $tl-contained breathing apparatus, proteclive clothing. ll poa$ls' Avdd contact with liqukt,
or mix wiih vemiculiia, godium bicarbonate or sand. This may be packagad in cardboatd clrlon! lnd
in an op€n pil. Wash sit€ thoroughlywilh strong soap solulion.
It r $lll ccrn c.ll aht N.llorl Rm Clrar. IH lt . .Dlll scun, cdl thc Nraloml RcDoM Certer, 8fl)-424-t8ll2.
' Vapor Pr.rrua:
frrtrt lnrrhr 3t0O nmHg at 10.5'
fl
SCANNED BY MKP & BARIS A. 2004 l9
l.l.DICHLOROETHANE lt, SpoyDF
2,2"DICHLOROETHYL
Chlorex: ChloroeihylCtha.:
ETHER
1916
UnltedNrtlons Nunbe........,.,.......,...,.,.,......
Synonyms-Asymmetrical Oichlorosthane;Chlorinated 2362
UDitedNstionsNumbcr.......,.,....,....,.,..,.,,.,.. bis(2-Chlor@thyl)ether; bio-bete-Chloro€thytether;
hydrochloricether: Ethane, 1,1-dichloro-;
Ethylidenechloride;Ethylidene
dichloride;l,l.Ethylidene dichloride
CllRtS Code........... .... OCH
lr DCEE; 2,2lDichlorodisthyl othor; Ochloro€ther:
Dichloro€thyl€the/; b€la, b€ta'-Oichlor@thytether;
sym-Dichloroethyleth€r: Oichloro€thyloxide;
Ethans, 1,1'-oxybis[2-chloro-;1,1'-oxybisl2-chtoro-;
C}IRIS Codc..
1,1'-Orybbl2-chloro€thanel
Fomula-GHrCh
Fomule-CICHTCH"OCHzCH,CI Bolll!3 Polnt . . ......... 178'C 352"F
BoilingPolot...........
,.,.,.,.,.,.,., 57"" ,*'a
Apperruc-Odor-Colorle$ liquid:chloroform-likeodor _'c _'F
Appeannce-Odor-Coldless oily liquid; chlorotormlikg - 58'F
FrEzlr8 Polnt ......... 50'c
ethereal odor Fredns
Point...............
........
-92,E SDoclficGnvtty- 1.22 _'c _'F
Specific Gravity-1.18 =tE
VrDorPr{rru Zt'C (6t'D (mnHg).......... L2
Vapor Presure 20'C (6S'F) (mmHg)..........lg2- Ctcmlol Frdly-Ether
Chemical Fmily-Halogenatsd compound 7.35 nc|d V.tpr PHurc (D.tr).........
ReidV.Dor Prsure Osia)...........................
Vrpr Prauru l5'C (tl5"l) (prtr)............ 0 04
Vrpr Prww rl6'C (115'F)(Drir)............. 9.9 Pollutl0 C.ttary-USEPA A tMO I
C B 3.41 V|por D.rlty (Alr = 1,0)...........................
4.9
Pollution cNtegory-USEPA IMO Vrpor DeNlty (Atr : 1,0)........................... Appllqblc Bult Rcg. 45 Cf|n Srbctr*ar..... .. O SolubllltylnW.!er......................... Neoliqible
ADplioble Bulk Reg. 46 CFR Subcbapter........ O Solubilityin Wrtq......................... Neolioibls
Gruic-D: CombBtible liquid
Flammableliouid
E|etrlcd Groul+C
Electricsl Group-O
Ccrcrd-Wh€n hoated to de@mposition,it emils highly ioxic tumes; it reacts with water o. stsam to ovolve
heated, toxic and highly flammablevapors are given otf. ioxic of corosivs tumes.
Flsh Point CF).............................

131 (cc)
F l s b P o i n t C n . . . . . . . - . . . . . . . . . . . . . . . . .1. 7. . .
Ilumble Linitc..........................
Unavailabl€
Flmmlble Limits.......................... 6 to 16% ('F)
AutolgnitionTenp. ................696
Autoignition TemD. CD................ 856
Erthguishin8 ASerts Foam, CO2,dry chemical
Extinguishing ASerts Dry chemical, foam, CO,
Sfctd Fire Prceduq................ WeaJ full protsctive clothing and resdratory protection.
Waler may be inetfectiveon lire. Keep exposed tanks cool with waler gpray
Fire Prcc€dures................
Providelire tighters with protectiveclothing and seltcontained breathing apparatus.

Haltl Hrad Rrtir$ Odor Tbreshold (Dpn) PEI.zTWA (ppn) TLV,/TtryA (ppm)
Herlth Haad Rrthgs Odor Threshold (pDn) PEL,/TwA (ppn) TLV,/TWA (ppm) 3,2, g Unavailable
1, '1,2 Unavailable 100 2OO
s/Skin s/Skin
Gercrd-Vapor is irritantto mucous membranes of sy€s and nose. lt atfects kidneys and liver in varying
irritating.Liquid slighlly irritating.
dsgress, and is a mild narcotic.
Synptomr-Nausea, irritalionof eyes ano nos€.

causes eye irrilation,diziness, intoxication.Liquidcauses slight irrilation
Sbort ErDdure Tolemr5o0-1000 ppm causes sev€re irritationof the eyes and nos€ atter briel exposure.
ExtGure Tolemce-4000 ppm in 30 minules. 100 ppm produces slight nausea and irritation.
ExDcure Prcedurs-Remove victim to tresh air. Skin or sye contact-rsmove @nlaminated clothing and
ExposurePrceduro-Remove victim lo fresh air, it breathing stops, apply artilicial respiration.Skin or eye gently flush atfecled areas with water lor 15 minutes.Get medi€l advice or attention.
contact-tlush areas immediatelywith water lor 15 minutes.

Strblhtv-Stable until hsated to d€composition.Will rsact with watsr or steam, and can feact vigorouslywith
St bility-Generally stable, but decomposeswhen heated forming toxic and flammable vapors. Incompaliblo
oxidiing materials.
with strong oxidizersand caustics.
Unavailabls.
ConD.dblllty-Mderld: Usual materials ol conslruclion are suitable.
Cego: Group 36 ot compatibilitychart.

I Csgor Group 41 ol compatibilitychart.

I _.
weat rubb€r gloves, larg€ hsavy fac€ thi€ld, s€tf€ontained breathing apparatus. Secur€ ignition sources.
Wal protacilve clolhing, lace shi€ld, gogglee, respiratory protection. S€cu.s ignition rourcor. Welar rg.ry Flush with large quantitiosol watel
rnay ba utad to fluah rpills away.
. .Cll crt. oll rh. \.6nd Rmnr C*. mar/|-tilr.

I ll r rolll ccrn. qll tbe Nrtlold Ccrter. 8q)-424-8Ell2.
lcnrrla t Unrvaileblo
l-l Thr compognd b a torstogaft; 1,2-Orchlqoallranor! s luapaoLd clrcrnogon.
f
SCANNED BY MKP & BARIS A. 2004 el
2.2'.DICHLOROISOPROPYL
ETHER l l
Syoonynr- bis(2-Chloroisopropyl)ethei 2190
Unit€dN.tionr Number................................
Melhylens dichlorids
Dichloroisopropylelher; Ether,
-methyl€thyl);Propane,
bis(2-chloro-1
2,2'-orybis[2-chloro
CHRIS Code........... .... DCI CHRIS Codc....... ..................................
__oaM_
Formuh-CH:Clr
Fornulr-[ClCHzC(CHr)HlzO 't04'F
,ar', BollinS Polnt....... ........... 40'c
BoiltngPotnt.......................... 187'"
Apponnce-odor-Colorless liquid _'c _'F Appemce-Odor-Colorless liquid with a --gz'c
- 143'F . -r+g'p
Fiezing Point ... 97'C chloroform-like odor Frezlr8 Po1trt.....
SDecificGrrvity- 1.11 _'c _'F Specilic Gnvlty-l.34 _'c _'F
vspor Prsue 20"c (6s'F) (mnHg).......... --O19- Vrlnr Prwure 20"C(6E'F)(mnH8).......... 350
Chemicsl Family-Halogenated hydrocarbons ReidVaDorPressure 13.9
(DEh)...........................
Ctenicrl Fmily-Ethers Rcid VeporPrsue (psi8).........
Vrlnr Prmure r|6'C (ll5'n (IEi!)............. i vrtnr Prsure 46'C (ffs'F) (psir)............ 19.0
Pollution Cstegory-USEPA - IMO D VrDorDeEity (Air : 1.0)..........................3.0
Pollutior CrteSory-USfPt C fuo C v o p o r D e N i t y ( A t r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .5. . 9. .0. .
Appliqble BulI Reg. 116CFR Subchrpter........ O Solubilityin Wster......................
. 1 3"h
ApplicabteBulk Reg.46 CFR Subchapter........ O SolubilityinWater......................... Slioht
Gr.de-Non-f lammable
Elstricsl GrouD-D
ElectricalGroup-NA
Ganerd-No tlash point by conventionalmethods, but forms llammable vapor-air mixturesal 212'F and higher.
G€treral-Liberales hydrogsn chloridevapors whon combustionoccurs.
Evolves phosgene, a poisonous gas, and hydrogen chloride gas when heated.
F l s h P o i n tC n . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ' 1 8 5 F l s h P o i r t ( " F ) . . . . . . . . . . . . . . . . . . . .N
. . o. .n. .e. . .
F l a m m a b lLei m i t s . . . . . . . . . . . . . . . . . .1. .2. .l o . . .1. 9 o h
Flommable Linits.......................... Unavailable
AutoignltlooTemp. ('F) ................ 1033
AutoiSnitionTaDD.CF) ................Unavailable
ExtinSuishirgAgents Water, foam, dry chemical CO2
ErtinSuilhingA8ents..................... Water,foam,COr, dry chemical
S!ffid Flre Pruedurq................ Wear sll-contained breathingapparatus.Cool sxposed tanks with waler.
speid Fire Prceduro................ Waler to blanket tire. Wsar s€ll-containedbreathing apparatus.

Herlth HErd Rstings odor Thrsbold (pDm) PELITWA (Dpn) TLvAwA (pDn) Heallh Hred Rrtin8s Odor Threshold(ppn) PELAWA (pDn) TLV,/TWA (pDm)
Unavailable Unavailable 2.1.2 214 Unavailable 50
Unavailable o.32 mg/l
Canersl-Suspected carcinogen.Vapor causes anesth€tic etfects at high concentrations.Liquid causes skin and
Gererd-Skin and eye irriiationby direct contact.
eye irritation.Prolongedor repeatsd skin contact may cause defatting of the skin and may produce
dermatilis from daily contact.
Symptoms-Lightheadodness,mental contusion, nausea, vomiting and headache.
syDptomr-Slrong r€spiratorytract irritationand damage to liver and kidneys.
Sbort ExposureTolerance-Nol well €stablished,possibly in the range of 10,000 to 20,000 ppm by volume in air.
Short ExposureTolermc+The lowel lethal concentrationlor rats in 5 hours was 700 ppm.
However, incoordinalion,dizzinessand slight nausea begin after a half-hour exposure to approximately 1000
ppm.
ExDosurePrmedure-Give artificialr€spirationif breathing has stopped. ll the eyes are involved,llush and then
Exposue Pruedure-Remove immsdialelyto fresh air. Adminisl€rartiticialr€spirationor oxygen as necessary.
irrigate with large amounts of waler tor at least 15 minutes. lf ingestion has occurred, obtain medical
For ingestion,provide immediale hospilalization.
attention.

-Stable; but contact with opan flame causes decomoosition.
Reacts with oxidizingmalerials.
-Materid: Compstibility-Material: Corrosiveto aluminum and magnesium;corrosive to steel when wet.

Incompatiblewilh aluminum,copper, epory coatings.
CuSo: Group 36 of compatibilitychart.

Crrgo: Group 36 ot compaiibilily chart.

Avoid contact with liquid
Wear lolt.containing broathingapparatus,lull protectivoclothing and rubb€r glo\ra!.
lt I ttlll ccuc cdl abc Nralod Rmre Cbnter. EIXI-424-8802.

ll r rdll aon, cdl lhc N.doll
nao.rla:
&arrlr: I UnavaiLbb
l l i
. ; ; i l i n * i l - l $ k " ' , , ' , . , * r . * l , ,;.. . r - - o
n ...i..
..,*...,--;,.,.u,:rlud8lbdi&
2.4.DICHLOROPHENOL l,2.DICHLOROPROPANE
Synonyns- Chlorophenols,liquid;Dichlorophenol; 2021 Synonyne- Oichloropropan€;Propan€, 1,2-d€hloro-; Unlaed N.tlo[ Numbq.... 1279
Urited Nqtions Numb€r
Propylenechlorid€; Propylen€dlchlortdo
I
Phenol,2,4-dichloro-
Fornule-GHTCbOH qa.a ,nq"F

B o i f i n g P o i r t . . . . . . . . . . . . . . . . . . . . . . .2. .1. 5 ' C 419'F B o l l i n l P o l t r t . . .. . . . . . . . . . . . .
Appeararce-Odor-Whitelo tan solid needles;colorless Apperrre-Odor-Colorls8s liquid: sweetish. _"F _'c
chlorotorm-likoodol F r e d n S P o l n a .. . . . . . . . . . . . . -80'c -112'F
liquid;strong medicinalodor Fr€€Zin8Poirt...................- t2:3-*-:F
SDecificCrsvity-1.4 at 140'F (liquid) _'c _'F SpeclllcGrrvlty-l.16 t
1.4 at 59'F (solid) VrDorPresure20'C (68'F)(nmHg).......... 0 10 vrr,r PEun al'('(6t"t),.*rrl'c *
ChemicslFamily-Phenols Ct€nlcd l'rnlly-Helogcnaled hydrocerbom ReldV.Dor Praur. (Ddh)...... . ...,., 1.9
ReidvrporPrsurc(psis).................... t
Vrpor Prsure {5'C (f fs'n (D6ir)............ t V.Dnr Prsurc {6'( (I|5"r) {pir).............--?.5--
A Polhtlo! C.tctory-USEPA C fMO I V . D o rD o u l a y( A l r ' 1 . 0 ) . . . . . . . . . ........ . . . . . 3 . 8 9
Pollution category-UsEPA --E-- IMO Vrpor D€nsity(Air : 1.0)........................5.6
... 4.5 oll ADDllcrbleBull R.$ 5 Cl'R Subcheptrr . . O SohbllhyhW.lcr.................. Slioht
AppticableBulk Reg.46 CFR Subchepter........
---Q.- Sofubilityin Wrts......................
FIRE & EXPLOSION HAZARD DATA I'IRE & EXPLOSION HAZARD DATA
crade-E: Combustibleliquid Gndc-C; Flsmmablo liquid
Elecirical Group-D Electrlcl GrouP-D
Generel-Slight tire hazard when oxpossd to heat or llame. May decompose in a lire, releasingloxic products Gererd-Both th€ liquid and vapor, on contact with a hot surtaco or a naked llam€, decomDoselo form
phosgono, an oxtr6mly poloonou! ga!. Hlghv toxic hydrogsn chtoride gas is a combustion product.
includinghydrogenchloride.
Flsh Point CF).............................

237 F l u h P o l n tC F ) . . . . . . . . . . . . . . . . . . . . 6
. .5. . . . .
FlammbleLimits..........................
Unavailable Flannrble L|Dlts.......................... 3.4 to 14.5%
AutoigritionTemp. ('F)................
Unavailable Autoignltlo!Tenp. ('D................1035
Extirguishing Walerfog, alcoholloam, carbondioxide,dry chemical.
A8etrts..................... ExtingulchlnSA8entr CO:, dry chemical, toam, watsr log
Spcchl Fire Prcedures................Water and loam may cause Irothing. Specirl Fire Prceduro................ Keep exposed tanks cool with wator spray. Provide body and respiratory
protection tor fire parlies.

Odor Threshold(ppm) PEL,/TWA (ppn) TLVAIryA (Dpm) Helth Hrard Rrdqt Odor Thrahold (Dpm) PEL,/TwA (ppn) TLV,/TWA (DpD)
1r
Heslth Hffid Ratirgt
Unavailable o.o2 Unavailable Unavailable 1, 1, 3 Unavailable 75 75
General-Will irritate skin and burn eyes on short exposure. Possibilityol thermal burns trom hot liquid. Generd-Skin contact can cau$ dermaiiiis. Vapor inhalationcauses fatty degenerationof the liver and kidn€ys.
Symptoms-ltritation,burning,nausea,vomiting,diarrhea,hyperactivity,and/or convulsions. Sympt@Headache, weakness, nausea, dizziness.Skin contact may caus€ dermatitis.
Short Exlosure Tolennce-lnhalalion: Dust and vapor toxic; 15 ppm very irritating. Short ExposureTolerucFshort-term psak exposures of workmen to 4OOto 5OOppm were tolerated wilhout
apparenl ill etfects.
trjxposurePrcedures-Get medical attention.Inhalation:Remove to tresh air, rest, mouth to mouth resuscitation ErDcu€ Pr@edus-Vapor-remove victim lo fresh air; il breathing stops, apply artiticialrespiration.Skin or
or oxygen if needed. Ingestion:Oo not induce vomiting. Give large amounls ot milk or waler. Skin: Wash eye conlact-remove contaminaled clothing and gently tlush attected areas wilh wal6r tor 15 minutes. Get
with water for 15 to 30 minutes.Eves: Flush with water for at least 30 minules. msdical advice or attention. Symptoms may be delayed several days or longer.
REACTIVITY DATA
strbility-Stable below 200'C. Reacts with acids and causlic and alkali solutions. l l REACTIVITY DATA
Strbility-Generally stable. Can reacl vigorouslywith oxidizingmaterials
( i,mprtlblllty-Mnterisl: Rapidlycorrod€s aluminum,slowly corrodes zinc, tin, brass, bronze, copp€t. Us6 Conpatibility-Mrteri.l: Corrodes aluminum.
stainlesgor mild sleel with nitrog€npad (to keep dry). Linings are gsnerally unsuitabl€.
Crrgo: Group 21 of the compatibilitychart. Cugo: Group 36 ol compatibilitycharl.
SPILI, OR LEAK PROCEDURE SPILL OR LEAK PROCEDURE

Avod conlscl, wolt 9oggl€3, body covering clothing including rubber or nooprene glov$, gauntl€ts, and Wea. rubb€r glove3 and prolectiv€ clothing. Avoid coniact with tiquid. S€cure ignition sourcoa
l,()ols Uso sslt-containodbrolthing apparatus. For solid spills prevent €ntry into affon of naiural wat€ryaya;
\lrovol Inlo clean dry containerS.For liquid spills, diks and let lfe€ze, shovol into dry c€ntrine.t. Oo not us
wrlor Mrlenel ir e ssrious oollulion huard.
I tglll mcrn cdl llc N.aloul RI|ou (lrt r. tdFara-tllr.
I ll . tglll acun, crll Oa Nralon.l SlxHiL-rr02.
lnrrh lUnsvsr|rbla lrub:
l l
9a SCANNED BY MKP & BARIS A. 2004 el
l.3.DICHLOROPROPENE DICYLOPENTADIENE
synorynr- alpha-Chloroallylchloride; United Nrtions Number 2047 Synonyro- Cyclopentadiene; 1,3-Cyclop€ntadiene: 2048
UnltcdNrtlou Nunbcr................................
gamma-Chloroallylchloride; Dichloropropen€; I l,3-Cyclopenladiene
dim€r:Oicy:3e, 4, 7, 7a-;
'1.3-Oichloropropylene;
alpha, Dicyclo-l,4.pentadien€;
I-
gamma-Dichloropropylene;! -Propene,1,3-dichloro-; Tetrahvdro.4.T-methanornd€n€
ielone cHRIs code........... .. DPU CHRIS Code DPT
Fomuh-ClCHz : CHCHTCI I Formule-CroH,z

Boiling 104"C
Pof.t.......................... 219'F I Bo[ln8 Potnt 166'c 331'F
ApDcarrnce.odo.-White or yellow liquid;sweet _'c _'F I App"*-ce-Odor-Colorless cryll,al! or moltsn liquid; -"C -'F
-60'C
penetratingodor Freezinc point........................ 76"F camohor-likeodor FGdtrsPoin.........................
-------33"3 ------".F
SpecificGr.vity-l.23 _'c _'F Spelllc Gravlty-O.98
-#- I - Vrlor Pruure 20'C (68"F)(mmHg)..........---JJ-
Frmiry-subsrirured
chenic.r ailyrs Hff'"";ffi3l.:,$"?.i::11-......: chentel FrDilv-olotin Reid vrpor Prwure (Dsir) : 016
VaporPrwure 46'C (f ls'D (pcir).............---0,L- I
porution -:€:-
PollutionCrtegory-USEPA B IMO B 3.84
vrDor Density(Air : 1.0)........................... catesory-usEp^
- ruo B J:ilI;:ffil",ff;":tt1t,".1i1i]..:....
AppficsbleBulk Reg.tt6 CFR SubchrDter..... Solubilitv in w41er. .......... ......... O'1o/' Applicable Bulk Reg. 16 CFR sub.hrDter . .... D. O solubility in w.tc......................... ln$luble
Combustibleliouid Crrde-D: Combustible
Elstricll Group-D Electrical Grou!-C
produces toxic vapors ot hydrogen chloride, phosgene,and carbon monoxide.Fire may Getrersl-Keep away from heat, sparks and tire.
cause violenl ruoture ol tank.
F t r s hP o i n tC n . . . . . . . . . . . . . . . . . . . . . .9. 5. . . . . . F h s h P o i n t( " D . . . . . . . . . . . . . . . . . . . . .8. .0. .t .o. .1. 0 0

Flmmrble Limits.......................... 5.3 to 14.5'.6 Fhnmrble Limits.......................... 0.8 to 6.3%
AutoiSnition Temp.CF) ................ Unavailable AutoignitionTemp.("F)................ above 500
Eilinguiehirg Agetrts..................... CO,, dry chemical,foam, water tog Erlinguishing A9eots.........,...,....... Foam, carbon dioxide, dry chernical,water spray
snacid Fire Prcedures................Fire parties must wear lull respiraloryprotectionand, where danger ol skin SD€cirlFire Prcedu.6................ Water may be inettective.Ksp exposed tanks cool with water spray.
contacl exists, tull body prolection as well.
HEALTH HAZARD DATA

ll HEALTH HAZARD DATA
Herlth Hmrd Rrtings Odor Thrchold (ppm) PEL,/TWA (Dpn) TLV,/TWA (Dpm) Herlth Hrard RrtinSs Odor Thrahold (ppn) PELITWA (pDn) TLV,/TWA (ppn)
2.2.3 1to3 l/Skin l/Skin 1,1,2 l e s st h a n 0 . 0 0 3 5 5
Generul-Suspectedcarcinogen. Liquid is severely irilating to eyes. Vapor is a severe irriiant. GeDersl-Liquid causes skin and eye irritation.Avoid prolonged or repeated breathing of vapor. Possibilityot
thermal burns from hol liquid.
SymDtoms-Blistersand burns when in contacl with skin, Brsathing the vapors causes irritationto nose and SymptomFlnhalation-diziness, drowsiness.Skin contacl-dermatitis following prolonged contacl.
eyes.
short ExposureTolermcFunavailable. However,it should be noted thal the commercial product is a mixture ot
isomers.The physical propertieswill vary somewhat depending upon the proporlion ot each isomer pressnt.
I Short ErDGure TolemcFl ppm caus€d slight eye and throat irritationafter 7 minutes. Eye iritation rslt€d
aftsr 10 minutes at 5.5 ppm.
The mixture should be handled in the same manner as a Class B poison.
ExposurePrmedurrvapor-remove victim to fresh air; il breathingslops, apply artilicial respiration.Skin or ExposurePruedurd-Vapor-remove victim to fresh air; if breathing stops, apply artiticialrespiration.Skin or
m€dical advice or attenlion.

'l
eye contact-remove contaminatedclothing and genlly flush attected areas with water lor 5 minutes.Gst
ll eye contact-remove coniaminat€d clothing and gently flush aflected areas with waler lor 15 minutes. G€l
medical advice or attantion.

stsbility-stable. -Slable.
Conpstibility-Mrterid: Will cause corrosionol steel il wet or ai elevaled temp€raturss;also attacks aluminum Usual materialsof constructionare suitabl€.
and rubb€r.
Cargo: Group 15 of compatibilitychart. Cergo: Group 30 compalibilitychart

I SPILL OR LEAK PROCEDURE
W€ar rubb€r glovos, lolkonlained b.eathing spperatus, prot€ctive clothing. Avoid contact wlth llquid. Sccute l{alr rubb€r glov€s, lace shi€ld, protective clothing. Havs all-purpos€canister mask avriltb€. Seurc ignitroo
I
to(,oat. 60utcea.
llrdll.rrll tb l{drl feaCrlrr. &aftI:l ltr tlll cgrt' oll rlc N.ddl IIm. C.rr.r. llFa2+aar2.
lrrr
lr
tn'b
SCANNED BY MKP & BARIS A. 2004 ,

DIESELOIL DIETHANOLAMINE
127O SyroryFOiethylolamine; 2,2'-Dilrydrcxldl€thylamine; Untted Nrtloil Nunbar.. .........................
_____L
Synonyns-Diesel iusl; Fuel oil no. 1-D; Frel oil no. Ulited Nstiors NuDber.........................,..,...
Di-(2-hydroryothyl)amine;
bis(Hydroryathyl)amine;
2-D; Petroleumoil
CHRIS Code........................ ops

I- bis(2-Hydroryethyl)amine;
2.2rlminodielhanol
2,2'-lminobisothanol
;
CIIRIS Cod.. . . . . . . . . . . . ... . DEA
Fmuh-(HOCH'CH')'NH
Fomuls-Not chemicallydistinguishable.
Boilin8 Pollt. 268'C 514'F
...............232-425'C 450-800'F
Bollht Pofrt...........
- -zg'3 ADlmce-Odor-Thick, colorl€ss liquid; ammonia-lile _'c _'F
Appesmce-Odor-Brown, slightlyviscous liquid;smellg
odor Freezing Point 26'C 82"F
like kerosene Frecdr3point................ .. -a-'F
_'c _'F SDc|llc Gnvlty-1.09 _'c _'F
SDecificGravity-o.8 to 0.9
' Vr;nr Prwure 20'C (58'n (EuHd.......... <0.1
Vrlnr Prwure 20'C (68'F)(nnHO.......... C'hemicd Fuily-Amina
Chenical Fmily-Misc. hydrocarbon mixtures Varies
(p6ir)........................... 0.97
Reldvrpor Presurc (D.ia)...........................
ReidVeporPrsure
Valnr Prwure {6'C (ll5'F) (psir).............-J3!QS- Vrlnr Prwure 46"C (f 15'F) (D6h)............ V. Low
I Pollution Crte8ory-USEPA - IMO lll Velnr l)encity (Air : 1.0)..............
Pollution Crtegory-USEPA - IMO VrDorD€nrity(Air : 1.0)...........................Varigg
ADplicsbleBulk Reg.il6 CFR Subchrpter........ D Solubility ir W.ter Slioht ADpllcbtc Bulk Rcg. rl5 CFR Subcbapter........ O Solubllity in l{rter ......... Comolete
GndeE: Combuslibloliquid
or E dependingon llash point
Electricd GrouF-D
Eletrical Group-D
fire hazard when expossd to h€al or Ilamo. lriladng vapors ar€ ganerated when heated.
€nl-Diesel luel, due to its elevat€d tlash poinl, will gonerallynot constitute a fire hazard. Ksp away lrom
heat or flame.
Flsh Polot CF).............................
280
Fl$h Poirt CF).............................
110 lo 190
Flmmble Llnits..........................
1.6% (calculated)to 9.8"/"(ostimatod)
Flmmrble Linits..........................
1.3 to 6.0%
AutoiSnitiorTenp. ('F) ................
1224
AutoignitionTemp.("F) ................494
Ertinguishirg ASerts COz, dry chemical, water tog, alcohol foam
ErtinguishingAgents CO,, dry chemical,foam, water log
Flre Prcedure................ Watsr or loam may cause frothing. Provide tire lighters with soll-conlained
Fir€ Prfteduru................ Waleaor loam may cause frothing.Do not direct water directly inlo fire.
brealhing apparatusand protectiv€ clolhing.

H€dth Hurd Rethls Odo. Thr6hold (pDm) PELITWA (ppn) TLV,/TlryA (ppm)
Hedth Hurd Rrttngr Odor Ttuhold (ppar) PEL,zTWA (ppn) TLVAWA (ppm)
2,2,2 Unavailable 3 3
C€nerrl-lnhalation ot high concentrationsol vapor can caus headacheand stupor. Liquid is irritatingto the Gencrd-Liquid is idtaling to skin and highly corosive to eyss. Avoid inhalation ot high vapor concentrations.
skin.
Synptoms-ltching or burningat points of contact.
symptom-lngestion causs irritationol stomach and intestineswith naus€a and vomiting. Inhalation:
headache.sluoor.
Short Erlsure TolemcFunavdlabl€
Short ErDcue Tol€rurunavailable
Exl@ure Prcedurskin or eye contact-remove contaminaledclothing and gently flush atfected areas with
Exposw Pmcedurs-Vapor-ro|we victim to tresh air; it breathing stops, apply arlificial respiralion. Skin or
water tor 15 minules. Gel medical advice or attenlion.
eye contact-remove contaminatedclothing and gently flush aflectod areas with water to|I 5 minules. Get
medical advic€ or attention.

Strbtlity-Relatively stable.
Strbility-Stable.
ConDrdbtlity-Mrterld: Avoid copper and its atloys.

ConFdbillty-Mrtcrld: Usual materials ol conslruclbn ars suitabb.
Crgo: Group I ol compatibilitychart.

Cuso: Group 33 ol compatibility chart

wear butyl rubber glov€s, tace-shield or all-purposa canislsr respirator, protective clothing. May cov6r with
Wsar Jubb€r glov€8, protective clothing. Have r€spirrlory protstion aveilabl€. Sacrra [trltoft Grut. Soil
brsultaL, spray with large excess ot water and wash up.
up with ]|e3, paper, or dry vermiculil€.
lt . .Dlll K!t. oll tlc Nrtlord

lt ! rUl Grr, oll rh. N.rbrd f-I. Atr. D4raflt.
llrrrrlr 'irtr,' tlr,
'VTpa txr.' ilr{l{,ils| r! rclld at rmtiont t€mperalulo!, diothlnolamine may b€ catri€d in equsout
tryla Pr.r&n:2.C ltfnHg al 5O'O. rtltrxr ,' rt ot.'v.ttd lrmporrtu.o lO kaap I lhuid.
I l ,'[rr|(,rf,d
.,.-----ia,-&rrc.. . I SCANNED BY MKP & BARIS A. 2004

,-o*;uid8ir
99
DIETHYLAMINE DIETHYLBENZENE
Synrnye DEN; N-Ethylethanamins 115/t
UnitedNrtionsNunb€r..,..........,.....,..........., Synolyms-Diethylbsnz€no ('1,2-,1,3-or 1,4-); tJnli.d Nrttor Nunbcr.....................
........ 2049
*lhylbsnzene. m- or o- i8omers
I
DEN
T
CHRTSCode........... ....
Fmuh-(QHr)zNH FormulrCaHr(CrHr)r
BoilingPoin1.......................... 56'C 132'F llolllaj I','lnt 182'C 38O'F
Attcrrrnce-Odor-Colorless liquid;ammonia-likeodot --so'3 llquad; ben2ene-hk€ odot
Freezinspoirt......... i-'F 'rcezlnjPotnt......... 43:3 -r-:F
'c
SpecilicGrrYity-o.7l _'c _'F SDefic Grrvlty-0.87 _"F
Vapor Prwure 20"C (5s"F) (nmHg).......... --293-
clrurcdFmry-Aromaric -ok-
Chenicd Frmily-Amine ReldVaporPrwure (psir)...........................0.7 t hydroca.bon |if'"F;fj.:lfnl 1""r- ..
VsporPre$ure{6'C (115"F)(prir)............. 1.0 v.!D. Prsutc aa'C (ll5'l') (Fh) . .. . . 0 08
B
-
C II PolludonCrlqory-USEPA -
^
C
PoflutionCrtegory-USEPA IltO vrpor Density(Air - 1.0)...........................2.5 IMO V|Do. Dcnjty (Atr : 1.0)..........................
4.62
ApplicrbleBulk Reg.{5 CFR Subchapter........
--3- solubility in water......................... Comolete ApDllqbleBult Res.45 cFR SubchDrer...... O. O solubilttyin wrier.........................
-NnCliCiblg-
Flammableliouid Grade-D: Combuslibl€liouid
Elclricrl Group-C ElectricalGroup-D
flammable.Dangerouswhen exposed to heat or tlame. Vapors are heavier than air and Ge!€rrl-Moderato haard, when exposed to heal or flame.
may travel considerabledislance lo an ignition source and tlashback.lrritatingvapors are generatedwhen
heated.
F I s h P o i n t ( . n . . . . . . . . . . . . . . . . . . . . . . . .2. 4
.... FlGh Point CF).............................
133
F'hmmbleLinit3.......................... 1.8 to 10.1% Flmmsble Limits..........................
Unavailable
AutoianitionTenp. ("F) ................594 Autoignitiotr
Temp.CD................ 806
ExtinSrishinSAgents COr, dry chemical or alcohol loam Extinguishing A8ents.....................
COr, dry chemical,foam,wats fog
Fire Pucduq ................Providelire tighters with self-containedbreathing apparatus and protective SpecialFire Pruedurs................ Fight in th€ same manner as any Grade D petroleum product fir€. Firefight€r
clothing should wear respiratoryprotection.
HEALTH HAZARD DATA

II HEALTH HAZARD DATA
Health H@rd R.tirgr Odor Thr6hold (DDm) PEL,/TtryA (ppn) TLV,/TItrA (Dpm) Healtt Hurd RrtinSs Odor Thrshold (ppm) PEL,zTWA (ppn) TLV,/TWA (ppm)
3.2.2 0.14 10 10 1, 1, 1 Unavailable Unavailable Unavailable
very irritatingon coniacl and is toxic by skin absorption.Vapor causes sevare irritaiionof nose G€rcrrl-Vapor harmtul,
and respiratorypassages
iquid causes eye injury and skin irritaiion. Symptoro-Headache, diziness, nausea
Short Exposu€ Toleruce-1oo ppm lor 30 minutes. Short ErDcure Tolme-Unavailable
Erp6ur€ Prcedu6-ln cas of contact with eyes or skin, immediatelyllush with plenty ol water fot al least 15 Exposue Preedures-Vapor-remove viclim to tresh air; il breathing stops, apply artiticialrespiration.Skin or
minutes;tor eyes get medical attention. Remove contaminatedclothing and shoes al once.
l l eye contact-remove contaminatedclothing and ggntly llush aflected areas with water tor 15 minutes. Gel
medical advice or attenlion. The effects of inhalation mav be delaved.

Strbility-Stable. Strbility-Relatively stabls. Can r€act wilh oxidizingmatsrials.
ConpUbiltty-tltrterlrt: Stsl and stainless steel arc compatible. Copper and its alloys should not bs us€d. (:onFtlblllty-M.rcrlrl: Flubber,on long imffison. will lirrt awelt, th€n soften.
Csgo: Group 7 ol compatibility chari. ('flo: Grop 32 ol compaltbtlllycharl
SPILL OR LEAK PROCEDURE sPll,l, (,|a t.]:Ar l,R(x'] l)trRl:

Woar butyl rubbor gloves, laco-ghiold oJ all-purposs canbter respirator, protocliva clolhing. Sacurc rgnilbn Avdd oo.rtacl dh fqtld g.orr. rrrq
l||I||(n
touces. Covs with sodium bisullate and clsan up. Flush spill with larg€ quantitiosof wrtar.
lt. thc ll . dll r.s. ..ll rL bdbl a .o1.. Ur ala Ull
lrytr: l.*1.1 lrrrlt ar{{tl ar a r[.ir.,il rrre. lt-,rltt,.,rt t,4,. l,r'r'6 *.1 t,,o,l,'li'r4L.
tu) SCANNED BY MKP & BARIS A. 2004

-. ",*letu!4illh
tol
Symny|r
DIETHYLENEGLYCOL
DEG; Oiglycol; Dihydroxydiethyl ethsr; U n i t e d N r t l o N N u m b € r . . . . . . . . . . . , . , . . , . . . , . , . . , . . . . . .r
lr DIETHYLENEGLYCOL BUTYL ETHER
Synonye Butorydi€thyl€ne glycol: 2-(2.guloxy
2,2'-Dihydroryethyl ether; bis(2-Hydroxy€thyl)ether;
3-Oxa-1,5,-pentanediol; 2,2'-Oxybisethanol;
2,2'-Orydiethanol
cHRrscodc........... .... -AEC-
ll ethory) elhanol; 2-(2-Butoxy othoxy) €thanol; Butyl
Carbitol; Butyl diglycol; Butyl dioxitol; Oiglycol
monobutyl 6ther; Dowanol DB; Ektaelve
Solvent
OB
Fomuh-(CHzCHTOH)rO
Appernnce-odor-Colorless,
Speilic Gnvity-1.12
syrupy liquid; slight odor
' o i I i t r s p o i n t . . . . . . . . . . . . . . . . . . . .2. 4
Point.........
Freezins .....
. .4. .' ." 1 ' ,
6'3
_'c _'F
.:F ll Form ulr-Cr l.lrOCHrCHrOCtltCHrOH
ApDerruce-Odor-Colorl$s liquid; faini plgasni odor

Bolllng Point..........................
F r e e z i n gP o i n t . . . . . . . . . . . . . . . . . . . . . . . .
231"C
-eg"c
448"F
-go'r
Specltlc Gr.vity-0.95
Vrpor Prsure 20"C (68"f) (mmH8).......... V. Low
C'henical Fmily-Glycol ethers Reidvrpor Presure(Dcir)............. .............V. Low VaporPressure 20'C (58'F)(mnHg).......... V. Low
Ctenlcd Fmlly-Glycol othd
vapor Prsure 46'C (115"F)(psir)............. V. Low ReldVaporPr$ure (psis)........................... V. Low
Polludon Category-USEPA - IMO ----l!L- vrpor Denslty(Air : 1.0)...........................3 66 Vrpor Pr*ure 45'C (f15'D (Ddia)............. V. Low
Pollutlq Crtrtory-USEPA - tMO lll VrFr DeNity (Air : 1.0)................,.......... 5.5
ADDlic8ble Bulk Rc& {5 CFR Subchapter........ ----Q- Solubilityin wrt€r......................... Comolet€
Applicrble Bull Rca. il6 CFR Subchrpter D S o l u b i l i t y i D W a t e r . . . . . . . . . . . . . . . . . . . .C
. .o
. .m o l e t e

GredeE: Combuslibleliquid
Gredc-E: Combustibl€liquid
Electricd Group-C
Eletdcd GruFC
Genenl-Slight hazard, when exposed to hsal or flame; can react with oxidizing materials.
255
Flsh Point Cn.............................
ll Gclsd-Modgrate tire haard when exposed lo heat or flame.
nrh Point CF).............................

172
Flmmble Lim|ts..........................'1.6
lo 10.8'/5
Flunble Limits..........................
il
AutolgritionTemp,("F)................444 Unavailable
Autoigtrltior TcmD.("F) .....,.,........442
CO2,dry chemical,alcohol foam, water spray
ExtinguilhingAgents.....................
ErtinguirhirS A8ents..........,..........
Contined area-Cor, dry chemical. Open area-polarsolvonl loam
SD€ctdFire Preedus................ Wat€r or foam may caus€ frothing. Do not dirsct watar dir€ctly into lire.
SDsid Flre Prmedures................Wat6r spray may cause frothing.
HEALTH HAZARD DATA

l!
Herlth Hred Rrtingr Odor Tbreshold (ppm) PELITwA (pDm) n-vlTlvA (pDn) HEALTH HAZARD DATA
Hedth Haed Ratings Odor Throhold (ppn) PEL/TIVA (pDn) TLV,/T|VA (ppn)
l l
1, 0, 1 Unavailable Unavailabls Unavailabie
ordinaryconditionsof handling,not consideredtoxic.
Generel-Slight eye irritation.Low toxicity.
which has come into contact with the liquid may burn or itch.
Symptol|lFliquid-slightly painlul and irritatingto oyss; repeated skin contact causes slighl irritation.
Vapor-eye irritation.
Short ExposureTolerrrunavailablg.
Short ErDosure TolemcFunavailable
Exp6ure PrcedureFEye or skin contact-flush atfected arsa gently with water tor 15 minut€s. For eyo
contact, or if skin is blistoredor p€eled, get medical attention. ErDcure PrsedurrLiquid-flush with water. Vapor inhalation-remrye victim to tresh air.
REAC'TIVITY DATA
Stlbility-Stable. REACTIVITY DATA
Strbility-Stable.
ComDotibllity-Mrterid: Compatiblewith most malerials ot mnstruction..

comDrtibili8-Mat€risL Mild steel and stainless st€l ar€ suitable. Certain rubbers and Dlasticsare unsuilable.
Crrgo: Group 40 ol compatibilitychart.


W€ar rubb€r gloves, taco-shi€ld, proteclive cothing. Avoid contec.t with liqukt.
Avoid contact with liquid.Secure ignition sources. Absorb on paper towel and vgrmiculite.
It r slll aqn. oll Oo Nrlloml Rn Crntcr. uxH24-tlrt.

ll | .Dlll mc!n, cdl tLc Netlond Cctrt r. to-.24-8m2.
&]rlr: I Unat.ig,|.d
l l
ldrr I Unrf,ragnd
t02
-*.--
-.- .* - -..--*.*---ds. rot
DIETHYLENEGLYCOLETHYL ETHER
DIETHYLENEGYLCOL METHYLETHER
Synonyms- Carbitol solvent; Dowanol DE: Ektasolve United Nstions Number :t
DE Solvent; Eihoxy daglycol; Synuyms- Dowanol DM; Eklasolve DM Solvent: U n l a € d N s t | o n s N u m b e r . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .t
2-(2-Ethoxyethoxy)ethanol 2-(2-M€thoxyethoxy)ethanoli
Methyl C6rbitol
cHRIs cod€........... ... DGE

CHRIS (irde ..... ..................._
. ._. .a. .q. M
.
Formuh-HOCH,CH,OCH,CH,OC,H"
8oi1in8Point..........................202'C 396"F Formule-CHTOCHTCHTOCH,CHTOH
Appeuuce-Odor-Colorless liquid;mild pleasant odor -- Bolllit Polni.....,., .... 193'C 379"F
FreezingPoinr......... zo'c - ros'r AD!€$mce-Odor-Colorless liquid with a mild plasrnl _'c _'F
Sp€cificGrrvity-1.03 _'c _"F odor Frczhg Polnl..... 120'F
. -84'C
VoporPr*ure 20'C (68'F)(mmHO.......... --!QW- SDecificGrrvity-1.03 _'c _'F
ChemicalFamily-Glycol 6thsr ReidVsDorPrsure (psis)........................... ---!914- Vtpor Puure 20"C(6E'D (nrHO.......... 0.2
Vrpor Prwure,|6'C (115'ID(Fis)............. 0.01 Chenicsl Flmily-Glycol eth€r
ReldVaporPrcsur€ (D.b)............ ......... 0.01
Pollutior Cstegory-USEPA - IMO lll V r p o r D e N i t y ( A i r: 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .4. . 6. .2. . VlDor Prruure 46"C (lfs'F) (pcir).............---gO2-
ApDlicble Bulk Reg.46 CFR Subch8Dter........ D Solubility in Wster Comolete Pollutior Crtegory-USEPA - IMO C Vryor DeNlty (Alr : 1.0)...........................
4.14
Applicrble Bulk Reg.rl5 CFR Subchapter... ... D. O Sohbility itr Wrtel Complete

Gnde-E: Combustibleliquid FIRE & EXPLOSION HAZARD DATA
ElectricalGroup-C Grade-E: Combustibloliouid
Electricsl GroulFC
Genenl-Moderate hazard when exposed to hgat.
Generd-Moderate lire hazard when exDosedto heat or flame.
F h s hP o i n tC D . . . . . . . . . . . . . . . . . . . . .2. .0. 5
.....
FlrmmableLimits.......................... LEL:I.2% UEL:8.5ol. (sst.) Fhsh Point ('D.............................
200
ArioignitiorTemp. ('F)................ 400 Flmbfe Linits..........................
LEt: 1.2"/"UEL-unavailable
ExtiDguishirs A8erts..................... Dry chemical,alcoholfoam or carbondioxida. Temp.('F)...........
Autoigtrition .... Unavailable
SpecialFire Prcedurs................ Coal exposed tanks with waler. Extlnguiihing Agents.....................
Wator, carbon dioxide, dry chemical, or alcohol toam
Sp€cialFire Prcedur6................ Cool exDosedtanks with water.
HEALTH HAZARD DATA

Hqltb H@rd Rrtings Odor Threshold(ppm) PEL,/TWA (Dpm) TLV,/TtryA(ppn) HEALTH HAZARD DATA
0.0. 0 Unavailable Unavailable Unavailable Holth Haard Rstingr Odor Threbotd (ppm) PELAWA (ppn) TLVAWA (Dpm)
ingeslive toxin. Mild local irritant.Und€r ordinaryconditionsot handling not consideredtoxic. 0, 0, o Unavailable Unavailable Unavailable
G€rerrl-Not consider€dtoxic under ordinary conditions ol handling.
SynDtoms-None expected with normal use.

may irritats eyes.
Sho.t ExIGure Tolerance-Unavailable.
Short ExDoEure
TobrucFunavailable.
Exlmure Prmedurs-Vapor-remov€ viclim to fresh air. Skin or eye contact-remove contaminaledclothing

and gently llush atfected arsa with water lor 15 minutes.Get medical advice for eye conlact.
tl ExpocureM@Vapor-rsmove victim to fresh air. Skin or €ve contact-remove conlaminatedclothino

and gently llGh aflected ar€a with water lor 15 minutes. Get medical advics lor eve contact.
REACTIVITY DATA
Strbility-Stable. Can react with oxidizingmaterials. REACTIVITY DATA
-Stable. Can reaci with oxidizingmaterials.
ComFtibillty-Mrterid: Usual materialsol constructionarg suitable.

Usual materialsof construclion are suitabl€.

Crrgo: Group 40 of compalibilitychart.

Avoid contact with lkryid. S€cure ignition sources.Absorb on papsr towel and v€lmicullb, SPILL OR LEAX PROCEDURE
AvokJcontacl with liouid.
lf I sDill mut, Call |la Nrlloml Ratsn Centcr. to.4:lltto2.

ll r rglll ccul cdl ahe Nrtlon.l . 8lx!42lt-t802
Lrfr I Un{atr.d
f *
lllbr I Un.r.|grad
. Ji*li!ill;;'d;1",.,---",*#1,,,1,"",";,..,' SCANNED BY MKP & BARIS A. 2004 t0t

DIETHYLENETRIAMINE DIETHYLETHANOLAIIINE
Synonymr-bis(2-Aminosthyl)amins; United Nrtlons Number. __2079_ Synonyor- DEAE; Diethylamino€thanol;2-Oiethyl Utrltcd Natlor Number 2686
......
2,2 -Oisminodielhyl6mine amino elhanol; 2-N-Oielhylamlnoethanol: 2-Oiethyl
amino€thylalcohol; bete-Di€thylsminmthylllcohol:
N,N.Diethylsthanolamins;Disthyf (2-hydroxyethyl)
CHRIS Code __aEI_ amin€; 2-Hydroxylriethylamine C H n I S C o d c . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ._. ._. p E
Fornuh-NHTCHzCHTNHCH,CH,NH, Fornulr-(GHr)zNGHTOH
BoilingPoint.......................... 2O7"C 404'F
BolllnSPo|tri................. 163"C 325'F
App€rrrnce-odor-Thick yellow liquid;ammonia-like -"c -"F 'c 'F
-39'C -38'F liquid:week ammonia-like
odor. FreezincPoirt........................ 't odoi Fcrlr8 Pot!t..... pour point1A"C 108'F
SpecilicGmvtty-o.95 SD€cinc GrrYity-o.88 _'c _.F
vapor Prwure 20'c (68'D ,..", -:: Lot
CliemicolFrmily-Amine 0.02 VrDor P6ur€ 2ll'C (6t'n (nmHd.......... ----1-
R€idVrpor Presure (pcia)........................... C'heDicd Frnily-Amim
Rcld VrDor Pr$ure (0cid.........
Vrpor Presure 46'C (1f5'D (pcie)............. --Q!4-
Vrpor Prwure 46'C (115"F)(Dsi!)........... 0.15
D 3 48 .
PollutionCategory-USEPA - twtO Vrlor D€nsity(Air : 1,0)........................... Polhtioa Crtegory-USEPA - flfO C VtDor DcEity (Air : 1.0)..............
Applicdlc Bulk Reg"{6 CFR Subchpter '...... O sotuUitityln wrter......................... Comolete
Apglteble Bulk Re8. il6 CFR Subch.pter ........ O Solubtlity in W.t€r....... Comolete
crrd€-E: Combustibleliauid Grrde-O: Combuslibleliouid
Elecdel Group-D Eletrtcl GrunC
ambieni temperaturesth€ lire hazard is low. lrritEtingvapors are generatedwhen heated Gercrrl-Modsrate tir€ hazard whgn expos€d to heat or flame. Toxic and irritatinggas€s may be generaled.
l - l c h P o i n t C n . . . . . . . . . . . . . . . . . . . . . . . . .2. .1.5. Fbb Poirt CF).............................

126
Flommable Limitc..........................1 to 10% (calculaled) trlmnrbl€ Linit!......................
.... 7 lo 12y"
Autoiglition Tenp. ('F)................ 750 AutoiSnitiorTenp. CD................ Unavailable
Extinguishing Agents..................... COz, dry chemical, alcohol loam, waler Jog. ErtingubhltrSA8otr.....................Ory chemacal,Cq, abohol toam, water fog
cial Fire Prcedurw................ Water increas€sthe amount of vapor prod|rc€d.Fire parties should wear body SDeid Flre Preeduq................ Cml exposed tanks with water. Providefire fighters wiih sell-contained
and self-containedbreathingapparatus. breathing apparatusand protective clothing.

Heatth Hryd Ratings Odor Threshold (ppm) PEL,4WA (ppm) TLVAWA (DDD) Hedth Hrad Rrtil8t Odor Threshold (pDn) PELITWA (ppo) TLV,/TwA (pD6)
2, 2,2 l0 1 1/Skin 1, 1,3 0.04 .to/Skin
io/Skin
Generrl-Liquid causes severe burns. Vapor is irrilating. Generd-Vapor irritatinglo oyes, mucous membranes.Liquid irritatingto skin.
SymDtorThroal irritation,nausea,wheezing breath. Liquid contact can cause serious eye and skin burns and Synptoms-Vapors cause nau*a, vomiting, rcspiratoryirrilation. Liquid causes eye and skin irrilalion.
severe allergic reactions.
short Exr$ure Tolermc€-Unknown. No animal deaths lollowed on 8-hour exposure to sturated vapots at Short Erlmur€ Tole|.t||r5oo ppm in 30 minutes;200 ppm is toxic to central neryous svslem.
room temperature.
ErDGure Pr@edures-Vapor-remove victim to tresh air; il breathingstops, apply artificialrespiration.Oxygen, EtDcure PrcedurFRemove victim to lresh air, if breathing stops administer artiticialrespiration.lmmediately
administ€redby trained personnel,is helpful. Skin d eye contacl-remove contaminatsd clothing and gently flush with large amounts of water for 15 minutes,g€t medical attention.
tlush atfected areas with water tor 15 minutes.Get medical advice or atteniion.

Stsbility-Stabl€. Wat€r dilution will evolve toxic vapors. Sbblllty-Can react with oxidizersand strong acids.
Com9otibility-Mrterial: Corodes copper and its alloys. Con!trtibility-Mrterid: lncompatibls with zinc, galvanizediron, copper, and copp€r alloys.
Cugo; Group 7 of compatibility chart. Sse also Appendix l-Exceplions to the Charl Crrgo: Group 8 of compatibilitychart

Wear rubber glovss, tacs-shi€ld or all-purpos canisler mask. and protoclive clothing. Avc*t @nLact wilh th€ Waar protectivs clothing, goggles, gloves. Sscure igniiion sources. Cover with sutficient quantiti€s of soorum
lrquid.May cover wiih sodium bisulfate,sprsy with large excess ol wal€r and washup. bisulfate and sgrinkl€ water.
lf r rdll acun, cdl th. Nrtlond Rcaou Crltrr, UXt{2}1t02, lt I rDlll ccuE, c.ll ahc Nrtlond SXI-424-E802.
l*frr lrfr t Unavrl.ble
106
SCANNED BY MKP & BARIS A. 2004 107
DIETHYL SULFATE DIISOBUTYLAMINE
Synonyme N-(2-Methylpropyl)amrne; United Nrtions Numb€r 236'l
Sylonyro- Ethyl sultate; Sulluric acid, diethyl United NstioN Number................................1594
ester 1-Propanamine,
N,N-bis(2-Methylpropyl)amin€;
2-m€lhyl-
Fornuh-(GHr)lSOr Fomuh-CrHreN
'208"C 406'F Boiling Point.. 139'C 2A3'F
BoilinS Poirt.......................
App€srrnce-Odor-Colorlessoily liquid;pepperminlodor ---lil'r Appeararcc-Odor-Waterwhite liquid; amine odor -'c -"F
-77'C 107"F
FreezinS Point..................... u"c
'c 'F
F eezirg Point
Sp€cificGnviB-1.18 SDecilicGrsvtty-O.745 _'c _'F
Vrpor Prsure 20'C (68'F) (nmHg.......... --9!1-9- Vrpor Pressure20'C (68'F) (mmHg)..........-lQ-
Chemicd Fsmily-Estq Ctemlol Fmlly-Amines ReidVrDorPrsure (psia)............... .......... 0.29
Reidvrpor Pre$ure(Fir)......................... . V Low
VlDor Prsure 46'C (lls'F) (prir)............. VaIEr Presure 46"C(115'F)(psia)............. -i-9-
B Potlution Crtegory-USEPA - IMO C VsDorDensity(Air : 1.0)..............
Pollutiotr Cstegory-USEPA - nfO vrpor DeNity (Air : 1.0)........................... 5.3
Applicrble Bulk Reg.,16CFR Subchapter....... O Solubilityinwater......................... Slioht
ApDlic.bleBull( Reg.,15CFR Subchrpter........ O s o l u b i l i t y i n W a t e r . . . . . . . . . . . . . . . . . . . . .I.n. .s o l u b l e
Grrde-E: Combustibleliquid crrde-D: Combustibleliquid
Electriel Group-D Electricsl G.oup-C
cenerrt-Low hazard when expos€d to fire or flame. General-Highly dangerouswhen exposed to heat or tlame
Flsh Point CF).............................

84
Fl[h Poirt CF).............................
220
Flsmm.ble Limits..........................Unavailable
1.1 lo 12.4% (estimate)
nmublc Limits..........................
Autoignitiotr Temp. ("F) ............... Unavailable
AutoiSnitionTenp. ('F)................
8 l7
Extinguishing A8erts.....................Alcohol loam, COr, dry chemical
ExtinguirhingAgeDts Alcohol loam, COz, dry chemical
SDeld Flre Prcedures................ Full respiratory proteclion as well as body prottrtion.
specid Fire Prcedurc................ Water or foam may cause lrothing. Do not direct water diractly into fire. Wear
self-containedbreathing apparatus,gloves.

Health Hsrd Ratingr Odor Thr6hold (ppd PELITWA (ppn) TLV,/TWA (ppn) Heslth H|4d Rrtiqr Odor Threrhold (Dpm) PELAWA (ppm) TLV,/TWA (pph)
Genersl-Highly toxic by ingestionand inhalation.Strong iritant. Decompositionliberatesethyl ether and sultur Genersl-Liquid causos burns and eye injury.
oxrdes.
Symptons-Highly initating to skin and mucous membranes.Burns are caused on prolonged contact. Naus€a Symptoms-lrritationol lungs and respiralorytracl. Skin-lightirritationto burns.
and vomiting.
Short ErDcure Tolermce-Animal sludies showed the lowest lethal concentratjonto be 250 ppm for 4 houB. Short ExposureTolermce-Exposures gr€aler than 100 ppm will produce irritationol respiratorytract. Pulmonary
Seriousillness may result lrom prolongedcontact. edema may result.
ErDGule Pr6eduFRemove victim lo lresh air. Adminisler artificialrespirationor orygen as necasagry. Etposurc Pr@edures-Remove to fresh air. Give artilicial respirationor oxygen as necessary.Skin, eyes-llush
lrrigateeyes with water. Wash skin with soap and water. Get medical advice or attention. immediatelywith water lor at least 15 minutes. Remove conlaminaled clothing al once.
REACTIVITY DATA
Strbility-Decomposes to torm eihyl ether; water slowly docomposessubstance to lorm sulfuric acid,
Incompatiblewith strong alkalies.
t Stsbility-Slable.
REASIIVITY DATA
Compatibility-Mrterid: Will dissolve paint and most plastic materials.

Canpdblllty-Mrterids: Aluminum,zinc, galvanizediron, lead, nickol or coppor and its alloys should not ba
u8€d. Ph€noliclined or stainlesssleel are suitabls.
Crrgo: Group 34 ot compatibilitychart.

I Csrgo: Group 7 ot compatibililycharl

t SPILL OR LEAK PROCEDURE
w€ar slf-containod br€athing apparatus, full protective clothing and rubb€r gloves. Avoid contact wilh liquid
Wolr protetive clo0rhg, s€lt-contain€d broathing epparatus, glov€s. Soak up smdl spills with rbeottanl or
S€cure ignitlon aourcsg.
rcdr |th. Walh largo lpllls wilh water.
lar rall mn, crll ltc Nrdul tm Crt . O{ltl{|.

I lt I Dlll en cdl tbe Nrtlonrl RG&u Crntcr. UXI-42-tt02.
' E.oho lo dccompolo ll6rrlrl
bglrr
t Umv.ihbL
below rt! boahngpornl.
I
i i ,
-ffitu---:Ll .^ rc SCANNED BY MKP & BARIS A. 2004 t$
DIISOBUTYLCARBINOL DIISOBUTYLENE
x Synonyms- Diisobutene;Diisobutylene,rsom€ric Utrltcd Nillons Number............ ..........
__?450
synonyno-2,6-Dimethyl-4-heptanol;
sec-Nonylalcohol Urited NrdoncNumber................................
comp's;2,4,4-Trimethyl tEntone-t ; 2,4.4-Trim€thyl
tEntene-2; Trimethyl penten€
CIIRIS ( ode.... ..... DBL

cHRtscode........... .... -AEg--
Fornula-GHra
Formula-[(CHt'CHCH:lzCHOH
178'" a*', Eolllng I'olnt.... .. 102'C 215"F
BoilirgPoirt.......................... Apperrence-Odor-Waior whil€ lhuld; typical o'!trnlc
App€orance-Odor-Colorless,
oily liquidwith a -os:3 _'c _'F
-*'F odor. J'reezinS Polni... -93'C -136'F
characteristicodor F ezirg Poirt......... SDeclllcGrsrtty-o.72
SDecificGrsvity-o.81 _'c _'F _'c _'F
V.rpr PEure 20'(' (68'F, lmmHo.....
VrporPrwure 20'C(5S'F)(nnHg).......... --93- C'bemic.ll'.f, ily---Olelin
Clemical Family-Alcohol 0.06
(prie)........................... Rcld V.por Pr8sure (prlr). .................. 16
ReidVaporPressure
Vrpor Prerrurc 46'C (ll5"l.) (Wi.|............. 22
VaporPresure,l6'C(115"D(psir)............. 0.1 Pollution Crtcgory-USEPA - fMO B
PollutionCsteSory-USEPA - IMO @C 4.98 Vqr'lnr Density (Air : 1.0) ...................... 3.97
VaporDersity(Air : 1,0)...........................
ADplicrbleBult RcA.{t CFR Subchrpt€r D. O Solublllty in water lnsoluable
ApplicableBulk R€g.46 CFR Subchapter........ D. O Solubility ln Wrter lnsoluble
Grade-C: Flammable liquid
Combustibleliquid
Eletricd Grcup-D
Electric8l Group-D
Gerersl-Dangerous when exposed to heat or flame. Flashbackalong vapor trail may occur. Vapor may
hazard. when exoosed to heal or flame.
explode if igniied in an enclosed area.
F l G b P o i n t( ' F ) . . . . . . . . . . . . . . . . . . . . .2. 0
.......
FlEh Point CF).............................
165
Flmnsble Limits.......................... LEL:0.9% (est.)UEL-unavailable
Flmmrble LiniG..........................0.8 to 6.1ol" at 212'F
AutoignitionTemp.('F)................ 788
Autoignitior TemD. ('F)................ 494
Extinguishing A9ents..................... Foam,carbondioxide,or dry chemical
Extinguishing A8ents..................... Carbon dioxide, dry chemical, alcohol foam
Specid Fire Preedur6................ C@l exposed tanks with water. Waler may be inetfectiveon fire.
Speciel Fire Pr@edur6................ Nol pertinent

Odor Thresbold (pDm) TLV,/TWA (Dlm)
Health H'ad RrtiDgs Odor Thrchold (ppm) PEL,/TtryA (pDn) TLVATVA (ppm)
Health H@rd Ratingr PEL,/TWA (ppn)
1, 1. 1
General-Low toxicily.
l l 0, 1,0 Unavailable
Genercl-Slight vapor haard, and slight skin irritant.
Unavailable Unavailable
SymptorHeadache, nausea, weakness, mental depression,inabilityfor sustained attenlion.

Symptoms-Vaporcauses eye, nose, and throat irritation.Liquid conlact causes redness, flaking, cracking.
Short EtlGue Tolemce-lrritant and narcotic in high concenlration.Has caused liver damage in tost animals.
Short Erlmure Tolerme-Eye irritationat less than 5 ppm. Nos€ and throal irritationat 10 ppm.
Extuure Prcedurer-Vapor-remove victim to fresh air. Administerartilicial respirationif necessary.

Expdure Pr@edur6-Vapor-remove victim to lresh air. Skin or eye contact-remove contaminalsdclolhlng
Skin-wash wilh copious amounts ol water. Call a doctor.
and flush atfected areas with water tor 15 minutes.Get medical advice.
REACTIVITY DATA REAC:TIVITY DATA

Stsbility-. Will not stpntaneously decompose.
Strbility-Stable. Can react with oxidizingmaterials.
ConFtibility-Mrterid: Usual malerials ot constructionare suitable.

ComDstibili8-Msterial Usual materialsof constructionare suilabl€.
Crrgo: Group 30 ol cgmpatibilitychart.

Cr4o: Group 20 of compatibilitychart.

Avold contact with lhuld. S€cure ignition sources.
Avoid contact with liouid.
ll r rllll rrcurr. c.ll th. l\atlonrl (..ntcr, lxFl2g02.

Itr cdl tL Ndlad l4rC-i.r,&ara-|lr.
'
V|tu I'r0rro 0/ 'rntr)lg rl :15'(
l t
ltgler
ncnrrlr: I Unaralgnad
SCANNED BY MKP & BARIS A. 2004 ul

KETONE
DIISOBUTYL DlISOPROPANOLAMIl{E
Synmym- 2,2'-Dihydrorydipropylamine;
OlpA: Unltcd N.tlo[ Number.......... t
Synonyno-DIBK: sym-Diisopropylacetons;sym-s- Utrited Nrtions Number...........,.,......,.,.........1157
Diisopropylacetone;2,6-Dimelhyl-4- 1,1alminodi-2-propanol
heptanone; lsovalerone;Valerone
CHRIS Code........... ,... --qf-
Fornuh-[(Cft Fomuh-(CHTCHOHCH,),NH
),CHCHz]zCO
'oi'tngPotnt.......................... 168'" l', Bolllrg Polnt 249"C 480'F
Appemnce-Odor-Whit€ crystalllnesolid or colorless
ApDes.mce-odor-colorless liquid;mild odor
FreezinsPoint......... .. 41:3 -*:i molten liquid;ammonia-likeodor Frezfns Poinf.........
. ... 42'3 *"F
Sp€cificGrrvlty-0.81 -'c -'F SDecincGrrvlty-O.g8 at 42'C _'c _"F
VaDorPrwue 20'c (6t"F) (mmHg)..........-----L- vrtDr Pruure 2O'C (68'F) (nnHg) ...... . 0.0
Cbemicd Fully-Alkanolamines R c t d V r D o r P r r o u r e ( p c h ) . . . . . . . . . . . . . . . . . . . .0. ...O. .
Ctmicd Fmlly-Ketone ReidVaDorPressure .. O.21
(Dsis).........................
Vrpor Prwure ,16"C(lls'D Osir)............. 0.48 VrDor Prsure {6'C (1r5'F) (pch).............-lL!A!{-
D Polludon Cste8ory-USEPA - fUO C V|Dor De$lty (Air : 1.0)........................... 4.59
Pollutiotr Category-USEPA - IMO V$or DeNity (Air : 1.0)..............
D Solubilityinwrter......................... Neolioible Applteble Bull Reg.il6 CFR Subchrpter ...... O S o t u b i l i t y l n W s t e r . . . . . . . . . . . . . . . . . . . . .C. .o. m
. olete
ApplicsbleBulk Reg.,16CFR Subchapter........
GredeE: Combustibls
cr8de-D: Combustibleliouid
ElectricalGroup-D Elctriel Groul+D
Iire hazard when exDos€d to heat or tlame. General-Slight lirg hazard when exposed to heat. Maierial kept at 120'-140'F for ease ol handling.High
lemperature evolve ammonia and other loxic vapors.
Flsh Point CF).............................

140 Flsh Point CF).............................
260
Flmmble Limits..........................
0.8 to 6.2"/. Flmmrble Linits..........................
1.1 lo 5.4"h
AutoiSrition tenp. ("F) ................580
AutoignitionTenp. ('D................745
ExtinguirhingASertc Carbon dioxide, dry chemical,alcohol loam ErtlnguishinSASertr Carbon dioxide, dry chemical, atcohol foam.
Fire Procedor6................Wear selt-containedbreathingappalatus.Cml fire-expG€d tanks with wat€r. Specid Fire Procedure................Wear self-coniainedbreathing apparatus and tull protective clothing. Water
Water may b€ inetfectiveon fire. may be inelfective on fire; water or foam may cause lrothing.

TLVAWA (ppn) Heslth H{ed Rrtirgs Odor Thrshold (ppm) PEL,/TWA (Dpr) TLV,/TlryA (ppn)
Hedth H@rd Ratin8r Odor Threshold (Dpn) PEL,/TWA (ppm)
'1, 1 25 25 2,2,2 Unavailable Unavailabte Unavailable
2, Unavailable
General-Slight skin irritationfrom contact. Slight vapor irrilation.principal haard is to eyes. Wear eye
Generd-Fairly toxic if inhaled; minor skin irritation.
protection. Possibilityof thermal burns from hot liquid.
Symptons-Liquid: skin irritation.

SymptorRedness or initation ot skin; irritationol eye, nose and throat.
Short Erposue Tolcmce-Breathing the mist generated from the chemical held al 338'F was not latal to
Short ExDGureToleruce-Animal tests show minor skin irritation,traces of eye injury. Inhalationresulted in
33olodeath raie in 8 hours, on test. animals in an 8 hour exposure.
Exlosure Pr@edur6-ll 6yes are splashed with diisopropanolamine,wash with water imm€diately.Obtain
ExposureProedelnhalation: Remws victim to tresh air; il breathingstops, apply artiticial respiration.Skin
medical aid.
or eye coniact Flush atfected areas to|I 5 minutes with water. Get medical advics or attontion.

Stebility-Ch€mically slable. Upon heating breaks down into original starting materials.
Stlbility-Stable. Can teacl with oxidizing materials.
Compatibility-Mtterld: No action on common materialsat ambient conditions.Copper or copper alloys should

CanD.tlblllty-Mrterid: Mild stsl can be used.
not be used.
Cugo: Group 18 ot compaiibilitycharl. Crrgo: Group 8 of compatibilitychart.

Wcrr lull lec€ shi€lds or gogoles with sid€ shield, or equivalant.Woar rubbsr glov€s and proloctivo clothing
ll possiblo,w€ar rubber gloves, tace shield, and protectiveclothing. S€cur6 ignition sourcos. Hrye all-ptxpos
Avold ooarttct with liqdt whrch can caus€ th€rmal burns.
canirier meak avtilable. Ke€p unprotecled p€rrcnnel upwind ot conl,amlnaLd area. Flush with sfrt.
ll r olll ccnrt oll ih. N.tlorl nr. C-tr, S4fa*l lt | -all cnE. cdl ri. C.!t r, tlxH2+ti2.
lxil.r I trrurr{,t-
frb
"*-,- ^4"',d&, -., SCANNED BY MKP & BARIS A. 2004 l|l

DIISOPROPYLAMINE
il SynonycOimethylamine, anhydrouS; DMA;
DITIETHYLAMINE
Uniled Natlotrs Number .....1932_
Mslhanamin€, N-m€thyl-; N-Methylmelhanamine
SyndytF DIPA; N-('l-Methylethyl)-2-propanamine U n i t e d N r t l o N N u n b c . . . . . . . . . . . . . . . . . . , . . , . , |.!,6, .0, . .
CHRIS Codc........... .. DIA

I1 CllRlS Codc.. ...... DMA
Formuh-(CHr)zNH
Boilln8 Polnl.. ......... 7' C 45'F
Formula-[(CHr)zCH]:N H Appanrnce-Odor-Colode!! ga8; lish-like or _'c _"F
BollingPoint.......................... 84'C 183'F
emmonia-like odo, Fctlng Polnl ........... 96'C 141'F
Appearrnce.odor-Colorless liquid; amine odor --so'3 Spelflc Grrvlty-O.68 al 7'C (a liquid) _"c _'F
FreezinsPoirt......... -*'F
-'c -'F Vrgor Praure m'C (6t'D (nnl|g1..........--1988-
Specific Cravity-O.72 Clhemlcd F.mlly-Amine R c l d V r p o rP r o u r c ( g d r ) . . . . . . . . . . . . . . . . . . . . . . .4. .5.
Vrpor Presurc 20'C (5S"F)(mmHg)..........--fQ- Vrpor Prroure 46"C(tls'D (D3h)......... 58
Chemlcrl Family-Amine ReidVsporPrsue (Dsis)........................... 2'5 Pollution C.teSory-USfpl C IMO ----ggs- Vrpr Dcrlty (Air : 1.0)....1............ ......... 1.55
VaporPresure,|6"C(us'D (Dsia).............3.7 Applicrble Bull Reg. {5 CFR Subchapter..... . O Solubtlityltr w.t.r........................ Aoolociebl€
Pollution CateSory-USEPA - fUO C VrDorDenll8 (Atr : 1,0)...........................3.5
ADplicsble Bulk Reg. ,16 CFR Subchaptcr........ -!- Solubilityin Wrt.r......................... Comolete
GrrdFliquefied FlammableGas (LFG)
FIRE & EXPLOSION HAZARD DATA Elctricd GrouF-C
GrrdeC; Flammableliouid
Elecricd GrouF-C Gercrd-Unl$s the tlow ol gas can be slopped, putting out a dimethylaminefire will p€rmil an explosive vapor
concentralion to accumulate.Extremely flammable.Vapors are eye, skin and respiratoryirritants.
Geoerd-Dangerous. Keep away trom heat and open tlame. Toxic oxides ot nitrogen may form in fires.
Flashbackalong vapor kail may occur. Vapor may explode il ignited in an enclosed area. Flammablegas; solutionsof 5oloor more are consideredflammableliquids
Flsh Point CD.............................
Flmmrblc LimitE..........................
2.8 lo 14.4o/.
F l s h P o i n t( " n . . . . . . . . . . . . . . . . . . . . . 3. .0. . . . . . AutoignltionTemD.('F)................
756
Flemmable Liniti.......................... Unavailable ErtitrgubhiDg Stop tlow of gas; CO,, dry chemical,water fog
48er1s.....................
AutoiglitionTemp.("F)........-...... 6O0 Speid Flrc Preedurs................ Use ol loam is not recommend€d.Tanks exposed to tire shilld be cooled
Extinguishing A8ents..................... Alcoholfoam,COr, dry chemical wilh a water sp.ay. Firelightingp€rennel should be providedwith self-containedbreathing apparatus and
SpecialFire Preeduro................ Water may be ineffective.Wear eye prolection and self-containedbreathing body protection.
aDgaratus.
HEALTH HAZARD DATA

Hedth Hlnd Retlngr Odor Thchold (pDm) PELAWA (pDn) TLV,/TWA (Dpm)
HEALTH HAZARD DATA 3. 2.3 0.047 10 10
Heslth Haard Rstirt odor Thresbold(pDm) PELITwA (ppn) TLvlTwA (pDm)
Gererd-Vapor €xtremelyirritating.Liquid caus€s burns.
3.2.4 Unavailable s/Skin s/Skin
Gere.rl-Liquid irritatingto skin and eyes on contacl. Inhalationof tumes can cause pulmonaryedema.
iritation; initation lo nose and throat, coughing and snee2ing;headache, nausea
SymptoN-Eye, skin, and respiratoryirriiation.

Erpo$ur€TolenncF2o ppm tor 5 minutes
ErDGore TolersrDsalh results at 2200 ppm, or ,rom repeaied exposurgsof 260 ppm; nausea and
impairm€ntof vision occur between 25 and 50 ppm. ErD6ur€ Prc€durFvapor-remove victim to fresh air; it breathing stops, apply artilicial respiration.Oxygen,
administsr€dby trained personnel, is oliBn helplul. Skin or eye conlact-immedialely flood aflected arcas
ExDosurePrmedurd-Flemove victim to fresh air. Apply artificialrespiration,il breathing stops. Skin or eye gently with water. R€move contaminaiedclothing and continue to tlush atfected area tor 15 minutes. Get
contact-remove contaminatedclothing and gently llush altected area with water for 15 minutes.Get medical attenlion.
REACTIVITY DATA
Strbtlity-Stable. DMA is highly reactive wiih other material.
REACTIVITY DATA
Strbility-Stabl€.
ComDrtibllity-Mlt€rlcL Steel is a suitable constructionmaterial.Copp€r, aluminum,and their alloys,
magnesium,zinc and galvanizedmetal are attacked readily and should not be used.
CrnFtlbilty-M.tcrtrt Avoid coppsr and copp€r alloys.
Crgo: Group 7 of compatibilitychart

SPILL OR LEAK PROCEDURE Wear bulyl rubb€r gloves, all-purpose canister r€spirator,protective clothing. Avoid contact wilh liquid. S€cure
ignition $urces. Flush spill wiih large quantities of water. For a gas leak lrom a taulty tank, keep concsniration
ll fD3srbl€, wear builyl rubb€r gloves, tace shield or all-purpose canisler respiratory proleciion, prol€ctiv€ ol gas below the explosive mixture range by forced vontilation.
(:lothrng. Sacuro ignlto.r rcurces. Coyor with sodium bisullato and cloan up. Flulh spill wtth latga qurntiti€! ol
?llar
Il r sDill ftcurs, csll the \ationd RcrDns C€tras. tlXL42AEt02.
ll r dl mn, cdl th. N.rlonrl RCru CrtLr, tq}42f{O2. Rcmb:
lrrq

It5
DIMETHYLAMINESOLUTION.40olo DIMETHYLAMINESOLUTION.50%
Synonyns-Methanamine, N-methyl-; N-Methyl United Nations Number............................... 1160 SynonyEF Melhanamine, N-msthyl-; N-M6thyl Unltcd Nrtlonr Number......................
. .. ... 1160
methanamine. 40olo mslhanamin€, 50o/o
Formula-(CHg)rNH Fornuh-(CHr)rNH
B o i l i n gP o i n t . . . . . . ....... 54'C 129'F Bolling I'oint 45"C 11 3 ' F
'C
App€rrsnce-Odor-Clear, colorlsss liquid; ammoniacal -'F Appearance-Odor-Cloan,colorlrst liquidi ammonllcal, - q3'3
fishy odor F r e e z i n SP o f n t . . . . . . . . . . . . . . . . . . . . . . . . -37 'C 35'F fishy odor rre.zfn8Potnr......... -*'F
"c "F
Specific Gravity-0.892 SpeciflcGnvlty-0.863 _'c _'F
VrDorPresure20'C (58'D (mmHg).......... --l-29- Vllu Prerure m'C (6t"1-) (mmHgt .. . 316
Cheolel Frnily-Aliphatic amin€s R e i d V a p o r P r e s s u r e ( p s i a ) . . . . . . . . . . . . . . . . .6. . 9. . . . . . . . ChemicelFamily-Aliphalic emlna8 Rcld Vrpor I'rcsure (Fb).
-f
porution -f*- ",1;;:]it::]

crtesory-usepr
--l- ruo c Iffi i'"""T,il",f;t:tt1il"
1illil......:....:. porutiotr
clrGgory-usEp^ c rMo c I:[: l'"ffi",fi;t
Applicobl€ Bulk Reg. ,16 CFR SubchsDtcr........ O Solubility ir Wrter...................... AoDreciable ADplicrbleBulk Reg.46cFR subch.ptcr..... O SotubllliyIn wrter ..................... Aooreciable
Grede-C: Flammableliquid Grrde-A: Flammableliquid'
Eletdcrl GrouD-B Electrical Group-B
I
Generrl-Vapor is extremelyllammabl€.Flashbackalong vapor trail may occur. Vapor may explode il ignited in Genersl-Vapor is extremelyllammable. Flashback along vapor trail may occur. Vapor may explode it igniled in
an enctoseoar€4. an enclosed area.
F | s h P o i n t C F ) . . . . . . . . . . . . . . . . . . . . . . .I. . . . . .
FhmmableLimits.......................... 2.8 to'14.4ol"(anhydrous)
AutoignitionT€mp.("tr)................ 752 (anhydrous)
ExtinguishinS A8ents..................... Water tog, CO,, dry chemical,alcoholfoam
SpecislFir€ Preedures................Use water fog to protect personnel and cool containers.Wear proteclive
clothing and self-containedbreaihing apparatus.

Health HrAd Rstings Odor Threshold (Dpm) PELITWA (ppr) TLVITWA (DOn) Heslth H@rd R.tings Odor Threshold (Dpm) PEL,/TWA (pDm) TLV,/TWA (pDn)
3.2.9 0.6 10 10 3.2.3 0.6 10 10
Genersl-Vapor very irritating,liquid causss burns. Gercral-Vapor very irritating,liquid causes burns.
Synptoro-Vapor causes sneezing,coughing,pnsumonitis,pulmonaryedoma. Liquid bums skin, syos, mouth, Symptoms-Vapors cause sneezing,coughing, pneumonitis,pulmonaryedema. Liquid burns skin, eyes, mouth,
throat. throat.
Short ExposureTol€rrnrvapor very irritatingabove 10 ppm. Short ExposureTolermce-Vapor very irritatingabove 10 ppm.
Exposu.ePr@edur6-Get medical attention.Inhalation:Remov€ to fresh air, rest, give mouth to mouth ExpoaurePrccedures-Get medical attention. Inhalation:Remove to fresh air. rest, give mouth lo mouth
I
resusitation or oxygen il needed. Ingestion:Do not induce vomiling. Skin conlacl: Flush skin and 6yes tor resuscitationif n€eded. Ingestion:Do not induce vomiting. Skin conlact: Flush skin and eyes for at least 15
al least 15 minules. minutes.

strbility-Generally slable; reacts with acids, stronq oxidizeB. Can explode in contact with m€rcuryif ammonia rility-Gsn€rally stable; reacts with acids, strong oxidizers.Can explode in contact with mercury it ammonia
pre*nt, so keep mercurylhermometersand similar instrumentsaway. present, so keep mercury thermometersand similar instrumentsaway.
Conpatibilily-Mrterisl: Suitable:Stainlessst€el, mild steel, iron. Unsuitable:(Corrosive)Aluminum,copp€t, Suitable:slainless steel, mild steel, iron. Unsuitable:(corrosive)Aluminum,copper, zinc,
zinc. brass. bronze. brass, bronze.
Cargo: Group 7 of compatibilitycharl. Cargo: Group 7 of compatibililychart.

Avoid conlact. do not brsath vapor. Waar prolsctive clothing (facs shisld, hard hat, goggles, rubb€r Oaunllet Avoid contact, do not breath vapor. Wear protective clothing (face shield, hard hat, goggles, rubber gauntlet
glov68. apron, b@ts). Use s€ll.contained breathing apparetus if n6ad6d. Do noi tlush into !awar8: dike and gloves, apron, boots). Use self-contained breathing apparatus it needed. Do not flush into s€wers; dike and
romov€,lh€n llush spill arga wilh watgr. Secure all iqnilion sourcss. remove, lh€n flush spill arga with water. Sacur€ all ionition sourcos.
lf r Blll occu. crll ah. N.tlold R6mnF Crttlr. tlx)-.a24-llo2. ll r roill ecurs. cdl ih€ Natlond
n.irrla: ' Grado bs3od on calculated veoor r99t,

llrll rel oressurs tor 55./o solution.
I Unavllrblo
I
t l
E

ll7
DIMETHYLETHANOLAMINE DIMETHYLFORMAMIDE
Synonyns- Deanol; 2-(Dimethylamino)ethanol; United Nrtions Nmbel .................205'l SynonyrN,N-Dimethyllormamid€; DMF; DMFA United N.tlons Nunbcr....................
............ 2265
b6ta-Dimethylaminoethyl
alcohol;
N,N-Oimethyl-N-(2-hydroryethyl)amine
CHRIS Code................. DMB CHRIS Codc.. . . . . . . . . . . . . . . ._. _

. ._ a M F
Fomula-(CH:LNGHTOH Fomuh-HCON(CH!h
BollinsPoirt.......................... 136'C 277'F Bollln8 Polrt.. 153'C 307'F
Appearance-Odor-Colorless
liquid;ammonialiks odol --sg:3 Appesmc-Odor-Colorless liqurd;unpl€a$nt rnd flrhy _'c _'F
FreezinsPoini......... . . -.:F ooor. lrcezing Polnt 58'C 73'F
SpecificGravity-O.89 SD€citicGnvlty-0.95 _"c _'F
vrpor Prsure 20'C (68'D (nnHg).......... 4.2 Vrpor Prruurc 20'C (6E'F)(mnHO..........----:-
ChemicalFmily-Alkanolaminss Ctemicrl Frmlly-Amide R c l dv r p o r P u u r e ( D . l s ) . . . . . . . . . . . . . 0.16
Reld Vrpor Presure (pcia).........
VaDorPre$ure 45'C (115'D (psid.............
--l- Vrlbr Prsurc 45'C (lt5'F) (psia)...........--Q3O-
PollutionCate8ory-USEPA - IMO D Pollutlon C.t€8ory-USEPA - tMO D Vrpor Dcufty (Atr : 1.0).............. ........... 2-51
VaporDensity(Air : 1.0)..............,....,.......
3.03
Applicabl€Bulk Reg.45 CFR Subchrptcr........ O SolubilityinWat€r..................,......Comolet€ Appliobtc Edk Reg.{6 CFR Subchrpter ..... O SolubilitylnWraer...,...,............C , . .o.m D l e t e
Gnde-D: Combustibleliquid Grsde-O: Combustibleliquid
Electricsl Greup-C Electricd GroulFD
G€erd-Moderate hazard,when exposed io heat or llame; can react vigorouslywilh oxidizingmaterials. G€reral-Mod€ralo hazard,when exposed to heat or flame; can react with oxidizingmaterials.Vapors are
iritating.
Flsh Point CF).............................

105 F l s h P o i n tC n . . . . . . . . . . . . . . . . . . . . . .1.3. .6. . . .
FlennableLimits..........................
Unavailable FlrmmableLimits.......................... 2.2 lo 15.2o/o
AutoigritionTemp.('F)................ Unavailable AutoigritionTemD.('F)................ 833
ErtingilishingA9ents.....................
COz dry chemical,alcohol foam, water log ErtingubhirS A8ents..................... Alcohol foam, COr, or dry chemical.
SD€cislFire Prueduro ................Waler may be inettective Specid Ftre Praeduq................ Provide fire-tighterswith self-containedbreathing apparatus and prolective
clothing.

Health H8Ad RrtiDgs Odor Threhold (Dpm) PELAIVA (ppm) TLVAWA (Dpm) Health Hrad Rrtir8s Odor Threhold (ppm) PELAWA (ppn) TLVAWA (ppE)
2, 2,3 100 1o/Skin 1o/Skin
l l
General-Skin contact extremelydangerous, Cenerd-Moderate hazard. May be absorbed through skin. Experimentalevidence ol liver and kidney damage.
May defat skin. Highly irritating.
Symptoms-lrritalionof nose and throat. SynDtoms-Nausea, vomiting;skin irritalion lrom liquid contact.
Short ExposureTolersnce-Unavailable Short ErposureTol€rmce-Prolonged inhalation of 10Oppm has produced liver damage in experimentalanimals.
EtpGure Pr@€dures-Vapot-remove victim to fresh air; il breathingstops, apply artiticial respiration.Skin or ExposurePrcedures-Wash contaminatedskin with copious amounts of water. lrrigate eyes with water lor at
eye contact-remove contaminatedclothing and gently tlush aflected areas wilh water tor 15 minut€s.Get least 15 minutes.

Stsbillty-This is a relativelyreactive subslancewhich can react with many olher chemicats. Srrbility-Stable.
CoDp.libility-Msterirlr Copp€r and copper alloys, and zinc and galvanizediron are corroded readilyand Conprtibility-Mrtorirt Compatiblewith all common metals except copper and copper atloys.
should be avoided.
Cugo: Group I ol compatibilitychart. C$go: Group 10 ot compalitility chart.

f-l SPILL OR LEAK PROCEDURE
Woar rubb€r glov€s, tull-protective clothing. Avoid contact with tiquid. S€curo ignitbn |ourc.|, Weat rubber gloves, safety glasses, protsclive clothing. Avoid contact with liquid. Sscuro ignilion sources
Scoop up, 6dd alcohol and burn in a safe place outsid€.
lt . .Dlll Gn oll ah. Nrllonrl

l-l lf . slll cu. c.ll tbc Nrtloul Rqmu Ccntc.. 8fi)-42,L8t02.
'
nrub t UmvdLb|i ll.r.rl.: Vtrlx)r I'(rssrir'
rl
3.7 mmHg Nl 25'C
- rm*,[.**.**-"------.. --
Itr SCANNED BY MKP & BARIS A. 2004 ll9
DIOCTYL PHTHALATE fl 1,4-DtOXANE
Synonymr- Di-(2-ethylhexyl)phthalale;DOP;
SymtD- Diethylensdioxido; 1,4-Diathyl€nsdioxkh Ulttcd NrdoE Nubcr..,............................. 1 165
bis(2-Ethylhexyl)phthalate;
bis(2'ethylhexyl)esler
Ocloil; Phlhalicacid,
ll El}glhyleneether: Di€thy'onsoxid€; Dioxan;

Dioxan€; p-Dioxane;Glycol €thylgne ethor
tl
Fomuh-Gil(COOGHTT)r
386'C 726'F Fomuh_O : (CHr).: O
BoilingPoint......................... 'C 214"F
Boftl[ Po1rf...........
ApDerrrnce-odor-Colorlessoily liquid;mild odor. _'c _'F
Freezing Point....................... -55'C -67'F Apgametxc-Clear lQuid; mild, alcohollc odor _'c _'F
Flcczhg Po|rt......... 12'C 54"F
SDccificGravity-o.gg _"c _'F
SDeillc Crrrtty-l.O4 "'
al 20' / 2O'C
Vapor Pr*ure 20'C (68'D (nnHO.......... --9gL-
Ctemicd Fmily-Ester
PollutionC.tcgory-USEPA - fUO lll

ReidvsDorPr$ure (p6is)...........................
Valor Presure 46"C (ffs'F) (psia).............
Low
-]4.!9!t-
13.45
VrporDensity(Air : 1.0)...........................
l l C't€Elql Fully-Cyclic
Pollutlotr Crtqory-USEPA
etha
B fMO D
Vrpr Prcurc a)'C,*'O,.*-L
R c l dV r p o r P u w
VrDorPrcre {i'C (ll5'F) (prtr)............. 1.8
VrDorDcrrlty (A|r : f.0)...........................
u
( ! d r ) . . . . . ........ . . . . . . . . . . . . . . ' 1 . 4
3.0
Apptiqble Bulk Reg.'t5 CFR Subchapter........ O solubilityinWater......................... lneluble
ApplicablcBulL Rca. '16CFR Subch.iler........ O SohbilityhWGr........................ Comolets
crrdFE: Combustibleliquid
FIRE & EXPLOSION HAZARD DATA I I Flammable liouid
Elstrlcd Group-D
Eletrlcd Grou!+C
General-Slight hazard,when exposed to heat or llame.

l l anlrydrous, lorms sxplosive p€roxides with air. Dangorous, when oxpos€d to h€at or flame.
Flashback along vaFpr trail may occur. Vapor may explode if ignited in an enclosd area. Toxic vapors ar€
g€n€rated when hsaled.
Flsh Poitrt("n.............................
425 nah Polrt CF).............................
54 (cc); 74 CrOC)
FhmmableLimit!..........................
Unavailablg
AutoignitionTemp.
Extinguishing
("F) ................
770
A8ents.....................
Carbondioxide,dry chemical,foam,water spray
Sp€cialFire Preedurer................Water or foam may cause frothing. Do noi direct water directly into fire. Use
water to keeo fire exDosedcontainerscool.
tl tr'lunble Limit8..........................
2 lo 22"/"
Autoi8nittonTemp.("F) ................356
Extirguishing Agerts CO2, dry ch€mical, alcohol foam
Fire koced|re ................Wear goggles, solf-containedbreathing apparatus and rubb€r orrerclothing.
Wat€r may b€ in€tletivs on fire.
HEALTH HAZARD DATA

f l
Hedth Hsed Ratings Odor Threshold (Dpm) PEL,/TWA (ppm) TLV,/TWA (Dpn)
HEALTH HAZARD DATA
Health H.ad Rrd4r (Xor Throhdd (Dpm) PELITWA (Dpd I!V,/TWA (ppn)
carcinogen.Producesno ill etfects at normal temperaturesbut may give ott irritating
vapors at high lemperatures.
Unavailable
l l '1,1,
3 620 mg/ms 2slskin 2slskin
Gererd-Suspocted carcinogen. Vapor has poor warning prop€rlies and can be inhalod in amounls which may
caus€ s€dous intoxicationor death with iniury ot liver and kidneys. Liquid can b€ absorb€d through skin in
slticisnl quantiti€sto producs injury.
SynDtorAtter repeated exposuresto skin, liquid causes reddeningand scaling of th€ skin. SyDpaorlritation to eyes, nos€ and throal (300 ppm)
Short ExposureTolersnce-Unavailable l l Short ErDosue TolerucF3oo ppm for '15 minutes cause mild kritation.
w Proced@For eys or skin contact-flush with water for 15 minut$ and r€move arry contaminated
tl
ExD6ure Prcedurs-Skin contacl-wash atlected parts as soon as possible. Eye contact-flood eye gently clothing. Obtain medical cars il expos€d to high vapor concenlration.
with clean water. Continuewashing for at least 15 minutes.
' NOTE: Oettrtabl€
odor is greator lhan the TLV. Exposure to potentially dang€rous vapor concentrations can
occur b€fors tho vapor is dotected by smell.
Strbility-Stable.
REAC'TIVITY DATA
l l REACTIVITY DATA
-Stabl€, no polymsrization; torms p€roxides whh air, should be padd€d wilh nitro96n.
CoDFtibility-M.terial; Usual materialsol conslructionare suitable.
c{r8o: Group 34 of compalibilitycharl.

f l disolorization.
Catbon st€el r€commsndgd. Copper and copper alloys may causs slighl
C$gor Group 41 ot compatibility chart.

f I SPILL OR LEAX PROCEDURE
Avoid contact wilh liouirt. Wear rubb€r glov€s, laca shield, protective clothing. Havs all-purposecanisi€r mask availablo.S€crr6 ignitlon
lt I Dlll cc!n. cdl thc Nrlloul

f l Small spills may b€ flushsd away with watsr.
lt. atl
trrtr: I Umcsrgnod
f l l-.rfr
ta, SCANNED BY MKP & BARIS A. 2004

-*4,;rii!id4&, lll,
DIPHENYL.DIPHENYL
ETHERMIXTURE DIPHENYLMETHANE
DIISOCYANATE
Synonyu- 4,4-Diisocyanodiphonyltrrlhane; Utrltcd Nrtlou Number................................2489
Synonyrs- Biph€nyl-diphenylether mixture; United Nrtions Numbcr........,........-,
4,4!Oiphsnylmethanediis@yanale;
Diphenyl-diphenyloxide mixture:Diphenyl Oiphenylmethane-4,4'-diis@yanate;MOI: Methylen€
oxide-diphenylmixture;OowlhermA; Phenyl bis(4-phenylisocyanate);Melhyl€m
€therbiphenyl mixture bis-ph€nylisocyanate OPM
CHRIS Code ..................... .',.,.''',.'.''.''.'
--a@_
Fornulr-(OCNQHT)rCHz
Fomulr-CrzHroO Oecomposes 392"C 738'F
BolllnS 11,int
Boiling Point..................... 257'C 495'F
Appcmnce-Odor-Light yellow solid (rt room
Appearuce-Odor-Straw color liquid;phenol-likeodor _'c _'F 37
'C
99'F
12'C 54'F
lemp€rature) or moll€n liqurd.sliohlly musly o(bt F.czftr8 Pofnt........................
Freezing Point........................
't SpcclflcGrrrlty-1.19 at 77'F (25'C) _'c _'F
SpecificGnvity-'1.07
Vrpor Puurc 20'C (6t'T) (nnHdl....... V Low
valnr Prwure 20'c (68'D ,rr"r, -:" u. Lo* Ctenlcd Fmlly-lscyanatg
Ch€hicrl F.nily-Ether R.ld v|Dor Prcrure (p!ir). .... V Low
R e i d V r p o r P 6 u r e ( p s i a ) . . . . . . . . . . . . . . . . . . . . .L. .t .r Vrpor Prourc a5'( (tl5't') (psis)............-lL-1g!ll
vslDr Prmre 46'C (lls'F) (IEir)............. --tgd- B
PollutlotrCta.8o.y-USf,PA -_ tUff Vrtor D.rdty (Alr : 1,0)..............
......... 8.5
PollutionCategory-USEPA - IMO A VrlDr DeEity (Air : 1.0)........................... 5.87
ApDllc.bleBull Rca /|6 Cl'R Srbch.pl.r .. Solublllty In WriGr .......
Appliqble Bult Reg.il6 CFR Subcbrpter........ D. O Solubilityin Wrter......................... Neolioible
FIRE & EXPLOSION HAZARD DATA F'IRE & EXI'LOSION HAZARD DATA
Gnde-E: Combustible
GrrdeE: Combustibleliquid
Eletrlc.l Group-NA
Elecdcal Group-D
Generd-Light yellow solid. Flemmabloal hrgh tamp€.aturaa,TorE vrpora ol ceJbon monoxide,oxides of
Gerefd-Moderate hazard,whsn expos€d to heat or flame. lrritatingvapors generated when haatod, niirogen, hydrogen cyande ars genorslod when hoated. Fire may caus potmization and decomposition
leading to violeni ruptu.o ol contarnorsor tanka.
n u h P o i n i C n . . . . . . . . . . . . . . . . . . . .3. .7. 4
F l u b P o i n t( ' n . . . . . . . . . . . . . . . . . . . . . .2. 5
. .5. . . .
ll.mmrbl€ L|n|tt.................... Unavarlable
FlammbleLimits.......................... 0.8 to 3.3oloat 300'F
AutoignltlonTenp. ('n........... 465
AutoiSnition Temp.('F) ................ 1150
ErtltrSulsbln8 A8entr................Waler spray,Col, dry ch€micrl,watgr spray.
ExtirguiebingA9ent8..................... CO,, dry chemical,water fog and loam
SDeld Flre Prccdus,............... Wear sell.conlran€dbreathingrpparltus and protsctiv€ clothing. Cool
SpecislFirc Prcedures................Wear sell-containedbreathingapparatus.
exoos€d tanks with weter.
HEALTH HAZARD DATA

HEALTH HAZARD DATA Haltb Htad Rrdur Odor Threbold (ppm) PEL,/TwA (Dpn) TLV,/TwA (ppm)
Health H@rd Ratil Odor Thrghold (tpm) PEL,/TWA (pDn) TLV,/TWA (ppD)
3,2.4 Unavailabl€ 0.01 0.005
1. 1. 1 1 Unavailable Unavailablg
Gencrd-Vapor is slrong irritant to eyes and throat; can cause eye and lung injury. Cannot be lolerated even at
iriiation ot more or le$ mild degres may be expecled only lrom prolonged and repeatod low concentrations.
contzlcts.
SymDtomr-Walering or redd€ning ol eygs, diarhea, and loss ol weight. Breathlessness,chest discomlort, and
or respiratoryirritation.Skin contact-redd€ning, slight iritation. reduced pulmonarytunction.
ExDosureTolerrnce-Animal t3sls have shown slight eye damage in 50olosolution; oral lethal dose is in
Short Erlcure TolemcFunavailable excess of 21.6 g/kg of body weight; no primary skin irrilation;no deaths by inhalationin 5-6 hours.
ExposurePrc€dures-Vapor-remove viclim to lresh air; it breathing stops, apply artificialrespiration.Skin or

ErD6ure Praedu.evapor-remove victim to tr€sh air; it brsathing slops, apply artiticial rssdralion. Skin ot eye contact-remove contaminatedclothing and immediatelyflush atfected areas wilh water toills minutes
eye conlacl-remove contaminatedclolhing and gently flush with water.
Call a doctor.

Strbtlity-Malerial musl be blanketed wilh dry nitrogan; unstable in traces of moisture,slowly forming carbon
Stsbility-Very stable.
dioxide gas.
Comlntibility-Mrterisl: Do nol have in direct contact with wood.

ComFtibility-Mrterirl: Usual mt€rials ol construction are suitable.
Cego: Group 12 of compatibilitycharl

Cergo: Group 33 ot compatibilitychart

Weat rubb€r glovss, face shield, protectivo clothing and s€lt.@ntain€d br€athing apparalus. Avoid contacl
Woer rubb€r glove3, frco shi€ld, lull protsctive clothing. Secuje ignilion sourcss. Small spills may be lludrtl liquid. Secur€ ignition sources.
rsry wlth waler.
It | .Dill m cdl the Nrrion.l RqDm Ccnrcr. tfl)-i124-tt02.

ll . r0l n oll ah. NrlloDd
' Nr'0lrgrblo,
lxrh retct8 slowly
lryff, | Un.[ig|.d
l i
lfr-**, SCANNED BY MKP & BARIS A. 2004 t2t
DI.n.PROPYLAMINE DIPROPYLENEGLYCOL
2383 Synonyhs- 2,2-Dihydroxydipropyleth€r; Unlted Nrtlonr Number
Symoy|ltF Dipropylamins;DPA; l.Propanamine, Urltcd Nda Nunber................................
N.propyl 2,2'-Dihydroxyisopropyl
6ther; 1,1'.Orydi-2-propanol
CHRIS Cod.................. DPG
Fomule-(CH3CHOHCHz)rO
FomrL-(CHsCH,CFlr)'N
107'C 225'F Bollln8 Point......,.......... .. 232"C 449F
Bollll8 Po1ni...............
liquid; pung€nt _'c _'F
Appcarrncc-Odor-Colorless,slighlly viscous liquidi _'c _'F
ammoniacalodor Fr6dr8 Po1ni............. -6:l'c -81'F odorlgss F ezln8 Polnl .............. super-eeels"c-'F
SpecificGnvlty-1.03
SDeciflcGrrvity-O.74 _'c _'F
Vepor Prrlurc 20'C (68'D (nnHg).......... ---29- Vrpor l'rroure 20'C (68'n (nnHj).......... -Y,-LQ!tl-
Ctemiel Fmily-Amims Ctemicsl Fmily-Glycol ether Rcld Vrpor Prwure (!alt)................ V. Low
ReldVrpor Presure(tdr).......................... 0.87
Vrpor Praure a6"C (ff5'D (psie)............. Vrlnr Prwure 46'C (ffs'D (psie).............---Q.gf-
--l-45- Pollution Cstegory-USEPA - IMO lll
Pollution Category-USEPA D fVO C vrDor Dcmlty (AIr : 3.5 V a p o r D e n s i t y ( A i:r 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .4. . 6
. .3. .
1.0)........................... D
ApplicableBulk Reg.46 CFR Subchrpter...... Solubility in Wrter..... Complete
Appliqble Bull Reg.il5 CFR Subclrptr........ O Solublllty In Wrto 2.5% bv woioht
GndFC: Flammableliquid Grede-E: Combustibleliquid
ElectricalGroup-C
Eletricd Group-C
G€nerd-Oangerous when axpos€d to hoal or tlame. Flashback along vapor trail may occur. Vapor may General-Slight hazard when exposed to heat or flame.
explode il ignilod in an erclos€d arsa.
FlEh PotntCF)............................. Flsh Point CF).............................

280
63
Fh|mrble Linitr....................-.... FlammrbleLinits..........................
LEL:2.2" UEL-unavailable
Unavailable
AutoignitionTemp. ("F)................Unavailable
AutotgrltionTenp. ('F) ................Unavailable
ErttnSrishtng ASerts Foam, CO,, dry chemical Extinguishin8Agents.....................
Water,CO,, dry chemical,alcoholfoam
Spccid Fire Prffedur6 ................Water or foam may cause frothing.
Firc Prcedurd................ Wear slf-contained breathing apparatusand prolsctive clolhing.

Hedth Hffid Ratings Odor Threshold (ppm) PELITWA (ppm) TLVAWA (ppn)
Heltt Hlrud Retingr Odor Threhold (pDn) PELITWA (ppn) TLV,/TWA (Dpm)
Unavailabls 0.01 to 0.1 0,0, 1 Unavailable Unavailable Unavailable
Unavailable Unavailable
noxiouS. Generrl-Not consideredtoxic under ordinary condilions ot handling.
burns, eye damage (permansnt).Inhalation:pulmonaryedema. lngestion:alkaline burns, dsath Symptoms-Minor eye irritant.
ErDosue Tolmce-lnhalation: Short ExDosureTolerance-Unavailable.

l0O0 ppm produces severe iriiation of respiraiorytract and lungs, with
possiblepulmonaryedema.
ExporurehaeduttFcet Exluure Preedures-Skin or eye contact-remove contaminatedclothing and gently llush with water for 15
medical attention.Inhalation:Flemovelo iresh air, adminisl€r orygen if ne€dsd. Skin,
eye contact Flush with waler for at least 15 minutss. minules. Get madical advice for eve conlaci.

Stlbility-Stable. Stsbility-Stable.
Raacts with acids.
Compstibility-MsteriaL Usual materialsol constructionaro suitable.

Di$olves paint and mosi plastics; swells rubber. Suitable: Carbon steel, stainless sts€l
Unsuitable:Copp€r, zirc, brass, bronze,aluminum,magnesium.
Cugo! croup 7 on compatibility chart Cargo: Group 40 ot compatibilitychart.

Avoid conlact. Wear 3€ll-contained breathing apparatus, lac€ shield, protctive clothing. Wrah clothing Avdd contact with liouid.
b€lor€ reus. For small spills, flush arsa with water gpray.Secure ignilion sourct.,
lt I dll cuq q|| alc Nrtiold Rerpre Cortcr. tllll-424-t002

lt . rDlll acuE, c.ll C.ntcr. Ul-,424-ttlD.
lrglr: r n t l'nrrtr t Unltdgnod

r2t
DODECENE
synonymF alpha-Dodecylene; Propylene tetramer;
DODECYLBENZENE
Tetrapropylene Sytronyms-Alkylbenzene;
Oelorgentalkylate#2: United NatioN t:
Number
n-Dodecylbenz€ne:Laurylbenzene;
1-Phenyldodscan€
( ' H R I S C o d e . . . . . . .... . . . __aaB

Formula-CrzHzr
Formulr-CrrfLrGHr
Apperrance-Odor-Colorless liquid; ploaganl odot Boilin8 Poina. 246"C 475'F
ADperuce-Odor-Wat€r-white liquid; kerosns-like
Speclllc Gravity-O.76 ooor FrezttrsPoinr.... 1"3 --"F
Sp€cilicGrrvity-o.86 _'c _"F
C'hemical Family-Olefin
VrporPrroure20'C(58'n (nhHg)..........
--QPl-
Chenicd FrElly-Aromatic hydrocarbons Reid Vslpr Pr$ure (psir).........
Pollutior Clt€gory-USEPA - IMO B
vsNr Prsure 46"C (1f5"F) (pcie).............--lJ-
Appticsble Bulk Reg. 45 CFR Subchrpter........ O. O Pollution C.tc8ory-USEPA - IMO lll V a p o r D e n s i t y ( A i r : 1 , 0 ) . . . . . . . . . . . . . . . .. .. . . . 8.4
ApplicsbleBulk Reg.it5 CFR SubchtDter........ D Solubilityinwat€r................ Neolioible

Grade-D: Combustibleliquid FIRE & EXPLOSION HAZARD DATA
Elctriql GrouF-D Grade-E: Combuslible liquid.
Eletrical Group-D
G€nard-Moderate fire hazard when expos€d to hoal.
Gererd-CO and COr lumes produc€d on combustion.
Flsh Point CF).............................

144
FluMble LiDits..........................
LEL:0.8% UEL-Unavailable Fl$h Point Cn.............................
235
AutolgnltlDrTemp. ("F) ................40O Flum.ble Limits..........................
Unavailable
Ertll8uiEhlngAgents.....................
Carbon dioxide, dry chemical,or foam AutoiSnitionTemp.('F)................Unavailable
SDecislFire Prcedures................Cool exposed tanks wilh water. Water may b€ inetleclive on fire ExtinguishingA8ents.....................
Conlined area-Coz, dry chemical, Open area-foam, water spray.
SpecialFire Pr@edur6................Water or foam may cause frothing.
HEALTH HAZARD DATA

Health Hred RstitrSE Odor Threshold (Dpm) PELiITWA (DDd TLVITWA (ppn) HEALTH HAZARD DATA
1, 1, 1 Unavailable Unavailable Unavailable Hedth Hrud Rrtirgr Odor Threshold (ppm) PEL,/TWA (ppn) TLV,/TWA (pDd)
General-Vapor slightly irritatingin high concentrations. 0, 0, 0 Unavailable Unavailable Unavailabte
General-Very low toxicity.
Sympioms-Slightsmarting of the eyes or rsspiratorysystsm il present in high concentrations.
Sympioms-Very low loxicity.
Short Expcure Tolersnce-Unavailable
Short Ertmure Tolerance-Very low toxicity.
Erpcure Prmedures-Vapor-remove victim to lresh air. Skin or eye contact-remove contaminatedclothing
and gently flush atfected areas with water. ErDcure Prredures-Skin contact-wash well with soap and water. Eye contact-flush with potable water.
Strbllity-Stable.
Conprtlblllty-Mrterid:
REACTIVITY DATA
Can rsact with oxklizing materials.
Usual malerials ol construction are suitabl€.

t- Stsbility-Stable.
REACTIVITY DATA
Comprtibility-Material: Usual materials of construction are suitable.

Csgo: Group 30 of compatibilitychart.
Crgo: Group 32 ol compatibilitychart

Avoid contact with liquid. S€curo ignition sourcas. SPILL OR LEAK PROCEDURE
Avoid contact wilh liquid
fl r rDfff acut. 6ll the Nrtlod R6Dn CGrtrr. em12+o'02.

' Vapor lt I rtll Grn. c.ll thc Nrtl0l Ccntcr. t(XH2l-Cflr2.
lrtr: Prelruro: t mmHO!t 47.2'C.
I uno.agn d l[..1r: I Una|l|hnod
t26
-,ilidumilil4lLfi$nilitril*.,,- SCANNED BY MKP & BARIS A. 2004
,,'*-r.*iaia-di{t{ililia t21
DODECYLPHENOL il EPICHLOROHYDRIN
Synonyms- No common synonyms Synonymr- 1-Chloro-2,3-€FDrypropan€; Unlted Nrtions NrDbel ... 2023
CHRIS Codc..............,........... ooL

Ir 3-Chloro-1,2-epoxypropene: Chloromelhyloxiran€;
2-Chloropropyl€neoxido; gamma-Chloropropyl€n€
oxide; Oxirans, (chloromsthyl)-;Propsn€.
1-chloro-2,3-epoxy ('IlRlS Code ................
Formula-CHsCrrHzCsHTOH
colored liquid;phenolic odor

ADpes.NDce-Odor-Straw
SDecificGrsvity-o.go to 0.99
Bolllng Point...
Frezlng Point.
314-344'C 597-632'F
_'a
_'c
t'c _'F
_'r
_'F
It, Fomuh-CHTCHCHzCI
Aplnnncc-Oda-Colorle$
sweetish odor
liquidi chlorolorm-like,
Eollltrl Point ................
l'rerlr8 Poltrl..... .........

_'c
116'C
58"C
_'F
240"F
73'F
Speclfic Gr.!lty-1.18 _'c _'F
Vrpor Pwure 20'C (5t'D (mnH$.......... ---I- Vtlor Prsu€ 20"C (6t'F) (nnHg.......... --J25-
Crhenicd Frmily-Phsnols R€idVrpor Prsure (pair)...... Chcnicd Frnlly-Epichlorolrydrin R c l d V r p o r P r e s u r e ( g d r ) . . . . . . . . . . . . . . . . . . . .0. . .6. 7. . .
VaporP6rre 46'C (115'F)(pcia)............. ----l- Vrpor Prsure 46'C (tf5'F) (Dotr)............. 1 O
Pollution CEtegory-USEPA - fUO A V s D o r D e n s i t y ( A:i r 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .9. . 0. .9. . Pollution Crtegory-USEPA B C
Iw|O V r p o r D e r o l t y( A i r : 1 . 0 ) . . . . . . . . . .......... . . . . . 3 . 1 9
ADpliqble Bulk Reg.46 CFR Subchrpter........ O sohb|IltyInwater......................... lnsolublo Applicsbl€ Eulk Reg. {6 CFR Subchrpter........ O 6"/"
Sohblllty ln Wrtcr ........
Combustibleliouid Combustibleliouid
Elehical Group--D Electrlcd GroulFC
fire hazard when exposed to heat or tlame; decomposeswhen heatad yi€lding loxic products. of the products ol combustion is hydrochloricacid gas, which is both toxic and corosive. lgnited
by heat and open flame. This product can decompose to lorm highly toxic phosgene gas.
Flsh Polnt CF).............................

325 Flsh Poirt('F).............................'105
FlenmebleLinite..........................
Unavailable FlsnmableLimits..........................
3.8 lo 21'/"
AutoiSnitlotr
TemD.CF)................Unavailable AutoignitlonT€mp.('F) ................
804
Exti4uLhltrS ASents CO', dry chemical,alcohol loam, waler tog Extirgul8hlnSASenb CO:, dry chemical, alcohol loam, waler tog.
Specld Ftrc Praeduo................ Weat s€ll-containedbreathingapparatus.Waisr can caus€ frolhing. Flre Prc€dur6................ Keep exposed tank cool with water spray. Provide respiratoryand body
protection to firefightingpersonnel.

Holil Hurd Rrtirys Odor Threshold (ppn) PEL,/TWA (Dpm) TLV,/TWA (DDn) Health H@rd Rrdngs Odor Thr$hold (Dpm) PEL,/TWA (Dpn) TLVITWA (ppn)
Unavailable Unavailabls Unavailable Unavailable 3, 3, 4 10 to 25 2/Skin 2/Skin
toxic, highly irritating. carcinogen.Vapor extremely initating. Lung injury may b€ delayed. Liquid causes severe
burns; absorb€d by leather and causes delayed burns. Class B poison.
Ing€stion:Burning pain in moulh and throal, abdominalpain, vomiting, diarrhea,weakness, Th€ liquid blisters skin on contact. The vapor causes eye and respiratoryirritaiion. lt may also
dizziness.Corrodes digestivetract. lnhalation:lritation, bronchitis,pneumonia.Skin: iritiation, pain cause vomiting, convulsions,rapid pulse, and respiratoryparalysis.
short Erlmure TolemcF Short ExposureToleme-Concentrations exceeding 40 ppm rapidly produce irita'tion to nose and eyes.
Ertmurc Prccdurs-Get medical attention. Ingestion:Drink water or milk, swallow activatgd charcoal or castor ExDqure Prcedues-Vapor-remove victim to tresh air; it breathing stops, apply artiticial respiration-Skin or
oil. Inhalation:Ramove to fresh air. Skin conlact: Wash twice with soap and waler. Eye contact: Flush with eye contact-r€move contaminaled clolhing and gently tlush affected ar€as with water for 15 minutes. Get
wat€r for al leagt 15 minules. medical attenlion as soon as Dossible.

sldlllty-G€nsrslly slabl8 but decomposeswhen heated forming toxic producis. Reacls with oxidizing Strbllity-Stable under usual handling conditions. However, it will polymerizeat elevated temperaturesor in the
materiala. presenc€ of certain catalysls; acids, alkalies and metallic halides are known io be effectivs catalysts for
polymerizationand should be avoided.
'ooFtlbllliy-Mrtcrld:
ComDrtiblllty-Material: Usually caried in steel tanks; however,the wet product wiil pit steel.
Cu|o: Group 21 ol compatibilitychart. CsrSo: Group 17 of compatibilitychart,

Avold contact. Woar paoloctivo clothing and tace shisld. ll spill is hoated ot burning, saar aalt€ontaln€d Wear rubb€r gloves, sell-containedbreathing apparatus,prolective clothing. Evacuate personnsl noi oquipped
rppt'elu8. Malofil b a ledous pollulion huard. with prolective cloihing and respiratoryprot€ction. Secure ignition sources.
Bcun c.ll lL Nrrld n-|pu Cc.ar. tflr{2.-lor. ll r rDlll Ecm, cdl the Nrtlord R6po@ Cetrter, 8m-424-t802,
buhr f t nrvalLb|.. rrt llnrrlr:
l2t
SCANNED BY MKP & BARIS A. 2004 t29
ETHANE ETHANOLAMINE
Synonynr- Brmelhyl:Oimethyl;Ethyl hydrid€; Unitcd Nrtiors Numb€r... relrigerated 1961
Synonyms-Aminoethanol; 2-Amino€thanol; United Nstions Number................................2491
Melhylmothane compressed 1035
beta-Aminoelhylalcohol; Colamine; Ethylolamin€;
2-Hydroxethylamine;b€ta-Hydroxethylamine;
Monoethanolamine
CHRIS code .. MEA
Fmulr-GHc Fomule-HOCHzCHzNHz
Boiling Point .. .......... 172'C 342"F
Apgcrrrnce-Odor-Colorlessgas, colorless liquid; _"c _'F
odorless ...... 180'c 292'F ADD€rrrnce-Odor-Colorlessliquid;ammonia-likeodor -r
Freezing Point..
_'c _'F Frezing Point o"c so'r
SpecificGrrvity-0.45 (liquad) Sp€citicGr.rity-1.02 _'c _'F
VaporPrsure 20'C (5S'F)(nnHd........ . V Hioh
chenicrl Fmily*Saturated hydrocarbon V. Hioh Valnr Prroure 20"C(68"F)(nmHg).......... 0.48
R€idVrDorPrsure (Dsir)........................... Chemicrl Fmily-Amine Reid Vapr Prsure (psh)......... .............. 0.01
VeporPrwure,l6'C (1l5'F.)(Fir).............V. Hioh
1.04 Valnr Prwure 46'C (lfs'D (psia).............0 03
Pollutio! Crtegory-USEPA - IMO ---9gS- V$or D€Eity (Air : 1.0)........................... Pollution Crte8o.y-USEPA - IMO D V a l n r D e n c l t y ( A i r: 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .2. . .1. 0. .
ApDlicsbleBult Reg.,16CFR Subchapter........
---Q.-Q- sohbilityinwrter......................... lnsluble Applicrble Bulk Reg.a6 CFR Subchapter.... .. O S o l u b i l i t y i n W r t e r . . . . . . . . . . . . . . . . . . . . .C
. .o
. .m o l e t e
FlammableGas (LFG) GrrdeE: Combustibleliquid
Electric.l GreuD-D Eletrisl Grou!+D
Generrl-Oangerous, when exposed lo heat or flame. Unless the flow of gas can be stopped, extinguishinga G€rerd-Moderate hazard,when exposd to heat or llame. lrrilating vapors generated when heated.
fire will permit accumulationol an explosiveconcentrationof vapor, and subsequenl explosionor re-flash.
F l s h P o i r t C n . . . . . . . . . . . . . . . . . . . . . . . . .2. l.l. . l l s h P o l n tC D . . . . . . . . . . . . . . . . . . . . . 2
. .0. .O. . . .
FfanmrbleLimits.......................... 3 lo 12.5o/" Ilumrble Linits.......................... Unavailable
Autolgnitlon Temp.CD ................ 959 AutoignitionTenp. ('F) ................ greaterthan 500
Eltlnguishirg Agents Stop flow of gas; COr, dry chemical ErtiryuishinSA8crts..................... COr, dry chemical,alcoholfoam, water tog
Spelal Fire Pruedurc................ Shut otf gas supply, then us€ dry chemical or CO2.Tanb exPosedto lir€ Spccid Fire Prcedurq................ Resoiratoryand body protection should be worn by fire parties.
should be kept cool with a continuousspray ol waler.

Hcdih Hr8d Rrtitrgs Odor Thr€hold (Dpn) PELAWA (pDn) TLV,/TWA (pDn) Hesltb Hurd RitinSs Odor Threshold(Dpm) PEVTWA (ppn) TLV,/TWA (ppm)
Unavailable 899 Unavailable Unavailabl€
2, 2, 2 Unavailable 3 3
Genenl-Simple asphyxiant.Breathingvapor may cause unconsciousnesswithout warning becaus€ of lack of General-Liquid contact causes severa eye irritation.Vapor inhalalion causes respiraldy irritation.
orygen. Contact with liquid will caus frostbite.
Sympto|rlnhalation-headache, diziness, drowsiness.Skin contact-frostbite. Synptons-R€spiratory itritation will range from itching to severe burning dop€nding upon concentration.
Short Expcure Tole.ucFExposure of guinea pigs to concentrationsol fiom 4.7 to 5.5% for 2 hours caus€d Short ExDosureTolerance-S0 ppm for 30 minutes.
only slight drowsinessand irregularrespiration.
ExposurePruedurevapor-remove to lresh air; il breathingstops, apply artiticial respiration.lf the liquid has ExDGurePrcedur6-Vapor-remove victim to fresh air; if breathing siops, apply artiticialrespiration.Oryg€n,
spilled onto the skin, points ol contact may be frostbitten;handle gently and protecl from mechanical adminisleredby trained personnel,is otten helpful. Skin or eye contacl-remove conlaminated clothing and
damage. DO NOT RUB. Get medical attention. genlly tlush atfected areas with wal€r for 15 minut€s.Get medical advice or attention.
REACTIVITY DATA REACIIVITY DATA

Strbllty-Stable. Strbility-lt will oxidize in the presence of air, so is otten shipped under a pad ot inert gas. Ethanolamineis a
reactive maierial combining chemically with many other substances.
Cor9.tibility-Mrteri.l: Noncorrosive C4nprtibility-Mrterid:
I
Corrosiveto copper and its alloys; also anacks rubb€t.
Crrgo: Group 31 ol compatibilitychart Crrgo: Group 8 of compatibilitychart.

Werr rubb€r glove3, face shiold, protslive clothing. Havs allfurpos€ crnittsr resfriator rvdLbL. Lrquid r{l Wear butyl rubb€r gloves, lace shield or all-purposecanister respirator,proteciive clothing. Avoid conlact wilh
rapidly.S€cure all possible sourcos of ignition. liquid. Cover spill with sodium bisutfate.Wash wilh excess ot water.
ltr Nrlloul R6Dou Ccrtcr,

If . tDlll acrn, c.ll ti. N.tlotrd noDore Ccnt.r, 0llGa2+tt02
filfa llcrerlr;
f-
r!q SCANNED
- BY MKP & BARIS A. 2004
".4i.!t Dl
ETHYL ACETATE
ETHOXYTRIGLYCOL ' 11 7 3
Synonyme-Acetic acid, ethyl ester; Acelic ester: Acetic United Nations Number...........
Synonyne 2-[2-(2-Elhyoxysthoxy)ethoxy]ethanol; United Nstions Nuf, ber....................... ether; Ethyl sthanoale; Vinegar naphtha
EthyoMriethyl€m glycol; Triethyleneglycol ethyl
ether: Triglycolelhyl ether; Triglycolmonoethyl
sther ETA
CHRIS Code ETG
Fornuh-CHTCOOCTHs
Fornuh-C:H.O(CH")zO(CHr),OCHTCHzOH Boiling Point 77"C 17'l"F
B o i l i n g P o i n t . . . . . . . . . . . . . . . . . . . .2. 5. 5 ' C 491'F Appearance-Odor-Colorlo!! liqurd: pleasanl, lruily odor _'c _'F
Apperrrnce.Odor-Colorlessand practicallyodorless _'c _'F FreezlngPoint........................ -83'C -117'F
Freezing Point .. .......... -19"C -2'F Sp€cific Grsvlay-0.90 _"c
SpecificGravity-1.02 _'c _"F Vrpor Prssure 20'C (68'n (nmHg)..........
.
Vapor Prsure 20'C (68'F) (mmHg)..........---9!-l- Chenicrl Frnily-Eal] Reid Vspor Pressure (psia)..-...... w
ChemicalFamily-Glycol ethel ReidVrpor Pressure (psia)................... ... V. Low Vtpor Presure46'C (1fS'n (psls)............. 4 5
VsporPre$ure45"C(ff5'F) (Dcit)............. V. Low Pollutior C.teSory-tlSl:p,r D lM() D V r p o r D e n s i t y( A i r : t . 0 ) . . . . . . . . . . . . . . . . . . . . . 3 . .0. .4. .
Pollution CrteSory-USEPA - IMO D V a p o r D e n s i t y ( A :i r 1 , 0 ) . . . . . . . . . . . . . . . . . . . . .6. '.1. .4. . ApDlicsblc Butt Rcg.,16 ( t,R subchrptcr D S o f u b i l i t y i n W a t e r . . . . . . . . . . . . . . . . . . . . . . .8. . 7 " / "
ApDlicobleBrlL Re8.{5 CFR Subchapter........
--D- SolubilityinWrter.........................Comolete
FIRE & EXPI,OSION HAZARD DATA

FIRE & EXPLOSION HAZARD DATA Grade-C; Flammableliqurd
crrde-E: Combustibleliquid Electricd Group-D
ElectricalGroup-C
(;enerrl-Ethyl acelal€ is highly llammabl€ and its vapors torm explosive mixtureswith air. Flashback along
Gercrsl-Slight firo haard, when expos€d lo heat or tlame. vapor trail may occur. Vapor may explode il igniied in an onclosod area.
F l s b P o i n t( ' D . . . . . . . . . . . . . . . . . . . 2. .4. .(.c. c. )

Flsh Point('n.............................
275 Ffmnrble Limits ... 2.2 lo 'l l 5"h
F|rnmble L|nits..........................
Unavailabla AutoignitionTemp.("D ................ 800
AutoigritionTcmp.('F) ................Unavailable ExtinSukhlnS A8ents.... ................ CO,. alcoholfosm, wal€r fog, dry ch€mical
Extinguishing Carbondioxide,dry chemical,alcoholtoam
^8ents..................... SpecialFlre Prmedures................ Use ot dry ch€micalwher€ it can get into a tank of ethyl acetateis not
Specirl Fir€ Prcedurer................Wal€r and loem may be ineltective on tire. Cool exposed tanks with water. recommended.Fire involvingspills outsid€ ol lanks can be extinguishedwith dry chemical.
HEALTH HAZARD DATA

HEALTH HAZARD DATA Hellth Hrard Rstings Odor Threshold (Dpn) PEL,/TWA (ppn) TLVAIVA (ppm)
Hqlth Hrard RrtiDSs Odor Thr6hold (ppo) PELITWA (ppm) TLVITWA (ppn) 1,1,2 100 400 400
0,0,0 Unavailable Unavailabls Unavailable causes some irritation.Absorption is chielly by inhalation.Continued skin contact will dry and
G€nersl-Under ordinaryconditionsof handling,not consideredloxic. crack skin with chance of dermatitisand infeclion.
Symptoms-Headache,irritationof respiratorypassages and eyes.

SymDtoms-Noappreciablehazard in ordinaryhandlingor uso.
Short ExposureTolermce-l 000 ppm tor 5 minutes.
Short ExDGure Tol€.rncFNot pertinent.
ExposurePrcedures-Vapor-remove victim to fresh air; if breathing stops, apply artificialrespiration.Skin or

ExposurePrecdures-Eye contact-llush gently with water. eye conlact-remove contaminatedclothing and gently flush attected areas wilh water fo|I 5 minutes. Gel
REACTIVITY DATA
REACTIVITY DATA stability-stable. will hydrolize(roact with water) on standing to form acetic acid and ethyl alcohol. This
reactaonis greatly accelerated by bases (alkaties).Can react vigorouslywith oxidizingmaterials.
Compstibility-Mrterial: Softens and dissolves rubber and many plastics.

Usual materialsof conslruclion ar6 suitable.
Cargo: Group 34 ol compatibilitychart.

c.180: Group 40 of compalibilitychart.

SPILL OR LEAK PROCEDURE Wear rubber gloves, lace shield, prolective clothing. Have all-purpos€canister mask availabl€.Avoid contact
Avoid contacl with liquid. liquid. Secure ignition sources.
lf e calll ccurs, cdl the Nstiod.l Center. tflH24-t802.

!t. tal Nrn, c.ll tL N.alcd Itlr Ccrtor, ' Vapor Pressursr100
lcnrrlr: mmHo at 27'C.
ll.ul.r I Url||rgrrd
iit.d, :, ;,*d$;eiii|irii*,i.,,i.i&Etd&" SCANNED BY MKP & BARIS A. 2004 ilt

ETHYLACRYLATE ETHYL ALCOHOL
Synonyms- Alcohol; Alcohol Anhydrous; Alcohol C-2;
Synonyms- Acrylic acid, ethyl ester; Ethyl propenoate;
Cologne spirit; Denatured alcohol; Ethanol; Ethyl
Ethyl 2-propenoale;2-Propenoicacid, ethyl ester
hydroxide; Fermenlation alcohol; Grain alcohol;
Methyl carbinol
Formuh-CzHrOH
Forolr-CHr: CHCOOGHs
IloillnS Poltrt. 99'C 211'F Boilidg Point........... ........ 78'C 17 3 " F
Appearmce-Odor-Colorlessliquid;pungent odor -'c -'F Appeererce-Odor-Colorless liquid; smells like wine or _'c _'F
l'reerln8 Point -3e'c __ -_103'F shellac thinner Freezing Poirt......... ........ -114'C -173"F
Specific Grsvity-o.79
SpecificGrrvity-o.93
vqpr Prdrre 20'c (6t'n t..H1f ...... eg.g Vrpor Pressure 20"C (68'F) (mmHg)....... . 44
Chemicd Frnily-Alcohol
ChemicalFanily-Acrylatos RGldVttor Pressure (!Elr)................... -- 1.4 Reid Vapor PKule (psia)..............
Vrror Puu.c 46"C( I l5'l) (t lr)............. 2.0 Valnr Presure 46'C (115'F) (psis) 3.5
D A Pollution CrteSory-USEPA - IMO lll Vslpr Density(Air : 1.0)........................ 1.6
PollutionCstegory-USEPA IMO Vttor Denslty(Air r.01........................... ---31-
Appliceble Bulk Re8. ,16 CFR Subchspter........ D S o l u b i l i t y i n W s t e r . . . . . . . . . . . . . . . . . . . . .C. .o. .m g l e l e
ApplicrbleButk Reg.,16CFR Subchrpter...... O S o t u b f f i ti yn W r i e r. . . . . . . . . . . . . . ....... . . . . 1 . 5 o / o
Flammable liquid
Grad*C: Flammable liouid
Electricd Group-D Electrical Group-D
General-lgnited by heat, sparks or open flame. Flashbackalong vapor trail may occur. Vapor may explode if G€neral-Dangerous when exposed to heal or tlame. Flashbackalong vapor trail may occur. Vapor may
ignited in an enclosed area. Fire may cause violent rupture ol tank. Toxic and irritatingvapors generatsd explode if ignited in an €nclosed area.
when heated.
60(oc);48'F (TCC)
Flsh Point CF)............................. F l s h P o i n l( ' D . . . . . . . . . . . . . . . . . . . . . .6. 5. . . . .
1.8 to 9.5'l. (calculaled)
Fl.mmableLimits.......................... F l m m r b l e L i m i t 6 . . . . . . . . . . . . . . . . . .3. . .3.t.o. . .19 %
Autoignition Temp,('F)................
700 AutolgritionTenp. ("1) ................ 793
Extitrguishirg COz,dry chemical,water fog, alcoholtoam
Agents..................... ErtlnguishingA8ents..................... CO,, dry chemical,alcoholfoam, water fog
Fire Preedur6................Keeptank cool with a waler sprayto preventpolymerization. Wear chemical Fire Pc€durw................ Watsr may nol b€ etftrtive unless large quantilies are used.
protectiveclothing, eye protection and sell-containedbreathing apparatus.

Halth Hurd Ratings Odor Thrdhold (ppm) (ppn) (ppm)
Health Hmrd RrtiEr Odor Thr6hold (Dpm) PEL,/TIVA (Dpn) TLVITWA (pDm) PELlTlryA TLV,4'WA
0.00047 s/Skin 5 1, 0, 1 t0 1000 1000
3.2.3
Gererrl-Suspected carcinogen.Vapor irritating. ol the least hazardousindustrialoroanic solvents.
Symptoms-Eye and throat irritation,shortnessof breath, and convulsions. SyhptorDizziness, double vision, and other classic alcohol intoxication symptoms. These may be
accompaniedby symptoms such as vomiting, attributableto the denaturant.
short Exlsure Tolemce-50 ppm tor 15 minutes.2000 ppm vapor killed rats in 4 hours with death attributable ExposureTolerucFsooo-10,000 ppm irritates eyes and upper respiratorytraci; stupor and drowsiness
to severe pulmonaryirritation. may result atter an hour at this concentration. More than 1000 ppm may cause headache and eye irritation.
ExDosurePr@edures-Vapor-remove victim to tresh air; il breathingstops, apply artilicial respiration.Skin or ExpocurePreedura-Vapor-remove victim for tresh air; if breathing stops, apply artilicial respiration.Eye
eye contact-remove contaminatedclothing and gently flush affected areas with water for 15 minules. Get contact-gently flush with water for 15 minutes. Get medical advice or altention.
medicaladviceor attenlion.
REAC]TIVITY DATA REACTIVITY DATA

-Slable.
Strbilig-Will polymerizespontaneouslyif not inhibited.
Compdibility-Miieridi Usual materialsof conslruclion are suitable. Usual materials of conslruclion are suitable.
Cargo: Group 14 ol compatibilitychart. C8.8o: Group 20 ot compatibilitychart. See also Appendix l-Exceptions lo the Chart.

Wear rubb€r gloves, face shield, proteciive clothing. Have all-purposscanistof ma8k available.Avdd contacl S€curg ignition sourcog. Spille may bs llushed away with waler, but should not be llushed into a contined
with liquid.S€cure ignition sources. space boceuse ol the oxplosion hazard.
ll . rDlll Gun. c.ll thc N.tlonll R6m (bnr.r. t{xH2/Flll2. lt . .plll €on, c.ll the Nrtlonrl Rilnn* Centcr, &lt)-42i1-tE02.
l|cub Rrmrrlr:
lL SCANNED ---,r.rtt*
BY MKP & BARIS A. 2004 ltt
ETHYLAMINE
ETHYLAMINESOLUTION,70olo
Synonyms- Aminoethane;Ethylamine,anhydrous; United Netions Number ...........
1!3€_
Monoethylamine Synonyms-Ethylamine,
aqueoussolutions;MEA, 70"/.; UnitedNationsNumb€r....................
........... 2270
Monoethylamine solution, 70olo
CHRIS Code EAM

( lIR|S Code EAN
Fornula-CHTCHzNH: 'C
BoifingPoint...................... 17 62'F Formula-CrHrNHr
Appearrnce.odor-Colorlessliquid or gas; strong _'c _"F B o i l i t r SP o i n t . . . . . . . . . . . . . . . . . . . . . . . . . 38'C 100'F
ammonia-like odor. Freezing Point.... -81'C 114'F Appearance-Odor-Colorless liquid; sharp, ammoniacal
SpeciticGravity-o.80 _'c _'F ordor l'reezing Point < -90'c < 130"F
Specific Gravity-0.8
VtDor Pressurc 20'C (68'F)(mmHg).......... 880
ChemicalF mily-Amine ReidVaporPresure(psia)......... ............ 29.8 Vapor Pressure 20'C (6E"D (mmHg).......... 450
Chemical Family-Amine
VayrrPrmure,t5'C(lls'n(psia).......... 40.8 Reid Vrpor Pressure (Dsia).. . .. 14.8
PollutionCategory-UsEPA B Ilto C v r D o rD c n d t y( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .1. .. .5. 5 Vapor Pressure il6'C ( I l5' F) (psia)............. --L.L5--
Pollution Category-USEPA - IMO C V!!Dr Dedsity(Air : 1.0)..................
ApplicrbleBulk Reg.46 CFR Subchspter........ O S o l u b i l i t y i n W r t e r . . . . . . . . . . . . . . . . . . . . .C
. .o. .m o l e t e 1.56
ApDticabl€ Bulk Reg. il6 CFR Subchspter ..... O Solubility in Water .... Comolete

crade-A: Flammable liquid
Grade-A: Flammable liouid
Electrical Group-C
Electrical Group-D
G€nerrl-Toxic oxides ol nitrogen may lorm in fire. Dangerous. Keep away from heat and open llame.
Genersl-Highly flammable vapor. Keep away from ignition sources. Flashback along vapor trail may occur
Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area.
Vapor may explode if ignited in an enclosed area.
F l N h P o i n t ( " n . . . . . . . . . . . . . . . . . . . . . . . . .l .e. s. .s t h a n 0
F l a s h P o i n t ( ' F ) . . . . . . . . . . . . . . . . . . . . . . . .b. .e. l. o w 0
F l a m m a b l eL i m i t s . . . . . . . . . . . . . . . . . . . . . 3 . ...5. . t o ' 1 4 . 0 %
Flgmmable Limits..........................3.5 to 14.0olo
Autoignition Temp. ('F)................ 725
Autoignition Temp. ('D................ 723
Extinguishing Agents..................... Alcohol foam, carbon dioxide, oI dry chemical
Extinguishing A8ents..................... Water log, dry chemicat, CO,, alcohol foam
SD€cirl Fire Pr@edur6................ Keep burning tank and tanks adiacent to it c@l with a waler spray.
Special Fire Procedures................ Wear protective clothing, self-contained breathing apparatus, and eye
protecton.
HEALTH HAZARD DATA

Heslth Hsard Rstings Odor Threshold(ppn) PEL,/TWA (ppm) TLV,/TWA (Dpn) HEALTH HAZARD DATA
3,2,3 Unavailable 10 10 Health Haard Rrtings Odor Thrshold (ppm) PEL,/TWA (ppn) TLVAWA (ppm)
3,2,3 0.83 10 10
Generll-Direcl conlact can cause burns.
Generd-This very volatile solution produces a toxic irritatingvapor.
symDtons-Liquid causes eye injury and skin irritation.

SymDtoms-lnhalation:lrritation,coughing, chest pain, pulmonaryedema. Ingestion:severe burns of moulh and
stomach. Skin and eyes: Severe irritalion and burns.
Short ExposureTol€rare-Unavailabl€
short ExposureTolennce-High volatility means vapor concentrationcan easily exceed TLV €ven at room
temperature.
ExlDsurePr@edurs-ln case ol contacl with eyes or skin, immediatelyflush with plenty of water lor at leasl 15
Expcure Prcedur6-Gel medical attention. skin or eye contact: Flush skin and eyes with water for 15
minutes;for eyes get medical attention. Remove contaminatedclothing and shoes al once.
minutes. Inhalation:Remove to fresh air and provide mouth to mouth resuscitatim or oxygen as need€d.
REAC:TIVITY DATA
Stlbility-Stable. REACTIVITY DATA
Stability-Slable. Reacts with acids and oxidizers.Reacts exDlosivelvwith mercuru.
ConDatibility-Material: Steel, stainlesssteel and nickel are compatible.Aluminum and copper should not be
compstibility-Mrterial: Suitable:Stainless steel, mild steel, nickel, tinned iron. Unsuitable:Copper, aluminum,
used.
zinc, brass, bronze, galvanizediron, polyethylene,rubber.
Crrgo: Group 7 ol compatibilitychart. See also Appendix l-Exceptions to the Chart
Cugo: Group 7 of compatibilitycharl.

ll possible, w€ar buiyl rubbsr gloves, lace shi€ld or all-purpose canister fespiralor, and prot€ciive clolhing.
Avoid contact and stay upwind. Eliminate ignition sources. Wear self-contained breathing epparatus or
Socure rgnition surc€s. Cover with sodium bisulfat€. Clean up. Do not llush spill into conlined spac€s where
amine-type mask, plastic gloves, tace shield, goggles. Wash clothing belore reuse. Flush spill arsa with water.
vlport can accumulate.
Do not tlush spill into confined spaces where llammable vapors can accumulate.
lt I |Dlll cc!n, cdl the Nilloul RoDoDE Cbnlq, llx}-a2l-8t02.

la . tDlll Nrn. crll thc N.tion.l C.nter. tlXF42/H01.
krryll
Rcnrrlr:
SCANNED BY MKP & BARIS A. 2004 n?

ETHYLBENZENE ETHYLBUTANOL
Synonyms- EB; Ethylbenzol; Phenylethane United Nrtions Number 1175 SyroryD-2-Ethylbutsnol; 2-Ethyl-'l-butanol;2-Ethyl United Nrtios Numbel . . . . . . . . . . 2. 2 7 5
bu9l alcohol; sec-H€xylalcohol; sec-Pentylcarbinol;
Psudohexyl alcohol
CHRIS Code EBT
Fornula-GHsGHs Fomule-CHTCHzCH(qH5)CH'OH
'C 293'F
Bollins Poina 136'C 277'F BolltnS
Potnt........... 'c 'F
ADp€rrance-Odor-Colorlessliquid;aromatic odor --gs'3 Appearance-Odor-Colorlessliquid; mild odor
FreezlnsPoinr......... . - t*"F Frezln3Potnr rra'c lzg-"r
SpecificGravity-0.87 _'c _"F SpecilicGravliy-o.83 _'c _"F
Vrgor Puure 20'C (6t'D (mmHd.......... 15.3 Vrlnr Pressure 20'C (68"D (mmHg).......... 0.9
Ctemical Family-Aromatic hydrocarbon Chemiel Frnlly-Alcohols Rcid vspor Presu.e (pslr)........................... 0.07
R e l d V r p o r P @ u r € ( D d r ) . . . . . . . . . . . . . . . . . . . . .0. ...4. . .
Vrgor Pmure {5'C (lf5'n (psia)............. ---Q-&- Vapor Pressure 46'C (lf5'n (psi8)............. 0.14
C C' Pollution C.tegory-USEPA - IMO @O V r p o r D e n s l t y ( A i r : t . 0 ) . . . . . . . . . . . . . . . . . . . . . . . . . .3. . 4
Pollution Crtegory-USEPA IMO V r t o r D c n l l t y( A t r : 1 , 0 ) . . . . . . . . . . . . . . . . . . . . .3. .6. 6. . .
Apptic.ble Bulk Reg.45 CFR Subchpter ...... O SolubilityinWster........................ Sliohl
ApplicableBulk Reg.45 CFR Subchapter........
---Q.-Q- S o l u b l l t t y i n w s i e r . . . . . . . . . . . . . . . . . . . . .N
. .e. .o l i o i b l e
cndFc: Flammableliouid Grade-D: Combustibleliouid
Electricd Group-D Electrical Group-O
Gene.al-lrritating vapors are generatedwhen heated. Vapors may travel considerabledistancestrom a source Generll-Moderate tire hazard when exDosedto heat or flame.
in a llammable concenlration.Flashbackalong vapor trail may occur. Vapor may explode il ignited in an
enctoseoarea_
l ' l s h P o i n tC F " ) . . . . . . . . . . . . . . . . . . .5. .9. . . . . . . . F l E h P o i n t( ' D . . . . . . . . . . . . . . . . . . . . . .1. 3
. .7. . . .
l'lemnableLimits.......................... 1.0 to 6.7'l. Fhmmsble L i d i t s . . . . . . . . . . . . . . . . . . .1. ...9.t.o. .8 . 8 %
Autoignition Temp.('D ................ 810 AutoignitionTenp. ('F) ................ 580 (calculated)
Extinguishirg Agerts................... CO?,dry chemical,foam,wai6r tog ExtinSuishinSAgents Water spray, dry chemical,foam or CO2.
SpecialFire Pre€durd................ Fight in the same manner as any Grade C petroleum lire. Firefightersshould Specirl Fi.e Prcedures................Cool exposed tanks with water. ll a leak or sdll has not ignited, use waler
wear selt-containedbreathingapparatus,prolective clothing and eye protection. spray to dispersevapors.

Heslth Hrard RdinSs Odor Threshold (ppm) PEL,/TWA (ppm) TLVAWA (ppn)
Herlth H@rd Rrtings Odor Thr6hold (ppm) PELITWA (ptm) TLV,/TWA (ppm)
2. 2. 2 '140 100 100 1, 2, O Unavailable Unavailable Unavailable
General-Vapors cause eye irritation,dizziness,narcosis (paralysis),burns of the skin, sensation ol chest Genersl-Low toxicity.
constriction.lrritationol respiralorytract, conjunctivitis,dermatiiis.Exfoliationol large patches ot skin and
chapped appearanceresult.
SymDtoro-lrritation to eyes and throat, dizzinessand a teeling ot chest constriction. Symptons-Animals tesls show minor skin irritationatter 24 hou6. Severe surface damage ol eye wh€n alcohol
in sutficient concentration.No deaths upon ingestion.
Short ExposureTolermce2oo ppm for 30 minutes; 1000 ppm irrilates skin and mucous membranes.2000 ppm Short ExDosureTole.rnce-Unavailable
extremelyirritaling.
ExpmurePreedures-Vapor-remove victim to fresh air; if breathingslops, apply ariificial respiration.Skin or ExposurePrcedures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration.Eye and
gye contacl-remove contaminaledclothing and gently tlush attecled areas with water lor 15 minutes.Get skin contact-gently llush afiected areas with water tor 15 minutes. Get medical attention.
medical advice or atlention.

sr8bility-stable. Stsbility-Stable.
Compstibility-Mrterhl: Usual materialsof construction are suitable.

Comp.tibility-Miteri8l: Rubber in prolongedexposure to ethylbenzenefirst sweels, then softens.
Cargo: Group 32 ot compatibilitychart. Cargo: Group 20 ot compatibilitycharl.

Secure agnitionslces. Wear rubber gloves, lace shield, protective clothing. Have all-purposecanister mask
Wear rubber gloves, lace shi€ld, protgciive clothing. Havs all-purposecanisl€r mask availablo.Avoid contact
available.
with liquid.ScuJo ignilion sources.
la I |9ill acm, cdl the Nrtior.l ResDons Cotcr, t00-424-8t02,

lt I Dlll ccun. c.ll ah. N.ilond
tcmrtr 'Pollution Cdagory C oiflik€,33 Rcmrlr:

CFR 151.49
Jir@t*,^* "-, -,
rJt SCANNED BY MKP & BARIS A. 2004 l.l9
ETHYL CHLORIDE ETHYLENE
SynoDyms-Chloroethane;Ethsr, hydrochloric; Urited Nations Numb€r................ 1037
Synonyms- Bicarburetted hydrogen; Elayl; Ethem; United Nrtions Numbcr... compressed 1962
Hydrochloricether; Monochloroelhan€;Muriatic Oleliant gas refrigeraled 1038
ether
CHRIS Code ........... ... ECL

C H R I S C o d e . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . .E
. .T L
Fomuh-CHrCHrCl Fomula-CHrCHz
BoilingPoint.......................... 12'C 54"F -104'C
BollhS Polnt...................... 155"F
App€arrre-Odor-Colorless gas or liquid;ether-like Apperrrnce-Odor-Colorless liquid or gas; v€ry faint,
odor F r e e z i n gP o i n t . . . . . . . . . - 139"C Zrg"f
'c 'F sweel odor. l ' r e e z i n SP o | n t . . . . . . . . . . . . . . . . . . . . rog'c nlt
SpecilicCrrrity-o.92 "c 'F
Sp€cific Grsvity-o.34
Vapor Pressure20'C (6S"F)(mnHg).......... --l!Q9-- Vrgor Puure 20'C {6t'F) (mnHd..........-
Chedicsl Family-Halogenated hydrocarbon Reidvspor Pressure (psie)........................... 34.5 Clremical Family-Olef in ReldVrpor Presure (Dsir)...-..........
Vt1rerPressure 46"C(115'E (Dcir)............. 40 Vrlnr Prwure,l6'C (115'D (psis)
'
PollutionCategory-USEPA - IMO # VaporDensity(Air : 1.0)........................... 2.22 oas
Pollution Crtegory-USEPA - IMO Vlpor Dctrdty(Air : 1.0).............. ... 0.98
Applieble Bulk Re8.,16CFR Subchapter........ O S o l u b i l i t y i n W r t e r . . . . . . . . . . . . . . . . . . . . . . .S. .l i o h t Applicable Bulk Reg,46 (ll'R sub.hrptcr D. O S o l u b i l l tlyt r w s t e r . . . . . . . . . . . . . . . . . . . . . . .Neolioible
..
Grade-A: Flammableliquid crsde-Liquelield FlammableGas (LFG)
Eletrical Group-D Electricsl Croup-C
General-A highly flammable,volatile liquid;produces highly poisonousphosgene gas when ignited. Unless flow General-Unless flil ol gas can be siopped, putting out an elhylene fire will permit the accumulationof an
ol gas can be stopped, putting oui an ethyl chloride fire will permit accumulationof an explosivevapor explosive vapor concentration.Vapors are anesthetic.
concentralion.
F l s h P o i r t C F ) . . . . . . . . . . . . . . . . . . . . .- .4. 5
...... F l s h P o i n t ( " D . . . . . . . . . . . . . . . . . . . . . . .2. .1. 3
...
F l a m m r b lL€i m i t s . . . . . . . . . . . . . . . . . .3. . 6 . .t.o. . 1. 4 . 8 % Ffamm.bleLimits...................... .... 2.7 lo 34oh
Autoignition Temp.('F)................ 966 AutoiSnition TemD.("F)................ 842
ExtinguishingAgents..................... Stop flow of gas; COr, dry chemical,water tog Extinguishing A8ents..................... Stop flow of gas; COr, dry chemical,water fog
Spsial Fire Prcedug................ Fire parties musl wsar respiratoryprotfftion. Keep tanks cool wilh water SpecialFire Prcedurs................ Tanks exposed in fire should be kept cool with a waler spray. Attompt to shut
spray. ofl leak. Wear self-containedbreathing apparatus.

Health Haad Rrtings Odor Threshold(ppm) PEL,/TWA (ppn) TLVAWA (Dpm) Hedth Haard Rstings Odor Threshold(ppm) PEL WA (ppm) TLvAwA (ppn)
1. 1. 1 Unavailable 10OO 1000 0. 0. 1 Unavailable Unavailable Unavailable
GeD€.d-Vapor harmtul.Liquid may cause skin or eye injury similar to frostbite. Gener.l-A simple asphyxianl.High concentrationscause anesthssia.
Symptoms-lrrilatingto eyes. Drowsinessand dizziness.Frostbittenareas will be white. SymDtoms-Dizzinessand drowsiness.Contact with liquid will cause frostbite.
Short ExposureToleruce-lnhalation ol 19,000 ppm in air caused partial intoxicationin one minute which Short Expaure Tolerrnce-Unavailable
increasedto dislinct intoxicationwith slight analgesia in 12 minutes.
Exp6ure Prtredurg-Vapor-remove victim to fresh air; il breathingstops, apply artificial respiration.Skin or Exposur€Pr@edur6-Vapor-remove victim to fresh air; il breathing stops, apply artiticialrespiralion.It the
eye contact-remove contaminatedclolhing and immediatelyllush aftected areas with water for 15 minutes
Handle frostbitten parts gently. Get medical advice or attention.
I liquid has spilled onto ihe skin, points of contacl may b€ frostbitten; handle gently and protect lrom
mechanicaldamage. DO NOT RUB. Get medical attention.

Stsbility-Oangerous reaction is possiblewith oxidizingagents. Slow hydrolysis(reactionwith water) in Stsbility-Ethylen€ is a reactive compound but must be catalfzsd betore mosl reactions take place
presence of salt or fresh waler to form toxic and corrosivefumes of hydrogen chloride gas.
Compatibility-Msterirl: Compatiblewith mosl materialsof consiructio;r. Compatibility-Mlterid:
t
Ethylene is not corosive.
Cergor Group 36 of compatibilitychart. Cargo: Group 30 ol compatibilitychart

Wear rubber gloves, selt-containodbreathing apparatus, protective clolhing. Sscure ignilion Sources.It water Wear rubber gloves, lace shield, protective clothing. Have all-purpose canister available. For a gas leak lrom
tam9€talure is above 54"F, lhe ethyl chloride will soon boil otl. Do not llush spill into conlin€d spaceg whsr€ a faulty tank, keep concentration of gas below the explosive mixture range by forced ventilation.Avoid contact
llemmabl€ vapors can accumulal€. Personn€l nol wearing respiratoryprotection should b€ kepl upwind of lhs with liquid. Secure ignition sources. The liquid will rapidly boil away, leaving no residue.
|oill
lt a .Dlll Gcun, crll thc Nrtldd nqonsc C€nter,tlxl424-Ct02. If . tDlll @curs, csll the Nrtlonrl R6lpns€ Cent€r, 8(L42iL8802.
ll.i.rlr: , Nr) l)otrmrnatorr
Rcnulr: ' Ethylen€ is gag
a at tomp€raturesabove 48.7'F
,Biilld8deflid, . ,-.
t40
SCANNED BY MKP & BARIS A. 2004 t4l
ETHYLENECHLOROHYDRIN ETHYLENECYANOHYDRIN
synorynr- 2-Chlorethanol; 2-Chloroethanol; United Nations Number 11 3 5 Synonyns-2-Cyanoethanol; Glycol cyanohydrin; Llnited Nrtions Nomber..................
2-Chloroethyl alcohol; Ethylene chlorhydrin; Glycol 1-Hydroxy-2-cyanoslhane;
Hydracrylonitrilei
chlorohydrin 3'Hydroryptopanenitril€;
3-Hydroxypropionitrile;
beta-Hydroxypropionitrile
cHRIs code........... .... ECH ETC
CHRTS Code
Fomula-ClCHu CH:OH Fornule-HOCHzCHzCN

. .....
BoilingPoint.................. 128"C 262"F 440"F
BoilinsPoinr....p.eqqmB9sgs
-----22'C
ADp€rrance-odor-Colorless liquid; laint - Ap!rcaronce-Odor-Straw-colored
liquid: not unpleasanl _'c _'F
Frffzirspoitrt......... . -69"3 -r-"F
alcohol-ether-like odor. odor. Freezing Poinl 46'C 50'F
Sp€cific Cravity-1.21 _'c _"F SpecificGrsvity-1.04 _'c _'F
'
vrDor Pressure20"C{6E'F)(mmHg).......... VaporPresure 20'C (6E'D (nmHd......... V Low
Chenicsl Family-Alcohol Reidv|por Presure(psia)......... Chemicd Frmily-Alcohol ReidVaporPressure(psia)............... ....... V. Low
VaporPressure 46'C (115'n (psir)............. 0.44 Vrpor Pre$ure46'C (rts"F) (D6ia)............. J-!9!!-
Pollution Cat€gory-USEPA - IMO C 2.78
VaporDemity (Air : 1.0)...................-....... Pollution Crtegory-USEPA - D
IMO VsporDensily(Air : 1,0)............... . ....... 245
Applicsble Bulk Reg. ,16 CFR Subchopter........ O SolubilityitrWtter.........................Comolete ApDlieble Bulk Reg.il6 CFR SubchsDter. .. O S o l u b i l i t y i n W a t e r . . . . . . . . . . . . . . . . . . . . .C. .o. m o l e t e
Grode-D: Combustibleliouid Grrde-E: Combustibleliquid
ElectricslGrouD-D Electrical Group-D
(;enerrf-Moderate lirc hilard when exposed to heat or flam€. Dangerous;when h€ated to decomposition, Cene.d-When healed, ethyl€ne cyanohydringives off poisonous lumes ol cyanides. Reacts with water to
emits highly toxic lumes ot phosgene. produce cyanide gas, which is highly poisonous and llammable vapors.
l ' t s h P o i n t( ' n . . . . . . . . . . . . . . . . . . . . . .I.4. .0. . . . F l s h P o i n tC F ) . . . . . . . . . . . . . . . . . . . . .2.6. .5. . . . .

Flrnnlble Lim|ts.......................... 4.9 to 15.9olo Flammsbfe Limibts.......................... 2.3 lo 12.1'/o
Autoignition Temp.('D................797 AutoignitionTemp.('F)................ 922
Extinguishing A8ents..................... water, CO,, alcoholfoam and dry ch€mical Extinguishing A8ents..................... CO?,dry chemical,alcoholf oam
Spccid Fire Prsedures................Wear sll"containod breathing apparalusand full prottrtiv€ clothing. Coo SD€cialFir€ Procedures................ Firefightersshould wear self-containedbreathing apparatus and tull protective
exposed tanks with water. clothing.

Hedth H@rd Rstings Odor Threshold(Dpm) PELITWA (ppn) TLv,/TwA (ppm) Health Hsaid Retings Odor Thr6hold (pDm) PEL,/TIVA (Dpn) TLV,/TWA (ppn)
'l/Skin 1/Skin
3, 2, o High O,0,2 Unavailable Unavailable Unavailable
General-Little margin of safety between early reversiblesymptoms and tatal intoxication-Faial amounts may be Generel-Toxic by ingestion.Avoid high vapor concentrations.
absorbed by the skin.
SyDptoms-Vapor-causes nausea,vomiting,vertigo, inc@rdination,numbness. Symptoms-Headache,dizziness,bluensss of lips and lingetnails.
short Eag6ure Tolerance-Absorptionby inhalationor skin may cause death. lnhalation-24o ppm lethal to rats Short ExtGur€ Tolerue-Unavailable
in four hours. Human tatality at 350 ppm lor two and one-hall hours.
ExpGure Pr@edures-Vapor-remove victim lrom vapor and adminislerorygen il available.Administerartilicial ExposureP@edures-lf ingested,induce vomiting at once; vapor-r€rcve victim to lresh air; it breathing stops.
respirationil necessary.It swallowed,induce vomiting. Call a doctol. apply artilicial respiration.Skin or eye contact-remove contaminated clothing and gently flush aflected
areas with water for 15 minutes. Get medical advice or attention.
See Medical Kit Intormation,Appendix B

Stsbility-Dangerously decomposesat high tsmperatures. Strbility-Avoid basic contaminationto prevent polymerization.Stable on prolonged storage. Reacts with water.
Reacts vigorouslywith oxidizingmalerials, chlorsulfonicacid, oleum, sodium hydroxide,sulluric acid.
Compatibility-Mrterial! Sleel is satisfactory. Compstibility-Mrterisl Corrosiveto mild stel.
Crgo: Group 20 ot compatibilitycharl. C$go: Group 20 of compatitility chart.

W€ar neoprene gloves, plastic protective clothing and s€lt-coniained breathing apparatu!. Provida good Avoid all contEct with liquid or vapor. Wear rubber glov€s, tace shield, lull protectivs clothing. Socurs ignition
ventilation.Secure all igniiion sourc€s.Wash skin immodiatelywith water. sourcoa. Flood with coDiousamounts of water.
lt I rDlll acu. crll rhe Ncalod n-oox Clnr.r. t{p-.2,1-t8ltt. ll r rglll rrcon, cdl thc Nraloul Rerqrnsc Ctator, t@-4ll-tt02.
llcnrrh: ' V{por l'r{,ssura:
C,EmmHe at 25'C L.ELr I Ur[rr.grul
I Umvlllrbl(l
-&d$*"{"
ral SCANNED BY MKP & BARIS A. 2004 t4t
ETHYLENEDIAMINE ETHYLENEDIBROMIDE
Synonyms- Bromotume; 1,2-Dibromoethane; United Nrtions Numbet . .........................
synon' n.- 1.2-Dramtnoethane; 1,2-Ethangdiamine; United Nstiors Number .. .. .... --L€04- __t€05_
sym-Dibromo€thana; EDB; Ethane, 1,2-dibromo_;
Elhylenedigmine, anhydrous Ethylene bromide; Glycol dibromroe
C H R I S C o d € . . .. . . . . . . . . . . . .
CHRIS Code................ .....................
laa_
Fornuh-BTCH,CH!Br
Fomula-NHzCHTCHzNH:
117"C Boiling Point ........ .. 131'C 268"F
B o i l i t r gP o i n t . . . . . . . . . ...... . 243"F Appeararce-Odor-Colorless liquid; sweet odol _'c _"F
App€arsnce-Odor-Colorless liquid; mildly ammonialike _'c _'F
11'C 52"F Frezltrg Point ........... . 8'C 48"F
odor Freezing Point............... Specific Grsvity-2.1 7 at 60"F
Specific Grrvity-0.91 _'c _'F _'c _'F
Vllor Pressure20'C (68"F)(mnHg)......... 9.0
VaDorPrsure 20'C (68"t-)(nnHg .......... 10.7 Chemical Family-Halogenated hydrocarbon
Chemic8l Family-Amine (psia).......... . ........ 06 ReidVaporPressure(Dsi!)........................ 0.4
ReidVaporPressure
VaporPressure 46'C (115'D (psis)............. 0.7
VaporPrsure 46'C (f fs'D (psia)............. ---O9- Pollution Category-USEPA X IMO B
C VsDoD r € n s i t y( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . 6 . .. 5
Pollution Crtegory-USEPA ----0- IMO v s D o r D € n s i t(yA i r : 1 . 0 ) . . . . . . . . . . . . . ....... . 2 . ' l Applicsbl€ Bulk Reg. 46 CFR Subchrpter O
...... S o l u b i l i t y i n W s t e r . . . . . . . . . . . . . . . . . . . . . . .S
. .l i o h l
Applicrble Bulk Reg. 46 CFR Subchrpter.. .... O s o l u b i l i t y i n w r t e r . . . . . . . . . . . . . . . . . . . . . .C. .o. m o l e l e

FIRE & EXPLOSION HAZARD DATA Gmde-NA
Grrde-D: Combustibleliouid Electrical GrouD-D
Elctricrl GrouD-D
General-Ethylene dibromide is difficulty flammable.Dangerous,wh6n heated to decomposition,it emits highly
by heat and open tlame. lrritatingvapors are generatedwhen healed. toxic lumes ol bromides.
F l s h P o i r t ( ' n . . . . . . . . . . . . . . . . . . . . . .N
. .o. .n. .e.
F l G h P o i n t ( " F ) . . . . . . . . . . . . . . . . . . . . . . . .9. 9. . . . Flmmrble Limits.......................... None
Ihmmable Limits..........................5.8 to l 1.1 o/o AutoignitionTemp.('F) ................ 960
Autoi8nition Temp. ('F)................ 725 Extinguishing A8ents..................... Water spray,dry chemical,foam or COr
Extinguishing A9ents..................... COr, dry chemical, alcohol loam, waler tog specid Fire Pr@dures... ........... Fire lighters should wear tull-prot€ctiveclothing and respiratoryprotection.
Fire Procedures...............-
Becauselhis malerial can cause severe eve and skin burns and resoiratoru
distress,fire parties musl wear full body and respiratorypfotection
HEALTH HAZARD DATA

HEALTH HAZARD DATA Health Hurd Rrtings Odor Threthold (Dpm) PEL,/TWA (ppn) TLV,/TWA (ppm,
Heslth Hrard Ratin$ Odor Thrshold (ppm) PELAWA (ppn) TLVAWA (ppn) 1, 1, 3 22 Unavailable Skin
3.3.3 Unavailable l0 10
Generrl-Suspected carcinogen.Prolonged conlact with skin should be avoided. Toxic bv inhalation.skin
General-Causes severe burns. VaDorharmful. conlact and ingestion.
SymptomFBlistering of skin; destruclion of tissue.

rednessof eyes.wheezingbreath.Liquidconlaclcan cause immedialeskin damageand
blislering.
Sbort ExposureTolerarce-2oo ppm for one hour; 5OOOppm for several minutes miqht be latal.
Short ExposureTolemce-400 ppm has been reported to produce immediateand severe irritationlo nos and
throat.
ExposurePrceduru-Contaminated shoes and ctothing should be removed at once and the skin should
be
I
ExposurePrccedures-Vapor-remove victim to fresh air; if breathingstops, apply artificial rcspiralion.Orygen, thoroughlycleaned with soap and water. lf eyes are accidently contaminated they should be flushed
adminisieredby trained personnel,can prove helptul. Skin or eye contact-remove contaminatedclothing lhoroughly with tlowing water for 1S minutes. A physicianshould be consulted.
and gently flush aflected areas with water lor 15 minutes.Get medical advice or attention.
REACTIVITY DATA
REACTIVITY DATA Stability-Slable' has no oxidizingor polymerizingcharacteristics.will not react wilh air, water vapor, lresh
Strbility-This is a reactive substance,combiningchemicallywith many others. ot
salt water at temperalures below 11S.F.
rpstibility-M.t€riat Reacts vigorouslywith aluminum and magnesium.No apprsiable attack on

CrmD.tibility-Material: Copper and its alloys are corroded readily and should be avoided. steel,
wood, or clolh. Sofiens and deterioratesrubber and oaint.

Cergo: Group 7 compatibilitychart. See also Appendix l-Exceptions to the Chart.

w€at rubbor gloves, 8€lt-containedbreathing apparatus,protectiv€ clothing. wash away wilh water.
Wsar butyl rubb€r glovo3, ell-purposecanister respiretor. prolectiv€ clothing. Secur€ ignilion sources Keep
unprotecledpersonnsl eway lrom spill. ll possible covsr with sodium bisullate. Spray with water. An lllsrnrlivo ia
lo roduce vapor hazerd by covering with alcohol loem.
lt | {illl r.rn, cdl th( Nrtlon.l Crenaer.0lXI-lZ-tt02.
lf r rpill rrccurr, oll th. N.tloi.l n6Frn* C.nt.r, ilXL,a2a-Cllt,
I rmr.lal
nn.hr On.scail tup€ryrsors should tvod vtpor orporuro to porsons who havo rtlhme or olhar rcrprtloft
]lmnlt.
SCANNED BY MKP & BARIS A. 2004 rat

ETHYLENEDICHLORIDE ETHYLENEGLYCOL*
sy.dy||r 1,2-Oichloroethane; sym-Dichlorosthan€; Iltl
UnltedNrtlou Number................................ Synonyms-1,2-Dihydroxyethane; 1,2-Ethanediol; Nrtiou
.t
Ullted Nunber
Outch liquid; Dutch oil; EDC; Ethan€, 1,2-dichlorc; Ethylenealcohol;Ethylenedihydrate;Glycol;Glycol
Elhylsn€ chloride; Glycol dichlorid€ alcohol; Monoethyleneglycol
CI{RIS Code........... ..... IDC- CHRIS Code................. EGL
Fmuh-CICHTCFLCI ,lrr', Fornule-HOCHzCHzOH

Bollirg Poltrt.......................... 84'C 't97"C 387'F
Bolllng Point.................
ADDerue(xor-Cdodess, oily liquid; chlorolormlik€ --gs:3 Appcrrrnce-Odor-Colorless, syrupy liquid; slight odor, --tz'c
ooor trtedagPohi...................... -*:F
swgelish taste FrezingPoint......... ro'r
SEeclficGnvtty-1 .26 _'c -'F SpeciflcGr.vity-1 .13 _'c _'F
'
VrDor Prsue 2ff'C (6S"F)(mHO.......... Vapor Pre$ure 20"C (58'F) (mnHg.......... 0.05
C'hedcd Fuily-Halogenaled hydrocarbon RetdVrDorProre (noia)...........................2-7 Ct€micd Fmily-Glycol Reid Vrpor Pre$ure (psia)........... ... . ... 0.008
v|Dor Pm 46'C (115'F)(Fh)............. 4.0 Vrpor Pre$ure 46'C (lls"D (psia).............---9.!l-
Pol|lttoo Crtegory-USEPA B IMO B VDrDor g-12
lrcufty (Alr : 1.0).......................-... D
Pollution Catcgory-USEPA - IMO Vrpor Density (Air : 1.0)..............,...,..,..,
, 221
ApDllqblc Bulk Reg.,16CFR Subchrpter........ O Solubllltyln wilc.....................-.. Applicrble Bulk Reg.46 CFR SubchaDter........ D Solubility in Water Comolete
Grrdc-C; Flammableliouid Gnde-E: Combustibleliquid
Eletrlql Group-D Electricd Group-D
Geoerd-Tha vapors ar6 iritating. In contscl with a hot surlace, ethylene dichloride deompos€s into Generrl-Slight hazard whsn exposed to heat or llame.
phosgen€,which is highly poisonous.lgnitod by hsat, sparks or open flame.
F l u b P o b i ( ' F ] . . . . . . . . . . . . . . . . . . . . .6. 5
....... F l a h P o i n tC F ) . . . . . . . . . . . . . . . . . . . . 2
. .4. .0. . . . .
Fhnmille Llnlts... 6.2 to 16% Flmmrble Linits.......................... LEL:3.2"/" UEL-unavailable
ArtolgtridonTemD.(F)................ 775 AutoignitiorTemp.("F)................ 775 (antifreezegrade);752 (pur€)
Ertlngtrl.hlng ABeDts CO2, dry chomical, toam, waler fog Extinguirhing Agents..................... COr, dry chemical,alcoholloam, water fog
Flre Prcccdug................ Keep expos€d tanks cool with wator spray. Waltr may b€ iretl€ctive on firs. Sp€cirl Fire Prcedures................Water may be ineffectiveon ti.e. Cool fire exposed tanks with water.
Supply respiratoryprotoction and lull protsctive clothing for lire partjes.

Helth Hr8d RrthEN o|ior Thruhold (pDE) PEL/TIVA (pDD) TLVITWA (pDn) Herlth Hrard Rrdtr83 Odor Threchold(ppm) PEL,/TlryA (Dpn) TLVITWA (ppn)
2,2,3 200' 1 10 0, 0, 1 Unavailable 50 50
carcinogen.Vapor harmful;causs systemic poisoningthrough inhalation.Liquid contact on Genenl-Relatively non-loxic unless ingested. lf ingested,s€rious iniury or doath may result trom as little as 60
skin may cau$ dgrmatitisor a burn. Toxic by inhalalion,skin contact and ing€stion. ml ( a p p r o x . 2oz.).
Symptom-lrritation, diziness, nau$a, rapid pul$, blusness of lips and fingernails. Symptoms-Headache,nausea, and dizziness.
Short Etlare Toleruce-20o ppm for one hour. Short Exrffure Tolermcc-lnhalation is no hazard at normal room temgeratures.
ErDosre PreedueVapor-rsmovo viclim to lresh air; if breathing slops, apply artificialrespiration.Skin or

eye contact+€movs contaminatedclothing and g€ntly flush atfecled areas wilh waler for 15 minules. Get ExDocurePrcedures-lngestion: induce vomiting and call a physician.Never give fluids or induce vomiling if
medical advic€ d attsntion. victim is unconsciousor having convulsions.Skin and eyes: llush with water fo|10 minules.
' NOTE: D€tectableodor is grsatsr
than th€ TLV. Exposur€to potentiallydang€rous vapor concentrationscan
occur b€fore th6 vapor is del€cted by smell.
REACf,IWTY DATA REACTIVITY DATA

St billty-Relatively stabl€. Strbility-Stable.
CrDlottbility-Mrtedrt Non-corosive al normal atmosphoric tomp€ratures when dry. Wh€n contaminaled with Most materials of construction are suitabl€.
waler at elevated temp€ratur€s it corrodes iron.
CrSo: Group 36 of compatibility chart. S€€ also App€ndix l-Exc€ptions to lhe Chari. Crrgo: Group 20 ol compatibilitychart. See also Appendix l-Exceplions to the Chart
SPILL OR LEAK PROCTDURE SPILL OR LEAK PROCEDURE

Wsar rubb€r glovos, 3€lf@ntain€d breathing apparatus, proteclivo clothing. Avoid contecl wllh lhuid. Saqj.o Wear rubber gloves, face shield, protectiv€ clothing. Avoid contact with liquid.
ignilion surces.
uxr{2+tt)2. lf I tplll iNB, cdl th. Nrtlond Rdtonr C.nt.r, t00-a24-t602.

' VT|o. Prc..lr.: ' Ortr
fitr 1o0 mmHg rt 29.4'C. fuulr: rr€ ld th€ pur€" grrdo, not th€ "enti-frszs" grade
I untrt|gned
_.'.fu --.. - '.-

l.16 SCANNED BY MKP 't& BARIS A. 2004 la?
GLYCOLBUTYLETHER
ETHYLENE ETHYLENEGLYCOLDIACETATE
synonyns- 2-Butyl gthanol; Butyl Cellosolve; Butyl 2369
Unit€dN.tionsNuober................................
Synonynr- 1,2-Ethan€diol diacetale; Ethylgne ecetat€; United NrtloN Number .....................
____ii_
oxitol; Dowanol EB; Ektasolve EB Solwnl;
Ethylene diacetale; Glycol discsiat€
Ethanol, 2-buioxy-
CHRIS ('ode. . . . . . . . . . . . . . . . . . .E
. .G
. Y
Fornula-HOCHzCF TOCTHe
171"C 340'F Formuh-CHsCOOCH,CHTOOCCH!
Boilin8 Poirt.. .......... '190'c
o^ oE Bollln8 Polna . 375'F
Appeurnce-Odor-Colorless oily liquid; mild rancid odor --az"c
Fr@zitrg Point . -rzs"r Aplmrrnc-Odor-Colorloss liquid; lainl fruity odor _'c _'F
l'reerln8 Poinl -41'C -42'F
Specific Gravity-O.90
Specific Grrvity-1.13 _'c _'F
vrpor Pre$ure20'C (68"F)(mmH$......... 0.76
Clhemicd Frmily-Glycol ethd 2.2 Valnr Pressure 20'C (6E'D (mmH$.......... 0.3
ReidVoDorPresue (Dslr)........................... Chemical Family-Est€r
Reid Vopnr Pre$ur€ (psla).........
Vrpor Pressur€ {5'C (115'F)(psia)............. ---32-
ValDr Prsure 45"C (ffs'n (Fir)............. Low
Pollution Category-USEPA - IMO lll Vrpor Density(Air : 1.0).............. ............, 07 4
Pollution Category-USEPA - IIUO C VrDor DeNlty (Air : 1.0)......................... t
Appliclble Bulk Reg. 46 CFR Subchpter........ O s o l u b i l i t y i n w a t e r . . . . . . . . . . . . . . . . . . . . .C
. .o
. .m o l e l e D. O 'lo"/o
Applicsble Bulk Reg. 46 Cl'R SubchrDter...... . Solubility in Woiei.........
Grrd+E: Combustible liouid
Grade-E: Combustible liquid
Electrlcd Croup-C
Electrical Group-D
Genenl-Moderale hazard, when exposed lo heat or flame.

General-Moderate lie hazard.
F l s h P o i n t ( ' F ) . . . . . . . . . . . . . . . . . . . . . . . .1. 4. .1. . ( c c )

I l u h P o i n t C D . . . . . . . . . . . . . . . . . . . . . . . . .2. 0
. .5.
Flammable Limits..........................1.1 to 10.6ol"
Fhdmable Limits..........................1.6 to 8.4%
Autoignitior Temp. ('F)................ 472
Autoignition Temp. ('F)................ 900
Extitrgutuhirg A8ents..................... Water, alcohol loam, carbon dioxide or dry chemical.
Extinguishing Ag€nts..................... Contined area-@r, dry chemical. Open area-polar solvent foam, waler log.
SD€ci.l Fir€ Pruedurs................ The same techniques used lor fighting lite involving combustible petroleum
SDecisl Fire PrErduE ................Unavailable
products are applicable. Cool tire exposed tanks with water.

Hslth Haed R.tin8r Odor Threshold(ppn) PELITIVA (ppm) TLV,zT|{A (ppm)
Health Hsard Rrtings Odor Threshold(Dpm) PEL,/TWA (ppn) TLVITWA (ppn)
1, 'l, 2 Unavailable Unavailable Unavailable
0, 0, 0 Unavailable Unavailable Unavailable
General-Eye and respiratorytract irritation,narcosis,blood, kidney, and lo a lesser degree, liver damage can
Ceneral-Low toxicity
be produced in animals from a single or repeated exposuresal concentrationsless than saturation.
SymDtoms-Eye,nose, and throat irritation.

Symptomr-Unavailable
Short ExposureTolerance-20o ppm for approximatelyone hour.

Short ExposureTolerrnce-Animal tests show: No pfimary skin irritation,a trace ol eye injury. Inhalationcaused
no deaths in 24 hour period.
ExDcrrc Prccdur6-Prevent repeated skin contact by wearing protective clothing. ExposurePrcedurs-Vapor-remove victim to lresh air; il breathing stops, apply artificialrespiration.Skin or
eye contact-remove contaminatedclothing and gently llush atlecled areas with water. Call a doctor.
REAC:TIVITY DATA REACIIVITY DATA

general,an inert solvent.
Stability-Stable.
-Mrterial: Compatiblewith usual materialsof construction.Plastic maierials and rubber are not Conprtiblli8-Msterial: Usual materialsot constructionare suitabl€.
recommended.
Cargo: Group 40 ot compatibility chart.

SPILL OR I,EAK PROCEDURE SPILL OR LEAK PROCEDURE

Wear rubb€r gloves, fac€ shisld, protective clothing. Have ell-purpos€ caniater mask availablo. Avoid
Weat lubber gloves, lace shield, protective clothing. Have all-purposs canister mask available.Avoid contact
p€rgonnelconlacl wilh liquid and vapor. Sscur€ all sources ol ignition.
wiih liquid.Secureignitionsources.
lt | .rlll ccrn, cdl |l. fi.tkrml ntDE ( rntcr, tlxl42,f-6g)2.

lt a .Dlll '!sn, cdl th€ N.tl6d
lailtalal
Lcoaalrr llrdvilrl'rlrlI
r tJnlfrgtnrl
lar
SCANNED BY MKP & BARIS A. 2004 1a0
ETHYLENEGLYCOLETHYL ETHER ETHYLENEGLYCOL ETHYL ETHERACETATE
Synonym-Cellosolve Solvent; Dowanol EE; EE Synonync- CellosolveAcelat€i Elhanol, 2-ethoxy-, Unltcd Nrtlons Nunber .. 1172
Solv€nt;Ethanol, 2-ethoxy-;2-Ethoxyethanol; acetate; 2-Ethoxyethylacetat€;Glycol monoeihyl
Ethylom glycol monoethylether; Glycol monoelhyl ether acetais
sther
('llRlS Code................. EGA
Fornule-CHsCHzOCHTCHzOH Fornula-CHTCOOGH.OGHT
BoilitrS Poltrt..... 135'C 275"F
R o l l l n nP o i n t . . . . . . . . . . . . . . . . 156'C 313"F
App€arrnce-odor-Colorlessliquid;ether-likeodor. -'c -"F
F.eezitg Poirt...
-76'C -94'F liquid; ple.sanl frui9 odor -oz"c
Practicallyodorless. FreczlnS
Poltrt. . ......... zs"r
SpecificGdvity-o.93 _'c - 'F Sp€ciflc Grrvlty-O.97
Vrpor Pressure20'C (6S'F) (mnHd.. .. . . ---4-!- Vrlnr Prourc 20'C (6t'!') (mmH8)....... 1.2
ChenicalFuily-Glycol eth€rs ReidVaporPresrure(Dsia)......................... O1 C.||emicrl Fmily-Esler R c l dV r p o r P r r u u r e( p s i r ) . . . . . . . . . . . . . . . . . . . . . 0
. ...1. . .
vapor Pressure46'C (r15'F) (psia)............. -!l-Z-
V.po. Prilurc 46'(' lr5"n ( (pcte).............
C D (Air : 31 ---92-
Pollution Crtegory-USEPA IMO vaDor Density 1.0)......................... C
Pollutlon Crtegory-USEPA - ltlttl v r D o r D a n r l t y( A l r 1 . 0 ) . . . . . . . . . . . . . . ... . . . 4 , 7 2
....... ----9-
ApDlicsbleBulk Reg.46 CFR Subchapter Solubilityin lvlte.....................,.... Comol€ls ADpllc.ble Bulk Res. il5 CFR SubchrDl.r O. O Solublllry In W.tet 23 o/" Aoor€ciable
FIRE & EXPLOSION HAZARD DATA FIRE & I.]XPLOSIONHAZARI) I)ATA

Combustibleliquid Gnde-D: Combustibloliquid
ElectricslGroup-C Electricsl Group-C
Genersl-Moderale hazard,when sxposed to heat or flame. Geocrd-Moderatg hazard,when exDoaedto h€at or flarno.
F t s h p o i n t( . n . . . . . . . . . . . . . . , . . . . . . .1.2. .0. . . . I q u h P o h t C F ) . . . . . . . . . . . . . . . . . . . . .1. .3.5. . . . .

F l a m m a b Ll ei n i t r . . . . . . . . . . . . . . . . . . .1. ...7.t.o. . 1 5 . 6 % Flmnrbfe LfElr!..................... ... LEL 1.7o/" UEL-Unavailable
AutoignitiorTemp.('F)................ 460 Autoi8nitionTemp.('F)............ . . 715
Ertinguishing 4gerts..................... COr, dry chemical,alcoholtoam,water lo9. ErtlnguishingAgentr................. . COr, dry chemical,alcoholfoam,water log
SD€cialFire pr@edur6................The same techniques used tor lighting liro involving combustiblep€troleum SDelrl Firc Pmcdos................ The same techniques used for fighting fire involvingcombustiblepetroleum
products are applicable.Cool lire exposed tanks wilh water. producls are applicable.Cool lire exposed tanks with water.

Hedth H@rd RatinSs Odor Threshold(Dpm) PELAWA (Dpn) TLV,/TWA (ppn)
Hedth Hurd Rrtings Odor Thr6bold (Dpm) PELAWA (Dpm) TLV,/TIYA (pDn)
1. 1. 2 Unavaiiable Unavailable s/Skin
1, 1, 1 0.056 Unavailable s/Skin
Generrl-Low hazard for acute inhalation;moderate lor chronic inhalation. General-Slight skin irilation. More of a chronic systemic hazard from inhalation.
nausea, eye irritalion. Symptorlrdtalion lrom skin contact. Vapor: lritation ol nose and throal.
Short ExposureToleme-Exposure to air saturated with cellosolvevapor (0.6%) for a few seconds resulted in Short Extmure Toleruce-High vapor concontralions can cause nose and throat irritation.
irritationof the eyes.
ExposurcProcedures-Vapor-remove victim to lresh air; il breathingstops, apply artificialrespiraiion.Skin or Er!6ore Pre€dur6-Vapor-remove viclim to fresh air; it breathing stops, apply artificial respiration.Skin or
eye conlact-remove contaminatedclothing and gently flush atfgcted areas with water for 15 minutes.Get eye contact-remove contaminated clothing and gently tlush altected areas with water lor 15 minutes. Get
medical advice or attenlion. medical advice or atlention.

Stsbility-This is a relaiively stable compound. This is a relalively siable compound.
c4nDrtlbitity-Marerisl: Softens rubber and many plastics.Avoid aluminumand its alloyg. Sottens many plastics.
Cargo: Group 40 of compatibilitychart. Crrgo: Group 34 of compatibilitychart.

woar rubb€r glov6s, lace shield, protectivo clothing. Havs all-purpos€canist€r mask $rrlbblc. Avod cotrl,scl Avoid contact with liquid.Secure ignition sources.
with liquid.S€curs ignition sources.
ll I tDill ccrE, cdl lhc N.llond Rqila Cca.r, tqLa2/Hml.

tt . .'all oacsr, 6ll thr N.alon.l ndDtre C.nier, t{10-a2+tll2,
ntrta lulrl
lt0 SCANNED BY MKP & BARIS A. 2004 ttl

ETHYLENEGLYCOL METHYLETHER
ETHYLENEOXIDE
Synonyms- Dowanol EM; Ethanol,2-methoxy-;Glycol
monomethyl ether; 2-Methoxyethanol; Synonyms- Anprolone; Dimethylone oxide; EO; LltrlaedNatloN Nunb€r..... 1040
Melhyl Cellosolvo;Methyl oxitol Epoxyethane; 1,2-Epoxyelhane; Oxirane
('HRIS (ode ...... EOX

Fornuh-CHTOCHzCHzOH
BoilinSPoirt..... . . . . . . . . . . . . . . . . 1 2 4 ' C 255'F Formulr-GHrO
Apperrsrce-Odor-Colorlessliquid; mild, agreeableodor _'c _"F Bolll{ Polnt...... ....... 1l " c 51'F
Fruzing Point... . . . . . . . . . . . . - 8 5 " C - 1 21'F Apparrncc-Odor-Cl€ar, colorl€ss kqudi ether-ltko odor
SpecificGravity-O.97 _"c _'F Ireczing Polnt... -rrrc -too-'p
Sp€cinc Grrvity-0.88
Vrlnr Presure 20"C (68"F) (nnHd.......... 62
Chenicrl Fmily-Glycol ether ReidVrpoi Pre$u.e(pclr).................,.......
0 39 Vlpor Prsu.c 20"C (68"f') (mmHg).......... 1090
Chemicrl Fsmlly-Alkylen€ orkLl
VsporPrsur€ 46'C (lfs'D (Dsit)............. 0.6 Rcld Vrtnt Pr@ure (pdir) .. . . 38.5
PollutionCdegory-USEPA - IMO D VaporDencity(Air = 1.0)...........................
2'62 Vrlnr Pr*ure il5'C (ll5'fl (Dsh)............ 48.0
Polluaion Crtegory-USEPA A lMo # V t D o r D c n s i l y ( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . . . . .1. . 5 2
ApplicrbleBulk Reg.,16CFR Subchrpter....... D Solubility in Wstel Comdsts
Applicrbl€ Bulk Re8. 116Cl'R Subchrpter O Solubilitl in Wraer Comolete

Gnde-D: Combustibl€liouid FIRE & EXPLOSION HAZARD DATA
Eletric.l GroulFC Grade-A: Flammableliouid
Eleclricd Group-B
Generd-Moderate hazard, wh€n exposod to h€at oJ tlarn€.
General-lrritating vapors generated when h€aled. Flammable-does not need orygen for combustion. lt local
"hot
spots" develop in the tank, the liquid in ihe tank may explode
F l a h P o l r t C F r . . . . . . . . . . . . . . . . . . . . .1.1. .5. (. .c.c. )
FhmmrbleLln|ts.......................... 2.5 to 19.8% F l s h P o i n t( ' t ' ) . . . . . . . . . . . . . . . . . . . . .b. e
. .l.o. .w.0.
Autoignition Temp.('F)................ 551 FfsmmableLimits...................... .... 2 lo 1O0"/"
Ertinguishing Agentr..................... COr, dry ch€mical,alcoholfoam,wat€r log Autoignitiontemp. ('F)............ . 804
SpecirlFir€ Prftodrq................ The sam€ techniquesus€d for fighting tirog involving combustibls potroleum ExtirguishingAgents Slop flow ol gas; CO,, dry chemical, water fog
products are applicable.Cool fire €xposed tanks with water. Sp€cid Fire Pr@edur6................lt is important to keep the temperature ol storage tank low; use large
amounts of water. Approach only alter consideringexplosion danger. Keep tirefightingpersonnel behind
cover if practicable.lf the water supply is inadequateor the tank shows signs ol overheating,evacuate the
area.
HEALTH HAZARD DATA

He8lO H@rd Rstings Odor Threshold(ppm) PEL^WA (ppn) TLV,/TWA (Dpn) HEALTH HAZARD DATA
1,1,2 0.9 Unavailable s/Skin Health Haard Rstirgs Odor Threhold (ppm) PEL,zTWA (ppn) TLV,/TWA (ppm)
3,3,2 50 2 9 C F R1 9 1 0 . 1 0 4 7 1
G€neral-Harmlul vapor; liquid absorptionthrough the skin may be harmful.
Gen€.d-Suspsted carcinogen. Moderate hazard, lor both acute and chronic exposures.Volatilityis high and
pulmonary absorption is rapid.
SymptorDrowsiness, confusion,loss of mental atility, headache.
Symptoms-Burning sensation in eyes, nose and throat; dizzinessand headache.
Short Extmure TolemcFunavailabte.

Short ExposureTolerance-2oo ppm lor 30 minutes.
ExpocurePrcedurer-Vapor-remove the victim to fresh air; if breathing stops, apply artificial resdration. Skin
or eye contacl-remove contaminatedclothing and genlly llush atfected areas wilh water for 15 minutss. ExposurePrcedure-Vapor-remove victim to lresh air; if brealhing stops, apply artilicial respiraiion.Skin or
Get medical advice or attention. eye contact-remove contaminaled clothing and gently tlush atfected areas with water for 15 minutes. Gel
medical attention immediately.
REACTIVITY DATA
Strbility-This is a relativelystable compound. REACIIVITY DATA
sttbility-Ethylene oxide's tendency to polymerizeincreases rapidly when the temperalure go€s above 3o'C. lt
will decompose wilh explosive violence whon the temperaturereaches 571"C.
CoDD.dbllity-Mrterld! Sottsns many plastics.
Compatibility-Materirl: EO may polymerizeviolently when in contacl with highly active catalytic surfaces such
as anhydtous iron, tin and aluminum chlorides, gure iron and aluminum oxides and alkali metal hvdroxjdes
Crrgo: Group 40 ol compatibility chart. Oo not use copper, silver or their alloys.
Csrgo: Unassignedin the compatibilitychart. For compatibilityassistance,call
G-MTH-1 eO2-267-1 577\.

Wear rubb€r gloves, face shield, protective clothing. Have all-purposecanEtar mask availabls. Avoid contect
wilh liquid.Socur€ ignition sourcsg. Wear rubber gloves, large heavy lace shield (it in doubt use body shield also) and self-containgdbr€athing
apparatu8. Socute ignition sources. Avoid contact wilh liquid. Flush with la.ge quaniiiies ol water. Do not flush
tprll Inlo contin€d spaces where flammable vapors can accumulale Notity local fire department.
lf r rplll m, c.ll thc Nadill
F.un, crll thc Nillon.l Rc![nie C€nter, tlxL424-tm2.
ll.ul!l
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lo SCANNED BY MKP & BARIS A. 2004 i

ETHYL ETHER 2.ETHYLHEXANOL
Synonyms- Aneslhesiaether; Anestheticether; Diethyl Synonyns- Alcohol C-8; 2-Ethyl-1-hexanol;
ether; Diethyloxide; Ethane, 1,1-orybis-; Ether; 2-Ethylhexylalcohol; Octanol; Ociyl
Ethoxyethane:Ethyl oxide; 1,1'-Oxybisethane; alcohol
Solv€nt ether; Sulluric ether
Formula-CH1(CHr)3CH(CrH")CH,OH
Fomula-(CzHs)rO
Bollltrg Polni.......... _ 183'C 362'F
BolllnSPo1nt.......................... 34'C 94'F q^ oc
ADpeesrc€.odor-Colorlsss liquid: swoet, pung€ni odot _'c _"F App€.rmce-Odor-Colorless, slightly vigcous liquid; -+76"C
ros'f
Frzlnt Po|ni.......... .... -118'C -180'F alcoholic odor F.@zlt8 Polnl........ <
't
Specifi c Gr8vity---o.83
Specific Gravity-o.70 _'c _'F
Vrrpr Prwure 20'C (68'n (mmH3)..........--48- l'ap.r Prrourc 20'c (6t'D a.*-" o*
Chemicrl Fsnily-Alcohol R e i d V e p o r P r $ u r e ( p d t r ) . . . . . . . . . . . . . . . . . . . .0. . .0. 1. .
Chehicd Frmily-Elher ReldVrDorPr{rrc(D.lr).....................1 . .6. ...0.
Vrpnr Prourc r6'C (f lf'F, (Fl.)............. 23O VaporPrwure 46'C (tls'n (Dctr).............0.015
B lll Pollution Cste8ory-USEPA - IfU<f @ C VeporDculty (Air : 1.0)........................... 4.5
Pollution CateSory-USEPA IMO V . t o r D c u f a y ( A l r : t . 0 ) . . . . . . . . . . . . . . . . . . . . .2. ...5. .5.
Applicable Bulk Reg. 45 CFR Subch4ter........ O Sofubllltyh W.acr ... 7.Oo/o Appliceble Bulk RG8. il6 CFR Srbchrpter........ O. O S o 1 u b i | | t y i t r w r t e r . . . . . . . . . . . . . . . . . . . . . . .S. .l i o h t
FIRE i} EXPLOSION HAZARD DATA FIRE & EXPLOSION HAZARD DATA

Grrdc-A: Flammableliouid GradeE: Combustibleliouid
Elecdcd Group-C Eletrisl GrouF-D
General-A highly llammable,volatils liquid with a wid€ explosiverange end low auloignitionl€mpsature. G€Derd-Moderate heard, when expos€d lo heat or llame.
Flashbackalong vapor lrlil may occur. Vapor may sxplods il ignlled in an onclosed ar€a.
F l u h P o l n t( ' F ) . . . . . . . . . . . . . . . . . . . . .-.4. .9. . . . . Flsh Point CFr..................,..........

179
Flannrble Linits.......................... 1,85to 48.0% Flmmable Limits..........................
Unavailabl€
Autoignition Tenp. ('F)................ 356 AutoigritionTemp.("F)................
581
Extinguishing Agents..................... COr,dry chemical,alcoholtoam,waterfog ExtirgutubirgA8ents.....................
Alcoholfoam, Co,, dry chemical,water spray
SD€cialFire Procedures................ Cool tank with waler spray. Ko€p surroundingscool to reduce the amount ol Specid Fire Prcedu6................ Cool exposed lanks with water.
vapors produced.The danger ol reignitionis high.

Health H@rd R8tings Odor Threshold (ppm) PEL,/TWA (ppn) TLV,/TWA (pDn) Healt} H@rd Rttltr8s Odor Thrcbold (ppm) PEL,/TWA (ppn) TLV,/TWA (ppn)
1.0.2 1 400 400
1, 1, 1 Unavailable Unavailable Unavailable
ether is a volatile liquid possessingirritalive and narcotic properties.Absorption ol excessive Gererrl-Practically non-hazardous.Slight etfect from absorptionol liquid through skin.
quantiliesby any route may l€ad progressivelyto a state ol intoxicalion,loss ol consciousnessand death
due to respiratoryfailure.
symptoms-Exhilarationmay be experiencedfirsl followed by drowsinessand unconsiousness. Contact with Symptoms-Mild skin itritation.
the skin may cause dermatitis.
Short Exlmure Tolermce-1000 ppm tor 30 minutes. Short Erluure Tolersnce-Not pertinent
ExposurePrcedur6-Vapor-remove victim to tresh air; il breathingstops, apply artificial respiration.Oxygen, ExposurePrcedura-Vapor-remove victim to tresh air; il breathing stops, apply artiticial respiration.Skin or
when adminisloredby trained personnel,is helplul. Skin or eye contact-remove contaminatedclothing and eye contact-remove contaminatedclothing. Flush affected areas gently with wal€r lor 15 minutes; 20-30
gently flush atfected areas with water for 15 minutes.Get medical advice or attention. minutes lor eye contact. Get medical attention.
REACTIVITY DATA REACIIVITY DATA

Strbility-ln the presence ot air, ether forms ethyl peroxide,which may explode if heatsd. Strbility-Will undergo sell-reactionif contaminated.Does not require stabilizer.
ComFtibility-Mrterial: Compatiblewith most of the usual materialsol construction.Ether swells natural Usual materialsof conslruction are suitablo.
rubber, so protectiveclothing should be made of plastic which resists ether.
Cargo: Group 41 ot compatibilitychart. Cargo: Group 20 ot compatibilitychart.
SPILL OR LEAK PROCEDURE SPILL OR LEAK PR(rcEDURE

W€ar rubber gloves, large heavy fac€ shield (it in doubt use body shi€ld also). Havs s€ll-contsinedbreathing Avoid contact with liouid.
appantw aveilabl€.Avoid conlact with liquid. Ssure all agnitionsources. Do not llush spill inio confined lprces
llammsble vapors can accumulato. lf a spill occurs into navigabl€ wator, tha sthar will tloal dtwnetarm
and crsat€ a wete tir€ hazard until il h6s all vaDotizod,
lf r rdll coB, cdl the Nrtlonrl tfi)-424-8t02.
lt . rDlll @cu1 crll thc Nrtlond R6Dom C.nlcr, tlx){24-tt02.
lxryfr n.m&kr: t Unr8Signed
_ . . _ . - . . . - . . _" @
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tta SCANNED BY MKP
* l & BARIS A. 2004 t55
2.ETHYLHEXYLACRYLATE 2-ETHYLHEXYL NITRATE
Synooyu- Acrylic scid, 2-ethylhexyl ester; Synonyns-Alkyl (C7-Cg) nitralest Mixed octyl nitrates; United Nrtions Number. ____t_
z-Elhylh€xyl, 2-prop€noate; Ociyl acrylats Octyl nitraies
CHRIS Code ONE
Formula-CHz : CHCOTCH,CH(GHs)C4H, Formuh-CHrCHrC,'H' rNOr

'83"C '362"F
Boiling 215-21A"C418-425'F
Point.......................... Boililg Point............. ....
Appeerance-Odor-Coiorless liquid; pleasant odor --gs'3 ADp€srnce.Odor-Light yellow liquid: ester, fruity odor Decomposesbetore'C boilinq'F
Freezins
Point..........
. *:F F r e e z i n gP o i n t . . . . . . . . . . . . . . . . . . . . . . . 17'C 58'F
Specilic Grrvity-O.89 _'c _'F Specitic Crrvlty-o 96 _"c _'F
Vapor Ptwure 20'C (68'F) (mmHg).......... 0.1 VaporPressure 20"C(58"1')(mmHd..........--qO4-
Ctemical Frmily-Acrylate Chemlcrl l'rnlly-NrkaleS ReidVaporPressure (Dsia).
Reid Vlpor Presure (p6ir)........................... 0.01
Vapor Presure 46'C (lf5'D (Dsir)............ 0 015 VsporPressur€ il6'C (l15"F) (psia).............0 31
Pollution Crtegory-USEPA - IMO B VsDor Density (Air : 1.0)........................... 6.35 Pollutlon Crtegory-l lsl:t'A - IMO B VsDorDensity(Air : 1.0)..........................6
Applicrble Bulk Reg. ,15 CFR Subchapter........ ---9.- Solubility in Wrter......................... Neolioible Applicrbte Bull Rcg. 46 ( l,R Subchrpaer O S o l u b i l i t y i D W a t e r . . . . . . . . . . . . . . . . . . . . . .O
. ...O 2
FIRE & EXPLOSION HAZARD DATA I.'IRE & EXPLOSION HAZARD DATA
Grrde-E: Combustibleliouid Crrde-E: Combuslrblo ||aurd.
Eletricrl Group-D Elctrlcal (,lroup-NA
Generrl-Moderate hazard,when exposed to heat or flame; will polymerizeon heating. G€ncrd-Combustibl€-grvss oll loxrc nrlrogon oxrd€s, carbon monoxide, and carbon dioxide gases when
healed or burnsd
188 (cc)
Flsh PointCF)............................. FlDh Point ( l') ................ 175 lccl
Fl.mmsbleLimiis..........................
LEL:0.87. UEL:6.4% Fhmmable Limiis............... LEL 025ol" UEL-Unavailabl€
485 Autoigniiion Tenp. ('l')......... . 256
Extirguishing Dry chemical,CO2,toam, watgr
A8crti..................... ExtinguishinS Alcntr.. .......... Wator log, loam, dry ch€mical, Co,
SDeirl Fire Prc€du6................ Water or foam may caus€ frothing.Cool exposed tanks with watet sDccirl Fire Prcedurer ........... Avoid brealhlng vgpor Can oxplods if h€ated while conlin€d-cool storage
container with waler.

Health H.Ad Rrtings Odor Thr6hold (Dpm) PEL,/TWA (ptn) TLV,/TWA (ppn) Health Haard Rrtlngs Odor Threshold(ppm) PELITWA (ppm) TLV,/TWA (Dpm)
Unavailable 'l to 10
0. 1. 1 Unavailablo Unavailable Unavailable Unavailable Unavailable
General-Liquid irritatingto skin on contact. General-When heated, decomposes to lorm nitrogen oxides. Low loxicity by ingestion and inhalation;slightly
toxic by skin contact.
Symptoms-Skin irritalion, Symptoms-Mild skin and eye irritationon contact. Inhalalion produces headaches,dizziness,nausea, and low
blood pressure.
ExIGure Tolermce-Unavailable Short ExnpsureToleranc€-Low heallh risk from inhalation unless lhe liquid is heated lo decompositionor mist
is formed.
ExDosurePr@edur6-Vapor-remove victim to lresh air; il breathing stops, apply artiticial respiralion.Skin or ExposurePrGedures-lngeslion: lf conscious, drink water, induce vomiting. Inhalation:Remove to fresh air. Skin:
eye contacl-remove contaminatedclothing and genily llush wilh water, Flush with soap and water. Eyes: Flush wilh waler tor at least 'l 5 minutes.

Stebility-Unstable; polymerizeseasily unless inhibiled. St.bility-Stable at ambient temperature,decomposes when heated. Can explode il hea'tedto high
temperatureswhile confined. Reacts with strong oxides, strong bases, strong reducing agenls.
Compatibility-Mrterisl: Non-corrosiveto carbon steel. Compatibility-Mrterisl: Suilable: Mild steel, stainless steel, aluminum,copper, zinc, tin, brass, bronze,
neoprene, nitrile rubber. Unsuitable:Butyl rubber, ethylene-propylenerubber.
Cargo: Group 14 ot compatibilitychart, Cargo: Group 34 of lhe compatibilitychart. See also Appendix l-Exceptions to the Chart.

ll possibl€,w€ar rubber glovos, tace shield, and proifftiv€ clothing. Have all-purpole canill,ar mad( avalhlb. Avoid contact, especially vapor. Secure all ignition sources. Wear goggles and neoprene or nitrile
S€cure ignition sources. Fluah spill away with wal€r. glov€s-use self-contained brealhing apparatus il neded. Dike spill, soak up with sand or earth; dispose by
controllod burning.
lf | .plll lf r rDlll occurs, crll the N.ilorll C€nter,E0O-42,LEm2.

'l1)lynx{t?oa Rrmr;lrr' ll(r{)trllx)\r|()n l)ornl
leulr;
lL.,nall|gnod I trrIvrthl,lo
SCANNED BY MKP & BARIS A. 2004 r7

Synonynr- 5-Ethylidenebicyclo(2,2,1
ETHYLIDENENORBORNENE
)hept-2-ene;
l l Synonyms- Ethyl 2-melhacrylate;Ethyl
ETHYL METHACRYLATE
U n i t e d N s t i o n s N u m b e r . . . . . . . . . . . . . . . . . . . . . . . . . . . .2. 2
. .7 7
Elhylidenenorbornylene;Ethylidenenorcamphene alpha-methacrylate;Ethyl 2-methyl-2-propenoate;
l l Melhacrylic acid, ethyl €sl€r; 2-Propenoicacid,

2-methyl-,eihyl ester
CHRIS Crde.......... . ETM
Formula-GHrr Formule-CTHTCOOQHs
Boilirg Point.......................... 148:9 ,98::
B o i l i n g P o i n t . . . . . . . . . . . . . -. . . . . . 117'.C 243".F
ADD€rrrnce.Odor-Colorlessliquid with a iurpentine-like -go'c Appemce-Odor-Colorlsss liquid: sharp unpleasant --
ooor FreezingPoint......... . rrz'r ooor Freezing point......... so'c sa"r
Sp€cificGi8vity-0.90 -'c -'F SpecificGravity-0.92 _'a _'F
VrDor Pressure20"C (6S'F) (mmHg)..........-l5L- VclDr Prsure 20'C (68'F) (mnHg) ...... . 15
ChemicslFmily-Oletins ReidVaporPressure (psia)...........................0.23 Chemicrl l'rmily-Acrylates
Reid Vapor Presure (p6ia)......... . . . O.77
VaporPressure,l5"C (115"F)(Dsir).............0.33
Valnr Presure ,16'C (t15"F) (psia)............ 1.0
PollutionC.tegory-USEPA - IMO B Vepr Deroity(Air : 1.0)........................... 41 Pollutioo ClteSory-USEPA C D
tMO Vspor D€rsity (Air : 1.0).................... 3.94
ApplicableBulk Reg.46 cFR Subchspter........ O SolubilityinWater......................S . . l. i o h t ApplicsbleBulk Rcg. it6 CFR Subchrpter....... O Solubility in Wat€r........... .. .. . Neolioible
Combustibleliouid Grgde-C: Flammable liquid
Electricrl Group-C Eletrical Group-D
-Dangerous lire haard. Ceneral-Fire may cause violent rupture of tank due to polymerization.Ftrms explosive mixtureswith air in the
presence ot heat or flame. Flashback along vapor trail may occur. Vapor may explode il heated in an
enclosed area.
F l $ b P o i r t C n . . . . . . . . . . . . . . . . . . . . . .9. 6. . . . . . F l s b P o i n t( ' F ) . . . . . . . . . . . . . . . . . . . . .7. 0
.......
Fhmmble Lio|ts.......................... 0.9 to 6.4% Ffumrble Linits.......................... 1,8o/o lo saturation
Autoignltlon Temp.('F)................ 522 AutoignitionTenp. ('F)................ 740
Extin8uiEhing A8entr..................... Carbondioxide,dry chemical,loam EttlrSubhinSA8ents..................... CO,, dry chemical,chemicaltoam
sD€cid Fire Prqedur6................ Wear prot€ctiveclothing. Water may be inottsclive on firs. Cool exposed Speid Flre Prced|rc................ Easily forms explosivgs mixtureswith air. Remove all sources of flames,
conlainerswith waier. sparks or other ignilion sourcss. Electricaldevices should be grounded and bonded. C@l tanks wilh warer
tog.

Health Haard Ratingr Odor Thrshold Opn) PEL^WA (ppd TLV,/TWA (DDn) Heslth H.ed Rlttngs Odor t'hr6hold (ppm) PEL,/TWA (ppn) TLVAWA (ppmr
3. 1. 4 0 . 0 0 7t o 0 . 1 4 5 5 1,1,2 Unavaitabte Unavailable Unavailable
c€ned-Moderate skin irritant. Excessivecontact with skin should be avoided. G€nerd-Moderately toxic, liquid causes skin irritation.Vapors mildly irritating.
symptmFlnhalation-vapors cause headache,dizziness,naussa, vomiting and respiratorydistress. Symptoms-Skin allergy develops,vapor causes corneal ulceratron,visual disturbance,irritationto resDiratory
lngestion-irritation of entire digestivesystem. lrritates eyes and skin. tract, lack of appetitie,nausea, convulsion, coma.
Short ExDosureTolerrnce-Prolonged exposureto vapor proved toxic to rats. Shoft ExposureTolerarce-1 00 ppm over 8 hours. Animal tests show ellects are not cumulative.
Erpcure Preedures-Remove contaminatedclothing and llush affected areas with plenty of water tor at least ErDque Prm€dur6-Remove victim to fresh air. lmmediatelyflush atfected area with water, use mild sap and
15 minutes.Remove victim to fresh air. Administerartilicial respirationil necessary. lf ingested,induce
fl
water for skin exposure. Experimentshave shown Ethyl Methacrylatelo be a teratogenithis means lhat
vomiting.Get medical atlention. physical detects can be produced in the devetopingembryo.
REACTIVITY DATA REAC'TIVITY DATA

stability-Slable al t€rmperaluresbelow 200'C, bul unstable above 350"C, decomposingrapidly in presence of Stlbility-Polymerizes; inhibitorrequired. Can react with oxidizingagents. Ground storage drums or lanks to
ai(. prevent accumulationof stalic eleclricity.
CoDpatibility-Mrterisl: Non-corrosiveto steel, stainless siel and aluminum.Glass, "Teflon" and ceramics are Compotibility-Materisl: Glass, types 316 and 304 stainlesssteel, or aluminum are suitablo;corrosive to mild
acceotable. steel.
C.rgo: Group 30 ol compatibilitycharl. See also Appendix l-Exceplions to the Chart. Cargo: Group 14 of compatibilitychart.

W€ar butyl rubber gloves, lace shield and protectivs clothing. Secure ignition sources. Protective clothing, goggles, neoprene gloves, sell-containedbreathing apparatus should be worn. Flush spills
with water tog. Dike flaming pools and extinguishusing chemical foams. secure ignition sources.
lt 8 sDlll ecun, crll the Nstionil RoDou Centcr. dX!.02!t{12. If r lplll ccm, cill the Natioral Center
naorrki: I Unessigned Renerlr:
I
N
2.ETHYL.3.PROPYLACROLEI FORMALDEHYDE
SOLUTIONS(37 to 50olo)
Synonyns- 2-Ethyl hexanal; 2-Ethyl-2-hexanali U n i t e d N a t i o n s N u m b e r . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .:.t. Synonyms- Formalin; Formalith;Formtc aldehvde UnitedNrtions Number...solutions 22Og
2-Erhyl-3-p.opyl acyraldehyde solutaon;Formol; Fyde; Methanal sotution; flammablesoln. 1198
Methyleneoxide;Morbicid
CHRIS Code . EPA ., FMS
Formula-GHzCH : C(C,HI)CHO Formula-HCHO

Boiling Point....................... 175'C 347'F Bolllng Polnt . . j u z u o T
-g'c -t'c -'r
c ^
Appearrnce-Odor-Yellow liquid; sharp, powertul, ApDerrance-Odor-Colorless liquid; pungent, irritating

irritating odor Freezing Po|nt..........-.......... s8"r odor F.cezlng Poina.
SDecific Grrvity-o.85 _'c _'F SpecilicGravlty-1.11 to 1.13 _'c _'F
Vrpor Prrcure 20'C (63'D (mmHg).......... -il- Vrgor Presure 20'C (68"F)(mnHd .......... 1.3
Chemicd Fmlly-Ald€hyde
Chedicd Frmily-Aldehydo R c l d V o p o r P r e s r r u ( D . i r ) . . . . . . . . . . . . . . . . . . .0. ...0. 7 ... Reld Vrpr Pr@ure (pcir).............. 0.09
Vr;pr Presure 45'C (115'D (prir1.............---9J2- Vspor Pr6ur€ a6'C (tls"D (Drir) 0.15
Pollution Cat€gory-USEPA - tNtO B veor )endty ( A l r : 1.0)...................... ... 4 . 3 5 Pollutior Crtegory-USEPA - ItrlO C V s D o r D e n r l t y ( A i:r 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .1. . .0. 3 .
Applicsbl€ Bulk Reg. 46 CFR Subch.pter..... . O S o l u b i l i t y i n w r t e t . . . . . . . . . . . . . . . . . . . . . .N. .e o l i o i b l e ApplictbleButk Reg.,16CFR Subchapter........ O S o l u b i l i t y i n W a t e r . , . , . . . . . . . . . . . . . . . . .C. .o. m o l e t e
urao€-E: uomousl
Combustibleliouid Grade-D or E: Combustibleliquid (grade depends on concentration)
Elcctrical Group-C Electricil Croup-B
hazard.when €xoosed to h€at or flame. General-When the solution is heated, highly flammable vapors are given off.
F l s h P o l r t C F ) . . . . . . . . . . . . . . . . . . . . .1.5. .5. . . . . F l G h P o i n l( " D . . . . . . . . . . . . . . . . . . . . . 1. .2. .2.l.o. . 1 8 5

Flammable Limih.......................... Unavailabls Flmmable Limits.......................... 7.Olo 73o/o(formaldshyd€vapor in air)
AutoignitiorTemp.('F)................ 392 AutoigritionTenp. ('F)................ 806
ExtirguirhingAgents..................... CO1,dry chemiml,water log, alcoholloam Extitrguishing Ag€rts..................... COr, dry chemical,alcoholloam, water fog
Specid Fire Preedu.6................ The vapors ol this chemical are highly irritating.For this reason, respiralory sp€cisl Fir€ Preedures..............,.The vapors are highly irritating,so fire parties should wear respiratory
protectionis necesary. In other respects,firefightingtechniqueswill be the same as lor a Grade E protection.
petroleumproducl.

Herlth H@rd Ratings Odor Thr6hold (ppm) PELAWA (ppn) TLv,/TlryA (ppn) Ilerlth Hred RstinSs Odor Thrahold (ppm) pEL,/TtryA (pDn) TLV,/TWA (ppm)
3.2.2 Unavailable Unavailable Unavallable 3,2,3 belowl 3 t-
Gen€ral-Vapor is irritatingto respiratorypassages.Liquid irilating to skin. General-Susp€cted carcinogen.Major €ftect is local irritationol ayss, nos6, and throat. Strong formaldehyde
solulions caus€ a hardgningstfecl and primary skin arritationupon direct contact.
Symptoms-Burningsensaiion in respiratorypassages or on skin in contact with the liquid. Symptoms-Coughing,copious walaring of eyes, sevgre respiratoryirrilalton.
Short Expcue TolereUnavailablo short ExpnsureTolerrnce-Al a vapor concenlration of lO to 20 ppm breathing becomes difticult. Exposure ta
650 ppm lor a few minutes may cause dealh.
ExposurcProc€dures-Vapor-remove victim to lresh air; il breathingstops, apply artificial respiration.Skin ot Exp6ure Pr@edures-Vapor-removs victim to fresh air; il breathing stops, apply artilicial respiration.Skin or
eye contact-remove contaminaledclothing and gently flugh atlected areas with water lo|I 5 minutes.Gel eye contact-remove conlaminated clothing and gently flush aftected areas wilh water for 15 minutes. Get
medical advice or attention. medical advice or attenlion.

Stlbility-Stable. Stability-Solutions are often shipped al elevated temperaturesto prevent polymer lormation.
ComlEtibility-Meterid: Unavailable ComFtibility-Msterialr Corrosiveto steel and to copper and ils alloys.
Cugo: Group 19 ol compatibilitychart. See also Appendix l-Exceptions to the Charl. Cargo: Group 19 ot compatibilitychart. See also Appendix l-Exceptions to the Chart.

Wsar rubb€r gloves, sell-conlained breathing apparatus, protective clothing. Avoid contacl with liquid. Small Wear rubber gloves, selt-containedbreathing apparatus,prolective clothing. Avoid contact with liquid. Sscur€
spills may b6 washed away with waler. For large spill, cover with sodium bisullite (NaHSOt. Add small amounls rgnition source. lf possible, cover large spills with sodium bisullite (NaHSO3).Add small amount ol water and
watgr and mix Scoop up. Wash siie with soap solution. mrx.Scoop up. Wash sile with soap solution.
ll r Dlll ccun. oll th. N|tlDml RrDnr (intcr, 0Ol{A-$02, If r rplll ccurs, csll the Nstional Center, tlX!.42F86112,
n6rrl.: n.n..kt: Thg commeacial mat€rial ts shigpgd as wat€r solution ol lrom aboul 37"/o lo 5O7o concenlralton
lUnassrgned
Melhanol is ottsn ussd to Inhibit potymorizatron
'
P.oposed chango In TLV to 0 3 ppm
lUntvrtlrble

I f{) r6l
FORMICACID FREON
Synonyns- Formylic acid; Hydrogencarboxylic acid; United Nations Numbar _lll9_ Synonyr Genetron; lsolron; Haloni Relrig€rantgas;
Msthanoic acid ucon
CHRTS Code........... .... FMA

CtlRlS Codc
Formula-HCOOH Fornulr-'S€€ "Remark!"

b€low. 'C
Boiling Point........... C 213'F
Boiling Polrt........... -'F
App€ar.nce.odor-Colorless liquid; sharp, penelrating -a''3 Appemcc.Odor-Colorl€ss liquid d gas; sweelish --variJs'3 -'F
ooor FrezinsPoint......... . .""i
odor F*rlns Poin..........
Specific GrsYity-1.22 _'c -'F SDelllc Grrvlty-above 1.0 _'c _'F
Vapor Prwure 20"C (6S'F) (mmHg).......... --i-S- v.Ip. Pressurc 20'C (68'F) (mmHg)........ Varies
C'hemical Family-Organic acid ReidVaporPrwure(psia)...........................'1.5 Ctenicrl Fmlly-Halogenated compoundg Reid vlpor PrNure (!Eir)......... Varies
Valnr Presure il5'C (r15"F) (poie)............. ---2J- v.Dor Pressure 46'c If 15'n (psis).............-Jgdgs-
Pollutiotr Crtegory-USEPA D IMo D V r p o r D e n s i t y ( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . . . . .1. . 6 oasos
Pollution Cricgory-USEPA - IMO vspor Density (Air : t.0)..........................90--0!-!09!9
Applicable Bulk Reg. ,16 CFR Subchapter ........ ----L SolubilityinWater......................... Comol€te ApDlicrbleBulk R€g.il6 CFR Subchrpter........ O Solubilityinwater......................... Neolioible
crrde-E: Combustibleliquid. GmdeNA
Eletricd Group-D Eletrical Group-NA
Cener.l-Formic acid is a corrosive,combustibleliquid.Toxic vapoB ate gen€rated in fir$. Genersf-Freon 11, 12, and 114 do not burn. Freon 22 and 113 when heated can form weakly combustible
mrxlures.
F l s h P o i DCt D . . . . . . . . . . . . . . . . . . . . . 1. .5. .6.(. c c ) Flsh Poirt ('n.............................

Non-flammable
Ffammable Limits.......................... 18 lo 57"h FlammrblcLimits..........................
Non-llammable
AutoignitiorTemp.('F) ................ 1114 AutoiSritiotrTemp.('F) ................
Nonjlammable
ExtinSuishing A8ents..................... COr,dry ch€mical,alcoholfoam,water tog Extinguishing A8ents.....................
Nonjlammable
SpecialFire Procrdur6................Firetightingparties should wear rubber boots and gauntlels and self-contained SDecialFire Prcedurd................ In conlaci with hot surfaces or a naked llame these compounds form
breathingapparatus. phosgene, an extremelypoisonous gas. Keep tanks, adjacent to fire, cool with water spray. Fire lighters
wear full protectiveclothing including self-conlainedbreathing apparatus.

H€rlth Hsard RrtirSs Odor T}rehold (ppm) PELAWA (ppm) TLV,/TtryA (ppn) Hedth Hurd RrtinSs Odor Thrdhold (ppm) PELITWA (pDo) TLVAtryA (Dpn)
3.3.3 Unavailable 5 5 Unavailable Unavailable Unavailable 1000
G€nerrl-Nalural, slow decompositionyields carbon monoxide (CO), a chemical asphyxiant,and waler. Getrerd-Vapors are non-irritatingto eyes, nose, throat, lungs, and skin, very low toxicity.
Enclosed spaces must be tested for orygen conteni (19.5ol"min.) belore entering.Vapor irritating.Liquid
causes burns.
Symptoms-Choking,respiratoryitritation,watering of the eyes; skin contact will cause severe itching or burning SymptorDrowsiness with or wilhout nausea.
Short ErD6ure Tolerurunavailable Short ErDsure TolemcelO,o00 ppm for 5 minutes.
ExpogureProcedurc-Vapor-remove victim to fresh air; it breathingstops, apply artiticial respiration.Skin or Expcure Prmedurs-Remove victim to fresh air. lf breathing stops, apply artilicial respiration.Get medical
eye contact-remove contaminatedclothing and immediatelyllush alfected areas genlly wilh water for 15 attention. ll the liquid has spilled onto the skin, points of contact may be trostbitten, handle gently and
minutes.Gel medical atlention. Use protectiveclothing to prevent personal contact. protect lrom mechanicaldamage. DO NOT RUB. Get medical attention.

Strbility-Reacts will bases (alkalis)lo produce heat. lt is also a reducingagent. Strbility-Chemically stable, but see Special Fire Proceduresabove.
Compstibility-M.t€rill: Type 316, stainless steel or lead-linedtanks are stisfactory. Conprtibility-Msterial: Compatiblewith most mateJialsof construction.
Cugo: Group 4 of compatibilitycharl. S€€ also Appendk l-Excsptions lo ths Chad. Crrgo: Group 36 ol Compatibilitychart.

Avoid contact with liquid. Us respiratoryprotection and protsctivs clothing. Eliminate all surco! ol agnllmrl Avoid contact with liquid. Th€ liquid may boil away (ss bclor) at ambiant tamparrluro. Extrngurchopon
contaminated surlaces and spill wilh larg€ quanlilies ot loda ash or sodium bicarbonat€. Mix end edd llatnoS in viciniiy ol lh€ spallin order to avoid generationot phoagana.
it necessarytor good mixing.Scoop up slurry.Wash sil€ with soda lsh solulion.
lf I tplll 6c[r, cdl the N.llo..l (trlcr, (..t.r.

ll . rDlll r.crrr, crll tb. N.tl.[rl n!r6, t|n al. ||lll
Rcnrrlr: 'l
U.n..l. !iltilf I turtt 4UU)
(.(.t,1 | | tt3 r /l tr | t( |
c(itrf r ta ral ,l lt (x,l
(lrllr ,t ril ar a U(:F
( , c|?. trt ,l r lllO I It
SCANNED BY t6l
MKP & BARIS A. 2004 ,.1
| (:tt. I ta r:ll{ t ) tI
lc.l
FURFURAL FURFURYLALCOHOL
SynonyrAnt oil, artilicia'; Artiticial oil ol ants; Fural; United Nrtions Numbcr................................1199 Synonyro-2-Furancarbinol;
2-Furanmslhanol: 2474
UnitedNationsNumber................................
2-Furaldehyde;2-Furancarbonal; Furylcarbrnol:
Furfuralcohol: 2-Furylcarbinol;
I
2-Furancarboxaldehyde; Furluraldehyde;FurluJan alpha-Furylcarbrnol:
2-Furylmethanol:
I
carborylic aldehyde;Furlurole;Furols; Pyromucic | 2-Hydroxymethylluran
aldehyde CHRts Code........... .... FFA CHRIS Code FAL
Fornuh-CTH.OCHTOH
Formula-CTHTOCHO
""1,
' o t f f t r g P o i n t . . . . . . . . . . . . . . . . . . . .1. .6. 1. Appeararce-odor-Colorless-amb€r liqud turning to Bollln8 Poin.........................
.. 171'C 340'F
Apperrance-Odo.-Colorl€ssto r€ddish-brownliquid;
"c "F
dark red-brownwhen €xpos€d to light and ail
J7:3 :r-'F "C
penetratingalmondlike odot Freztns Potnr......... .. Slight brineiike odor. FEzfnB Pofn4......... 31 U"f
SDecificGrrvity-1.20 _'c _"F SpecificGrrvity-1,29
vrDor PErrc 20'C (6s"D (mmHd.......... 1 53
chemrcsr
Fsmiry-Arcohor -.i,
Ctenicsl Fsmily-Aldehyda ReldV4nr P6ure (D.lr)........ . . . ... 0.1 1"":l
x:il'"ffffi"11;:11"1"?
^ Vrlpr Pwurc,l6'C (ll5'l) (psir)............. ---QJ5- ^ vrlor Pr$ure,l6'C (lls'D (Dsir)............ 0.1
Pollutio.Cstegory-USEPA D IMO C vrDor D.nrtiy (Atr = f.0).............. .. ... 3.31 PollutionCsteSory-USEPA- IMO ---L- 3.37
V.tpr DcNtty (Air : 1.0)..........................
ADDlicrbleBulk Re& {5 CFR Srbchapter....... O fiolubllliyln wrter . . ................... 8.3% ........ O. O
AppllcableBulk Reg.a6 CFR SubchrDter solubiliiyin wster......................... Comolete
Grrde-E: Combustibleliouid GradeE: Combustibleliquid
Electricrl GrouD-C ElectricalGroup-C
Genersl-Moderate hazard,when exposed to heat or tlame. Furluralcan explode on contact wilh strong mineral General-Slighl explosion hazard when exposed to heat or llame. However ii will react with explosive violence
acids and alkalis (caustics).lrrilatingvapors are generatedwhen heated, in contact with mineral acids or their vapors, or with strong organic acids or lheir vapors.
F l s h P o i t r (t ' n . . . . . . . . . . . . . . . . . . . . . .1.5. .5. . . . F l s h P o i n t( " n . . . . . . . . . . . . . . . . . . . . . .1. 6

. .7. . . .
FhmmableLimits.......................... 2.1 to 19.3'l. F l m m a b l eL i m i t s . . . . . . . . . . . . . . . . . .1. ...8. t. o. . .16 . 3 %
AutoignidmTemp.CD ................ 743 AuioiSnitionTemp.("F)................ 916
Extinguisbing Agetrts..................... COr,dry chemical,alcoholfoam,waterfog ExtinSuishing Agents..................... Conlinedarea-Cor, dry chemical.Open area-polar solventtoam, waler
SpecislFire Prcedurs................ Wear eye protection,sell-containedbreathingapparatus and prolective spray.
clothing. SpecialFire Prccedures................ Wear eye protection, clothing resistantto furfuryl alcohol, respiratory
proteciion.

Herlth Hsard Rstings Odor Threshold(ppm) PELAWA (ppn) TLV,/TWA (Dpm) Health H.ard RathSs Odor Threshold (ppm) PEL,/TIVA (ppn) TLV,/TWA (Dpn)
2.2.3 0.4 2/Skin 2/Skin 2.1.2 I lo/Skin 1o/Skin
General-Liquid is irrilatinglo skin and eyes on contact. Vapor is respiratoryirritant. Genersl-Skin absorption may cause toxic etfocts. Harmlul if swallowed.Toxic concentfationsot vapors may be
present at lemperaturesabove room temperature.
Symptoms-lrritationof rospiratorypassages. Symptoms-Headaches,watering eyes, irritated skin.
Short ExposureTderme-l5 ppm for 15 minutes. Short ExDosureTolerancFvapor exposures-Rab shil 8 percent mortality atter one six hour exposure to 47
ppm and 100 percent mortalityal 243 and above. Absorptionthrough skin is very rapid.
ExIGure Prcedures-Vapor-remove victim to fresh air; if breathingstops, apply artificial respiration.Skin or ExposurePrcedures-Ey€s-wash with water for 10 minutes.Bemove contaminated clothing and wash.
eye contact-remove contaminatedclothing and g€ntly flush aitected areas wiih water tor '15minutes.Get Skin-wash with soap and water. Ingestion-induce vomiting. Inhalation-move to lresh air. Get medical
medical advice or attenlion. advice or attention
REACIIVITY DATA REACTIVITY DATA

Strbility-Furfural can explode on contact with strong mineral acids and alkalis. Reacts with numerousorganic Stability-Stable. Reactivewith organic or mineral acids.
materials.
Comp8tibility-Material: Dissolvesor sottens many plastics and rubb€r formulations. Com!trtibility-Msterial: Do nol use n€ar lacquers,varnish, or resins. Can ship in ordinary steel.
Crrgo: Group 19 ol compatibilitychart. Crrgo: Group 20 of compatibilitychart. See also Appendix l-Exceptions to the Chari.

Wear rubbs gloves and proteclive clothing. Have self-containedbresthing apparatG available.Avoid contacl Wear rubber glovss, face shield, protective clothing. Have ail-purpose canister mask available.Avoid contacl
wilh hquid.Small spills may be washed away with water. Covsr large spills with sodium bisultile (NaHSO'). Add with liquid. Secure ignition sources. Spill area may be washed with water.
rmall Jnounl of water and mix Scoop up. Wash site with soap solution.
lt. rDlll ccun. oll thc N.tlond Rer@ne (ttrtcr. tlxL,l2+Edrt. lf e spill mcurs, call the Nrtionsl Center, 8fi1424-8802
horlr Remfh Ground storage drums or tanks to prevent accumulationol static el€ctricity
t6a SCANNED BY MKP & BARIS A. 2004 t6t

GASOLINE.MOTOR GLUTARALDEHYOE
SOLUTION.50%
SyroryrBenzin; Motor spirit; Petrol United Nstions Number............................. 1203 Synonyms-Cidsx;1,3-Ditormylpropane;Glutaral; UniredNaaionsNumber....
I Glutaricdialdehyde:Glutarol;Penten6dial:
I r,s-Pentanedial
I
CHRIS Code ..... ...... GAT ('I|RIS Codc .. .. ... GTA
Formula-GHrz lo GHr r Fomuh-HOC(CHzhCOH

B o i l i n g P o i t t . . . . . . . . . . . . . . . . . . . . . . . . 6, .0 - 1 9 9 " C ' l 4 0 - 3 9 0 ' F I n"lllns Potnt .... 188'C 370'F
'c "F lpp"srrnce-Odor-Light ysllow liquldi rotlen apple odor
Appearrnce"odor-Colorlessto straw-whiteliquid; -t'c -"r I -"C -'F
sweet, pleasantodor-gasoline Freezidg Point......... , Frezlng Polni " - 14'c 7"F
SpecificGravity-o.7 2 lo O.76 _"c _"F sp€citiccrsvity-1.124 _'c _'F
- .,".icrrFm'y-Ardehydes -*-
chemicar hydrocarbon
Fmiry-Misc. mixrure Htr'"ltri..""3l;:.t$*l1"13-....:::::.'.,.1-.*- | Hf!:;"ffi,iffi,,$"T]1.-":1 .
. vapor Pressure 46'c (lls'D (psio)............. --l2l- -I _ _ _ Vsporpressurezl6.C0t5"1) (psis)...........
PollutionCtteSory-USEPA- IMO -----L- VaDorDensity(Air : 1.0).......................... 3.4 PollutionC.tcgory-USEPA - tl,IO D VrDorDeNity (Air : 1,0)........................9.4
ApplicablcBulk Re8.il6 CFR Subchepter........
----D- Solubilityin Wrter......................... Neolioible ApplicrbleBulk Reg.45 CFR Subchspter. . ... O Solubitityin tryrter......................
.. Soluble
GradeC: Flammable liquid Grsde-Non-llammable
Electricrl Croup-O Electrical Group-NA
Generrl-Dangerous fire and explosion hazard in pres€nce of heat or llam€. Flaghback along vapor ttail may Geneml-Will decompose it heated (greater than approximately 400'C) to yield carbon monoxide, carbon
occur. Vapor may €xplode il ignit€d in an 6nclosed area. dioxide, hydrocarbons.
F l s h P o i n t C n . . . . . . . . . . . . . . . . . . . . . . . . .-. 4. .0. F l N h P o i D t C F ) . . . . . . . . . . . . . . . . . . . . . . . .N. .o. .n. j l a m m a b l e

Flammable Linits..........................1.4 lo 7.60/. Fhmmsble Limits..........................NonJlammable
AutoigDitioD Tenp. ('F)................ 495 Autoignition Temp. ("F)................ Nonjlammable
Extingulshing Agenb COr, dry chemical, loam water fog ExtinguishinS A9ents.....................Non-tlammablg
sD€cisl Fire Preedures................ Tanks exposed to fire should be kept cool with a watel spray. water may be SDeid Fire Prc€dures................ Non6
inetfective on tire.

Hedtb Hadd Ratings Odor Threshold (ppm) PEL,/TWA (ppn) TLV,/TWA (Dpn) Heelth Hiaid R8tirSr Odor Threshold(ppn) PEL,/TWA (Dpn) TLVITWA (ppm)
1.1.2 0.25 300 300 1, 3, 3 0.04 0.2 0.2
General-Liquid irritatingto skin and eyes on contaci. Vapor inhalationleads to intoxication. G€oeral-Moderale itritationto the skin.
Marked vertigo, inabilityto walk a straight line, hilarity,inc@rdination,intens burning in SymDtoms-Exlendedexposures result in irrilation of respiratorytract. Ingestionyields irritalion of mouth ano
throat and lungs, possiblybronchopneumonia,nausea, vomiting. stomacn.
Short Exposur€Tolerance-o.s to 1.670vapor concentralim was latal to a man after 5 minutes exposure;500 to Short ExDosureToleruceThe lowest lethal concentrationlor rats in 4 hours is SO00oDm.
30,000 ppm was fatal to a youth
ExposurePreedures-lnhalation: lmmediatelyremove victim from contaminatedatmosphere. ll breathingis ExposurePtcedure-lmmediately flush with plenty of water for 15 minutes. For ingestion,givelarge.amounts
interrupted,artificialrespirationshould be applied immediately.A physician should be called. ol waler and induce vomiting if conscious.

Strbility-Chemically stable. Stsbility-Stable, but decomposes thermally about 4OO.Cforming carbon oxides and hydrocarbons.
CoDp.tibility-Materid! Almost any usual matsrial ol constructionis suilable. Natural rubb€r i8 sotlsned and ComFtibility-Msterial Mildly corrosive to mild steel, aluminum,copper, zinc, tin, brass and bronzs.
will deterioraterapidly.
cargo: Group 33 ol compatibilitychart

l l csrgo: Group 19 of compatibilitycharl

W€ar poly€thylenegloves, facs shield, proiactiv€ clothing. Have all-purposacrnht€r matl tvraLb|i. l}cur. Flush with wai€r. Wear goggles or lace shield and rubber gloves. Prevent water conlamination.Toxic to fish
ignition sources.Small spills may b€ flshed away wilh wat€r.
lt I Dlll acrr, flll lh. N.llonrl Ronr ( .rtcr, Gara{lt. lt . sDlll ccrr, cdl thc Nrlloml Clenter,
ll.rrlr: I UrravelLblo lnrlr: t Unavallable

I Unass|gned
raa SCANNED BY MKP & BARIS A. 2004 167

l)
f,
GLYCERINE HEPTANE
Synonyms-Glycerol; Glycyl alcohol; 1,2,3-Propanetriol; United Nrtions Number................................ l: Synonynr-Dip.opylmelhane; n.H€ptan6;Heptyl (JnitedN.tions Nunber...............................
1206
Trihydroxypropane; 1.2,3-Trihydroxypropane |, hydride; Normat heptane
D
C H R I SC o d e . . . . . . . . . . . . GCR ( ll RtS r bdc .,.,, HPT
Fornula-CH"COCH:COH(CH3), l) l'ornuh-CH,(CH,)rCH,
Boilirg Point.......................... 290'C 554"F llollina lhint 98"C 208'F
U T li
Appearance-Odor-Colorless liquid; laint pleasant odor -tg"c Ôr"arrtrce-()dor-Volatrl€, colorloss lrqurd. swool _"c _"F
F eezinS Point......... la-'r gasolino-lrke odo. l r(rrinr ll,lnt 91'C -132'F
'c 'F Spelflc Grrvity-O 68
Specific Gravity-1.26
'""o
chenicar
Famly-Kerone/Arcohorproperries X:tr'"il::'[.i"11;:jff,,f'
(exhibits +fHf *".,crrl'mry-sarurar.d
hyd,6a,bon l:il'l'-'iT'.'-iffl$rllillt-l
of both) vrpor presure 45'c (ils"F) (psis)............v. Low
| (ecrr) t-:F
... poruri,)n
PollutionCrtegory-USEPA - IMO --JlL- 3.17
v.por Density(Air : 1.0)........................... (hrcrory-rrsl:p^- ru' - c l;il:: l','.';:iJ',f;t'(t,T;n
ADDlicableBulk Reg.46 cFR subchapter..... Solubilityin wster....................... Comglete AppllctrbleBultRrs.{6(tRsulKhrptcr AÔ sotxbitir}inWallr........ Neolioible
FIRE & EXPLOSION HAZARD DATA r.'tRt,:& t:xPt,ost()N ltAZARD DATA

Grade-E: Combustible liquid Grede-C: Flammablo lqutrl
Electricrl GrouP-D Electrlc.l (;roup-D
General-Slighl hazard, when exposed to heat, flame, or powerful oxidizers. Generd-Highly llammeblo. dengarous ltro risk Flashback along vapor trail may occur. Vapor may exptode il
ignil€d In an enclosod aroa
F l a s h P o i d t ( " n . . . . . . . . . . . . . . . . . . . . . . . . .3. .2.0. f ' h s h P o i n l ( " 1 , ) . . . . . . . . . . . . . . . . . . . . . . .2. 5

. . .l.c c )
Flamdable Limits..........................Unavailable l f e m m s b f e L i n l t i . . . . . . . . . . . . . . . . . . . . . 1. ? l o 6 . 7 o h
Autoignition Tenp. ('F)................ 698 A u t o i g n i t i o t rT e n p . ( " 1 ) . . . . . . . . . . .. 4 3 3
Extinguishing Agents..................... COr, dry chemical, alcohol toam, water log Extinsuthh3 ^3cnts................... Conlined area-CO,, dry chsmicel. Open area-toam.
Special Fire Prcedures................ Water may be inetlective on fire. Cool expos€d tanks with water. SDecid Flre Prcduu......... . Fire fightors should h6v9 raspiratory devic€s. Kesp fire exposed containers
cool wilh waler.

ll€alth H@rd Ratings Odor Threshold(ppm) PELAWA (ppm) TLVAWA Opm) Hedth H@rd RrtinSr Odor Threshold(ppm) PEL,/TWA (ppm) TLV,/TWA (ppm,
0,0,0 Odorless 10 mg/mrasa mist 1 0 m g / m 3 a sa m i s t 0,0, 1 220 400 400
Ceneral-Skin contact with liquid causes slight skin irritation. G€nenl-Moderately loxic by inhalation.
Symptoms-Contactwith the liquid can cause skin irritalion. SymDtoms-lrritationof mucous membranes,dizziness,slight nausea, intoxication.
Short Exlbsure Tol€rilce-No appreciablehazard. Short Expcure Tolerance- 1000 ppm for 6 minules developed slight dizziness.5OOppm for 15 minules resulls
in a condition resemblingintoxicationby ethyl alcohol.
Exlnsure Prcedures-Wash glycerinetrom skin with water. Launderclothing contaminatedby the liquid. ExposurePrcedures-lf inhaled in conc. amounts, remove victim to tresh air and use oxygen. ll splashed in
eyes, wash with water for 15 minutes. Call a doctor.

Stsbilify-Reacls with strong oxidizingagents. Polymerizesabout 300"F. Strbility-Non-reactive but dangerous tire risk. Keep away lrom heat, sparks, or open flame.
ComDrtibility-Mrterilt: No apparont ellect on steel or aluminum. conpatibility-Material: Mild steel and stainless stsel are suitable. Natural rubber will sotten and deteriorat€
rapidly.
Cargo: Group 20 of compatibilitychart. See also Appendix l-Exceptions to the Charl Cargo: Group 31 of compatibilitychart.
SPILL OR LEAK PROCI]DURE SPILL OR LEAK PROCEDURE

S€cure rgnitionsources. Spills may be washed away with water. Avoid contact with liquid. Have all-purposecanister masks available.Secure ignilion sources.
lt I rDlll ec{F. crll lhc Nrilol nm (tnie. lxLata.alor. ll r rplll mn, crll rh. Ndloul ndrDrr Cctrtcr, tlxt-42,L8m2.
l|ar.rhi I vorr n smlll rnxrrrl ol w8l6r or olhor rmpu.rty wtll g.oally lowor th€ lreeztng potnl Xcnrrlrt
I Un.rr{rn d
{!!-::ur4....-!...-. ......."S&e,"
- n SCANNED BY
-*,. MKP & BARIS A. 2004 to
IgO.HEXANE
HEXAMETHYLENEIMINE
Synonyne2-Methyl p€ntare Unllcd N.tlons Nunbel 1208
syn(nyil-Azacyclohslane; Hexahydroa€plne; United Nrtions Nmber 2493
Homopiperidine
CHRIS Codc.. IHA

CHRISCode........... .. HMI
Fornuh-CHr(CHrhCH(CHsh
Fomutr-GHrrN Bollln8 Pohi.. ... ... 60'c 140'F
8 o i 1 i n 8 P o i n t . . . . . . . . . . . . . . . . . . . . . . 1. .3. 2 ' " C . 270'.1
Appruce-Odor-Colorless liquid;gtraolim-llke odor _"c _'F
Apperrance-Odor-Colorlessto light yellow liquid; lrezln8 Poht ........... 152"C 242"F
.
FreezinsPoint.................. 38'C 36'F
ammonialike odor 'F SpecificGnvlty-0.66
Sp€cificGrsrity-o.88 -
5- vrtDr PHure 20'C (6E'D (mmHO.... .. \ 100
Vapor Presure 20'c (6s'F) ,.*-" Chemicd Frnlly-Satural€d hydrocarbons Rcld vrDor Prmcure(pcle)........... ...... 6.0
Flmily-lmine
Chemical Reidvrpor Prwure (psla).......................... 4'2
Vrpor Prsure,l5'C (f fs"n (pdi.)............. 9.0
Vapor Piwure 46'C (ll5"F) (paia)...... . . . -$- Pollutlon Crte8ory-USUPA - IfUO C V r p o rD c n l l t y( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .3
. .. 0
PollutionCstegory-USEPA - IMO C VeporDemity (Air : f.0).............. Appllc.ble Bull Reg.116CFR Subchepter... O. O Solubiliay in Wrter ,...... ln$luble
ADplicableBulk Reg.46 CFR SubchDter.. . .. O s o l u b i l i t y i n w r t e r . . . . . . . . . . . . . . . . . . . . . .C o m D l e t e

FIRE & EXPLOSION HAZARD DATA Grade-B or C: Flammableliquid depending on llash point and Reid Vapor Pressure.
Grede-C; Flammableliquid Electricsl Group-D
Electricsl Group-C
Genenl-Oangsous. K€€p away from sparks, heat, or open tlame. Flashback along vapor trail may occur.
G€nenl-Toxic oxides of nitrogen may torm in fire. Dangeroustir€ hazard.Flashbackalong vapor trail may Vapor may explode if igniled in an enclosed area.
occur. Vapor may explode if ignited in an enclosed area.
I { s h P o i n t ( ' n . . . . . . . . . . . . . . . . . . . . . . . . . 1. .0. .
F l s h P o i n t( ' F ) . . . . . . . . . . . . . . . . . . . . 6
. .2. . . . . . . Flumrble Lihits...................... .... 1.7 to 7.Ooh
FlmmableLimits.......................... 1.6 to 2.3% AutoiSnition Temp,('F) ................ 583
AutoignitiorTemp.('F) ................ Unavailable ExtirsuishingA8ents..................... Carbondioxide,dry chemical,water spray
Extinguishing Agents..................... Water,COr, dry chemical SDecidFire PutduG................ Cool conlainers with water if exposed lo lire. Water may be inetfective on fire.
SpecialFire Pruedur6..-............. Wear eye prolection and sell-containedbreathangapparatus.
HEAI,TH HAZARD DATA

HEALTH HAZARD DATA He.lth HNard RatinSs (Xor Thr6hold (ppm) PEL,/TWA (ppm) |LVITIVA (ppm)
Herlth H{ed Ratirgs Odor Thr6hold (ppd) PELAWA (ppn) TLvnwA (pDm) 0, 0, 1 Unavailable 500 Unavaitabre
3, 3,3 Unavailable Unavailable Unavailable
G€nerd-Vapor slightly irritaling.Liquid causes slight skin irritation on contact.
cenenl-Liquid is irritalingto the skin and respiratorytract and the vapor causes eye injury. High vapor
concenlrationmay cause senous eye Inlury. Symptoms-lnhalationcauss irritationof respiralorytract, cough, mild depression,cardiac arrhythmia.Aspiration
causes severe irritationol lungs, coughing, pulmonaryedema; exciterent lollowed by depression.Ingestion
symptoms-Eye, skin and respiratoryirritation. causes nausea, vomiting, swelling ol abdomen, headache,depression.
Short Exlnsure ToleraneUnavailable
Short ExDcure TolermceThe approximatelethal vapor concentrationlor a four hour exposule is reported to
the 4800 ppm in rats.
ExposurePreedura-lnhalation: maintain respiration,give oxygen, if needed. Aspiration:enforce bed rest.
ExposurePrmedurm-Vapor-remove victim to fresh air; it breathing stops, apply artilicial respiration.Orygen,
administeredby trained personnel,is otten helpful. Skin or eye contact-immediately flood atfected areas
gently with water. Remove contaminatedclothing and continue to flush affected areas lor'15 minutes.Get
medical attention.
l l adminisler orygen. Ingeslion: DO NOT induce vomiting. Get medical attention or advice. Eyes: wash with
copious amounts of water. Skin: wipe off, wash with soap and water.
REACTIVITY DATA
REACIIVITY DATA Stability-Oangerous; keep away from sparks, heat, or open flame. Can react vigorouslywith oxidizing
Strbility-Slable. mal€rials.
Conp.tibillty-MrtGrld: Usual malerials of constructionare suitable.

conpatibility-Mrterirll Corrodes copper and its alloys in air; corrodes aluminumespeciallywhsn wet.
Removes paint; swells rubber. No effect on carbon steel, wood, cloih.
Crrgo: Group 31 ot compatibilitychart. See als Appendix l-Exceptions to the Chart.

SPII,L OR LEAK PROCEDURE Avoid contact with liquid. Secure ignition sources. Do not flush spill into confin€d spaces where flammablc
Soll-containedbreathing apparatus ot all-purposecanister mask should be worn when contaci is anlrcrpato(l vapors can accumulete.
Woer imperviousgloves and satoty goggles. Keep away lrom hsat, sparks and op€n flames; avoid breathlng ol
vapors. Flurh spill with lsrge quantiliss ol waier. Sscur€ ignition sourcsS.
lf r rplll ecurr, cdl the N.tion.l R6Dons C.rter, tlxL424-tt02.
lt I rDlll acora ctl thc Nrtlud natoix (brtcrr llD'af/Ltm2.
leorh
Lrrrlr: I UnavaLbb
SCANNED BY MKP & BARIS A. 2004 t7t

N.HEXANE
HEXANOL
Synonyns- AlcoholC-6; Amyl carbinol;1-Hexanol; 2282
UnitedNationsNunber................................
Synonyms- Hexane; Hexyl hydride; Normal hexane United Nrtions Number.. 1208
n-Hexanol;Hexanols;Hexylalcohol;n-Hexyl
alcohol; l-Hydroxyhexane;Pentylcarbinol
CHRIS Code................... .................H

. . .X A
Fornuh-CHr(CHz)rCHrOH
Fomuh-QHrr Boiling Poinl 157'C 315"F
Boilirg Point................... 69"C 156'F
Appearance-Odor-Colorlgssliquid; mild-swsol odor --sz:3
Appemce-Odor-Colorle$ watery liquid;ga$linelike Freezirs
Point......... -*:i
odor. Frezing Point .......... 94'C 137' F
'c "F SpecilicGrrvity-o.82 _'c _'F
SpecificGravity-0.66
20'C(68"D(mmHd..........<1 0
VlDorPressure
VaDorPressure20"C (68'F) (nmHg).......... --92!- Chenicd Fmily-Alcohol R e l dV N D oP r r e s u r e( D s i s ) . . . . . ....... ... 0 75
ChemicalFamily-Saturaled hydrocarbon ReidVaporPresrure(Drir)........................... 5.0
Vrpor Pre$ure46'C (ffs"D (Dsia)........... 1 00
Vrpor Pressure ,15"C(115'F)(psia)............. 7.O PollutiotrCrtGgory-USEPA - flfO ----Q-- (Air : 3.52
C Vrpor Density 1.0).................. ........
PollutionCriegory-USEPA - IMO V$orDetsity(Air : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . . . 9. .8. .
2
ApplicebleBulk Reg.,15CFR Subchspter........ D s o l u b i t i t y i n W s t e r . . . . . . . . . . . . . . . . . . . . . . .S
. lioht
ApplicrbleBulk Reg.45 CFR Subchapter........ D. O Solubility in Wster . lnsoluble

FIRE & EXPLOSION HAZARD DATA Grade-D: Combustibleliquid
Grrdc-C: Flammable liquid Electrical Group-D
Elctricd Group-D
cenersl-Moderate hazard,when exposed to h6al or flame.
cenenl-Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed araa.
Flsh Point CF).............................

140
n s h P o i t r t C n . . . . . . . . . . . . . . . . . . . . . . . . .-. 7. ...0 1.2 to 7.7% (calculated)
Flmmable Limits..........................
F l a m m a b l eL i m i t s . . . . . . . . . . . . . . . . . . . . . 1
. ...1. .l o 7 . 7 " h AutoignitionTemp.('F)................559
Autoignitiotr Temp. ('D................ 500 ExtinguishingAgents Carbon dioxide, dry chemical,alcohol loam, water spray
ExtinguishinS A8ents..................... Dry chemical, loam or carbon dioxide. Speial Fire Preedures................Water may be inetfstive on fire.
Speciil Fire Prcrdurc................ Waler may be inetlstive on tire. Cool tira exposed tanks with wator.
HEALTI{ HAZARD DATA

HEALTH HAZARD DATA Health Hrard Ratltrgr Odor Threshold(pDn) PEL,rfVyA (pDD) TLV,/TlryA (ppn)
Health Haard RatiDgs Odor Threshold(pDm) PEL,/TWA (Dpm) TLV,/TWA (Dpn) unavailable Unavailable Unavailable Unavailable
0.0. 1 Unavailable 50 50
C4rerd-Practically non-toxic.Handle as a detergent.
GeDersl-Minor skin itritant. lrritationcaused by vapor inhalation.n-Hexaneis toxic by ingestion.
SynDtoms-lnhalationcauses irritationol respiratorytract cough and mild depression.Aspiralion causes severe Symptons-Similar to alcohol inloxication.
lung irritation,coughingand pulmonaryedema. Ingestioncauses nausea, vomiting, swelling ol abdomen,
headacheand depression.
Short ExDqure Tolerrnce-Saturaled vapor not latal.
Short ExposureTolerance-30,000 ppm vapor concentrationcauses narcosis ol rats in one hour. 0.570vapor
concentrationcaused distinct dizzinessand giddinessol humans in iust ten minutss.
ExporurePrcedures-Vapor-remove victim to fresh air; il breathing stops, apply artificial respiration.Skin or
ExDosureProcedures-Vapor-remove from area and administerartificialrespiration,il necessary,and then eye contacl-remove contaminatedclolhing and gently tlush aflected areas with water for 15 minutes.
orygen. Eye-washimmediatelywith copious amounts of water. Ingestion-Do NOT induce vomiting.Get
medical attention or advice.
REACTIVITY DATA
REAC:TIVITY DATA Stsbility-Stable.
Strbility-Stable.
Compstibility-Mst€risl: Usual materialsof constructionare suitable. May sotten some paints and plastics.
Compatibility-Mrterisl: Csrtain Dlasticsare unsuitable,
Cargo: Group 20 of compalibilitychart.

Crgo: Group 31 ol compatibililychart.

Woar chemical gloves and goggles. Avoid contact with liquid.Secure ignition sources.
Wear rubber glovos, lace shield and prolective cloihing. Have all purpose caniste. mask available. Gsa
l€ak-keep concentration of gas below explosive limits by lorced ventilation. Liquid-absorb on pap€r 6nd
paper. Secure ignition sources
If r roill ccurc. cdl th€ Nrtiond R6w C€nter. 8fi)-424-tt02.

lf I cplll @urs, c.ll lhe N.llonal R6Fnp Ccnter, t00-42,Ltt02.
Rcmerhl
R.nr.lf

171
t72
HEXYLENEGLYCOL
T
HYDROCHLORIC
ACID
Synonyms- 2-Methyl-2,4-pentanediol; United Nrtions Number.......................
.
Trimeihyltrimethylene glycol; alpha, alpha, Synonyms- Chlorohydricacid: Hydrogen chloride; United Nrtions Numb€r .... . __lzgs
alpha -Trimethyllrimethylene glycol Muriaticacid
CHRIS Code........... .... HXG

( ' l l R l S C o d e . . . . . . . .. . . . . . . . .. .. __te!_
Fornula-(CH")"COHCH,CHOHCHJ
B o i l l n S P o i n t . . . . . . . . . . . . . . . . . . . . . . .1. 9
. 6'C 385'F Fomula-HCl (dissolvodin wateo
App€arrnce-Odor-Colorless liquid: slight odor - lloillng Point . ............. . 110'C 230'F
FreezingPoint......... -so'c -sg-'r ADtparsnce-Odor-Colorlessto tight y€llow liquid: -ze.c
Specific Gravity-0.92 -'c -"F irfltating,pungenl odor Frecrln8 Point ........... . - tos-.r
Vlpor Pressure 20'C (6S'F)(nnHO.......... 0 05 SpeclflcGr.vity-1 .01 to 1.21
Chenicd Fsily-Glycol R e i dV r p o rP r e s u r e ( F i a ) . . . . . . . . . . . . . . . . . . . . .L. o. .w ... Vrpor Pressure20"C(68"F)(mmHd.......... 212
VaporPresure,l6'C(l15"D (pris)............ 0 01 C'h€nicrl Frhlly-lnorganic acid R€idvrpor Pressure (pcir)............ -.. 80
Pollution Cat€gory-USEPA - IMO lll V r D o r D e D l t y ( A l r: 1 , 0 ) . . . . . . . . . . . . . ... . . . . 4 0 Vrpor Presure 46'C (ffs'D (p6ir)............. 10 5
Applicsble Bulk Reg. ,16 CFR Subchrpter........ O S o l u b l l l t y I n W s t e r . . . . , . . . , . , . , . . . . . . .C . . o. .m o l € t e Pollution Category-USEPA D fVO D V r p o r D e n s i t y( A i r : f , 0 ) . . . . . . . . . . . . . . . . . . . . . .1. . 2
. .6
ADplicsbteBulk Reg.116CFR Subchapter ... O S o l u b i l i t y i n w a t e r . . . . . . . . . . . . . . . . . . . . .C
. omDlete

Grrde-E: Combustible liquid FIRE & BXPLOSION HAZARD DATA
Elfftricd Group-D GrsdhNon-flammable. Classilied as a corrosive liquid.
Electriol Group-B (based upon possible hydrogen gas (H,) generation should a leak or spill occur)
Gereral-Moderale hazard, when exDoged to h€al or tlam€.
General-Hydrochloric acid will not burn. lt will react with many metals, giving ott hydrogen gas which is highly
flammable. lf hydrogen is trapped in confined spaces, it can form an explosive mixture with air. See dara
F l s h P o i n t C F ) . . . . . . . . . . . . . . . . . . . . . . . .2. 0. .5. . sheet lor hydrogen.Toxic and irritatingvapors are generaled when heated.
Flammsble Limils.......................... 4.7 to lOOo/o Flsh Point ('n.............................
Non-tlammable
Autoigrition Temp. ('F) ................greater than 500"F. Flmmable Limits..........................
Nonjlammable
Extirguishing Agents..................... COr, dry chemical, alcohol foam, water fog AutoignitionTemp.('F)................ Non-flammable
SDccial Fire Prmedures................ Water or loam may caus€ frothing. ErtinguisbingA8€trts.....................
Non-flammable
SpecialFire Preedurs................ Acid tanks exposed io a fire should be cooled by a water spray. Fire parties
must wgar respiratoryprotection in order to avoid breathing acid vapor. Full protective clothing must also be
HEALTH HAZARD DATA

Hedtb Hurd RatinSs Odor Threshold (ppm) PEL,/TWA (ppn) TLVAWA (Dpm) HEALTH HAZARD DATA
'1.0.0 l e s st h a n5 0 25 25 Heslth Hurd Ratin8s Odor Threshold(ppm) PEL,zTWA (ppm) TLV,/TWA (ppn)
Generll-Vapor irrilaling to skin and eyes at high concentrations.Liquid very irritatingto eyes, slightly irritating 3,3,2 1to5 5'
to skin. canerd-lnhalation ol gas results primarilyin irritationot upper respiralory passages. Liquid severely irritatingto
skin and eyes.
Symptoms-Headache,diziness, nausea;strong local irritationof the eyes, nose, and throat; and respiratory
discomfort. Symptoms-Whoro louched by liquid,lhe skin may tingle or burn. Breathing the vapors will cause severe
Short Expmure TolerucFl ppm for 30 minutes. coughing and walering of the eyes.
Short ExpnsureTolermdnhalation ol 1500 ppm in air are fatal in a lew minutes.
ExDqrre Prmedures-Flemovevictim to lresh air. Give ariilicial respirationif necessary.Wash spilled liquid lrom
skin with water. Get medical attention il rash develops or it victim has any breathing difticully. Expcure Prceduret-Vapor-remove victim to fresh air; il breathing stops, apply artilicial respiration.Oxygen,
administeredby trained personnel,is otten helpful. Skin or eye contacl-remove ceilaminated clothing and
gently llush affecled areas with water lor '15 minutes. Get medical advice or attention.
REACTIVITY DATA
St8bility-Beacb with strong oxidizinga96nts. REAC]TIVITY DATA
Strbility-Reacts with bases (caustics)to generate heal.
Compstibili8-Mrtcrld: Usual malerialsof conslructionare suitable.

compstibility-Materisl: Corrodes many melals, causing the evolution of hydrogen gas. lron and aluminum are
corroded readilv.
Cargo: Group 20 of compatibilitycharl.

Avoid contact with liquid. SPILL OR LEAK PROCEDURE
Wsar rubb€r gloves, selt-contained breathing apparatus, protective clothing. Have body shietd available.
Secur€ ignilion sources. It possible, cover th€ contaminatedsurface and spill with sodium bicarbonate or a soda
ash, slakod lime mi)dure (50-50). Mix and add water if necessary to form a slurry. scoop up slurry. wash site
ll r rjlll rcurr, c.ll the Nrtlotrd RaDoe Caracr, qxt{21-t802. with soda ash solution.
lf r Dlll acurs, c.ll the Nrtlord CcDter. 8fi1-421-tt02.
lnrrlr I tJnaaalgnql
Rcrulr: ' PEL md TLV brr€d
upon hydrog€n chtoride gas.
t7a
SCANNED BY MKP & BARIS A. 2004 t7!
(NOTE: Thle cargo ls currently not permlttod to be 3hipped in bulk in U.S. wateru)
HYDROGENPEROXIDE
HYDROGEN(Liquefied) (72% or lo.!)
Synonyms- LH:; Liquid hydrogen;Protium UnitedNstionsNumber...compressed 1049 Synotryms-Albone; High-strength hydrogen peroxid€; Uniied Nrtions Numbei................................2O15
refrigerated '1996
Hioxyl: Hydrogen droxide: Hydroperoxrde: Peroxids;
SuDeroxol
CHRIS Code........... ... HXX ('llRls Code HPO
Formula-H: Formule-HzO:
B o i l i n t P o f n t . . . . . . . . . . . . . . . . . . . . .-. 2
. 53"C -423"F
Bolflnslt)int 125'C 257"F
gas or liquid;ododess
ADp€arance.Odor-Colorless -- App€arrnce-Odor-Colorlesswatery liquid: slightly sharp -ao'c
.a
Frczlng Pornr. zsg"c -lg5"r odor. - ao r

I rc(rins lt)inr
SpecificGravity-o.o7 at b.p. _'c _"F Sp€cificG.avity-l.29 or less
Vrpor Pwure 20'C (6t"F) (dmHO...... V Hioh VrDorPrqurc 20'C (6t'D (mmHg)........
Chenicrl Frmily- ReldVrpor Presurc (D.lr).................,... V. Hioh Chenical Family-
Rcld VeporPrdure (Dd.)............
. .. ... Varies
porutroncategory-usEpA-rMo l#*
# I:il:ilffi",f;ttt,ti,t'11lil],........... porurion
cste8ory-usEp^
- rMo c Y:il: l*ilif;1t1i," 1t-:] .....+:ii*
ADplicsble Bulk Re8. il6 CFR SubchaDter ..... Bulk Rca.15 ('l'R subch.Dacr......
Applicable O llDlrbiltryIn w.rer.....................
... Soluble
Grrde-Liquetied FlammableGas (LFG)

ElectricalGroup-B
1 l Grade-Not applicable
Elatricrl Group-Not applicsble
I.'IRDII EXPT,OSIONHAZARD DATA
react violentlywith strong oxidizeB. Will ignite easily with oryg€n. Vapors lorm explosiveor Gcr€rrl-Not llammabl€ but may cause tire and reaci vrol€ntlywith combustiblesand metals. Powerlul oxidizer
combustiblemixture with air over a wide range ot concentrations.Flame is almost invisible.Flashbackalong May caus€ fire and axplodo on conlacl with combustrblosand m€lats.
vapor trail may occur. Vapor may explode it ignited in an enclosed area.
F l s h P o i r t ( ' n . . . . . . . . . . . . . . . . . . . . . .G
. .a. .s. . . F l 8 s hP o l n t( ' D . . . . . . . . . . . . . . . . . . . . . .N. .o n - l l a m m a b l €
Flmmble Linits.......................... 4.0 to 757o F l a m m r b l Le l n l i 3 . . . . . . . . . . . . . . . . N o n J l a m m a b l e
AutoigritionTemp.('D ................'l 075 A u t o i g n i t i o n T G m p . ( " F ) . . . . . . . .N. o n - f l a m m r b l g
Extinguishing A8ents..................... Firsl stop flow ol gas. CO:, dry chemical,water E x t i n g u i s h l u A g e n t s . . . . . . . . . . . .N . . o. n - f l a m m e b l e
Sp€cialFire Procedures................ Source of hydrogen MUST be eliminatedbefore fire is put out to prevent Sp€cirl l'irc Pmcduro.............. . Powerlul oxidiz€r.W€ar prolective clothing includingself-containedbreathing
accumulationot explosivevapors. lf the insulationfails on a liquid hydrogentank exposed to lire, the tank apparalus. Flood dischargearea with water.
will explode; evacuate firelightersand have them take cover.

Hcrltb Haed Ratings Odor lhrohold (ppn) PEL,/TWA (Dpm) TLVITWA (DDn) Health H.Ad Rstings Odor Threshold(ppm) PEL,zTWA (ppm) TLVITWA (ppn)
Unavailable Odorless Unavailable Unavailable 2,3, 1 Unvailable I i
asphyxiant.Not consideredtoxic. Avoid skin contact wilh liquid Gen€.d-Vapor is irritating.
Symptons-lnhalation. Drowsinessand high-pitched,squeaky voice. Skin contact: Numbness and whiteningot SymDtoms-Vaporscause eye and nose discomfort in moderale concentrations;less than 52olocauses
skin at the area of contact. temporary irritation.Above 527" can cause blisters and eya damage.
ExDosure Tolersnce-Unavailable Short Exlosure Tolermce-77 ppm lor 30 minutes.
Ernmure Preedures-Remove victim to fresh air: if breathing stops, apply artiticialrespiralion.It the liquid has Ex!6ue PrftedurAvoid conlact, immediatelyflush with watei. lf ingested give waler, induce vomiting if
spilled onto the skin, points of contact may be trostbitten;handle gently and protect lrom mechanical conscious. Remove contaminatedclothino and sh@s.
damage. DO NOT RUB. cet medical attention immedialely.Avoid sparks and open flames.

Strbility-Will ignite readilywhen exposed to spark surce. Liquid hydrogenwill tlash into vapor at lemperatur€ grades are stable, but contaminationwith metals or dirt can cause violent or raoid
above -400'F resultingin a sudden and large increase in pressure if conlined. decomposition.
Comprttbility-Material Mild steel and mosi iron alloys become brittle at liquid hydrogen temperatures. rp8tibility-Msterisl: Incompatiblewith iron, copper, brass, bronze, chronium, zinc, lead, manganese,silver,
Aluminumand stainless steel (300 series) may be used. and catalytic metals.
Cargo: Not shipped in bulk, Csrgo: Unassignedin compatibilitychart. For compatibilityassistance,call

G-MTH-1 (202-267-1 577t.

Sacurs all noarby ignilion sources immodiately. lsolat€ spill area and csll local tire dgpartmont and tha wear proteciivo inner and outer clothing, impermeableapron, neoprene gloves. Flush area with water. lsolate
Caplein ol tho Port, U.S. Coasi Gusrd. ll th€ liquid does not catch firs. it will soon boil ofi and lsave m rosduo. from contacting llammable liqurds or combustible materials. Evacuate area lor al least 1/2 6ile il lie
exrsts
ll t dll rrcrun. (.ll th. \rtlond RoDnr ('.ntcr. EUH24-tt02. If I cplll ccuB, 6ll abe Nrtlonrl RdDon* ('entcr. tm-424-8002.
lrrrlr: ' l|l rlrlpmrnlr nol garnliird. llcorrlr

'
V,rlrrr IJrilrsurrr 5 mmHg At 86'F
176
2.HYDROXYETHYL
ACRYLATE ISO' (as a preflx)
Look und.r D.rani comDound.
Synonyms- Ethyleneglycol monoacrylate;HEA;
Syaonyms-
beta-Hydroxyethylacrylate;2-Hydroxyethyl
2-propenoate
('llRlS ('ode..
Fomuh-HrC: CHCOOCH,OH
Fornuh-
Boiling Point......................... <210'C <410"F
App€arrnce.Odo.-Colorlessliquid with sweel odor -'-:n"r Bollh8 Point . . . . . ._ ' c _'F
Fre€zing Point.......................
go'c Appeerucc4dor- _'c 'c _ ' F
SD€cificGrarity-1.10 _'c _'F Freczln8 Polrt _'F
Specinc Gnvily- -'F
Vspor Pressure20"C (68'F) (mnHg).......... ---!Q!tL-
Chemicd Frmily-Monomers and polymerizableesters (Dsir)..... Vrpor prrourc 20.c (58.F) ,^-"' *--"
R€idVaporPressure .....................
-!e!!- Chemicd Frnlly- R.ld V.!p. Presurc (Doh)........
vapor Pressure46'C {tl5'F} (psis)............. --!8!{:-
PollutionCategory-USEPA - IMO B NP v.!nr Prilure 46'C (t15'F) {Dsir).............
-
Vslnr Dencity(Air : 1,0)...........................
O
Pollutlon Crtctory-USEI'A --- lM() - vrfor Dc[lty (Ai. : t,0).........
ApDlicsbleBulk Reg.46 CFR Subchspt€r........ Solubilityinwrter............,.....,-.... Comolels
Applic.blc Bdf nt3. a6 ( l.R sub.hrpr.r s.rlubllhyIn W.ter ....
FIRE & DXPLOSION HAZARD DATA l lRE it !.:XPL()S|()N HAZARI) DATA

Combustibleliouid
Grade-
Electrical Group-D
Eletrlcd Group-
-Moderate lir€ hazard; howsver, dang€rouswhen expos€d to high tsmpsrsturss due to lib€rationot
Ccaol-
toxic fumes.
F l s h P o i r t ( ' n . . . . . . . . . . . . . . . . . . . . . .2. 2
. .0. . . .
Flsh Polrt ('F) ..............,,.,,..,.,.,..
FlammrbleLinits.......................... LEL 1.870UEL-unavailable
FlmublcLimitr....
Autoi8nition Tenp. ('F) ................ Unavailabl€
AutolSnltlon Temp. ('l')................
Extin8uishing Agents..................... CO?,dry chemical,water,alcoholloam.
Extlngubhlnl A8cnts
Fire Prcedur6................ Wsar eye proteclion, ssll-containodbrealhing appatatus, and impermeabl€
Spechl Flrc Procrdurq ..,........,.,..
protectiveclothing
HEALTH HAZARD DATA HF]AI,'TTI

HAZARD DATA
Health Hs6rd Ratings Odor Threshold (ppm) PELITWA (ppm) TLV^WA (DpD)
Health Hud nrdrla (Xor Threshold (ppn) I'EI,/TWA (ppn) TLV,/TWA (Dpm)
4,4,4 Unavailable Unavailable Unavailable
-Severe eye damage, itritated skin, serious illness after ingestion.Class B poison.
Generd-
Symptods-Walering of eyes, red or irritatedskin.

Symptoms-
Short ExposureToleruce-Avoid inhalationof hot vapors. lrritationof skin upon short contact; burn after
prolongedcontact. Animal tests show no dealhs atter ingestion. Short Erlfiur€ ToleruF
ExposurePrcedures-ll swallowed,induce vomiting; remove victim to fresh air if any ill etfects from breathing
ExD6ure Prcedur6-
vapors are tell. Fluqh eyes and skin immedialelyafl€r contact lor approximately15 minutes.Call a doclor.

Strbility-No spontaneousdecomposition,but can polymerize.
Stability-
Comprtibility-Mrterial: Corrodes mild steel, tin plate, and polymerizes.No etfect on stainless steel, aluminum,
ComFtibility-Mrtedd:
or mild steel wilh phenolic resin surfaces.Swells rubber, removes paints.
Cargo: Unassignedin compatibilityguide. See Appendix l-Exceptions to the Chart.

Crrgo:

W€ar eye protection. N€oprens rubber o. other imp€rmsable proleclive clothing should b€ worn. S€curs
ignilion surces.
lf I rplll Gurr, c.ll the Nrtiond Ralre Ccnae.,

lt I sDill @cun. c.ll ahc Nrllotrd lipnc ( enrer. tUI42/t-8&12
R.n..l.i I UnaSrigned '
llrnrrlr: I or ilx{rilplo, rt you want€d to l@k up i8o-propyl alcohol rt would bo shown as r&-PROPYL
"P"
At(I)ll()t un(krr nol l"
l7t
SCANNED BY g:Tr
MKP & BARIS A. 2004 t?9
ISOPHORONE ISOPRENE
Synonyms- bela-Methylbivinyl: 2-Mattryl-1,3-buiadime; United Nriions Number.................... 1214
Synonym$- lsoacetophenone; United Notions Numbcr., . . . . . . . . . ._. l. -
-one 3-Methyl-1,3-buladi€ne
3,5,5-Trimethyl-2-cyclohexene-1
lPH
('URIS Code.. IPB
cHRIs code"""
r--------------t
Formula-C(O)CHC(Cru)CH,C(CHr),CH'
Fornulr-CH, : C(CH!)CH = CH,
Bolllng Polnt.. 34'C 93"F
BoilinSPo|trt.......................,. 2'15'C 419'F o^ oE
Appeumce-Odor-Wat€r white liquid;p€ppermint-like ----e'3

App€.rrnc€Odor-Colorless liquid; mild aromatic odoa -rao'g
Frezlng I'oint -xr"r
odor FreezinsPoint......... . t'F
SDecific Grrvlty-0.69 U T
Sp€cificGravity-o.g3
Vapor Prwure 20'C (6S'n (mmHg).......... 0 3 Vrtnr Prcsure 20'C (6E'n (mmHg..........-
C'henlc.l Frmlly-Oleling
Ctemicrl Fmily-Ketono R e i d V r p o r P r e s u r e ( ! E i . ) . . . . . . . . . . . . . . . . . . .L. .o. .w. . . R e i dv q p o l P r c s u r e ( F l r ) . . . . . . . . . . . . . . . . . . . . . 1. .5. ...O.
Vf,porI'resure 46'C (ll5'F) (pctr)............. -23!-
VaporPressure 46'C (lls'n (Dsh)............ Low Pollutlotr Crtc8ory-UStpf C
Pollution csteSory-USEPA O IMO D V $ o r D e n s i t y ( A i r: 1 . 0 ) . . . . . . . . . . . . . . . - . . . . 4
----E-- tl,t<t V r p o r D e n s f t y ( A i r: t . 0 ) . . . . . . . . . . . . . . . . . . . . . 2. ...3. .5.
. ...7. .5. .
D Appllcrble Bull Rej 116CFR Subchepter........ ----.Q-- Solubility in Wrter lcduble
ApplicableBulk Reg 46 CFR Subchrpter........ Solubility in W.ter.........................
Grade-A: Flammabls liouid
Electricd Group-D
Electiicsl Group-D
General-ln a fira, polymerizationmay occur and violenlly ruplure the container. lt is recommendedthat
Generrl-Moderate tire haard when exDossd to h€at or flamE.
isoprene be stored under an inert atmosphere (preterablynitrogen)with at least 50 ppm tert-butylcatechol
present as an inhibitor.Keep away lrom sparks, heat or open flame.
F l s h P o i n t ( " D . . . . . . . . . . . . . . . . . . . . . . . .6. 5
....
Fluh Point Cn.............................
184
Fhmnsble Limits.......................... 2.0 to 9.0olo
Flumrble Linits..........................
0.84 to 3.8'l.
AutoigritionTenp. ('F) ................ 428
Autoigritioo Tenp. ('F) ................860
ExtinguishinSAg€nts Extinguishing A9eils..................... Carbondioxide,dry chemical,foam
Water spray, carbon dioxide,dry chemical or foam.
SDcigl Flre Preedurq ................Cool exposed lanks with water spray.
SD€cislFire Pr@ednrs................Use water spray to dispersevapors. Water may be used to llush spills.

Heslth Hred Ratings Odor Thr€shold(ppm) PEL,/TWA (ppn) TLV,/TWA (ppn)
Herlth H@rd Ratings Odor Thr6hold (ppm) PEL,/IWA (ppn) TLV,/TWA (ppn) '|, 1, 1
2,2,O 0.005 Unavailabte Unavailable
Unavailable 4 5
Generd-lsoprene is an irritant to mucuous membranes of the eyes, nose, and upper respiratorypassages.
General-Highly toxic, strong irritanl to skin and eyes.
SynDtomFvapor-Eye and upper respiratorylract irritant.Liquid may irritate eyes.

SymDtomr-Eye,nose, and throat irritation;narcosis.
Short ErDGure Tolermr25 ppm is an irritantto most humans. Animal tests resulted in eye iniury and slighi Short Expsurc ToleranceNo data on human exposure are available but concentrationsof 57. in air are tatal
skin irritationafter 24 hours; inhalationkilled 1 ol 6 animals in I hours. to mice.
Extmure Prcedurc-Remove victim to fresh air and use orygen. Flush eyes for 15 minutes with water. Wash ExDosurePr@edur6-R€move to fresh air. In case ot contact with liquid immediatelyflush skin or eyes with
off skin. Get medical help. water lor at least 15 minutes;remove contaminatedclothinq and shoes at once. Call a ghvsician.

Stsbility-Readily oxidized,polymerized.Should be inhibiled to prevent polymerization.
strbiltty-slabls.
ConFtibility-Mrterid: Compatibility-Mrterid: May sotten some types ol rubb€r or paint.

Steel is satistactory.
Cugo: Group 18 of compatibilitychari. See also Appendix l-Excsptions to ths Chart. Crgo: Group 30 of compatibilitychart.

Woar rubb€r glov€s, tece shi€ld, and protectiv€ clothing. Sscur€ ignition sourcss. Hlvo alt-putpooacar{!k}l Wear rubb€r gloves, tace shield, protective clothing. Have all-purposecanister mask available.Avoid contact
mask availabl€.K6€p unFotactsd personnelugwind. Flush spill with watsr. with liquid. Secure ignition sources. Do not flush spill into contined sgaces where flammable vapors can
accumulat€,
('.u ( If e gdll ccurs. cdl the Nrtlonrl Center,

lt t.Dlll c.ll th. N.tlad Imx
Rcmerb: 'Va[pr Pressuro:400 mmflq at l5"C
lryl.r I Unor1gi-
ID SCANNED BY MKP & BARIS A. 2004 Itl

LIQUEFIEDNATURALGAS
KEROSENE
Synonyms- LNG; Methane, relrigeratedliquid,or United Nrtions Number... compressed 197'l
Syronynr- Coal orl;Fuel oil no. 1; llluminating
oil; Natural gas; relrig€ratsd liquid relrigerated 1972
Kerosine;Rang€ oil
CHRIS Code LNG
Forhuls-Mixture ol CHr end C,l"l.

Fornuh-Mixlur€ of hydrocarbons 8ollltr8Poinl 161'C 258"F
BoiliDS Point............... ... 170-300'c 338-572'F liquetied gas; usually -tgz'c
Apperroce-Odor-Pale yellow to water white oily liquid; _'c -'F odonzed to give g weak skunk like odor Frecztn8Potnt. -zs6'r
Frezing Point............. . . . . . .
-45'C -50"F
stong odor Sp€cific Grrvlty-o.41 to 0.45 al 162'C _'c _'E
Speilic Gravity-o.81 _'c -'F
VaporPreuure20'C (68'n (mmHd.......... Hioh
VaporPressure 20'C (6E'n (mmHg).......... 2 04 C:hemicsl Fsmlly-Paraff ins Reidvrpor Prffure (prh)......... Hioh
ChemicalFrmily-Petroleum oil R e i d V r p o r P r e $ u r (ep s i s ) . . . . . . . . . . . . . . . . . . . . .0. ' l Vlpor Presure46"C(ff5"n (psir)...... ...... Hioh
vrpor Prsure il5'c (115'D (psia)............. ---0J5- Pollutlotr CateSory-USEPA - IMO ----999- VrDo. DeNity (Air : 1.0)............... .. 0.55-1 0
PollutionCategory-USEPA - IMO I vrpor Dersity(Air : 1.0).......................... 4.5 Applicrble Bulk Reg. 46 CFR Subchpter ... .... D. O S o l u b i l i t y i n w r t e r . . . . . . . . . . . . . . . . . . . . . . I. n. .s o l u b l e
ApplicableBulk Re8.il6 CFR SubchrDter........ D SolubilityinWoter........................ Neolioible

FIRE & EXPLOSION HAZARD DATA Grrde-Liquefied FlammableGas (LFG)
Grrde-D: Combustibleliquid Electricsl GrorlF-D
ElectricalGroup-D
Geo€tsl-Containg6 may explode in fire. Vapor may travsl to ignition source and tlash back along vapor trail.
Genenl-Flammable, moderate risk. Unless the tlow ol gas can be stopped, putting out an LNG lire will permit the accumulationof an explosive
concentration ot vapor and subsequentexplosion or reflash.
Flsh Point ('F).............................
Flammablegas
100 to 150
Fl$h Poirt CD............................. Flmmrble Linits..........................
5.3 to'14.0%
0.7 to 5.0olo
FlammbleLinits.......................... Autoigritiontenp. ('D................999
AutoigDitiorTemp.("F)................
444 Extitrguishing
A8erts.....................
Stop flow ol gas; Dry chemicallor smallfires.
ExtinSuishingAgents Conlined area-Cor, dry chemical.Open area-loam, waler fog. SpecialFlre Prft€du€s................ Use waler lo c@l exposed tanks. Do nol extinguish large spill fires. Allow to
Fire Pr@edur6................Tanks exposad to tile should be kept c@l with a water spray' water may be burn while cooling adiacenl equipmenl with water spray.
inetfectiveon fir€.
HEALTH HAZARD DATA

HEALTH HAZARD DATA Hqltb Hurd Rrtltrgr Odor Thr6hold (ppm) PEL,/TWA (ppn) TLV,/TWA (ppn)
Hqlth Hurd Rstinss Odor Threshold (ppm) PEL,/TWA (ppn) TLVITWA (ppn) 0,0,0 Unavailable Unavailable Unavaitable
1. 1. 1 1 Unavailable Unavailable
G€nerrl-VapoB ars non-irritatingto ey€s and throal. Liquid will cause lrGtbit€.
cenersl-Moderalely toxic by ingeslionand inhalation.
concentrationol gas is high enough, may cause asphyxialion.No systemic efiect even at 5%
Symptoms-lnhalation:Marked vertigo, inabilityto walk a siraight line, hilarity,incoordination,intense burning in concenlralion in air.
throat and lungs, possiblybronchopneumonia,nausea, vomiting.
Short ExDosureToleraDce-Dala not available.
Short ErposureTol€roce-Unavailable
ExpGurc Pruedur€s-Vapot-remove victim to open air. Administer artificial respirationit necessary.lf the liquid
ExDosurePrcedureFlnhalation: Remove victim lrom contaminatedatmosph€re.lf breathing is intetrupted, has spillsd onio lhe skin, points ot conlact may be lrostbitten; handle gently and protect from mdchanical
artilicialrespirationshould be applied immediately.Call a doctor. damage. DO NOT FU8. Get medical attention.
REACTIVITY DATA
REACTIVITY DATA
Slrbility-Stable.
Stainless steel, nickel steel and aluminumare suitable.

comDrtibility-Material: Most metals are suitable,but korosone cau*s rusting ol stegl,

Crrgo: Group 33 of compatibilitychart.

SPILL OR LEAK PROCEDURE Wear rubbsr gloves, lace shield, protective clothing. Have all-purposecanister mask available.Secure ignition
Wo!. rubb€r gloraa, laca shield, protetiv€ clothing. Hav€ all-purpos€caniltgr mask availrble. Sacute lgniiion sources. Call fire department. For leak lrom faulty tank keep concentration below flammable limits by torced
Small rpillr may be llushed away with water. vsntilation. lf th€ LNG does not catch tire. it will soon boil off.
If I qilll @curs, cdl the Nrtional C€nter. 800-42i1-E602.

lt. dll crn. all lh. i\irrlod nim (j!nt(r.0|tr{l.-lAn2.
Itnrrlr:
llrnrrlt
It
l8.l
I12
,..*iod.;ii**-*
LIQUEFIEDPETROLEUi'GAS MALEIC ANHYDRIDE
\tiGtm.- Eotlled gar; LPG; Pslroleum gases,
Slnonyms-cis-Butenedroic anhydride;2,s-Furandione United Ndlons Number............ 2215
lqugiod, Propane-Butlne mixtures;Pyrotax
CHRIS Code. MLA

Fornula-CrHrOr
lornuh-Mixiure of C"H"'sand CaHro
Boiling Point.. .. -40'c -40'F
Appearsnce-Odor-Colorl€rsliquid,white solid (a8 ll{,ilin8 Point.
Appcrronce-odor-Colorlesscompressedgas, with faint _'c _'F 3 w J Y Z |
NP"C _'F needles, crystals or lused tablels); acrid, choking _'c _"F
skunk odot Fre€zin8 PoiDt ..
ooot I'reezing Point 60'c 140'F
specificGnvity-o.s1 to 0.58 al -50"C (liquid) _'c _"F
Speciliccnvlty-Molten: 1.3 at 70'C; Solidr L48 at _"c _'F
VaporPressure 20'C (68'F)(nmHg.......... Hioh 15 " C
chemlel Fmily-Paraff ins ReidVaporPressure (psia)................. .. Hioh Vtpor Preuurr 20'C (6t'F) (mmll8).......... 0.1 5
ChemicalFamily-
VsporPressure 45'C (115'D (Dris)........... Hioh RcldVrporPre$ure(psir)........................ f
PollutionCrtegory-USEPA - IMO oas V . D o rD e n s i t y( A i r : 1 , 0 ) . . . . . . . . . . . . . . . . . . . . . .1. . 5 Vtlnr Prewurc46"('(tl5"F)(psia)............. t
Pollution CrteSory-US[PA D lMO D V|Dor D€nslly(Air 1.0). .................... 3.38
Appliuble Bulk Reg.46 CFR Subchapter........ D. O S o l u b i l i t y i n w a t e r . . . . . . . . . . . . . . . . . . . . . l. n. .s. o l u b l e
ADplic.bleBulk Reg.46Cl'R Sub.hrpre...,...,. O Solubilit) in Wrter... ...

Grrde-Liquelied FlammableGas (LFG)
crade-E: Combustibleliquid
Elcctricsl GrouP-D
Electric.l GrorF-O
cener.l-Containers may explode in lire. Vapor is heavier than air and may travel a long distance to a source
Genersf-Mild lie hazard. Inertion with nitrogen recommendedto avoid reaction with waler vapor. When heated,
of ignitionand llash back. Unless the llow ol gas can be stopped, putting out an LPG fire will permit the can decompose and overpressurizestorage tanks.
accumulationof an explosive concentralionot vapor and subsequentexplosion or reflash.
F l N h P o i n tC F ) . . . . . . . . . . . . . . . . . . . . .1.5. 6
...... Flsh PoitrtCF)............................. 215 (cc);230 (oc)
FlrmmableLimits.......................... 2.2 to 9.5"k
F l a m m a b fLei m i t s . . . . . . . . . . . . . . . . . .1. ...4. t. o. . 7
. .1yo
Autoignition Temp.('F)................ 871
AutoignitiorTemp.("F)................ 878
Extinguishing Agents..................... Stop flow of gas; Water (Let lire burn)
ExtinSuishing A8ents..................... Alcoholfoam, carbondioxide
Fire Prftedures................ Allow to burn while coolingadiacentequipmentwith water.Shul otf leak it
SlEcisl Fire Prcedur6................ Water and loam can cause trothing. Can react with dry chemical. Keep tanks
cool in lire by sprayingwater on them trom safg distance. Wear self-containedbreathing apparalus, and
protective clolhing.
HEALTH HAZARD DATA

H€8lth Haard RrtinSs Odor Thr6hold (ppm) PEL,/TWA (ppn) TLvnwA (ppn) HEALTH HAZARD DATA
Hedth Hrrud Rstings Odor Thmhold (ppn) PELAWA (Dpn) TLV,/TWA (ppn)
0. 0. 0 5000 to 20000 1000 1000
2,2, 1 0.3to 0.5 O.2E O.2S
Geneml-Not irritatingto eyes, nose or throat. ll inhaled,will cause diziness. Liquid will cause lrostbite.
G€nerd-Will burn skin and eyes; dangerous to aquatic lite.
Symptoro-Concentration in air greater than 10"/. caus€s diziness in a fw minutes. High concentrationcaus€ symptoms-lnhalation: Moderatelyirritating,coughing, sneezing,bronchitis from chronic exposure.skin:
asphyxiation. lrritation,redness; dermatitisfrom chronic exposure. Eyes: lrritation,can be severe, tearing. Ingestion: Litfle
Short ExposureTolermce-None or no risk; nausea.
Short ErDGure Tolemc€-Limited inhalation risk it sDace wgll ventilated.
ExposurePreedure-Vapor-remove victim to open aar.Administerartilicial respirationit necessry. ll the liquid Exp6ure P.cedurdngestion: Induce vomiting. Inhalation:Remove to lresh air, give oxygen if necessary.Skin
has spilled onto the skin, points ot contact may be lrostbitten; handle gently and protect from mochanical contact: Flush with water tot at least 15 minutes. Eye contact: Ftush with watei for at leasl 15 minutes; call
damage.DO NOT RUB. Gel medical attention.
I physician.For skin contact with molten maleic anhydride,remove solid from skin and lreat as normal
chemacaland thermal burn, and wash with soag and water.
REACTIVITY DATA
Strbility-Stable.
ComDstibility-Materi8l: Stainlesssteel, nickel st€el and aluminumaro suilable.

I REACTIVITY DATA
st8bility-Generally stable- When heated in presence of alkali metals or amines (even in low concentrationsol
200 ppm)' decomposes rapidly and can overpressurizetanks. Reacts with strong oxidizers.No reactiviry
except anpresence ol water (corrosive).
Compoiibitity-Mite.ial: Not corrosive to metals excepl in the presence of water.
Cargor Group 31 of compatibilitychart I Cargo: Group 11 of compatibilitychart.

Wea. rubber gloves, tace shield, protectiveclothing. Have all-purposscanisler mask availablo.Secure rgniton
I
sourcos. Call tare d€partm€nt. For leak trom faulty tanks, ke€p concantralion b€low tlammrble limilt by lotcod .. us€prorecrive
squipmsnr,"",,r:;::;,:1::l'j.:,:r:,"r",-"JL,o"*", ooo,.,covera,s,
rubber
apron.
us€ organic vapor-acid gas canisler. Dike and lel spill solidify, the; dispose. Alternative,add water to dissolve
ventilation.ll lh€ LPG does not catch tirs, ii will smn boil ofl.
spill (torming maleic acid) and neutralizewith soda ash, then disoose.
lt I rilll occurs. c.ll ahc Nrliond ncNne C.racr. tllL.l2Stt02. I If r rpflf ecun, cdl the Nilioml R6Dons C4trter, A(/.[4,/-88f/2.
lnrll
Rcnrrks: ' Hydrolizesslowly with cold wat6r; trothing with hot wal€r
I Umvailable
I
Ita
MESITYLOXIDE METHACRYLICACID
Synonynt- lsobutenylmethyl ketone; Unlt€d Natiors NuDber _lzp_ Synonyms-alpha-Mothacrylic acid; 2-M€thylacrylic Urltcd Nrtions Nunb€r . . . . . . . . . . . . . ._._. .2. .5. 3 - 1
t
lsopropyliden€ac€tone;Methyl iso-butenylketone; acid; 2-Methylpropenic acid; 2-Msihylpropenoic
Methyl isobut€nylketone; 4-Methyl-3-penten-2-one; acid; Propenioic acid, 2-m€thylene
Fo-Propylidemacelono
CHRIS Code................. MSO CllRlS Code................. ....................
__uaD_
Formulr-CHr : C(CH!)COOH
Fonule-(CHshC : CHCOCH3
8oi1in8Po|nt..........................130"C 266'F lloiling Polnt.. .............. 16 1 " C 325'F
AlDerrrnce-Odor-Oily, colorless liquid;honey-likeodor -s9:3 ADlnrrnce.Odq-Water-while liquid with e vinegar-like
Fr@zingPoint......... -^:F mor FczlnS Polnt ........... ra'c st"r
SpeciticGrsvity-o.86 -'c -'F SDecific Grralty-l,015 _'c _"F
vaDor Prsure 20'C (68'D (nnHg).......... -9.J- Vrpor Prwure 20"C (68"t) (mmH9... . . . 1
ChemicslF.mily-Ketones Chenicd Frnlly-Organrc acrd
R e i d V a p o r P r s u r e ( D s i r ) . . . . . . . . . . . . . . . . . . . . .t. . . . . . Reld Vepor Presure (psia)......... ...... 0.048
Vspor Prsure 46'C (f f5'F) (psia)............. --Q€Z- Vrgrr Presure 46'C (ffs'D (psia).............--0!92-
D Pollualon Cta.to.y-tJSt:PA - IMO O
PollutionCrtegory-USEPA - IMO V r p o r D e n s i t y ( A t:r 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . 3. ...5. . . V a p o r D e n s l t y( A t r : t . 0 ) . . . . . . . . . . . . . . . . . . . . . 2 . 5
Applicabl€Bulk Reg.,15CFR SubchsDt€r..... Solubilityinwrtcr..................... Sliohl Applicrble Bult R.s. ,16 ('l'R sub(hrDte......... O SolubitityinWster........................, Soluble
FIRE & EXPLOSION HAZARD DATA HRE E EXPLOSION HAZARD DATA

Grade-D: Combustibleliquid GndFE: Combustibl€ houd
Electrical Group-D Electrlcl Gnt+D
Generd-Flammable, dang€rousfire risk, vapor forms explosive mixlure with air. Flashback along vapor trail Gercrrl-Moddrte lo dangerou! when h€6ted to d€composition, emitting toxic lumes.
may occur. Vapor may explode if ignitsd in an enclosed area.
F l s h P o i n tC n . . . . . . . . . . . . . . . . . . . . . .8. 4. . . . . . Fluh Point ('l) .................... 171

Flsmmsble L|ntts.......................... 1.3 to 8.8olo Fhnmsble Llnlar. .. .............. 2.'l lo 12 6%
Autoisnition Tefrp.('F)................ 652 AutolgnitionTcnD.('F)......... Unavsilsblo
Extin8uishing Agents..................... Alcoholfoam,carbondioxideor dry chemical Ertln8ulrhlns A3cnts ....... Alcohol lo!m, Co,, dry ch€micals or water spray.
SpecialFire Pr@edur6................Wear complete protective clothing and self{ontained breathirE appatatus. Flrc Prcrdur6....... High lempatrlures givs oll ioxic acidic fumos. Wsar sell-containedbrealhing
Cool exposed tanks with wat€r. Water may be ineffectiveon fire. apparatus,and lull protoctrveclothing.

Heslth Hud Rrthgs Odor Thrchold (ppm) PEL,/TIVA (Dpn) TLV,zTWA (ppn) H€dth Hrad Rrttnsr (Xor Threshold(Dpn) PEL,/TWA (Dpm) TLV/TWA (ppD)
't2 15 15 Unavailable 5 20 20
3 . 3 .3
toxic by ingeslion,inhalation,and skin absorption are mildly irritatingto lhe eyes; the liquid is strongly corrosiv€ to the skin and eyes.
SymDtoms-lrritationof eyes, headaches,coughing,difiicult brealhing, nose and throal irritation,mild Synptoms-lrritation of eyes, nose and throat; skin may experiencea slight burning sensation.
intoxication.
Short ExposureTolerance-s minutes-1oo ppm predicted ey€ and mucous membrane irriiationwith difficult Short Erleure Tolersnce-Unavailabl€
breathing,headache.Similarexposureat 800 ppm. Predictedsevere eye and respiratoryirritation.Vapot
conc. 500 ppm tor 30-60 min. considereddangerousto lile.
Erp6ure Prcedug-lmmediatdy remove victim from exposure and treat on symptomaticbas€s. Flush skin Expcure Prcedurc-Move victim to fresh air, keep warm and quiet. Eyes-llush with water lor al least 15
promptlywiih soap and water. lf swallowed,do not induce vomiting.Get medical attenlion. minutes.Skin-llush wilh water then wash wiih soap. Ingestion-do not induce vomiting. Call a physician
immediaiely.
REA(NIVITY DATA REACTIVITY DATA

Stsblllty-Stable. Reacts with oxidizingagents; strong alkalis (caustics),and mineral acids. Stability-Normally stabls; however, il stored above 120'F for long periods of time, il can polymerizeviolently,
giving off heat. Reacts with oxidizers.
Com9.dblllty-M.teri.l: Non-corrosivelo steel. Crntntibility-Mrterial: Corrodes sleel, wood, cloih and paint. Glass, 3O2, 304 and 3j6 stainlesssteet are
suitable.
C*go: Group 18 ol compatibilitychart. See also Appendix l-Exceptions to the Chttt C$go: Group 4 of the compatibilitychart.

Waar rubb€r glo\re!, lace shi€ld. proloclive clothing. Havs ell-purpoao canlllcr mlak lnlLbL. Avold conLcl Woar rubber glo\re8,rprons, bmts 6nd acid goggleg. Avdd skin conlact and prolong€d oxposuro !o vapors.
wlth liquld.Secura lgnilion sourco!. N€uiralize spills wllh !od! alh and flush wilh water.
lt a rDlll ccrn. cdl thc Nrd6d Rouc ('cnt... flxFal+

I ll r r||lll qcurr, ..ll lh. N|.lond (tnict. dXt-02+tE02.
l lltlrvnrlabb ntorhi Molhacryhc r.(l rs n{)ilntrlly rrlrtnl(xt w,th hydroquinono or lho rn(,thyl elhot ol hydroqutnona
krrh:
I
f'e"'""*"*" ,- -,-, -,
ti6 SCANNED BY MKP & BARIS A. 2004
METHACRYLONITRILE
METHANE
synonyn$- 2.Cyanopropene; lsopropene cyanide: United Nationr Number 3079
SynonynrMarsh gas; Methyl hydridet Natural gas UtritedNstions Number... compressed 1971
MAN; 2-Proponsnitrile, 2-methyl-
refrigerated 1972
CHRIS Code................. MET

CHRIS Code............ . . __ldlr_
Fornuh-CH: : C(CH3)CN
Fornule-CH.
B o i l i n gP o i n t . . . . . . . . . . . . . . . . . . . . . . . . . 9 0 " C 195'F
-259"F
Bollln8 Point............ 162'C
Appearance.Odor-Clear, colorless iiquid; no
FreezingPoint......... 36'"3 *:i Appearence-Odor-Colorlessgas: mild, 3we€l odor -fizc
appreciable odor
_'c _'F Frezing Polnt.......... zg6'r
SDecilic Grsvity-o.80 "c 'F
SpecificGrsvity-O.42 at 160'C (a liquid)
VaporPressure 20"C(68'D (mmHO.......... 48.3
chemicrl Family-Cyanides R e i dV a p o rP r e s s u r(eD c l o ) . . . . . . . . . . . . . . . . . . . .7.'.6 4 VoporPrwure 20'c (68'l') (mmHg)..........V. Hioh
Chenicsl Frnily-Paratf in Reidvrlpr Prsure (psir).......... ...... V. Hioh
VaporPressure 46"C(ll5'F) (psi8).............10.8
Pollutiotr crtegory-UsEPA C Ilto B v a l D r D e r s i t y( A i r : f . 0 ) . . . . . . . . . . . . . . . . . . . . . .1. .1. .7 vrpor Prsure 45"C(115'F)(p6ia)....... V. Hioh
Pollution Crtegory-USEPA - IMO oas V r p o r D e n s i t y( A i r : f , 0 ) . . . . . . . . . . . . . . . . 0.55
Applicable Bulk Reg. ,|6 CFR Subchrpt€r....... O S o l u b i l i t y i n W s t e r . . . . . . . . . . . . . . . . . . . . . . .2. 6 7 "
ApplicableBulk Re8.il6 CFR Subchipter.. ... D. O S o l u b i l i t y i n W r t e r . . . . . . . . . . . . . . . . . . . . .N
. .e o l i o i b l e

crade-Ci Flammable liquid
Grsde-Liquelied FlammableGas (LFG)
Electrical Group-NA
Eletrical Group-D
General-Very flammable; tends to polymerize violently rather than burn. D€composes to toxic products.
General-Unless the tlow of gas can be stopped, putting out a meihane lire will p€rmit the accumulationol an
Flashback along vapor trail may occur. Vapor may explode il ignited in an enclos€d area.
explosive concentrationol vapor and subsequenl explosion or retlash.
F h s h P o i n t { ' F ) . . . . . . . . . . . . . . . . . . . . .5.5. .
F t c h P o i n t ( ' D . . . . . . . . . . . . . . . . . . . .- .3. O
..o
...
Flimmable Limits.......................... Unavailable-tends to polymerize violently
I'lumable Limits.......................... 5.0 to l 5%
AutoiSnition TeDD. ("F)................ Unavailable-tends to polymerize violently
fog, alcohol foam, CO:, dry chemical
AutoignitionTemp.('F) ................ 1000
Extinguishing Agents..................... Water
ExtinguishinS A8etrts..................... Stop flow ol gas; Water,COr, or dry chemical
Specisl Fire Prcedures................ Wear sell-contained brgathing apparatus and protectrve clothrng. Use water to
Sp€cislFire Preedures................Keep burning tank and melhane tanks adjacent to it cool with a water spray.
cool exoosed containers.
Stop flow ol gas.
HEALTH HAZARD DATA

Health Hrrud RstinSs odor Threrhold(Dpm) PELITWA (ppn) TLVAWA (ppm) HEALTH HAZARD DATA
1' l/Skin
'llskin Health Hrard Rrtings Odor Threshold(ppm) PEL,/TlryA(ppm) TLVITWA (ppn)
Unavailable
0, 0,0 200 Unavailable Unavailable
Genersl-Very toxic, avoid all contact.
Generrl-Simple asphyxiant.Br€athinggas may cause unconscrousnesswithout warning because ol lack ol
oryg€n.
Symptoms-Only moderatelyirritatingto eyes and skin. lnhalation:Weakness,headache, confusion,nausea,
SymptoeLiquid can cause troslbite on skin contacl. High gaseous concentrationsmay cause asphyxiation.
vomiting,respiratoryparalysis,convulsions.
No systemic effects, even at 57o concentration in air.
Short ExposureTolerance-
Short ExposureTolerance-Unavailable
ExDcure Proc€dureo-Get medical attention.Inhalation:Remove to fresh air, create artilicial aiMay it needed.
ExtDsurePrcedures-Flemove lo lresh air; if breathing has stopped, apply artificial respiration.lf the tiquid has
Eyes: Flush with water lor at least 15 minutes.Skin: Wash with soap and water twice. Medical personnel
spilled onto the skin, points of contact may be frostbitien; handle genlly and proteci lrom mechanical
should wear protectiveclothing.'
damage. DO NOT RUB. Gel medical attention.
See MedicalKit Information.
AopendixB
REACTIVITY DATA
Stability-Generally stable except when heated. Polymerizeson prolongedexposure to light. Reacts with REACTIVITY DATA
Stsbiliry-Stable.
oxidizersand reducers.
Compatibility-Msterial: Suitable:lron
Comprtibility-Mrterld: Non-corrosiveto st€l
Crrgo: Group 15 ol compatibilitycharl.


Avoid all contact, including vapor. Remove all ignition sources. Absorb with clay, €arth, sawduEt.Otspota by
Have all-purposscanisler mask available.Avoid contact with liquid. Secure ionition sourc€s. ll methane doog
authorized incineration or landfill. Wear gloves, goggles, rubber aprons and bmts, sell-conlsrnod b.oolhlng
not calch tir€, it will soon boil olt.
apparatus.Wash clothing before reuse.
lf . rDill (rcccB. crll thc Nrtionrl n6DtrE (tnt(r. &XHAim2.

ll r rplll ccun, c8ll tbe Nrtlond Crntcr. Eln-{24-8802.
'
Rcmrrlr: NOIL Doloclat)lo odor an(! TIV aro lho $atru, lhsrslore odor rs nol o rolrabl€ molhod ol
lrolr:
doltrlrng hrzardour conccnlral|ona
Irl
SCANNED BY MKP & BARIS A. 2004 It9
METHOXYTRIGLYCOL METHYLACETATE
Synonyms- 2-[2-(2-Methoxyethory)ethoxy]ethanol; United Nstiors Numb€r Synonyms- Ac€tic acid, methyl estsr United NstioN Numb€r ........ 1231
Trigthylene glycol methyl ether
CHRIS Code................. ..........

__MrG_ ('llRlS Code.. . . . . . . . . . . . . . . . . . .M
. TT
Fomuh-CHrO(G,H.O)sH Fomulr-CHTCOOCHT
B o i l i n s P o i n t . . . . . . . . . . . . . . . . . . . . . . .2. .4. 9 ' C 480'F
Bolllng Polnt .. 54'C 129'F
Appesuce-Odor-Colorless liquid; mild odor --qq'c liquid: lragrenl odor --ga"q
Frezing Point........ -q7'r -ru"r
Freezhg Polnt
Sp€cilic Crsvity-1.05 _'c _'F Specific Grrvlty-0.92 _'c _'F
Vapor Presure 20'C (68'D (mmH8).......... Low
C'hemicd Fmily-Glycol
Vrlnr Pruure 20'C (58't) (mmHg)..........--JZ9-
ether Reid Vapor Prsure (psis)..............,.,.......... Low C'hcmlcd Frhlly-E3ler 4.6
Rcld Vrpor Praurc (Doir),..........................
Vlpor Pressure '16'C (f15"n (psir)......... . Low
Vrpor Prcuure,l5'C(lls'F)(D!is)............. 6.1
Pollution CateSory-USEPA - IMO O Vrpor Dencity (Alr : 1.0)......................
. 5 66 lll
Pollutton CrteSory-USEPA - 11119 Vrpor Dculty (Alr : 2-6
1.0)...........................
Applicable Bulk Reg. 45 CFR Subchspter........ D SoIubi1ityinWrts.........,,.............. Comolet€ Slioht
ApDlic.ble Bulk Rcj. 116CFR SubchrDlcr... . D Solubtllty In Wrter .....
FIRE & EXPLOSION HAZARD DATA I'IRE & T|XPLOSION HAZARD DATA
crrde-E: Combustibleliouid Grede-C: Flammableliquid
Eletrical Group-C Eletrlcel GrouD-D
C€nerd-Moderaie fire hazard if exoosed to heat. Gcnerel-Oangerous, when orpossd to h€at or flame. Flashbackalong vapor trail may occur. Vapor may
oxplod€ if igniled in an onclosed area.
F l s h P o i n t( ' n . . . . . . . . . . . . . . . . . . . . . .2. .4.5. . . . F l s h P o l n (t ' n . . . . . . . . . . . . . . . . . . . .1. 4 .....

Flumable I.imits.......................... Unavailabls F f r n m b f € L i h i t s . . . . . . . . . . . . . . . . . .4. .l .o. . 1 4 " / "
Autoignition Temp.("F)................ Unavailable AutolgrldonTemp,("F)................ 850
Extinguisbing Agents..................... Alcoholfoam ErtlrgulshinSAgents.................... Alcoholfoam,dry chemical,or CO,
SpecislFire Prcedurd................ Unavailable SDeclrlFire PrGedures................ Water may be ineftectivedue to low flash point, but water should be used to
keep fire-exposedcontainers cool. It a leak or spill has not ignited, use waler spray to dispense the vapors
and to protecl men atlempting to stop a leak. Waler may dilute spills to non-flammablemixtures.

Health Haard Ratirg Odor Threshold (ppm) PEL,/TWA (ppn) TLV,/TWA (ppm) Heslth H@rd Rltings Odor Thrshold (ppn) PELAIryA (ppm) TLV,/TIVA (Dpm)
0.0,0 Unavailable Unavailable Unavailable 2,0, 1 Unavailabl€ 200 2OO
G€n€r8l-No heallh hazard under normal conditions of handling. Generd-Skin conlact with liquid causes delatting and cracking ot skin. Vapor irritating.
Symptoms-lrritalion of respiratorypassages, eyes, diziness, depression, burning of eyes.
Short Exlsure ToleruceUnavailable Short Ex!ffure Toleruce-4oo ppm lor unknown duration.
ExDque PrcedueEye contact-flush gently with water. Get medical advice it any discomlort. Ex!reure Prcedurc-lf the eyes are atfected, irrigatecontinuouslywith water for at least 15 minutes. Obtain

Stlbility-Stable. Stabiliry-Stabls.
Comldibility-Matsld: Usual materialsol constructionare suitable. ComFtibility-Msteridr Compatiblewith common materialsot construction.
Crrgo: Group 40 ot compatibilitychart. Cugo: Group 34 of compatibilitychart.

Avoid conl,rcl with liquld. wsar rubb€r glovas, face shield, protective clothing. Have all-purpose canistsr mask availablg.Avoid contact
liquid. Sscure ignilion sourcas.
lt I xall 6sr. c.ll th. ltrthr..l ll r rglll ccun, crll the N.tlord C.!ier. 8m-424-Et02.
lenrrlr I lrrrrrr{rrft, t. n.r l.
liro
METHYLACETYLENE.PROPADIENE
MIXTURE METHYLACRYLATE
1060 Synonyru-Acrylic acad,methyl estsr; M€thyl
Synonymr- Allene-methylacetylene mixture;MAPP UnitedNrtio$ Nmber................ propenoate:Methyl 2"prop€noate;2-Propenoicacid
Gag; Methyl acetylene-allenemixture; methyl est€r
Propadiene-methylacetylene mixture;
Propyne-allenemixture
CHRIS Code.. MAP
Fomuh-CH, = CHCOOCHs
Formula-CH"C-CH, H1C:C:CH, plus other C-ss -'c "F Bolllng Polnl . . . . ....80'c 17 6 ' F
and C-4s, saturatedand unsaturated. Boiling Poirt..
Apprcarance.Odor-Colorl$sliquid;ahatP pungent odor _'c _'F
Appearuce.odor-Colorless gas with musty odor _'c _'F
"'c ""F lreerhl Point ........ -75'C -103'F
Freezing Point
SDecilicCrrrlty-o.95
SpecificGrrvity-o.58 _'c _'F
Vrlnr Praure 20'C (6t'D (mnllg.......... ---09€-
vsDo. Pre$ure20'c (68'F)(mnHd.......... 5620 Chenicd Frhily-Acrylalo!
c'hemical Fmily-Hydrmarbon (Olsfin) 1 65 R c l dV r p o r P r w u r c ( p r l e ) . . . . . . . . . . ... . . . . 3.1
R e i dV a p o rP r s u r e ( p s i 8 ) . . . . . . . . . . . . . .....
Vrlnr Prwurc 46'C (f l5't) (prie)............. ---!l-
VaporPresure,16'C(us"F) (psia).............Hioh Pollutlon C.tegory-USl:PA --- IMO B
15 Vrpor Deulty (An : 1.0)........................... 3.0
Pollution Category-USEPA - IMO ----9gS- VaporDensity(Air : 1.0)...........................
ADplloblcBulk R3t il6 ('l'R Srb.hrpld.,... . O SofubflftylnW.ter.......................5 . .. 2 " / "
ADplicrbleBulk Re8,,16CFR suDchspter.. . .. O solubilityinwrter......................... Noolioible
I.'IRI] & I]XPLOSTON HAZARD DATA

FIRE & EXPLOSION HAZARD DATA Flamm6bl€ [ourd
Gr8de-Liquitied FlammableGas (LFG) Eladcd Group--D
Elstricsl GreuD-C
cnl-lrriiiting vapo.8 a,e genefalsd in lires. lgnit€d by heat, sparks or open llame. Fire may cause violent
Genersl-MAPP gas is highly flammablebut nol shock sensitive.Unless lhs llow ol gas can b€ stoppsd, puning rupturo of tanl du€ to polymerizalion.Flashback along vapor trail may occur.
out a MAPP gas fire will permit the accumulationol an explosiveconcsnirationof vapor, and subsequ€nt
explosionor reflash. F l $ h P o l n (i ' n . . . . . . . . . . . . . . . . . . .1. 8
. .l.o 2 7
Flammabl€gas
Flsh Point CF)............................. Flsmm.blcLfniit .............. . . . . 2.8 to 25"h
3.4 to 10.8ol"
FhmmsbleL|mits.......................... Autolslltlon T r c p . ( ' F ) . . . . . . . . . . . .8
. 75
850 Erth8ulrhln843cntr............. CO,, dry ch€mical,foam,watsr log
Extinguishin8 Stop flow of gas; Water,COr, dry chamical
Agents..................... Specld Flrc Pu.aril...........,.,.. C@l trnk with a water spray. Supply lire parties with body and respiratory
Use water spraylo cool burningtank and adjacentMAPPlanks.
SpecialFire Procedurc................ o.otection.
HEALTH HAZARD DATA

HEALTH HAZARD DATA Hcrlth Hrrd Rrtinss odo. Ihqhold (ppm) PLL,/TWA (pDm) TLVAWA (ppm)
H€rlth H@rd RatinSs Odor Threshold (ppn) PEL,/TWA (ppm) TLV,/TtryA (pDn)
3,2,3 20 lo/Skin 1o/Skin
Unavailable 100 Unavailable Unavailable
Genenl-Vapor sever€ly irritating.Liquid may caus g€vere damage trom prolonged skin contacl.
General-The toxicity of MAPP is similar to lhat of propane and acetylene.
Symptoms-Watering ot eyes, severe burning sensation of lhroat and nasal passages, coughing and sneezing.
Symptoms-Conlact with MAPP liquid may cause frost-type burns.
Short ExposureToleruce-25 ppm for 30 minutes.

Short ErD6ue Toleruce-Toxicity is slight, but high concentralions(5000 ppm) can have an an€slhelic effecl.
Exlmure Prcedures-Vapor-remove victim to fresh air; il breathing stops, apply artificial respitation.Skin or
ExposurePrcedurc-Remove lo tresh air. Give artificial respirationif breathing stops. lf liquid has spilled onto eye contact-remove contaminatedclothing and gently tlush aff*ted areas with water for 15 minutes. Gel
the skin, points of contact may be f.ostbitten; handle genily and protect from mechanical damage. DO NOT medical advice or attention.
RUB. Get medical attention.
REACTIVITY DATA
REACTIVITY DATA Stability-Methyl acrylate will polymerizereadily, unless inhibited,evolving considerableamounts ol heat. At
St8bility-This cargo is slabilized. high temperaturesii may polymerizeeven though inhibiied.
ComDstibility-Msterial; Usual materials of constructionare suilabls.

Comprtibility-Mrterid: Alloys containingover 67o/"copper should not be used.
C&go: Group 14 ol compatibilitychart.

Cargo: Group 30 ol compatibilitychart

SPTLLOR LEAK PROCEDURE
Wear rubbor glovoS,fac€ shield, protective clothing. Havg all-purpose canister mask available.Avoid contacl
Avoid contact wilh lhuid. Ssur€ igniiion sources. wilh liqurd.Secure igniiion sourc€s.
ll . rllll '{cun cll th. Nralond Ccrtcr. t{Xl{*ttll2.

ll r qlll rxrwr. crll lL N.llql llr.a Cr!r. u-a:blto2.
' ll.r.rl.
lrryb: Hohrrg lltrpo llt t(t ?O (. :ltl t() l'F
" ll.,na l0l to tol lo
[.xrr{ llrc, ?la'F.
In SCANNED BY MKP & BARIS A. 2004 t9J

METHYLALCOHOL METHYLAMINESOLUTION.4OOIO
Synonyms-Aminomethane; Monomethyl amina
Synonyns- Alcohol C-'1; Carbinol;Colonialspiriis; 1230
UnltedNrtlom Numbcr................................
Columbianspirits; Methanol; Methyl hydroxide;
Pyroxylicspirii; Wood alcohol; Wood spirit
CHRIS Code.........................
Fornulr-CHrNHz
Fomuh-CHTOH 48'C 118'F
148'F Bolllng Polnt.. ....
Bolllng Polnt . _____.04'c ApDe|roe-Odor-Weler whils to pale tlrew color: _'c _'F
ADpernnce.Odor-Colorlessliquid;sm€lls like win€ or _'c _'F fishy or ammonlscd odor ........ -38'C -36"F
Po1n4....................... -98'C -144'F l'reezlng Polnt
shellac thinner FGzltrB 'c
Speific Gravity-0.79 _'c _'F
SD€clficGr.vlty-o.807 _'F
Vrpor Praure 20'C (6t'n (mnHg)..........--245-
Vrpor Prourc m'C (68"n (mmHg..........--JJIQ-- Ctedlcl Fully-Aliphatic lr{naa
Chemicd Fsmily-Alcohol 4.5 R e l d v . ! D r P r $ u r e ( p s i r ) . . . . . . . . . . . . . . . . . . . . . . .1. 0
...
Rcld Vrgor Prilur. (!f,|.).... .. . ..
Vrpor Proure,l6'C (f t5'F) (Dsin)............. 13
Vrror Puurc aS'C(f f!'n (D.lr)............. 7.0 Polluilon Ctitacy-UsllPA - lM(, C
PollutionCrteSory-USEPA D IMO lll ( A l r : 1 .1'l V r F ) r D c i l l l y ( A l r : 1 , 0 ) . . . . . . . . . . . . . . . . . . . . .1. . .O. .7.
V r g o rt h n d t y t . 0 ) . . . . . . . . . . . . . . . ..
ADpllc.bleAdl ncf; a6 ('t'R Sub.hrDtcr O Solublllty ltr Wrier........ Comolete
ADplicrbleBult Reg.il5 CFR Subcheptcr........
--A- Solubility in Wrl.l ........ Comolet€
FIRE & F]XPI,OSION IIAZARI) I)ATA

Grrda-B: Flammabloliquid
Grrdc-C: Flammableliouid
Elctrlcrl GrouD-O
ElecHcd Group-D
G.nenl-Vapor v€ry flammable.Whon hoatod, can docompose to loxrc nrtrogenoxidos. Flashback along vapor
Geileral-Methyl alcohol is a tlammableliquid.At "room" tomperatur€,giv€s otl a vapor which is both loxic and,
trail may @cur. Vapor may explode il ignrled In an €nclosed area.
when mixed with air, sxplosive within csrtain limits. Flashbackalong vapoi trail may occur. Vapor may
explode il ignited in an enclosed area.
F l s h P o l n l( ' n . . ............ l0 (cc)
F l s h P o i n tC F ) . . . . . . . . . . . . . . . . . . . .6. .1. . . . . . .
Il.mm.bl. Llmltr. . . ............. 4.4 lo 2O.7%
Flmnrble Limtts.......................... 5.5 to 36.5olo ('t)..........
AutolgrltlonTcmp, . . 806
Autoignition TenD,('D................878
ErtlntubhhS A8c!1r..................... Alcoholtoam, wator spray,COr, dry ch€mical
ExtirguishitrgA8crts..................... COr, dry chemical, alcohol toam, waler log
SDeld Flre Prerdru................ Wear prolectivo clothing, solt-conlain€dbrsathing apparalus and eye
Sp€cialFirc Procpduro................Avoid brealhingvapors. Provide body and respiratoryprotection for tire pfotclion.
parties. Keep tanks cool with waler spray. Water may not be effective unless large quantitiesare used.

Hedth Hurd Rrttngs Odor Thrcbold (ppn) PELITWA (ppm) TLV,/TWA (Dpn)
Health Haed Rttings Odor Threshold (ppm) PELAwA (ppn) TLV,/TIVA (Dpd)
Unavailable O.O21 10 10
1. 1. 2 50 to 2000' 200/Skin 200/Skin
Genersl-Vapors are highly iritating and toxic.
Generd-Vapor inhalationdangerous.May be aberbed through skin. Poi$nous if swallowed.
rDtoru-lngestion: Digestivetract burns. Skin: Initation, dermatitis,burns. Eyes: lritation, burns, pulmonary
SymDtoms-Dizziness,unconsciousn€ss,and sighing respiration.
edsma. Inhalation:Sneezing,coughing, burning chest pain.
Sbort Erposur€Tol€mceAs little as 20-100 ppm causes eye, nose, throat irritation.Vapor it so irritatingthat
Short ExpocureTolerur'1000 ppm lor t hour has caused headache,eye irritationand tatigue.
people do not voluntarilycontinue hazardousexposure.
ExposurePr@edurFcet medical attenlion. Eyes and skin: Flush with watsr al least 15 minutes. ll skin burned,
ExposurePrmedreRemove victim to fresh air. Give artificialrespirationif breathing stops. Skin or eye
do nol cover 01 apply ointment for tirst 24 hours. Inhalaiion:Remove to tresh air with moulh to mouth
contacl-remove contaminaledcloihing. Flush affected areas genily with water for 15 minutes.Get medical
resuscitationor orygen il needed. Ingestion:Oo not induce vomiting. lf conscious, drink water.
advice or attention.
'NOTE; Odor threshold is not
consideredadequale warning ot potentialdangerous vapor concentrations.

Strbility-Stable. Can react with acids and oxidizers.
Stsbility-Stable. Can react vigorouslywith oxidizingmatsrials.
ComD.tibility-Msterill: Suitable:Stainless steel, mild steel, iron. Unsuitable:Aluminum,copp€r, zinc,

ComDrtibility-M.terid: Compaliblewilh most materialsof construction.
magnesium.
Cugo: Group 7 ol compatibilitycharl.

Crgo: Group 20 of compatibilitychart. See also App€ndix l-Exc€plions to tho Chart

Avoid contact includingvapor. Secure ignition sources and dilute with waier or use absorbent malerial. Wear
Wear rubb€r gloves, prot€ctivo clothing. Havo all-purposecanisler mesk available. Avoid contecl with liquid
hat, ssfety gogglss, tace shi€ld, rubber gaunilet gloves, rubb€r apron, rubber safety sh@s or rubbsr boots,
Secure ignition sources.
breathing apparatus,as nsed€d. Do not flush spills into contined spaces where tlammable vapors
accumulale. Ksp lrom enioring walgMay
li . rDlll acun cdl ttc N.tlood Remre Center. 6m-424-8E02.
| .Dlll mcur!, cdl aha Nrtlor.l R6MF Ccntcr. t{XL/424-tm2.
&rrrtrl

METHYLAMYL ACETATE METHYLAMYL
ALCOHOL
Synonymr- 1,3-Oimethylbutyl acetate; sec-Hexyl Synotryms- lsobutyl msthyl carbinol; lsobulyl methyl Unlled Natlons Nunber............................... 2053
acalat6; MAAC;Methyl iso-butylcarbinol acelate; methanol; MAOH; Meihyl iso-butyl carbinol;
Mothyl iso-butylcarbinyl acetate; Methylisoamyl 4-Methyl-2-p€nianol; MIBC; MIC
ac€tete; 4-Methyl-2-pentanolacetate;
4-Methyl-2-pentylacelate CHRIS Cod.. ....... Mtc
Fornuh-CHTCOOCH(CHr)CHTCH(CHs), Fornulr-CH3CH(OH)CH,CH(CHth
BoilingPoint......................... 146'C 295'F
Bollllg Polrt.. 132"C 269'F
App€$rnce.odor-Water whit€ liquid;mild fruity odor _"c _"F
64"C 83'F ADpe.mcc-Odor-Colorless liquid; mild alcoholic odor _'c _'F
Freezing Poinl....................... Fcdng Point -90'c - 130'F
Spcific Gravity-0.86 _'c _"F 'c 'F
SDecific GrrYlty-O.81
Vrpor Pressurem'C (68'F)(nmHg.... .... 36
VaporPrwure 20'C (68'F)(mmHg).......... 3.8
Ctenic8l Fuily-Esler Reid vapor Pressure(psi.)......... Chemicsl l'rnily-Alcohol O-2
0 34 Reidvspor Presure(Ddia)...........................
VeporPressure 46'C (f15'F) (psia)...........
.
C 5'0 Vlpor Presure46'C (f15'F) (psia)............. ---Ql-
PollutionCrt€gory-USEPA - IMO VrDorDeNity (Air : 1,0).......................... Pollutlon Cat€gory-USEPA - tMO C V r D o rD e n s i t y( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . 3 5
ApplicrbleBdk Reg.{6 CFR Subchrpter....... D O ... . .
Sofulitityio Water................. Neolioible
Appltcrble Bulk Rc8. {6 CFR Subchrpier...... O. O S o l u b i l i t y i n W s t e r . . . . . . . . . . . . . . . . . . . . . . . 1. .. a o / .
Grade-D: Combustibleliquid Grrde-D: Combuslibleliquid
ElectricslGrouD-D Elctrlcel Group-D
cenersl-Flammable, moderate fire risk. Genersl-Mod€rate hazard,when exposed to heal or flame.
F l s h P o i n t( ' n . . . . . . . . . . . . . . . . . . . . .1. 1
. .0 F l s h P o i n t( ' F ) . . . . . . . . . . . . . . . . . . . . .1.3. .1. . . . .
Fhnmrble Limits.......................... 0.9 to 5.7% (calculated) Flmnrble Limits.......................... 1.0 to 5.5"/"
Autoignition Temp.('F) ................ 510 (calculated) AutoiSnition Tenp. ('F)................ 583 (calculated)
Extin$isbitrg Agenb Conlined area-Cq, dry chemical.Open alea-foam, water spray ExtinguiEhingA8entr..................... CO,, dry chemical, alcohol foam, waler fog
speid Flrc Prcedur6................ Water may be inetfoctiveon fire. Cool exposgd tanks with waler. SDecidFlre Prccrduru................ Provide tire parties with respiratoryprotection il they must enter spaces to
fighl the fire.

He8lth Hred Rotitrgs Odor Thrqbold (pDm) PELAWA (ppm) TLV,/TWA (ppm) Herlth Hred Ratings (ppm) (Dpn) (Dpm)
Odor Threshold PELlTtryA TLV,/TWA
2,1,1 Unavailable Unavailable Unavailable 1. 1. 1 50 2slskin 2slskin
Cererrl-Moderately toxic by ingestionand inhalation,can cause skin irritationon prolonged exposure. Gererd-Essentially an anestheticwilh little or no cumulativetoxicologicalproperties.Prolongedcontacl with
liquid may produce drying and cracking of the skin.
Symptorlrritation of r€spiratorypassages,vomiting, dizziness,depression,burning of eyes. Symptoms-Burningol nasal passages and walering ol eyes, burning or itching al site ot skin contact, dizziness
or drowslness.
Short ErD6ure ToleraocFAnimal tests: No primary skin irritation,traces ol eye inflammation;4 houl exposure Short Expcure TolemcF2900 ppm cause immediateirritationo, the eyes, nos and throat; 2-4 hours,
inhalationkilled 1 out ot 6; I hours exposure killed 5 ol 6. narcosis;8-10 hours, profound depressionand possible death.
ExposurePrcedures-lngestion-induce vomiting. Inhalation-remove victim to fresh air and adminasteroxygen Exlmure Pruedurs-Vapor-remove victim to tresh air; it breathing stops, apply artificial respiration.Skin or
if necessary.Eye or skin contact-llush gently with water for 15 minutes.Get medical atlention. eye contacl-remove contaminatedclothing and gently flush atlected areas with water for 15 minutes. Get

Stlbility-Slable. Stability-Flelatively stable.
ConDrtibility-M.terirl: No etfects on steel; will swell rubber and can dissolv€ certain coatings. Compstibility-Mrtcrid! Most malerials of conslruclion are satistactory.
cuSo: Group 34 of compatibilitycharl Csrgo: Group 20 ot compatibilitychart.

Wgar rubb€r gloves, protective clothing, face shield. Have all-purposecanislst mask evailabl€.Avoid conleci Wsar rubber gloves, face shield, protective clothing. Have all-purposecanist€r mask available.Avoid contsct
wilh liquid. Secure ignilion sources. with liquid. Secure ignition sources.
ll a Dlll acuE. cdl ahc Nrliotrd R6ptr& ( enlrt,

I rDlll ecuB, cill ahe Nrtlond
n.n.rb: lrrlr:
re6
SCANNED BY MKP & BARIS A. 2004 le7
METHYLBROMIDE METHYLCHLORIDE
Synonyms- Bromomethane; Embalume; Methane, Unit€d NstioN Number __l_qae_ Synonyms- Chloromethane: Methane. chloro- UnitedNationsNumber......... 1063
bromo-; Monobromom€lhane
CHRIS Code.. MTB C H R I SC o d € . . . . . . . . . . . . . . . . . . . . . . . . . . MTC
Formula-CHsBr Formula-CHgCl
Boiling Poirt.. 5'C 40"F Bolll4 Point..........................
Appearance-Odor-Colorless liquid; sweet, _'c _'F gas or liquid; laintly sw€sl
chlorolorm-like odor Freezing Point 93'C 135'F odor F r e e z h 8P o i n i . . . . . . . . . . . . . . . . . . . . . .-gz'c
.. -tqz"r
'c "F
Specific Gravity-1 .73 al 20"C (a liquid) SpecificGr8vity-o.92
vapor Pressure 20'C (68'n (mnH8)........ 1420 Vtlnr Prusure 20'C (68'F) (nmHg).......... 3800
Chemicsl Family-Halogenaled hydrocarbons Reidvspor Presure(Dsia).......... . ....... 45 Chemicrl Frmily-Halogsnaled hydrocarboni
R c l dV r l n r P r e s u r e ( p s i a ) . . . . . . . . . . . . . . . . . . .1. 1. .6. ...7. .
vapor Pressure il6'C (lts'F) (Dsis)........... 60 VeporPwure 46"C(fls'D (psir)............. 142
Pollution Cstego.y-USEPA C IMO ---g!ls- VeporDensity(A= i r. 1 . 0 ) . . . . . . . . . . . . . . . . . . . . 3 . ,2, .7, , , Pollution C.teSory-USEPA ---E- IMO -gA8_ V r p o r D e n s i t y( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .1. ...7. 8
..
Applic.ble Bull Reg. 46 CFR Subchspter........ O S o l u b i f i t y i n W a t e r . . . . . . . . . . . . . . . . . . . . . . .1. . 7 " h Applicrble Bult Reg.45 CFR Subchapter . O Solublllty in W.ler....... o.5%
Gmde-Liquelied CompressedGas (LCG) Grade-Liquelied Flammablecas (LFG)
Elettrical Group-D Electricd GroulFD
Generrl-Toxic and irritatinggases ar€ generalod whsn €xposad to haal or fire. Practicallynon-tlammable.Fire G€ne.8l-As wilh a Liqu€fisd FlammableGas, sxlinguishingthe fire wiihout stopping the gas leakage may
and explosionhazard is slight. increa$ the danger by permitling the accumulationof an explosive mixlure. lgnited by heat, sparks or open
tlame. Toxic and irritatinggasss are generaled in fires.
FlDh Point CF)............................. Virluallynonjlammablein air; burnsin oxygcn (Oz). F l s h P o i D t( ' n . . . . . . . . . . . . . . . . . . . . . .<. .3. .2. . .
F h m m s b lL
e i m i t s . . . . . . . . . . . . . . . . . .1. .0. t. o
. . .l .5 % Flmneble Limits.......................... 8.1 lo 17.2oh
AutoiSnition Temp.("D ................ 998 AutoiSnitiorTemD.("F)................ 1170
ExtirguishinS A8ents..................... Waterspray,dry chomical ExtirguisbitrS ASerts Stop flow ol gas; CO:, dry chemical, water fog
SpecialFire Procedurcs................ Cool tanks in vicinityol lire with a wat€r spray.L€akingtanks must not be Fire Praedures................Keop tank cool with water spray. Both the vapor ot the product and its
approachedunless wearing full body and respiratoryproteclion. combustion products are poisonous. Provide tirefighterswith respiralory protection and full protective
clothing.

Heslth H@rd Rstings Odor Threshold(ppm) PEL,/TWA (ppn) TLV,/TWA (ppm) Health Hrud Ratingr Odor Threshold (ppm) PELAtryA (Dpm) TLVAWA (ppm)
3, 3,4 Unavailable. s/Skin s/Skin 0,0,2 50 so/Skin
Generrl-Suspected carcinogen.Poisonousby inhalation.Etfects may be delayed. Liquid causes burns; may be carcinogen.Vapor very harmful. Liquid or cold gas may cause skin or eye injury similar to
absorbed by clothing, particularlyshoes, lo cause delayed burns. Class B poison. frostbite
SymptomFDouble vision, nausea, diziness, headache.Severe exposure results in convulsions,muscular rptoms-Dizinsss, slaggeringgait, drowsiness;recovery is slow. Froslbitten areas will be white. D€ath may
tremors, and possiblydeath. result trom a single high exposuro or repeated moderate exposuros.
Short ExposureTolerance-2o ppm tor 5 minutes. Expcure Toleruce-soo ppm lor 5 minul€s.
ErDosurePruedures-Remove viclim to tresh air. Apply artificiatrespiration il breathing stops. lf the liquid has
ExposureProcedures-Removevictim to lresh air. Administer artificialrespirationit unconscious.Oxygen spilled onto lhe person, poinls of contact may be lroslbitlen. Prolect any trozen areas from mechanical
administeredby trained personnelis often helpful. Get medical ailention immediately. damag€. Get medical attention.
t NOTE: Detectable
odot is greater than the TLV. Exposureto potentiallydangerous vapor concentrationscn
occur belore the oroducl can be smelled.

Stability-Formsaluminumalkylsin presenceof aluminum.Aluminumalkylsare spontaneously
ignitable stlbility-oecomposes upon contact with moisture.At high temp€raturesit may decompose tc phosgene,
materials. chlorine and carbon monoxide.
Conpatibility-Msterial: Not corrosiveto most relals. rDrttbility-Moterirl: when in contact wilh aluminum,the producl which forms may ignite spontan€ouslyin
air. Do not use aluminum,aluminum alloys, zinc, die castings, magnesium or magnesiumalloys.
CarSo:Group 36 of compatibilitychart. Cargo: Group 36 ol compatibilitychart.

Wear rubber glovss, self-contained breathing apparatus, protective clothing. Avoid contact with liqurd Wsar rubbor gloves, self-coniained breathing apparatus, proteclive clothing. Secure ignition sourc6s. Small
Personnslwithout respiratoryprolection must be kept upwind ol spill. spills will vaporizs and disperse.
lf s spill occurs, sll the Nation.l Respon$ ( cntcr, tlXH2,l-llEO2 lf r rpill eur, ell thc Nrtiotr.l Rc|Door C6td, tlx){24-tt02.
Rcnrrlr: '
NOTE Ths eltecis ol Inhaltng ihis mateflal may be d€laysd. Exposur€ to polenliElly dsngeroo R.m.rh: Lhucticd FlammableGas€s rra regutated by 40 CFR part 38
vlpor concentral|on8 can occur belore lhe p,oduct can b€ delocled by lmell.
ret
SCANNED BY MKP & BARIS A. 2004 I ()9
2.METHYL.6.ETHYLANILINE
Synonyns-6-Ethyl-2-methyl benenamine; U r i t e d N l t i o n s N u m b e r . - . - . . . . . . . . . . . . . . . . . . . . . . . . . . .t. METHYLETHYL KETONE
Ethyl-o-toluidine;Methylethylaniline
Syronyms- 2-Butanon€;Ethyt methyl kstone; MEK 1193
UnlaedN.alou Nunber............................-...
Fornule-GHrrN
CHRIS Code.......... MEA
T CHRIS Code
231'C
BoflingPoint.......................... 448'F
Fornulr-CHsCOGHT
ApDerrrnce.odor-Clear to amb€r liquid;mildly pungent -'c -"F
odor FrcczhsPoitri........................ -25"C 13'F
't
Bollltrl Polnt..
Appearence-Odor-Colorless liquid wiih a lacquer
SDecificGrrYlty-0.97
thinner odor Freezhl Point
vrpor Pressure 20'c (68'D,tt"r--: o*
Sp€ciflc Cr.vity-0.80
ChemicrlFrnily-Aromatic amines ReidVrpor Pres6ure (psia).........
Vrpor Prrcure 45"C(115"n (psis).......... . 0 009 VaporPr*ure 20'C (68'F)(nmHdt.......... 100
Chemlcd Family-K€long
Pollutior Crtegory-USEPA - IMO C vrDor D€nslty(Air : 1.0)........................... 4.67 R e i dV a p r P r w u r e ( p s i a ) . . . . . . . . . . . . . . ... . 3 . 5
Applioble Bulk Reg.il6 CFR Subchrpier. .. O s o l u b i l i t y i n w a t e r . . . . . . . . . . . . . . . . . . . . . . . .S. l i o h t Vrpor Pre$ure46'C (115'F)(pcia)............. 4.5
Pollutlon Crtegory-USEPA D IMO lll V a p o r D e n s i t y ( A i:r 1 . 0 ) . . . . . . . . . . . . . . , . . , . . . .2. . 5. . .
ADplicrble Bulk Reg. {5 CFR Subchapter .... O S o l u b i l i t y i n W a t e r . . . . . . . . . . . . . . . . . . . . . . .2
. .7 o k
Grad*E: Combustibleliouid FIRE & EXPLOSION HAZARD DATA
Electricrl Group-NA
Grade-C: Flammableliouid
Elechical Group-D
Generd-Mild hazard,toxic tumes of nilrous oxides and COr, are given ott by high temperaturesor combustion
Generd-Dangerous fire hazard,when exposed to heal or flame.
F l s h P o i n tC F ) . . . . . . . . . . . . . . . . . . . . 2. .3. .2. . . . .
Flumble Limits.......................... Unavailable
FlGh Poirt CF).............................
3O
Autoignition Temp,('F) ................ Unavailable
Flmmsble Linits..........................
1.8 to 1 1.5"/"
Extin8uishing A8ents..................... CO,, dry chemical,foam,waler spray
AutoignitionTenp. ('F)................
960
SD€cirlFire Prmedur6................Water prot€ctiveclothing, gloves, and goggles and selt-containedbreathing
ExtinguishlngAgents COr, dry chemical, alcohol foam
apparalus.
Sp€cialFire Prcedus................ Water spray may be inetfectiveon lire. Cool exposed tanks with water.
HEALTH HAZARD DATA

Herlth Hsed Ratin8r Odor Thr6hold (Dpm) PEL,/TwA (pDm) TLV,/TWA (ppm)
Unavailable Unavailable Unavailabl€ Unavailable HEALTH HAZARD DATA
Hedth Hadd Rsting Odor Threohold (ppm) PEL,/TWA (ppm) TLV,/TWA (Dpm)
Gercral-Severe eye irritant,nonirritatingto the skin. 1, 1, 2 .t0
200 2oo
Generil-Vapor is irritaiingwith moderats narcotic ettscl when inhaled. Vapor very irritatingto eyes. Slight skin
irritationon contact.
Symptoms-Skin develops blue tinge lrom lack of orygen in the blood.
symDtoms-lrritation in €yes, nose, and throat. Dizziness,headache, nausea and lack of communication.
Short Expcure Toleruce-Rals subject to 260 ppm tor 4 hours produced no symploms.
Short ExDoslreTolerance-Limited by irritant propertiesot vapor. 30,000 ppm is intolerableto man because of
irritaiion ot eyes and nasal passages;3000 ppm is intolerableto man for more than just a short period ol
ExposurePrcedures-Flush eyes immedialelywith water lof 15 minutes.Wash skin with water. Remove to
time.
lfesh air.
ExposurePtcedure-Remove any contaminated clothing promptly and flush skin with copious amounts ot
water. In cas€ of eye burns, tlush with water for ten minutes.
REACTIVITY DATA
Stsbility-Stable.
REACTIVITY DATA
Stabilitt-Stabl€.
Compaiibility-Mrterirl Usual materialsof constructionare suitable,
ComDatibility-Msteridr Sottens and dissolves many plastics.
Cargo: Group I of compatibili9 chart.
Crgo: Group 18 of compatibilitychart. See also Appendix l-Exceptions to the Chart.

Soak up spill with sawdusi, sand, or incinerale. Wear protsctivs clothing, goggles, havo solf-contain€d SPILL OR LEAK PROCEDURE
apparaius at hand. Wear rubb€r gloves, lace shi€ld, protective clothing. Have all-purpose canister mask available.Avoid conlacr
wilh liquid. Secure ignition sourcss.
lf r rdll murs, crll the Nitionil RertpE Ccrtcr, tlx)-{24-tt02.
l..[tr: t Uneveilablo ll r rdll mn oll tbr Ndlor.l Ccntcr, tlXH2.-o2.

1 UnaEEqnad l-.1.:
SCANNED BY MKP' &r BARIS A. 2004

2fi)
,01
2-METHYL-5.ETHYLPYRIDINE METHYLFORMATE
synonymr- Aldehyd€'colladrne; Ald€hydine; Synotryms- Formic acid, methyl ester; Methyl Unlted Nrtions Nunber... .. 1243
3 Fthyl-6-methylpyridine;5-Ethyl-2-methylpyridine; methanoate
MEP
5-tthyl-2-picolrne;
CHRIS Code...................., .. MFM
Fornulr-CH:GHsNCrH", or CsHlrN Fornula-HCOOCHT

Boilins 178"C
Poirt.......................... 353'F RoifingPoint.......................... 32'C 89'F
Appe.r.nce-Odor-Colorlessliquid;sharp penetrating -"c -'F ADpearsnce-Odor-Colorless liquid; pleasant odor
odor F r e e z i n g P o i n t . . . . . . . . . . . . , . . . . . . . . .7 O " C 94'F FrEzinq Point.............. 100'c -148'F
''
specltlcGrrvity-O.92 Specific Grevity-0.98
vspor Prsure 20"c (68'F) at."r*-" o,'9 Vrpor Prwure 20"C(68'F)(mnHg).......... 400
0.'l Chemicd Fsmily-Estsrs
Ct€nlcd Frmily-Amine Reidvrpor Pressure (D6ia)........................... R c i d V e p o rP r e $ u r e ( p s i r ) . . . . . . . . . . . . . . . . . . . .-.1. .8. . . .
VaporPrwure rl6'C (115'D (Dsis).......... 0'16 Vrpor Prroure 46'C (lls'F) (pcia)............. -=1259-
Polhtlor Crtegory-USEPA - IMO B VsporDersity(Air : 4'18
1.0)........................... Potlutlon CrteSory-USllPA - IMO D vfpor Dcnrfiy (Air : 1.0).............. ........... 2'O7
ADDltcsbleBulk Rq. ,16CFR Subchapter........ O So|ubilityinW8ter......................... Slioht ADplicdle Bulk Reg. 46 ('t'R Subchrptcr,.. ,.. O Solubllity in Wrtel Solubl€
FIRE & EXPLOSION HAZARD DATA I'IRE & EXPLOSION HAZARD DATA
Grade-E: combustible liouid Grrde-A: Flammableliquid
ElectricalGroup-D Electrlcd Group-D
cenersl-Moderate fire hazard when exposedto heat or flame. lrritatingvapors are generatedwhen healed. Gener.l-Toxic vapo(3 a.€ generated.Very dgngerous whsn exposed to heat, tlame or oxidizers.Flashback
along vapor trail may occur. Vapor may explode if ignited in an enclosed area.
165
I{ah PointCn............................. F l s h P o i r t ( ' D . . . . . . . . . . . . . . .. . . . . . . 2 6 ( c c )
Flsmmsble 1.1to 6.6%
Linits.......................... Ffonnrble Llmltc.... ................ .... 5 lo 22.7o/o
AutoigritionTemD.CF)................ 939 AutoignitionTenp. ('l) ................ 853
Extingui$hing Alcoholfoam,carbondioxide,dry chemical,waier spray
Ag€nts..................... ExtinguishinS A8ents..................... Dry chemical,alcoholtoam, CO,
Fire Pr@edurei................Wear protectiveclothing and s€lf-containedbreathing apparatus' Specid l'ire Precdurs.......,....,... Wator may not be effective. Wear self-containedbreathing apparalus, rubbet
oloves.

Health Haard Ratings odor Thrdhold (ppn) PEL,/TWA (ppn) TLvAwA (pDE) Health Hurd Rrtings Odor Thrahold (ppn) PELITWA (ppm) TLVAWA (ppn)
2.2.2 Unavailable Unavailable Unavailable 3, 1, 1 Unavailable 100 100
Genersl-Moderately toxic, skin irritant. Gene.rl-Vapor and liquid are irritalingto eyes, nose, skin and throat.
SymDtoms*Rednessand swelling from skin contact with liquid. synDtoms-lrritalion of mucous membranes,narcosis,lemporary visual disturbances.Liquid causes skin and
eye irrilation.
ExposnreTolerunce-'|7oo ppm lethal to a rat in 3.7 hours. Short ExposureTolerance-Unavailable
ErDosurePrftedurFvapor-remove victim to fresh air; if breathingslops, apply artilicial respiration.Skin or ExposureProcedure-lnhalation-move to lresh air, give artificialrespirationor oxygen as necessary.
eye contact-remove contaminatedclolhing and gontly flush atfected area with water for 15 minutes.A Eyes-tlush with water for 15 minutes. Skin-wash with soap and water. Ingestion-Do not induce vomiting.
physicianmust see all cases of eye contact immedialelyatter eye wash is completed. Get medicalhelD.
REACIIVITY DATA
Sbbllity-Stable. Can react wilh oxidizingor strongly alkaline (caustic)malerials, I REACTIVITY DATA
Stability-Stable. Slow non-hazardousreaction with water to lorm lormic acid and methyl alcohol. Reacts with
oxidizers.
Comprttblllty-Msterial Stainlesssteel, aluminum or lined carbon steel afe suilable.
t-
PolyethyleneJinedconlainers suitablg.
Crrgo: Group I ol compatibilitycharl C$go: Group 34 of compatibilitychart

Avoid contact wilh liquid. Kesp unprottrted psrsonnol away lrom spill rrea. Collocl mltadll in Plattr( S€cure ignition sources. Restrict access. Disperss and flush. Oo not flush sDill into confined soacos where
conlalnersu3ing abso66nts. tor lmall spills; lluEh llrgs spills. llammabl€ vapors can accumulato. wear self-containedbreathing apparatus, rubber gloves, goggies or salety
gl88Eot.
ll | .Dlll scuil cdl tic N.tloul Rm ( cnlct. l0{Lal4-ttt2. Il r rplll mc!.r, crll tba N.llon.l Rctolr Ccltcr, t00-42!tt02.
lrerb:
SCANNED BY MKP & BARIS A. 2004 l(, I

METHYLISOBUTYLKETONE METHYLMETHACRYLATE
Synonyns- Hexone; lsbutyl methyl k€tone: U n i t e d N r i i o n s N t m b e r . . . . . . . . . . . . . . . . . . . . .........'.l . . 2 4 5 Synotryms-Crystalite;Methacrylatemonomer; United Nrtionc Number 1247
lsopropylacelone;4-Methyl-2-pentanone;MIBK; MIK Methacrylicacid, methyl ester; Methyl methacrylat€
CHRIS Code ...... MtK

f l monomer,inh.;Methylalpha-methacrylate:
Methyl-2-methylpropenoate:2-Methylpropenorc
acid; 2-Propenoicacid, 2-methyl-,methyl ester CHRIS Code.................
Formuls-CH3COCH,CH(CHs), Formule-CH, - C(CH3)COOCH,,

B o i l t n g P o i n t . . . . . . . . . . . . . . . . . . .1.'.1. .6. ' C 241'F 2 '1C2 ' F
Boi|ingPoint.........................'100
App€uance-Odor-Colorlessliquid;dffisnl odd App€erance.odor-Colorless liquid: agrid odor
Freezins
Point......... .. *'3 -t*:F Frezitrs Point......... a8'3 :t-"F
Specific Grrvity-O.8o _"c _'F Specific Grrvity-0.94 -'c -'F
'
Vapor Presure 20'C (6E'F) (mmHd.......... -l-8- VsDorPrcssu.e20'C (68'F)(mmHg.......
Ctenicrl Fmily-Ketons (D6ia)......... Family-Acrylates - 0.5
Reid Vapor Prsure Chenicsl ReidVaporPr€sure (Dsis)...........................
Vapor Presure 46'C (ffs'D (psia)............. ---l=2- Vrpor Pressure 46'C (ll5'F) (psia)............. --2!?-
Pollution crtegory-uSfPl D IMO D VsporDersity(Air : 1.0)........................... 3.45 Pollution Cstegory-USEPA C IMo ----q- V r D o r D e n s i i y ( A i:r 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .3. . 4
. .5. .
Applic8bteBulk Re8.il6 CFR Subchapter........ D SofubifityinWrter......................... 2.O Applicsble Bulk Reg. 46 CFR Subchrpter........ O Solubilityinwrier........................ ioht S l
Grrde-C: Flammableliouid crad€-C: Flammable liquid
Electricd Greup-D Electrical GrouD-D
Cenerd-lritating vapors are generat€dwhen hoaled. Dangerouslire hazardwh€n expos€d to heat or tlame; ceneral-lgnited by heat, sparks, or open flame. Fire may cau* violent rupture ol tank because of
moderate explosionhazard when vapor exposed lo heat or flame. polymerization.
F l N h P o i n l( " F ) . . . . . . . . . . . . . . . . . . . .7. .5. . . . . . . F l a s h P o i n t ( ' F ) . . . . . . . . . . . . . . . . . . . . . . . .5. .5. . .

FlMmrble Linits.......................... 1.2 to 8.0% at 200'F F l s m m a b f eL i m i t s . . . . . . . . . . . . . . . . . . . . .2. . 1. . t o 1 2 . 5 " / "
Autoi8ritiorTenp. ("F)................ 858 Autoignition Temp. ('l') ................790
ErtinSutuhing 48ent3..................... COz,dry chemical,alcoholtoam,water fog Extinguishing Agents..................... Foam, carbon dioxide and dry chemicals
SpedC Flrc Precduc................ Fire partis muot mar re3piratoryproleclion. Watsr may bs in€fl€ciive on firs. Special Fire Procedures................Cool exposed lanks with water. Wear eye protection, self-contained breathing
apparatus and protective clothing.
HEALTH HAZ,.ARDDATA HI.]ALTH HAZARD DATA

Heslth Hrard Raritrg Odor Thr6bold (ppE) PELITWA (Dfr) TLvlTwA (pDil) 'lhreshold(ppm)
Health Hsard Rstinss odor PEL,/TWA (ppn) TLV^WA (ppn)
1, 1, 1 0.47 50 50 3.2.3 0.05 100 100
G€ner.l-Vapor causes eye, nose, throat irritaiion.Aspirated methyl isobutyl k€tone may cause severe lung c€neral-Vapor irritating.
damage and present a signilicanthazard.Bepeated or prolongedskin contact may cause detatting ot the
skin with primaryirritationresulting.
SyDptoms-Headacho,diziness and nausea. SymDtorsmarting ol the skin and first-degr@ burns on short exposure and may cause second-degreeburns
on tong exposure.
shorl Ertosure Tolemce-200-400 ppm for 5 minutes has produced eye irritalion;400 ppm for 5 minutes may Short ExposureTolermce-2oo ppm
produce nasal irritation.
ExposurePr@edures-Vapor-remove victim to lresh air; if br€athingstops, apply artificialrespiration.Skin or Exlsure Prc€du6-Vapor-remove victim to fresh air; iI breathing slops, apply artiticial respiration.Skin or
eye conlacl-remove contaminatedclothing and gently flush atfected areas with water for 15 minutes.It eye contact-remove contaminatedclothing and flush aftected areas with water tor 15 minutes. Get medical
swallowed,do nol induce vomitino.Get medical attention. advaceor attentaon.
R,EACIIVITY DATA REACTIVITY DATA

Strbility-Stable. Stsbility-Polymerizes readily.Methyl methacrylatewill not decompose on prolonged storage rl properly
inhibited.
Comprtibility-Mderisl: Will soften many plastics. Comprtibility-M.teri0l: Noncorrosiveto steel, aluminumor stainlessste€|,
Crrgo: Group 18 ol compatibilitychart. Cargo: Group 14 of compatibilitychart.

Wsar rubber gloves, tace shi€ld, protectivoclothing. Have all-purpo$ canist€r mask evaihblo. Avoid contict Wsar rubber glov€s, face shield, protective clothing. Have all-purposecanister mask available.Avoid contact
with liquid.Sscurs ignition sourc€s. with liquid.Secureignitionsources.
lt | .Dlll B!16, cdl ttc N.aloul Rarou Crarr, I0..l2ltll. lf . sDill trcuB, cdl rhe Nstionsl ResDois Cenier, t0O-424-tE02,
trrtr llcnerlr.
'
vdtur lirossuro 40 mmHg ai 25.5'C
SCANNED BY MKP & BARIS A. 2004 lo5

alpha-METHYLSTYRENE METHYLTERT-BUTYLETHER
Synonyms- AMS; lsopropenylbenzene; ............ 2303
united N8tionsNumber.................... Synonynr- terl-Butyl methyl elh€r; MTBE 2398
UnitedNetionsNmber................................
1-Methyl- t -phenylethylene; Phenylpropylene
CHRIS Code........ MSR

CHRIS Code.......... . MBE
Fornul.-CGH5C(CH3) : CH,
Fornrh-(CH')rCOCHr
.... 167-17O"C 333-338'F
..........
BoilingPoint........... B o i l i r gP o i n t . . . . . . . . . . . . . . . . . . . . . . . . 5 5 ' C 131'F
ADpearance-odor-Clear yellow liquid; characteristic --zg'c ADDcu.nce-()do.Jlea., colorl€ss liquid; sharp, --
aromalc ooor Freezingpoint.........
.... :-'g I tortEns-like odor tog'c lo+"r
I Frezing Poinr.........
Specific Gravity-0.89 _"c _'F Sgefflc Gnrlty-O.74 sl 2O'C
Vapor Presure 20'C (68"D (mmHg.......... 4.08
Chemicsl Family-Oletin 0.23 (l|cnlol
Vlpor Pressure 20'C (68'F)(mmHO..........
Reid Vapor Prsure (Fls)....... .... ........... limlly-Alkyl elherg
0 40
ReidVaporPrwu€ (p6ir)......... ...............,.. 7.4
Vrpor Pressure 46'C (ffs'n (Dsis)...........
.
A VrFr Pr6sure 45'C (ll5'n (Feia,............. -
Pollution Category-USEPA - IMO Vrpor DetrBlty (Alr = t.0)............... . 4 Og Poltuilor Crlrtory-lls!:PA D
- IMO VrlDrDenEity(Air : 1.0)........................... 3.1
ApDlicable Bulk Reg. 46 CFR Subch.pte...... O Solubility in Wrlel Insolubl€
Appllobh Bdl Rcj. ,16 ( lfR Subch.pt€r . . .. D S o l u b i l i t y i n W a t e r . . . . . . . . . . . . . . . . . . . . .C. .o. m
. olete
Grrde-Dr Combustibleliquid Grrdc-Cr Flammablo l|qutd
ElectricslGrcup-D Elctrlcd G.ouD-C
ceneral*Moderate tire hazard when sxDos€dlo h6al or tlame. Cenc.d-Flammable and, when conlinsd, sxplosive. Flashback along vapor trail may occur,
F l r s hP o i n tC F ) . . . . . . . . . . . . . . . . . . . . 1
. .2. .5.t.o. . 1
. 35 F h t h P o l r t ( ' F ) . . . . . . . . . . . . , . . ,. . . . . l4 (cc)
F l e n m a b lLei m i t s . . . . . . . . . . . . . . . . . .1. . .9.t.o. .6. . 1 o l o FhnmblcL|n|tr............,.,.... l6lo84%
Autoignition Temp,('F) ................ 1066 AutolSddo Tcmp. ('l)..,.,.. . . l9l
Extinguishing Agents..................... Dry chemical,foam,CO, waler log ExairSlbf,lrt AScntt ....,...... Alcohol loam, dry chomicsl, Co2
Speciall'ire Prcedures................ Waler may be inetfectiveon fire. SDccld Flrc Pmcc{ura......... . Oool oxpogad tmks wlth water spray.

Heslih Hsdd Ratings Odor Thrdhold (ppm) PEL^WA (pDm) TLV,/TIVA (ppm) H€dtb H|ed Rrdry ()dor'Ihrdhold {ppm) PE|.,/TWA (DDn) TLVAWA (Dpn)
Unavailable Less than 10 50 50 Unavailable Unavailable Unavailabl€ 0.25
General-Avoid skin contact. Not known to be absorbed. Gsnerd-Nol too toxic, similar to gasoline.
Symptoms-Will cause skin irritalionil not removed promptly- Breathingconsiderablequantitiesmay caus€ symptotrlrritates eyes, skin, mucous membranes. Inhalation:For prolonged €xposure,coughing,shortness of
headacheand/or dizziness. breath, dizziness,intoxication.For shorl exDosure,diziness.
Short ExposureTolerrnce-Unavailable Short Exlpsure Toleruce-
Erpcure Prftedw6-Skin contact-tlush body splashes wilh plenty of water. Inhalation-remove viclim to
fresh air. Administerartificialrespirationil necessary.
t- Erpocue Pruedurc-lnhalation: Remove to tresh air, give oxygen or artificial respirationas needed. Eyes:
Flush with water tor at l6ast 15 minutes, hold eyolids open, call physician.Skin: Wash with water. Ingeslion:
Do not induce vomiting.
Srability-Stable. Can react with oxidizingmaterials

REACTIVITY DATA
I REACTIVITY DATA
strbility-Generally stable. Forms peroxides al much slower rate than mogl ethers. Reacls with mingral acos.
organic acids, other oxidizers.
Conpstibiltty-Mrteris! May caus rubber to swell.
Cargo: Group 30 ot compatibililychart.

t ConDrtibility-Material Compalable with steel, iron, aluminum,copper, magnesium,zinc, neoprsne,
polyethylene,polypropylene.Incompatiblewith viton elastomer.
Crrgo: Group 41 of compatibilitychart. Sss also Appendix l-Exceptions to the Chart.

t SPILL OR LBAK PROCEDURE
Wear rubber gloves, tace shield and proloctivs clothing. Have all-purpo3ecenislsr mask availabls Securo all StoP relgas€, remove all ignition sources. Dyke to preveni spill trom entering sewers (explosion hazard
sourcesol ignition. pollution) and wat€ilays. Remove spill with in€rt absorbenl. wear gogglss or lace shi€ld, boote, and usu
selt-contdned brgathing apparatus il spill largs or in confined arsa.
ll . rDlll (Kr, c.ll lL Nadal l.to.x ( 6t.r, in-ara-lrt.

It r tDill Gurs, crll tbe Nraloul R6Du ( enter. t0(HZ-t802.
loub lcr
Illal$ircrirlrrtrnn-",*,,.&i&--e&stlr t SCANNED.*d-s**rfo**,
BY MKP & BARIS A. 2004
MINERALSPIRITS MOLASSES
Synonym!- Ligroin (in U-S.A.);Naphtha;Petroleum 1300 Synonyms- Treaclo UdaedNrtlw Nunber......,....
Unit€d Nstlons Number
spirils; Turpentinesubstitute
CHRIS Cod€..........
ForDuls-Petroleum distillate,not chemically Formulr-A mixlur€ ol sucrose and sugars

distinguishable 93-204'C 200-400'F Botlir8Poitrt.......................... V. Hioh'C -"F
BoillnS Poinl
ApDerrrnce-()dor-Dark brown syrupy liquid -'F
Appearance-Odor-Waterwhite liquid with gasoline-like _'c _'F
'C Frezinspoint.......... vaic'3
odor I'rezinS Point......... -'F
Sp€cilicGrrvity-O.7s SDccilicGrsvity-1.45
_'c _'F
vrpor Prsure 20'C (68'D (nnHg).......... --2.55- vrtDr Prsure 20'C (68'F) (mmHd.......... Low
Ctemiel Fmily-Alcohols, Glycols and Glycol Ethers R e i d V a p o r P r s u r e ( p s i a ) . . . . . . . . . . . . . . . . . . . .L. .o.w ....
C'hemicalFamily-Hydrocarbon mixture R e i d V r p o r P r N u r e ( p s i s ) . . . . . . . . . . . . . . . . . . .0
. ...1. .3. . .
Velnr Prwure 45'C (1f5'F) (Dsi.).............0.20 VaporPresue 46'C (115'F)(poid............. Low
I Pollution Crtegory-USEPA - IMO lll Vrpor D€Nity (Air : 1.0)..............
PollutionCrteSory-USEPA - fMO VrDorDenslty (Air : 1.0)........................... 4 0-4 3
D Neolioible ApDlicsble Bulk Reg. 46 CFR Subchipter S o l u b i l i t y i n W t t e r . . . . . . . . . . . . . . . . . . . . . . .S. .o l u b l e
AppllcableBull Reg.46 CFR Subchrpter. . Solubility in Wster .
Gnde-Non-tlammable
GradeD: Combustibleliquid
Eletrical Group-NA
Elstricrl Group-D
General-NonJlammable and non-combustible.
General-Moderate fire hazard whsn exposed to heat or flame.
nah Point ("1').............................

Non-flammable
F l s h P o i n tC D . . . . . . . . . . . . . . . . . . . . . 1
. .0. .5.t.o. . 1 4 0
Flmm.ble Limits..........................
Nonjlammable
Flammsble Limits.......................... 0.8 to 6.0%
AutoignitlonTenp. ('F) ................
Non-flammable
Autoignilion Tenp. ('F)................ 540
ExainSulshlnS^getrts.....................
Nonjlammable
ExtingnishingAgenb Foam, carbon dioxide, dry chemical
specislFlrc Pmedurec................ NonJlammabls
SpecialFire Prcedur6................ Do nol use straighl hose waier slream.
HEALTH HAZARD DATA HEAI,TH HAZARD DATA

Health Hsed RatingE ()dor Thmhdd (ppn) PEL,/TtryA (ppm)
He.hh l|rArd Rrdlt Odor'tt.qf,old (ppm) PDL,/TWA ODn) TLVAtryA Opm)
TLV,/TWA (ppn)
Unavailable Unevailable Unavailabls Unavailabie
0, 1, 1 Unavailable Unavailable 200
General- toxic. Molassss lermontation occurs when molasses is dilutsd wilh salt or lresh water and is
accelerated by heat. During tarmontation CO, (wilh FDssibletracos of sthancl and higher alcohol vapor) is
givon otl. which will produce inhalation hazard in comparlment containing molasses residue.
Symglom-Non-loxic
Symptoelnhalation: Mild irritationot respiratorytract. Severe lung irrilant. Central nervous system excitemenl
lollowed by depression.
Sbort ErImrc Toler.ncFunavailable
Short Expcure Tolerrnce-4ooo to 7000 ppm for one hour
Erpcw Prccodurq-Vapor-remove viciim to fresh air. Skin or sye conlacl-remove contaminatedclothing

ExposureProcedures-lnhalation:Remove victim to fresh air. Administerartiticialrespirationit necessary.
Ingestion:DO NOT induce vomiling. Eyes: Wash with copious amounts of water. and tluth rtloctsd areas gently with water.
Stsbllrty-Stabb.
REACTIVITY DATA t REACTIVITY DATA
Strbllliy-Slable. Reacts with conc. niiric acid and conc. sulphuric acid. Ferments when diluted with salt or
tresh water.
Compstibility-Materill Usual materials of construction are suitabl€.

t" Crmpstibillty-Materiat Mild stel and stainless steel are suilable.
r

Wash area with water atler removing bulk of spill by general means.
Wear polyethyl€neglov€s, tace shield, protectivo clothing. Have all-purpo!€ clnistsr mask avallrble Sacg'a
ignilion sources.
r
ll r rplll acun, cdl the N.tlord Crntcr, t(xH24-Egl2,
ll r rdll mcun. cdl ric Nrlload
'
ll.urlr: tjnroguleled, Table 2, 46 CFR Part 153
lmrlr: I UnsvsrlabL "
ll,0 v6oor onlv
I Um80n d
SCANNED BY MKP & BARIS A. 2004 rt

MOTORFUELANTI.KNOCK
COMPOUNDS
(conl.lnlnc lcad alkyb)
MORPHOLINE
Synonyns- Lead telraethyl; Lead tstramathyl; TEL;
!iynonymr- Dielhylen€ imidoxide; Diethylene oximide; 2054
UnitedNstionsNunber................................ Tetraethyl lead compounds;Tstramathyl l€ad
( )r(!thyfenimide oxide; Tetrahydro-1,4-oxazinei compounds;TML
lolrahydro.2H- 1,4-oxazine; Tetrahydro-p-oxaine
C-lIRlS Code MFA
CHRIS Codc........... .... MPL
Fomulr-(GHr)rPb, or (CH.).Pb in mixturea
Fornule-(CHr)rONH 93'C 200'F
B o l l l n g P o i n i . . . . . . . . . . . . . . .. . . . .
Boi|itrgPoirt.......................... 128'C 262"F ApperuceOdor-Oily liquid;containing dye; musly _'c _'F
ADDer.ance-Odor-Colorless oily liquid; ammoniacal _'c -'F sweel odor FGzlng Point............ ....... 9'C-!3la_1€'F
"C 25'F
odor FreezitrS
Point......... SpecificGnvlty- l .5 to 1.7 _'c _"F
't
SDeclfic Gr.vity-1 .0O Vrpor Prsure 20"C(68'F)(mmHd.......... 5 to 41
vspor Prwure 2o'c (68'F) arm", --: ^ C'henlal Fmlly-Lead alky't R€ldvrDor Presure(psia)......... -.. O'2-1'7
...............
Chemicsl Fmily-Amine 0.55
Reidvrpor Prwure (pcle)........................... V.IDr Prsure 46'C (115'n (Dsir)........... I
VrDor Prsue 46"C (1f5'F) (pcia)............. ---qE- Polhdotr oacSory-USEPA A IMO --3- 4 Io 7
VrDorDensity(Air : 1.0)...............,.....,.,.,.
Pollution C.tegory-USEPA - IMO D 3.0
V|por Denstty(Air : 1.0)........................... ADDltc.bleBolt Rca.'6 CFR sub.h.plcr O Solubllityinwrter......................... Neolioible
Applicrble Bulk Reg. 45 CFR Subchrpter........ O Solubllityinwrter......................... Comolele
FIRE & EXPI,OSION HAZARD DATA

FIRE & EXPLOSION HAZARD DATA cndFD or E: Combusllbloliquid,dop€nding upon tlash point.
Grede-D: Combustibleliouid Elct'lrlcl Group-O
Elstrical Group-C
Gcmrd-Moderate lire hazard when exposod to heat or flam€. Dang€rous.When heated to decomposition,it
c€nerrl-Moderale lire haard when expos€d to tlame or h€at. Wh€n haatad to decomposition,it emits highly emits highly toxic lume8 ol load
loxic fumes of oxid€s ol nitrogsn.
F l s h P o l n t( ' n . . . . . .. . . . . . . . . . . . . . . .8. .9. .t o 2 6 5
Flsh Point Cn.............................
100 nmmb|.Lln|t.................... Unavailablg
FhmmableLimits..........................
1.8 to 10.8'l. AutolS[ttlonTemD.('F).......... . . Bsginsto drcompos above 212'F
AutoignitionTemp,('F)................590 Erdqulrhln3 48dtr.................... CO", dry chemical,foam,water log
CO,, dry chemical,water log, alcohol foam
ExtirguishingAgerts..................... Spccld Flrc Procedurq................Tanks axposed to lir€ should be kopt cool wilh a waler spray to prevenl
Speid Fire Preeduru................ Providefire parties with full body and respiratoryproteclion. dsompodtion of the lead compounds. Bsause of lhe high toxicity of the compound and its combustion
products, only personnelwith lull rsspiratoryprotection should approach burning antiknock compounds. ALL
OTHERS SHOULO BE EVACUATEDAS QUICKLY AS POSSIBLEI
HEALTH HAZARD DATA

HEALTH HAZARD DATA Heslth Hand Rdin8s Odor Threshold (Dpm) PEL,/TWA (ppn) TLVAWA (ppm)
Health Hmd Rating Odoi Thr6hold (DDm) PEL,/TWA (ppn) TLVAWA (Dpr) 1,2,4 0.2as lead 0 . 0 7 5m g / m r a s l e a d
1, 1, 1 0.01 2o/Skin 2olskin GGncrd-Prolong€d skin conlact, ingestion or inhalationol high vapor may result in a toxic psychosiscausing
Generrl-Vapor moderatsly irritating.Liquid causes severe burns. anxiety which may progressto mania and death. Class B poison.
Symptoms-Neruousness,irritability,insomnia,dreaming;emotional instability;hallucinations,anorsxia, vomiting,

symptoms-Burning of throat and eyes; itching or burning oI the skin at site of contact. constipalion, pallor and tremor.
Short ExD$ur€ Toleruce-See TLV
Exp6ure Toleme-Unavailable
ErD6ue Prftedurg-Personnel MUST avoid inhaling the vapors or allowing the liquid to touch the skin.
Expdure Pr@edur#Vapor-remove victim io fresh air; it breathingstops, apply artificial respiration.Skin or Cloihing and other absorbenl malerial in contact with the liquid should be destroyed since they cannol be
eye contacl-remove contaminatedclothing and gently flush affected areas with water tor'15 minutes.Get dscontaminated.Liquid spilled onto the skin should be scrubbad ofl with kerosen€ al once. Get medical
medical advice or atlention. attenlion.
REACTIVITY DATA
REACTIVITY DATA Stlbility-Relalively stable at ambient temperatures,but it may dsompose it heated above 212'F.
Sbbility-This material is more stable than rtost ol th€ other amines listsd in this volume. ll i9 a mild bas€.
Conprdblllty-Mrterid: May be carried in steel tanks. No chemical oltscl on common materialsbut will readily
ConDrtlblllty-Mrterld; Copper and its alloys and galvanized iron are not compatible. permeale absorbent malerials.Avoid contact with oxidizingagenls or concsntrated acids.
C.rgo: Unassignedin compatibilitychart. For compatibilityassistance,call

Cugo: Group 7 ol compatibilitychart. See also Appendix l-Exceptions to the Chart. G-MTH- 1 (202-267-1 5771.

SPILL OR LEAK PROCEDURE Woir rubbat glov€s, full protoctiv€ cloihing, sye protection and self-containedbrsathing apparatus.Secur€
Woaa butyl rubbsr gloves, plastic prot€ctive apron, sell-contain€d breathing appalatus. Avoid contrcl wrtlr ronrtron&tutca3,
lhuld. Secure ignition sources.Small 8lill8 may b€ wash€d away with wat€r.
It t dU c.r,.dl aL Ndal n-|m C.ra.r, tm-a2&t102.

ll | .Dlll mn. crll th. N.llon.l n6@r* Ccnlcr. l0Ga2l-lOr.
lr*b:' llV IWA (t4xn) 0 | tu0 l.i rn/mratlaad
16.rlal I Ilrrrvorlnlra
SCANNED BY MKP- &t BARIS A. 2004 2tl

NAPHTHA:
STODDARD
SOLVENT NAPHTHA: Vil & P
SynonynF Dryclean€rsnapl'tha; Drycl€anerssatety United N.tions Nunber.................... Synonyns-Lighl naphtha;Ligroin(in U.S.A.);Nephtha, 1255
UnitedNrtlons Nunb€r................................
solvsnl; Ligroin (in U.S.A.);Mineral spirits; petrolsum; Painl€rs naphlha: Petrolsum solvenl;
Pstrol€umsolvent; Spotting solvent; Stoddard R€tinsd solvsnl naDhtha:Solvsnl naDhihe:Varnish
solvent; Whiie spirits makers' & painters' naphtha
Fornuh-Mixlure Formuh-Mixture
160-199'C320-390'F I
BoilinsPoint.......................... i Bolltn8Point.. 93-149'C 200-300'F
'c 'F
ApD€rrmce-odor-Colorless liquid;gasoline-likeodor ) Appemcc-Odor-Colorless liquid;gasoline-likeodor -'C -'F
Freezina Point......... -------r'C -"f I I F r e e z l t rPSo | D t . . . . . . . . . . . . . Low'C -'F
SD€cificGravity-o.78 SpecincCnvity-o.74 to O.77 _'c _'F
-++- ch€micd
c.hemicd
Frmily-perroreum
oir Htr'""";:'i::.11;:,t$"1.1::13-......:.. r Fmiry-perroroum
oirs [tr'"ltrffiil;:,t$"?..11-"'-........ .:z-
Vapor Pressure 46"C (115'F) (psia)............. O.2
Pollution CateSory-USEPA - IMO
-
(o Oil
Vapor Density (Air : 1.0)........................... t
i porutron
cste8ory-usEp^
- rMO @| I:# ilffiif;":",1il" 1::1"] ..... +L
Applic8ble Bulk Reg. 45 CFR Subchapter. . .... D Solubility in wrter......................... Neolioible Applicrbl. Bulk Re8. i|6 CFR Subchrpter . O Solubility in lry|tq......................... Neolioible
Grrde-D: Combustibleliouid Flammable liquid
Elctricd Group-D Eletrical Group-D
cen€rd-Flammable, moderatelire risk. moderate fire risk. Produces sutfocatingatmosphere ol smoke, COr, and lumes
F l s h P o i n tC F ) . . . . . . . . . . . . . . . . . . . . 1 . . (. c. .c. )
. .1. 0 Flsh Point ('F).............................
20 to 55 (cc)
Flumsble Limits.......................... 0.8 to 5.0% Fhmm.bleLinits..........................
0.9 to 6.7olo
AutoigritiorTemp. ('F) ................ 540 (approx.) AutoignitionTemp. ('F)................
45O
ExtiDSuifhirS A8€rts..................... Foam,dry chemicalor CG ErtinguishinSAgents Conlined area-Co2, dry chemical. Open area-foam.
SpecialFire Pruedurg................ Cool exposed tanks wilh water. SDeid Fire Procedure................Fight like gasoline tire. Waler respiratorydevices.

Heelth Hr8d R.tingr Odor Thr6hold (Dpm) PELAWA (ppn) TLVAWA (ppm) Herlth Hqrd Rdings Odor Thr6hold (ppm) PELAWA (ppn) TLV,/TIVA (ppn)
Unavailable Unavailable 100 100 1. 0. 1 300 300 300
Generd-Toxic. Prolongedor rspsat€d skin contact may cause delatting ot the skin and may produce dermatitis General-Will remove oils from skin. Prolongodcontacl with liquid may produce drying and cracking ot lh€ skin,
lrom daily contact. and may produce dermatitisfrom daily contact. Toxicity by absorption,inhalation,ingestion.
Synptons-lnhalation-lntoxication may result lrom high vapor concenlration. Symptons-Headache, dizziness,insomnia,coughing,diarrhea,bronchitis and pneumonia,neryousnessand
irritability.
Short ExposureToleiance-soo ppm lor 30 minules. Short ExpocureTolerance-40o0 to 7000 ppm for t hour resulis in developmenl ol symptoms ol narcosis.
ExDosurcPrmedur6-lnhalation; Remove victim to fresh air. Administerartilicial respirationit necessary. ExposurePrcedure-lnhalation: lmmediat€lyremove victim lrom contaminated area. Get medical attention, ll
Ingestion:DO NOT induce vomiting.Eyes: Flush with waler tor 15 minutes.Call a doctor. splashed in eyes, wash thoroughly.
I i
Stlbility-Stablq. Stability-Stable.
Comprtlbillty-Mrterial: Solvent ellects on some paints and rubber. Carbon steel satistactory. Comp.tibility-Mrterid: Solvent etlecls on some paints and rubb€rs. Carbon sleel not aflected. Corrosive in
presence of salt water.
Cargo: Group 33 of compatibilitychart. Cargo: Group 33 ot compatibilitychart.

Wear rubb€t gloves, lace shield, protoctive clothing. Wear s€lf-containedbreathing apparatG. S€cure ignition Wear rubber glov€s, lac€ shisld, prot€ctive clothing. Wear slt-contained br€athing apparatus. S€cu?a all
sources. ignilion Furces.
Rcnrrlr: t Unavailable
cdl the N.tlold nltDor& Cclt3r. lllF42a-tt0r, I tl.ruLr I tjnrvrllabla
lf | .Dlll mn, cdl ahr N.tiond RoDore ('enter, tlXLa2/Fl&12.
I Una8srgncd
I
2t2
SCANNED BY MKP & BARIS A. 2004 2tl
NAPHTHALENE
NAPTHENICACIDS
Synonyms- Camphor tar; Naphthaline;Naphthene;Tar UtritedNrtiors Numb€r... mollen
camphor; White tar cruoe or Synonyms- No common synonyms United Nrtions Numbrr T
relined
CHRIS Code........... ...........

__Nr!d_
( IIRIS (bde................ NTI
Formula-CroHe
BoilingPoiDt..........................21A"C 424"F Fomule-Cnl'Ln-sCOOH to C.H?, ,"COOH where
Apperuce.Odor-Colorless liquid or white solid; odor n= 13-28 Eofltns Point........... .. . ........ 132-243',C 27O-470'"F
of mothballs Frezins Point......... .. . so'3 t^"F Appearrnce-Odor-Goldto dalk red to black liqudi -ao'c
SpecificGravity-l.15 -'c -'F penetrating,perstslanl,putridodor' Frezlng Polnt.. . o'r
VrDorPrwure 20'C (6t'n (mmHg........ - 1 SpecificGrsrity-o.98 at 20"C _'c _"F
ChemicalFmily-Aromatic hydrocarbon ReidVaporPre$ure(Fis)...........................
---te!-- Vrpor Pressure 20'C (6t"1')(mmHg).......... -_(QL
VaporPrruure 46"C(ll5'R (psir)............. ---LQ!!.- Chemicll Family-Otganic acids Reidvspor Pressute (psis).. ................. <0.1
Pollution category-UsEPA I IMo ----A- 4'42
vrnpr Dersity(Air : 1.0)........................... v.por Pr6u.e 46'C (ll5"F) (psi!)............. <0.1
solubilityir water......................... Neolioible Pollution Crtesory-USEPA B IMO A V . p o r D e n s i t y( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . 0
. ...9.
Ap!ilioble Bu[. Re& il6 CFR Subcbrpter........ O
ApplicableBulk Reg.'16CFR Subrhspter...... D. O Solubilityin Water........ . .. Insoluble

Grsde-See "General" comments below. FIRE & EXPLOSION HAZARD DATA
Electric.l Group-D crrde-E: Combustibleliquid
Electrical Group-NA
ccner.l-Combustible Grade E solid normallycari€d in the molten stala. Whsn ceried moltsn, it pres€nts a fiJe
hazard comparableto that of a Grade C llammable liquid. Naphthal€novapor or dusl can form €xplosiva Generd-Combustible liquid.
mixtur€swith ai.. Toxic vapors given off in a fire.
F l s h P o i n tC F ) . . . . . . . . . . . . . . . . . . . . 1
. .9. .0. . . . .
F l m m a b l eL i m i t s . . . . . . . . . . . . . . . . . .0. . 9. .t.o. .5. . 9 % F l s h P o i n t( " F ) . . . . . . . . . . . . . . . . . . . . 3
. .0. .0. . . . .
AutoigritiogTgn TemD. ('F)........... 979 FlamnableLimits...................... . LEL: 1% UEL-Unavailable
Extitrguishing Ag€nts..................... COr, dry ch€mical,toam,wal€r lo9 AutoignitionTeop. ('F) ................ Unavailable
SpecirlFire Prcedor6................ Othomisethe
Do not dirst a hos€ into a tank of molt€nnaphthalene. Extinguishing A8ents..................... Foam,dry chemical,carbondioxide
naphthalenewill be spattered about with explosive torce. Water or foam must be applied carelully to molten Specid Fire Prcedures................Water may be ineflective; cool exposed tanks with water to prevent over
naphthalenelo prevent excessivelrothing. Wear eye protection.s€ltcontained breathing apparatusand pressurizationand rupture.
HEALTH HAZARD DATA

Hedth H@rd Rstlngs Odor Threshold (ppm) PEL,/TwA (ppm) TLV,/TWA (ppn) HEAI,TH HAZARD DATA
2.1.2 25' 10 10 Hedth Hurd Rstings Odor Thrdhold (ppm) PEL,/TWA (ppn) TLv,/TrryA (ppD)
Unavailable ' Unavailable 10 mg/m3
G€tr€.d-Molten liquid is scaldingon contact. Vapor is irrilatinglo skin and eyes.
Generrl-Mildly hazardousto man; hazardousto aqualic lile in low concentrations.
Symptons-Eye irritation,h€adache,naus€a,protuse perspiration,vomiting.

SymptmFlrritating to eyes, nose, throat. Inhalation:coughing,ditficulty in brealhing. Skin contact: irritating.
Ingeslion: nausea.
Short Expcurc Toleme-1s ppm lot 5 minutes.
Short Exposure TolerrncF
Exp6ure Pr@eduH-Vapor-remove victim to fresh air: if breathingstops, apply artilicial respiralion.Skin or

eye contacl-remove contaminatedciothing and gently llush affected areas wilh water for '15 minutes.Get
I
ExDosurcPrcedures-lnhalation: rgmove to fresh air. Ingestion:give large quantities ol fresh water. Eye contact:
medical advice or anenlion. ' NOTE: Detectableodor is greater than the TLV. Exposureto potentially flush with water until irritalion stops. Skin contact: tlush with water and soap.
dangerousvapor concentralionscan @cur belore the product can be smelled.
Strbility-Stable.
REACTIVITY DATA
I Stability-Slable.
REACTIVITY DATA
ComDatibility-Msterisl: Nonconosive.Most materialsof constructionare satistactory.
I
Compstibility-Mrterish Generally corrosive to metals.

Cargo: Group 4 of compalibilitychart

Wear rubber gloves, lace shield, protective clothing. Have all-purposecanist€r ma8k availabl€.Upon spilling,
t SPILL OR LEAK PROCEDURE
the material will solidity and can be scraped up with nonsparkingshovels into a wasl€ conlainer. NrphthaLm Avoid contact, wear $tety glasses or lace mask- Dike and remove spilled material. Prevent from reaching
spillinginto wat€r will €ithor solidityand sink, or solidity into a foam and floal. bodies ol water, since it louls beaches, and taints aquatic life.
lt | .Dlll mn cdl the Nrdod R6mr c.rt.r. 8{xH2/a-tfr12.

It t Dlll ccu6. cdl ttc N.tlond Resrs C€trter. E00-424-E&2.
R.n.rl.r Normallylransporlsd at el€valod l€mp€raturo8.Se€ 48 CFR 36-Elovslod TemFEreturaCrrgoaa.
' Oflen
lmrrlr: odoaletSafter processrng. r9'0
IUnavatlalta
Ia
SCANNED BY MKP & BARIS A. 2004 2tt
NEATSFOOT
OIL NITRIC ACID (56 to 68o/o)
syray||rBabulum oil; Hoof oil U n i t e d N r t i o n r N u n b e r . . . . . . . . . . . . . . . . . . . . . . . .I. . . . . . . . Synonyne Aqua toriis; Azotic acid; Engravgrsacid; ....... ...
IJnited Nations Number.................... 2031
Engraversoil; Hydrog€nnitrate
cHRls code........ oNF CHRIS Codc.. .....................

__Nep
Fmulr-lndelinite mixture Formule-HNOs
B o i l i n g P o i n t . . . . . . . . . . . . . . . . . . .V. ...H. .i.o h ' C U*U*"' 8ollltr8 Polnt .. 122'C 251'F
App€$mce-odor-Pale yellow oily liquidwilh a peculiar -- Appesrsrce-odor-Colorloss to y€llow liquid, fumes in _'c _"F
ooor FreezinsPoitrt......... to+:8 ,,-*:F moisl air; characleristic,choking odor Frezlng Polnl -34'C 30'F
SpecificGr8vity-0.91 to 0.92 -'c -'F SpecificGrrvity-1.35 to 1.41 _'c _'F
Vepor Preure 20"C (68"F)(nnHg).......... --2.O4- Vrpor Pressure2O'C (6t'F) (nmHg).......... ---Zl--
ChemicalFamily-Esters R e i dv a p o rP r c s u r e( D r i r ) . . . . . ........ . . . . . . 01 Chenicil Fsnlly-lnorganic acid Rcld VoporPresure (psir)........................... 27
VaporPresure,15'C(115"F)(psi8).............0'15 vrpor Pressur€ il5'C (rr5"F) (psia)............. 3.6
PollutionCstegory-USEPA - IMO D V t p o rD e N i t y ( A i r : 1.0).............. ..... t . . Pollutlon CsteSory-USEPA C IMO C VrDor Demlty (Air : 1.0).............. ............. 2 17
ADplicrbleBulk Reg.,16CFR Subchapter.. .. . D S o l u b i l i t y i n W r t e r . . . . . . . . . . . . . . . . . . . . .N
. .e. .o l i o i b l e Applioble Bulk Re8.46 Cl'R SubchtDter........ O S o l u b i l i t y l n W r t e r . . . . . . . . . . . . . . . . . . . . .C
. omolete
cndFE: Combuslibleliquid Grrde-Non-tlammable. Classitiedas corrosive liquid.
Electricsl GrouD-O Electriol Group-B (based upon possible hydrogen gas (Hr) generation should a leak or spill occu0.
cen€ral-Moderate fire hazard if exposed lo high heat. G€n€ral-Nitric acid will not burn. lt will react with many metals, giving ott hydrogen gas which is highly
flammable. It hydrogen is trapped in confined spaces, it can lorm an explosive mixture with air. See data
sheet for hydro96n.May give otl toxic oxides ol nitrog€nand acid lumes when healed in a lire.
430
Flsh PointCn............................. Flsh Point CF).............................
Non-tlammable
FlamnableLinits...................
...... Unavailable Flmmable Linits..........................
Non-tlammable
AutoigDitionTenp. ("D................ 828 Temp,("F) ................
AutoiStrition Non-tlammable
Extin8uishing Dry chemical,foam or carbondioxide
Agents..................... Extinguishing Ag€nt!.....................
Water
SDecialFire Prffedurg................ Waler may b€ in€lfective on tire. Specid Fire Pr@edures................lf lire results, water will absorb the toxic oxides generaled. Fire fight€rs should
wetr full protective clothing including respiratoryprotection.

Hcrlth H.Ad RrtirSr Odor Thr6hold (Dpn) PEI-,/TIVA (ppn) TLvAwA (ppD) Heslth Haad Rrtings Odor Thrchold (ppm) PEL,/TWA (ppm) TLV,/TWA (ppn)
Unavailable Unavailable Unavailable Unavailable 3, 4, 3 Unavailable 2 2
Generd-Not harmful Generd-Breathing of vapors is extremely dangerous. Littls warning ol danger is at firsl appar€nt and initial
sympioms are obscure. Liquid burns lhe skin lorming deep ulcers which leave lealh€ry scars.
Symptoms-None SymDtomFvapor: immediatesevere skin and lung burns. Liquid: smarting, itching, and yellow discoloration
uDon skin contact.
ExDosure Tolerance-LD5o above 1 5 g/kg. Short ExposureTolermrl5 ppm lor 5 minutes.
ExDorue Prcedures-Wash thoroughlywith soap and water, ExposE Pr@edur6-Remove the aftected individualtrom the contaminated almosphere and call a physicianat
once. Keep pati€nt at rest until seen by the physician.In €se of eye or skin contact, flush immediatelywith
copious quantitiesof waler while removing contaminatedclothing. The eye irrigationshould be continued for
15 minutes.Cases involvingeye contact and inhalationMUST have medical help!

St!bility-Stabl€. Stsbility-Reacts violentlywith numerous organic materials.Decomposes at temperaturesnear boiling. Soda
ash will neutralizeresidualacid trom spills.
ConDatibility-Msterial Usual materialsot constructionare suitable. Compstibility-Mrterial: Attacks aluminum;compatible with stainless steel and high chrome iron alloys.
csrgo: Group 34 ol compatibilitychart. Crrgo: Group 3 ol compatibilitychart.

Wear rubber gloves, face shield, proteclive clothing. Body shield and self-contained breathing apparatus
Wsar rubber gloves, lacs shield and protsctive clothing.
should be available.Secure ignition sources. Flush cautiouslywith water. Avoid directing strsam inlo larger pools
t
or Pockets of concenlraled acid. It possible, cover conlaminated surlacss and spill with large quantities of soda
ash or sodium bicarbonate. Mix and add waler if n€cessary to effect good mixing. Scoop up slurry. Wash site
with Boda ash solulion.
lf r olll acun. c.ll rh. Nrtlill n6mu ('cnt r. tlll!a24-tt02, lf e rplll acu, qll thc Nttlotd Rsporre Ccntcr, 8ln-42,1-8t02.
Lorrtr: t UnavarltbL lcmrrlr;
I Unessryrad
I
210
SCANNED BY MKP & BARIS A. 2004 217
(NOTE: Thb clrgo l! cun ntly not pGrmltt d to b. rhlpp.d In bulk In U.S. wal.rr)
NITRIC ACID (95o/ol NITROBENZENE
Synonyms-Aqua fortis; Azotic acid; Engraversacid; 2032
United Nrtio$ Number................................ Sytroryru- Essenceol mirbane;Benzene,nitre; 1662
Uiltcd NstlonsNumber................................
Engravers oil; Hydrogen nitrate; Red fuming nitric Mononilrobenzene;Nilrobenzol;Oil ot mirbAne
acid: White luming nilric acid
Formula-HNOr Fomule-CrHrNor
BoilingPoint.......................... 94"C 2O2'F 8 o 1 1 f n 8 P o f n t . . . . . . . . . . . . . . . . . . . . . 2. .1. .' .l " C 412"F
App€rr8Dce-Odor-Water-white to light brown liquid; Apgeennce-Odor-Light yolloil grsn to brown liquid:
acrid odor poinr.........
Freezins ...............
-l*i! :' j similar odor io dl ol biner llmondr porrr........................
Fuatrs -------rtE:,F
Specilic Gravity-1.50 SgectllcGnvtty-1.20
-*- chemicar
Frnry-N.rocompoundr -"qff-
crremicar
Fmiry-rnorsanic
acid nil'r:ffil*l;:.tff"?..11-i"-?-:...... [il'":#trjl;:,tff'.? 1lll3_.:...:..:.
porfutioncrtesory-us'pA
c rMo c lfr:";ffil",fi;"=ttr1l,".iT-:].:.:...'...-tF porurrotrc.rc8ory-usr:rr
c rMo B #
l:ililffil",f;":tt1i,".1Tl1l:.:.:.:.:...
ADDlicrble Bulk Reg. il6 CFX Subchapter ..... Appltoblc Edl Rca. 16 ('lR subchr!'tc.,.,..,., O solubiltty in wrter......................... Neolioible
FIRE & EXPLOSION HAZARD DATA }.TRD& EXPI,OSION HAZARD DA'TA

GndFNon-f lammable.Classiliedas corrosive liouid. Combuslibleliouid
Elff trlcrl Group-Non-f lammable Eletric.l GroulFO
Generd-Nitric acid will not burn. lt will react with many m€lals, giving ott hydrogen gas which is highly lir€ hlurrd; rt aLvated lornperature!, lhmmabl€, toxic vapo( may be givon otl.
flammablo.It hydrogen is trapped in confinod spaces, it can form an sxplosive mixtur€ wiih air. Soe daia
she€t for hydrogen.May give oft toxic oxides ol nitrog€nand acid fum€s when heated in a lire.
trlsh Point('F)....... Nonjlammable l ' l s h P o i n a( ' n . . . . . . . . . . . . . . . . . . , . . .l.9. .0. . . .
Flmm.ble Linit3..........................
Non-flammable l'hmmrbleLlnltr...... LEL 1.8"/"UEL-unevailable
AutoigtritioDTemp. ('F)................
Non-tlammable AutoigrltlonTcnp. ('D................900
Extingutuhing ^gertc.....................
Water Extingulrf,ln8 A8cttr................... Continedarea-COr, dry chemicals.vOpen
Pgrr area-loam.
q req_rvqlr.
SpocialFire Prcedurd................ lt fire results,water will absorb the toxic oxides generatod.Fire tighters must Flre Pracduu.............. . Use water to keep lareexposod contein€rs cool. Wear comDlet€rubber
wear full protectivoclothing includingrespiratoryproteciion. proloctive clolhing includingeye protection and sell-containedbreathing appafatus

H€8lth Haed Rstings Odor Thrshold (ppm) PEL,/TwA (Dpn) TLVITWA (Dpn) Hedti Hrfrd Ratin8s Odor lhreshold (pDm) PEL,/TIVA (ppm) TLV,/T|VA (DpD)
4.4.3 Unavailable 2 2 3, 2, 4 O.OO47 1/Skin t/Skin
G€nerrl-Breathing of vapors is exlremely dangerous.Little warning ot danger is al lirst apparenl and initial Generrl-Highly toxic when absorbed thru the skin, inhaled as vapor, or swallowed.This is a btood goison and
symptomsare obscure. Liquid burns the skin forming deep ulc€rs which leave leathery $ars. a nerue poien which is readily absorbed by the body.
"Blue lip"
Symptoms-Smarting,itching, and yellow discolorationupon skin contact. lf acid is not removed at once, intense or bluish tinge sen in lingernail beds, lips, lob€s ol ears; coniunctive,mucous
Dainand severe burns result. membranesand tongue. Fatigue, headaches,vomiting,general weakness and signs of nervous system
involvement.
Short ErposureTolemcFls ppm lor 5 minutes.
ExpGure Tolemce-2oo ppm lor one hour-no serious disturbance;40-80 for a lew hours-slioht
Exp6ure Preedu$-Upon skin contact, wash with large amounls ot waier at once. Remove the atfected symptoms. Absorption may cause death due to neryous sysl€m poisoning.
individualtrom the conlaminaledatmosphereand get medical help. In case ot eye or skin contact, flush ErDosw Prsedurq-Remove all contaminatedclothing, wash skin with sap and water, llush skin tor approx.
immedialelywith copious quantitiesof water while r€movingcontaminatedclothing. Eye irrigationshould be 15 minutes. lf swallowed,inducg vomiting unlil vomit tluid is clear. lf inhaled, remove victim to fresh air and
continuedtor at least 15 minutes.All cases involvingeye contaci and inhalation MUST be seen by a starl orygen inhalation.Contaminatedclothing should be thoroughly washed in soap and waler before using
physician. again. Gel medical help.

Stsbility-Reacts violentlywith numerousorganic materials.Decomposesat temperaturesnear boiling. Soda Stlbility-Slable.
ash will neutralizeresidualacid from soills.
ComDotibility-Mrterirl Compatible with stainless steel or aluminum. Comprtibility-Mrterirl Usuai materials ol constructionare suitabl€.
Cego: Unassignedin compatibilitychart. For compatibilityassistance,call Cugo: Group 42 of compatibilitychart.

G-MTH- 1 (202-267 - 1577l

Weat rubber gloves, lace shield, protsctive clothing. Body shield and self-containgd breathing apparatus Flush arsas wilh large quantities of cold water. Ventilate treely. Hot water can be used lo r€mov€ $me
should b€ available.Ssure ignition sources. Flush cauliouslywilh watsr. Avoid direciing stream inlo largs pools absorbed mal€rial. Wear complete protective clothing includingeye and respiratoryprotection.
pockets of concentratedacid. ll possible,covsr contaminatsdsurlaces and spilt with largo quanlitiss ol toda
ash or lodium bicarbonato.Mix and add watgr il nff€3sary to etloct good mixing. Scoop up sturry.Warh Ctr
with aoda alh solution.
lf e rCll cura cdl tlc Nrilrl exl{2a-t8{12. lf I spill @curi, cdl the Nrtionrl Rergm Ccrtcr, tlH;!Ftt02.
lrrfa ' ]rlt .hlFranl of thlr cof,c.ntr.llon lr ml parmlttad ln Ul rrtr[. lrulr;
ill SCANNED BY MKP & BARIS A. 2004 2le

O.NITROPHENOL 2.NITROPROPANE
1663 Synonyms- lsonitropropane;2-Nitropropane; United Nrtiom Number................................2608
2-Nitrophenol:ONP
Synonyms- 2-Hydroxynitrobenzene; United Nrtions Number...............
Nitropropanes;sec-Nilropropane;2-NP; Propane,
nitro-
C H R I S C o d e. . . . . . . . . . . NTP CHRIS Cod€.................. ..... . . __Nee_

Fornub-GH'NOr
Fomulr-HOQHTNOT
214"C 417'F BoilinSPoint.................. 12'1'C 249"F
Boiling Point.
yellow solid; aromalic
Appeerence.Odor-Colorlessliquid; odorless
Appearrnce-odor-Crystaline -93'3 -
tt'c trr"e FrezinsPoint......... r*-"F
sweel odor Frezing Point
SDstfic Cnvlty-0.99
Specilic Grality-1.49 (solid) _"c _"F _'a _"E
Vapor Pressure 20'C (6E'F) (mmHd.......... < l vatnr Prsure 20'C (68'F)(nnHg).......... 12.9
Chenicd Fmlly-Nitro compounds R e i dv r l o r P r $ s u r e( D s i a ) . . . . . .. . . . . . . . . . . t
Ch€mical FrDily-Aromatic nitro compounds R e i d V t p o r P i e s s u r e( p s i a ) . . . - . . . . . - . . . . . . . . . . . . .<. .0. . 1
VaDorPresure,l6'C(f15'D ( p s i r ) . . . . . . . . . . . .1. . 0 5
Vapor Presure 46'C (ll5"D (Dsiq)............ <0.1 Pollutlon C.t.gory-USEPA A D
B lMo VrDorDenEity(Air: 1.0)........................... 3.06
Pollution Category-USEPA --ll- IMO Vrpor D€nrity (Air - 1.0)..............
0.25"h ApDltc.bleBulI Re3.46 CFR Subch.pler. . . O S o l u b i l i t y i n W a t e r . . . . . . . . . . , . . . . . . . . . . . .S. .l i o h t
Applicabl€ Bulk Reg. ,16 CFR Subchapter....... O solubilityinwrter........................
Grade-D: Combustibleliquid
Ei Combustibleliouid
Electrlcrl Group-C
Electricrl Group-NA
'180'C. G€rcrd-Toxic oxid€s ol nitrogen may torm in tire. Moderats lire heard. Decomposeswhen subjecled to high
General-Violently decomposes above Can give otf toxic nitrogen oxides and unburned vapor when
temp€ralure.
healed or burned.
trlsh PolrtCD.....................1 . .0. .3. . . .

F I s h P o i n t ( " F ) . . . . . . . . . . . . . . . . . . . . . . . 2. .1. .5. .
FlemhableLlnlts...... LEL==2.6%UEL-unavailable
f'hmmsble Limits.................... . ... Unavailable
('l)
AutoignitionTcmp. ................
802
AutoiSnition Temp. ("F) .......,........Unavailable
Exiinguishing Ag€nts....................
Alcoholloam, walsr spray,COr, dry chemical,toam
Extinguishing Agents..................... Water, foam, dry chemical, carbon dioxide, Halon
Specirl Fire Prccdure................ Wal€r prolective clothing and soltcontained breathing apparatus.
special Fire Prceduro................ Cool exposed tanks with water spray. Wear sell-conlained brsathing
apparatus and lull proisctiv€ clothing.

TLvlTwA (ppm)
Health H@rd Rltirgs Odor Threshold (ppm) PEL,/TWA (ppn) TLVITWA (ppn)
Heslth Hsard RrtinSs Odor Threshold(ppm) PEL,/TWA (ppd)
1,1,1 300. 10 10
General-Suspected carcinogen.Slight irritationtrom liquid conlact with skin and eyes. Vapor inhalation is
General-Liquid, solid, dusl are toxic. When heated or burned, toxic nitrogen oxides and unburnedmaterial
irritatingto respiratorytract with mod€rate systemic effect.
produced.Harmlul to aquatic lile even in very low concentrations.Molten material will burn tissue.
Symptoms-Headache,diziness, nausea, vomiting, diarrhea.
symDtoms-lngeslion-headache, nausea,unconsciousness,drowiness.Inhalation-headache, nausea,
unconsciousness,drowsiness,cyanosis,breathing difticulties.Skin-irritation, headache, nausea,
unconsciousness,drowsiness(absorbedthrough skin). Eyes-irritation. Short ExlGre TolcmcFsoo- 1000 ppm for up to one hour
Shorl ExposureTolennce-
ExposurePrcedures-ln case ol pulmonary symptoms or cyanosis, remove workers from contaminaled area at
ExposurcProcedures-lngestion-ll conscious,drink water or milk; induce vomiting. lf unconscious,do not give
once; place in bed, rest, use oryg€n, il respiratorydistress is pre$nt, and obtain medical attention.
liquidsor induce vomiting,but keep victim warm. Eye contact-flush with excess water tor al least 15 'NOTE: D€lectable
odor is greater than the TLV. Extpsure to potentiallydangerous vapor concentrationscan
minutes,call physician.Skin conlact-wash thoroughlywith soap and water-quickly remove material.
occur belore lhe vaoor is detecled bv smell.
Inhalation-remove to lresh air, give oxygen or artificialrespiration,as necessary.

Stability-Slable under normal conditions. Decomposeswhen subjectod to high temperatures.Rapid heating to
Stability-Stable below 180'C. Keep away from caustics to avoid foamationof unslable products. Reacts
high tsmperatures may caus an explosion.
violentlywith potassiumhydroxide(caustic potash).
comprtibilitv-Msterisl: copper and ils alloys, wet mild steel, and lead and its pigments ar€ incompatible.
ComD.tibility-Mrterial: Softens rubber and paint. Compatiblewith mild steel, stainless steel, and polyethylene

Cargo: Unassignedin the compatibilitychart. See Appendix l-Exceptions to the Chart

lf possibls, w€ar neopr€ne gloves, plastic protective apron or coal and self-containedbrgalhing apparatus
Avoid liquid, solid, dust. Wear rubber gloves and goggles. lt lumes present, use ssltconlained bresthing
Provide good ventilation.Socure ignition sources. lf possible,cover with soda ash and mix and spray with water
apparatus.K€€p upwind. Stop disharge il possible,dike (includingfne fighting water) and prev€nt lrom €nteri.€
Scoop up. Wash site wilh soap soluton.
wateruays.
lf r cpill ccurs, crll the Nraionrl ReDons Cetraer, 8()()-42|-t802.

lf r sDlll acuB cdl thc N|tlonrl
Rcm.rlt: I Unavailablo
Rc[ral] Itn
120 SCANNED BY MKP & BARIS A. 2004 221

O-NITROTOLUENE NONANE
Synoy||r 2-Methyl nitrobenzene; 2-Nitrotolu€ne; Unit€d NdioN Number ....... 16611
Synonyms- 1-Nonan€; n-Nonan€ Unlted Nrtlru Numb€r 1920
Orlhonitrololuen€; o-Nitrotoluol; Toluen€, orthonilro-
CTIRIS code "" " NIE ('llRlS Code.................
Fornula-CrHrNOz Fornulr-GHzo
Boillng Point ............ 222"C 432'F BolllnSPolnt. .. ............ .... 149'C 300'F
Appeermce-Odor-Oily light yellow liquid; bitler almond liquid; gasoline-likeodot --sn.c
oa
odor Freezins
Point.........
............ 4'3 *:F :5-.p
l'reezing Polil...............
Sp€cific Gnvity-l.16 _'c - 'F Spetllc Gnrlty-O.72 _'c _'F
Vrpor Presure 20'C (68'D (DrHd Vqnr Presure 20"C(6t'D (mmHg).......... 10
Chemical Fmlly- ReidVrjorPrsure(Drir)........................... Lil Ctenicrl Fmlly-Saturat€d aliphatic hydrocarbon RefdVrpor Prwure (pcla).......... ................ O.2
vipor Pre$ure 45'C (115'F) ([Ei8)............. 0.02
C C
VaporPresureil6'C (115'F)(psiq)............ 0.4
Pollution CrteSory-USEPA IMO VrDor Density (Air : 1.0)........................... 4.72 Pollutior Crtegory-USEPA - IMO C' VsporDetrrlty (Air : 1.0)..............
Applicrble Bulk Re8. il6 CFR Subchapter........ O Solubitity in wrter......................... Neolioible D. O
Applieble BuU(ReB.il5 CFR Subchspter........ S o l u b i l i t y i D W r t e r . . . . . . . . . . . . . . . . . . . . .N. .e o l i o i b l e
Grade-E: Combustibleliquid Grade-O: Combustibleliquid
Electricsl GrouD-D Electrical Group-D
Genenl-Low hazard to heat or opsn flame; combustible,poisonousga$s may be releaS€din tirs. Gen€rsl-Moderate lire hazard when exposed to heat or flame.
223 (ccl
FLlh Point CF)............................. 86 (cc)
Fhsh PoitrtCF).............................
Ffmnrbfe Lid|ts..........................
LEL: 2.2"h UEL-unavailable Flmmble Limits..........................
O.74lo 2.9o/o
ArtoignitionTenp. ("F)................
Unavailable AutoignitionT€np. ('D ................
545
E(inguishinS Agentr Waler fog, COr, dry chemical Extinguishing Ag€nts.....................
Dry chemical,foam, CO,
SD€cidFire Prcedurq................ Wear goggles,lelf-contained breathingapparalus,rubb€r gloves. Cool SDecialFire Predum................ Tanks exposd lo fire should be kept cool with a waler spray. Water may be
exposed tanks wiih water spray. in€tfective on tire.

H6lth H84d Rstirgs Odor Threshold(ppm) PELITWA (Dpn) TLV,/TWA (ppm) H€rlth Hsed RrtinSr Odor Thrchold (Dpn) PEL,/TtryA(DDn) TLV,/TWA (DDD)
3.2.3 3 2/Skin 2/Skin 0. 0.0 Unavailable 200 200
G€Deml-Toxic by ingestion,inhalationor absorptionthrough skin. G€trersl-Low toxicity; irritant,narcotic in high concentrations.
dizziness,ditficult brealhing,nausea, vomiling, convulsions,irriiability.Skin becomes Symptoms-lrritationol respiratorytract. Narcotic in high concentrations.
irritated.
Short ExposureTolerance-2o0 ppm for 30 minutes. Short ErD6ure Toleruce-Unavailable
ExDo8urePrcedures-Remove victim from source ot exposure and give resl. ll breathing stops give artilicial Expocue Prceduro-Remove victim to lresh air. Apply artilicial respirationif br€athing stops. Get medical
respiration.Remove conlaminatedclothing and shoes; tlush atfected areas with wator. Call a physician, attention.
REAC:TIVITY DATA REACTIVITY DATA

srrbility-stable. Reacts with sulturic acid, oxidizsrs. Strbility-Stabls.
Crmpstibillty-M8teri.l Usual materialsol constructionara suitable. ComD.dbllity-Material: Compatiblewith most materialsol construction.
Crgo: Group 42 of compatibilitychart. Cargo: Group 3l ol compatibilitychart.
I'-*
SPILL OR LEAK PROCEDURE I SPILL OR LEAK PROCEDURE
W€ar prolactivs clothing, s€ll-contain€d brsathing apparalus, butyl rubb€r glovos. Avoid rblorption through Heve all-purpos€canister mask available.Secure ignition sources.
the skin.
lf | lDlll acun, cdl thc N.lloosl ttG4ll{112, ltr Nrdoul ReM C.nter. 80G,|X-E802.
Rcm.'li: Thos€ data aro tor tha orlho form; lha pata and m€tr torm6 ol Nltrotolufia mty dltlar a(,rnowhrrtrl llr..
'
l'olluttr,il ( [l0gofy C rrl trkO,33 CFR 151.49
spocric physrcelproportro!.
' Vspor Pratru.er I mmHg rl 5O'C.
221
I
l.NONENE I NoNyL pHENoL
stutD- n'Hoptylethylsns; I -Norryl€n€ Synonyms- No common synonyms. UnitedNrtionsNunbcr.............................. I
CHRIS Cod€ . NNE NNP

CHRIS Code.......... .....
l'ornuh-CHr(CHz)6CH : CH, Fornuh-GHTOHGHTT

Point..........................
BoiliDg 147"C 297'F Eollln8 Point..... 304'C 579'F
ADDclrucc-Odor-Colorless liquid with a pungent - -az'3 App€rmce-Odor-Clear, straw-color€dgyrupy liquid; - -zo'3
hydrocarbonodor FreeziPn so i r t . . . . . . . . . . . . . . t *'F phenolic odor, liks disinlectanl FreztnsPoint......... -'F
spectncGrrvtty-o.73 _'c _"F Spcific Gravtty--4.94 _'c _'F
-*3i- Vrlnr Pr$ure 20'C (68'F) (nnHg)...... . Low
chemrcrr
Family-orerin ffi'r-"fi:il"""11;:,($"?..1::ll-.:....:.. C'hemicilFrmily-Phenol ReldVrDolPresure(prir)....................... Low
- vspor Presue {6'C (115'D (Dsis)........ 0'35 v.por Prsure 46'C (115"F)(psia).............Low
.
PollutionCstegory-USEPA- IMO -----E- Vrpor DeNity (Air : 1.0).........................4.3 PollutionCat€gory-USEPA- IMO A Vrpor Density(Air : 1.0)...........................
7.59
ADDlicrbleBnlk Reg.46 cFR Subchr!ter........ D. O .
Sohbilityin wr1er....................... Neolioible ........ D. O
ApplicsbleBulk Reg.46 CFR Subchrpter Solubilityin water.......................
. Neolioible
Gnde-D: Combustibleliquid Grade-E: Combustibleliouid
Eletrlcd Group-D Electricd Grou!+D
ccrcrd-Modorate fke heard when exposed to heal or flame. G€rerd-Slighl haard, whon exposed to hsat or tlame.
F l s h P o l n t( ' F ) . . . . . . . . . . . . . . . . . . . . .8. 5. . . . . . . Flsb Point ('F).............................

300
f'lennrble Linits.......................... 0.7 to 3.9% LEL: 1% UEl-unavailable
FlammsbleLimits..........................
AutoigritionTemp,('F)................ Unavailable AuloignitionTenp. ('n ................Unavailable
Extinguishitrg A8ents..................... Confingdspace-dry powder,COr. Open area-toam. Extinguisbing A9ents.....................
COz,dry chemical,alcoholfoam,waler fog
Specld Flre Prcedures................Water may be ineffeclive on fire. Cool exposed tanks with waler. Specid Fire Prcedures................Water or foam may cause frothing. Firefightingpartiss should be provided with
lull body and respiratoryprotection.

He.lth Haad Ratingr Odor Thr*hold (ppn) PEL,/TWA (ppn) TLVAWA (ppn) Heslth HMrd Rrtingr Odor Thsbold (ppm) PEL,/TWA (ppn) TLV,/TWA (ppm)
1, 1, 0 Unavailable Unavailable Unavailable 1, 2, 1 Unavailablo Unavailabl€ Unavailable
General-Low toxicity. Etfects similar to gasoline and kerosene. rrntAtingto skin and eyes
vapor concentrationirritateseyes and respiratorylract; acts as an anesthetic. Symptoms-Skin contact may cause bu.ns and blisters.
Erposure Tolerdce-Unavailable rl ExDosureTolerurBreathing the vapors in a state approachingsaturation in room air was not tatal to
animals nor was a 4-hour exposure to mists, generat€dtrom the chemical heated to 170'c. Eight hours
exposure to the mist killed 2 of 6 animals.
ErDcure Pr@ed|rrlf ingested do NOT induce vomiting. Vapor-remove victim to lresh air; it brealhing stoPs, ExposurePrftedurehRemove viclim lo lresh air; il breathing stops, apply artiticial respiration.Skin or eye
apply artificialrespiration.Skin or eye contact-remove contaminatedclothing and gently tlush afiectsd contact-immediatsly tlush atfected areas gently with water lor 15 minutes. Remove contaminatedclothing.
areas with waler for 15 minutes.Get medical advice or attention. Get medical atlention.
Strbiltty-Stable.
REACIIVITY DATA
I REACTIVITY DATA
Confdblllty-Mdcrldsr Mild stol is suitable; may sotl€n som€ rubb€rs, painis, or plastic!. Crnpatibility-Msterial Should be stored in stainless steel. Nonyl phenol picks up iron in plain steel. Copper

I and its alloys promote color formaron.
Car8o: Group 21 of compatibilitychart.

Wclr rubb€r glove!, taco shield, protectiveclothing. Have all-purposocanbtor mlrk lvalhblc. A\old conLcl
Wgat rubbgl, lace shield, Protective clothing. Have all-purpose canister mask available. Avoid contacl wrn
wrlh hqud SmurC lgnition lources.
lf r olll acrn. oll tbc Nrtlool nm C..rcr. m0!.ara-llo2.

I ll r rplll mrr, cdl tic Nraloul R6mE Ccnacr
t-
l-.br t Unr.r0nad l..hr I Um.rgn.d
ll SCANNED BY MKP
,rY --t& BARIS A. 2004 n,
iso.OCTYL ALCOHOL
NONYLPHENOLSULFIDE Synonyns- Alcohol C-8; Dimelhyl-1 -hoxanol: United Nrtionr Number ..... r
ls@tanol; lsooctyl alcohol: 8-Mathyl- l'
Synonyms- No common synonyms. United Nltions Numbe. ___l_ h€ptanol; Octanol; iso-Octanol; Oxooctyl
alcohol
CHRIS Code................. ..... toA
CHRIS code........... . NPS Formulr-CzHroCHzOH
8 o i 1 1 n f P o f t r t . . . . . . . . . . . . . . . . . . . . . . . . . . ' 1 7 1 ' C3 3 9 " F
Formuls-Mixture Appeme-Odor-Clsar liquid; mild odot
B o i l i n SP o i n t . . . . . . . . . . . . . . . . . . . . . . . . . . 3 1 5 ' C 600'F Frezlns Polnt. IOS"C -tSZ"f
App€arance-Odor-Dark brown liquid with mild --trc Speclflc Gravlty-0.83 _'c _'F
petroleum odor. Freczln8 Point......... .. . ro'r
Vrpor Prcsure 20'C (6t"F (mmHd....
Specific Grrvity-0.97 _'c _'F Ctemicd Fmlly-Alcohol
Reld V4nr Proure (prh)...
Vipor Pre$ure 20'C (6t'F) (mmHo.......... V Low Vepor Prcsure 46'C (f15"t) (psl8)'............. 0 03
Chenicsl Family-Petroleum oils Pollutlor Cde8ory-USEPA.- lMO. C
Reld Vepor Pressure (psis)......... ............. V Low VrDorDcmlty(Air t , 0 t . . . . . . . . . . . . . . . . . . . . . . . . . .4.. 5
Vlpor Pressure 46'C (ff5'F) (psir)......... . V. Low Appliceblo Bulk Rq.46 CFR Subchapter ... .. D. O Solubility In Water Neolioible
Pollution Category-USEPA - IMO |, V o p o r D e n s i t y( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . NP
Applicsble Bulk R€g.45 CFR Subchrpter........ D Solubility in Water Neolioible
I,'IRE & EXPLOSION HAZARD DATA
Grrde-E: Combustibleliquid
FIRE & EXPLOSION HAZARD DATA Ele-tricd Group-D
GradFE: Combustibleliquid
Electiical GrouD-NA G€nerd-Moderata fire h&ard if exDosedto h€at or flams.
Genenl-Moderaie tire hazard when exposed to high tsmperatures.Combustionproduces some sultur dioxide
and carbon monoxide.Above 140'F, hydrogensulfide, a poisonousgas is given ofl. F l s h P o l r t C D . . . . . . . . . . . . . . . . . . . . .1
. .8. .0. . . .
Flmnrble LiDits.......................... 0.9 to 5.7%
greaterthan 200 (cc)
FlsshPointCF)............................. AutoiSnltlon Tenp. ('F)................ 530
FlammrbleLimits..........................
Unavailable Extin8ulshlng49ents..................... Confined area-Co,, dry chemical. Open-foam.
AutoigritionTemD.('F)................Unavailable Sp€cislFire Procedur6................Use water to cool tire exoosgd tanks.
ExtinguishingA8ents.....................
Carbondioxide,dry chemicals,water sprayor loam.
SpecialFire Preedurg................ High temperaturescreate toxic lumes. Keep tanks cool with waler spray.
Firefightersshould have self-containedbreathingapparatusand protectiveclothing.
HEALTH HAZARD DATA

Hedth Hurd Ratings Odor Thrshold (ppm) PEL,/T|VA (ppn) TLV,/TWA (Dpn)
HEALTH HAZARD DATA 0,0, I Unavailable so/Skin SOlSkin
Health Haard Rrlin8! Odor Threshold(ppm) PEL,/TWA (Dpm) TLV,/TWA (ppm) General-Low toxicity; irritationot skin and mucous mgmbranes.
Unavailable Unavailable Unavailable Unavailabl€
General-Negligibleeffects lrom inhalation,ingestionor skin absorption.Persons hypersensitiveto amine
derivativesshould avoid all exposure. SymDtoms-lrritatesgkin and ey€s.
Synptoms-Mild skin irritationand reddeningol skin will occur after prolonged contact with skin. Short ExDosu.eTolclreFunavailable
Short f,xlmure Tolerance-No cumulativetoxic or sensitizalioneflect results trom repeated exposure,

ErposurePrcedurd-Vapor-remove victim to fresh air Skin or eye contact-rgmove contaminatedclothing
and g€ntly flush aft€ctgd sreas with water tor 15 minutss. G€t m€dical advice or atteniion.
ExpmureProcedure-Skin-wash atfected area with water. Eyes-flood eyes with copious amounts ol waler.
Vapor-no particularhazard at room temperature,but toxicity increaseswith increase in temperature.tl
exposed to odorous lumes, get medical help.
REACTIVITY DATA
Strbllify-Stabls.
REACTIVITY DATA
Stability-Avoid high temperatures(140"F) and prolonged or repeated heating since one component will
decomposeand give off poisonoushydrogen sultide. Usual matarialsol constructionare suitable.
Comprtibility-Msterial: Has no corrosiveor destrucliveetfects on steel, wood or cloth. May sotlen natural
rubber and some paints. Cargo: Group 20 of compatibilitychart. See also Appendix l-Exceptions to the Chart.
Crgo: Group 33 of compatibilitychart.

wsar rubber glovss, tace shield, prolective clothing. Have all-purposecanister mask available.Avoid contact
SPILL OR LEAK PROCEDURE h liquid. S€cure ignilion sources.
Wear rubber gloves, lace shield and sell-contained breathing apparatus. Avoid contact with liquid. Socure
ignilion source.
It r |l|lll ccun, cll lhe Nstionsl nEtpnre CeDter, t0O-424-E802,
l? | |'lll ocarr.. call lh. Nrtlonrl R6r6x lrlr: lUn dgmd

C.ntcr, tdL42+!112.
lcnrrlr: Thic serie8 ol ptoduclt containr dput 5oq" lubncttrng orl! Tho romatn,ng compounds, whlch ncluda
nonyl phonol iultrdo il concontrttlont
, No l)otormtmlon
I Unr[tgnad
ol lear tlun 6\, tro orKtrton Inlrbtto.! or dotorgont sddttuoa
I 227
OLEUM
{20 to 66% SOr) oltvE orL
SynonyrFuming sulluricacid;Sulturicacid,tuming UnliedNltions Nunber....................
......... 1831 Synonymr-Swo€t oil Unit€dNationsNumber............................. f
CIIRIS codc........... .... OLM CHRIS Code........... .. OOL
Formula-HrSO..SO. Formuls-Mixlurs includingoleic, palmitic and linoleic

Bolllrr Poini....................Dgpeloleses-'9
-'F acros . . . .H. i o h ' 9 - ' :
8oi1in8Point..................V
Appeararce-Odor-Colorless,oily liquid;sharp, Appemnce-(Xor-Pale yollow or greonish-yellowliquid; -t'c -'P
penetralingodor l'rednt Polnt'....... --l-ro-!p'C zs ru'r slight characleri8ticodor. FreezingPoint.........
SpecilicGravity-1.88 to 1.98 Slmillc Grevlty-0.91 lo 0.92
VrDorPmure 20'C (68't1 (mmHg,........ Low vatpr Presure 20'C (58'D (mmH9.......... --2!4-
ChemicslFsmily-lnorganic acid C'hcElc.l l'rmlly-Etrlcrt R e i d v r l D r P r e $ u r e ( D s i a ) . . . . . . . . . . . . . . . . . . .0
. ..,1.
Rcld Vtror Praurc (pri.). . Low
- vtDor Prdurc {5'C (ll5'}') (psir}............ Low - VsporPrsure rl6"C(115"F)(Dsi!)........... . 0.15
PollutionCateSory-USEPA- IMO --Ja- V1po,D.ulty (Al, 2.76 Pollutioncrtclory-UsDPA .- fMO D V4nr Demity (Air : 1.0).......................... NP
f.0). ..........
ApplicobleBulk Reg.{6 CFR Subchrpler ... O Solublllty ltr Wrte. . . Comolete ApplicebloBrlt Rcg.116( l'R subchrpter........ D Solubilityin wrter......................... Neolioible
GrrdFNonjlammabl€. Classitiedes a corrostveliquad. Grrde-E: Combustibleliquid
ElectricalGreu!+B (based upon possible hydrogengas (H,) generationshould a leak or sdll occuo Electricd Group-D
Cenerd-Olsum will not burn. lt will react with many mgtals, giving olf hydrogengas which is highly flammable. C€nerd-Slighl tr€ huard whon grpo8€d to heat or flam6.
ll hydrogen is trapped in confined spacas il can form an explosivemixlure with air. See data sh6et for
hydrogen.May cause fire on contacl wiih combustibles.
Fluh Point ('F).............................
Non-tlammable F l s h P o h a( ' n . . . . . . . . . . . . . . . . . . . . 4. .3. .7. . .
FlanmrbleLidits..........................
Non-tlammable Flmmrblc L|hits. . .................... Unavailable
Autoignition Temp.("F)................Non-flammable A u t o l g n l t l o n T e m( p
' D. . . . . . . . . . . . . .6 5 0
ExtiDguishinS A8entE.....................
Not applicable ExthSubhltrSAgenrE.. . ...............Ory chemical,loam or carbondioxide.
SpecislFir€ Prcedur6................ DO NOT USE WATER to put oul a tire il the waler can get into oleum. lf tire SDccid FLG Prcedurec.......,........Waler may b€ inotl@tive on firs. Cool exposed tanks with water.
is next to an ol€um tank, wear respiratoryprotection against lumgs. Wear full protectiveclothing.

Hedth H@rd Rrtings Odor Threshold(ppm) PELITWA (Dpn) TLV,/TWA (pDm, Hedtb Hred Rrah3' (Xor Ttrotold (ppn) PEL,/TWA rppm) TLV,/TWA (pDn)
4,4,3 1mg/m3 1mg/m3 1mg/m3 0, 0, 0 Unavailsblo Not D€rtinent Not oertinent
G€renl-Vapor extremelyirritating.Liquid causes severe burns. (;en€r.l-Not harmful
Symptoru-Severe respiratoryirritation.Skin burns will result lrom contact with the liquid. Symptoms-None
Short ExDosu.eToler.nce-s ppm can be toleratsd lor 5 minutes without permanent damage. Individual Short Erln6ur€ Tolerance-Non-toxic
sensitivityvaries trom unpleasantto unbearablelrom 0.2 to 20 ppm.
ExposurePrcedurd-Vapor-remove victim to tresh air; il breaihing stops, apply artificial respiration.Skin or ExposurePrcedure-Non-toxic. Wash thoroughlywith soap and watef
eye contact-remove conlaminatadclothing and gently llush aftected areas with waler tor 15 minules. Gel
medical attenlion as soon as Dossible.

Strbility-Reacts violentlywith water, producinga great deal of heat. Stability-Slable.
-Oleum rsacts vigorouslywith many m€tals releasingfrydrogen.Extremetyhaardous in ih6 Comprtibility-Mrterial: Usual materials of construclion are suitable.
presenceol many materials.Oleum destroys many plastics and rubbers atter briel contact. Glass and
Teflon, however,are completelycompatible.
Cugo: Unassignedin compatabilitychart. Compatibilityassistance availabtetrom CrrSo: Group 34 of compatibilitychart.
G-MTH-l 1202-267-1577r.See Appendix t-Exceptions to rhe Chart.

Wear rubber gloves, self-contained breathing apparalus, protective clothing. Have body shi€ld available
contaminatodsurlace and spill with sodium bicarbonateor a soda-ash-slakodlims mixtur€ (50-50).Do not
scoop up unlil neutralizationis completed.
If r spill occurs, cjl the Nrtlold ndDons Centq. mG,a24-tto2. It r $ill occuB, crll ahe Nrtiond Center. 800-42i4-Eg)2.
Rcmrrlr: ' Tho frszing poinl lo( 20"/" SOi is about 25'F. lt riges with SO! conc€ntrationto about 95'F at Rrmb: I Unevsilabls
45ol.,thon lalls otf lo about 30'F at 66%. I Unassrgn€d
229
(IOTE: Thlr c.rgo lt cuircnlly nol plrmltt.d to b. .hlpp.d In bulk In U.9. w.l.ra)
OXYGEN fllquefled) PARAFFINWAX
Synotry|r Liquid oxygen; LOX compressed '1072 Synonyms-Hard wax; Paraffin:Pa.aflinscale; United N.tions Numbe. . ____t_
Uritcd Nrdou Nrmb€r
relrigerated 1073 Petroleumwax
Formulr-Oz
cHRIs code " .. oxY t Formula-High weighl hydrocarbons(for
CHRIS Code................. ..... ....... wPF
.-698"F
-183'C -297'F example:C,"H,o) Boiling Point.......... .... --370'C
BoilingPo1nt........................
Apperrmce.Odor-Light-blue liquid;odorlsss _'c _'F Appcarrnce-Odor-White to yellow translucent
Freezing Poht...................... 227'C -376'F practically odorless, solid l ' r e € z i n gP o i n t . . . . . . . . . . . . . . . az-oo"c roe_1ao'r
'c 'F SpecificGrsvity-o.80 to 0.88
SpecificGravity-l.14 (at bp)
VaDorPr$sure 20'C (6E'D (nnHO.......... -V--Ejgh- Vlpor Pressure 20"('(6t"D (mmHg)........ V. Low
Ctemicd Frnl|y- ChemicalFrmily-Saturated hydrocarbon Reid vrpor Presure (psi&) V Low
ReidVaporPrsure (psi8)........... .. ..... V Hioh ...
Vrpor Prsure {5'C (rrs'D (psir).............lg-lligh- Vapor Pressure 46"( (It5'1.') (psia) ........... V Low
Pollutiotr Crtegory-USEPA - IMO ---ga!t- Pollution Cltesory-USEPA - IMO lll Vlpor l)cnsity (Air NP
V r p o rD e n s i t y( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . 1. . 1
.. 1.0)........ .
ApplicableBulk Reg.46 CFR Subchapter
..... Solubility in Wster ... 4.5vo ADplicsbteBulk Reg.il6 CFR Subchapter D S o l u b i l i t yi n w i l c r ... ..... Neoliaible

Grrde-Liquelied CompressedGas (LCG).Classilied as nonflammable.
ElectricslGroulFNot applicable
I Grrde-E:
Electric.l
Combustible
Croul-O
General-Oxygen does not burn but supports combuslion vigorously.A combustiblematerial onlo which LOX Generrl-Slighl lire hazard it subiecled io h€al or tlam.
has spilled will burst into llame or explode if exposed to a spark source.
Flsh Point CF).............................

Non-llammable, but supportscombustion. Flsh Point ('l') .....................3 . .8. 0 t o 4 6 5
Flmm.bl€ Linits..........................
Nonjlammable F l . m m r b l e l , i m i t s . . . . . . . . . . . . . . . . . . . . .U. n a v a i l a b l e
AuloigDitiotr
TeDp.CF)................ NonJlammable A u t o i g n i t i o nT e m p . ( " 1 ) . . . . . . . . . . . . . . 4. .7 3
Extinguishitrg49ents.....................
Use media suitablelor substancewhich is burning. Extinguishing Ag€nts................... Conlined area-Co2, dry chemical pen area-toam, water spray.
sp€cialFire Prcedures................ lf the insulationlails on a LOX tank exposedto fire,lhe tank will explode. Specill l'ire Pr@edu.es................Water or loam may cause frolhing.
Evacutelirefightersto a safe disiance and have them take cover.
Health Hsard Ritings

HEALTI{ HAZARD DATA
Odor Threshold (ppm) PEL,/TWA (Dpn) TLVAwA (ppm)
I Hedth Hrud Ratirgs Odor Threshold(Dpm)
HEALTH HAZARD DATA
PEL,/TWA (ppn) TLV,/TWA (pp6)
Unavailable None Unavailable Unavaiiable Unavailable Unavailable 2 mg/m3 as a lume 2 mg/m j as a fume
General-No hazard for gas. Liquidcan cause severe "burns" Generd-Non-toxic, but possibilityol thermal burns trom hot liquid.
and tissue damage on contact with skin.
Symptoms-Skin coniact with liquid will freeze tissue. Symptoms-Non-toxic
Short ExDcure Tolemrunavailable Shorl ExposureTolerance-Non-toxic
ExDo6urePMedureFlf the liquid has spilled onto the skin, points ol contact may be frostbitten;handle gently ExDosurePr@edures-Liquid on skin-remove wax and contaminatedclothing and cool altected areas with
and protect lrom mechanicaldamage.DO NOT RUB. Get medical attention without delay. AVOIO SPARKS
AND OPEN FLAME.
r water. Liquid in eye-llood eyes gently with clean sea or lresh water. Continue washing lor at least 15
minutes.Get medicalattention.
REACTIVITY DATA
REACTIVITY DATA
stebility-Lox will flash into vapor at temperaturesabove 180"F. ll uncontined,lhe vapor will occupy about strbllity-Stable.
860 times lhe volume ot the liquid. lf conlined, a sudden and large pressure increase will result.
comDrtibility-Materid: LOX causes all combustiblematerialsto burn vigorously.A spark is not always needed ('omDrtlblllty-Mrtcrl.lr Usuel melerials of construction ars suitablo.
lo ignite such a mixture.
CsrSo: Unassignodin compatabilitychart ( rrgr: Gtoup 3l ol compalrbrlrty chan
SPILL OR LEAK PROCEDURE \l'll l (rn l.]:Ax I'Rrx t.j)trR]:

Secure ignition sources, rope otf the spill area and call ths tire deparimsni. Oxyg€n will quickly borl oll Avtx, ' dllr I nlrt lpl li|/{l W..r 0r{lillrr rr l|aa llrll. trotr.lF, r)krthno lor |x)t hqu(l (;lorn or B(.rtrt),.
Extr€me precaution against sparks must be observed belore ro-entgringihe 8pill ar€a bocruta, unlaaa tha itrll it nb ml.|rr
rs in th€ open with a good brsz€ blowing,the area will be orygen-rich for I long tim€.
lrlr: ' Xol .llowcd

ll r rplll ccurq cdl th€ Nrtlond
to b. rhlpgad In bult.
C.rtc.. tm-42/a{t02. t l.:rlr t{,. ,,r t}r.a..Et rt er.r!t teris.t,rdr .q1 4ll ( | ll llr I l'vdh'r' lr,ilt|"r{lur0 (jflre()t's
| , .{rql
2ro $l
PARALDEHYDE PEANUTOIL
Synonyms- p-Acelaldehyde;Paracetaldohyde; Synonymc-Arachis oil; Earthnut oil; Groundnut oil; Uniied NrtloN Numbcr.. , . . , . , . , . , . , , . , . , . , r.
2,4,6-Trimethyl-1,3,5-trioxan€;
1,3,5-Trioxane, Katchung oil
2,4,6-trimethyl-
( llRlS ('odc. ................ ' . . . . . .. . . . . oPN
Formula-CsHrrOr Fomrh-Mixture
Bolllng Point.. 128"C 262"F I l o i l i n gl ' o i n l . . . . . . . . . . . V. Hioh"C _'F
App€rrance-Odor-Colorlessliquid;aromatic odot _'c _'F ApDcrrrnce-(No.-Yellow to greeniSh-yollowhquid wllh
i?.c 56.F
FrezinS Point a p€8nul{iko odor F r o c z l n t P o | t r t . . . . . . . ... . . . s'c s7'r
SpecificGrrvity-o.994 _'c _'F SpccltlcGrrrlty-O.92
ValDr Presure 20'C (6S'F) (mnHg).......... t Vrjnr I'rrsurt 20"(' (68'l') (mmHg.......... 2 04
Chenicsl Fmily-Aldehydes ReidVrDorPresure(prir)........................... t clEmlcrl l'rdlly-Eal'? ttcld Vrpor l'rcsurc(lrlr). ....................... 0.1
Vrpor Pressure il6'C (115'F) (psia)........... 8.3
Vrp.)r I'rerrurr 46 ( (tl5 t) {Dsir)... ... 0 15
PollutiotrCrteSory-USEPA C IMO C V r p o r D e N i t y ( A i r : 1 , 0 ) . . . . . . . . . . . . . . . . . ... . . 4 . 5 5 Pollutlon Cractory-l 'Sl:l'A - IMO p- V|Por t)rnrity (Air I.0) . . NP
ApplicrbleBulk Reg.,16CFR Subchapter..... O Solubility in Wster Slioht Appllc.blaBulh Rcg,ra6( IrR Sub.h.ptrr .. .9 Solublllty ltr I'lrter Neolioible
FIRE & EXPLOSION HAZARD DATA rlRE a ltxl,r.()sloN ilAZARt) DATA

Grsde-D: Combustibleliquid unoe-E: Combustibleliqurd
uomougt
ElectricalGreup-C Eletrlc.l (;roop-O
Genersl-Toxic lumes are given otf when heated. Oangerouswhen sxposed to heat, flame, or oxidizers. Gcnerrl-Slight tir€ hazard rl exposed to hoat and llame
F l $ b P o i n t( ' F ) . . . . . . . . . . . . . . . . . . . . .9.6. . . . . . . F l s h P o l n t ( ' n . . . . . . . . . . . . . . . . . . . . . . . . . 5. .4 0

FlmmableLimits.......................... LEL: 1.3oloUEL-unavailable Rrmmrblc Llnltr...... Unavailable
AutoigritionTemp,('F) ................ 460 Autoignltlo TcnD. ("1')................
833
Extirguirhing Agents Alcohol foam, CO, or dry chemical Extingulrhln8A8cntc .............. Ory ch€mical,foam, or carbondioxide
SpecialFire Prcedurg................ Water may be inettectiveon lire. Wear lull protective clothing and respiratory Flrc Prcedures................Watgr may be inelfectiv€ on firg. Cool expos€d containerswith waler
orotection.
Health Hafrd Ratingr

1, 1,2
HEALTH HAZARD DATA
Odor Thruhold (pDm)
Unavailable
PEL,/TWA (pDm)
Unavailable
TLV,/TWA (ppm)
Unavailable
t Herlth H|4d Ratil8r
HEALTH HAZARD DATA
Odor Threshold (ppm) PEL,/TWA (ppn) TLV,/TWA (Dpn)
Unavailable Unavailable Not pertinent Not pertinent
Generrl-Vapor harmful il inhal€d.
SymptodFlrritation, headache,bronchitis,incoordination,drowsiness,digestivedisturbance.Can cause $rioug

I Generrl-Nol
Sydptoms-None
harmlul
eye Inlury.
Short ExlDsureTolerance-4oo0 ppm latal to 3 of 6 rats in hours. The lowesl toxic dose lor humans is 14
mg/kg.
ExDosurePr@edures-Remove from exposure;give artificialrespirationor oxygen if needed. Flush eyes wilh

I ErDcur€ Toleme-Not
Exlnsure Prcedures-Non-toxic. Wash thoroughlywith soap and water.

harmful
water for 15 minutes,wash skin with soap and water. Bemove contaminatedclothing and sho$.
I
Strbility-Dangerous when exposed to heat or flame. Can react vigorouslywith oxidizing materials. st bility-stabl€.
ConDstlbility-Mrterld: Usual materialsof constructionare suitable- ConFtibility-Msterid: Usual materialsol construclion are suitable.

t Crryo: Group 34 ot compalibilitychart

W€ar prolecliv€ cloihing, goggl€s and self-containodbreathing apparatus. Avoid contecl wdh lrqurd S.clra
ignilion sourceg.
Waar rubber glova!, lace shield and protective ctothing.Avoid contact with hot liquid.
lf r dl ccun. c.ll thc Nrtlond lt. crll N.llod R6mnr Ccntrr, 8fi)-42,1-88{12.
Larrl.: I Uilvadabla lxb I trurqtEl
212
1 -I 2.rt
-.'* -& _._ SCANNED BY MKP & BARIS A. 2004
l,3.PENTADIENE
PENTACHLOROETHANE
Synonyn!-alpha-Msthylbivinyl; cis-Penladisns-1,3; United NatioE Numb€r __l_
synmyms- Ethane, pentachloride;Ethane, trans-Psntadieno-1,3; l,Msthylbutadi€n€; Pip€rylene
p€ntachloro-;P€ntalin
CHRIS Code................. PDE
Fomulr-CHr . CHCH. CHCH'

Fomuh-CHCITCCL Boilirg Point.......................... 43'C 108"F
Boilirg Poirt . . 162'C 324'F
Apporuce-Odor-Colorless liquid; laint odor.
Appesrance-odor-Liquidwith sweetish chlorolorm-like --zg'3
-r:F Freezing Poltrt .............. -88"C -126'F
odor Frezirg Point......... "c 'F
SDcclfic Gr.rlty-0.68
SD€cificGrrvity-1.67 _'c _'F
valDr Prwure 20'C (68'F)(nnHO.......... 345
VsDorPrsure m'C (68'n (mnHg..........----:- Ctcmlcd Fully-Ol€lin! ReldVrpor Presure (Dsis)........................... 10.9
CrhemiolFrnily-Halog€nated hydrocarbon Reidvspor Prsue (Drir)...........................
----l- vapor Prsure 46"C(rr5"F) (psia)............. -JJ-9L
VstDr Prsurc 45'C (1f5'F') (Dsir).............-L- Pollutlotr C.tctory-tlslpr B lM() C V r p o r D e r l t y ( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .2. . 3 6
PolludoDCsteSory-USEPA A IMO B vrDor DeBlty (Air : 1.0)..........................7.0
ApDllqble Bult RcS. a6 Cfn Subchepter O Solublllty in Water lnsoluble
Applicrbl€Bul* Reg.{6 CFR Subchapta........ O Solubllltylnwrter......................... Insoluble
I.'IRI.]& EXPLOSION HAZARD DATA

FIRE & EXPLOSION HAZARD DATA Grede-B: Flammabl€liquld
GrsdFNon-llammable El€ctrlc.l GrouD-O
Elctricd GrcuP-NA
Gcncnl-Highly flammable,d.ngdous lirs r8k.
cencrst-Dangerous when healed to decomposition; dshalogenation will produce spontaneously explosiv€
chloroacetylenes.
F l s h P o l n t( ' F ) . . . . . . . . . . . . . . . . . . . . . . .2. .0. . .
Flsh Point Cn.............................Nonjlammable F l m m b l c L | m l t r . . . . . . . . . . . . . . . . . .1 . ...5. .l o
. 8.0%
Nonjlammablo
FlaDmsble Limits.......................... Autotnlilon TcnD,("1) .............. . Unsvailabl€
Autoignition Temp. ("F)................ Non-flammable Erdtrgukhln8A8cnts ............... Foam,dry chemical,CO,
ErtirguishirS ASents Non-llammable SDccld Flre Prucdurw.............,.. Wat€r mey b€ inetfsctive on tire but may bo us€d lo cool tanks. Vapor may
Fire Preedur* ....,........-..Non-flammable accumulais in an enclosod area presentingan €xplosion hazard.Wear sell,containedbreathing apparatus
HEALTH HAZARD DATA

HEALTH HAZARD DATA Heslth H'@d Ratingt Odor Thr6hold Opn) PEL,/TIVA (ppn) TLV,/TWA (pDm)
Hedth Haed Rrtings Odor Thshdd (Dpn) PELAWA (ppm) TLvAwA (pDn) 2, 1, 3 Unavailable Unavailable Unavailable
GeDersl-Modsrate haa.d for vapors, slight tor liquid coniact, and acute for ingestion.
General-Highly narcotic. Eye and upper respiratorytract irriiani.
SymptomrDizziness, hgadache.lrritates eyes, nose and upper respiratorypassages.

Symptoms-Has been indicatedas being more narcotic than chlorolorm. Exposureto this material may cause
injury to liver, lungs and kidneys.Has alcohol irritalingeftect on eyes and upper respiralorytract.
Short ExD6ue Toleridce-Lethal oral dose ol 1.75 glkg ol body weight in dogs.
ExDosurcPr@edur€-Remove victim to fresh air. Give artificial respirationor orygen as necessary.Eyes-flush

Exposur€Prcedures-Vapor-remove victim to fresh air and administerartificialrespirationif necessry. with water lor at least'15 minutes. Remove contaminatedclothino immediatelv.
Skin-flush affected areas with water. Eves-flush wilh water lor 15 minutes. In all cases call a doctor.
REACTIVITY DATA
REACTIVITY DATA Stlbility-Polymerization may occur. Must contain inhibitor.Reacts with oxidizersviolently.
Strbility-Stable.
ComFtiblllty-Moterid: Dissolvesrubber and paini. Stainlesssteel, aluminum,lined steel and carbon steel are
Comprtibility-Material: Usual materialsof constructionare satisfactory. suitable.

cuSo: Group 36 of compatibilitycharl

Stop dischatge il possible. Evacuate area. Sscuro ignition sources. Stay upwind and use water spray to knock
Wear rubb€r gloves, g€lt-contain€d brgathing apparatus and prolgctive clothing. S€cure all ignilion aouroaa down vlPotE. Woar self-containedbrsathing apparatus,rubber gloves and shoes. Do not flush spill into conlinsd
rpacer whare tlammable vago.s can accumulate.
lt. c.ll lhc Nrlionrl RedDoE C€raer, t00-42,1-8802.

If r olll acun cdl tlc Nrtlond nnu Ceil.r. ttlLa2/a-tt0L
' Vapor Pressuror3.4 mmHg L.-.rlrr I trrt..lon d
lloub: !l 25'C.
t UnrY.llrbl.

1Jt
iso-PENTANE PENTANE
Synonynr- Elhyl dimethylmethane;lsoamyl hydride; United Nrtions Number _l?a!L Synonyns-Amyl hydride;Normalpentane;n-Pentan€ 1265
Utrit€dNrtionr Nmber................................
lsp€ntane; 2-Methylbutane
IPT ( ltRts code........... PTA

CHRISCode........... .... ....
Fomula-(CH:):CHCHzCHT Formula-CHr(CHr)rCHr
' o f f t n s p o i t r t . . . . . . . . . . . . . . . . . . . . . .2. B
. . ' al ' , lloilins I'oint 36'C 97"F
ApD€srnce-Odor-Colorless,mobil, liquid;pleasant -tsg:3 AppMnce-odor-Colorloss liquid wilh O|loline-lik€ --:rio:8-
ooor FrezinsPoint......... -*:F odor l'reezinsPofnt......... n:F
SpociflcGrsrity-0.62 _'c _'F SpeclllcGrrrlty-0.63 _'c _'F
VlporPressure 20"C(68'F)(mnH$.......... 510 Vtpor Pressure 20"C(68"n (nnHo.......... 431
ChemicalFmily-Saturated hydrocarbons Chemlcrl Frmlly-Saturgtod hydrocarbon Reld Vrpor Pr6[re (D8h)........................... 15 5
R e l d V a p o r P r e s u r e ( p s i r ) . . . . . . . . . . . . . . . . . . .2. .0. . . .
Vlpor Pressure {6'C (ffs"F) (psia)............. --Z- V.por Pressur€ 46'C (rl5'F) (ph).............--21-!-
PollutionCsteSory-USEPA - IMO C' PollutlonCsteSory-USEPA-- IMO. C' V . p o r D e N i t y ( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .2. . 4
. .4, .
VsporDensity(Alr : 1.0)............... . ........ 2.44
ADpliflble Bulk R€g.,16CFR Subchspte...... . D. O Solubility in Wrter ....... I n s oluble ApDllc.bleBulk Reg.il6 CFR Subchrpter . D. O Solubilityin Water....................... . Sliohtlvsoluble
Grade-A: Flammabl€liouid Grsde-A: Flammable liouid
Eleclricd Group-D Electrical Grorrp-D
Genersl-Severe explosion hazard in enclosed space in presnce ol a source ot ignition. Eleciroslatic G€rerd-Highly dangerous when exposed io heat or flame. Flashback along vapor lrajl may occur. Vapor may
generalionlikely. Flashbackalong vapor lrail may occur. Vapor may explode il ignited in an enclosed area. explode il ignited in an enclos€d area.
F l s h P o i n tC n . . . . . . . . . . . . . . . . . . . . . .-.7. .0. . . . F l s h P o i n t C D . . . . . . . . . . . . . . . . . . . . . . . . .-.5. .6.

Flammsble Limits........................,. 1.4 lo 7.6"/" Flammrble Linits..........................1.4 to 8.5olo
AutoignitiorTemp.('F)................ 788 Autoignition Temp. ("F)................ 544
Extinguishing Agents..................... Foam,COz,dry chemical Extinguishing A8ents..................... Foam, dry chemical, carbon dioxide
SpecialFire Prftedur6................ Water may be inellective on tire. Cool exposed tanks with water. Use water SD€cial Fire Pr@edures................ Water may be ineffective on fire. Cool exposed tanks with water. Use water
"knock
spray to "kn@k down" vapors. spray to down" vapors.

Health HErd Rstlngs Odor Threhold (ppm) PELITWA (ppn) TLVlTlryA (pDn) Health Ha4d Rrtings Odor Threshold (Dpm) PEL,/TWA (ppm) TLV,/TWA (ppm)
0,0. 1 Unavailable Unavailable Unavailable 0. 0. 1 10 600 600
Geneml-Liquid irritatingto skin and eyes. Inhalationcauses slight local irritation.An asphyxianl,also a narcotic Generd-Vapors may cause diziness or ditficuli breathing. Liquid is harmtul il swallowed.
in high concentrationsresultingin dizzinessand drowsiness.
SymptorBreathing high concentrationsot vapor lor some time may caus diziness, drowsiness. Symptons-Low toxicity.Vary high concantrationol vapors may cause nar@sis.
Short ExpnsureToleruce-Unavailable Short ExposureToleruce-Unavailable
ExposurePreedurc-Remove viciim to tresh air; it breathing stops, apply artiticialrespiralion.Skin or eye Extmure Proccdoru-Vapor inhalation-move victim to lresh air. lf breathing stops, administerartificial
contacl-remove contaminatedclothing and gently tlush aifected areas wilh waler fo|15 minules. G€t respiration.Liquid-have victim drink plenty ol water or milk. DO NOT INDUCE VOMITING.Call a doctor.

Stlbility-Stable. Dangerousreaction possiblewith oxidizingagents. Strbility-Stable. Oangerousreaction possible with oxidizingagenls. Keep away lrom heal, sparks, or open
flame.
Comprtlbility-Mrterld: Certain plasticsare unsuitable. ConDstibility-Msterial Mild steel and stainless stsel are suitable. Natural rubber will soften and deteriorale
rapidly.
Cargo: Group 31 of compatibilitychart, Cargo: Group 31 ot compatibilitychart

W€ar polyethyl€neglovos, tace shield, protective clothing. Have all-purpos€ canister mrsk evrilrblc Avold Wear polyelhylsne gloves, face shield, protective clothing. Have all purpose canister mask available. For gas
contact with liquid. S€cura ignition sources. Do not llush spill into confinsd spaca! whero flemmeblovrporr crn leaks k@p vlpot concentralion b€low explosive mixture range. Secure ignition sources, Do not llush spill into
accumulale. r()nlrn{xlspacet whoro llammablevaporscan accumulate.
lf r cplll Gurr, c.ll the \rtiond Rm Ccrt.r. tm-424-tt02. It i ltlll m cdl ihc Nrtionrl RqDe Cetter. 8lD-42i-tE02.
' pollrrlkrr
Rcnrrkr: ' PolluironCategoryC orl-Ik€.33 CFR 151.49 lErrhr 0ato{Kry C oll.lrka, 33 CFR ! 5t 49

236 Irt
SynonynFElh€ne, tstrachloro-;
Perchlor€thylene; Tetrachlorethene;
PERCHLOROETHYLENE
Ethyleneietrachloride; 1897
UtritedNrtionsNumbcr................................
l l Synonyms- Paralfin ielly; Petrolatum ielly; Pgtrol€um
jelly; Vaseline; Yellow pelrolatum
PETBOLATUM
t;nircd Nrtiotrs Number t:
Telrachloreihylens; Telrachloroethylen€
tI
cHRIs code........... .... PER I ( llRls ( r'de PTL
Formula-ClzO : CCh, or GClr Formulr-Mrxtureol hqurdor semrl|qud alphattc

BoilingPoint.......................... 121'C 250'F hydrocarbons 8oilinrPoltri. -150"C -302"F
oa oE
App€arrnce-Odor-Colorless liquid; chlorolorm-lik6 odor -----=-22'c App€.rrnce-()dor-Colorless to amber, oily translucenl
Frercnc point......... . -----=-g'r no odor r ; r r ( , i n *r ' o i n r . . . . . . . . . g8 60:3 roo-tlo-'F
Specific Gravity-1.62 Sp€cincGrrviay-0.82 lo 0 85 _"c _'F
Vllxrr Prcssure 20'('(68"I;) (mmllg) . . V Low
chenior
Fanly-Unsarurared
harosenar€d fttr'":ii:H*l;:,$"?.1::"-?_ ......:. 0"68 Chemic.lF.nlly-Saluratad hydrocarbons Reid Vapor Pressure (psia) . . - .. V. Low
hydrocarbon Vapolpressure,l6.C (ils.D (Dsi{).............1.23 Vapor I'ressure rl6'C (ll5'l') (psi8) V Low
_ ...
PollutionC.tegory-USEPA B IMO B VsporDensity(Air : f.0)...........................
5.83 Pollutlor CrtcSory-t'SUPA - t\t() - lll VsF,r t)cnsiry (Air = 1.0). . .... . NP
ADpliobleBulk Reg.46 CFR Subch8pter.....
. O Solubilityin water.......................
. Ndioible Applicable Bulk Reg. ,16 Cl'R Sub.hrptcr D Sotubiliry in water Neolioible
Grsde-Non-f lammable (Jrade-D: Combustible
Electrical Group-NA lllectricd GroulpNA
Gercr8l-Does not burn. The liquid or vapor in coniact with a hot surtace or a llame can decompos to form Gene.al-Moderate fire hazard when exposed to heat or tlame.
phosgene, which is highly toxic.
Flsb Point ('F).............................

None F l s h P o i n t ( " F ) . . . . . . . . . . . . . . . . . . . . . . . .1. .3. 6. .
Flumrble Lif,its..........................None Flammrble Limits..........................Unavailable
Autoigrition Temp. ("F)................ None Autoignition TemD. ('D ................Unavailable
ExtinSuishing A9enis..................... None Extinguishing Agents..................... Confined area-Coz, dry chemical. Open area-water spray, loam.
In case of tire near a perchloroelhylenetank, cool the tank with water. Wsar
Fire Pr@edures................ Specirl Fire Prcedures................ Waier or foam may cause trothing.
selt-containedbreathingapparatus.
HEALTH HAZARD DATA

'Ihreshold(ppm)
HEALTH HAZARD DATA
Herlth Hsard Rrtir$ Odor PEL,/TWA (ppm) TLVITWA (ppm) Hedth Hsard RrtinSs Odor Thr€shold(ppm) PEL,/TWA (pDn) TLV,/TWA (ppm)
1,'1,2 20to40 25 50 Unavailable None Unavailable Unavailable
Gen€nl-Suspsted carcinog€n.Prolonoed,gxcessive,or rspaated exposurss to ih€ product in any form are Generd-Non-toxic, but possibilityof lhermal burns trom hot liquid.
hazardous.Can d€fat the skin and may produce dermatitistrom frequent daily contact.
Symptoms-Headache,dizziness,blurred vision, teaB, burning of the eyes, irritationof nos6 and throat. Symptoms-Nox-toxic
Short Ex![Eure TolerucF20o ppm Short Exlpsure Tolersnce-Non-toxic
ExposurePrceduevapor-remove victim lo tresh air; it brealhing stops, apply artificialrespiration.Skin or Expcure Prcedures-Liquid on skin-remove contaminaled clothing and cool alfected areas with cold warer.
eye contact-remove conlaminatedclothing and genily tlush atfecled areas with water lor 15 minules. G6l Liquid in eye-tlood eyes gently wilh clean sea or fresh water. Continue washing lor at least 15 minutes.
medical advice or attention. Get medical attenlion.

Stlbility-Slable up to 258'F; at this temperaturethe product decomposesand gives off poisonoustums. Strbility-Slable.
Compatibility-Msterid: Compatiblewith galvanizediron, black iron or sleel. Cohpatibility-Mat€rial: Usual materialsol consiruction are suitable.
Cargo: Group 36 ol compatibilitychart, Cargo: Group 33 of compatibilitychart

Wea. rubb€r gloves, protectiveclothing.Avoid contact wilh liquid. Avoid contact with hot liquid.Wear goggles or face shield, protective clothing for hot liquids.Wash away with
waler. Sgcurs ignition sourc6s,
lf . rDlll ccu6. crll ah€ N.ilor.l lt ! rgill ccun, (sll thc Nstional R(s@nie Cetrtcr.8fi)-{2{-tt02.
Rcruh: ' Vapor Prsssurer15.8

mHg !t 22'C. lenrrlr; Nornrally lrrniporlcd !l elovalod tompsratur€s Se€ 46 CFR 36-Elevated Temp€ratur€ Carg@8
I Unrr.|gnod
SCANNED BY MKP"t& BARIS A. 2004

2.lt :.le
PHENOL PHOSPHORICACID
Synon) mr- Benzene, hydroxy-; Carbolic acid; United Nations Number . molten 2312 Synonyms-Metaphosphoric acid; Orthophosphoric 1805
UnitedNrtionr Numb€r...............................
Hydroxybenzene; Monohydroxybenzene; solid 1671 acid: meta-Phosphoricacid; oriho-Phosphoncacid;
Oxybenzene: Phenicacid; Phenylhydroxide; While ohosDhoricacid
Phenylicacid
CHRIS Code .. ... .. . PHN CHRIS Code PAC
Formub-GHTOH Fomuh-HrPO.
B o l l l n 3P o i n l . . . . . . . . . . . . . . . . . . < 130'C <266"F
App€rr.nce-Odor-Colorless-to-pinksolid or thick liquid; Apprcrrrnce-(Xor--€lsar, syrupy liquid; practically
odor (like Lysol)
sweet,disinfeclant-like odorless Frczlng Polnt.........
SpecificCravity-1.07 Specific Crrvlty-'1.83
V.Dor Pruure 20 C (6t'n (mmHs).......... --!9!g-
chemicar
Famly-phenor HiJ'rffiT::"11;:113,"? 1"13_.:...:...03 clhemicd Fully-lnorganic acid Rcld Vrpor Prsure (psh).......... ...... Ltr
porution -"i#- - VrDorPresure46'C (ll5"n (psia)............. Low
c rMo B
catesoiy-usEpA Y;il:i:ffi;",ff;':",1i,1]lll11l..:.:.:.:. Pollutim Crtcgory-USEPA O IMO D VrDor Denliry (Alr t.C).. 3.38
Applicable Bulk Reg. 46 CFR Subchapter........ O Solubility in water........................ at 16'C. 6.7"/. ApplicsblcBrlt Rc8.l|6 CFR Subch.Dter........ O solubilityin wster................
. ..... Comolete
at 66'C. comolete
Grade-E: Combustible (;rrde-Nonjlammable. Classilied as corrosive liquid.
Electrical Group-D lletrlcal GroutpB (based upon possible hydrogen gas (H,) generation should a leak or spill occur)
Gen€rsl-When heated, it emits toxic and irritaling fumes. Moderate tire hazard when exposed to heat or tlame Gerenl-Phosphoric acid will not burn. lt will react with many metals, giving otf hydrogen gas which is highly
flammable. lf hydrogen is trapped in a conlined space, it can form an explosive mixture with air. See data
sheet lor hydrogen.
F l a s h P o i d t ( ' n . . . . . . . . . . . . . . . . . . . . . . . . . 1. .8. .5 Flsh PoitrtCD.............................
Non-flammable
F l a m m s b l eL i m i t s . . . . . . . . . . . . . . . . . . . . . . . . . . t' o 1 . 87 . 6 ' l " Flanmble Limits..........................
Non-flammable
A u t o i g n i t i o nT e m p . ( " D . . . . . . . . . . . . . . . 1. 3 1 9 AutoignitionTemp.('F)................Non-tlammable
Extinguishing Agents..................... CO, dry chemical, alcohol loam, water fog Extinguishing4gents.....................
Non-llammable
Special Fire Procedures................Where there is danget ot skin contacl, provide full body protection. Full Sp€cid Fire Prftedures................Keep tank cool with water spray. Since toxic fumes of oxides of phosphorous
respiratory protection should be worn by tire parties at all times. are evolved when phosphoricacid is heated to dsomposition, tire lighters should be provided with
self-containedbreathingapparatus.

Heslth Hsard Ratings Odor Threshold(Dpm) PELAWA {ppm) TLV,/TWA (pDm) Ilealth Hryd Rrtirgr Odor Thrdhold (ppm) PEL,/TWA (ppn) TLVAWA (DpD)
2,3,3 0.047 S/Skin s/Skin 0,3,1 None 1mg/m3 1mg/m3
Generrl-Causes severe burns. Poisonousby skin absorption.Class B porson. Cenerd-Causes burns.
Symptoms-Headache,weakness,ringing of the ears, and irr€gularbrealhing.Skin contacl will cause while Synptom-lrritation ol skin in conlact with liquid; burning ot eyes.
wrinkled,sott skin at site ol conlact. Absorptionthrough skin is rapid and can cause death within 30
minutesafter exoosure. Short Erloure Tolerrnce-Unavailablg
ExposureProcedurc-Vapor-remove victim to fresh air; if breathingstops, apply artificial respiration.Skin or ExposurePruedureskin contacl-remove contaminal€d clothing and flush atfected areas gently with large
eye conlact-remove contaminatedclothing and gently llush aflected areas with water for 15 minutes.Get amounis ot watet. Eye conlact-immediately flush syes gently with watsr; continue to flush lor 'l5 minutes
victim to a hospital or lreatment center as soon as possible.All exposurevictims should get medical Get medical atlentionr
t
attention.

Strbiliry-Stable. Stsbility-Slable over a wide temperaturerangg.
Compstibility-Material: Rubber,aluminumand its alloys, zinc and lead are attacked by phenol. conpttibility-Mrt€risl: Very corrosive to ordinary ferrous metals and alloys particularlyal temperaturesabove
180'F.
C$go: Group 21 of compatibilitychari. Cargo: croup 1 of compatibilitychart.

W€ar rubber gloves, tace shield, protectiveclothing. Have all-purposecanisler mask availablo. Do not p€rmrt Wear rubber gloves, protective clothing. Have body shield available.Avoid contact with liquid. Secure ignition
anyone near spill unless suitablyprotected. sources. Flush spills wilh large amounts of walsr or, il possible, cover contaminatsd surface and spill with
sodium bicarbonate,or a soda ash-slaked lime mixture (50-50).Mix and add water, if necessaryto torm a slurry.
Scoop up 8lurry.Wash site with soda ash golution.
lf r snill acurr. crll the :\raled nrn Cxnlc.. Sllll-,1:A$0a In lhe evelt of r mlior rDill, cdl the Nrtiond ResNtrs Cenrer,8m-42'l-tt02,
ncnrrlr: Normally lrrnaporl({t at 0l(,v,rtr,(lt('nrp€rtturat. Saa ,10CFR 38-Elovttad Tlmpatlturo Lwoeor n.6rh: Ihs informationprovided is tor 100% phosphoricacid.
' Vlpor Proaau.o30 ti mmliq st
?5 C,
l{f SCANNED BY MKP & BARIS A. 2004 14l

PHTHALICANHYDRIDE
(White)
PHOSPHORUS SynoryG 1,2-Benzenedicarborylicacid anhydrid€; ........... 2214
UnitedNrtionsNumber....................
synyn.- Whrte phosphorus;WP; Yellow phosphorus United Nrtions Nunber... l,3.Dioxophalan;1,3-lsob€nzofuandione;
PANi
Phthalandione;Phthalicacid anhvdride
CHRIS Codc.. PAN
Fomlle-QHr(COLO
Fomule-P. Bollln3 Poltrt.. ......... 2A4'C 544"F
ADtqruce-Odo.-White o. colofbar clyststs wlth I
Appernnce-odor-wary, pale-yellowsolid; gadic-like _"c _'F mild odor !'rczlnS Polnt rgfc zaa"r
odot Fr*zing Point............ 44'c 1 1t ' F SDecificCntlry-1.53
SD€cificGrsvity-'l.82 _'c _'F Vrlnr Praurc 20'C (6t'n (mmHd.......... Low
Cholcrl Fully-Acid anhyd.lda
vrpor Prsur€ m'C (6E"D (mnHg).......... -V.-LQ!- Rcld Vrgor Prilu.e (p.h).. -.................. Lof
Ctemicrl Family-Phosphorus V Low
ReidVrpor Prwur€ (psir)........................... Vtlpr Prourc '16'C (f t5'F) (prir)............. Low
Vrpor Prwure,l6"C (lls'D Osis)............. V. Low Pollution ('rictory-USDPA O f I!|() ---Q- vqrD.dlty(Alr 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . . . . .5. .. 1
Pollutiotr Crtegory-USEPA ----L- IMO A VrporDeNfty(Air : 1.0)...........................4'42 Appllc.ble Bdt RcS.a6 ( l,R Srbchrpk'r O solubllltyhw.acr..................... Slioht
Applic8blcBulk Re8.il5 CFR SubchaDter........ O Solubilityln W.tcr......................... Nmlioiblo
FIRT] & EXPI,OSION IIAZARD DATA

FIRE & EXPLOSION HAZARD DATA cnde-E: Combustible
solid El$trlc.l GrouF-O
Electricd GrouD-NA
Generd-Mollen phlhalic rnhydride will burn it igniled and ll! vepo. may lonn m oxplosive mixtur€ with air.
cancrd-Pyrophoric-ignites spontaneouslywhen sxposed to air and burns vigorously.When shipped in bulk,
air is kept away by a water btankei. Burningrel€ases dans€ irrilatingfumes; intense white smoke is formed.
F l u L P o h l ( ' D . . . . . . . . . . . . . . . . . . . . . .3. 0. .4.
Flsh Point ('D.............................
lgnitesspontaneously in air F l m b l c L | m | t r . . . . . . . . . . . . . . . . . .1 . ...7. .l o
. . .1 0 . 4 %
Flmmrble Linits..........................
lgnitesspontaneously in air AutoltnltlorT@D. ('l) ............... 1083
AutoigDitionTenp, ('F)................86 ErttnSulthln8A8cnt!.................. Wet€r tog, CO,, dry ch€micel
Extinguishing EXCLUDEAIR; use water spray,sand,or earth
^8entE..................... S9.chl Flte Pr(rcedr€....... ......,. Wal6r siream mey caus trothing. Steam is an €ttgctive extinguishingagent
Sp€cirlFire Prtredur6................ Use suitable respiratoryprotection.DO NOT use high-pressurewater slream, tor tighting moltsn phthalic anhydrido fires in tanks.
as it may spread molt€n phosphorusover a wider area. Do not use carbon dioxide extinguisher.Try to
smother in tire wilh sand. Wear lull protectiveclolhing.
HEALTH HAZARD DATA

HEALTH HAZARD DATA Hedth Ht4d RrtlnAs Odor Threshold (pDn) PEL,/TWA (ppn) TLV,/TWA (pDn)
Health Hrad Rrtings Odor ltrehold (ppm) PEL,/TWA (ppn) TLV,/TWA (Dpm) 2, 3, 1 Unavailable 1 |
NA, 4, 4 Unavailable 0.1 mg/m3 0.1 mg/m3 Gcnerd-Local irritantto body tissu€s, especiallymoist skin. Vapor irritalingto skin, eyes, nose, throat and
ccnerd-Causes severe burns. Vapor inhalationis very dangerous.Can be absorbed through the skin. upper respiratorytract. Molten material causes severe burns.
synPtomFooughing, sneezing,burning sensationsin nose and throat, increasedmucous secretion; on contact,

SynDtoro-Weakness and unusualsensitivityof eyes to light. Vapor of burning phosphorusis irritatingto nose, phthalic anhydrideis very irritating to wet skin.
throat and lungs. Skin conlact causes burns and ulcers. short ExlErure TolerucF2s mg/m3 in air produced some signs of mucous membraneirrilation with 30 mg/m3
Short ExposureToleruce-Unavailable causing delinite ey€ irritation.
ExDcure PrcedreVapor-remove victim to fresh air; spraying or gargling with water will help relieve nasal
or lhroat irritations;it respiratorydistress or violent coughing occurs, administrationof oxygen is helptul; call
a physician immediately.Skin contact-wash aflected ar€a thoroughly with soap and water; remove
t
ExposurePrcedure-Skin contact-immediately plunge infmted area inlo water or get victim under a
tlood-typs shower and deluge contacied parls. Large amounts ol copper sulfate solulion (10-150/")should contaminatedclothing and launder betore reuse. Eye contacl-tlush eyes thoroughlywilh water and irrigate
be applied.Continuethis tor 3 minules and then try lo wash away the phosphorus particles.Contacl a for 15 minutes or more. Call a Dhvsician.
doctor.
REACTIVITY DATA
REACTIVITY DATA Strbllty-Stable.
Strbility-Phosphorus must be shipped covered wilh water, because on exposure lo air ii ignites
sponlaneously.Reacls vigorouslywith oxidizingagenls. Incompatiblewith dry air.
Conpdblllty-Mrterid: Compatibl€ with most matorialswhen dry; however, when wet, phlhatic anhydride
CoDD.tibiltty-Msterisll forms a solution ol phthalic acid which attacks ordinary iron and mild steel.
Crgo: Group 1 l ol compatibilitychart.

C!r8o: Unassignedin compatibilitychart. For compatibilityassistanca,call
G-MTH-1 (202-267-1 577\.

Woar rubbor glovos, protectiv€ cloihing, targ€ facs 9hi6ld. Avoid contact with lho spilled mrlf,||l C,ov, b'ih
WaJ rubbor gloves, lacs shietd, protective clothing. Body shield and selt-contained breathing apparatus
shold b€ avsilsblo. ll possible, cover spill with soda ash or sodium bicarbonate. Mix, and add water it
ntrolaary lo otlect gmd mixing. Scoop up slurry and wash sit6 with soda ash solution. Secure all ignition
wol send. Spray with waler lo ke€p snd wgt. Scoop into buckots or barol ol water Ahor rlrndlng @dn\Jl'l
reovl J'td roprckag€. Secur€ ignition sourcas. l)urcoa
lt | .Dlll con, 6ll tlc Nrtlonrl R6pon* Center, 8m-42'L8802.
lt. rDlll Krn 6ll rtc \rrlild lrroo. Cril.r. n-|2+Ol. lborr ltr N, 'il'ully trroip{rrod rt stovsted ternpatrtur€s. S€e 46 CFR 36-El€val€d T€mp€ralurs Carg@!
lrlrr
r4t
,a SCANNED BY MKP & BARIS A. 2004
POLYBUTENE POLYMETHYLENE
POLYPHENYLISOCYANATE
Synonyns- PAPI United Nrtions Number..........
Syny> Butene r$ins; Polybutylen€;Polyisobutene; United Ndlou Number................................ t
Polr|obutylone, plastrcs,resins & wil6s
('llRlS Code . . P P I
cHRrscod€ " " PLB
-',
Fonule-C,.H ',,OrNs
Fonulr--€(CHrlOHr -
l l o l l l n 8 P o | n t . . . . . . . . . . . . . . . . . . . . . . . . . .- 232"C -450'F
Bolling po'at.......................... v. Hioh'"
Apperrrncc"Odor-Oark brown liqurd; no appreciabl€ _-"c _"F
Appcruce-(Xor--Colorless, odorless, oily liquid -t'3 -:F
ooor. Frazlni Polnt
Fr@zirspolnr............ Sp€citic Grrvlty-1.2
'15'C _'c - 'F --"c _"F
SDclltc Gnvlty{.8i lo 0.9'l at
Vlpor Pressurr 20 ( (6t'F) (mmllg) V. Low
vrpor Prww 20'c (6s'F) (nnHd.......... iy-!9!d- Chemlcrl F'rmlly-ltocyanatos
Cfcniqt Frn||y-Olelin V. Low
(Irb)........................... Reld Vapor Pressure (lEh)-.,........ ..... V. Low
ReldVtpor Prsw
V. Low V t p o r P r e s s u r e , 1 6( ' ( l l s ' t ' ) ( F i s ) . . . . . . . . . . . V . L o w
Vrpor Prwue,l6'C (115'D (pEis)............. Pollution CrteSory-USEPA - IMO D
Polludor C.teSory-USEPA.- IMO--llL- NP Vrlp.Denlity(Air t . O l . . . . . . . . . . . . . . . . . . . . . . . . .N
. P
VrDorDeBlty (Atr : 1.0)........................... Applicable Brll Reg. 116CFR Subchepter .. O Solubllityinwater................ Reacts
Applieblc Bu|l Re8.,16CFR tubcbrpter........ D Solubilityin wrts......................... Nslioibl€
Grrde-E: Combustibleliquid
Gnde-E: Combustibleliouid f,lectrical Group-NA
Elccdql GUD-NA
Gen€ral-Minor to moderatefire risk due to high tlash point. Somewhat self-extinguishingas CO, asgiven off.
Gcnerd-Mild tirs hazard wh€n oxpG€d to heat or flame.
F l a s hP o i n t( ' n . . . . . . . . . . . . . . . . . . . . . .4. .2. 5. . . .

Flsh Poirt CF).............................
215 to 470 FlamnableLimits.......................... Unavailable
Fbnmble Linits..........................
Unavailabl€ AutoignitionTemp.('F) ................ Unavailable
Autolgritlor Temp.('F) .-.-....-.-. Unavailable ExtinguishirgAgents..................... Confinedarea-CO'; sell-exlinguishing.
Ertlngubhlng Agentc CO2, dry chsmical or foam Sp€cislFire Praedures................Wear protective clothing and respiratoryprotection.Self-extinguishing.Beacts
sDetd Flrc Prcedurs ................water may be ineffectiveon lire. Cml expos€d tanks with wal€r with water to evolve CO, and form solid oolvmer.

Hedth Haard RatinSs Odor Threshold(pDm) PELAWA (ppm) TLVAWA (EDn)
Hqlth Hr4d Rrd{r ()dor Thrdhold (Dpm) PEL,/TWA (DF) TLV,/TwA (pDD)
Unavailable 0.4 Unavailabte O.O1
Unavailabls Nore Not pertinent Not psrtin€nt
General-Will discolor skin lo brown color, reacting slowly and painlesslyil nol promptly removed. Additives
cenenl-Non-toxic. Vapor may ec-taa a simpl€ asphyxiant in high conc€ntration. used are extremely toxic.
Symptoms-Labored breathing,watering ot eyes.

SynDtoDFNon-loxic
short ExposureTolermc€-Animal tests showod inhalationot 2.2 pgm werc fatal to 4 ot 6 rats. No loxic eflects
Shorl Erpqrrc ToleFNon-toxic
were obseryed on skin coniact; eye distress was temporary.LDsowas 10,000 mg/kg.
ExposurePrcedures-Remove victim to fresh air; administeroxygen if breathing is labored. Flush skin with
ErDaw Prcedu6-R€move to fresh air, apply artificial rospiration if ns€ded. water atter removing contaminatedclothing. Wash eye wilh water for at leasl 15 minules. Ingestion-induce
vomiting 3 times, follow with quart of mitk and a mild cathartic.Get medical help.

Stability-Stable. Heal, water, and acids will react to evolve COz.
Strbltity-Stablo.
ComDatibility-Materiali Not corrosive to mild steel, however, aluminum cannot be used.

Conlodbillty-Mdertrh Usual materials ot construclion are suitablo.


Cover spill with watsr spray. Cloanup. Secure all ignition sources. Wear protective clothing and possibly
Wear rubb€t glov€s, taco shield and protoctiveclothing. Socurs ilniuon sourcos.
proteclDn.
nrre t Umvdl.bb
Il I rglll ccu, qll thc Nrdod Ralou Ccntcr, lXl..l2t]-1t02. I L.trtI.
lf I rplll mcuB, crll the Nrtiond Center.800-42i1.tE02.
"1ril,'r0 r,r'lor d ,l'y rn.,rl rrlrrx)sl)l)oro al sltght posittve pressure lO eliminate traces Of moisture
(.(rittdxrratrr! [ trr{prtlrvo
t Unuhn d I lhva{altu
l l I i,r.rrt|fst
/
t45
24
PROPANE iSo.PROPANOLAMINE
Synonyns-Dimethylmethane;
Propylhydride 1978
UnitedNatiorsNumb€r................................ Synonymr-1-Amino-2-propanol;2-Hydroxypropylamine;UnitedNstionsNumber....................
. ...... t
lsopropanolamrne:MIPA; Monoisopropanolamin€
CHRIS Code........... .... PRP C H R I S C o d e. . . . . . . . . . .... MPA
Formula-GHe Fomda-CHTCHOHCH:NHr
"C -44"F B o l l l n 8P o i t r t . . . . . . . . . . . . . . . . . . . . . . . .1. 6 0 " C 320'F
BotlinSPoint........... 'C
App€$arce-odor-Colorless gas or liquid; natural-gas | ,lpperrance-Odor--Colorlesstiquid:llight
- immoniacal - _'F
187:3 -*-"F ooor !.rcezln8poinr......... -'c ga'r
odor Freezin8Potrt......... I
r SDeclficcrrrity-0.96 _"C _"F
SpeclncGnvity-o.53 (liquid) _"c _'F
vrpor Presure 20"C (68"D (nnHg).......... --0999- cteni c.|Fr ni |y_Am i neVtlnrP reuure20.c(68.F)(mmHg)' .' .' ..' .0.51
Ctemicd Fmily-Saturated hydrocarbon Rcid VoporPresure(Dcia)......... ................. 190
Vrpor Prwure ,16'C(115'D (psi8).............224
1.55
I -Pollutlon
. . Crtclory-USHPA--... - lMO. C V|Irr Denrtty(Alr : f.0).............. .......... 2.59
PollutionCrteSory-USEPA- IMO ---gas- VrDorDensity(Air : 1.0)........................... I
I Appllc.blcBoll Rcg.46 ( I,R Subch.Dler O Solubilty In lryrter........................ Comolete
ADDlicableBulk Reg.it5 CFR Subchepter
........---Q-9- Sotubilityin wrter........................ Neolioible
Grrde-Liquefied Flammabls Gas (LFG) Grede-E: Combustiblellouid
ElectricslGrouD-D Eletrlcd Croup-D
-Unless ths flow ol gas can bs slopped, ox$ngulshlng a propane ffr€ will pormil tho accumulallon ot an Generd-lrrilalrng vapora given ofl when heatsd. Mod€rrte lifo hazard when exposed to heat or flame: can
explosiveconcentrationol vapor, and subSequenl€xplosion ot rotlash. react wilh oxidizingmaterials.
lass than -64

Flsh Point ('n............................. F l u h P o l n iC F ) . . . . . . . . . . . . . . . . . . . . .1. 6. .5.
2.2 lo 9.5"/"
FlrmmrbleUnits.......................... Flmnrbfc Lfnitr...................... . 2.2 lo 12ch(approximat6)
ArtoiSnitlonTenD. ('D................842 AutolSrltlonTmp. ('n.............. 706 (estimatod)
ExtinguirbhSAg€Dts Stop llow of gas; COr, dry chemical,water fog Extln8ubhinS Agcnts.............. Ory chamical,w!t6r spray,alcoholfoam, or carbondioxide
Fire Prcedurc................ Tanks exposed lo lire should be kept cool wilh a continuous spray ol waler Specirl Fire hccdures............ Weat goggloa, t€lt-conlainsd breaihing apparatus and protective clolhing.

Heslth Haed Rrtings Odor Thr6bold (pDm) PEL/TWA (Dpn) TLv,/TwA (ppn) Hedth Hrud RstltrSs Odor Thresbold (ppm) PEL,/TWA (Dpn) TLV,/TWA (ppn)
0. 0. 0 5,000 io 20.000' 1000 Unavailable 1, 2, 1 Unavailabte Unavailable Unavailable
Generol-Liquid causes lrostbile on skin contact. Cold vapor causes skin damage. Inhalationcan lead to G€nerd-Single short exposure to skin may cause considerableirritation.Liquid expected to burn eyes.
asphyxiation. Inhalationcauses very slight respiratoryirritation.
SymptoN-Headache, dizziness,drowsiness.Contact wiih the liquidwill cause frostbile. SymDtoms-Nose and throat irritation.
short ExDosureTolerance-A vapor concentrationol 10,000 ppm tor briel periods has bsgn reported as Sbort Exluue TolemcFunavailable.
producingno symptoms.
ExposurePrcedures-Bemove victim to fresh air. Give artificialrespirationil brsathing stops. Get medical Expcure Prcedures-ln case ol skin coniact, wash well with soap and water. For eye contact, Washwilh targe
attention. lf liquid has spilled onto the skin, points ol contact may be troslbitten; handle gently and protect amounts of water.
from mechanicaldamage. DO NOT RUB. Get medical attention. 'NOTE: Exposureto polentiallydangerous
vapor concentrationscan occur before the product can be detected by smell.

Strbility-Stable. Strbility-Stable; torms soaps with organic acids.
CrnFdbtlity-Mrterld: Usual materials ol conslruction are suitable. comD.tlblllty-Material: Will remove paint, swells rubber; recommend type 304 stainl€ss steel clad tanks.
Cargor Group 31 ol compatibilitychart. Cs8o: Group 8 ol compatibilitychart.

wsar rubber glov$, tacc lhlold, protective clothing. Have all-purpos€ canistor malk avallablc S€curo dl Avold contrcl wllh liouid
sorrrcaa ol ignltlon and call lhe lire departmsnt. Ths gpilled liquid will boil away npidly, leavlng no
It I llll ,rcurr. call lL \rtkrn.l niDu C.nter. &X}{2&ttlt2. rcrr, (tll thc Nrdod l4ou Cenrer, 8fiL4,|-6tll2.
It|r kf,l. I lJ.trqr.rd
l .
tt -l
_
1.6
PROPANOLAMINE (NOTE: Thls cargo l! currently not permitt.d to be 3hlpped in bulk in U.S. waters)
beta-PROPIOLACTONE
Synonyms-3-Amino-1-propanol;3-Hydroxypropylamine; UnitedNstionsNumber....................
3-Propanolamine:
l-Propanol.3-amino- Synonyms- Hydracrylic acid, b€ta-lactone; United Nrtions Number....-... f
2-Oxetanono; Propanolid€; bsta-propionolaclone
CHRIS Code........... .... PLA

CHRIS Code......................... PLT
Fonuh-CaHsNO
BoilingPoint.......................... 168'C 334'F Fomule-OCHTCHTCO
Apporance-Odor-Light yellow lo colorlessliquid;tishy Eollln8 Point......................... 15 5 ' C 3 11 ' F
ooor FreeziDg
Point......... 12'c la-'p ApDorrnce-ONolorless liquid; irritrting odor
SpecificGravity-O.982 _'c _'F F r e e z i n 8P o 1 n 4 . . . . . . . . . . . . . . . . . . . - . . . ,g3'c -zg'p
Sp€cltic Gr.vlay-1.15
'c 'F
valDr Piessure20'C (68"F)(mmHO.......... 2.1
Chemisl Fsmily-Amino-alcohol ReidVaporPressure (psis)......... Vrlnr Prruurc 20'C (6E'l) (hnHd.......... -lL!Q!!-
VrlDr Presure45'C (lt5'n (psia)............. l Cltenlcrl Frmlly-Kelonat (Drie).
Rcld Vrpor Prffure
Pollution Cstegory-USEPA - IMO C VrporDensity(Air : 1.0)........................... 2.59 Vltor Pr*ure {6'C (f l5"t') (pcia)............. 017
ADplicsbleBulk Reg.45 CFR SubchrDter........ O S o l u b i l i t y i n W r t e r . . . . . . . . . . . . . . . . . . . . . .S
. .o. l u b l e Pollutlotr CrteSory-USllPA - tVO ---9- VttDrDenslty(Air t . 0 1 . . . . . . . . . . . . . . . . . . . . . . . . .2. . 5
ADpllcrble BulL Reg,46 (:l'R Sub.h.Dtrr Solubilityin wster............. .. Soluble

GndeE: Combustible liquid FIRE & EXPLOSION HAZARD DATA
Eletrical GrouF-NA Combustibleliouid
Elcctrlcd CrouFNot applicable
cfrerd-Modsrate tire hazard when exposod to h6at or flame.
conlainers may explode in fir€. Vapors ol unburned material are very toxic.
F l s h P o i n t ( ' F ) . . . . . . . . . . . . . . . . . . . . . . . .1. .7. 5

..
Flsmmable Limlts.......................... Unavailablg 165 (cc)
FlGh Point CD.............................
Autoignition Tenp. ('F) ................Unavailable Flmmable Limits..........................
LEL:2.9"/" UEL-unavailable
Extin8uishing A8ents.........,........... Alcohol foam, dry powdet, COr AutoignitionTemp.('F) ................
Unavailable
Speci.l Fire Prcedur6................ Water may b6 inelt€ctive on firo. ExtinSuishing
ishingA8ents.....................
Water,dry chemical,foam, CO
C(
Fire Pr@edur6................Wear self-conlain€dbreathingapparatus, full protectiveclothang,rubb€r
gloves to prevenl all contact with liquid. Cool exposed tanks wiih water.
HEALTH HAZARD DATA

Health Hrud RstitrSs Odor Threshold(Dpm) PEL,/TWA (ppn) TLV,/TIVA (ppm) HEALTH HAZARD DATA
1, 1, 1 Unavailable Unavailable Unavailable Health Heed Rstings Odor Threshold (ppn) PEL,/TIVA (ppn) TLV,/TWA (ppm)
G€ner8l-Moderalely irritatingio skin and eyes. 3, 3,4 Unavailable 29 CFR 1910.1013 0.5
errl-Suspected carcinogen.Vapor moderatelyirritating.Liquid is a fairly severe skin irritant.Poison. Gel
medical attention after all exDosuresto this comoound.
Symptoms-lrritationot mucous membranesand respiratorytract. Severe exposure re$lls in blisters and burns
symptorlnhalation-irritation of nose, throat and respiratorytract. Liquid causes eys irritationand tears. Skin
Short Exlosure Toleruce-Unavailable contact resulls in arritationand blislering. Ingestion-mouth and stomach burns.
ExposureTolmce-Unavailable
Expcure PruedureRemove victim to frosh air. Give artiticialrespirationor oxygen as necessary.Flush eyes
and skin well wilh water. Bemove conlaminatedclothing. Wash oul mouth with water if ingested. Exposue Preedures-lnhalation-move victim to fresh air. Give artificial respiiation or oxygen as necessary.
Eyes-flush with water lor 15 minutes. Skin-flush with water. Fluid trom blisteF will cause additional
blisters. Ingestion-give large amounts of water, induce vomiting.
REACIIVITY DATA
Strbility-Stable. REACTIVITY DATA
but at elevated lemperatures can polymerize.
Conpstibility-Mrterid: Copper and copper alloys are readily corroded.

lompatibility-Material:
Crrgo: Group 8 ot compatibilitychart

Csrgo: Group 18 ol compatibilitychart.

W€ar $ll-conlained breathing apparatus and rubber gloves. Absorb matsrial on vsrmiculit€, swaap up, mrt SPILL OR LEAK PROCEDURE
wilh dry caustic, wrap in pap€r and burn in an incineralor.Wash sDillsit€. wou lull protoctivo clothing. Avoid any contacl whatsoevor. Wear self-contained broathing apparatus and
otrlsf gloraa. Olrpa.|€ end llurh largs spills.
ll . rDlll Gu, 6ll ahc Nrtlond R6oou C€Dtcr. 80ca2/a-ttlr2.

It r rrlll qrun, cll r|. Nrdql
lryb: t Un.ydlrblo
' lA
I Un0.lgned lryh, .hlp.n nt no,l ,fillatti,
r trrard.lb
I tlrql..l
2ar
.ra9
Synonyms- Methyl ac€taldehyde; Propanal; Propionic
aldehyde; Propyl aldehyde; Propylic aldehyde
PROPIONALDEHYDE
l l Synonyms- EthanA carborylic acid; Ethylformicacid;
Methacetonicacid; Meihylac€ticacid; Propanoic
PROPIONICACID
United Nrtlons Number................................1848
acid
Fornula-C:HsCHO
il Formuh-CH:CH:COOH
CHRIS Code................ ..............P
. NA
Boillng Point .. 47'C 117'F B o l l l n gP o | n t . . . . . . . . . . . . . . . . . . . . . . . .1. 4 1 ' C 286'F

App€arance-Odor-Colorless liquid wilh sutfocating and --zrc Alrpcmce-Odor-Clear, colorb$ lhuid; pung€nl odof
fruity odor Frezing Point -ttz"r FreerfngPofnt......... ..... x'3 ='F
Specific Gravity-O.80 _'c _'F Sp€cificGrrvlty-o.995 _'c _'F
Valor Presure 20'C (6s'F) (nnHg).......... 258 Vrpor Prwure 20'C (6E'D (nnHO.......... ---?l-
Chemicsl Fmily-Aldehyde R€idVrDorPrsre (psis)........................... 67 Chenicd Frmlly-Organic acld ReldvrporPresur€(!sis)....................0 . ...2. . . .
Valor Prwure 45"C(115'F)(p6ir)............. 14 VeporPrwure 46'C (1f5"F)(Ddir)............. 0'3
Pollulion Crtegory-USEPA - IMO O Vslor De!8ity(Air : 1.0)........................... 2.0 Pollutlo qiesory-USDIPA D lM() , D Vfpo. Dentfty(Air : 1.0).................... ...... 2.56
Appllcrble Bulk Reg. 46 CFR Subchepter........ O S o l u b i l i t y i n W a t e r . . . . . . . . . . . . . . . . . . . . . . .2. .2 h Appllcrblc Bult Rcg.46 (:l'n Subhpler O S o l u b t l l t y l n W . t € r . . . . . . . . . . . . . . . . . . . . .C
. .o. .m o l e l e
FIRE & EXPLOSION HAZARD DATA TI'IRE& EXPI,OSION HAZARD DATA

Flammableliquid crrde-D: Combu8tlbL liquid
Electricsl Greup-C Eletrlcd GrouD-D
lire haard du€ to low llash point. Flashbackalong vapor trail may occur. Vapor may €xplode Cilol-lgnil9d by heal and op€n llame.
if ignited in an enclosed area. Reacts vigorouslywilh oxidizers.
F l s h P o i n tC n . . . . . . . . . . . . . . . . . . . . . .1. 5
. .t.o. . 1
.9 F L r i P o l n t ( ' l ) . . . . . . . . . . . . . . . . . . . . . . . . .1. .4 0
FfmmableLimits.......................... 2.9 to 176h Flumblc L i D l t s . . . . . . . . . . . . . . . . . .. . . 2 . 9 t o
'14.8",6
AutoigDition Tenp. ('F)................ 405 AulolSnltlon Tcmp. ('l)............ 955
Ertinguishing A9ents..................... Carbondioxide,dry ch€micaland alcoholtoam. Ertlngulrhlng Agentr.............. Alcohol foem, water gpray, CO", dry chemical
Fire Procedures................ Ke6p tanks cool with wat€r spray. Providefire fightsrs with self-contained Speci.l l'lre Prrredurer. . .... . Provid€ frre lightars with goggleg, Solt-contain€d breathing apparalus and
breathingapparatusand protectiveclothing. Fire may be ditlicult to control due to ease with which vapor is protaclive clothing.
re-ignited.Water may be inettectiveon fire.

Health Hs4d Ratings Odor Thr6hold (ppm) PELAWA (ppm) TLVITWA (ppn) Hellh Hurd RrdrSr Odor Thr6hold (Dpn) PEL,/TWA (pDm) TLV,/TWA (ppn)
2, 1,2 1 Unavailable Unavailable 2.3,2 Unavailable 10 10
-Liquid irritatingto skin and causes eye injury.Vapor inhalationdangsrous. G€ncrd-Vapor extr€melyirritating.Liquid causes severe burns.
SymDtoms-Dizziness,drowsiness. Synptoro-Cau$s burns on the skin, particularlymucous membranes (mouth, nose) and eyes.
Short Exlbsure Tolerance-8,oo0 ppm Short ErD6ure TolerilcFunavailable.
EIDGU€ Prcedurer-Skin contact should be thoroughlywashed otf with soap and water. In case ol liquid Erpque Prcedures-Vapor-remov€ viclim to lresh air; if brealhing stops, apply artilicial respiration.Skin or
contact ol the eyss, tlush eyes with water for al least 15 minules then obtain medical treatment. eye conlact-remove contaminaledclothing and genlly flush altecied areas with waler lor 15 minutes. Gel
medical attention.

Stability-Highly reactive. Normallystored under nitrogen blanket. Reacts vigorouslywith oxidizers. Strbllty-Stabl€. When heated, emits acrid fumes.
Comprtibility-Mrterial: Either stainlesssleel or aluminumare suitable materials.Tanks mav bg coaled with Corftrttbtllty-Mrtcrld: Corosiv€.
ohenolic resin.
Crrgo: Group 19 ot compatibilitychart. Crrgo: Group 4 ot compatibilitycharl.

W€ar rubber gloves, seltcontained breathing apparatus,protective clothing. Avoid contacl with liqud Setl,o Wosr rubbor glovgs, tace shi€ld, protgctive clolhing. Body shield and self-contained breathing apparatus
ignilion sources. ll possibl€, cover with sodium bisullite (NaHSG). Add small amount ol water rtrd fllx Scoog \ltrxrl(t bo Rvarlable.AvoE contact wilh liquid. Secure ignition sources. ll possible, cover spill wiih soda ash or
up. Wash sit€ with saD solution. l,xttrrrn tttr:rirtnnalo Mix rnd add water it necsagaryto sllsct good mixing, scoop up slurry and wash site with
lrxh [h mlulpn
lf r rplll cctn, cdl rhc Nrtloul naFu Ccntcr, ll . {lll Grn, c.ll th. N.alonrl RBpon* C'enter, t00-424-8t02,
L.rtf fr-
tJl
PROPIONITRILE
PROPIONICANHYDRIDE
Synonymr- Cyenoethane;Eihsr cyanatus;Ethyl . ...,.,.,, 2404
UnitedNrtionsNumber....................
Synonyms- Methylaceticanhydride;Propanoicacid 2496
UnitedNationsNunber................................ cyanido; Hydrocyanicether; Propanenitrile;
anhydrid€;Propanoicanhydride;Propionyloxide Propionicnitrile
CHRIS Code........... .. PCN

CHRI5 code........... .... PAH
Formule-GHrN
Fornuh-(CHrCHzCOlzO Boiling Point.......................... 97"C 2O7"F
BoilinSPoitrt.......................... 169'C 336'F ADDormce-odor-Brown liquid;pungent odor -gz'3
Appcmce-Odor-Colorless liquid;pung€nt odor _'c _'F Frezinspoint......... .... l*'F
FrezinS Point ..... 45'C -49'F "c 'F
SpecltlcCnrlty-0.7E
SDecificGrsvity-l.01 _'c _'F
VrDor Prgaure 20'C (6S'F) (mmHg)..........--3.9--
Vrpor Prsure 20'C (6t'n (mmHd . ....... 1.0 (1|€nlol Fully-Nltril63 . .......,... 1.6
ReldVsDorPresure (psir)............
C:henicalFmily-Organic acid Reid Vepor Prsure (psi.,. . . Low VrDor Pisure 46'C (115'F) (psia).............
---?l-
VaporPreuure46'C (ll5'n (Dsir)............. Low Polludon6cpry-l1st:PA -,- tMO - C 1.4
V$or DeEity (Air : 1,0)...........................
PollutiorCrte8ory-USEPA.--Q-- IMO- C v r p o . D c n s i t y ( A l r= 1 . 0 ) . . . . . . . . . . . . . . . . . , . . .4. .. 4
, .9. . Appllcblc Bdl Rcr. a6 (:l'n Subch.Dt.r. O Solublllty in lilater....... Soluble
ADDlicsbleBulk Reg ,15CFR Subchrpter........
----Q- S o l u b l l l ai ny w r t G ! . . . . . . . . . . . . . . . . . . . . . . .
I.'IREiI EXPI.,OSI0N HAZARD DATA

FIRE & EXPLOSION HAZARD DATA Grr&-C: Flammabls liouid
urto€-E: Comb$tible
wm0u5! liquid Elcc.lrlql GrouD-D
Electrical Greup-D
cemrd-Produces toxic gata! ol hydrogen cyanide, nitrogen oxkjes, and carbon monoxidewhen heated or
tire haard when 6xpo9€dto heat or tlame: mor€ ot a h€alth huard than a fir€ or stability near ooon flam€.
heard.
F | [ h P o l t r (l ' l ' ) . . . . . . . . . . . . . . . . . . . . .5. .4. . .
F l B h P o l n t ( ' F ) . . . . . . . . . . . . . . . . . . . . . . . . . .1 6 5 F h m n r b l eL l n l a r . . . . . . . . . . . . . . . . . . 3 . .. 1 t o 1 4 . 0 " / "
F h m m r b l e L i n t t r . . . . . . . . . . . . . . . . . . . . . .1 . ...4. 8 t o ' l l . 9 o l o Autol8nltlon TcmD.("1) ............Unavailabla
Autoignition T€mD, ('F)................ 600 ErthSulshlnS A8cnt.. ... .... Alcoholfoam. dry ch€mical,CO:
Eriinguishing Carbondioxideor dry chemical
A8enb..................... Specirl Ftrc Precdurer.... . . ..... Cool sxposod tanks with water. Wear sell-conlgined breathingapparatus and
DO NOT USE WATERas extinguishing
Sp€cislFire Prcedurd................ media;propionicanhydridereacts full proteclive clothing includingboots.
slowly with water to form propionicacid-reaction rate increaseswith temperature
HEALTH HAZARD DATA

HEALTH HAZARD DATA Hedth Hsed RatirSs Odor Thrghold (ppm) PEL,/TWA (Dpr) TLV,/TWA (ppn)
Health Hrard Rstirgs Odor Thr6hold (ppm) PEI-ITWA (ppn) TLVITWA (pDm) 3.2.3 Unavailable Unavailable Unavailable
3.2. 1 Unavailable Unavailable Unavailable
G€nenl-May be fatal il absorbed through skin. Liquid causes burns.
'Vaporsirritatingwhen inhaled. Liquid irritatingto skin on contact. May produce sensitizationettects.
nausea, rapid pulse, respiratorydistress,cyanosis,coma- May be latal if inhal€d,

Symptoms-Respiratoryirritation,skin irritation. swallowedor absorbed through skin.
ExposureTolemnce-LD"" for rats in a 4 hour period was less than 1,6 gm/l
Short ExposureTolersrce-Unavailablo
ExDorurePr@edur6-Antidote is amyl nitrite. Always have a cyanide kit at hand. Remove to fresh air.
ExposurePr@edures-Vapor-remove victime to tresh air; apply artiticialrespirationif breathing stops. Skin ol Adminisierartiticial respirationor oxygen as necessary.
eye coniact-remove contaminatedclothing and gently flush aftected areas with water. Get medical
atiention if discomlort persists.
See Medical Kit Inlormation,Appendix B
REACTIVITY DATA
REACTIVITY DATA Sbbility-Stable. Incompatiblewilh strong acids and alkalies.
Strbility-Decomposes on contacl with water. Can react with oxidizingmaterials.
ConDrtlbtlity-Materid:
ComDotibtllg-Mrterirl Noncorrosiveto aluminumor stainlesssteel.

Cutor Group 1 l ot compatibilitychart.

SPII,L OR LEAK PROCEDURE
Koop poopk) away Secwe 8ources of ignition. Shui otf leak il without risk. Siay upwind. W€ar sell-contained
ll|va dl4onldn d b..alhlne rpprratua available. Avoid contBct with liguid. S€cure ignilion louroat. brerllrt\t npparahrs and lull proteclive clothing including boots. For large spills, dike and pump into salvage
Lnlr lrr(r wrlor ipray lo knGk down vapors Prevent run oft lo sowers.
lf I ulll ,x rurr, (rll thc Nrtkrnrl Romtre Center. 8fi)-424-8t02.

lt a lall E.rn, ..ll tL it.tlon.l nate. (!nlr. G2.-00r.
llrrryh
' lloar
ll...rl. lr rrllr rale k, krrr' tr'{rxrx {r {l
]JJ
Iil
iso-PROPYL
ACETATE N-PROPYLACETATE
12?3 Synonyms-Acelicacid, n-propyl6sler; Propylecelate '1276
synoyn!-Acetic acid,isopropylest€r;lsopropyl UnitedNrtionsNunber............................... UnitedNstionsNumber.........._....................
acetale; lsopropyl ester of acetic acid; 2-Propyl
acetat€; sec-Propylacetate
II CHRIS Code................. PAT
Formulo-CHTCOOCH(CHs)z Fornuh-CHTCOOGHT
90"C 194"F 'C
BoiIingPoirt...................... Boilin8 Point........... 215'F
Appeuance-Odor-Colorlessliquid;pl€asant,fruity odor -'C -'F Ap!.mcc-Odc-Colorleas liqurd; pleasani, lruity odor _'C _'F
Frezin8Point.................... -73'C -99'F Frezlng Point........................ -92'C - 134"F
SpecificCravity-0.88 -'C -'F Sgelllc Grrvlty-O.87
T
Vapor Pressure20"C r68'F) ,.."r, -.
Frmiry-Esrer
ch€micrr .'. z.o
Hili,ffil"#;:..$"? 1'1"-?-.:.:.: Chemlc.l !'rnlly-Estel
R e i d V a p o r P r e s s u r e ( p s i r ) . . . . . . . . . . . . . . . . . .1. . .3. . . . . .
Vapor Prsue {6'C (1f5'D (psia).............--Xl-
PollutionCstegory-USEPA- IMO -M- 3.52
VaporDemity (Air : 1.0)........................... po'u.ron
('rresory-r.rsh'A
-- rMo o -1%-
J:# 3:""'"",",;",ff;":tt1t,".1::l].:.:::..::...
Applicable ........ D
Bulk Re8.it6 CFR Subcbapter ..
Solubilityin \ryrter................... Moderate Apglic.ble Bull Rer. 46 Ct'n Subchrpter ..... . D Solubility in 1ryater......................
. Slioht
FIRE & EXPLOSION HAZARD DATA ITIRE & EXPLOSION HAZARD DATA
Grade-C: Flammableliouid Gndc-C: Flrmmable liouid
Electricrl Group-D Elctrlcrl (;rouFo
cenenl-Dangerous. Keep away from heat and open flame. Flashbackalong vapor trail may occur. VapoI may Generrl-Dangerous, when exposed to heet or ftam€
explode il igniled in an enclosed area.
F l s b P o i n tC D . . . . . . . . . . . . . . . . . . . . .6. .0. . . . . . Fluh Polnt ('l') .................... 7O

FfsnnableLimits.......................... 1.8 lo 7.8o/o FlMnrble l,imlt!................ 1 7 to 8.0%
Autoignition Tenp. ('F)................ 860 AulolSrition Temp. ('l) ........ A42
ExtinguishinS Agents..................... COr, dry chemical,alcoholtoam,water log Ertlnguishin8 A8.nts COl, dry chemical, alcohol loam, water log
sDecialFire Prcedurcs................Use ol dry chemical where it can get into a tank ol isopropyl acetate is nol SDecid lire Prccdurcs . .... . . Use of dry chemical where it can get into a tank of propyl acetaie is not
recommended.Fires involvingspills oulside oi tanks can be slitinguishedwilh dry chemical. recommended. Fires involving spills outside ot tanks can be extinguished wilh dry chemical. Water may be
inetfectiv€ on fir€.

Heslth H@rd Rstings Od,orThreshold (ppm) PEL,/TwA (Dpm) TLVAWA (ppn) Herlth H|ed Rriin8s Odor Thr6bold (ppm) PEL,/TlryA (pDn) TLV,/TWA (ppn)
1.1.2 100 250 250 1, 'l, 2 Unavailable 20O 200
cercrd-Vapors harmlul, Gencrd-Liquid causes slighi initation on contact. Vapor inhalationresults in irritationof mucous membranes
with modelate systemic eftect.
and drowsiness. SymDtoms-Sleepiness,latigu€, and retarded respirationrate.
Short ExposureTolemrunavailable Expcure Tolerance-Unavailable
ExposurePrcedurc-Vapor-remove victim lo lresh air; if breathingstops, apply artiticial respiralion.Skin or ExposurePraedures-Vapor-remove victim to tresh air; if br€alhing stops, apply artiticialrespiration.Skin or
eye contacl-remove contaminatedclothing and gently tlush atfected areas with water lor 15 minutes.Got eye conlact-remove contaminaled clothing and gently llush affected areas wilh water for 15 minutes. Get
medical advice or attention. medical advica or attention.
REACNIVITY DATA REACTIVITY DATA

Strbilify-Hydrolyzes (r€acts wilh water) on standingto form acetic acid and isopropyl alcohol. The pressnc€ ol strbility-Hydrolyzes (reacts with wate4 on standing to form acetic acid and n-propytalcohol. The presence of
bases (alkalis)speeds up the reaction.Reacts vigorouslywith oxidizingagents. bases (alkalis) speeds up th€ reaction. Reacts vigorouslywith oxidizingagents.
Compstibility-Mrterirl: Softens or dissolvesmany plastics. Softens or dissolves many plastics.
Cargo: Group 34 ot compatibilitycharl. Cr.go: Group 34 ot compatibilitychart.
SPII-L OR LEAK PROCEDURE. SPILL OR LEAK PROCEDURE

Weaf rubb€r glovos, laco shlold, proteclive clothlng. Hrve all.pupora canistgr mark avrllable. Avoid conlr, I wort tubbor glove!. laco shEld, prolstivo clothing. Hav€ all.purposs canister mask available.Avoid contact
with liquid. S€curo lgnilion lourcar, h lqxl S..cu,r enlllon a€f,rces Small spills may ba washsd away wilh waler.
lf r rolll rxcgr, (rll rb. \rtlcd l.oa.a (td3r. Gata-ln . It r rplll .x r u'r, .rll iL N.llon.l ncrbn* ('enter, tU)-424-EE02.
l..mrrh ' Vspo. Prraauo ae mf |0 al I t'C, fiiti ' Yfn trtnr. m |m)to d 2t l.C
SCANNED BY MKP & BARIS A. 2004 lrr

iso-PROPYLALCOHOL N.PROPYLALCOHOL
'1219 SynonynFAlcohol C-3: Ethylcarbinol;Propanot;
Synonyms-Alcohoi C-3; Dimethylcarbinol:IPA: Urited Nrtions Numbel UnttcdNralodsNumb€r ........ 1274
lsopropanolilsopropyl alcoholi Petrohol: - l-Propanot; n-propanot:propyl alcohot; propyl
I
2-Propanol;sec-Propylalcohol; Rubbingalcohol alcohot normat; Propytrcalcohol
I
I
('llRIs Codc ........ PAL
Fornulr-(CH:hCHOH Fon!h-C,H,OH
'C
Boiling Point........... 182'F BolllnS Polni 97"C 207"F
'c 'F
Appemce-Odor-Colorless liquid; sharp, somewhat --gs'3 Appe.rrncc-(Xor-Colorless liquid: elcohol-liko odor
unDleasantodor FreezinsPoint.........
. - *t'F lrczfng Polnl.... -127"C 197"F
SpeciflcGravity-0.79 _'c _'F SDecltic (;r.vliy-0.80 _'c _'F
20'C(68'D (mnHg)..........
Vlpor Pressure ---33-
C'hemicslFmily-Alcohol Reid Vapor Presure (Nia).........
clrcnrcrr
lrnry-Arcorrqr l:f'":Fffi"1;: l$,"]]il'", 03?
... Vrpor Prsue,l6'C (lls'F) (Dci.)............. 3.0 ... V e y r r l ' r r u u r c 4 6 ' ( ( l l s ' n ( t 6 i r ) . . . . . . .. . . . 1 , 2
Pollution CrteSory-USEPA - IMO --J!!.- Vrpor Density(Air : 1.0)...........................2.O7 PollutlonCracSory-llsl:PA.- lM()- lll V.por l)enstty(Air 1.0)........................... __2!Z_
AlplicableBulk Reg il6 CFR Sub.haDter........ D Solubitityin water ......................... Comolele Appllcrbl. Bull Rat. il6 ('1.'RSubchrptcr D solublllty in wsrcr .. Comolete
FIRE & EXPLOSION HAZARD DATA T'IRE I} ]]XPLOSTONHAZARD DATA

Grsde-C: Flammableliquid (lredc-O Combustrble lqurd
ElectricalGrouD-D l:lslrlcrl (;roup-D
Gener8l-Dangerous.Keep away from hsat and open flame. Flashbackalong vapor trail may occur. Vapor may (;enenl-Dangeroug, when €xposed to h6at or tlama.
explode it ignited in an €nclosed area.
F l a s bP o i n t( ' I r ) . . . . . . . . . . . . . . . . . . . . 5. .3. . . . . . . Flsh Polnl ('l') . . . . . . . . . . . . . . . . . . . . .8. 5

.
l'lsmmsbl€Limits.......................... 2.Oto 12.O'/" llenmrblc l-lmits ................. 2.0 to 13.5%
AutoigDitiotr Temp.('F)................ 750 Auaolgnlllon TcmD. ('n . ......... 700
ExtitrguishltrgAgctrts COr, dry chemical,alcohol foam, water fog Flxtln8tlshlng A8ctrts. ................ COz, dry chemical, alcohol loam, water tog
SpecislFire Pr@edur6................Cool lank wilh water spray. Water may be ineltective on lire. Sp€chl Flre Prcedures................ Waler may be inettective on fire. Cool exposed tanks with water.

Hedth Haed Rrtings Odor Threshold (ppm) PEL,zTlilA (ppnD TLV,/TWA (Dpn) Ile.lth H@rd Ratings Odor Threshold(ppm) PEL,/TWA (pDn) TLV,/TWA (ppm)
'1,o,2 400 1, o,2 Unavailable 2OO 200/skin
20o {Q0
Generd-Acts as a local irritant and in high concentrationsas a narcotic. Prolongedor rsp€ated skin contact Cenerrl-Vapor inhalationcauses slight irritationof mucous membraneswith moderate narcotic etlect resulling
may cause detatting ot the skin and may produce dermatitistrom daily contact. Severely irritatingto th€ in dizziness,drowsiness.
eyes and may cause eye jnjury if not removed promptly.
Symptoms-Dizzines and sleepiness;eyes, nose, and throat irritation. Symptoms-Salivation,retching,vomiting.
ExposureToleruce-4oo ppm lor 30 minutes. Short Expsure Toleruce-4oo ppm to 30 minutes.
ExDosu€Prcedlr6-Vapor-remove victim to fresh air. Apply artificialrespirationil needed. Eye Expeure Prcedures-Vapor-remove victim to frosh air. Apply artificial respiralion if needed. Eyo
contact-wash eyes gently lor 15 minutes with lresh water. Get medical attention tor eye conlact.
I contacl-wash eyes gently tor 15 minutes with water.

Strbility-Stable Strbillty-Stable.
-Mrlerid: Aluminum,especiallyai el€vatsd t€mperaturesis unsuitablo. ComD.ttblltty-Mrteri8l: Usual malerials ot constructionare suitable.
CrrSo: Group 20 ol compatibilitychart. See also App€ndix l-€xceptions to the Chart. Crrgo: Group 20 ol compatibilitychart. See also Appendix l-Exceptions to the Chart.
SPII,I,OR I,EAK PROCEDURE SPILL OR LEAK PROCEDURE

\ryarr rubbar glova! l|ca rhhld. prot(rctrvaclothrng.Hav6 all-purposgcar{lter maal avalLblc. Avoid contr(it Wear rubb€r glovss, laco shi€ld, protective clothing. Have all-purpose canister mask available.Avoid contact
wilh llqurd S*uro rgnrttonrcurcor wrlh |qurd SecureignilionEourc€s.
lr a il a. n|| rt \.il@l lqr. (-rtr, m{t+tmt. ll r rglll xcro, cdl tbr Nrtlqd loooc C€nter. E0-424-8802.
'Valxt
Itdl llcrl. l"orrtxo t(r rrrrll! trl l4 / (
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l l
SCANNED BY MKP & BARIS A. 2004 ,rt

PROPYLAMINE
iSo.PROPYLAMINE
Synonyms- 1-Aminopropane;Monopropylamine;
1221 'l-Propanamine;
Synonyms-2-Aminopropane;lsopropylamine; United Nrtions Number. n-Propylamine;mono-n-Propylamin€
Monoisopropylamine;2-Propanamine
CHRIS Code.................. IPP

Fornuh-CHg(CHz),NHr
Fornula-(CHs):CHNHT
BoilinsPoint.......................... 32:9 ,0.: Apprcerance-Odor-Colorlsss
liquid wilh a pung€nt _'c _'F
Appearance-odor-Colorlessliquid;pungenl, irritating, -gs"c ammonracalodor when concsntration is high l'rezlnS Polni ..... -82'C -116'F
FreezirgPoint......... -rgg'p Spctflc Gravlty-O.72 'c 't
typical amine odor
SpecificCrrvity-o.69 -'c -'F Vrpor Proure 20'c (5t'F) ,r."O ,50
t apor Prwure 20'C (68"F)(mmH$ ........,.---l- Ctcnlcd Fully-Aminc R e l d V r p r P r d u r € ( p 8 h ) . . . . . . . . . . . . . . . . . . .1. .0. . 4
ChemicalFsmily-Amine ReidV.por Pr*ur€ 18.2
(psi8)........................,.. Vrpor Prwure a5'C (115"F)(pris)........ . 141
vapor Prwur€ 45'C (115"D (pcia).............--291- Pollutlon C.rcSory-USEPA O IMO C V|DorD.ldty(Ah 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .2.0
PollutionCstegory-USEPA - IMO C 2.03
Vrpor DeEity (Air : 1.0)........................... Applloble Brll R.s. il6 CFn Slbch.ptc......... O Sohbllltyinwrter....................... Soluble
ApplicrbleBulk Reg.46 CFR Subchrpter........ O SolubilityinWater......................... Soluble

FIRE & EXPLOSION HAZARD DATA Gnde-B: Flammable liouid
Grade-A: Flammableliouid EleHcd Group-D
ElectricalGroup-D
Generrl-Ouilo tlammable.Emits toxic and irritatingvapors when heated. Vapor is heavier than air and may
General-Toxic oxides ot nitrogen may form in tire. Readilylorms sxplosive mixtureswith air. Fires are diflicult travel to a source of ignition and flash back.
to control because of the aase ol re-ignitionot lhe vapor.
I l s h P o i n t ( ' F ) . . . . . . . . . . . . . . . . . . . . . . . .3. .5. . .
F l s h P o l n tC n . . . . . . . . . . . . . . . . . . . . . .-.3. .5. . . . trlumrbfe Limits.......................... 2.Olo 10.4o/o
trhmmabl€LinttE.......................... 2.3 to 10.4ol. Autoigritio! Temp.('F)................ 604
AutoiSnition TemD.("n ................ 756 ExtinSuisbing A8entr..................... Carbondioxide,dry chemicalor alcoholtoam.
Extinguilhing 4gentr..................... Watersprayis parlicularly€tfsctivs,CO, SDecidFire Pruedures................Waler may be inetlective on fire. C@l exposed tanks with waler.
Flre Pr@edures................ Considerabl€ lires and
cauhonrs indicatedin approachingiso-propylamin€
particularlyin extinguishmentas an explosive mixture may €xist immadiatolyfollowing extinguishmsntand is
readily re-ignited.Self-containedbreathingequipmentwith tull lace piece is requirod.
HEALTH HAZARD DATA

HEALTH HAZARD DATA Hedth H|ed Rrtings Odor Thrghold (pDm) PEL,/TWA (ppm) TLV,TIWA (Dpn)
H€dth Hoed Rstings Odor Threshold (ppm) PEL,/TIVA (ppn) TLv,/TwA (pDn) 3,3,0 Unavailable 5' S.
3, 2, 4 Unavailable 5 5 Generd-A s€vere eye, skin and respiratoryirritant.Highly toxic when ingested or inhal€d.
cenerd-lsopropylamine liquid and vapor are irritatingto the skin, producingtypical alkali burns. Vapors will
initate eyes and lungs.
SymptoG-Sevsre irritationol skin, eyes and respiralorytract.
Symptoms-Vapor-nose, throat, and lung irritation;severe eye idtation or burns.
Short Erlnue Toleruce-Unavailablo
Short ExD6ure Tolemrunavailable
ExDocurePrcedurs-Skin-wash with soap and wal6r, then flush area wiih water. Eyes-flush wilh copious
ExposureProcedures-Skincontact-remove all contaminatedclothing,tlmd affected areas with latge quantities amounts of wat€r. Vapor-remove victim to fresh air. Adminisier artiticial respirationif necessry. In al.
of water, wash all aftected skin thoroughly:it any evidence ot skin burning is noted, a physicianshould be cases call a d@tor.
seen. Inhalation-remove patient to fresh air; nose and throat irritalionmay be relieved by sprayingor
garling with water. lf patient is unconscious,apply artilicial respiralion.
REACTIVITY DATA
REACTIVITY DATA Sbbtlity-Stable.
Strbility-Unstable-highly llammable, readily ignited by static sparks of relativelylow energy.
Compodbiltty-Mrt€ri8l: Glass and slaiilless steel.

ComDrtibility-Material: Can be handled safely in steel equipment;severely corrodes aluminum,copper, and
copper-basedalloys (except Monel).
Cugo: Group 7 ot compatibilitychart.

SPILL OR LEAK PROCEDURE woar full skin protection and s8lt-contained breathing apparatus. Secure ignilion sourc6s. Ackt eodium
Wear butyl rubbor glovor, rll-purpoao canister respirator,and protecliv€ clothing. Sgcuro ignition sourcos. It bisulfal€ and spray with water. Then clean up.
possibl€.covor lplll with rodium bisulfrt€. Spray with watar and wash up with large exco8s ot wator.
It I rplll ccu, crll ah. Nraloul R6Don* Cctricr, E00-42a-tt02,

lt . .rlll 6.r.r. c.ll th. N.ik,n.l nCFnF Ccnter. t{XLa2+ttll2. ' P€L rnd lL V
lrlrr blrart upon iro-Propytamim
' I'riltrrrr,' "(x) ilr'rliU ill ;','-C
&mrb Vl;xr
t- t59
*'"--,"". \**.
tJt
PROPYLENEOXIDE
PROPYLENE
Synonyel,2-Epoxypropane; Methyloxirano;
Propene 1280
UniiedNrtioN Numbcr................................
Synonyms- Methylethene;Methylethylene;Propene United Nations Number....................
............ 1077
oxid€
Formule-CHuOCHCHT
Formula-CHTCH: CHz Bollhg Po|n1........ ............. 34'C 94"F
Boiling Point............. 48'C ,54'F
'c 'F ApDcmnce-Odor-Colorl$s liquid; other-llk€ odor _"c _'F
-Appcarance-Odor-Colorless gas, liquid undsr pressurs; -- l.reerint PolDl..... -112"C -170"F
charactedsticolelin (gassy)odor F*zing Point......... tgs'c -go1'r
SDcclficGrrvlty-O.86 _'c _'F
SDeciticGravity-o.52 at 20'C _"c _'F 449
Vrlpr Prdure 20'C (6S"n (nfrHd..........
vrlDr Pressure20"C (6t'D (dnHg).......,,. 7840 Ch€nlcrl Fmlly-Alkal€ne oxkte Reld v.Dot Presure (psir) .... ........ 18.0
C'henicd Fmily-Olefin ReidVaporPressure (prir)........................... 227.2 Vrlnr Prwure ,16'C (ll5'D (psiq)............. 22.O
vrlDr Pre$ure46"c (r15'F) (psi!).............273.0 Pollution CatcSory-USEPA- B tMG O VrDor DeNtty (Alr : 1.0)........................ 2.00
Pollutlon Crtegory-USEPA - IMO ----ggg- V r l o r D e n s i t y( A i r : t . 0 ) . . . . . . . . . . . . . . . . . . 1 . 4 8 ADplicsbleRull Reg.45 CFR Subchrpter........ O Solublllty ln Wrier .... 597"
Applic8bleButt Reg.,l5 CFR Subchepter .... D. O Solubility in Wrter 45 ml oas/100 ml waler

FIRE & EXPLOSION HAZARD DATA Grade-A; Flammable liouid
crdFliquefied FlammabloGas (LFG) ElectricalGroup-B
Elecdcel Group-D
Gerer8l-An extremely reactive,llammable liquid with a wide explosive range. lgnited by heat, sparks or open
Cenerrl-As wilh all gas lires, lhe only etfeclive method of €xtinguishingis to shut otf ihe luel supply. Ilame. Flashback along vapor trail may occur. Fire or conlaminationmay cause violent rupture of lank.
OtheMise a mor€ dangeroussituation,the lormation ol an explosiv€mixiure can rssull.
F l u h P o i n t( ' n . . . . . . . . . . . . . . . . . . . . . .-. 3. .5. . . .
l l s h P o i n t C D . . . . . . . . . . . . . . . . . . . . . . .1. .6. 2
... Fbmmsble L i h i t s . . . . . . . . . . . . . . . . . . .1. . 8 . .t.o. .3 8 . 5 %
I'ltmmrbleLiDlts.......................... 2.0 to 11.Oolo AutoignitionTemp.('F) ................ 869
AutoiSnition Tenp, ('F) ................ 927 EriinSuishing Agents..................... Stop tlow of gas; largevolumesol water,COr, alcoholfoam.
Extinguirhing A9ents..................... Stop tlow ol gas; water log Specid Fire Procedures................ It a fire breaks out near a propyleneoxide tank, keep tank cool wilh a watel
SpecialFire Prcedures................Tanks exposed to fire should be kepi cool with a water spray. spray. Explosionhazard requiresapproachinga burning tank with caution.
HEALTH HAZARD DATA

HEALTH HAZARD DATA Hedth H.ed Rstings Odor Thr6hold (ppm) PEL,/TWA (ppm) TLV^WA (Dpn)
Health Hsard RrtinSs Odor Threshold (pDm) PEL./TWA (ppn) TLV,/TWA (Dpm) 3.2.2 200' 20 20
0,0, I Unavailable Unavailable Unavailable
Genenl-Suspected carcinogen.Vapor harmful. Liquid causes eye burns. Liquid or water solutions absorbed
Genersl-Simple asphyxiant.Absence ot adequale warning indicationssuch as strong odor or pronounc€d inio clothing, particularlyshoes, cause delayed skin burns.
irritationof mucous membranesol eyes and nose inlroduces possibilityot exposure to hazardous
concenlralions.Contact with the liquid may cause trostbite. SymDtoro-Nausea, vomiting and irritationto eyes and respiratorypassages.
Symptons-Dizziness,sleepiness
Short Ex!trure Tolemce-2000 ppm for 4 hours.
Short ExDcure Tolennce-Mixture of 6.46l"propyleneand 26olooxygen inhaled for 2 'l /4 minutes produces mild
intoxication,drowsiness,tingling of the skin, and inabilityto concentrate. ExposurePruedures-Vapor-remove victim to lresh air; if brealhing stops, apply arlilicial respiration.Skin or
eye contact-remove conlaminated clothing and gently flush atfected areas with water lor '15 minutes. Get
Etpcure Prcedures-Bemove victim to fresh air. Apply artificialrespiralionif breathing stops. Contact with medical advice or attention.
liquid may cause trostbite. It the liquid has spilled onto the skin, points of conlact may be frostbitten;handle 'Note: Detectableodor is greater than the TLV. Exposureto potentiallydangerous vapor concentration can
genlly and protect trom mechanicaldamage. DO NOT RUB. cet medical attention. occur before product can be detected by smell.
REACTIVITY DATA
REACTIVITY DATA -Polymerizes violently with catalysts such as acids, bases, and certain salts. Reacts violently with
Strbility-Stable at ordinary temperatures. chlorine and with ammonia.
I Avoid copper and other acetylidejorming metals.

Compstibllity-Msteddt Usual materialsol construciion may be used.

Csgo: Group 30 ot compatibilitychart.

wrur frJl)berglovos, lsrg€ h€avy face shaeld,(it in doubt, use body shield also), self-containedbrsalhing
Heve allpurpos canister mask available.Shut otf ignition sourc€s. Call the tire d€partmgnt. ll product do.r lttltrfrlur Avod conlrct wilh liquid. Secure ignition sourcss. Do not tlush spill into conlinsd spaces where
not catch fire. il will soon boil otl. lltmriltlrn virnai (:tn tc(:Umulalo
ll r rrlll r{crn. ..ll lh. Nrtlonrl Ramnre C€nter. tlXL42AEt02.

It r aDlll6cn oll rl. Nill,od
llrylri larf,l tF rlttll *rlh trrdt l)nrt
llcn.rltr
16l
2fr)
jg
SyDonyme-Diisopropyl
ether;Diisopropyl
2-lsopropoxypropane;lsopropylether;
oxide;
|So.PROPYLETHER
1159
UnitedNstionsNumb€r................................
l l S! nonyms- Azab€nzene; Azine
PYRIDINE
United Nations Number 1242
2,2'OxybisIpropane]
cHRls code.......... .. PRD
Fornula-(CHs)TCHOCH(Cft), Formulr-HCN(CH).
'C
BoilingPoint........... 154'F B o i t i n cp o i n t . . . . . . . . . ... . . . . 115'C 239'F
Appesnnce-Odor-Colorless,volatile liquid with an --g8'c ApDerr.nce-Odor-Yellow lo colorless ltquid:
ether€alodor FreezingPoha......... - rzo"r
nauseating, unpleasant odor l'reezingpoint......... . .. 42'3 *-'F
Sp€cificGnvlty-o.72 - L ,
'c 'F
S0.citlc Gr.vity-0.98
Vapor Prwure 20'C (6E'F) (mmHg).......... 119 '
C'hemicslFsmily-Ether Vrpor Pressure 20'C (68"F)(mmHg)..........
Hioh
ReidVeporPrsure (psis)........................... ('h€mlc.l Frmily-Amine
R e l dv s p o r P r e $ u r e( p s i ! ) . . . . . . . . . . . . . . . . . . . . O 7 7
-fff -;#
porution
crtesory-usEpA
- rMo p l:il:3:triliff;":tt1t,".1t".].........:.:. polrurioncrrerory-rsr:pr
c rlr() o J:il:l;::'""Jiff;":tt1i,tlllllil
. ..
Applicable Bulk Reg. ,15 CFR Subchapter........ O Solubitity in wstar................. ... . Neolioible
Appticrble Bult Reg, 116( t,R suhchsptcr O Complete
Solubility in Wrter.......................
.
GrrdeC: Flammableliquid Gredc-C: Flammable liouid
ElectricalGroup-D Elstricil Croup-D
G€nersl-Highly tlammable,dangerouslire risk. Ssv€re explosionrisk when expossd to hsat or flame. Generrl-Highly toxic lumes given ofl upon decomposition. Fie hazard high, when exposed to heat or flame.
Flashbackalong vapor trail may occur. Vapor may explode if ignited in an onclosed arsa. Explosion hazard severe, in the torm of vapor, when exposed to tlame or spark. Flashback along vapor trail
may occur. Vapor may explode if ignited in an enclosed area.
F l s h P o i r t C D . . . . . . . . . . . . . . . . . . . . . . . .1.8. .(. c. c ) F l s h P o i n t ( ' l - ) . . . . . . . . . . . . . . . . . . . . . . .6. .8. . .
Flrmm.blcLfnits.......................... 1.4 lo 2'loh Ffammsbfe l,imits. . ......................1.8 lo 12.4o/o
AutoiSnition Tefrp.("F)................ 830 Autoignition Temp, ('n ................900
Ertirguishin8 Agents..................... Carbon dioxids, alcohol toam, water log, dry chemical ExtinSuishing A8ents..................... Alcohol foam, dry chemical, CO,
SDecidFire Procedures................ Cool tanks with water spray. Keep surroundingscool to reduce lhe amounts SDecirl Fii€ Prsedures................ Keep tanks cool with water spray. Provide fire tighters with self-contained
of vapors produced.The danger ot reignilionis high. breathing apparatus.

Health Hmrd Ratingr Odor Threshold(ppm) PEL,/TWA (pDn) TLV,/TWA (DDn) Herlth Hurd Ratings Odor Threshold(ppm) PELITWA (Dpm) TLV,/TWA (ppn)
1, 1, 1 Unavailable 500 250 2,2,1 0.021 5 5
General-Toxic by ingestionand inhalation.Strong iritant. Prolongedor repeated skin contact may muse Genersl-Liquid mildly irritatingto the skin and can be absorbed through the skin. Vapor inhalation results in
dermatitis. slight irritationot aiNay with slight anaesthetic eflect.
Symptoms-Unavailable Symptoms-Nausea, headache,insomnia, neryous symptoms, low back or abdominal discomtort.
Short Expcure Tolerme-Animal tesis showgd 8000 ppm for 4 hours resulted in a 0"6 death rate, a trace ot Short ExposureTolerrnce-Very disagreeableodor at 30 ppm. Exposureaveraging 125 ppm, lour hours per day
eye injury,and no skin irritation. lor one to two weeks give rise to symptoms.
EtposurePr@edures-Vapor-remove victim to fresh air; if breathingstops, administerartilicial respiration.Skin ExposurePr@€dur6-Vapor-remove from exposure, use artiticial respirationil necessary,and obtain medical
or eye contact-remove contaminatedclothing and gently llush atfocted areas with water for 15 minutes. attention. Skin contact-remove contaminated clothing and wash skin thoroughly with large amounts of
Get medical attention.
l l water. Eye contact-irrigate eyes with waler for at least 15 minutes.

Strbility-ln presence ol air, may form peroxide which will explode it heated, or on impact. Stlbility-Stable. Possibiliiyof a dangerous reaction with acid anhydrides.
ComDstibility-Mrterirb: Steel is not aftected. Compatibility-Materirl: Copper and its alloys and some synthetic rubbers are unsuitable.
Crr8o: Group 41 ot compalabality

chart Cargo: Group I ol compalibility charl
SPII,I, OR LEAK PROCEDURE SPILL OR LEAK PROCEDURE

Walr rubbor glov3r, hrgo lplw hco Ehreld (body shield il neca!€6ry). Hav€ s€tt.contsined breething ll possrbl€, w€6r bools, rubber gloves, rubb€r or plastic coai, and sell-contained breathing apparatus
appltllus avlllrblo Avod corlacl wllh lrqud Socuro ignrlion sourcea. Notity polic€. harbor master, rnd lka xlrngurahsoufcos ol rgnrlronlf possible,cover large spillswith sand and soda ash mixtur€(90-10). Mix and
d€parlmenl Elhot wtll llort dornalroam (x iprold oul and crealo severo lire huard. rlxrv{rl rnlo a cerboar(t l}or
lrnrrll
,rrr,., (.ll t|r ildxl lm (
I l..Jll
'
V{xr ltrorturo
lf r rprll rrcurr, rrll tha N.alonrl Reipons (cntcr, t00-42,1-8t02.
;ro ntnrll0 rt ;,,r (
l l
t6l 261
\ -,', -,-o.,-it{""-
Synonyms- Codoil; Resin oil; Retinot;Rosinol
ROSTN
OtL
U r i t e d N a t i o n s N r m b e r . . . . . . . . . . . . . . . . . . . . . . . . , . . . . .2. 8. '6! lr SODIUMCHLORATESOLUTION.50o/"
Synonyms- Chlorate ol soda; Soda chloric acid,
sodium salt
Uoited Nations Number..... ' -- - . - . . . . . . - J ! 2 8 -
Fornuh-Mixture
CHRIS Code
BoilitrsPoint......................... 300-400"C 572-7 sO",F

__q8N_
l l Formula-NaClO,
('llRls Codc..................... . ........
_-saa_
'170"C 338'F
Boiling I'oinl
App€mce-Odor-White to brown liquid with a oinetrg€
-'r Appesrrncc-(Xor-Ygllow liqurd, odorless _'c _'F
pitch odor Frezing Point......... . . 19'C 65'F
t'c Frce?int l")inl
S!rccificcnvity-o.g8 to 1.11
_.c --.F SDecitlc Gr.vlly-1.5 _'c _'F
Clemical Family-Hydrocarbon mixture Valor Prwure 20"C(6t"D (nnHg)......... 0.04 Vrlor Prcssure 20 ('(6t'D (mmIlg).......... ---L-
ReidVaporPressure (pcie)...................... .. Low Chemlcel l'snlly- Reld Vrp,'r I'r(s\urr tpris). . t
VrDDrPressure 45'C (115"F)(psir)............. 0.15 V l F r r l ' r r s r u r e . 1 6( t l t s ' F ) { p s i r l . . . . .
PollutionCstegory-USEPA _ IMO B Valor Density(Air : f.0)................. ..... NP Pollution ( Ntetort -lrsEPA - f MO - lll VrFrr l)cnsily ( \ir 1 . 0 ) . . . . . . . ...
ADplicsbleBulk Reg.46 CFR Subchlpt€r....... D. O S o l u b i l i t y i n W a t e r . . . . . . . . . . . . . . . . . . . .N
. . .e.o. l i o i b l e Soluble
ApDtlcrble ltult Reg. 46 ( |lR sub(hrpter. O solubllity in \later ...... ...
FIRE & EXPLOSION HAZARD DATA I'IRE ' I.,XI'I,OSIONHAZARD DATA

Gmde-E: Combustibleliouid (;r{de-Non-llammabl€ Classrfiod as en oxrdrzor
Electriol Group-D
llleciric.l (;roup-NA
Generd-Slight tire hazard when exposed to h6at or llame.
(;enerrl-D6composes at hrgh lemperalures. Acts as an oxidizer. Not llammable bul supporls combustion.
Flsh Poirt CF).............................

25S to g9O l.lshPoiri ("1.) .......................
FhmmsbleLimits........ Unavailable |hmn.ble Limits. . Non-flammable solution
AutoigDitionTenp. ('D.............
.. 648
Autol8nltlotr Temp. {"F) ...............
ErtinguishingAg€nts.....................
Dry chemicat,foam or CO, I]rtlntulrhlng 48ents.....................
SpecialFire Pr@edur6................Watermay be ineltectiveon fire. spcclel Flre Preedurs................ Conlact with organic subsiances, sultur, sultides, powdered melals'
phosphorous or ammonium compounds can cause {ire and explosion. Sodium chlorate supplies ils own
oxyg€n for combustion Use copious amounts ol water.

Hqlth H@rd Rrtidgs Odor Threshold (Dpm) PEL,/TWA (ppn) TLV,/TWA (ppn) lleslth Hud Rstinss Odor Thrshold (ppm) PELITWA (Dpm) TLVAWA (pDn)
2,2,2 Unavaitabte Unavaitabte UnavaiiaOL O, 1, 1 Unavailable Unavailable Unavailable
Cenersl-Toxicity unavailable
ccneral-lrritating to the skin and eyes. No hazard lrom vapors. Not absorbed through the skin.
Symptoms-Unavailable
Symptoms-lngestion results in abdominal pain, nausea, vomiting, and cyanosis.
Short Exposure Tolemce-Unavaalable

Short ExposureToleranc*LDso for rats is 1200 mg/kg. Ingestionof 15 to 30 grams may be fatal.
Exlmure Prcedures-Unavailable
uxposurePrcedurg-For ingestion induce vomiting il victim is conscious. Flush skin and eyes with large
amounts ol walar.

stsbility-stabts.
Strblltty-Stable, but product decomposes at 300"F and liberatesoxygen.
Usual materialsoI constructionare suitable Comprtibility-M.terial: Stainlesssteel or lined steel are preferred;carbon steel and aluminum are suitable fot
several years seryice.
Cargo; Group 33 ot compatibititychan.
Crrgor Unassignedin compatibilitychart. See also Appendix l-Exceptions to the Chart

Wear rubbsr gloves, face shield and protectiveclothing. Secure ignition
sources. Covorallg and rubb€r bools should be worn. Clothing bocomas dangerously llanrnablo whon soakod wrlh
,hlorolos Uco rro loathor Dlod loalhor, such as sho€s, b€com€ hrghly llammabl(,rn conla(:l wllh s(xlurrr
, hknrlo So(:rro ill $)ur.os ol |0nrlron t-lush sprlls or leaks with wat€r Do nol lol $ptll nron (hY tinlll ll hel 1,, , r'
,hrlornrrod llr.l llxilo ri tt() r hk)tnkr ktll rn lhrt Aroa
loub: t UnsvriLblo
If r |Dlll mn, cdl thG Nrrton.l
I ll.-..1. I I r'r.v.i.lilo
lr r rprll 'x(orr...ll thr \rtkrnrl Rr\Frn{ ( (ntrr. xlx, ala rlll.l
lr
d
!
l6a
stnonynr- Sodrum brchromate; Sodium bichromate
SODIUMDICHROMATESOLUTION,70%
United Nrtions Number ...............
___-l__
l r SOLUTION,45%
SODIUMHYDROSULFIDE
$olulron Symnyms-Sodium bisullide;sodium hydrogen sultid€; Uniled Nrtlons Number... ........... 2949
Sodium mercaotan:Sodium sullhvdrats
CHRIS Code.. . .. . __sDr_

CHnIS Codc ........... sHR
lornulr-Na:CrrOz
Boiling Point .. ........... 11 4 ' C 238'F Fmrh-NaHS/N&S/HrO
-'F l f o f f h l a 3 P o t r t . . . . . . . . . . . . . . . . . . . . . .1. 4
. .0 " C 2a4'F
ApDarrrnce-Odor-Clear, red-orange liquid; no odor -'c
Freezing Point ........... - 3 8 ' C 36'F Apr.rrucc-Odor-Oark lmber lhuid wilh t rotl€n e99
-'F ooor t'rczlu Po1nt......... 4o'3 -*-"F
Speclflc Gravity-1.69 _'c
SpectllcGnrlty-1.23 lo 1.25 -"c -"F
VaporPresure20'C (68'n (mnHg).......... ---l-
t VrDorP.sutc il'C (6t't-) (mnHd......... 17 3
C'hemicrl Frmily-Oxidizer ReidVrpor Pre$ure(psia1......... .. .
Chemlcrl l'rnlly-Ceuallc! Rcld V|Dor PErrG (Ddr). ......................0.95
VaporPrruure il6"C (l15'n (psir)............. ----l-
Pollution Category-USEPA A fMO C V.por Density(Air : 1,0).............. VrDorPrurrc a6'C (tl5'l') tprle)............. --J,51-
Pollutlon (lrt.to.y-USDPA- D lM()- B V r p o r D c [ l a y ( A l r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .1. ...1. 7
..
Applicable Bulk R€g. ,16 CFR Subchrpter. .. O s o l u b i l i t y i n w s t e r . . . . . . . . . . . . . . . . . . . . .C. . .o m o l e t e
ADpllc.blc Bulh R4. rl5 CF-Rsubchrpler ......--A-- s . r l u b i l i r y l n w o a e r . . . . . . . . . . . . . . . . . . . .C
. .o m o l e t e

crade-Nonjlammable. Classilied as an oxidizer.
I'IRE & EXPLOSION HAZARD DATA
Electrical Creup-NA. cr.dc-C: Flammabl€liquid
Elctrlcd GrcuP-NA
Gen€ral-Non-flammable, but releases oxygen when heated. May ignite combustible materials upon contacl.
cererd-Moderate fir€ hazard due to hydrogen sulfide, a poisonous,highly flammable gas liberaled when
expog€d to hosl or llame
F l s h P o i n t ( ' n . . . . . . . . . . . . . . . . . . . . . . . . .N
. . o. .n - f l a m m a b l e
Flammrble Limits..........................Nonjlammable Fhd Polnt CF)......... 73
Autoigtrition Temp. ('F) ................Nonjlammable Flmmblc LlnlL....... 4.3 io 45.5%
Extinguishing A9etrts..................... Nonjlammable AutolgrlilonTcnp. ('F) ................
Unavailable
Fire Proedures................ Non-flammable Carbondioxide
ErtlngubbinSîertr.....................
s9etrl Flre Prccdurs................ Wear sell-containedbreathing apparalus and protective clothing.
HEALTH HAZARD DATA

Health Hurd Ratings PEL,/TWA (Dpm)
odor Threshold(ppm) TLV,/TWA (ppn) HEALTH HAZARD DATA
Unavailable 0.05 mg/m3as
None-No odor 0.05 mg/m3as Hertth H.4rd Rdirgs Odor Thr6hold (ppm) PELAWA (Dpn) TLV,/TtryA (ppn)
chromrum cnromlum Unavailable Unavailable' Unavailable Unavailable
cener|l-Even small quantitiesare highly toxic if ingested or absorbed through the skin. lf heated to the boiling Crnenl-Poisonous hydrogen sulfide may be evolved; this evolution increases with temperalure.Solution itsell
point will generate toxic spray. Some allergic responses.May cause lung cancer. is a skin irritant.
symptoms-Contact-Extremely i(itating to eyes and skin. Mist-Damage to mucous membranes,irritationto
respiratorysystem. Synptoms-Rapid or irregularbreathing,coughing,throat irritalion,bluish color, dizziness,lainlness, and weak
irr€gularpulse. Skin contact will caus€ a caustic type burn.
Short ExposureTolerance-Very irritatingat low concentrationsof misl.
Short Exp6urc Tol€rance-Unavailable
'l5
ExposurePrcedures-Get medical attention.Skin-Flush with soap and waler lor minutes, remove
contaminatedclothing. Eyes-Flush with water tor at least 15 minutes.Ingestion-Drink a quart of watgt, Erpque Prcedurq-Vapor-remove victim to lresh ai.loloh orygen inhalation is recommended.Skin-flush
induce vomitting.ll unconscious,do not attempt to give victim liquids or attempt vomiting. area with water. Eyes-tlush with copious amounts of water. In all cases call a doctor.
' NOTE: The odor (rotten egg) hydrogen sulfide gas should not be used as a warning, since its presence
ot
may deaden the sense of smell.
REACTIVITY DATA
strbility-Generally stable. Oxidizerreacts with reducing agents and many organics and inorganics.May ignit€ REACTIVITY DATA
linely divided combustibles. Srrbility-Slabls. Solution is mildly alkaline.
Compatibility-Msterisl: Suitable:Mild steel, stainless steel, aluminum.Unsuitable:Coppsr, zinc, tin, brasg,

bronze,organiclinings. CoDprtibility-M.teri* Corrosivelo steel above 150'F. Avoid use of aluminum
Cargo: Unassignedin the compatibilitychart. See Appendix l-Exceplions io the Charl.

Crto: Group 5 of compatibilitychart. See also Appendix l-Exceptions to the Chan.

Avoid all contact, includingbreathing mists. Oiks aJea, absorb on vermiculiteor sand, placo in a soalod molrtl
dispos€. Flush ar€a with wat€r. Don't allow inlo watemays. Wear proleclive clolhlng Includlrr\, W.a, rubbor glovct, boolr, snd gogglos, and full skin protsclion. Avoid contact with liquid.Secure ignition
gloves, boots and, il mists presenl, r€spiralor lu(iaa.
lf r olll acm cdl tb. Nrllord (,triGr. I lt I dll qcrn. crll th Nralud R..mx Catrter.E00-424-tt02,
Xcnrrk: IUn6varlable
Lr*gtr
l i
l6{r
lo?
SODIUMHYPOCHLORITE
SORBITOL
SOLUTION.15%
Synonyne- D-Gluciiol;L-Gulitol;
Synonyns-Chlorox; Hypochlorite, solutions; Javelle UtritedNrtions Number 1,2,3,4,5,6-Hsxanshsxol;
Sorbicolan:Sorbit; Sorbo:
water; Liquid bleach; Sodium hypochlorite Sorbol; SorbosM
CHRIS Code...
Formuh-CHTOH(CHOH).CH'OH
Fomuls-NaOCl Bolllng Polnt.. ..... V. Hioh"C -"F
Boiling Point... ADDcmnce-Odor-While, odorl6r cryslalline powder _'c _"F
App€srance-Odor-Green to yellow watery liquid; with a faint 8ws6l tast€. Freerlng Poinl ........ 110"C 230"F
bleaching liquid odor Freezing Point. SDcclflcGrrrliy-1.49 at 150'C. (liquid) _"c _'F
SD€cificGrsrity-1.21 lo 1.24
ValDr Prcssure20"C (6t'F) (mnHd.......... Low
vapor Pressure 20'C (68'n (mmHd.......... I Chemicd Frmlly-Glycol Low
ReldVaporPre$ure(psia)...........................
Chemical Frmily-Caustic Reid Vapor Pressure {psia). Vrpor Pressure 45"C(115"F)(psis).............Low
Vapor Pressure il6"C (t15"D (psia)............. I PollutionCrtegory-USEPA-- IMO- lll 32
Vrpor Denslty(Air : 1.0)...........................
Polluiion Cstegory-USEPA B IMO C VrpDr Density(Air : 1.0).................... r Applicrble Bulk Rcg. ,16CFR Subchepter Sotubilityin Wster......................
Applicable Bulk Reg. il6 CFR Subchapter....... O SolubilityinWater....................... Soluble

FIRE & EXPLOSION HAZARD DATA Grade-E: Combustible liouid
Crade-NonJIammable. Classifiedas an oxidizer. Electricgl GrouIFD
ElectricalGroup-NA.
Generaf-Slight lie hazad il exposed to heat or flam6
Generrl-May decompose in fire generatingirritatingchlorine gas. Conlairers may explode in lire due to
pressurebuilduD.
Flsh Point Cn.............. . . . . .... greater than 150
F l s h P o i r t ( " F ) . . . . . . . . . . . . . . . . . . . .N
. .o. .n. .j l. a. .m m a b l e Flsmmsble L|mits..........................Unavailable
F l a m m r b lLei m i t s . . . . . . . . . . . . . . . . . . . . . . . . . . AutoigDitlon Tenp. ("F) ................Unavailable
Autoignition Temp.("F)................ Not pertinent Extinguishing 4gents. ...................Water
ExtinSuishing Agents..................... Waterspray,log, foam,dry chemical,COr, or agentssuilabletor materialsin Specid l'ire Prcedures................ Us water lo cool fire exposed tanks lo avoid combuslion.
surroundingfire.
Spsid Fire Prcedures................ Cool tankswilh water.Wear full protectiveclothingand seltconlained
breathingapparatus.
HEALTH HAZARD DATA

HEALTH HAZARD DATA Heolth Hurd Rrttn86 Odor Thmhold (ppn) PEL,/TWA (ppm) TLV,/TwA (ppn)
He.lth Haard Rrtings Odor Threshold (ppm) PEL^WA (ppn) TLVITWA (Dpm) Unavailable None Not oertinent Not oertinent
Unavailable Unavailable Unavailable Unavaitable
General-No threat of damage from vapor inhalation since the volatility of sorbitol is so low.
irritation,burns, and/or corrosion from liquid.Vapor may cause sevore respiratorytract
irratalionand oulmonaryedema.
synptomFHot liquidwill burn skin.
Toxicily and corrosivitydepend upon concentration.Higher concenlrationol industrialgrades are
more damaging than concenlralion of household bleach (approx. 5.25olo min.).
Short ExposureTolerance-Nol applicable.
flxntrure Toleratrce-
ExposurePreedures-Treai for burns rasultinglrom contact with hot liquids.
l l
f.xposurePrcedures-lf ingested,DO NOT INDUCEvomiling, give large quantilies of milk. Skin or eye contact:
Flush areas with water for 15 minutesand consult phvsician.
REAC]TIVITY DATA
stability-Stable, but stabilitydecreaseswith concentration,heat, light, decrease in pH and contaminationby
metals. Strong oxidizer.
tl stsbili8-stable.
REACTIVITY DATA
Compstibility-Materirl Mild or stainless steel is acceptabls.

Conprtibility-Msterisl: lncompatiblewith steel, cast iron, 12 and 17./ochromium steel, mon€|, nick€l, incon6l,
aluminum,brass,silicon,bronze
Cargo: Group 5 ol compatibilitycharl.

Avoid contact with hot liquid. Wear goggles or lace shield, protstiv€ clothing fo. hot liquid.Stop dischargs il
Wear rubb€r gloves and rubber sately sho€s, goggles or lull lace shield, and rsspiratoryptotection. Oisp€rs€ possibl€.
ail(l llush sptllgdor lsakingmat€rial
ll . .Dill €cu6, crll th€ Nrtionrl Rgrcnse Centcr, EIX)-42,L8E02,

ll r slll ccu[. crll th. Nrtlonrl C.nler, E00.a2a-t802.
lborrlr: ' trtnoouhlrxr. Tat)l('
' 2, 46 CFR Pa.l 153
llenrlr: ll'i (rntnlsils sbovo I l0'(.1 l?ll0 l ) ' '
Vory ri)luble In hol wtlat
I lrn{v6rltrlrkl I llt6r1glq;
tu SCANNED BY MKP & BARIS A. 2004

SPERMOIL
SOYBEAN
OIL
Synonyms- Whale sperm oil Urited Nstions Nunber . . ' ' . ' . ' . . . ' . ' , ' . '.._' _ t
Synonyrchinese bean oil; Soyabeanoil; Soy oil United Nrtions Nuhb€...................
CHRIS Code................. , ' ' ' . . . . ' . ' ' . , ' . ,o

. SP
cHRIs code........... .... OSB
Formulr-lndefinite
Formuh-Mixture V. Hioh"C _'F
Bolllng Poin1.................
Boiling Polnt............. ........... V. Hioh'C -"F _'F
Appearrnce-Odor-Light yellow oily liquid; characteristrc _'c
App€rrence-Odor-Pale yellow liquid; weak odor t'c _"F
odot Freezhg Point...............
Fredrs point......... - 1/''3 :r-:F
.... .......
. Specific Grrvity-o.87 to 0.88
Sp€cific CnYity-o.g2 lo 0.93 _'c _'F vapor Pressure 20'C (68'D (mmtlg).... . 2 O
Prwure 20"C(68'D (nnHs).......... 2.04
Va1rer Chemical Family- Reid vsDor Pressure (psia)......... 0.1
C'heniel Fmily-Esters
Reid Vapor Pressure (psir)........................... 0.1O vapor Piesure 46'c (115'D (psia).......... 0.15
VrDor Prsure 46'C (1rs'F) (pstr)............. 0.16 Pollution Category-USEPA - IMO D vrpor Den$il' (Air - 1,0)..............
Pollution CsteSory-USEPA - IMO D Va!rer DeNity (Air : t.0)........................... NP Applicsble Bulk Reg. /16 CFR Subchapter..... D Solubilityinwaler....................... Insoluble
ApDlicsbl€ Bulk Reg. ,t6 CFR Subchapter........ D SolubilityinWrter......................... Slioht

FIRE & EXPLOSION HAZARD DATA Grade-E: Combustible liouid
Grede-E: Combustibleliouid Elctrical Group-D
Electrical Group-D
G€Dersl-Slight fire hazafd when exposed to heat or Ilam€.
Generef-slight lirc hazad when exposed lo heat or tlamo,
F ' l a s hP o i n t ( ' F ) . . . . . . . . . . . . . . . . . . . . . . . .4. .2. 8. .

F l B h P o l n t( ' n . . . . . . . . . . . . . . . . . . . . . .5. 4
. .0. . . .
F l a m m a b l eL i m i t s . . . . . . . . . . . . . . . . . . . . . .U. .n. a. v a i l a b l e
FhmmrblcL|mits.......................... Unavailable Autoignition T€mD. ("t') ................586
AutoigrldonTemp. ('D................ 833 Hxtinguishin8 ASents ............ Carbon dioxide, dry ch€mical
Extinguishing A8ents..................... Dry chemical,foam or carbondioxids Special Fire Prcedures................ Wat€t toam may cause frothing.
Specid I'ire Prcedurq................ Wetor may be ingtloctive on fir6. Cool exposed containerswiih waler
HEALTH HAZARD DATA

HEALTH HAZARD DATA Hedth Haard Rrtlngs Odor Threshold(Dpm) PELAWA (ppn) TLV,/TWA (ppm)
H€slth Hsard Ratings Odor Threshold (ppm) PEL,/TWA (ppm) TLV,/TWA (ppn) 0. 1. 0 Unavailable Unavailable Unavailable
Unavailable Not pertinent Not pertinent Not pertinsnl
Genersl-Toxiciiy probably low. Details unavailable.
Canerrl-Not harmful.
Symptoms-Non€
Short ExposureToleranceDes not penslrale skin in harmlul amounts.
Expoure Prcedures-Flush attecied areas with plenty of water; wash thoroughly wilh soap and watet.
Exlmure PredueNon-loxic. Wash thoroughlywith soap and water.
REACTIVITY DATA
REACTIVITY DATA Strbility-Stabls.
Compatibility-Mriorirl: Usual materialsof constructionare suitabl€.

Usual malerialsot constructionare suitable.Will sotten $me Daintsand rubb€r.
Clrgo: Group 33 ot compatibilitychart.

Crrgor Group 34 ol compatibilitychart.
SPII,I, OR I,I.]AX PROCEDURE

Wear rubber gloves, face shield and protective clothing.
lvaa, tuboargbvaa,lE at*d and p.otmtfv. ctothing.Secureall ignitionsourcas.
lf t sDill occurs. c.ll the N.tional ResDnse Cenler. 800-42it-8802.

I iill 'r.*r, r.ll t|' \.ll.n.l Rrrp.rn* ( cnttr,
ll.m.rh: | [rnavarlable
as|r I tirnaart: I lJns$urgnod
211
I
rro SCANNED BY MKP & BARIS A. 2004
STYRENEMONOMER SULFUR(molten)
Synonyms-Cinnamene;Cinnamol;Ethenylbenzene; United Nations Number................................2055 Synonyns- Brimstone;Sulfur; Sulphur United Nations Numb€r mollen 2448
Phenylethylene;Styrene; Styrol; Styrolene; solid 1350
Vinylbenzene
CHRIS Code..... C H R I S C o d € . . . . . . . . . . . . . . . . . . ' . . . . ' . ' , , ' . . ' . ' . 'S

. ,X X
Fornulr-Ce HsCHCHT Formula-S

Boiling Point..... ... 145"C 293'F Appearance-Odor-Yellow-to-brown solid; amber liquid Boiling Point.. . 444"C 832F
Aplcarrnce-Odor-Colorless liquid;sweet odor when ----------.^
----------"- above 238'F; sharpchokingSO, lumes usually
pure; sharp disagreeableodor when impure FreezinS Point... . . . i w - _ d r presenl Frezing Point . rra'c zg8"r
SpecificGravity-0.92 U I
Sp€cificGravity-1.80 at 265'F (liquid):density of solid
VrpDr Pressure 20'C (68'F) (nnHg).......... 6 0 sulfuris 2.07 g/cc VaDor Pressure 20'C (68"F) (mmH9.......... V Low
ChemicslFamily-Olef in Reid Vapor Pressure (psis)........................ O27 Chemic.l Fqmily-Element R e i d V a p o r P r e s s u r e ( D s i r ) . . . . . . . . . . . . . . . . . . . . . .V
. . . .L. o w
Vlpor Pressure ,l5'C (l15"F) (psis)............ 0 4 Vapor Pressure 45'C (1fs'D (psia)............. V. Low
Pollutioncategory-UsEPA C IMO B 3.6 Pollution Cttegory-USEPA - lll
V$orDensity(Air: 1.0)..... ... . IMO VrDor Density(Air - 1.0)..............
ADplicrbleBulk Reg.46CFR Subchapter........ O Solubility in Wrter Neolioible ApplicableBulk Reg.{6 CFR Subchapter........ O S o l u b i l i t yi n W s t € r . . . . . . . . . . . . . . . . . . . . . . . Neolioible
GrrdFD: Combustibleliouid Crrde-E: Combustibleliquid (when carried in molten state)
ElectricslGroup-D Electricd Groul+C
Genersl-lgnited by heat and open flame. Fire or contaminaiion may cause violsnt ruplure ol tank.
F l N h P o i n t( " n . . . . . . . . . . . . . . . . . . . . . .1. 0
. .0. . . .
ll Sulfur in the mollen stale giv€s otl hydrogen sullids (H,S) gas, which is poisonous end highly
llammable. Th€ ret€ ol ges avolulion d€pends on condilions, particularly th€ amount of hydrocarbon
impuritiss present.
Flsh Polnt ('l') .. ... . . ............ 335 to 370 ,1
F|rmmrblL e i m i t s . . . . . . . . . . . . . . . . . .l...l. .t.o. .6. . 1 % Fhnmrble l,lmltr..... .............. Unavarlabl€ I
Autoignition T€nD. ('F)................ 914 Autoignftfon TemD. ('l') ......... 374 lo 42a
Extinguishing Ag€nts..................... COr,dry chemical,water fog, toam ExtlnSuiihln8 A8cnas. COr, dry chomrcal, sleam, waler log
SpecialFire Pmedurcs................Avoid breathingvapors. Provide body and respiraloryprotection.Keep tanks Flre Predures ....... Do not drrsci8 solidslreim ol waier Into burningliquidsulfuror a steam
cool with water spray. explosion may result. When sullur burns, sulfur dioxide (SO,) is given otl. This gas is highly toxic, so
firefightingp€rsonnsl must be provided wilh r€spiretoryprotection.

Heslth Hurd RatinS! Odor Threshold (pDm) PELAWA (ppm) TLV,TTWA (ppn) Herlth H!a.d Rstings Odor Threrhold (ppn) PELITWA (ppm) TLv,/TwA (ppm)
2.2.2 0.15 50 so/Skin 1, 1, 1 ' TLV tor H,S,10 T L V t o r H , S ,1 0
Gererul-Suspected carcinogen.Vapor very irrilatingto eyes, moderatelyirritatingto respiratorytract with General-Liquid causes severe thermal burns. TLV for SO,' 2 TLV for SOz' 2
moderate systemic eifecl. Liquid irritatingto skin. Gas is poisonousby inhalation.
Symptoms-Weakness,dizziness,nausea,and sleepiness. Synptons-HzS-headache, nausea, dizziness;loss of sense ol smell. Sor-severe eye and respiratory
irritaiion.
Short Exlosure Tolersnce-10,000 ppm may be fatal in 30 to 60 minutes. Short ExposureTolermce-2oo ppm for 10 minutes. 100 ppm lor 30 minutes. 50 ppm tor one hour.
ExpmurePrcedurevapors-remove victim to frash air; il breathingstops, apply artilicial respiration.Skjn of ExposureProcedureFRemove victim to lresh air. ll breathing stops, apply arliticial respiralion.Oxygen,
eye contact-remove contaminatedclothing and gently llush alfected areas with water for 15 minules.
Soap, if available,should be used on atfected skin areas. Get medical attention.
ll administeredby trained personn€|,is often helpful. Body contact with hol liquid sulfur can cause severe
scalding. Do not try to remove the solidifiedsullur from such a burn. Get medical attention.
*NOTE: Odor alone does not give
adequate warning of dangerous HrS concentrations.
REACTIVITY DATA
Shbility-Will readilylorm peroxideswhich catalyze polymerizationunless inhibited.Heat, light, and strong
acids also catalyze polymerizationreaction.' ll REACTIVITY DATA
Stsbility-Stable except in contact with oxidizingagents or reactive metals. The rate ol HrS gas evolirtion trom
molten sullur increaseswith agiiation.
Conpttlbility-Mste.irl Most materialsot constructionare suitable.Oo not use copper or its alloys. Styr€no Compotibility-Mrterisl: Liquid sullur is not corrosive to stesl, but corrodes copper and its alloys. Moist sulfur is
can bo polymerizgdat explosiverates by certain contaminanls.
Crrgo: Group 30 of compatibilitychart. ll corrosive to steel.
C8rgo: Unassignedin compatibilitycharl
SPII,I, OR I,EAK PROCEDURE

woat rublpr glovor. hco rhdd, p'otxlrva clolhrng. Hav€ all-purposs canister mask availablg.Avoid contact
II SPILL OR LEAK PROCEDURE
Avoid contact with hot liquid. Wear heavy work gloves, goggles or tace shield, protective clothing for hot
wllh lrquad Scu. |gdtbn Frrcaa liquid. Have self-containedbrealhing apparatus available. Secure ignitjon sources. A major spill of liquid sullur
'
ll r rNll '*rrr ..ll rr. \.rr'n.l Lc ('dtt. U-a24-ttlt2.
ll into navigabls waters will solidify and sink, pr€sentingno unusual haards.
Il r rolff ccurs. crll the Notional Rcmn* Center, 8(X)424-an2.

feb. I y!, rh , | .as, lE.tqt etrrvu l?C.f . ct.r polymrtro wtth lho gonoralon ol rc Lrhrrl.r Seo 46 CFR 35-Elevated Temperature Ca,go€a.
II
ry,tr t-a taa I ..,
,'r
21t
SULFURDIOXIDE SULFURICACID
SyDotryms-Sulfur dioxide, liquelied; Sullurous United Nstions Numb€r .........__1929_ Synonyns- Battery acid; Chamber acid; Fstilizer acid; Utrlted Nrtlonc Nunber................. 1830
anhydride; Sulturous oxide Oil ot vikiol
CHRIS Cod€................. . . . . . . . . .s F o CHRIS Code SFA
Formula-SO2 t'ormula-HrSOr
'C
Boiling Point........... 14'F 340"C 644'F
Bolltr8 Poinl.........
Appeararce-Odor-Compressed liquefied gas with sharp Apperrrnce-Odor-Colorless-to-brownorly liquid; no
irritating odor. Freezitrs
Poirt......... ......... ?5"3 -t*'F ro"c so"r
odor unless hol, lhon lhe odor aschokirg l'reezing Point.......
Specific Gnvity-1.45 (at 10"C) SDecltlcGrrrlty-1.56 to 1.84
v.!nr Pressure20"C(58'F)(nnHO.......... 2488 Vlpor Presure 20'C (68'n (mmHg)..........---t8!!-
Chemical Family-Acid anhydride (psia)...............
ReidVaporPressure ......... 84 Ctemlcd Fmlly-lnorganic acid Reid vapor Pressure (psia).............. ......... Lil
VsporPressure il5'C (115'F)(psia)............. 108 Vapor Pressure46'C (f15"F) (psis).............--!eW-
Pollution Category-USEPA - IMO ----g!E- V{roorDensity(Air : 1.0)...........................
2.2 Pollrtion crtcSory-UstlPA C C
IMO V s l D r D e n s i t y ( A i r: 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . 3. ...4. . .
Applicable Bulk Reg. il6 CFR Subchapter. . . .. O Solubility in Water ApplicrbleBulk Re8.46 Cl'R Subch8pter........ O S o l u b i l i t y i n w a l e r . . . . . . . . . . . . . . . . . . . . .C
. .o
. molete
Grule-Liquetied Compressed cas (LCG) Grsde-Nonjlammable. Classifiedas a corrosive liquid.
Electricsl Croup-NA Eletric.l GroulFB (based upon possible hydrogen gas (H,) generation should a leak or spill occur)
G€neral-Non-flammabls, but in a tire, tank may ruplure and relea$ iritating, loxic sultur dioxide. Generrl-Sulfuric acid will not burn. lt will react with many metals, giving olf hydrogen gas which is highly
flammable. lf hydrogen is trapped in conlined spaces, it can lorm an explosive mixture with air. See data
sheel tor hydrogen.
Flsh Point ("F).............................
Non-tlammable F l u h P o i n t( ' D . . . . . . . .... . . . . . . . . . . .N
. on-tlammable
Flammable Limits..........................Non-tlammable Fl.nmrble l,imlts ... . Non-tlammable
AutoiSnition Temp, ('F) ................Non-tlammable AutoignilionTemp.('l') .......... .... Non-flammable
ExtirSuishing Agents..................... Non-tlammable Extin8uishingAgenls....... NonJlammable
Specirl Fir€ Pr$edurcs................ Cool expo$d tanks with wal€r. Woar eye protection and selt-contained Spcchl Fire Prcodurcs ..............OO NOT USE WATEB to put out a fire il the water can get into concentraled
breathing apparatus. sulluric acid. In case ol a tire n€xi to a sulluric acid tank, use respiratoryprotection against fumes.

Heslth H@rd Ratings odor Threshold(ppm) PELAWA (ppn) TLvlTwA (pDm) Hellth Hsard Rrtltrgs Odor Thrqhold (ppm) PEL,/TWA (ppn) TLV,/TWA (Dpm)
4,1,4 3 2 2
I
2,4,2 G r € a t e tr h a n 1 m g / m 3 1 mg/m3 1 mg/m3
General-Liquid can cause frostbile, Vapor is very irritatingto the eyes and lungs even at low concentrationa, Ccncnl-Liquid caus€s severe burns with destructionof tissue. Vapor very irritating.
Symptons-Vapor-causes irritationot eyes and lungs with severe choking. Liquid will cause trostbite. SynptoeThe inhalationhazard is slight at ordinary temperatures.The skin on which acid is spilled may feel
I
hot ot ii may sting or itch.
Short ExDosureTolermce-2o ppm for 5 minutes. ShortExposureTolermce-l0 mg/m3lor 5 minutes;5 mg/mr lor 10 minutes;2 mg/m3tor 30 minutes.
ExposurePreedurc-Vapor-remove victim to lresh air. Administeroxygen il possible. Skin-tlush skin with ExposurePrcedurc-Drench with waler. Remove contaminatedclothing and flow water onto atfected area lor
'15 minutes.
I
water. Eyes-wash with wat€r for 15 minutes. ll the liquid has spilled onto the skin, points ol contact may For gye contact, immediatelyflush eye with large amounts ot water for 15 minutes. Get medical
be trostbitteh;handle gently and protect from mechanicaldamage. DO NOT RUA. Get medical attention. anentron.
REACTIVITY DATA
Stabiliay-Reacts with water to fo.m sulfurousacid, HzSOr.
I REAC:TIVITY DATA
Strbiliay-Stable, but can react very easily with many other materials.
( onpdlbility-Mrterisl: The acidic roaction with water corrodss aluminumand sofii€ oihst metalr. ( omprllblllty-Mrterisl: Highly corrosive lo most mslals: particularlyal concentralion6bslow 60'Be. May cauae
Crr8o: Unassignedin compatibilitychart. For compatibilityassistence,call

G MTH-1{202-267-1577).
I wood or cellulose lo ignite
Crrgo: Group 2 ol compatibrhtychlri Soo slr Aplxndlr l-trcoptonr to tho Chart.

wo.r rubbor gloves, €ye proteciion, self-containedbr€alhrngapparetus, and protective clothing. Try to rhut
I sPll.l. ()L l.trAX PR()('ll)t'Rl.
Wont rllrtx{ {Jkrvot, roll t:(xrlailrff, Irorllxr\, all,aralUr ltrr)lq trvd ( l('tlrrU I l{v0 lxx,y sl)rokj avarlablo Avorl
,,rt tral, ,,xtll(rl wllll lklil! Sqrtro r0rllNtrr f,xrior lsde ol lltn tntdlrlly ol hyrlr(Xloil (ls\ 06noralon ll possrbk'.
I
,,tvd rlrll wllh axt{xs lx atlxxralo r, sxlt arh rlalql [rrF nrrlurD ltt{) ,rt)} Mrr trrtr, il(r(l walor lo lorm a slurry
"rrxttqrrhrry Warl'n.l.t*,11,r.!la.el,r'.lilNr! l)ll!'r*rrnl[[hrdutilrrrlywrtl,wilh,r Avo(l(ir0oltngStreilrr)
, , ' 1 , ,r t r o o r t r x r r r . r t x n I I "l
ll . .trlll rcrn, .rll th. Nr|lill Rmu (:entcr. t0t-a2a-til12. " ,1. \rtr.r.l L..F,is | .nl.r. llll {la Nllll.
lal. ' ll.a(:tr wrth w.tor
to lorm rutturouarcid. HrSOr. l.r-1. I Allllr{ lto,,,, .,ll .tld L, t,{ }rl r'tlst,.o l i l l ( x ( i n 1 l ( i l u l k x l r b r o q u r o ( 1 .a l w a y a
q ' a t t r t t r 1 Lw
I rll lt- rrl ft (J.har kr ttr.at- lt- rrt { t-.vs [ran rald lhoi, tho l$st ol rolulDn wrll b€
rhr. udirnlt a.|rht rrt i-||:rt, .l l- .yrrtrl
274
SCANNED.,., BY MKP & BARIS A. 2004
J?'
b,L -,, .- \
TALL OIL TALLOW
Synonyns- Liquid rosin; Talleol: Tallol Urited Nrtions Nunber Synonyms- Edible tallow; inedible tallow; Tallow oil United Nrtions Number
CHRIS Code........... .... OTL ( l t R l S ( l o d e . . . . . . . . . . . ... . ' , ' , ' , ' ',,.. TLo
Formula-Mixlure ol rosin acids Formuh-Fals containing Cr6 to C,"

B o i 1 i n g P o l n t . . . . . . . . . . . . . . . . . .V. . .H
. .i.o. h " 9 - " F B o i l i n g P o l n t . . . . .. . . .. . . . V. Hioh"C_'F
ADD€arrnce-Odor-Yellow, oily liquid; acrid odor -t'c -'r Appearance-Odor-Dark yellow liquid with a waxy odol
F r e e z i n gP o i n t . . . . . . . . . . . . . _ z-7"c g+.as'p
FreezingPolnr...
Specific Grarity-o.gs to 1.00 _'c _"F Specific Grrvliy-0.85 to 0.89 al 70'C
Vrpor Pressure 20'C (68"F)(mmHO......... 1.5 vaDor Pr6sure 20'C (68'F) (mmH9...... . 2O
Chemical Fmily- Chemicll Frmlly-Esters R e i d V a D o r P r e s s u r e ( D ! l r ) . . . . . . . . . . . . . . . . . . . . . . . . .0. . 1
R c l dV r p o rP r e $ u r e ( p s i s ) . . . . . . . . . . . . . . . . . . . .0. . 1. .
VrDorPressure,.6'C(f15"F) (psia)............ 0.15 Vapor Pressure 45'C (ffs'F) (psia).............---92-
B NP Pollution Crte8o.y-USEPA - IMO D Vrpor DeNity (Air : 1.0)........................... NP
Pollution Crtegory-USEPA - IMO V r D o rD e t r s l t(yA h : r . 0 ) . . . . . . . . . . . . . . . . .
Applicable Bulk Reg. 46 CFR Sub.hrDt€r........ O. O Neolioible Appticrble Bulk Reg. 46 CFR Subchryter. ...... D Solubility in Water Neolioible
Solubility in Wrter
FIRE & EXPI,OSION HAZARD DATA FIRE & EXPLOSION HAZARD DATA
GrrdeE: Combustibl€ liquid Grade-E: Combustible liquid
Electricel Group-D Electrical Group-D
Generll-Slight lire hazard wh€n exposad to h€at or tlame. General-Slight fire hazard when exposed to heat or llame.
F l s h P o i n t ( ' n . . . . . . . . . . . . . . . . . . . . . . . . .3. .8. 0. F I a s h P o i n t ( ' F ) . . . . . . . . . . . . . . . . . . . . . . . .5. .0. 9. .

Flanmrble Limits.......................... Unavailable Flammable Limits..........................Unavailable
AutoigDitior Temp. ('D ................Unavailable Autoignition Temp. ('D................ Unavailable
Extinguishing Ag€Dts..................... Foam, dry chemical or CO, Extinguishing A9ents..................... Foam, waler, COr, or dry chemical
SDecisl I'ire Prucdure................ Water may be ineflective on fire. Use water to cool exposed tanks. Special Fire Prmedures................ Waler may be inetfective. Cool exposed contarners with water.
HEALTH HAZARD DATA

I 'l
HEALTH HAZARD DATA
H€alth Haard Rstings Odor Threhold (ppm) PEL,/TWA (ppn) TLVAWA (pDn) Heslth Hazard RstinSs Odor hreshold(ppm) PEL,/TWA (ppm) TLV,/TWA (ppm)
Unavailable Unavailable Unavailable Unavailable Not pertinent Unavailable Not pertinent Not pertinent
GeDersl-Avoid contact with liouid. (;enerrl-Non-toxic, but possibilityol thermal burns trom hot liquid.
SymDtoms-Skin@ntact will cause minor reddening. SymptorNon-toxic.
Short ExposureTolerarce-Not pertinent Short ExposureTolerance-Hot liquid can burn eyes and skin,
ExpocurePrmedureskin-llush atfected areas with plenty of water; wash tho.oughly with soap and water. ExposureProcedures-Treat burns caused by hol liquid.

Stability-Stable. Stability-Stable.
('omD.tlblllty-Msteri.l: Usual materialsoI conslructionare suitable. Compatibility-Materirl:
Crr3o: Group 34 ot compatibilitychart. Csryo: Group 34 ol compatibilitychart. See also Appendix l-Exceptions to the Chart
SPII,I, OR I,EAK PROCEDURE SPILL OR LEAK PROCEDURE

Wot buM trbOaf glowr. irc. .hpld ond protectiveclothing. W€ar rubber glovss, face shield and protective clothing lor hol liquid.
It \.tlol nlplx ( rnter. t(XF4!FtC02. If t roill occurr. cEll the National Resmnse Center. 8m-424-8802.
a.atott,, "af Rcnrr\r: I Unassioned

I rx...{td
I
t?6
TETRAETHYLENE
GLYCOL
1,l,2,2.TETRACHLOROETHANE Synonyms- bis[2-(2-Hydroxyethoxy)ethyl]ether; TEG; Urit€d Nrtlons Nunber ,,.,.,.,, :L
3,6,g-Trioxaundecanol, 1 1 -diol
Synonyms- Acetylsne leirachloride; Ethane, United Nrtions Number ,....__1?9?_
1,1,2,2-tetrachloro-; Tetrachlor@thane;
sym-Tetrachloroethane
C H R I SC o d c . . . . .. . . . .
CHRIS Code................. ..... TEC
Formula-HO(GHrO)jGHrOH
Formula-CbCHCHCIz I t o f l f r g P o l n t . . . . . . . . . . . . . . . . . . .3. .2. 7
. .'.C. 621'F
'C Appeerance-Odor-Colorl€ss to pala-straw colored -o'E
Boiling Point........... 295'F
ADpearanc€.Odor-Clear to slightly yellow liquid with --u"c
liquid; sws€t odor !'r*ztnsPotni......... ""i
chloroform-like odor -47"F SDecific Grrvity- 1.'13 - U
Freezing Point.........
Spsific Gravity-l.60 _'c _'F Vtpor Pressure 20'C (68'F) (mmHg)......... Low
Chemicd Frmlly-Glycol sthal Reld Vepor Pressure (psia).........-..... Low
Vapor Presure 20'C (68'n (mmHg)..........--j-!LO- .
Chemical Family-Halogenated hydrmarbons ReidVrpor Prsure (psi.)........................... 0.5 Vtpor Pressure /t6'C (lls'D (Dsir).... ....... Low
PollutionCrtegory-UsllPA.- IMO- lll Vrpor Denllty (Air ... 1.0).............. . 6.7
VaporPressure 46'C (ffs'F) (Dsir)............. 1 0
Pollution category-uSfPl B IMO B V r p o r D e n s i t y ( A i r : 1 , 0 ) . . . . . . . . . . . . . . . . . . . . .5. ...8. . . Applicrble Bult Reg. ,15 CFR Subcheprer... . D S o l u b l l i t yI n w r t e r . . . . . . . . . . . . . . . . . . . . . . . . C o m o l ete
ApDlicable Bulk Reg. {6 CFR Subchrpt€r........ O SolubilityinWster......................... Slioht
FIRI] & EXPLOSION HAZARD DATA
FIRE & EXPLOSION HAZARD DATA Grrde-E: Combustible liquid
Grsde-Non-f lammable Electrlcel Grou!+C
Electrical Group-NA
Generel-Slight fire hazard when exposed to heat or flame.
Gercnl-Nonjlammable, corrosive liquid. When heated, it emils highly toxic decomposition products.
F l s h P o i n t ( ' n . . . . . . . . . . . . . . . . . . . . . . . . . 3. .4. 5
FINh Point CF).............................
Non-flammablE Fhmmrbl€ Limits..........................Unavailable
FlMmble Limits..........................Non-flammable Autoignltion Tenp. ('F) ................Unavailable
AutoiSrition TemD. ("F)................ Nonjlammable Extinguishing Agents..................... Alcohol loam, @2, water, dry chemical
Extinguishing Agents.....................
NonJlammable Sp€cisl Fire Procedures................ Water may caus frothing. Cool expos€d tanks with water.
Speial Fire Pr@edur6................ Wear selt-containsd brsalhing apparalus.
HEALTH HAZARD DATA

I Health Haard Ratings
HEALTH HAZARD DATA
Odor Threshold(ppm) PELAWA (ppm) TLV,/TWA (ptn)
Heslth Haed Rrtings Odor Threshold(ppm) PELAWA (pDm) TLVITWA (ppn) 0, 0, 0 Unavailable Unavailabte Unavailable
Unavailable 0.5 1/Skin 1/Skin C4nersl-Low to no toxicity; no skin, ingeslive or inhalationeffects.
G€neral-Suspected carcinogen.A powerfulnarcotic and liver poison.
Symptoms-lngestion-vomiting, diarhea. Acute intoxicalionwith unconsciousness,cyanosis, loss of retlexes
and death. Inhalation-can be absorbed by lungs. Fatal atter repeated inhalation. Short Exposure Tolme-Unavailable
Short ExposureTolerance-1O ppm lor 30 minuies.
ExposurePrcdures-Vapor-remove viclim to tresh air. Skin or eye contact-remove contaminatedclothing

Expcure Prcedurs-lnhalation-remove to fresh air and, it necessary,administerartilicial respiration. and gently llush aifected areas with water tor 15 minutes.Get medical advice or attenlbn.
Ingestion-induce vomiting. Eyes-flush with water for 15 minutes.Skin-remove clothing and wash skin
with soap and warm water. In all cases call a doclor.
REACTIVITY DATA
REAC'TIVITY DATA Stsbility-No sponlaneous decomposition,not dangerouslyreactive.
Stability-Stable.
Compstibility-Material: Steel or stainless steel recommended.

Conprtibilig-Mrterisls: May attack some forms of plastics.
Cargo: Group 36 of compalibilitychart.

SPILL OR LEAK PROCEDURE Avoid contact with liqurd.Secure ignition sources.
Woar rubber gloves, soll-conteinedbreathingapparatus and protaciivs clothing. Ssure all sourcer ol ignltlon.
AbEorbwilh vermiculit€and clean up. Wash sit€ with soap and walsr.
ll r ry'tl occurl cdl tha Nrtloorl RcrDonr ( .ntcr,

ll L.ub I Untrsrorud
lf i rplll 'Nn. c.ll ahe Nrtionsl R6Donr Cctier, 8{X}-424-tt02.
LrftrlI
t; 1.19
27r
SCANNED BY MKP & BARIS,lA. 2004
TETRAETHLYENE
PENTAMINE TETRAHYDROFURAN
Synonynr- 1,1'l-Diamino-3,6,9-triazaundecano United Nrtions Number.......... ... _-?!_ Synonyru- Diethylsn€ oxid€; Fujan, tetrahydro-: UnltedNrtionr Nunber..............................'.
-245e-
Tetramethyleneoxide; THF
CHRIS Code.. ...... TTP
Fornuh-NH:(CH:CHxNH)rCH,CH,NH,
Boiling Point.. eeeoa aer"t Fomutr-(GHr)uO
Bollhl Polnt 66"C 150'F
AD!€arance.Odor-Viscous liquid; amine odor _'c _"F
Freezing Point -30'c 22"F Appanua-Odor-Colorless liquid; ether-lik€ odot --llFe:3
l'r6zln3 Pot't......... -t*-'F
Specilic Gravity-1.00 _'c _"F
SDGdncGrrvtty-o.8g _'c _'F
Vlpor Pressure 20'C (68'F)(mmH9.......... Low 142
Chemicrl Family-Amine (psir)........................... Low vrlpr PEurc 2I)'C(6E'D (mHd..........
ReidVaporPressure Ctcntcd FDlly-Ether 7.7
VaporPressure,16'C (115'F)(psi8).............Low R.ld V.!pr haurc (plr).........................
..
Pollution CsteSory-USEPA - IMO D V r p o r D € n s i t y ( A i :r 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .6. ...8. . . V.lpr Prosre {6'C (l15'F) (D6h)............. 8.5
PollutloDCrtcgo.y-USEPA C lMo D 1.35
V.Do.Dcntlty (Alr : 1.0)...........................
Applicrble Bulk Reg. il6 CFR SubchaDter........ O Solubility in Wster ,. Aoorsaable
Appllcrblc Bdl Rcf. {6 CFR Srbctqrd... O Sohblllty ltr W.iet Aoor€ciable

Grode-E: Combustible liquid
FIRE.} EXPLOSION HAZARD DATA
Electrical CrouD-C
Grrde-C: Flammableliquid
Eletrlcd Greup-C
Cenenl-When heated to decomposition, it emits toxic tumes ot nitrogen compounds.
cererd-Oangorou8 lire hazsrd; mod€rat€ explosion hrzard. Flashback along vapor trail may occur. Vapot may
explode it ignitad in an enclosad aroa.
F l e s h P o i n t ( ' n . . . . . . . . . . . . . . . . . . . . . . . . .3. .2. 5.
Flammsble LiDits..........................Unavailable
Fluh Pohi CF)....................6 .........
Autoignition Temp. ('n................ 572
trlumble Llmltr..........................
2.0 to 11.8'l.
AotolgnltlodTenp. ('F)................
610
Extinguishing A8cnts..................... CO:, dry chemical, alcohol foam
SDecial Fire Prcedures................ Firefighters should wear full-protsctM€ clolhing and self-coniain€d
Ertlngulrhlng A8etrtr.....................
COz, dry chemical, alcohol foam, water spray.
br€athing
aDoaralus.
SDsld Ftre Prueduq................ Gives off toxic lumes when heated. Provid€ respiratoryprotection for
firsfighters. Walor may be inetfective.
HEALTH HAZARD DATA

Hellth Hsard RrtirSs Odor Threshold(pDm) PEL,/TIVA (ppm) TLV,/TWA (ppn)
HEALTH HAZARD DATA
Hetlth Hs4d RrtirSs (Xor TbrdhoH (DpD) PEVTWA (ppm) TLVITIVA (pDtrr)
1,2,2 Unavailable Unavailable Unavailabte
Unavailabl€ 400' 200 200
General-Liquid causes severe eye and skin burns
Gqcrd-Liquid irritatingon @ntact. Vapor inhalation causes sev€re irritation ol mucous membraneswith strong
narcotic action resultingin severe headach€ and drowsiness.
Symptoms-Burningeyes and skin.
Symptomi-lrritation of 6y6s and mucous membranes;hgadacho or drowsin€ss.
Short Exlo|ure Toleruce-An 8 hour exposureto a saturated vapor-airmixturs caused no deaths.

Short ExIDsue TdemcFsoo ppm for 30 minut€s.
ExposurePreedw-Skin Erposue Prmedurs-Vapor-Iemove victim to tresh air; if breathing stops, apply artilicial respiration.Skin or
or eye conlact Bemove contaminatedclothing and gently llush atfect€d areas with
water lor 15 minules. Get medical attention as soon as oossable. eys contact-remove contaminatedclothing and gently flush attected areas with wat€r lor 15 minutes. Get
medical advice or att€ntion. Exposureto a potentiallydangerous vapor concontration can mcur belore the
producl is detected by smell.

Stsbility-Stable.
Strbility-May lorm explosive p€roxidos upon storag€ or sxposurs to light. Should b6 stabilized to prevmt
peroxids formation.
Compstibility-Msterisl: Avoid copper and copper alloys.
Conp.tibility-Mrterid: This compound dissolves rubber.


lf possibl€, wgar butyl rubber gloves, face shield or all-purpose canister respiratd, prolactivs clothing ll
possiblecovar spill wilh sodium bisulfata.Spray with water and wash up. west l|olyethylan€ glovaa, p|otectivs clothing and lace shield. Hav€ all-purpo$ canister mask availabl€.
Avod conhct wilh lhuid. Socure ignition sources.
lf I rplff osn cll thc Nrtlod nc.Donx Crntcr, 'm-a2ffil

It r dl m all tL Nralo.d lm C-i... &|.2r1-lto2.
lllrb: '
b*b: M)lf t).ltrlilt ffkx rr 0r.rlf, lh.n tho ILV ExFbruro to I potmtlrlty dangJOrJO vtpoa
(.sxlf,tlralln clr (x:(u lFlsr llE llrulu.l rr dcl(lcd by rnrll
2il
Ygi .-rs"- SCANNED BY MKP & BARIS A. 2004
TETRAHYDRONAPHTHALENE
Synonynr- 1,2.3,4-Telrahydronaphthalene; Telralin; United Nttions Number.. _-l_
I TOLUENE
Synonymr- Benzene, msthyl: Mathacrd€; Unltcd Natlom Number ... . . . . . .i.n. ! _
Totraln€; Tetrafr|p: Tetranap
Methylbonzene;Methylb6nzol;Phenylmethans;
I Toluol
('lIRlS Code................. ............___rat_

Formula-C'oHrz
Formulr-QH.CH.
I
Boilitrg Poin1....................... 206'C 402'F
Boiling Point................. 111'C 231'F
Apperrsnce-Odor-Colorless liquid; odtr Similar to _"c _'F
25'C -13'F Appeerence-Odor-Colorlessliquid;benzene-likeodor --
turpentine Frezing Point.....................
FrezinS Poini...............
gs"6 - rgg'r
Specific Gravity-0.98 _"c _'F
SpeciflcGrrviiy-0.87 _'c _'F
VaporPrsue 20'C (6E'F)(mmHd.......... Low
V a p o r P r e s s u r e2 0 ' ( r 6 8 " F ) ( m m H 9 . . . . . . . . . -
Ch€mical Frmily-Aromatic
Pollution CateSory-USEPA
hydrocarbons
-
Applicrble Bulk Reg. 45 CFR Subchrpter........
IMO C'
D. O
R e i d V a p o r P r e s s u r e ( p s i a ) . . . . . . . . . . ... . . . .0. .. .0. 2
Vapor Prwure 46"C (115'f.) (pair).............---Q!4-
v a p o r D e r s i t y ( A i r: 1 . 0 ) . . . . . . . . . . . . . . . . . . . . 4
s o l u b i l i t y i n w r t e r . . . . . . . . . . . . . . . . . . . . . .l.n. .s o l u b l e
...
. ...5. .5. . I Ch.nlcd Fmlly-Aromatic
Pollution Crte8ory-Usnpa- C IMo.

hydrocarbon
C'
ApplicableBulI Re8.45 CFR Subchapter........---D.9-
Reid Vapor Pressure (psia).........
Vapor Pressure 45"C tll5"F) tpsiat ........... ---1-.L
V r p o r D e n s i t y ( A i r : f . 0 ) . . . . . . . . . . . . . . . . . . . . . . . . .3 . 1 4
SolubilityinWater....................... Neolioible
ElectricalGrouD-D
I Grsde-C: Flammable
Electricd Group-D
liquid
General-Moderale lire hazard when exoosed to heat or flame.
F l s h P o i n t( ' n . . . . . . . . . . . . . . . . . . . . . .1. .7. 2. . . .

I Cenerll-Oangerous
flame.
fire haard when exposed to heat or llame; moderate
R s h P o i n i ( ' n . . . . . . . . . . . . . . . . . . . . . . . . .4. .5. .

explosion hazard when exposed to
Flmmrble Linits.......................... LEL:0.8'l.. at 100'C. UEL:5.0%. al 150'C. Flmmabfe Limits..........................1.27 lo 7.O"/o

Autoignition TenD.("F)................ 722 AuioiSnition Temp. ('n................ 1026
Extin8uishing Agents..................... Foam,carbondioxide,dry chemical ExtinSukhing A8ents..................... COr, dry chemical, foam, water fog
SpecialFire Prcedures................Water may b€ ineflective on fire. Fightthe same as a petroleumlire. The vaporsare more toxicthan those ot
Fire Preedures................
petroleum and should be avoided. A fire should be fought in the same manner as any Grade C flammable
petroleum product.

He8lth Hrard Ratings Odor Thr8hold (pDm) PEL,/TWA (Dpn) TLVAWA (Dpn) Hedth Hra.d R.tings Odor Thrshold (ppm) PEL/TWA (ppm) TLV,/TWA (ppm)
1, 1,2 Unavailable Unavailable Unavailable 1.1.2 0.17 100 100
G€neral-Vapor irritalingat high concentrations. slightly irritating,Vapor inhalalion has moderate narcotic effect causing dizzinessand headache,
with severe latigue and mental confusion.
SymDtomFvapor causes headache,vomiting,eye irritation,and coughing.Skin contact is iritating. dizzinessand headache. The victim may appear to be drunk.
Short ExDDsure
Tolerurce-Unavailable Exlnsure Tol€rance-lnhalation ol 600 ppm for 30 minutes has caused severe tatigue, mental confusion,
nausea, dizzinessand headache
ExDosurePrc€dures-lngestion-induce vomiling. Vapor-remove victim to tresh air; if breathingstops, apply Exlmure Prftedurs-lngestion-do NOT induce vomiting. Vapor-remove victim to lresh air; if breathing stops,
artificialrespiration.Skin or eye contact-remove contaminatedclothing and gently tlush aflected ar€as with apply artificialrespiration.Skin or eye contacl-remove contaminatedclothing and gently llush allected
water for 15 minutes.Get medical advice or attention. areas with waler lor 15 minules. Gel medical advice or attention.

Strbility-Fairly stablo but will, however,polymerizeand oxidize giving rise to discolorationand resinous Strbility-Stable.
material.
ConDdibility-Mrterld: Some rubber and plastics unsuitable. Conlstibility-Msterirl: Rubber exposed lo toluene will swell, soften, and deteriorate.Most metals are
comDatiblewith toluene.
C.rgo! Group 32 of compatibilitychart. Crrgo: Group 32 of compalibilitychart.

woar polyethyl€negloves. lecs shield, protoctivs clothing. Hev€ all-purpos€ canisl€r mask availablo. Avoid W€ar plastic gloves, tace shield, protectiva clothing. Have all-purpose canister mask available.Avoid contact
| {)nhcl fllh hqud Secure ignilton sourco8,
with liquid. S€cure igniiion sources.
lt a rall m[ crll thc Nrllorl n6Dn* ( cntcr. lXf{2/F8el2.

ll r spill rrccurs.crll thr \rtioul
l.Ih ' Poll"trrr (;rlogtry
C oil-llk.. 33 CFR 151.4e. llrnrrh: ' Pollulion
Calogory C orl-|ke, 33 CFR 151 .49.
I Ut[.a0rut "
Vatu Presaurei 28 mmHO st 25'C,
2rl
,l&- SCANNED BY MKP & BARIS nA. 2004 2tt
TOLUENEDIAMINE tl TOLUENEDIISOCYANATE
Synonyns- Eenzenediamine,ar-methyl-; Synonyms- Benzene, 1,3-diisocyanatomethyl-;
2,4-Diaminotoluene;
2,4'Tolamine; I f 2,4-Diisocyanatotoluene;
TDI; 2,4-Toluene
2,4-Toluenediamine;
4-m-Toluenediamine;
m-Toluenediamine;Tolylenediamine;
2,4-Tolylenediamine;
m-Tolylenediamine TDA
II :ii:::f::E;n:ff;11fl::"JflH,'^;i;1i,i,""r"
diisocyanate
CHRIS Code........... ....
Formula-CHrGHr(NHr): Formulo-H.CGHr(NCO)z
BoilingPoint.......................... 283'C 541"F I 251'C 484'F
App€rrsnce-Odor-Colorlesscryslals;ammonia-like I Appesrrnce-Odor-Clear.laintly yollow liquid, strong
odor F r e e z i n gP o i n t . . . . . . . . . 8S'C fgO'f pungentodof lrreerlngI'oint 19"C 57"F
Sp€cific Gravity-Unavailable SpEcificCrrvity-1.21
I V|]Dr Prilurc 20'C (68'n (mmHg Low
chemicrr
Famiry-Aromatic
amines . f
Htr'":;::"i..""3l;:,,ff"T].illl3-:..... I
Chemical Fenily-Aromatic isocyanato Rcld Vrgor prdur. (p3la).......... ... .... Low
Vrpnr Prtssurc 46'C ( l l5't-) (psir) . Low
- vapor Pre$ureil6'C (lls'F) {psis)............. t I
PollutionCrtegory-USEPA A C Pollutim Crte8ory-tlSUPA B tllfO ---.Q- t,rix)r t)onilry (Air . 1.0) ..... .......... 6.0
IMO vrpor Drnsity(Air : 1.0)....................... f
ApplicrbleBulk Reg.46 CFR SubchrDter
........ O Solubilityin wrter........................ Soluble Applleblc Bult Reg. il6 ( |lR Subctader . O solubility in wrter .................... Reacts
E: Combustibleliouid
FIRE & EXPLOSION HAZARD DATA I Crade-E
Electricrl
(iombustibl€ lrqurd
(;rou}-D
FIRT] & I]XPLOSION HAZARI) DATA
Electricil Group-NA
Toxic Aases,NHr, CO, oxides ol Nitrogen,released by high temp€ratureor combustion.
Flssh Point ('F).............................

284
I cenerrl-Highly toxrc nttrog€n doxrde gas rs produced wheo th6 product burns.
! ' l N h P o l n t ( ' D . . . . . . . . . . . . . . . . , . . . . . , , .2. 7

. .0.
Flsnmsble Limits.......................... Unavailablo !'hmmsble Limits . .. 0.9 to 9.5olo
Autoigtritior TenD. ('F)................ 842
Extinguishirg A8ents.....................
Special Fire Prmedurc................
Water, COr, foam
Use complete proteciive clothing and selt-contained breathing apparatus.
I A u t o i g n i t i o nT c m p . ( " D . . . . . . . . . . . . . .a.b o v e 3 0 0
Extinguishing Agents....... . ..
Special l-lre Prcedure................
water to get inlo a tank ol toluene diisocyanale.
CO,, dry chemical, watgr log
Provide tiretighters with lull body and respiatory protection. Do nol allow
HEALTH HAZARD DATA

Health Hrud Rstingr Odor Threshold(ppm) PELITWA (ppm) TLV,/TWA (pDm) Health Haard RatinSs Odor Thrcshold(ppm) PEL,TTWAtppm) TLVAWA (ppn)
Unavailablg
syslem.
Genersl-Suspected carcinogen.Causes thermal burns in molten state. Toxic to the liver and central neryous I 3, 3, 4 0.4 0.005 0.005
ceneral-Suspected carcinogen.Liquid extremely harmful by skin absorption. Vapor inhalationseverely irritating
to nose and throat. Repeatedexposure to low concentrationcan lead to respiratory
dermatilis.
problems and severe
Symptoms-lrritationand blisters upon contacl. Symptoms-Burningat site ol conlact. Vapor inhalationcauses intense irrilation ol nose and throat. Inhalation
Sho.t Exlnsure Tolerance-LCsofor rats in t hour was 5.3 mg/l. I can also cause asthma-likesymploms, which may not appear for several hours atter exposure.
Short ExposureToleranc*O.S ppm are irritatingto nose and throat lor briel exposures.
ExposurePreedures-lngestion-do NOT induce vomiting. Vapor-remove victim to fresh air; il breathing stops,
ExDGureProcedures-Removeto lresh air, adminislerartificialrespirationor oxygen as necessary.Flush eyes apply artificial respiration.Orygen, administeredby trained personnel, is often helpful. Skin or eye
thoroughlywith water for 15 minutes.Wash skin with luke warm. not hot waler.
I contact-immediately llush aftected parts gently with water while removing contaminatedclothing. Continue
to tlush lor 15 minutes.Get medicalhelp promptly.
See MedicalKit Information,
AppendixB
Stebility-
REACTIVITY DATA
I REACTIVITY DATA
stsbllity-Product will react with water and even the moisture in the air in excess ol 100 ppm, evolving CO,
and heat. Can react violently with amines, alcohols and acids.
('onprtibllity-Material: Stainlesssteel, nickel and aluminumare satisfactoryconstruction materials.Avoid
I
Con!.tlbtlity-Mrt€risl: Incompatiblewith aluminum,copper, zinc, brass and bronze,
copper and copper alloys. Mild steel may be used if it is clean and entirely tree ol rust and moisture.
Crgo: Group I ol compatibilitychart Crrgo: Group 12 of compatibilitychart.
SPII,T,OR I,EAK PROCEDURE

I SPILL OR LEAK PROCEDURE
Woar butyl rubber glovor, proteclivo cloihing, sell-contained breathing apparatus, protective shoes. Avoid
Fvacurlo rral Avoid conlacl with hot lrqurd Wear lull prol€clive squipmonl and sell-conlarned broathhg
.l!).rrhrt (:onlaln f,ptll rnd allow lo soldrly Scoop Inlo drarns.Rinss down aroa with wal€r Provonl enlry Inlo , (rrltcl wrlh lho hqurd Ke6p unprotecisd p€rsonnel away lrom spill area. May mix with vermiculile, sodium
wt 0f rdf, corrot I r, rtlx)rr{|r,.rr rond Pcck trr (a.dbo6rd box end burn in op€n pit using crumpledpaper and wmd splintersas
r.,.,1 Wnrh itkr wrlli i{ttl) er)hllr)n
lf r ulll rrcun, c.ll th. Nrtlnd ( It i.plll r{'oh, c.ll ih. Nrtl|rnrl R$pon8e Ccntcr,
r',nrnurn
I
l.el. v.t,, I ih"rltg 6t tO/ l
'tr!aradalro
{ lrra.}tt!,
u-;=-ftr*-"*--
Ita SCANNED BY MKP & BARIS :11
A. 2004
1,1,l.TRICHLOROETHANE
1,2,4-TRICHLOROBENZENE
Synonyms-Chlorothene; Ethane, 1,1,1-krchloro-; Unitcd N.tions Nunber........ 2831
Synonyms- Trichlorobenzenes, liquid; United Nrtions Nuhber........................,.,.,,.. 2321 Methyl chloroform; 1,1,1-TCE
unsym-Trichlorobenzene; 1,2,4-Trichlorobenzol
C H n I S ( ' o d c . . . . . . . .... . . . . . . . . . . . .... . . . . . . . . . . . . .T. C E
Fornule-CHrCClr
'74' C 165"F
Fornule-C5H3Cl: B o l l l n t I ' o | n t . . . . . . . . . . . . . ........ . . .
Boiling Point ... 213"C 415'F ADDcnne-Odor-Colorl€ss lrqurd:sweetrsh, __'c _'F
ApDear.nce.odor-Colorless liquid; aromalic odor chloroform.likeodor Irrcrirt Pohi... 2'C 36'F
Freezins
Point......... 18"3 *:F SD€cttlcCrrvlty-1.46
SD€cific Gravity-1.45 -"c -'F ! ryrr I'rctsurr 20"(' (6E'n (mmHg).......... -i..gQ-
Vrpor Pressure 20'C (58'F) (mnHg)..,....,.. --l-!- Chemlol FrDlly-Halog€natad compound R r i d \ i l p o . I ' r e s s u . r ( p s l . ) . . . . . . . . . . . . . . . . . . . . . . . . .4. .. 0
C'hemicd Frmily-Aromatic halocarbon Reid Vapor Prdsure (Dsir)...........................
---t9!!- V r p r I ' r c r s u r c , 1 6( ( ! 1 5 " D ( p s i s ) . . . . . . . . . . . . 4 9
vspor Prsure 46"C (115'F) (psir)............. ---!91!- PolluttonCrteSory-lrst, I'A- -, Q lNt(r. - !-- V|'or tX'nrity (Air t.Ot. . .................... 4 6
Pollution Category-USEPA B IMO B vsporDensity(Air : 1.0)........................... 6.26 Applloblc Bull Res.,16( t R sub{hiptcr O. " - solubllity in Wrtcr Neoliaible
ADplicsble Bulk Reg. 45 CFR Subchrpter........ O Solubility ir W8ter lnsoluble
I.'IRE & T]XPI,OSIONHAZARD I)ATA

FIRE & EXPLOSION HAZARD DATA Grrdc-None assigned,
Combustibleliquid Eletrlcrl Group-D
Electricrl Group-O
crrl-O@s not burn rsadily bul can produce 6 dangorous "ll6sh" whgn vapors are exposed to a
fire hazard wh€n expossd to h€at or llame. Gives ofl hydrogonchlorids gas. high-energyspark sourcosIn a conlnod spaco.Whon In conlacl with hot metal or a llame, methyl
chloaolorm can d€composo to knrn phosoono, whrch rs hrghly toxic.
Fluh Pohl ( Ir) . .. Unavarlablo
F l s h P o i n t ( ' D . . . . . . . . . . . . . . . . . . . . . . . . .2. 3. .0. Fhnnrble l,imits 7 lo 1696 (approximato value lor llash describ€d above)
F l a m m a b l eL i m i t s . . . . . . . . . . . . . . . . . . . . . 1 . ...3. t o 7 . 1 % Autoignitlon T.mp. ( l)......... . 932
Autoignition Tenp. ("D ................1'l 80 Extinguirbing Agcnts ........... Dry chemical. loam or CO1
ExtinSuishing A9erts.....................Carbon dioxide, dry ch€mical or toam Flre Prcedurcr.,.,....... W€ar eyo protection,s€ll-containsdbreathingapparatusand protective
Special Fire Pr@ed[r6................ Wat€r spray may b€ us€d to control small tir6. Cml exP6€d tanks wilh clolhing
water. Wear seltcontain€d breathing apparatus.
HEALTH HAZARD DATA

HEALTH HAZARD DATA Hqlth Hurd Ratings Odor Threshold(ppm) PEL,/TWA (ppm) TLV,/TtryA (pDn)
Heslth Haard Rrtingc Odor Threshold(pDm) PELAWA (ppn) TLVAWA (ppn) 1 , ' 1 ,2 100 350 350
1,1,2 3 5 5 G€ner8l-Vapor inhalationgives moderate irritation ol air passages plus moderate narcotic etlect. Prolongedor
General-Moderatelytoxic by ingestionand inhalaiion,superficialburns to the skin. repeated skin contact may cause defatting ol the skin and may produce dermatitisfrom daily contact.
Symptoro-Dizziness, headache,nausea, and drowsiness.

symptom$-Repeatedexposure can lead lo liver, kidney, spleen damage.Coughing,watering eyes.
Short ExDosureToleranc*l500 ppm
Short ExposureTolermce-Animal sludies have shown that 756 mg/kg killed 50% of the population,etfecling
the liver, kidney and spleen.
ErposureProcedure-Vapor-remove victim to fresh air; it breathing stops, apply artiticial respiration.Skin or
ExposurePrmcdures-Skin and eyes-llush atfecled areas with plenty ol water. Vapor-remove victim to fresh eye contact-remove contaminaled clothing and gently llush affecled areas with water for 15 minutes. Get
air. lf conscious,have victim take water or milk and induce vomiling it swallowed.Administerartificial medical advice or attention.
respiralionit necessary.Call a doctor.
REACTIVITY DATA
REAC'TIVITY DATA Strbility-Begins to decompos€ at 350'F. May decompos€ to hydrogen chloride and other toxic products
Stability-Stable.
ComDrtibtltty-Miterial: The uninhibitedgrade is corrosive to aluminum,although the inhibitedgrade may be

Comprtibility-Materid: Most rubbersare not compatible used with aluminumand any common construction melals at temperaturesup to 175'F.
Cargo: Group 36 ot compatibilitychart. See also Appendix l-Excaplions to the Chart.

CargorGroup 36 ol compatibilitychart.

SPILL OR LEAK PROCEDURE Weer rubb€r glo\ros and protective clothing. Avoid contact wilh liquid. Securs ignition sourcas.
Wear plaslic Alov$, sell-contain€d br€alhing apparalus, prolectivo clothing. Absorb spill with vormicu||l'r.
a(xlum brcarbonalc,o. 8oda aoh.tand mixlure ( 10-80). After absorplion ot spill ih€ mixlure may ba p|cbgo(t ,',
, if(lborrd conlarmn rnd burnad in an op€n pit. Wash site ihoroughlywith slrong soap solution.
lf e dll qrn, c.ll ahe N.ilonrl R6Dome Center, t(x)-424-tt02
r ' lfE ( (rnnwclrl
ll6*hr hhrbitcd p(xtucl has I boiling range of 160-190'F
"
thro{.daldl. Irlio 2. 40 (ll ll 153
287
216
1,l,2.TRICHLOROETHANE TRICHLORETHYLENE
synonyms-Elhane trichloride: Ethane, 1,1,2-trichloro-: United Nations Number....................
......... f Synonyms-Chlorylen; Eth6ne,trichloro-;Ethinyl UniiedN.tlons Number....................
. 1710
beta-T; 1,1,2-TCE; beta-Trichlorethane; Vinyl , tflchlorido; Elhylene lrichloflde,Tn; Tilchtoroethgns
trichloride I
CHRIS Code
I ( ltRtS (i,de ............ TCL
Fornula-CHzCICHCI: l'ormuh-C|HC CCL

BoifingPoint.......................... 114"C 237"F I noilins Polnt iZ'C 189'F
Appearance-Odor-Colorless liquid; sweel, no*"rrnce-()dor-colorless hqud chlorolorm-hko
odo'
Frezingpoint.................
----:3gtE:tF I lirrt.rins pornr.... ar]3 ,^'"1,
chlorolormlike odor
SDecific Gravity-1.43 at 25'C Specific Grrvlty-1.47
-.t€- ''ll'- -Zt-
chemicar
r-amily-chrorinared
hydrocarbon l:il'"il:ru::"11;:,tll,j]1"":1 . . I chemicsr
Frmily-Harosonarod
compound nfl"-#$::"lil ljlril
Vapnr Pressure,l6'C (lt5'n (Dsia).............-----I- VeDorPiilure 46'( (lls"F) (Dcl.). . 35
rI P o l l u l i o n( s t e g o r y - l i s l l l , l
-
B lM()
-
B
Pollution Category-USEPA. B IMO- B vspor Density (Air : 1.()).......................... 4.55 Vrtnr DcElty(Air 1,0)................... 4.54
Applicable Bulk R€g.46 cFR subchapter O solubility in w8ter...................... 0.45olo at 20'C ApplicableBull Reg.46 ( llR subchrpt('r O solubilityIn wrter . Neqlioible
FIRE & EXPLOSION HAZARD DATA I.'IRI.]& EXPLOSION HAZARD DATA

Grade-None assigned Gnde-None assign€d.
Eletrical Group-D Iiletrlcel Group-D
ceneral-Very low degree ol tlammability.Normallywill not burn, bul will in lire of olher luel or with strong Gcnerrl-Although trichloroethylensdoes not ignile readily,it can flash under certain conditions.A high-energy
initiator(large spark, welding torch), will give off toxic and itritatinggases, includinghydrogen chloride, ignition source is one ot the necessary tactors. The liquid or vapor on contact with hot metal or a flame
chlorine,and/or phosgene. can decompose to lorm phosgene,which is highly toxic.
FlashPoint ('F)............................. None measurabledue lo low degreeol combustibility F l N h P o i n tC D . . . . . . . . . . . . . . . . . . . . . P
. . r. .a.c. .t.i c a l lnyo n j l a m m a b l e
F l o m m e t lLei m i t s . . . . . . . . . . . . . . . . . .6. .t.o. . 1
. .5. . 5 % Flammable Limits.......................... Variableat high temperatures
Autoignition Temp.('F) ................ Unavailable AutoignitionT€mp.('F)................ 770
Extinguishing Agents..................... Dry chemical,foam,CO: ExtirSukhingA9en8..................... Dry chemical,carbondioxide,or loam
SpecialFire Procedures................ Cool exposed tanks with water. Provide respiraloryproleclion tor lire parties SpecialFire Procedur6................Tanks should be c@led by a water spray to prevent vaporization.Wear eye
protection, self-containedbrealhing apparatus and protectiveclothing.

Health Haard Ratidgs Odor Threshold(Dpn) PEL,/TWA (pDm) TLV,/TWA (ppn) Hedth Haard Rstings Odor Threshold(pDm) PEL,/TWA (ppm) TLv,/TwA (ppn)
Unavailable Unavailable 1o/Skin 1o/Skin 1.1.2 50 50 50
G€neral-Suspected carcinogen.Very toxic, much more so than 1,1,1{richloroethane.Central neryous syslem Generrl-Suspected carcinogen.Vapor inhalation leads to slight irilation ol aiMay with moderate systemic
depressent.Toxic to liver and kidneys.Prolongedor repeated skin contact may cause defatling of the skin etfect. Prolongedor repeated skin contact may cause defatting ol the skin and may produce dermatitislrom
and may produce dematitis from daily contact. daily contact.
SymDtoms-Eyes-rrritation,discomforl,soreness.Skin-irritation. Inhalation-irritation, drowsiness, Symptoms-Headache,nausea, eye and lhroat irritalion,drowsiness,
unconsciousness.Ingestion-headache, lassitude,coma.
Short ExposureTolersnce-Short term exposuresnear 2000 ppm cause central neruous system depression,
distorts equilibrium l l Short ExposureTolerance-150 ppm for 30 minutes.
ExDmurePrcedures-Eye-flush with water for at least 15 minutes,call physician.Skin-wash with soap and ExposurePr@edures-Vapot-remove viclim to fresh air; if breathing stops, apply artilicial respiralion.Skin or
water tor at least 15 minutes. Inhalation-remove to fresh air, give oxygen or artiticialrespirationas needed. eye contact-remove contaminatedclothing and gently llush affected areas with water for 15 minutes. Gel
Ingestion-callphysician. medical advice or attention.

slable; decomposeswhen heated. Beacts with strong oxidizers,strong caustics,and active Stability-ln the presence of a strong alkali it reacts to form a gas which will ignite or explode spontaneously
metals to cause fires and exDlosions
-Msterirl: Attacks some plastics,rubbers, coatings. Fieactswith aluminum. ComFtibility-Mrt€rid: Stabilizedlrichloroethylenemay be used in the presence of air, water and light with
any ol the common construction metals at lemoeratures uD to 248'F.
Crrgo: Group 36 ol the compatibilitychart Cargo: Group 36 ol compatibilitychart. See also Appendix l-Exceptions to the Chart.

Woar proloclNo clothing, s€lf-coniained breathing apparalus, and tull tacs shield. Stop raloase, dik€ sprll, W€er rubb€. gloves, protective clothing, sell-conlained breathing apparatus.Avoid contact wilh liquid.
collocl wrlh Inerl absorbanl, disposo in ganitarylandlill.
lt I dll $(ur[ crll th. lf . NDill ccrn. sll ahe N.tionrl Resmtrse Clenler. 800-42!L8802.
l.sl.r I trmvtlabb Rrnrrlr:
I
llrl .18.1
ry; 'S&49rii&uJ&''*',."-- -..
1.2,3.TRICHLOROPROPANE TRICRESYLPHOSPHATE
Synonyms-Allyl trichloride; Trichlorohydrin; United \-rtions Numb€r Synonyns-o-Cresyl phosphate;Phosphoricacid, UnitedN.tion! Number...>3oloortho 2574
Trichloropropane tris(methylphenyl)ester;TCP:TOCP;
Tolylphosphate;Tra-o-cresylphosphate;Tri-o-tolyl
phosphat€; Tritolyl phosphat€
. <1oloortho isomer _IQe_
CHRIS Codc...........
17oor more ortho isomer TCO
Fornula-CHrCl-CHCI-CHrCl Fornulr-(CHsQHr)rPOr
B o i l i n g P o i n t . . . . . . . . . . . . . . . . . . . . . . .1. .5. 7 ' C 315'F 410'C 77O',F
Bofflnt Polrt......
Appearance-Odor-Amber liquid; chlorolorm-like odor -t A4mmc.Odor-Coloflo$ liqurd:slight odo. -stZ
Frezing Point......... s'c sg'p -rs"i
l'r€zfng potnt.........
Specific Gravity-1.39 _"c _'F SDoclnc
Gr.rlry-l.17 _'c _'F
VaporPressure 20'C (68'n (mmHg).......... ---ll- Vrpor I'ressure20'C (68"F)(mmH8)........ V. Low
Chemical Fanily-Halogenated hydrocarbon Reidv.por Presure(psia)........................ .. 0.11 C'hcmicdl'rFlly- Reid Vrpor Prilure (p6ia).... . ................ t
vaDorPrssure 46'c (115'F)(Dcir).............0.15 Vrpor Prruurc 46'C (fl5'F) (Dgir)............. V. Low
Pollution Cstegory-USEPA - IMO B v a p o r D e n s i t y ( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . 5. ...6. . . PollutlotrCrtGlory-USHI'A - lM() - A v r D o r D e n s t t y ( A l= r 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .1. .2. 7. . .
Applicable Bulk Reg. ,16 CFR SubchlDter........ O Solubility in Water <o.54" Appllcrble Bulk Rc8,il6 ( t.R Subchrpier O
- S o l u b l l l t iyn W a i e r . . . . . . . . . . . . . . . . . . . . . . N
. . .e o l i o i b l e
Crade-E: Combustibleliquid (;r.de-E: Combustibleliouid
ElectricalGreup-D Elctrlcd Group-D
General-Moderate lirc hazatdi releasestoxic HCI and other chlorideswhen heated. Gcnod-Slight hazard when exposed to heat or llame. vvill decompose ai extremely high temperatures
releasing toxic PO. gases.
l'lsshPoirt CF).............................
174 F l s h P o i r t ( ' n . . . . . . . . . . . . . . . . . . . . . .4. .3. 7. . . .
FfsmmfbfeLimitr..........................
3.27 to 12.6o/. FhmmrbleLimits.......................... Unavailable
AutoignitionTemp.('F)................579 AutoignitiorTenp. ('F) ................ 725
Extinguishin8A8ent8.....................
Waterlog, water blanket,COz,loam, dry chemical ExtinSuisbirg A8ents..................... COr, dry chemical
SpecialFire Prmedurg................Wear sell-contalnedbreathingapparatus. Fire Prcedurd................ Waler may be ineffectiveon tire. Cool exposed tanks with water. Wear
prolective clolhing, goggles or lace shield and sell-containedbreathing apparatus

Hesltb Hrard Rating! Odor Threshold(DDm) PELAWA (ppn) ILV,/TWA (pDm) Heslth Heard Ratln8r Odor Thr6hold (ppm) PELAWA (Dpm)
'10 TLV,/TWA (ppm)
Unavailable 5 1o/Skin 1,0,4 Unavailable Unavaitabte O.Oi/Skin
cencrd-Can cause permanont injury. (;ererrl-Vapor slight haard due to low vapor pressure. Liquid extremely loxic when ingested.
SymptoeSkin-irritation, dermatitis,blistering.Ey$-watering, permanenl iniury. Inhalation-anesthesia, may irrilale eyes at high lemperatures.Ingestioncauses severe damage lo central neryous
irritationol respiratorytract, moderate narcotic ettects, drowsiness,dizziness. syslem.
Short ExposureTolermce- Short Exlmure Tolemce-Unavailabte
ExDosur€Procedures-Get medical attention.Contact-flush eyes and skin with water. Inhalation-remove to ExposurePruedures-lngestion-induce vomiting and catl a physician.Skin or eye contact-for eyes flush with
fresh air. lngestion-induce vomiting il conscious. water tor 15 minutes;lor skin, wash with soap and water.
REACIIVITY DATA REAC:TIVITY DATA

stable. Decomposeswhen healed, may decompose in contact with aluminum,reacts -Stable. Can react with oxidizing materialswhen heated to decomposition.
vigorouslywith oxidizingmaterials.
Swells rubber. Suitable:Steel. Unsuitable:Aluminum. Competibility-Material: Usual materialsof constructionare suitable.
Cargo: Group 36 ol compatibilitychart Cargo: Group 34 of compatibilitychart.

Avoid contact. Wsa. goggle8,rubber gloves, and s€lt-containedbreathingapparatus.Absorb with aand. War prot€ctive clothing, gogglss or tace shietd. Remove ignition surces.
Ia I rDlll ecu|. oll thc Nrtlold a tDlll trcurs, c.ll the Nrtlonrl R$potrN. Center, td)-424-EE02.
Ln.rl.r |(r^rvrthblo L.s.l.r I trnrvll.blo
I
200 201
lryr*-"4s,it{Crytr*...,-
TRIDECANOL I.TRIOECENE
syrcnyns-Alcohol C-13; lsotridecanol; lsotridecyl United Nrtions Nunber........................ I Synonyro- Ol€fin C-1 3: Undecylathylene IJnlled Nrtions Numbe]
alcohol; Oxotridecyl alcohol; l -T.idecanol; Tridecyl
alcohol
('llRls (]ode. ............... . . . . . . . . . .. .. . . . . T D C
Formule-CrzH:rCHrOH Fornulr-CHr(CHz)r"CH CHr

274"C 525"F B o l l l n g P o l n t . . . . . . . . .... . . . 233'C 451"F
Boiling Polnl ...
ApDesrrnce-Odor-Water-white liquid wilh pleasant
oa
-
qc
Appeerence-(Xor-Colorlsss liquid with 8 mild plsasant _'c _'F
g7'f ooor l ' r c e r l n g P o i n 1 . . . . . . .... . . . -24'C - 11"F
alcoholic aroma Frezin8Point......... . ... 31'C
Specific Grrvity-o.85 _'c _'F Specific (,;ruYlay-o.77 _'c _'F
VaporPressur€ 20"C(58'F)(nnHd).......... Low V.Di)r I'rflurc 20"C (68"t) (mmHg).......... ---tQ!lL
Chemicd Family-Alcohol Chemlcrl lrnlly-Olelrn R c i d \ r p o r P r * u . e ( p s i s ). . . . .. . . . . . . .... . . . . . . . . L o w
ReidVaporPresoure (psis).. . ... ................ Low
Vlpor Pressure il6'C (tt5"F) (psir)............ Low V.por I'resure il6'C (ll5'F) (psir)............. Low
lll Pollutiotr Crlegory-t rsl:PA - 111'19 lll V.!x,r l)enrliy (Alr l.0l
Polltrtioncatcgory-UsEPA.- IMO- Vtpor Deosity(Air : 1.0).......................... 6.9
ADplicable Bulk Reg. 46 CFR Subchrpter........ D S o l u b i l i t y i r W a t e r . . . . . . . . . . . . . . . . . . . . .N. .e. o l i g i b l e Applicrblc Brlk Rcs. 46 ( l R sub.h.pter D Solubility in water........ Insoluble
( ;rrde-E: Combustible liquid
crlde-E: Combustible liouid
Elstricel Group-D I'lcctrical Group-D
(;enerd-Modsrate lie hazard if exoosed to heat or flame.

ceneral-Slight lire haard when exposed to heat or flame.
n s h P o i n t C n . . . . . . . . . . . . . . . . . . . . . . . . .2. .5. 0. I , l a s h P o i n t ( ' F ) . . . . . . . . . . . . . . . . . . . . . . . . -. .1.7. .5

FlMmble Limits.......................... Unavailable l l a m m a b l e L i m i t s . . . . . . . . . . . . . . . . . . . . . .U. .n. a. v a i l a b l e
Autoigrition Temp. ("F)................ Unavailable Autoignition Temp. ("F)................ Unavailable
Extingutuhir8 A8ents..................... Alcohol foam, water spray, dry powder, COr llxtinguishing Agents..................... Dry chemical, Ioam or COl
Specid Fire Prcedures ................ Wat€r or foam may caus frothing. Special l'ire Prcedur6................ Water may be ineffective on lire. Cool exposed tanks with water.

Heslth Hurd Rstings Odor Threshold(ppm) PEL,/TWA (pDm) TLV,/TIVA (pDm) tleslth Haard Rstings Odor Threshold(ppm) PEL,/TWA (ppm) TLV,/TWA (Dpm)
0.0. 0 Unavailable Unavailable Unavailable Unavailable Unavailable Unavailable Unavailable
(;eneral-Data are lacking; however, it appears that the 1-Trideceneis r€lativelynon-hazardous.
G€rcrsl-Possibility ol some adverse etfects from liquid contact with skin.
SymDtomr-lnhalationhazard is slight. Skin contacl causes minor iritation. Eye contacl causes svere irrilation. symptomFUnavailable
Short Expqure Tolemce-Unavailable Short ExposureTolerance-Unavailable
Exlnsure Pr@edures-Vapor-remove victim to tresh air; it breathingstops, apply artificial respiration,Skin or ExposurePreedures-Liquid may irritate lhe eyes. After skin or eye conlacl, llush with water for 15 minutes.
eye contact-remove conlaminatedclothing and genlly wash aflected areas with wator.
REACTIVITY DATA REASTIVITY DATA

Strbility-Stable. Stability-Stable.
( i,mpstibility-Materialt Usual materials ol construction are suitable.

ComDatibility-Mrt€ri.l: Aluminumunsuitable.
Crrgo: Group 20 of compatibilitychart. Crrgo: Group 30 of compatibilitychart.

Avoid contacl wilh liquid.Secu.e ignition sourc€s. woal rubb€r glovea, lac€ shisld, protective clothing. Have all-purposecanister mask available.Secure ignition
ti(xxco9
lt | .Dlll eu|' crll the Nrlionrl RoDou C6Lr, t@{r+lm2 lf r iglll ftcun, crll thc Nrtiond Rerrcnse Center. t0O-42,1-Et02.
lerrrb; llerrl] l(hr6rr{trnd

I Unlmlgnod

lel 2q3
TRIETHANOLAMINE TRIETHYLAMINE
Synonyms- N,N-Oiethylethanamin€; TEN (lnltcd Nalions Number 1296
SynorymF2,2',2'LNitrilotriethanol;TEA;
Trielhylolamine;Tri(hydroxyelhyl)amine;
Tri(2-hydroxyethyl)amine;Trihydroxytriethylamine;
Tris(hydroxyethyl)amine;Trolamine
( llRlS (bde TEN
Fornuh-(HOGHT)rN !ormulr-lCrlir)rN
343'C 650'F RoilinS l'oint.. 89'C 132"F
Boiling Point..........................
ADperrrnce-Odor-Colorless,oily laquid;slight _'c _'F AtDc.rrncc-()do.-Colorless lqurd; ammoniacal odor _'c _"F
19'C 68'F F.eering Point 115"C 175"F
ammonia-likeodor Freezing Point...-....-.........-.-... "c 'F
'c Spcclllc Grrvlty-O.73
SpecilicGravity-1.13 _'F
Vapor Presure 20'C (68'F) (nmHO.......... ---LQ!lL- Vrpor Pressure 20'C (5t'F) (mmHg..........--5.3J-
(:hemlcrl l'rmily-Amino 2.3
Chenicsl Frmily-Amine ReidVaporPresure(pcir)...........................Low Reid valpr Presur€ (psia)............ .
VrDor Pressureil6'C (115'F) (Dsis).............
---L9!-- Vrpor Presure 46'C (lt5'n (peia).............---21-
D Potlutlon CraeSory-USEPA D IMO C vspor Density(Air : 1.0)............... .. . 3 49
Pollutior Crtegory-USEPA - IMO VrDorDensity (Air : 1.0)...........................14
5
Applioble Bulk Reg.,16CFR Subchspter........ O SolubilltyinWater.........................ComDlete ApplicebleBull Reg.,16CFR Subchapter.... . O Solubility in Wrter Slioht
Grade-E: Combustibleliouid Crode-C: Flammable liouid
Electriql GreuF-C Electricsl Group-C
Gencnl-Slight hazard,when exposed to heat or flame. The oxidaiion products are poisonous. Genenl-Dangerous, keep away from heat or open flame. Flashback along vapor trail may occur. Vapor may
explode il ignited in an enclosed area.
I'lsh Point Cn.............................

365 R s h P o i n (t ' F ) . . . . . . . . . . . . . . . . .2. 5. . . . .
Flammable Limits..........................
Unavailable FlanmableLimits.......................... 1.2 lo 8.O"/"
Autoignition Temp.('F) ................
Unavailable AutoiSritiotrTemD.("F)................ 842
Extinguishing A9ents.....................
COr, dry chemical,alcoholfoam,water fog Extirguishir8A8etrts..................... Alcoholloam, COr, dry chemical
SpecialFire Prcedurg................ Ksep tanks cool with a spray of water. Provide respiratoryprotetion lor lire SDeid Fire Prcedures................ Use water to keep fire-exposed
containerscool. It a leak or spill has not
oarties. ignited, use water spray to disperse the vapors and to protect personnel attempting to stop leak. Water
spray may be used to flush spills and to dilute, rendering non-flammable.
HEALTH HAZARD DATA HEALTTI HAZARD DATA

Herlth HMrd Rrtitrgs Odor Threshold (ppm) PEL,/TWA (ppn) TLV,/TWA (ppn) Heslth Hrdd Rrtings Odor Thrcshold(Dpn) PEL,zTWA (ppm) TLV,/TWA (pp6)
0. 1. 1 Unavailable Unavailable Unavailable 2,2,2 Unavailable 10 10
General-Liquid causes irdtationand burns to skin and eyes on conlact. Generrl-Liquid dangerouslyabsorbed lhrough skin. Vapor inhalation harmlul. lt is one of the most severe eye
irrilants and perman€nt iniury may tollow eye contact despite prompt treatment efforts.
SymptomFllching or burningof skin at site of contact. ll inhaled,the respiratorypassages will be iritatsd. Synptoms-Liquid causes eye iniury and skin irritation.
Short Expsure Toleruc€-Unavailable Short Erpcure TolersncFLess than 100 ppm tor humans for 30 minutes. A 4 hour exposure was lethal to 1/8
of rats tested.
ExposureProcedureWash spill trom the skin with water. lf liquid has splashed in the eyes, wash them with ExposureProcedures-ln case of contact with eyes or skin, immediatelyflush with plenty ol water f6r al least 15
water for I 5 minutes and get medical attention. minutes; for eyes, get medical attenlion. Bemove contaminatedclothing and shoes at once.
REAC]TIVITY DATA REACTIVITY DATA

St.bility-Bogins to decompose at 450'F. Stlbility-Stable.
Compriibility-Mrterisl: Copper and its alloys are corroded. Copper and its alloys are incompatiblewith triethylamine
Cugo: Group I of compatibililychart. See also Appendix l-Excsptions to lh€ Chart. Cergo: Group 7 of compatibilitychart.

Wear butyl rubber glovss, protectiveclothing. Avoid contact wilh liquid.Co\rgr spill with sodium Ulullalc. ll possrble,wear bulyl rubbor gloves, face shield or all-purposecanister respirator,and tull-prot€ctfuaclothing
'iocuro rgnrlronsource!. Cover spill with sodium bisulfat€. Spray with waler and wash
Spray with €xcess water and wash up. Wash area wilh soap solution. up.
Il r rplll ccurr, c.ll thc Nrtlonrl Rdgonic ( enlcr, tllt{ra.al02. lt. dll Gs+ cdl rbc Nrtlotrd lrrou Crrter, tlXL4jl4-tll02
Pltlly lo lowsr th€ hrgh lro€urng pornt, lh€ commercrsl producl is a mixture ol tnelhanottmlm L.-!lrl
L.ilrh: wlth t?
lo ?5\ drolhanolamrno and 5',i alharc||minc, Th€ resulltng m[lura will hrve propcrlf,r lhrl vrry
rrnowhtl koil! lhoto ihryn.
I Unarlgn d

2e4 lqt
ibe4{&s**"-*.
TRIETHYLBENZENE TRIETHYLENEGLYCOL
Synonyns- 1,3,5-Triethylbenzene;
sym SynonynF Oi-b3la-hydroxyethoxy€than€: 2,2',Eihylene t inlted Nrtlo[ Number....................
Triethylbenzene dioxybis(elhanol);2,2'-Ethylen€dioxydrethanot:
Ethylene glycol dihydroxydi€thyleth€r; ctycol
bis(hydroxyethyl)€ther:TEG: Triglycol
( llnls (ide.......... .. TEG
Fornula-CeHr(CHzCHr)r t'ormulr-(CHzOCHTCHTOHL
Bofflnl I'ofnt 27a'C 533'F
Appearance-odor-Clear, colorless liquid; weak aromalic -"C -"F Appe.rrnce-()dor-Colorless lqud wrth a shghl, sweet -'C -'F
F r e e z i r SP o i D t . . . . . . . . . . . . . -70'C 94'F odoJ 7"C 19'F
odor Freztnr l'otni.
Specific Gravity-0.86 -'C -'F SDcclflc Gnvity-1.12 -'C _'F
-iH-
chemicrr hydrocarbo"
Frmiry-Aromatic ft#'"ffffi,1l.:,tS;?1""11.......... crcnrcrr
rr.mry-Grycor€rho. I:il'r:;ru*;:lf;t"?1'-t*1 .. {ff
VaDorPresure45"C(1f5'F) (psir)....... . 0 05
p,,rurron
(.rcrol'.r \r.r,^- "1.1,"
PollutionCrteSory-USEPA- IMO A VrDorD€nsity(Air : 1.0)..................... 5.6 rM() l' +:?t
l;fi::;'.".T,il",f;t lo''ll"-1....
........
Applicsbl€Bulk Reg.116CFR Subchapter. ... D. O Solubilityin waler..........
. ... . . . Insoluble Applic.blc Bult Rer.46 ( l,R subchrpter ... O sotubility in Wrter......................... Comolete
crsde-E: Combustible liquid Grrde-E: Combustibleliouid
Electricrl Croup-D Eleirlcd GroulFC
Generrl-Moderate lie hazatd when exposed lo heat or flame. General-Slight tire ha:ard when exposed to heat or flame. Modsrate explosion hazard when vapor is exposd
to flame, spark or heal source.
F l s h P o i n t ( ' F ) . . . . . . . . . . . . . . . . . . . . . . . .1. .8. .1. F l s s hP o i n r( ' F ) . . . . . . . . . . . . . . . . . . . . .3. 5

. .0. .(.c. .c )
FlsBmsbl€ Linits..........................Unavailable FlammabL l ei m i t s . . . . . . . . . . . . . . . . . .0. . .9. t. o. . .9 . 2 %
AutoigDidon Tenp. ('D ................Unavailable AutoigritionTemp.("F)................ 700
Extingufuhing Agents..................... Foam, carbon dioxide or dry chemica Extinguishing A8ents..................... Carbondioxide,dry chemical,or alcoholfoam
Watermav be inellectiveon fire.Cool expos€dtanks with water
Fire Prcedures................ SD€cislFire Prccdures................Water or foam may cause frothing.

Health Hrad Rsting, (Xor Threshold(ppm) PEL,/TWA (ppm) TLVITWA (pPm) Health Haard RdinSs Odor Threshold (ppm) PEL,/TWA (ppm) TLVITWA (ppn)
1. 1. 1 Unavailable Unavailable Unavailable 0, 0,0 Unavailable Unavailable Unavaitabte
Genenl- Generrl-Considered non-toxic under normal handlino conditions.
SymDtons-Slight smarting ol the eyes or respiratorysystem if present in high concentrations. -Liquid is a skin irritant.Vapor is a lung and upper respiratorytract irrilant.
Short Ex!ffure TolerurUnavailable Exposure Tolerance-Unavailable
ExposurePrcedures-Vapor-remove victim to fresh air. Skin or eye contact-remove contaminatedclothing Expqure Prcedure-Skin-llush eyes and skin wi'th water. Vapor-remove victim to fresh ai and adminisrer
and gently flush atlecled areas with waler. artilicial respiration.Call a doctor.

Stability-Stable. Can react with oxidizingmaterials. Strblllty-Stabl€. Can react with oxidizing matarials.
Compstibility-Mrtcrld: Usual materialsof constructionare suitable. lomDrtlblllty-Msterislt Usual materialsof conslruclion are suilable.
Cargo: Group 32 of compatibilitycharl Cergo: Group 40 ot compatibilitychart.

Avoid contact with liquid.Secure ignition sources. Avord contact with liquid.Secura ignition sources.
ll r lDlll ccun. cdl aheNrilotrd RdDnr Ccniq. t0o-424-ttlrr. lt I tall mcod, cll thr Nrtlon.l Cenler, 8fi)-42i1-tt02.
R.n.rhi :f Unaroign€d lt-.t1. I tlrrrirurx'(l
toa l.l7
TRIETHYLENETETRAIIINE TRIPROPYLENEGLYCOL
synorym- N,N'-bis(2-Aminoethyl)ethylenediamine; UnitedNrtionsNunber.......,....,................... 2259 Synonyms- No common synonyms. fJnited Nalions Numbc.
TETA; Trien
CHRIS Cod€........... .. TET

(lllRlS Code.................
Fornula-HrN(QHTNH)sH Fornuh-HO(GHeO)zC' HcOH

8oi1fn8Point.......................... 27A'C 532'F
lloifins Point 267'C 513'F
Appearrnce-odor-Moderatelyviscous,amber liquid; _'c _"F Appcennce-Odc-Colorless liquid; odorlerl
Fre€zingPoint.................... 35'C -31'F -"r
ammonia-likeodor "t lrerzing Polnt...... oors'c
. .....$uoer
Sp€cificGrsvity-o.g8 Specilic Gravlty-l.02
vrDor Prwrre 20'c (68"D a..", -:t ao*
Ctemicsl Fsmily-Amine V.po. Prwure 20'C (68'D (mnHg)....... . <0.01
R e i d V r D o r P r s u r e ( D s l s ) . . . . . . . . . . . . . . . . . . .L. .o. .w. . . Chemicd Fenily-Glycol €the'
(lls'F) (psi8) Reidvrpor Presure(psia).... .. . .......... Low
Vrpor Prewure,l6'C . .......... Low
D Vrpor Pressure 46"C(tls'F) (Dsi8)........... Low
PollutionCategory-USEPA - IMO V r p o r D e r d t y ( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .5. . 0. .4. . Pollution Crtegory-USItPA -- IMO lll V r D o rD e n s i t y( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . 6 . 6 3
ADplicrbleBulk Reg.il6 CFR Subchrpter........ O S o h b i | i t y i n W t t e r . . . . . . . . . . . . . . . . . . . . . .C. .o m o l e t e Applicrble Bulk Reg. il5 CFR Subchapt€r..... . D Comolete
Solubilityin Wrter............ . .
Grade-E: Combustibleliouid Grrde-E: Combustibleliquid
ElectricalGrouD-C Eletricel GrouIFC
cerc.d-Slight lire hazard when expos€d to heal or flame. No spontaneousheating. Genersl-Slight lire hazard when exposed to heat or flame.
Flsh Point ('n.............................

290 F l s h P o i n tC D . . . . . . . . . . . . . . . . . . . . . 2. .8. .5. . . .
FlammbleLimits..........................
Unavailable Flammable Limib.......................... Unavailable
AutoiglitionTemp. ("F)................
642 AutoignitionTenD.('F)............ Unavailable
Alcoholtoam, carbondioxideor dry chemical
ExtiquishingAgents..................... ExtitrguishinSASerts Wat€r, foam, carbon dioxide or dry ch€mical
SpecialFire Prftedurg................ Water or foam may cause lrothing. Fire fighters to wear slf-contained SpecidFire Prcedorc ................ Waler or foam may causetrothing.
breathingapparatus,goggles and protectiveclothing.

Hedth Harud Ratings Odor Thr6hold (Dpm) PEL,/TWA (Dpn) TLv,/TwA (ppn) Hedth Hsard RltinBs Odor Threshotd(pDm) PELITWA (pDn) TLVAWA (ppm)
2,2,1 Unavailable Unavailable Unavailable 0, 0,0 None Unavailable Unavailable
General-Liquid causes severe burns to skin and eyes wilh only slight contact. Vapor causes primaryskin Generd-No hazard undor ordinary conditions of handling.
irritationand dermatitis.
Symptoms-Vapor-skin irritation,dermtitis; naus€a, laintness, anxiety. Liquid-sev€re skin burns. Synptoms-Unavailable
Short ExposureTolemrce-Unavailable Sbort Extosure Tolerance-Unavailable
ExposurePrcedures-Vapor-remove viclim to lresh air; if breathingstops, apply artificialrespiration.Skin or Erlmure Prredueunavailable

eye conlact-remove contaminatedclothing and gently llush affecled areas with waler lor 15 minutes.Get

Stabillty-Stable. Can react wilh oxidizingmatsrials. Strbility-Stable. Can react with oxidizinomaierials.
Compotibility-Materid: Aluminumor stainl€sssleel are suitabls. Comp.tibillty-Material: Usual materials of constructionare suilable.
Cugo: Group 7 of compatibilitychart. See also Appendix l-Exceptions to the Chart Crgo: Group 40 ol compatibilitychart.

Wsar butyl rubb€r glovas, tace shield or all-purposecanister rs8pirator,protsctive clothing. Avoid contaci wiih Avoid contact with liouid.
|qukt. Cover spill with sodium bisullate.Wash up wilh water. Wash sits wilh soap solution.
N.tlonrl ('enta. 0lll-421-tt{12.

cdl tbe Nrilonsl ResDonse
Center,E(x)-42+8602.
&mrlr llrnrrlr: I tjnt.ienrd
l ,
2et
29(t
UREA.AMMONIUMNITRATESOLUTION
TURPENTINE {more lhan 27" lrae ammonlal
Synonynr- D.D. turpentine;Gum spirits; Gum United Nstions Numbel ............_$99- Synonyns-Solar nitrogon solution; UAN-Nitrogen f lniled Nrtlons Nunber....................
turpentin€;Oil of turpentine;Spiritsof turpentine; 9olution; UAN solutron
Steam distillodlupentine; Sulfate turpentine;
Sullate wood turpentine:Turps; Wood turpeniine
CHRIS Code.. ...,.'..,''.'.'.,.',...'
--UAs
Formula-MostlyCroHr6 Formula-NH:CONH,,NH{NOr,NH3,H?O mixtures
Boiling Point.. ....... 150-160'C 302-320'F 100"c 212"F
Boiling Point.. .
Appanence-Odor-Colorlessliquid;smells like oil-bas€ _'c _'F App€.r.rce.Odor-Colorless liquid; slight ammonia-lik€
Daint Freezin8Point......... odor Fre€zing Point o'c sz"r
SDeciflcGravity-O.8s to 0.87 SD€cilic Grrvtty-1.3 -"F
vrDor Prsure 20'C (6s'n (mdHg..........----:- Vrpor prssure 20'c (6g.F),.-"rr---"
chemicsl Fmlly-Oletin R e i d v r p o r P r s u r e ( p s i a ) . . . . . . . . . . . . . . . . . . . .0. .2.6. . . . Chemical Frmily- ReidVaporPre$ure(psia)........................... Varies
vrpor Presure45"c (ffs'D (psia)............ 0'40 VaporPressure 46'C (ll5'n (psir1....... ... Varies
PollutionCstegory-USEPA - IMO B vrpor Density(Air : 1,0)....................... . 4.44 C
Pollutiotr CraeSory-USEPA - IMO V r p o r D e n s i t y ( A i :r t . 0 ) . . . . . . . . . . . . . . . . . . . . V
. .a
. .r.i e s
ApplicableBulk Reg.46 CFR Subchapter........ D. O Solubilityin Weter.................... .. Neolioible O Soluble
Applicable Bulk Reg. 46 CFR Subchspter ...... Solubility in Wster
crrde-D: Combustibleliquid Grade-None assigned.
Electdcsl Group-D Elatrical Group-D
cerenl-Gives oll acrid fumes when heat€d. Mod€rate lire haard. Forms heavy black smoke and soot, General-No direct tire hazard until water evaporales. Thermal decompositionyields toxic ammonia, carbon
Flashbackalong vapor trail may occur. Vapor may explode in an enclosed area. monoxide,and nilrogen oxide gases.
F l s h P o i n t( ' n . . . . . . . . . . . . . . . . . . . . . .9. 5
...... l'lmh Point ('F)............................ Dureammoniumnitrale-ureasolutionis not tlammable.
Flammable Limits.......................... LEL:0.8"/. UEL-Unavailable F l r n n a b l c1 , i m i t s . . . . . . . . . . . . . . . . .f.o. .r .a. m
. . .m
. o n i a1 6 I o 2 5 o h
Autoignition Tenp. ('D................ 488 AuioiSni(ionfenp. ('l') .. for ammonia1205
Extinguishing Agents..................... CO, dry chemical,water fog, foam ExtitrSuishing Agents..... ...........Walgr
Sp€cialFire Pi@edur6................ A tank exposedlo fire shouldbe kept cool with a sprayof water. Speirl Flre Preedurcs ... Do not us€ COr, dry chemical, foam extinguishers.Dry ammonia in contact
wathcombustibl€sincreasospol€ntial for fire. lf confined an explosion will result. Use selt-contained
breathing apparalus and stay upwind.

Herlth Hurd Rltin8s Odor Thrdhold (pDm) PELAWA (ppm) TLvnwA (Dpm) Heolth Haard Rstings Odor Threhold (Dpm) PEL^WA (ppn) TLV,/TWA (ppn)
1, 1, 1 Unavailable 100 100 0, 1, 1 -'45 lor NH3,NH. OH
Gen€.sl-Vapor inhalationharmtul.Liquid irritatingon contact. Gederal-Urea itself is non'toxic. Solution will produce irritationdue to ammonia being pr6s€nl.
synptoms-Prickling sensationot eyes, dizziness,accelerationot pulse, respiratoryirritationand nausea. Symptoms-Prolongedcontact will produce mild irritation,blisters or rash. Eyes will become painful. Ingestion
results in nausea,vomiting, intestinalbleeding,coma, convulsions,and or death.
short ExposureToterance-750 to IOOOppm tor sev€ral hours caused eye irritation,headache,dizziness, Short Expcure Tolerance-100 ppm tor 30 minutes (ammonia gas). Lethal dose of ammonium nitrate is 10-1 5
'1878ppm lor one to four hours is toxic to man.
nausea and accelerationof pulse; grams.
ExpGure Pr@edures-Removevictim to fresh air; if breathing stops, apply artificialrespiralion.Skin or eyo llxposur€PiocedureFwash skin or eyes with water. For ingestion seek medical assistance promptly. Induce
contacl-remove contaminatedclothing and gently tlush atlected areas with water lor 15 minutes.Gsl vomiting after two glasses ot water only if conscious. Monitor breathing. Remove to fresh air.
REA(NIVITY DATA REACTIVITY DATA

strbiltty-under certain conditions(large surtace area exposed to air) turpentine can undergo spontansous Stability-Stable. Reacts with oxidizing material, combustible material, wood chips, organic materials, sulfur,
heating. metal, finely subdivided lead, zinc, galvantzed iron, or acids.
Compatibitty-Mrt€rial Almost any metal is suitable.Ordinaryrubbor is attacked and should not be u3€d fol ( i)mDitibility-Mrterirl:
gaskets or fittings.
Cargo: Group 30 ol compatibilitychart. Cargo: Group 6 ol compatibilitychart.

Wearpolyethylene
gloves,lace shield,protectiveclothing.l-laveall-purpose Avord
canist€rmaakavailable. oontatn metertal to pr€venl contamrnationol land or water. Allow water to ovaporate, scoop up rematning
wilh liquid.Secure ignition sourc€s. ,,,sxttri' I lueh aroa with water to remove remainingtraces.Avoid mixingor contactwith organicor combustible
,i,rrl(trrAl$ Sponlanoougcombuslionmay occut.
It 0 rDlll ccw c.ll thc Nralon.l Rqmm Ccnaer, tlHa-tt02. lr a aplll (Kcurr, oll ihe Nrtionrl ResDonsc ('cntcr. 800-424-tttt02.
Rmb: ' Vrpor Pres8ur€:5 mmHg rl 25'C.
116.rl. llb nxxo llun ?\ lkx' Arninonta normally roqutr€s shrpment Under pressur€ (O-30 psia at 104'F)
'
Vqrr llotft{o t.r rrrrrll0 trt //'F
"
M l. ., tinr, (;() .,{) ppnr, Nll, ?a) pprn, Nf]lOH I ppm
I tr,rrqlr,
3m
loI
iso-VALERALDEHYDE
UnitedNrtionsNumb€r................................
lQtt-
ll Synoyme Amyl aldohyde; Pontanal: Valeral; Valerac
N-VALERALDEHYDE
Unlicd Natlons Number 2058
Synonymo- lsovaleral;lsovaleraldohyde;lsovaleric aldehyd6
aldehyde;3-Methylbulanal;3-Methylbutyraldehyde
( llRIS Cod.................. VAL

CHRISCode........... .... tvA
Fornuh-CH,(Ct l,l,CHO
Fornula-CHTCHTGH(CH3)CHO Itoffftrt Poltri 103"C 217""F
B o i ' i n s p o i r t . . . . . . . . . . . . . . . . . . . . . .g. .2.'." l ' , ADD".r.ncr-()dor-Colorless lqurd wrlh a lrurly ()dg
liquid;weakly suffocating Freczlnr Point ,1'; lgTi
ooor Freezing
Point......... . .. -51'3 -*:F (;rrrlty-0
SDslll( 61 _'c _"F
Specific Gravity-0.80 _"a - 'F
Vrp.)r Prsu.e 20'( (68"1') (mmtlg).......... ---?0--
Vtlnr Pressure 20"C (5S"F) (mmHd.......... ----:- (:henlcrl frmtly-Aldehyd€ Itefd vrDor Proiurc {psh)... .... ...... 1.2
Chcmicsl Fmily-Aldehydo ReidvsporPrsure(pcir)........................... t Vtyrr Prilure 46 ( (ll5"t') (psia)........... ---1=9--
Vrpor Pr6sure,16"C (115'F) (Dci.)............. Hioh Pollution (llcao.y-l rsl,l'A tM() D I'rp()r Dctrrtty (Air 1.0) .. 2.96
Pollutior Crtegory-USEPA - IMO C VrporDemity(Air : 1.0)........................... 2.96
Appll..blc Brll Rca. 46 ('l'R silb(hrptcr O Solublllt' In Wstcr .. - Slioht
Applicrble Bulk Reg. ,16 CFR Subchspter........ O solubilityirWster......................... ln$luble
FIRI.] & }:XPI,OSION HAZARI) I)ATA

FIRE & EXPI,OSION HAZARD DATA Grrd.-C Flimmablolrqurd
Grade-C: Flammable liquid Eletricrl (l.oup-C
El€ctrical Group-C
cenerd-Flrlh brck rlong |trll may occur Vepol may €xplod€ in a closed area.
Generd-When heated, it emits acrid fumes. lgnited by heat, sparks or open flame. Vapor forms explosive
mixtures with air. Flashback along vapor trail may occur. Vapor may explode il ignil€d in an enclos€d area.
Rrb I'olna('F)........ ... . 54
F l s h P o i n t C F ) . . . . . . . . . . . . . . . . . . . . . . . .4. 9. . . . l'hnn.ble l,lmlit Unevsilabl€
Flammable Limits.......................... Unavailable Autoigrlalon lenp. ('l')..,..... Unavarlabl€
Autoignitior Temp, ('F) ................Unavailable Extlnguhhlng Agcntr. . ......... Carbon droxido, dty chemicals, loam, water spray
Extinguishing Agents..................... CO,, dry chemical, waler lo9, alcohol foam Specld Flre Pr@edurd........ Woar soll conlained brsathing apparatus and prolective clothing as proteclion
Special Fire Prmed[c................ Water may be ineftective on lire. Wear sell-contained breathing apparatus and agarnst acnd tumes. Wet€r may b€ Inetlective on liro
TIEALTH HAZARD DATA

HEALTH HAZARD DATA H€dth Hrard Rstltrgs Odor Throhold (ppm) PEI.,/TWA (pDm) TLV,UTWA(ppm)
Herlth Hrud Rstirgs Odor Threshold (ppm) PEL4WA (ppn) TLv,/TwA (ppm) 1, 1, 2 Unavailabl€ 50 50
'1.2. 1 Unavailable Unavailable
Unavailable
Crr€rsl-Vapor is flammable and very irritating.Liquid causes severe burns.
G€nerd-Vapor iritating to skin and mucous membranes.
Symptoms-Vapor-severe irritationof air passages with headache and rapid heart b€at, eye irrilation. Liquid
coughing,sneezing,burning and learing of ey6s, salivation,and all signs ot irritationof the causes severe skin and eye irritalion on contacl.
mucous memoranes
ExD6ure Tol€rrnce-Unavailabl€
ExposurePrmedurc-Vapor-remove victim to lresh ak; if breathing stops, apply artificial respiration.Skin or

Exposw Procedur6-Wash immediatelywith soap and water alter skin conlact. Contact of the liquid with the eye contact-immediately flood atfected area with water lor at least 15 minutes. Remove contaminaled
eyes can cause permanenl injury if prompt lreatment is not given. Wash eyes with clear water; obtain clothing.
medical treatment.
REACTIVITY DATA
REACTIVITY DATA Stsbility-Stable.
stability-Reacts with itselt and also undargoesthe condensationreaction in the presence of strong bases
ComDdtblllty-Mrteri8l: Siainless steel or aluminum are recommended
lr
Conpatibillty-Msteri* Compatiblewith stainless sleel or aluminum.
c|r8or Group 19 of compatibilitychart.


woar rubbor gloves, self-containedbrealhing apparatus,protectivo clothing. Avoid contact with liquid. Secure
Avoid conl,actwith lhuid. Wear rubbor gloves, goggles or laco shbld, and protective clothing. Socuro rgnilon rgnrlrorrsources Cover spill with sodium bisullits (NTHSO!). Add smell amounl ol wat€r and mix. Scoop up.
aoutcal. wrrlt srlo wrlh saD lolution.
lt I rDlll ccur, cdl tlc Nrllord Romnr Centq. lfll{24-ttl2.

lt a rglll Gun, c.ll the N.iion.l Roprrc Ccltt. I0{14-tlt0l.
' l.mrh:
ltmrb V.p<r Pre!r6: 50 mmHg et approx. 25'C.
I Umv.r|bb
I
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iso-VALERALDEHYDE
UnitedNrtionsNumb€r................................
lQtt-
ll Synoyme Amyl aldohyde; Pontanal: Valeral; Valerac
N-VALERALDEHYDE
Unlicd Natlons Number 2058
Synonymo- lsovaleral;lsovaleraldohyde;lsovaleric aldehyd6
aldehyde;3-Methylbulanal;3-Methylbutyraldehyde
( llRIS Cod.................. VAL

CHRISCode........... .... tvA
Fornuh-CH,(Ct l,l,CHO
Fornula-CHTCHTGH(CH3)CHO Itoffftrt Poltri 103"C 217""F
B o i ' i n s p o i r t . . . . . . . . . . . . . . . . . . . . . .g. .2.'." l ' , ADD".r.ncr-()dor-Colorless lqurd wrlh a lrurly ()dg
liquid;weakly suffocating Freczlnr Point ,1'; lgTi
ooor Freezing
Point......... . .. -51'3 -*:F (;rrrlty-0
SDslll( 61 _'c _"F
Specific Gravity-0.80 _"a - 'F
Vrp.)r Prsu.e 20'( (68"1') (mmtlg).......... ---?0--
Vtlnr Pressure 20"C (5S"F) (mmHd.......... ----:- (:henlcrl frmtly-Aldehyd€ Itefd vrDor Proiurc {psh)... .... ...... 1.2
Chcmicsl Fmily-Aldehydo ReidvsporPrsure(pcir)........................... t Vtyrr Prilure 46 ( (ll5"t') (psia)........... ---1=9--
Vrpor Pr6sure,16"C (115'F) (Dci.)............. Hioh Pollution (llcao.y-l rsl,l'A tM() D I'rp()r Dctrrtty (Air 1.0) .. 2.96
Pollutior Crtegory-USEPA - IMO C VrporDemity(Air : 1.0)........................... 2.96
Appll..blc Brll Rca. 46 ('l'R silb(hrptcr O Solublllt' In Wstcr .. - Slioht
Applicrble Bulk Reg. ,16 CFR Subchspter........ O solubilityirWster......................... ln$luble
FIRI.] & }:XPI,OSION HAZARI) I)ATA

FIRE & EXPI,OSION HAZARD DATA Grrd.-C Flimmablolrqurd
Grade-C: Flammable liquid Eletricrl (l.oup-C
El€ctrical Group-C
cenerd-Flrlh brck rlong |trll may occur Vepol may €xplod€ in a closed area.
Generd-When heated, it emits acrid fumes. lgnited by heat, sparks or open flame. Vapor forms explosive
mixtures with air. Flashback along vapor trail may occur. Vapor may explode il ignil€d in an enclos€d area.
Rrb I'olna('F)........ ... . 54
F l s h P o i n t C F ) . . . . . . . . . . . . . . . . . . . . . . . .4. 9. . . . l'hnn.ble l,lmlit Unevsilabl€
Flammable Limits.......................... Unavailable Autoigrlalon lenp. ('l')..,..... Unavarlabl€
Autoignitior Temp, ('F) ................Unavailable Extlnguhhlng Agcntr. . ......... Carbon droxido, dty chemicals, loam, water spray
Extinguishing Agents..................... CO,, dry chemical, waler lo9, alcohol foam Specld Flre Pr@edurd........ Woar soll conlained brsathing apparatus and prolective clothing as proteclion
Special Fire Prmed[c................ Water may be ineftective on lire. Wear sell-contained breathing apparatus and agarnst acnd tumes. Wet€r may b€ Inetlective on liro
TIEALTH HAZARD DATA

HEALTH HAZARD DATA H€dth Hrard Rstltrgs Odor Throhold (ppm) PEI.,/TWA (pDm) TLV,UTWA(ppm)
Herlth Hrud Rstirgs Odor Threshold (ppm) PEL4WA (ppn) TLv,/TwA (ppm) 1, 1, 2 Unavailabl€ 50 50
'1.2. 1 Unavailable Unavailable
Unavailable
Crr€rsl-Vapor is flammable and very irritating.Liquid causes severe burns.
G€nerd-Vapor iritating to skin and mucous membranes.
Symptoms-Vapor-severe irritationof air passages with headache and rapid heart b€at, eye irrilation. Liquid
coughing,sneezing,burning and learing of ey6s, salivation,and all signs ot irritationof the causes severe skin and eye irritalion on contacl.
mucous memoranes
ExD6ure Tol€rrnce-Unavailabl€
ExposurePrmedurc-Vapor-remove victim to lresh ak; if breathing stops, apply artificial respiration.Skin or

Exposw Procedur6-Wash immediatelywith soap and water alter skin conlact. Contact of the liquid with the eye contact-immediately flood atfected area with water lor at least 15 minutes. Remove contaminaled
eyes can cause permanenl injury if prompt lreatment is not given. Wash eyes with clear water; obtain clothing.
medical treatment.
REACTIVITY DATA
REACTIVITY DATA Stsbility-Stable.
stability-Reacts with itselt and also undargoesthe condensationreaction in the presence of strong bases
ComDdtblllty-Mrteri8l: Siainless steel or aluminum are recommended
lr
Conpatibillty-Msteri* Compatiblewith stainless sleel or aluminum.
c|r8or Group 19 of compatibilitychart.


woar rubbor gloves, self-containedbrealhing apparatus,protectivo clothing. Avoid contact with liquid. Secure
Avoid conl,actwith lhuid. Wear rubbor gloves, goggles or laco shbld, and protective clothing. Socuro rgnilon rgnrlrorrsources Cover spill with sodium bisullits (NTHSO!). Add smell amounl ol wat€r and mix. Scoop up.
aoutcal. wrrlt srlo wrlh saD lolution.
lt I rDlll ccur, cdl tlc Nrllord Romnr Centq. lfll{24-ttl2.

lt a rglll Gun, c.ll the N.iion.l Roprrc Ccltt. I0{14-tlt0l.
' l.mrh:
ltmrb V.p<r Pre!r6: 50 mmHg et approx. 25'C.
I Umv.r|bb
I
rot
VINYL ACETATE VINYL CHLORIDE
Sytronyms- Acetic acid, ethenyl esteri Acetic acid, vinyl Ulited Nrtionr Nuober.............. liut- SynonyeChlormth€ne;Chloao€thylene;Ethena, UtrltedNrtlouNumber. lag€_
ester; VAM; Vinyl acetate monomer: Vinyl A chloro-; Ethylgne monochlorid€;Monochloro€thsne;
monomer; Vy Ac Monochloroethylone;VC; VCL; VCM; Vinyl chlofldo
monom€r; Vinyl C monom€r
C H R I SC o d c . . . . . . . . . . . . . . . . . . VCM
Fornule-CHTCOOCH : CHr Formulr-CHr : CHCI

BoilingPoint.......................... 73"C 163'F BofllngPoftrt.......................... -14"C 7"F
Apperrance-Odor-Colorless liquid; sweet odor Appc.roeodc{dorleta lhuid of g[!; lwe€l odol -too"3
FreezingPoint......... 100"3 -t*"i ,*:F
Fradr8 Potrt......... 'c 'F
Specilic Grsvity-O.94 _'c -'F Stdnc G.rvlty-O.9l
Vapor Pressure20'C (68'D (mmHg........,. ---99-- VrIDr P|gurc 20'C (5t'D (mmHg........ 2580
Chemical Fsmily-Vinyl acetate R e i dV a p o rP r e s s u l(ep a i r ) , . . . ......... . , , , . , 3.7 Ctolcd Fully-Vinyl hrllda R c l dV r D o rP r w u r c ( p d r ) . . . . . . . . . . . . . . . . . . . . . . 75
...
Vrpor Pressure 46"C(f15'D (psia)............. ---5.!- V.IDi Proure '16'C(l I5'n (Ddl.)....... .. 95
Pollution Crtegory-USEPA D IMO C V r p o r D € n s i t y ( A i :r 1 . 0 ) . . . . . . . . . . . . . . . . . . . . .2. . 9. .7. . Polluttor Crtcgory-USEPA --lL lM() ---Il- Vt]Er Dcultt (Alr = 1.0). .....................2.15
Applicable Butk Reg. ,16 CFR SubchsDt€r. .. . . O Solubilityin W41er....................... .. - 27" ADpltoblc Bdl Rca. il6 Cl'n Sub.h.ptcr O 9rloblllty In W.icr Slioht
FIRE & EXPLOSION HAZARD DATA FIRE & I.IXPLOSIONTIAZARD DATA

Grade-C: Flammable liouid CrdFLiqueffad Fhmmeblo GaB (LFG)
Electrical GrouD-D Elccdcd GrufFD
Cincrd-Oang€ious llre huard. Unles tho llow ol ga! can bo stopp€d, putting out a vinyl chlodde fiJe will
General-When heated, acrid vapors are given off. lgnited by heat, sparks or open llame. Fire may cause p€rmil accumulalionof an oxplorlve vapor concenlratlon with incr€assd danger of reflash. Hsat
violent rupture ol tank due to polymerization. decompos€s vinyl chlorid€ to lorm highly toxacphosgene gas. Heat can ale cause vinyt chlorid€ to
tDlym6riz6 with €xplosive lorc€.
F ' l s h P o i n t C F ) . . . . . . . . . . . . . . . . . . . . . . . .1.I. . . . F l c h P o l n t( ' n . . . . . . . . . . . . . . . . . . . . . . -. 1
. .0. .8. .
Flmnrble Limits.......................... 2.6 lo 13.4ok F l m m r b l c L l n l b . . . . . . . . . . . . . . . . . . . .3...6. .t.o. 3 3 %
AutoiSDitiotrTemp. ('D................ 801 ArtolgtrldorT.ED. ('F) ................ 882
ExtinguishitrSA8ents..................... CO,, dry chemical, alcohol foam, water spray. ErtlnSulrhht 48crts..................... Stop tlow ot gas; CO2,dry chemical,waler tog
Sp€cirl Fire Pi@edur6................ lf lire parties must work in conlined quarters, provide respiratory proteclion. SD.ctd Ftrc hoccdurs................ Cool tank with wator spray. Provide self-containedbreathing apparatus and
Keep tank cool with a water spray. protsclive clolhing for tire-fightingperennel.

Health Haard RstinSs Odor Threshold(ppd)PEL,/TWA (Dpn) TLV,/TWA (ppn) Heslth Hszrd Rrti4s Odor Tbr$hold (Dpm) PEL,/TWA (Dpn) TLVITIVA (ppn)
1 , 1 ,2 0.12 10 10 2,1,2 260' 29CFR1910.1017 5
Genersl-Liquid irritatingto skin and eyes. Vapor inhalationcauses slight narcotic effect. Generrl-Human carcinogen.Vapor harmful. Liquid or cold gas may cause skin or eye iniury similar to lroslbile
Symptoms-Dizziness,drowsiness. SyEDtorDziness and drowsiness. Frostbitten areas will look white.
Short f,xpGure Tolerance-Unavailable Short Expcure TolemcFsoo ppm for 5 minutss.
ExposurePr@edur6-Vapor-rsmove victim lo fresh air; if breathingstops, apply artificial respiration.Skin ot ErDque Prcedurg-Ramove victim to fr€sh air. lf braathing slops, apply artificial respiration. tf th€ liquid has
eye conlact-remove contaminatedclothing and gently llush affecled areas with water lor 15 minutss. Gel spilled onto the skin, points ot contact may be trostbitten;handle gently and proteci from mechanical
medical advice or attention. damage. OO NOT RUB. In case ot €y€ contact, llood eye gently with wat€r tor 15 minutes. Get medical
attention.'

Stsblllty-Polymerizes readily if not inhibited.Heat can slart the reaction. Emits acrid lumes when heatsd to Strblltty-Polymerizes in presence of air, sunlighi or hoat.
decomposition.Can react vigorouslywilh oxidizingmaterials.
Compstibility-Mstedal: Most of the usual materialsol constructionare suitable. CoDFtlblllty-M.terial: Steel is satislactory. Hilwgr, contact wilh copper or other acetylide-torming metals
may form explosive compounds.
Crrgo: Group 13 of compatibilitychart. C[go: Group 35 of compatibilitycharl.

Wear rubber gloves, lace shield, proteclive clothing. Have all-purposecanistsr mask availabl€.Avold conLcl wear rubbar gloves, sell-contain€d breathing apparatus, protectiv€ clothing. Avoid contact with liquid. Secur€
with liquid.Secure ignition sou.ces. Flush area with watsr spray. |gnrl0n DUrOaa.
lf r rplll ecun, cdl thc Nillond Ccltcr. tlxl-ra2a-ttll2. ll r ollf occrr cll th. Nrdod nme Crntr. l,[[4?4-l',/0.2.
lcnrrh: lrl. ' N( ) I I Oalctrblo
odor la gterter than th€ TLV. Expoaureto polentially dangeroul vapor
r'.rx f,rtrrtsr. c.n Ncur tnto.a lha v|I|of b deleted by rrnall.
3fi 105
ls*t-,,.,w.-.-,.*^*.., SCANNED BY MKP & BARIS A. 2004
Synonyns- Ethoxyethene;
Vinamar
VINYL ETHYL ETHER
Ethyl vinly ether; EVE: UnitedNrtionoNumbcr..........,..........,.,........
Jne-
fl Synotryms-1,1-Dichloroethene;
1,1-Dichloroethyl€ne:
VINYLIDENECHLORIDE
t,rlt€d Nriions Number ...... 1303
asym-Ochloroethylene;Eth€ne, 1,l,dichloro-
Formule-CH:: CHOGHs
cHRrs code vEE
il CHRIS (trde .......... vcl
Bolling Point.......................... 37'C 99'F Foruule-GHTCL
l l
ADpearance-Odor-Colorless liquid; disagreeable odor Eoillnj 1bint......... ... . 32"C 89"F
F r € e z i n gP o i n t . - . . . . . . . . . . . . . . . . . . . . . .-r,ls.C rzs'r hqurd:gweel odor
Specilic Grsvity-o.763 -"c -'F pofn..........
rrreezinr 1.,':3 *t'F
Specitlc Gnvlty-1.21
Vapor Preure 20'C (68'n (mnHg).......... --120-
Chenicsl Fsmily-Ethers R e i d v r p o r P 6 u r e ( p s i a ) . . . . . . . . . . . . . . . . . . . . . . .t. . . . Vrpor Praurc 20'C (6t'l') (mmHg).......... ----:-
Ctcnlcd Fmlly-Vrnyl halde
vslDr Prsure il6'C (f l5'n (06i.)........... t Rcld Vrpor Presurc (Ddr) 18 3
Pollutior Category-USEPA - IMO C Vrpor Density(Air : 1.0)........................... 2.49 VtDor Proure 46"C (l15'l') (psir)........ 24
Pollutlon ('rrerory-ttSt:pt ----8. tM() I
Applicable Bulk Reg. il5 CFR Subchapter........ ----Q- SolubilityinWater......................... Sliohi V|tDr l)ctrrlty (Air . 1.0).............. .. 3.34
Appllc.blc Bull Rcg. 46 ('trR Subchrptrr O solubtlltylnwstcr...................... Neolioible

Grade-C: Flammableliouid I.-IRI]& EXPI,OSION HAZARD DATA
ElectricalGroup-C Grrda-A: FlammebleInurd
Eletrlcd Grcup-D
C€nerrl-Exlremely flammable;may form explosive peroxides.Flashbackalong vapor trail may occur. Vapor
may explode il ignited in an enclosed area. Getrer.l-Dengsrous flra hazatd: gxtrsm€ly flammable.Combustionproducts include hydrogen chloride and
poisonous phosgsne. Fire may result in violent ruptu.e of tank due to polymerization.
less than -50 (cc)
Flsh Poirt CF).............................
FlsmmbleLimits..........................
1.7 lo 28'h l ' l u h P o i n t( ' l ) . . . . . . . . . . . . . . . . . . . . . .O. . . . . . .
AutoigritionTenp. ('F)................
395 Flmmrble Linltr....... 5.6 lo 16.0o10
Extin8uishinSA9ents.....................
Alcoholfoam,loam, CO:, dry chemical. AutolStrltlon Tcnp, ('D................1058
SD€ci8lFire Prftedures................Wear goggles and selt-conlainedbreathingapparatus.Water may b€ Ertltr8utuhing ^8ents..................... Carbondioxide,dry chemical,foam, water fog
inetfeciiveon lire. Cool exoosed tanks with water. SpecielFire Prcedures................Keep tank cool with water spray. Wear eye protection,setf-conlained
breathing apparatus and protective clothing.
HEALTH HAZARD DATA

Herlth Hrard RatinS! Odor Thrshold (ppm) PEL,/TWA (Dpm) TLV,/TWA (pDm) HEALTH HAZARD DATA
1, 1, 2 Unavailable Unavailable Unavailable Hedth Hrud Ratings Odor Threshold (ppm) PEL,zTWA (ppm) TLVATVA (ppm)
2,2,3 5 0 0r o 1 0 0 0 | 5
General-Vapor or liquid may be irritatingto skin and eyes. Concentratedvapors result in rapid anestheticettect
and loss ol consciousness. Goerd-Suspected carcinogen.Liquid irrilating on contact. Vapor harmful and has narcotic effect.
SymptorExcitement followed by unconsciousnessand respiratoryparalysis.Prolongedskin conlact caus€a

dermatitis. Synptons-Dizziness, nausea, and sleepiness.Liquid causes skin burns and eye irritation.
Short ExposureTolerance-Data not available.
Short ExposureToleruce-lnhalalion of 4000 ppm rapidly produces symptoms of drunkenness;
unconsciousnessmay lollow shorlly afteruard.
Expcure Prcedures-Remove from area and administtr arlilicial respirationor orygen il necessary.Flush
aflected areas with large amounts of water. ExposurePrmedures-Vapor-remove victim to fresh air; il breathing stops, apply artiticial respiration.Skin or
eye conlact-remove contaminaledclothing and genlly llush affected areas with water for 15 minutes. Get
REACTIVITY DATA
Strbility-Can react vigorouslywith oxidizingmaterials. REACTIVITY DATA
strbilitv-will polymerizeil exposed to heat and air. This commodity must be inhibiled for shipmeni.
CoEpstibility-Msterid:
ComD.tibility-Mst€risl: Copper and copper alloys are unsuitable.
Crgo: Group 13 ol compalibilitychart.


Wear goggles,slf-coniained breathingapparaius,rubber gloves. Stay upwind, knock vapors down with wakil
spray. Socure ignition sources as dangerousperoxid€slorm upon heating. woar nrbbor glov€s, selt-contained bieathing apparatur, and protective clothing. Avoid contact with liquid.
'!r{:urs rgrrllronsourcss
Do not flush spill into conlined spaces where llammabl€ vaoors can accumulate.
lt. rDlll eqn| cll ahc Nriloul R6Doe Ccrtc,

lt I rrill acul crll thc Nrtlood RqDoe C.!a{. 8{XL.t:,t-tt02.
Rcorrhr: I Unavailable
hadbr '
Vaax, llorrtr! a{X) rirrnllq at t4 4'C
lfit
I
t(|?
VINYLTOLUENE O.XYLENE
Synonyme- Methylstyrene; para-Melhylstyrene; United Nations Number 2618 Synonyms-Benzene,dimethyh 1,2-Dimethyl
benzene; United Nations Numb€r ....... 1307
Tolylethylene Orthorylenei ortho-Xylene;Xylo
CHRIS Code........... .... VNT
Formula-CHzCHCeHTCHT Formuh-GHr(CHs),
Boilidg Point.......................... 168'C 334'F
App€rrsnce-Odor-Colorless liquid with a disgreeable Aplrcarance-Odor-Colorlessliquid: benzene{ike
odor FrezingPoint........................ -77'C 107'F
aromalic odor
't
Specific Gravity-0.90 Speific Gravity-O.89
vrDor Pressure 20'c (6s'F) a.-"r---: *
Chemic8l Fmily-Oletin Reid Vspor Pressure (prir)........................... 0.07 ChemicalFlmily-Aromatic hydrocarbons
Vrpor Pressure,l6"C (115'F) (psis)............ O.12
Pollutiotr Crtegory-USEPA - IMO A VrporDeDsity(Air : 1,0)........................... 4.08 Pollution Cstegory-USEPA C C'
IMO
Applicrble Bulk Reg. ,16 CFR Subchapter........ ----Q- SolubilityinWater......................... Slioht ApplicableBulk Reg.,16CFR Subchapter... . . D. O Neolioible
Solubility in Wster
Grrde-D: Combustibl€liquid Gr.de-D: Combustibleliouid
ElEtriel Group-D Electricd Group-D
GeDenl-Combustion may evolve toxic gases such as carbon monoxide.Moderale tire hazard when exposed to Cencrrl-Moderate fire hazard,when exposed to heat or tlame. Flashback along vapor trail may occur. Vapol
h€at or flame. Fire may cause violenl rupturs ot tank du€ to polymerization. may explode il ignited in an enclcsed area.
t r l o h P o l n tC n . . . . . . . . . . . . . . . . . . . . . .1. 2
. .7. . . . n s h P o l n t( ' F ) . . . . . . . . . . . . . . . . . . . . .9. 0. . . . . . .
F h m m 8 b lL . 1" / "
e i m i t s . . . . . . . . . . . . . . . . . .0. . 8. .t.o. .' 1 l ' f e m m a b lLel m f t s . . . . . . . . . . . . . . - . . .1. . 1l o 7 . O y "
Autoignition Temp. ('D ................ 914 AutoignitlonTcnD.("n ............... 867
Extinguishing A8ents..................... CO",loam, water tog Extinguishir8A8cntr ............. ..... CO?,dry chemical,loam, water tog
SpecialFire Pr@edures................ Wear goggles and self-containodbreathingapparatus.Cool fire exposed tanks SpEcirl Flre Prcedurcs ........... . Water may be ineflective but water should be used to keep fire-exposed
wilh water. conlaan€rscool. ll a leak or spill has nol rgnited,use waler spray to disperse the vapors and to protect
personnel attsmptrngto slop I leak. Water spray may be used to llush spills away from exposures.

Hedth Haed Rstillr Odor Threshold (ppn) PELAWA (pDd TLV,/IWA (ppn) .fhreshold(ppm)
Hedth Hred RrtlnSs Odor PEL,/TWA (ppn) TLVITWA (ppn)
2.'l.1 a b o v e1 0 100 50 1, 1, 2 0.05 10 0 100
Cenerrl-lrritation; narcotic. Generd-Vapor inhalationharmful. Liquid irritating.
Synptons-Liquid-skin irrilation,blistering.Vapor-eye and nasal irritation. Symptoms-Headache,dizziness,staggering,nausea, and drowsiness.
Short Expcure Tolerrnce-4oo ppm lor 5 minules. Short ExposureTolerance-Narcosis in animals begins wilh inhalationsot 2300-3500 ppm. Instances of
unconsciousnessin humans lrom severe exposures have been described,but the specific concentrations
were unknown.
ExposurePrcedures-Vapor-remove victim to fresh air; if breathingstops, apply artilicial respiration.Skin or ExposureProcedures-Vapor-remove victim to lresh air; it breathing stops, apply artiticial respiration.Skin or
eye contact-remove contaminatedclothing and gently wash aflected areas with water. eye contacl-remove contaminatedclolhing and flush affected areas with water for '15 minutes.Get medical
advice or atlenlion.

Stsbility-May polymerizeif exposed to heat and uninhibited.Can react with oxidizingmaterials. Stsbility-Stable.
ComDatibility-Mrlerlal: Usual materialsof construclion are suitable. comprtibility-Mrterial: Most materialsol constructionare saiisfactory.Rubber will swell and soften after
prolonged exposure.
Cargo: Group 13 ot compatibilitychart. Cargo: crJup 32 of compatibilitychart.

wear rubber gloves, face shield, protectiveclothing. Havs all-purposecanisler mask available.Avoid conls, I Woer polysthylen€ gloves, lace shield, protective clothing. Have all.purpose canister mask available. Avoid
with liquid.S€cur€ ignition sources. contact wilh liquid. Sscur€ ignilion sourc€s.
ll t rplll mch, call tic N.alon.l ('crtrr. tXl.l24-tt02. l, . |lilll @uro, oll thc Nrtionol c.tricr. t(xH2,l-tt02.
n.D[b: l.'$rhr ' Pollultrnr (l{togory (;
orl liko, 33 CFR 151.49
"
V.F I'rcrruro l0 mmHg at 32.1'C.
rot r{F,
M-XYLENE P.XYLENE
Synonyms-Benzene,dimethyl-;1,3-Dimethyl
benzene; 1307
UnitedNrtionsNumber............,................... Synonyms- Senzene, dimethyl-; 1,4-Dimethyl benzene; United Nations Number..... 1307
Metarylene; meta-Xylene;Xylol Paraxylene; para-Xylene; Xylol
QHRIS Code........... XLM
Fomula-GH.(CHs)r Fornub-C5Hr(CHr),
BoilinSPoint....................,...,. 139'C 242'F BoilinS Point......... . . 138'C 281'F
Appearance.odor-Colorlessliquid;benzene-like - -.q7:3 Appearlnce-Odor-Colorless liquid; bonzene,like
aromatic odor Freertn8Pofrt......... -*'F aromatic odof rg'c so'r
Fre€zing Point.......
Sp€cificGrsvity-o.87 _'c _'F Specillc Grrvlty-O.86
" "
Velnr Proure 20'C (68'l) (mnH$ .........- - Valnr Pressure 20'C (68'F) (mmHd..........
Chemicd Fmily-Aromatic hydrocarbons Reldv|Dor P|uuc 0.b)............... ........... 0.34 Chemlal Frnlly-A.omatrc hydrmarbona Reid VepnrPressure(psia)-......................0 . ...3. 4
Vrtor Prcur a6'C (lIS'ID (pelr)............--Oll- V.p{rr Pressure 45'C (ll5'D (psir)............. 0.51
Pollutioncrtegory-UsEPA C IMO C' V.Dor D.[lty (Alr 1.0)............ 3 66 Pollutlotr Crac8ory-l rs!:l'A Q tfrlrr c' V r p o r f ) e n s i t y ( A i r : 1 . 0 ) . . . . . . . . . . . . . . . . . . . . . . . .3
. ...6 6
ApplicsbleBu[. Re8.45 CFR SubchrDt€r........ D. O solubllltyIn wrlcr ... ..........,....... Insoluble Appllceble Bult Rcg. ,16 ( lR Silbchiplct pô Solubility in Wster... ..... Neolioible
FIRE & EXPLOSION HAZARD DATA IiIRF: & I]XPI,0SION HAZARD DATA
Flammableliquid Crrde-D: Combustrble
lqurd
Electricrl GroulFO Eleciric.l Crou!-D
tire hazard and moderato €x9losion hazard wh€n €xooa€d lo haat or tlame. Flashback G!trcnl-Modoral€ lira hazrtd, whan expo3ed lo hgrt or llams
along vapor trail may occur. Vapor may explod€ il ignrt€dIn rn enclosed rtea.
F l a h P o l n t( ' F ) . . . . . . . . . . . . . . . . . . . . .7.7. . . . . . . n u h P o h l { 1 . ) . . . . . , .. . . . . tll

F l a m m r b lLei m | t s . . . . . . . . . . . . . . . . . .1. . 1 . .t.o. .7. . 0 % Fhmmrblcl,imits lllo/0"/o
Autoignition Temp.('D................ 982 Autol8rltlon lcmp. ("1)...... . . 8ll)
Extinguishing Agents..................... Foam,CO", dry chsmical Ertln8ulshinS Agenb ....... CO,, dry ch{rmrcal loam. wrlor tog
sp€cialFire Prceduro................ Water may b€ ineftectivebul watsi should be used to keep fire-expos€d SDeclrl Flre Prucdure.... Walor may bo Inellocltvo but wator should be used lo keep tire-exposeo
contain€rscool. It a leak or spill has nol igniled, uso wator spray to dispersethe vapor and to proteci conlain€rs cool ll a leak ot sprll has nol rgnrlod, uso wal(lr spr;ry lo drspers€ the vapors and to proiect men
personnelattemptingto stop a l€ak. Water spray may be used to llush spills away. atlempting to slop a lsak. Wat€r spray may be used to llush sprlls away lrom exposures.

Heslth Haard Rrtlrgs Odor Thrshold (ppm) PEL,/TWA (ppn) TLVITwA (ppm) Health Haard Rrtlngs Odor Threhold (ppn) PELAWA (Dpm) TI-V/IWA (ppm)
1.1.2 0.05 100 100 1, 1, 2 0.05 100 10 0
-Vapor inhalationhas moderatesystemic etfect resultingin possible loss ol consciousness G€n€rd-Vapor inhalation harmlul.
confusion,nausea,diziness. Dermatitismay result from repeated skin exposure. Symptoms-Headache,dizziness,nausea.
Short Expcure Tolerme-Narcosis in animals begins with inhalationsof 2300-3500 ppm. Inslances ol Short Expmure Tolerance-Narcosis in animals begins with inhalation of 2300-3500 ppm. Instancesof
unconsciousnessin humans from severe exposureshas been described,but the specitic concentrations unconsciousnessin humans lrom severe exposures have been described, but the specilic concentrations
were unknown.300 ppm is the sugg€stedshort term inhalationlimit. were unknown.
ExposurePreedureRemove from €xposure;remove conlaminatedclothing, cleanse skin, and eyes. Artificial ExDosureProcedures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration.Skin or
respirationshould be started immediatelyit breathing has stopped. eye contact-remove contaminatedclothing and gently llush attected areas with water for 15 minutes. Get

Strbility-Stable.
Comprtibility-Msterld: Sollens rubber; not corosive to mosl metals. Most matedds of constructionare suitable. Rubber exposed to rylene will swell, sotten
and eventually deteriorate.
Cargo: Group 32 ot compaiibilitychart. CarSo: Group 32 ol compatibility chart

Wear tplyathyl€ne gloves, faco shi€ld, proteciive clothing. Have all-purposa canister mask availablg. Avor(l wsar poly€thylene gloves, face shield, prolective clothing. Have all-purposs canisler mask available. Avoid
contacl wlth liquid.S€curs ignitlon lources. Wash up wilh weter. contacl wilh liquid. Secure ignition sources.
l? . rplll mc!n, crll thc Ndlod nqDtre Ccntcr, fl r r!illl occurs, crll thc Nrdonrl R6mos Center. 800-424-8t02.
l6rrh 'Pollulon Ctlo0ory (l orl lrko. 33 Cf '
R l5l ag llemrrlr: l'ollulion Calogory C orl lko, :lat CFR 151.49
" V.lu Prorruro l0 mmHg al ?0 3'C. ' '
Vapor Pros$uro 10 mmHg al 28 3 C
II
Synonyns-Zinc dihexyldithiophosphate;
dihexylphosphorodithioate
Zinc
ZINC DIALKYLDITHIOPHOSPHATE
United NraloosNumb€r.. ____.r_
fr
C H R I SC o d e . . . . . . . . . . . . . . . . . . . ZDP fr SYNONYM INDEX
BoilingPoint................. . . Qecomooses'C-'F Many chemicals have several names. Of these, one may be a
Appearance-Odor-Light
Specific Gravity-l.10
20'C (solid)
yellow liquid; sweet odor
to 1.12 at 20'C (liquid); 1.6 at

Frezing Point...................egur-psil1l-g'3
_"c
-:F
_'F
II common name and several are chemical names. Many chemicals also
use trade names.
VaporPressure 20'C (68'F)(mmHg)........ Low
Chemical Family-Unassigned Reidvrpor Prwure (Dsir)........................... Low
vapor Pr€ssure 46'C (115"F)(Dcir)............ Low In this book an attempt was made to list the data sheets by the
Pollution Category-USEPA - IMO A v a p o r D e n s i t y ( A i r t , 0 ) . . . . . . . . . . . . . . . . . . .- . . . . . . . .
Applicable Bulk Reg. 46 CFR Subchapter........ D. O Solubility in Wster Neolioible names most likey to be used. Trade names were omitted in most cases.
An attempt was made to list every synonym likely to be in use in

GradeD or E: Combustible liouid the bulk shipping industry.
El€ctricrl Group-NA
Ceneral-Hydrogen sultide vapors may be evolved il lhe material is heated in excess of 150'F.
In listing these chemicals, a single-letter,greek-letter or a numeri-
cal prefix was ignored in alphabetizing.
F h s h P o i n i ( " n . . . . . . . . . . . . . . . . . . . . . . . . .-. 1. .5. 0
I'hmmsble Limitr..........................Unavailable
Autoignition Temp. ('F) ................Unavailable To Find Look Up
Extinguishin8 A8crti.....................Dry chemical, COz
Speciel Fire Prtredurg................ Fire lighters should be equipped with slt-contained breathing apparatus.
p-Acetaldehyde Paraldehyde
Acetic acid anhydride Acetic anhydride
HEALTH HAZARD DATA
Ilealth Haard RrtinBr Odor'lhrcshold(ppm) PEL,/TWA(pDd TI,V,/TWA(Dpn) Acetic acid, butyl ester n-Butyl acetate
Unavailable O7 10 ppm (H,S) 10 ppm (H,S) Acetic acid, iso-butyl ester iso-Butyl acetate
Genersl-lrrilating on prolonged contact with th€ skin; severe swslling and destructionot tissue may result in a
few hours. There is no inhalationhazard al room tomperalure.Skin p€netration is high. but there is no Acetic acid, ethenyl ester Vinyl acetate
nazato.
Symptoms-Red, swollen skin; coughing.
Acetic acid, ethyl ester Ethyl acetate
Short Exp6ure Tolerance-Skin penetratronat toxic levels-3.16 millilitersper 1000 grams of body weight; no
illness in 6 hour exposure. Minimumconcentrationfound fatal alter one hour exposure-600 ppm (HrS). Acetic acid glacial Acetic acid
ExposurePreedueUnavailable.
Acetic acid, isopropyl ester iso-Propyl acetate
Acetic acid, methyl ester Methyl acetate
Acetic acid, l-methylpropyl ester sec-Butyl acetate
REA(NIVITY DATA Acetic acid, n-propyl ester n-Propyl acetate

Stability-Anlioxidanl, may decomposewith evolution ol H,S if heated about 150'F. Contaminationby acid may
set up conditionsfor evolution of H,S. Contaminationby water effects stabitity. Acetic acid, sec-butyl ester sec-Butyl acetate
Compstibility-Msterial: No corrosiveor destructiveeflect on steel, wood or cloth. Normal materialsmay b€ Acetic acid, vinyl ester Vinyl acetate
used; may solten natural rubber and some paints. Acetic aldehyde Acetaldehyde
Cargo: Group 34 o{ compatibilitychart. Acetic ester Ethyl acetate
Acctic cther Ethyl acetate

Rubber Protective clothing, sell-contained breathing apparatus, etc. Cover with soda ash. Clean up rn(l
I Acctic oxidc Acetic anhydride
neutralizewith diluted hydrochloricacid and wash with excess water. Ar't't ylt'nc tct rachltlride l, 1,2,2-T etrach I oroethane
Rcnrrks: I. Unassrgnad
It r rDill mcu6, cdl the Nrtionrl R6mns Cot r. 8II-a2.-8t02. tx At'clyl oxitlc
At'roleic nt'id
Acetic anhydride
Acrylic acid
A c r y l u r t r t d ct n o n ( ) n r e r Acrylamide solution
Iti
3t2 1t1
To Find Look Up
To Find Look Up
Acrylic acid amide Acrylamide solution Aminocaproic lactam Caprolactam solution

Acrylic acid, iso-butyl ester iso-Butyl acrylate Aminocyclohexane Cyclohexylamine
Acrylic acid, n-butyl ester n-Butyl acrylate Aminoethane Ethylamine
Acrylic acid, ethyl ester Ethyl acrylate Aminoethanol Ethanolamine
2-Aminoethanol Ethanolamine
Acrylic acid, 2-ethylhexyl ester 2-Ethylhexyl acrylate
Acrylic acid, isodecyl ester iso-Decyl acrylate beta-Aminoethyl alcohol Ethanolamine
Acrylic acid, methyl ester Methyl acrylate bis(2-Aminoethyl)amine Diethylenetriamine
Acrylic amide Acrylamide solution 2-[(2-Aminoethyl)amino]ethanol Aminoethylethanolamine
Albone Hydrogen peroxide N-(Aminoethyl)ethanolamine Aminoethylethanolamtne
N-(2-Aminoethyl)ethanolamine Aminoethylethanolamine
Alcohol Ethyl alcohol
Alcohol anhydrous Ethyl alcohol N,N'-bis(2-Aminoethyl)ethylene- Triethylenetetramine
Alcohol C-l Methyl alcohol diamine
Alcohol C-10 n-Decyl alcohol Aminomethane Methylamine solution
Alcohol C-I3 Tridecanol I -Amino-2-Methylpropane iso-Butylamine
2- Amino -2- methylpropane tert-Butylamine
Alcohol C-2 Ethyl alcohol Aminophen Aniline
Alcohol C-3 Propyl alcohol, iso- or n-
isomers l-Aminopropane Propylamine
Alcohol C-4 Butyl alcohol,iso-,n-, sec- 2-Aminopropane iso-Propylamine
or tert- isomers l-Amino-2-propanol iso-Propanolamine
3-Amino-1-propanol Propanolamine
Alcohol C-5 n-Amyl alcohol Ammonia Ammonia, anhydrous
Alcohol C-6 Hexanol
Alcohol C-8 Z-F.;thylhexanol or iso-Octyl Ammonia, aqueous Ammonia solutions
alcohol Ammonia gas Ammonia, anhydrous
Aldehyde Acetaldehyde Ammonia water Ammonia solutions
Ammonium hydroxide Ammonia solutions
Aldehyde-collidine 2-Methyl-5-ethylpyridine Ammonium monosulfide solution Ammonium sulfide solution
Aldehydine 2-Methyl-5-ethylpyridine
Alkylbenzene Dodecylbenzene AMS alpha-Methylstyrene
Alkyl (C7-C9) nitrate 2-Ethyl hexyl nitrate Anryl acctitte iso-Amyl acctate
Allene-methyl acetylene mixture Methyl acetylene-Propadiene scc-Anryl ||celt|to iso-Amyl acctatr:
mixture Atnl'llt t'ttc cslcl iso Amyl acetate
l - A r r r y lt l c o h o l n-n rnyl alcohol
Allyl trichloride 1,2,3-Trichloropropane
Aminobenzene Aniline
l-Aminobutane
2-Aminobutane
n-Butylamine
sec-Butylamine
t: I r n t n | | r y - nA n t V l n l r ' o l t ( ) l
Anryl rrklchyrlr
Attttl t rllltnol
lr Anryl :rlcohol
rr- Vrrlcraldehyde
I lt'xitrrol
2-Aminoisobutane tcrt-Butylaminc Arrrylhydrdc Pcntanc
il4
l i
ilt
lt
To Find Look Up To Find Look Up
An Acrylonitrile 1,2-Benzenedicarboxylicacid Phthalic anhydride
anhydride
Anesthesia ether Ethyl ether
Anesthetic ether Ethyl ether Benzene,1,2-dichloro- o-Dichlorobenzene
Aniline oil Aniline Benzene,1,3-diisocyanatomethyl- Toluene diisocyanate
Anprolene Ethylene oxide Benzene,dimethyl- Xylene, o-, m- or p- isomers
Ant oil, artificial Furfural Benzene, hexahydride Cyclohexane
Benzene, hexahydro- Cyclohexane
Aqua ammonia Ammonia solutions
Aqua fortis Nitric acid (56 to 68Vo) Benzene,hydroxy- Phenol
Aqua fortis Nitric acid (95Vo) Toluene
Benzene,methyl-
Arachis oil Peanut oil
Benzene, I -methylethyl- Cumene
Artificial oil of ants Furfural
Benzene, nitro- Nitrobenzene
Benzin Gasoline, motor
Asphalt bitumen Asphalt
Asphalt cement Asphalt
Benzinoform Carbon tetrachloride
Asphaltum Asphalt Benzol Benzene
Asymmetrical Dichloroethane l,l-Dichloroethane Benzole Benzene
Azabenzene Pyridine Benzyl n-butyl phthalate Butyl benzyl phthalate
Bicarburetted hydrogen Ethylene
Azacyclohelane Hexamethyleneimine
Azine Pyridine Biethylene Butadiene
Azotic acid Nitric acid (56 to 68%) Bimethyl Ethane
Azotic acid Nitric acid (95Vo) Biphenyl-diphenyl ether mixture Diphenyl-Diphenyl ether
B mixture
Bis(2-chloroethyl)ether 2,2' -Dichloroethyl ether
Babulum oil Neatsfoot oil Bitumen Asphalt
Banana oil iso-Amyl acetate
Battery acid Sulfuric acid { Bivinyl Butadiene
BBP Butyl benzyl phthalate t
Blue oil Aniline
Benenamine Aniline Bottled gas t.iquefied petroleum gas
llrazil wax ('urnauba wirx
Benzenamine Aniline lf rimstone S r r l f u r ,m o l t c n
Benzene carbinol Benzyl alcohol
Benzene ctiloride Chlorobenzene ' llrontofuntc I r tl r v l t ' n ct l i b r o m i d e
Benzene,chloro- Chlorobenzene l l r o n r o n r cltr l n e N ' l t 'ltr v ' lh r o t t t t t l c
Benzene,chloromethyl- Benzyl chloride 'l
ll l X nrrrtrrrer l i t ' t t z c l r t ' , o l r t c n c .X y l e n e
l|ltJ(lur('s
Benzeneconcentrate Benzene,Toluene, Xylene l,I llutrrrlrcnc llrrt:rtlicnc
rnix t rlrcs
'l
Benzcncdiamine,ar-methyl- olucncdiamine rrlplu, gnnrnrnlhtnrlicne l l r r tl r l i t ' n c

ll7
-----A* -
To Find Look Up To Irind Look Up
Butaldehyde n-Butyraldehyde Butyl alcohol n-Butyl alcohol

Butanal n-Butyraldehyde Butyl aldelrycle n-Butyraldehyde
n-Butanal n-Butyraldehyde iso-Butyl alclclryde iso-Butyraldehyde
l-Butanamine n-Butylamine n-Butyl aldchydc n-Butyraldehyde
Butylaminc Butylamine, iso-, n-, sec- or
2-Butanamine sec-Butylamine tert- isomers
1-Butanamine,N-butyl- Dibutylamine
Butane n-Butane Ilutylaminc n-Butylamine
Butane-1,3-diol 1,3-Butylene glycol N - t l u t y l -| - b u l a l l l n l i n c Dibutylamine
1,3-Butanediol 1,3-Butylene glycol n-Butylclrbirrol n-Amyl alcohol
Butyl Clrbitol Diethylene glycol butyl
Butanic acid n-Butyric acid ether
Butanoic acid n-Butyric acid Butyl Cclkrsolve Ethylene glycol butyl ether
Butanol n-Butyl alcohol
1-Butanol n-Butyl alcohol Butyl diglycol Diethylene glycol butyl
2-Butanol sec-Butyl alcohol ether
Butyl dioxitol Diethylene glycol butyl
2-Butanol acetate sec-Butyl acetate ether
n-Butanol n-Butyl alcohol l-Butene Butylene
Butanols Butyl alcohol, n-, sec- or alpha-Butylene Butylene
tert- isomers beta-Butyleneglycol 1,3-Butyleneglycol
sec-Butanol sec-Butyl alcohol
Butylene hydrate sec-Butyl alcohol
tert-Butanol tert-Butyl alcohol 1,2-Butylene oxide, stabilized 1,2-Butylene oxide
2-Butanone Methyl ethyl ketone alpha-Butylene oxide 1,2-Butylene oxide
2-Butenal Crotonaldehyde Butyl ethanoate n-Butyl acetate
trans-2-Butenal Crotonaldehyde Butyl ether n-Butyl ether
Butene Butylene
Butyl 2-methacrylate Butyl methacrylate
cis-Butenedioic anhydride Maleic anhydride n-Butyl methacrylate Butyl methacrylate
Butene resins Polybutene n-Butyl alpha-methacrylate Butyl methacrylate
l-Butoxy butane n-Butyl ether tert-Butyl methyl ether Methyl tert-butyl ether
Butoxydiethylene glycol Diethylene glycol butyl Butyl 2-methyl-2-propenoate Butyl methacrylate
ether
2-Butoxy ethanol Ethylene glycol butyl ether Butyl oxitol Ethylene glycol butyl ether
n- llutyl-2-propenoate n-Butyl acrylate
2-(2-Butoxyethoxy)ethanol Diethylene glycol butyl llrrtyraldt'hyde n-Butyraldehyde
ether llutyric acid n-Butyric acid
Butyl acetate i s o - B u t y la c e t a t e l l r r ty r i c l l c o l t o l n-Butyl alcohol
Butyl acetate n - B u l y la c e t a t e
n ( ) r n r i l l -l u t y l a c c t a t e n-Butyl acctate llutyric nklehvde n-Butyraldehydc

ilt
f t
To Find
c
Look Up
l r To Find Look Up
bis(2-Chloroethyl)ct her 2,2'-Dichloroethyl ether

Camphor tar
Capric alcohol
Naphthalene
n-Decyl alcohol
I bis-beta-Chl()roethylcther
Chlorohydric acid
2,2'-Dichloroethyl ether
Hydrochloric acid
epsilon-Caprolactam Caprolactam solution
Carbinol Methyl alcohol bis(2-ChloroisopropyI )cther 2,2'-Dichloroisopropyl ether
Carbitol solvent Diethylene glycol ethyl Chloromethane Methyl chloride
ether (Chloronrcthyl)bcnzene llcnzyl chloride
Chloromethyloxirane Epichlorohydrin
Carbolic acid Phenol I -Chloro-2-nitrobenzene o-Chloronitrobenzene
Carbon bisulfide Carbon disulfide
Carbon bisulphide Carbon disulfide 2-Chloro- I -nitrobenzene o-Chloronitrobenzene
Carbon disulphide Carbon disulfrde Chloronitrobenzenes o-Chloronitrobenzene
Carbon tet Carbon tetrachloride Chlorophenols, liquid 2,4-Dichlorophenol
I -Chloro-2-propene Allyl chloride
Cellosolve Acetate Ethylene glycol ethyl ether 3-Chloropropene Allyl chloride
acetate
Cellosolve Solvent Ethylene glycol ethyl ether 3-Chloro- 1-propene Allyl chloride
Chamber acid Sulfuric acid 3-Chloropropylene Allyl chloride
Chinese bean oil Soybean oil alpha-Chloropropylene Allyl chloride
2-Chloropropylene oxide Epichlorohydrin
Chlorallylene Allyl chloride gamma-Chloropropylene oxide Epichlorohydrin
Chlorate of soda Sodium chlorate solution
2-Chlorethanol Ethylene chlorohydrin Chlorosulfuric acid Chlorosulfonic acid
Chlorex 2,2' -Dichloroethyl ether Chlorothene l, l, l-Trichloroethane
Chlorinated hydrochloric ether 1,1-Dichlorobthane alpha-Chlorotoluene Benzyl chloride
omega-Chlorotoluene Benzyl chloride
Chloroacetic acid, liquid Chloroacetic acid Chlorox Sodium hypochlorite
alpha-Chloroallyl chloride 1,3-Dichloropropene solution
gamma-Chloroallyl chloride I,3-Dichloropropene
Chlorobenzol Chlorobenzene Chlorsulfonic acid Chlorosulfonic acid
I -Chloro-2, 3-epoxypropane Epichlorohydrin Chlorsulfuric acid Chlorosulfonic acid
('hlorylen Trichloroethylene
3-Chloro- 1,2-epoxypropane Epichlorohydrin ('idcx Glutaraldehyde solution
Chloroethane Ethyl chloride ('rrrtrntrrcne Styrene monomer
2-Chloroethanol Ethylene chlorohydrin
Chloroethene Vinyl chloride ('utttnltroI Styrcncm()nomer
2-Chloroethyl alcohol Ethylene chlorohydrin ('onl rrrr;rlrlhl llt'ttzctrt'
('onl otl ( ' r t t t l t 'o i l
Chloroethylene Vinyl chloride ('onl otl K crost'nr'
('hloroclhyl ether 2 , 2 ' - l) i c h l o r ( ) c t h y le t h e r ('onl tlt cto.rrrlc ('rt'ilsolt'. ('()itl lOf
SCANNED BY MKP" &t BARIS A. 2004

120 uI
l l
Coal tar distillate Coal tar I,3-Cyclopentadiene Dicyclopentadiene

Coal tar light oil Benzene,Toluene, Xylene 1,3-Cyclopentadienedimer Dicyclopentadiene
mixtures Cymol p-Cymene
Coal tar naphtha Benzene
Codoil Rosin oil D
DCEE 2,2'-Dichloroethyl ether
Coke oven light oil Benzene, Toluene, Xylene D.D. turpentine Turpentine
mixtures DEA Diethanolamine
Colamine Ethanolamine Dead oil Creosote, coal tar
Cologne spirit Ethyl alcohol DEAE Diethylethanolamine
Colonial spirits Methyl alcohol
Deanol Dimethylethanolamine
Columbian spirits Methyl alcohol l-Decanol n-Decyl alcohol
Creosote from coal tar Creosote, coal tar decylbenzenesulfonic acid; Un-, Alkylbenzenesulfonic acid
Creosote oil Creosote, coal tar Do-, Tri-, Tetra-, Penta- or
C r e s o l( 2 - , 3 - , 4 - ) Cresols Hexa-
Cresylic acid Cresols
DEG Diethylene glycol
Cresylol Cresols DEN Diethylamine
o-Cresyl phosphate Tricresyl phosphate Denatured alcohol Ethyl alcohol
Crotenaldehyde Crotonaldehyde Detergent alkylate #2 Dodecylbenzene
Crotonaldehyde, stabilized Crotonaldehyde D-Glucitol Sorbitol
Crotonic aldehyde Crotonaldehyde
Diacetone Diacetone alcohol
Crude coal tar Coal tar 2,4-Diaminotoluene Toluenediamine
crude Epichlorohydrin Chlorohydrins (crude) 2,2'-D iaminod ieth ylamine Diethylenetriamine
Crude solvent coal tar naphtha Coal tar naphtha solvent 1,2-Diaminoethane Ethylenediamine
Crystalite Methyl methacrylate 1,I 1-Diamino-3,6,9- Tetraethlyenepentamine
Cumol Cumene triazaundecane
Cyanoethane Propionitrile Diammonium sulfide solution Ammonium sulfide solution

2-Cyanoethanol Ethylene cyanohydrin DIBK Diisobutyl ketone
Cyanoethylene Acrylonitrile I,2-Dibromoethane Ethylene dibromide
Cyanomethane Acetonitrile synr-f)ibromoethane Ethylene dibromide
2-Cyanopropene Methacrylonitrile I ) i - r r - h t yr tl a m i n e Dibutylamine
Cychlohexanamine Cyclohexylamine r r -I ) r h r rvt l ; r r r r i n e Dibutylamine

Cyclohcxatricnc Benzene I ) t - (r r ' h r rvtl ) l n r i n e Dibutylamine
C y c k r h c x y lu l c o h o l Cyclohexanol | ) r b r r yt l c t h e r n-Butyl ether
('yt'lohcryl kclorrc Cyclohcxanone l ) t r r l r r r l l . cl t l r c f n-Butyl ether
I
Cyckr;rrrllthcnc Dicyclopentadicne rr | )rhutylctlrcr n-llutyl ethcr
l2r
Dibutyl ethers n-Butyl ether Diethylene ether 1,4-Dioxane

Dibutyl oxide n-Butyl ether Diethylene imidoxide Morpholine
1,2-Dichlorobenzene o-Dichlorobenzene Diethylene oxide 1.4-Dioxane
o-Dichlorobenzol o-Dichlorobenzene Diethylene oxide Tetrahydrofuran
2,2' -Dichlorodiethyl ether 2,2' -Dichloroethyl ether Diethylene oximide Morpholine
1.2-Dichloroethane Ethylene dichloride Diethylenimide oxide Morpholine

sym-Dichloroethane Ethylene dichloride N,N-Diethylethanamine Triethylamine
I , I -Dichloroethene Vinylidene chloride N,N-Diethylethanolamine Diethylethanolamine
Dichloroether 2,2' -Dichloroethyl ether Diethyl ether Ethyl ether
I , I -Dichloroethylene Vinylidene chloride Di-(2-ethylhexyl)phthalate Dioctyl phthalate
asym-Dichloroethylene Vinylidene chloride Diethyl-(2-hydroxyethyl)amine Diethylethanolamine

Dichloroethyl ether 2,2' -Dichloroethyl ether Diethylolamine Diethanolamine
beta, beta'-Dichloroethyl ether 2,2' -Dichloroethyl ether Diethyl oxide Ethyl ether
sym-Dichloroethyl ether 2,2' -Dichloroethyl ether Difluorochloromethane Chlorodifluoromethane
Dichloroethyl oxide 2,2' -Dichloroethyl ether Difl uorodichloromethane Dichlorodifl uoromethane
Dichloroisopropyl ether 2,2' -Dichloroisopropyl ether Difl uoromonochloromethane Chlorodifluoromethane

Dichlorophenol 2,4-Dichlorophenol
Dichloropropane
Dichloropropene
I,2-Dichloropropane ll 1,3-Diformylpropane
Diglycol
Glutaraldehyde solution
Diethylene glycol
1,3-Dichloropropene Diglycol monobutyl ether Diethylene glycol butyl
1,3-Dichloropropylene
alpha, gamma-Dichloropropylene
1,3-Dichloropropene
1,3-Dichloropropene
lr 1,3-Dihydroxybutane
ether
1,3-Butyleneglycol
Dicy; 3a, 4, 7, 7a-

1,4-Dicyanobutane
Dicyclo- 1,4-pentadiene
Dicyclopentadiene
Adiponitrile ll 2,2'-Dihydroxydiethylamine
Dihydroxydiethyl ether
Diethanolamine
Diethylene glycol
Dicyclopentadiene 2,2'-Dihydroxydipropylamine Diisopropanolamine
Diesel fuel Diesel oil 2,2-Dihydroxydipropyl ether Dipropylene glycol
I,2-Dihydroxyethane Ethylene glycol
Diethyl n-Butane
Diethylaminoethanol Diethylethanolamine Di-beta-hydroxyethoxyethane Triethylene glycol
2-Diethylaminoethanol Diethylethanolamine Di-(2-hydroxyethyl)amine Diethanolamine
2-N-Diethylaminoethanol Diethylethanolamine 2,2'-Dihydroxyethyl ether Diethylene glycol
2-Diethylaminoethyl alcohol Diethylethanolamine 2,2'-Dihydroxyisopropyl ether Dipropylene glycol
| )iisobutene Diisobutylene
beta-Diethylaminoethyl alcohol Diethylethanolamine
Diethylbenzene(1,2-, 1,3-or 1,4-) Diethylbenzene | ) r i s o b r r t y l c n ci s, o m c r i cc o m p ' s Diisobutylene
Diethylbenzene;m- or o- isomers Diethylbenzcne 1 . 4 | ) r r r o ty l n o l o l ( ) l u c n c Toluene diisocyanate
Diethylene dioxide 1,4-Dioxane . 0 . . |1) r r r r xv' r r r o r lpr l 1 ( . s 1 y I l n c t h a n e Diphenylmethanc
1,4-Diethylenedioxide 1,4-Dioxanc
I diisocyanate
124 12t
I SCANNED BY MKP & BARIS A. 2004
To Find Look Up
To Find Look Up
sym-Diisopropylacetone Diisobutyl ketone
4,4'-Diphenylrncthanc [)iphenylmethane
Diisobutyl ketone diist>cyanatc rliisocyanate
sym-5-Diisopropylacetone
Diphen yl methanc-4,4'- Diphenylmethane
Diisopropyl ether iso-Propyl ether
diisocyanatc diisocyanate
Diisopropyl oxide iso-Propyl ether
Dimethyl Ethane
D i p h e n y l o x i d c - d i p h e n ym
l ixture Diphenyl-Diphenyl ether
Dimethylamine, anhydrous Dimethylamine
mixture
Dipropylamine Di-n-propylamine
2-(Dimethylamino)ethanol Dimethylethanolamine
Dipropylmethane Heptane
beta-Dimethylaminoethyl alcohol Dimethylethanolamine
Dithiocarbonic anhydride Carbon disulfrde
Dimethyl benzene Xylene, o-, m- or p- isomer
1,2-Dimethyl benzene o-Xylene Divinyl Butadiene
1,3-Dimethyl benzene m-Xylene DMA Dimethylmethyl amine
DMF Dimethylformamide
1,4-Dimethyl benzene p-Xylene DMFA Dimethylformamide
1,3-Dimethylbutyl acetate Methyl amyl acetate n-Dodecylbenzene Dodecylbenzene
Dimethyl carbinol iso-Propyl alcohol
Dimethylene oxide Ethylene oxide Dodecylbenzenesulfonic acid Alkylbenzenesulfonic acid
Dimethyl ethylamine tert-Butylamine alpha-Dodecylene Dodecene
Dolcymene p-Cymene
I, I -Dimethylethylamine tert-Butylamine DOP Dioctyl phthalate
N,N-Dimethylformamide Dimethylformamide Dowanol DB Diethylene glycol butyl
2,6-Dimethyl-4-heptanol Diisobutyl carbinol ether
2,6-Dimethyl-4-heptanone Diisobutyl ketone
Dimethyl-1-hexanol iso-Octyl alcohol Dowanol DE Diethylene glycol ethyl
ether
N,N-Dimethyl-N-(2- Dimethylethanolamine Dowanol DM Diethylene glycol methyl
hydroxyethyl)amine ether
Dimethyl ketone Acetone Dowanol EB Ethylene glycol butyl ether
Dimethylmethane Propane Dowanol EE Ethylene glycol ethyl ether
Dioxan 1,4-Dioxane
Dowanol EM Ethylene glycol methyl
Dioxane 1,4-Dioxane ether
p-Dioxane 1,4-Dioxane l)owthcrm A Diphenyl-Diphenyl ether
1,3-Dioxophalan Phthalic anhydride mixture
rI l)owtlrcrmE o-Dichlorobenzene
DIPA Diisopropanolamine
DIPA Diisopropylaminc l)l,A Di-n-propylamine
Diphenyl-diphenyl oxide mixture D i p h e n y l -D i p h c n y l c l h e r

l i l)ripolcne Benzene, Toluene, Xylene
mlxlurc mixtures
I ) r y e l c n t t c r sr u r p hht u Naphtha: Stoddard solvent
fi
12?
,*Ca&i!8!s@d,!!|rua. SCANNED BY MKP & BARIS A. 2004
Drycleaners safety solvent Naphtha: Stoddard solvent Ethane, 1,1-dichloro- I,l-Dichloroethane

Dutch liquid Ethylene dichloride Ethane, 1,2-dichloro- Ethylene dichloride
Dutch oil Ethylene dichloride 1,2-Ethanediol Ethylene glycol

1,2-Ethanediol diacetate Ethylene glycol diacetate
E
Ethanenitrile Acetonitrile
Earthnut oil Peanut oil Ethane, 1,l'-oxybis- Ethyl ether
EB Ethylbenzene Ethane, l, l'-oxybis[2-chloro- 2,2'-D ichloroethyl ether
EDB Ethylene dibromide
EDC Ethylene dichloride Ethane, pentachloride Pentachloroethane
Edible tallow Tallow Ethane, pentachloro- Pentachloroethane
Ethane, l, 1,2,2-tetrachloro- l, 1,2,2-T etr achloroethane
EE Solvent Ethylene glycol ethyl ethe: Ethane, l, l,l-trichloro- l, l, I -Trichloroethane
Ektasolve DB Solvent Diethylene glycol butyl Ethane trichloride I, I,2-Trichloroethane
ether
Ektasolve DE Solvent Diethylene glycol ethyl Ethane, l, 1,2-trichloro- l, I,2-Trichloroethane
ether Ethanoic acid Acetic acid
Ektasolve DM Solvent Diethylene glycol methyl Ethanoic anhydride Acetic anhydride
ether Ethanol Ethyl alcohol
Ethanol, 2-butoxy- Ethylene glycol butyl ether
Ektasolve EB Solvent Ethylene glycol butyl ethe
Elayl Ethylene Ethanol, 2-ethoxy- Ethylene glycol ethyl ether
Embafume Methyl bromide Ethanol, 2-ethoxy-, acetate Ethylene glycol ethyl ether
Engravers acid Nitric acid (56 to 68Vo) acetate
Engravers acid Nitric acid (95Vo) Ethanol, 2-methoxy- Ethylene glycol methyl
ether
Engravers oil Nitric acid (56 to 68Vo) Ethene Ethylene
Engravers oil Nitric acid (95Vo)
EO Ethylene oxide Ethene, chloro- Vinyl chloride
1,2-Epoxybutane 1,2-Butylene oxide Ethene, 1,1-dichloro- Vinylidene chloride
Epoxyethane Ethylene oiide Ethene, tetrachloro- Perchloroethylene
1,2-Epoxyethane
1,2-Epoxypropane
Ethylene oxide
Propylene oxide
t- Ethene, trichloro-
Ethenylbenzene
Trichloroethylene
Styrene monomer
Erythrene Butadiene I ' l th c r Ethyl ether

Essenceof mirbane Nitrobenzene l ' l t h c r ,h i s ( 2 - c h l o r o - l - m e t h y l e t h y l ) 2,2' -Dichloroisopropyl ether
Ethanal Acetaldehyde l r t l r c rc y l r n i r t r r s P r o p i o n i tr i l e
I i t l r c r ,h v t l r o c l r l o r i c F . t h y lc h l o r i d e
Ethane carboxylic acid Propionic acid I i t l r r r rIr t n t ' l r k r r i t l e Trichloroethylene :
1,2-Ethanediamine Ethylcncdiamine
Ethane, 1,2-dibromo- Ethylcnc dibronride I il lror ycl lrrrrre l:thyl cthcr
r2t ll0

t
To Find Look Up To Find
2-Ethoxyethanol Ethylene glycol ethyl ether
I Ethyl ethanoate
Look Up
Ethyl acetate
Ethoxyethene Vinyl ethyl ether Ethylethylene Butylene
2-Ethoxyethylacetate Ethylene glycol ethyl ether
acetate
I Ethylformic acid
2-Ethyl hexanal
Propionic acid
2-Ethyl-3-propylacrolein
2-Ethyl-2-hexanal 2-Ethyl-3-propylacrolein
Ethylacetic acid
Ethyl aldehyde
n-Butyric acid
Acetaldehyde
I 2-Ethyl- l -hexanol 2-Ethyl hexanol
Ethylamine, anhydrous Ethylamine 2-Ethylhexyl alcohol 2-Ethyl hexanol
Ethylamine, aqueous solutions
Ethylbenzol
Ethylamine solution
Ethylbenzene
I bis(2-Ethylhexyl)phthalate
2-Ethylhexyl, 2-propenoate
Dioctyl phthalate
2-Ethylhexyl acrylate
Ethyl hydride Ethane
2-Ethylbutanol
2-Ethyl- l-butanol
Ethyl butanol
Ethyl butanol
I Ethyl hydroxide Ethyl alcohol
2-Ethyl butyl alcohol Ethyl butanol 5-Ethylidene bicyclo(2,2, l)-hept- Ethylidene norbornene
Ethyl carbinol
Ethyl cyanide
n-Propyl alcohol
Propionitrile
I 2-ene
Ethylidene chloride l,l-Dichloroethane
Ethylidene dichloride 1,1-Dichloroethane
Ethyl dimethylmethane
Ethylene acetate
iso-Pentane
Ethylene glycol diacetate
I l, 1-Ethylidene dichloride I , 1-Dichloroethane
Ethylene alcohol Ethylene glycol Ethylidene norbornylene Ethylidene norbornene
Ethylene bromide Ethylene dibromide I Ethylidene norcamphene
Ethyl 2-methacrylate
Ethylidene norbornene
Ethyl methacrylate
Ethylene carboxylic acid Acrylic acid
Ethyl alpha-methacrylate Ethyl methacrylate
Ethylene chlorhydrin Ethylene chlorohydrin I 6-Ethyl-2-methyl benenamine 2-Methyl-6-ethylaniline
Ethylene chloride Ethylene dichloride
Ethyl methyl carbinol sec-Butyl alcohol
Ethylene diacetate
Ethylenediamine, anhydrous
Ethylenediamine I Ethyl methyl ketone
Ethyl 2-methyl-2-propenoate
Methyl ethyl ketone
Ethyl methacrylate
Ethylene dihydrate Ethylene glycol
3-Ethyl-6-methyl pyridine 2-Methyl-5-ethylpyridine
2,2' -Bthylene dioxybis(ethanol) Triethylene glycol T 5-Ethyl-2-methyl pyridine 2-Methyl-5-ethylpyridine
2,2' -Bthylene dioxydiethanol Triethylene glycol
Ethyl nitrile Acetonitrile
Ethylene glycol monoacrylate
Ethylene glycol dihydroxy-
2-Hydroxyethyl acrylate
Triethylene glycol
I Ethylolamine
Ethyl oxide
Ethanolamine
Ethyl ether
diethyl ether 5-Ethyl-2-picoline 2-Methyl- 5-ethylpyridine
Ethylene glycol monoethyl ether Ethylene glycol ethyl ether

I I i t l r V lp r o p c r r o a l e Ethyl acrylate
Ethylene monochloride Vinyl chloride I jtlrvl J-pro1)cn()ale Ethyl acrylate
Ethylene tetrachloride
I r .ht y l c n e t r i c h l o r i d e
Perchloroethylene
Trichloroethylene
I I I l:thyl I propvlacyraldchyde
lrthvlrrrllrrtc
2-Ethyl-3-propylacrolein
Diethyl sulfate
N-lithylcthanamine Diethylamine I | :tlryl-o.lolurrlrrrc 2-Mct hyl-6-ethylaniline
I lll

I
To Find Look Up
To Find
Ethyl vinyl ether

Look Up
Vinyl ethyl ether

I 2-Furanmethanol Furfuryl alcohol
Ethoxy diglycol Diethylene glycol ethyl Furan, tetrahydro- T'ctrahydrofuran
2-(2 -Ethoxy eth o x y)ethano I

ether
Diethylene glycol ethyl
I Furfuralcohol
Furfuraldchyde
Furfuryl alcohol
Furfural
ether Furfuran carboxylic aldehyde Furfural
2-[2-(2-Ethyoxyethoxy)- Ethoxy triglycol

I Furfurole Furfural
ethoxy]ethanol Furole Furfural
Ethyoxytriethylene glycol
EVE
Ethoxy triglycol
Vinyl ethyl ether
I Furylcarbinol Furfuryl alcohol
2-Furylcarbinol Furfuryl alcohol
alpha-Furylcarbinol Furfuryl alcohol
I
Ft2 Dichlorodifl uoromethane 2-Furylmethanol Furfuryl alcohol
Fermentation alcohol
Fermentation butyl alcohol
Fetilizer acid
Ethyl alcohol
iso-Butyl alcohol
Sulfuric acid
t Fyde
G
Formaldehyde solutions
Flourocarbon 22
Formalin
Chlorodifluoromethane
t Genetron
Glacial acetic acid
Freon
Acetic acid
Glutaral Glutaraldehyde solution
Formalith Formaldehyde solutions
Formic acid, methyl ester Methyl formate I Glutaric dialdehyde
Glutarol
Formic aldehyde solution Formaldehyde solutions
Formol Formaldehyde solutions
I Glycerol
Glycol
Glycerine
Ethylene glycol
Formylic acid Formic acid
Glycol alcohol Ethylene glycol
Formyl trichloride Chloroform
Freon 12 Dichlorodifl uoromethane I Glycol bis(hyroxyethyl)ether
Glycol chlorohydrin
Triethylene glycol
Ethylene chlorohydrin
Freon 22 Chlorodifluoromethane
Fuel oil no. I Kerosene
I Glycol
Glycol
cyanohydrin
diacetate
Ethylene cyanohydrin
Fuel oil no. l-D Diesel oil
Fuel oil no. 2-D Glycol dibromide Ethylene dibromide
Diesel oil
Fuel oil no. 6 Bunker C I Glycol
(ilycol
dichloride
e t h y l e n ee t h e r
Ethylene dichloride
1,4-Dioxane
Fuming sulfuric acid Oleum
Fural Furfural
I
I ( i l y c o l r n o n o c t h y lc t h e r
( i l y c o l r r r o r r o t . l l t yclt l r c r a c c t a t e
Ethylene glycol ethyl ether
Ethylene glycol ethyl ether
2-Furaldehyde Furfural
2-Furancarbinol Furfuryl alcohol I acetate
2-Furancarbonal Furfural I ( i l y c o l n t ( ) n ( ) r n ( . t l l ry.ll h c r Ethylene glycol methyl
ether
2-Furancarboxaldehyde Fur[ural
2,5-Furandione I ( ) l y ey l c l eo h o l Glyccrine
Maleic anhydride
I
t32
"
Grain alcohol Ethyl alcohol High temperature coal tar Coal tar
Groundnut oil Peanut oil H i g h t s o l v e n tn a p h t h a Coal tar naphtha solvent
L-Gulitol Sorbitol Hioxyl Hydrogen peroxide
Gum camphor Camphor oil
Gum spirits Turpentine f13N Ammonia, anhydrous
Homopiperidine Hexamethyleneimine
Gum turpentine Turpentine Hoof oil Neatsfoot oil
H Household ammonia Amnrtlnia solutions
Hydracrylic acid, beta-lactone beta-I)ropiolactone
Halon 122 Dichlorodifl uoromethane
Hard wax Paraffin wax Hydracrylonitrile Ethylene cyanohydrin
HEA 2-Hydroxyethyl acrylate Hydrochloric ether Ethyl chloride
Heavy industrial fuel oil Bunker C Hydrocyanic ether Propionitrile
Heavy oil Creosote, coal tar
Hydrogencarboxylic acid Formic acid
Hydrogen chloride Hydrochloric acid
n-Heptane Heptane
n-Heptylethylene l-Nonene
Hydrogen dioxide Hydrogen peroxide
Heptyl hydride Heptane
Hydrogen nitrate Nitric acid (56 to 68Vo)
Hexahydroaniline Cyclohexylamine
Hexamethyleneimine Hydrogen nitrate Nitric acid (95Vo)
Hexahydroazepine
Hydroperoxide Hydrogen peroxide
Hexahydrobenzene Cyclohexane 2-Hydroxethylamine Ethanolamine
Hexahydrophenol Cyclohexanol
Hexamethylene Cyclohexane beta-Hydroxethylamine Ethanolamine
Hexanaphthene Cyclohexane Hydroxybenzene Phenol
Hexane n-Hexane l-Hydroxybutane n-Butyl alcohol
2-Hydroxybutane sec-Butyl alcohol
7,2,3,4,5,6-Hexanehexol Sorbitol I -Hydroxy-2-cyanoethane Ethylene cyanohydrin
Hexanes Hexane, iso- or n- isomerf
l-Hexanol Hexanol Hydroxycyclohexane Cyclohexanol
n-Hexanol Hexanol bis[2-(2-Hydroxyethoxy)- Tetraethylene glycol
Hexanols Hexanol ethyllether
beta-Hydroxyethyl acrylate 2-Hydroxyethyl acrylate
Hexone Methyl isobutyl ketone bis(H yd roxyeth yl)amine Diethanolamine
sec-Hexyl acetate Methyl amyl acetate
Hexyl alcohol Hexanol bis(2-H yd roxyethyl)amine Diethanolamine
n-Hexyl alcohol Hexanol
tris(2-l I ytl roxyethyl)ether Diethylene glycol
scc-Hcxyl alcohol Ethyl butanol
| | v t l r o xy t ' tl r y l c th y l c r r e d i a m i n e Aminoethylethanolamine
N -l l - l I y t l r o x y c t h y l c t h y l c n e - Aminoet hylethanolamine
I lcxyl hydridc n-Hexane
tltnrrrtttc
I ligh-ritrcrrgthhydrogen peroxide Hydrogcrr peroxide
3t4
I
t
Look Up
To Find
N-Hydroxyethyl-1,2-
Look Up
Aminoethylethanolamine
I Isoacetophenone
To Find
Isophorone
ethylenediamine Isoamyl acetate iso-Amyl acetate
2-Hydroxyethyl 2-propenoate
l-Hydroxyhexane
2-Hydroxyethyl acrylate
Hexanol
I Isoamyl ethanoate
Isoamyl hydride
iso-Amyl acetate
is()-[)entane
alpha-Hydroxyisobutronitrile Acetone cyanohydrin 1.3-lsobenzofuandione Phthalic anhydride
alpha-Hydroxyisobutyronitrile Acetone cyanohydrin

T Isobutanal iso-Butyraldehyde
Hydroxymethyl benzene Cresols Isobutanol iso-tsutylalcohol
2-Hydroxymethylfuran-
4-Hydroxy-4-methyl-2-pentone
Furfuryl alcohol
Diacetone alcohol
I I s o b u t c n y lm e t h y l k c t o n c
Isobutyl acctale
Mesityl oxide
iso-Butyl aoetate
4-Hydroxy-4-methyl pentanone-2 Diacetone alcohol Isobutyl acrylate iso-Butyl acrylate
1-Hydroxymethylpropane iso-Butyl alcohol

I Isobutyl alcohol iso-Butyl alcohol
2-Hydroxy-2- Acetone cyanohydrin Isobutylaldehyde iso-Butyraldehyde
methylpropanenitrile
2-Hydroxynitrobenzene o-Nitrophenol
I Isobutylamine
mono-Isobutylamine
iso-Butylamine
iso-Butylamine
3-Hydroxypropanenitrile Ethylene cyanohydrin Isobutyl methyl carbinol Methylamyl alcchol
3-Hydroxypropionitrile Ethylene cyanohydrin

I Isobutyl methyl ketone Methyl isobutyl ketone
beta-Hydroxypropionitrile Ethylene cyanohydrin Isobutyl methyl methanol Methylamyl alcohol
2-Hydroxypropylamine
3-Hydroxypropylamine
iso-Propanolamine
Propanolamine
I Isobutyl-2-propenoate
Isobutyraldehyde
iso-Butyl acrylate
iso-Butyraldehyde
Hydroxytoluene Cresols Isobutyric aldehyde iso-Butyraldehyde
alpha-Hydroxytoluene Benzyl alcohol

t Isodecaldehyde, mixed isomers iso-Decaldehyde
2-Hydroxytriethylamine Diethylethanolamine Isodecyl acrylate iso-Decyl acrylate
Hypochlorite, solutions Sodium hypochlorite,
solution
I Isodecyl propenoate
Isonitropropane
iso-Decyl acrylate
2-Nitropropane
Isooctanol iso-Octyl alcohol
IBA iso-Butyl alcohol

I Isooctyl alcohol iso-Octyl alcohol
Illuminating oil Kerosene Isopentane iso-Pentane
2,2'-Iminobisethanol
2,2'-lminodiethanol
Diethanolamine
Diethanolamine
j I Isopentyl acetate
Isopropanol
iso-Amyl acetate
iso-Propyl alcohol
"l
I sopropanolamine iso-Propanolamine
l, l'-Iminodi-2-propanol
Impure camphor
Diisopropanolamine
Camphor oil
,I t l r o p r o p 1 ' t t sc y i l n i ( l e Methacrylonitrile
,I
Inedible tallow Tallow I roprolrcttvllrt'ttlctte alpha-Methylstyrene
IPA
iso- l
iso-Propyl alcohol
Omit prefix and look
I
up
I . l l r , t ; t 1 , t g 1111 v l ) r o p i t n c
I v r ; r 3r t 1 r 1I' n t ' t ' l t t l t '
iso-Propyl ether
iso-Propyl acetate
compound lrrgrnrpyInl'clolrc Mcthyl isobutyl ketonc
l:
ll
To Find
Isopropyl alcohol
Look Up
iso-Propyl alcohol
l l To Find
Lead tetramethyl
Look Up
Motor fuel anti-knock

Isopropylamine iso-Propylamine compounds
Isopropyl benzene
Isopropylcarbinol
Cumene
iso-Butyl alcohol
ll LHz Hydrogen (liquef,red)
Isopropyl ester of acetic acid iso-Propyl acetate Light camphor oil Camphor oil
Light naphtha Naphtha: VM & P
Isopropyl ether iso-Propyl ether Light oil Benzene, Toluene, Xylene
Isopropylideneacetone Mesityl oxide mixtures
4-Isopropyl-1-methyl benzene p-Cymene
Isopropyltoluene p-Cymene Ligroin (in U.S.A.) Mineral spirits, or naphthas
4-Isopropyl toluene p-Cymene Liquid ammonia Ammonia, anhydrous
Liquid bleach Sodium hypochlorite
p-Isopropyltoluene p-Cymene solution
Isotridecanol Tridecanol Liquid camphor Camphor oil
Tridecanol Liquid hydrogen Hydrogen (liquefied)
Isotridecyl alcohol
Isotron Freon
Liquid oxygen Oxygen (liquefied)
Isovaleral iso-Valeraldehyde
Liquid pitch oil Creosote, coal tar
Liquid rosin Tall oil
Isovaleraldehyde iso-Valeraldehyde
LNG Liquefied natural gas
Isovaleric aldehyde iso-Valeraldehyde
LOX Oxygen (liquefied)
Isovalerone Diisobutyl ketone
LPG Liquefied petroleum gas

Lye Caustic potash solution or
Javelle water Sodium hypochlorite
Caustic soda solution
solution
Judean pitch Asphalt M
K MAAc Methyl amyl acetate

MAN Methacrylonitrile
Katchung oil Peanut oil MAOH Methylamyl alcohol
Kerosine Kerosene MAPP Gas Methyl acetylene-Propadiene
Ketohexamethylene Cyclohexanone mixture
2-Ketohexamethylenimine Caprolactam solution Marsh gas Methane

Ketone propane Acetone MCA Chloroacetic acid
beta-keto-Propane Acetone MCB Chlorobenzene
. l MDI Diphenylmethane
L
diisocyanate
Laurylbenzene Dodecylbenzene
Lcad tetraethyl Motor fucl anti-knorck Ml:.A,700/o Ethylamine solution
c()nrp()und$ l\llrK Methyl ethyl ketone
I
ilt
t
MEP
To Find Look Up
2-Methyl- 5-ethylpyridine
I Methylacetic anhydride
To Find Look Up
Propionic anhydride
Metaphosphoric acid Phosphoric acid
Metaxylene m-Xylene I Methyl acetylene-allenemixture Methyl acetylene-Propadiene
mixture
Methacetonic acid
Methacide
Methacrylate monomer
Propionic acid
Toluene
Methyl methacrylate
I beta-Methylacrolein
2-Methylacrylic acid
Crotonaldehyde
Methacrylic acid
2-Methyl acetonitrile Acetone cyanohydrin
alpha-Methacrylic acid
Methacrylic acid, butyl ester
Methacrylic acid
Butyl methacrylate I Methylbenzene Toluene
Methylbenzol Toluene
Methacrylic acid, ethyl ester
Methacrylic acid, methyl ester
Methanal solution
Ethyl methacrylate
Methyl methacrylate
I alpha-Methylbivinyl
cis-Pentadiene-
1.3
1,3-Pentadiene
1,3-Pentadiene
1,3
trans-Pentadiene- 1,3-Pentadiene
Methanamine, N-methyl-
Methanamine, N-methyl-
Dimethylamine
Dimethylamine solution,
40%
I beta-Methylbivinyl Isoprene
l-Methylbutadiene 1,3-Pentadiene
Methanamine, N-methyl- Dimethylamine solution,
50%
I 2-Methyl- 1,3-butadiene
3-Methyl- 1,3-butadiene
Isoprene
Isoprene
Methane. bromo- 3-Methylbutanal iso-Valeraldehyde
Methane carboxylic acid
Methane, chloro-
Methyl bromide
Acetic acid
Methyl chloride
I 2-Methylbutane iso-Pentane
Methane, dichlorodifl uoro- 3-Methyl- I -butanol acetate iso-Amyl acetate
Methane, refrigerated liquid or

Dichlorodifl uoromethane
Liquehed natural gas

I Methyl iso-butenyl ketone
Methyl iso-butyl carbinol acetate
Mesityl oxide
Methyl amyl acetate
Natural gas, refrigerated liquid
Methane, tetrachloro-
Methane. trichloro
Uarbon tetrachloride
Chloroform
I Methyl iso-butyl carbinyl acetale Methyl amyl acetate
2-Methylbutyl ethanoate iso-Amyl acetate

Methanoic acid
Methanol
Formic acid
Methyl alcohol
I 3-Methyl butyraldehyde
Mcthyl carbinol
iso-Valeraldehyde
Ethyl alcohol
Mcthyl Carbitol Diethylene glycol methyl
Methenyl trichloride
2-Methoxyethanol
Chloroform
Ethylene glycol methyl
ether
I ether
Mcllryl ('clkxlrlvc Ethylcne glycol methyl

2-(2-Methoxyethoxy)ethanol Diethylene glycol methyl
ether I Methyl r'hhrroftrrm
c th c r
l, l, I -'I-richloroethane
|\lcthyl t !,nrrrrlc At'clrrrritrilc
2-[2-(2-Methoxyethoxy)- Methoxy triglycol
t'thoxVlt'tlrirnol
M c t h y l l c t . t n l . l tl r y d e r l'ropionaldchyde
I M c t h y l c r r ch t r h h r lr r l c
Mcth ylcrrc bn({'phcnyl
I )rclrlororrrctharre
I )iphcnyIrrrcthanc
Mctlrylrcetic rcid lr{x'ynnalc) tlitsocyarratc
Itroprorricacid
I ||l
.-*ai- jbc*fth-- -- SCANNED BY MKP & BARIS A. 2004
To Find Look Up
To Find Look Up
2-Methyl pentane iso-Hexane
Methylene bis-phenylisocyanate Diphenylmethane
2-Methyl -2,4-pentanediol Hexylene glycol
diisocyanate
4-Methyl-2-pentanol Methylamyl alcohol
Methylene chloride Dichloromethane
Methylene dichloride Dichloromethane
4-Methyl-2-pentanol acetate Methyl amyl acetate
Methylene oxide Formaldehyde solutions
4-Methyl-2-pentanone Methyl isobutyl ketone
4-Methyl-3-penten-2-one Mesityl oxide
Methylethene Propylene
4-Methyl-2-pentyl acetate Methyl amyl acetate
Methylethyl aniline 2-Methyl-6-ethylaniline
2-Methyl-2-petanol-4-one Diacetone alcohol
( I -Methylethyl)benzene Cumene
Methyl ethyl carbinol sec-Butyl alcohol
Methylphenol (2-, 3- or 4-) Cresols
Methylethylene Propylene
I -Methyl- I -phenylethylene alpha-Methylstyrene
2-Methylpropanal iso-Butyraldehyde
Methylethylmethane n-Butane
2-Methyl-2-propanamine tert-Butylamine
N-( I -Methylethyl)-2-propanamine Diisopropylamine
2-Methyl-l-propanol iso-Butyl alcohol
6-Methyl- l-heptanol iso-Octyl alcohol
Methyl hydride Methane
2-Methyl-2-propanol tert-Butyl alcohol
Methyl hydroxide Methyl alcohol
2-Methylpropenia acid Methacrylic acid
Methyl propenoate Methyl aarylate
Methylisoamyl acetate Methyl amyl acetate
Methyl 2-propenoate Methyl acrylate
Methyl isobutenyl ketone Mesityl oxide
2-Methylpropenoic acid Methacrylic acid
Methyl iso-butyl carbinol Methylamyl alcohol
Methylisopropylbenzene p-Cymene
2-Methylpropenoic acid Methyl methacrylate
I -Methyl-4-isopropylbenzene p-Cymene
I -Methylpropylacetate sec-Butyl aaetate
2-Methylpropyl acetate iso-Butyl acetate
Methyl methacrylate monomer, Methyl methacrylate
2-Methyl- I -propyl acetate iso-Butyl acetate
inh.
2-Methyl- I -propyl acrylate iso-Butyl acrylate
N-Methylmethanamine Dimethylamine
N-Methyl methanamine, 4O7o Dimethylamine solution,
l-Methyl propylamine sec-Butylamine
4OVo
2-Methylpropylamine iso-Butylamine
N-Methyl methanamine, 5OVo Dimethylamine solution,
N-(2-Methyl propyl)amine Diisobutylamine
so%
N,N-bis(2-Methylpropyl)amine Diisobutylamine
Mcthyl propyl benzene p-Cymene
Methylmethane Ethane
Methyl methanoate Methyl formate
h c t r - M c th y l p r ( ) p y lc t h u n ( ) a l c i s o - [ ] u t y la c e t a t e
Methyl alpha-methacrylate Methyl methacrylate
Mcthylstyrcnc Vinyltolucnc
Methyl-2-methyl propenoate Methyl methacrylate
p n r n l U c t l r v l \ tV r e n c Virryltolrrt'ttc
2-Methyl nitrobenzene o-Nitrotoluene
M t ' t l r y l lr r n r c h
t vlorc glycol l , I l l r r t v l c r rg
clyc<ll
Mcthyloxirane
Milrc M c l l r y h r l r r y rl l c o h o l
Propylene oxide
Mctlryl oxitol Ethylcnc glycol methyl
Milrx M e t l r y l t r o h t t yt l k t ' t o n e
cthcr
lal
llr
drry{d"**dryL*,.".d*-ilieui SCANNED BY MKP & BARIS A. 2004
MIC Methylamyl alcohol Naphthaline Naphthalene
MIK Methyl isobutyl ketone Naphtha, petroleum Naphtha: VM & P
Mineral oil Crude oil Naphthene Naphthalene
Mineral pitch Asphalt
Natural gas Methane
Mineral spirits Naphtha: Stoddard solvent NBA n-Butyl alcohol
MIPA iso-Propanolamine Necatorina Carbon tetrachloride
Mixed octyl nitrates 2-Ethyl hexyl nitrate Neolid Caster oil
Monobromomethane Methyl bromide 2,2',2"-Nitrilotriethanol Triethanolamine
Mono-n-butylamine n-Butylamine
Nitrobenzol Nitrobenzene
Monochloroacetic acid Chloroacetic acid o-Nitrochlorobenzene o-Chloronitrobenzene
Monochlorobenzene Chlorobenzene 2-Nitrophenol o-Nitrophenol
Monochlorodifl uoromethane Chlorodifluoromethane 2-Nitropropane 2-Nitropropane
Monochloroethane Ethyl chloride Nitropropanes 2-Nitropropane
Monochloroethene Vinyl chloride
sec-Nitropropane 2-Nitropropane
Monochloroethylene Vinyl chloride 2-Nitrotoluene o-Nitrotoluene
Monoethanolamine Ethanolamine o-Nitrotoluol o-Nitrotoluene
Monoethylamine Ethylamine 1-Nonane Nonane
Monoethylamine solution, 7OVo Ethylamine solution n-Nonane Nonane
Monoethylene glycol Ethylene glycol
sec-Nonyl alcohol Diisobutyl carbinol
Monohydroxybenzene Phenol Nonylcarbinol n-Decyl alcohol
Monoisopropanolamine iso-Propanolamine l-Nonylene l-Nonene
Monoisopropylamine iso-Propylamine Normal heptane Heptane
Monomethyl amine Methylamine solution Normal hexane n-Hexane
Mononitrobenzene Nitrobenzene
Normal pentane Pentane
Monopropylamine Propylamine Norvalamine n-Butylamine
Morbicid Formaldehyde solutions 2-NP 2-Nitropropane
Motor spirit Gasoline, motor
MTBE Methyl tert-butyl ether o
Muriatic acid Hydrochloric acid ()ctalrol 2-Ethyl hexanol
( )t lirrrol iso-Octyl alcohol
Muriatic ether Ethyl chloride
is()-()cliux)l iso-Octyl alcohol
Myricycl cerotate Carnauba wax ( )ctoil Dioctyl phthalate
( ) t ' ty l l c r v l n t e 2-Ethylhexyl acrylate
Naphtha Coal tar naphtha solvent

I ( \'tyl nlt'olrol 2-Ethyl hexanol
Nrrplrtha " :" Mineral spirits (h'lyl nrlrutcr 2-Ethyl hcxyl nitrate
w
lf 14t

Oil of mirbane Nitrobenzene Paraffin jelly Petrolatum

Oil of Palma Christi Caster oil Paraffin scale Parafftn wax
Oil of turpentine Turpentine Paraxylene p-Xylene
Pear oil iso-Amyl acetate
Oil of vitriol Sulfuric acid
Olefiant gas Ethylene Pentanal n-Valeraldehyde
Olefin C-13 l-Tridecene Pentanedial Glutaraldehyde solution
ONP o-Nitrophenol 1,5-Pentanedial Glutaraldehyde solution
Orthodichlorobenzene o-Dichlorobenzene
n-Pentane Pentane
l-Pentanol n-Amyl alcohol
Orthonitrotoluene o-Nitrotoluene
Orthophosphoric acid Phosphoric acid
Pentalin Pentachloroethane
Orthoxylene o-Xylene
Pentyl alcohol n-Amyl alcohol
3-Oxa-1,5-pentanediol Diethylene glycol
Pentylcarbinol Hexanol
2-Oxetanone beta-Propiolactone
sec-Pentylcarbinol Ethyl butanol
Perchlorethylene Perchloroethylene
Oxirane Ethylene oxide
Oxirane, (chloromethyl)- Epichlorohydrin
Perchloromethane Carbon tetrachloride
2-Oxohexamethylenimine Caprolactam solution
Peroxide Hydrogen peroxide
Oxooctyl alcohol iso-Octyl alcohol
Oxotridecyl alcohol Tridecanol Petroleum oil Diesel oil
Petrohol iso-Propyl alcohol
Oxybenzene Phenol Petrol Gasoline, motor
I , l'-Oxybis[butane] n-Butyl ether
l, l'-Oxybis[2-chloroethane] 2,2' -Dichloroethyl ether Petrolatumjelly Petrolatum
I,l'-Oxybisethane Ethyl ether Petroleum Crude oil
2,2'-Oxybisethanol Diethylene glycol Petroleum alsphalt Asphalt
Petroleum crude oil Crude oil
2,2'Oxybis[propane] iso-Propyl ether Petroleum gases,liquefied Liquefied petroleum gas
2,2'-Oxydiethanol Diethylene glycol
I, l'-Oxydi-2-propanol Dipropylene glycol Petroleum jelly Petrolatum
Oxytoluenes Cresols Petroleum pitch Asphalt
Petroleum solvent Naphthas
P
Petroleum solvent Naphtha: Stoddard solvent
Painters naphtha Naphtha: VM & P Petroleum solvent Naphtha: VM & P
PAN Phthalic anhydride
PAPI Polymethylene polyphen) Petroleum spirits Mineral spirits
isocyanate Petroleum wax Paraffin wax
Itaracetaldehyde Paraldehyde Phcne Benzene
I ' l r c n i ca c i d Phenol
I'uruflin Paraffin wax l'lrcrrol, 2,4-dichloro- 2,4-Dichlorophenol

To Find Look Up
To Find Look Up
Propanal Propionaldehyde
Phenylamine Aniline
Phenyl carbinol Benzyl alcohol
l-Propanamine Propylamine
Phenyl chloride Chlorobenzene
2-Propanamine iso-Propylamine
I -Phenyldodecane Dodecylbenzene
l -Propanamine, 2-methyl- Diisobutylamine
Phenylethane Ethylbenzene
l-Propanamine, N-propyl- Di-n-propylamine
Propanecarboxylic acid n-Butyric acid
Phenyl ether-biphenyl mixture Diphenyl-Diphenyl ether
mixture
Propane-Butane mixtures Liquefied petroleum gas
Phenylethylene Styrene monomer
Propane, l-chloro-2,3-epoxy Epichlorohydrin
Phenyl hydride Benzene
Propane, 1,2-dichloro- 1,2-Dichloropropane
Phenyl hydroxide Phenol
Propanenitrile Propionitrile
Propanenitrile, 2-hydr oxy -2- Acetone cyanohydrin
Phenylic acid Phenol
methyl
Phenylmethane Toluene
Phenyl methyl alcohol Benzyl alcohol
Propane, nitro- 2-Nitropropane
2-Phenyl propane Cumene
Propane, 2,2'-oxybis[2-chloro 2,2'-Dichloroisopropyl ether
Phenylpropylene alpha-Methylstyrene
1,2,3-Propanetriol Glycerine
Propanoic acid Propionic acid
meta-Phosphoric acid Phosphoric acid
Propanoic acid anhydride Propionic anhydride
ortho-Phosphoric acid Phosphoric acid
Phosphoric acid, tris(methyl- Tricresyl phosphate
Propanoic anhydride Propionic anhydride
phenyl)ester
Propanol n-Propyl alcohol
Phthalandione Phtlalic anhydride
1-Propanol n-Propyl alcohol
2-Propanol iso-Propyl alcohol
Phthalic acid anhydride Phthalic anhydride
3-Propanolamine Propanolamine
Phthalic acid, benzyl butyl ether Butyl benzyl phthalate
Phthalic acid, bis(2- Dioctyl phthalate
l-Propanol, 3-amino- Propanolamine
ethylhexyl)ester Propanolide beta-Propiolactone
Pimelic ketone Cyclohexanone
n-Propanol n-Propyl alcohol
Propanone Acetone
Piperylene 1,3-Pentadiene
2-l)ropanone Acetone
Polybutylene Polybutene
Polyisobutene Polybutene
I'ropellant l2 Dichlorodifl uoromethane
Polyisobutylene Polybutene
I ' r o p c l l a n t2 2 Chlorodifluoromethane
Polyisobutylene; plastics, resins & Polybutene
Itrtlpcnlrnitle Acrylamide solution
waxes 'l 2 l'ropcrritrrridc Acrylamide solution
Itropt.trc Propylene
t)olassiumhy<,lr<lxide Caustic p()tashs()ltttion
l)()lilssiurnlrytlroxiclesolution C a u s t i cp ( ) l a s hs o l t t l i o l t
I I ' l o g r t ' n c ,l , . l - d i c l r l o r o - 1,3-Dichloropropene
l ' r o p u t l t c t r c - r t rhcyl l a c c ly l e n e M c t h y l l c c l y l c n c -I t r ( ) p a ( l i c n c
I t r o g r r r c t rr t l c Acrylonitrile
n | |t I u r c rilixt rrrc
I
l'
To Find Look Up
I n-Propyl carbinol
To Find Look Up
n-Butyl alcohol
2-Propenenitrile Acrylonitrile
Propylene aldehyde
2-Propenenitrile, 2-methyl-
Propene oxide
Methacrylonitrile
Propylene oxide t Propylene chloride
Propylene dichloride
Crotonaldehyde
1,2-Dichloropropane
1,2-Dichloropropane
Propylene tetramer Dodecene
2-Propenic acid
Propenioic acid, 2-methylene
Acrylic acid
Methacrylic acid I Propylformic acid n-Butyric acid
Propenoic acid Acrylic acid
Propyl hydride Propane
2-Propenoic acid
2-Propenoic acid, butyl ester
Acrylic acid
n-Butyl acrylate I Propylic alcohol
Propylic aldehyde
n-Propyl alcohol
Propionaldehyde
iso-Propylideneacetone Mesityl oxide
2-Propenoic acid, ethyl ester
2-Propenoic acid methyl ester
Ethyl acrylate
Methyl acrylate
I Propyne-allene mixture Methyl acetylene-Propadiene
2-Propenoic acid, 2-methyl-, ethYl Ethyl methacrylate mixture
ester
2-Propenoic acid, 2-methyl-, Methyl methacrylate
I Protium
Pseudohexyl alcohol
Hydrogen (liqueflted)
Ethyl butanol
methyl ester Pvroacetic ether Acetone
Propenol Allyl alcohol

I Pyrofax Liquefied petroleum gas
l-Propenol-3 Allyl alcohol Pyromucic aldehyde Furfural
1-Propen-3-ol
2-Propenol
Allyl
Allyl
alcohol
alcohol
I Pyroxylic spirit
Pyrrolylene
Methyl alcohol
Butadiene
Allyl alcohol
2-Propen-1-ol
Propenyl alcohol Allyl alcohol

t Range oil
R
Kerosene
Propionic aldehyde Propionaldehyde Red fuming nitric acid Nitric acid (95Vo)
Propionic nitrile
beta-Propionolactone
Propionitrile
beta-Propiolactone
I Rcfined solvent naphtha
Rel'rigcrant l2
Naphtha: VM & P
Propionyl oxide Propionic anhydride Rcl'r'igcrant22 Chlorodifluoromethane
Propylacetate n-Propyl acetate

I Rcf'rigerantgases Freon, or
2-Propyl acetate
sec-Propyl acetate
Propyl alcohol
iso-Propyl acetate
iso-Propyl acetate
n-Propyl alcohol
t Rcritltrirlircl oil no. 6
Chlorodifluoromethane, or
Bunker C
R c r t t ro t l Rosin oil
Propyl alcohol normal
scr'-Propylalcohol
n-Propyl alcohol
iso-Propyl alcohol
I Rcttrtol Rosin oil
R t t ' t t t t t ro i l Caster oil
Propyl lklchyde
lt'ltrogry'llrrtittc
Propionaldehyde
Propylamine
Prrlpylantirte
I R r xI o t l
Rr l r r t o I
Crude oil
Rosirr oil
r n o n ot r . I t l r r p y l a m i n e
f( ublrtttl alt olrol iso-l'ropyl alcohol
l r r o g r y (l ' n rh t n ( ) l n-llutyl alcohtll
I 1 tI
150
&rol \r..* SCANNED BY MKP & BARIS A. 2004
I
To Find Look Up
I To Flnd Look Up
S p i r i t so f t u r p u r l i r r e Turpentine
Santicizer 160
SBA
Butyl benzyl phthalate
sec-Butyl alcohol
I S p t t t t i n gs o l v c n t Naphtha: Stoddard solvent
Slt'rrnd t i s t i l l t ' dl t r r ; ' r c n l i n e Turpentine
Secondary light oil Benzene, Toluene, Xylene
Senecaoil
mixtures
Crude oil
I S t o t l t l a r r ls ( ) l v e n I
:i t y rcnc
Naphtha: Stoddard solvent
Styrene monomer
Styrol S t y r c r r cm o n o m e r
Soda chloric acid, sodium salt

Soda lye
Sodium chlorate solution
T S ty r o l c n c
S u l t j r t cI r r r p t ' r ri l r c
S t y r e n em o n o m e r
'I'urpentine
Sodium bichromate Sodium dichromate solution
Sodium bichromate solution
Sodium bisulhde
Sodium dichromate solution
Sodium hydrosulfide
I S u l l i r t cw t x r t l t r r r p c n l i r r c
Sulfur
Turpentine
Sulfur, molten
Sulfur dioxidc, li<4uched Sulfur dioxide
solution
Sodium hydrogen sulfide Sodium hydrosulfide

I S u l f u r i c a c i t l ,d i c t h y l e s t e r Diethyl sulfate
Sulfuric acitl, fuming Oleum
Sodium hydroxide
Sodium hydroxide solution
solution
t Sulfuricchlorohydrin
Sulfuricctlrcr
Chlorosulfonic acid
Ethyl ether
Sulfurous anhydride Sulfur dioxide
Sodium hypochlorite Sodium hypochlorite
solution
Sodium hydrosulftde
I Sulfurous oxide Sulfur dioxide
Sodium mercaptan Sulphur Sulfur, molten
solution
Sodium hydrosulfide
I Superoxol
Sweet oil
Hydrogen peroxide
Olive oil
Sodium sulfhydrate
T
Solar nitrogen solution
solution
Urea-Ammonium nitrate I Talleol Tall oil
solution Tallol Tall oil
Solvent ether
Solvent naphtha
Ethyl.ether
Naphthas I Tallow oil
Tangantangan oil
Tallow
Caster oil
Tar Coal tar
Solvent naphtha
Sorbicolan
Naphtha: VM & P
Sorbitol I 'l
'l
ar :rcirls Cresols
Sorbit Sorbitol itr crrrrrphor Naphthalene
'l
Sorbo
Sorbrll
Sorbitol
Sorbitol I nr, lirlrritl
l nr orl
Coal tar
Creosote, coal tar
I rrri lrtprttl Asphalt
Sortxrrlyl
Soylhcntt oil
Sorbitol
Soybean oil I I lr^ tert-Butyl alcohol
Soy otl Soybean oil lx'trr l' l, 1,2-Trichloroethane
S ; u r t lo l l l n r l r h o r n Amrnonia s()luli()ns
I t , t . rt ( ' l l, l, | -'I'richloroethane
rt2
tJl
- "rlltu-*'-s *-.
II
1,1,Z-TCE
To Find Look Up
l, 1,2-Trichloroethane
IT- To Find

Look Up
TCP Tricresyl phosphate

fl- compounds
TDI Toluene diisocyanate TOCP Tricresyl phosphate

TEA Triethanolamine fr 2.4-Tolamine Toluenediamine
TEG Tetraethylene glycol il 2,4-Toluenediamine Toluenediamine
TEG Triethylene glycol 4-m-Toluenediamine Toluenediamine
TEL Motor fuel anti-knock
compounds il- m-Toluenediamine Toluenediamine
2,4-Toluene diisocyanate Toluene diisocyanate

Telone
TEN
1,3-Dichloropropene
Triethylamine it- Toluene-2,4-diisocyanate
Toluene, orthonitro-
2,4-Tolulene diisocyanate
Toluene diisocyanate
o-Nitrotoluene
TETA Triethylenetetramine
Tetrachlorethene
Tetrachlorethylene
Perchloroethylene
Perchloroethylene
IT Toluol (o-, m-, p-) Cresols
Toluol Toluene
Tetrachloroethane
sym-Tetrachloroethane
l, 1,2,2-T etr achloroethane
1,1,2,2-Tetr achloroethane
l{- Tolylethylene
Tolylenediamine
Vinyltoluene
Toluenediamine
2,4-Tolylenediamine Toluenediamine
Tetrachloroethylene Perchloroethylene
Tetrachloromethane
Tetraethyl lead compounds
Carbon tetrachloride
tf- m-Tolylenediamine Toluenediamine
2,4-Tolylene diisocyanate Toluene diisocyanate

compounds
Tetrahydro-4,7-methanoindene Dicyclopentadiene
lT- m-Tolylene diisocyanate
Tolylphosphate
Tricresyl phosphate
Treacle Molasses
1,2,3,4-T etr ahydronaphthalene Tetrahydronaphthalene
Tetrahydro- 1,4-oxazine
Tetrah ydro- 2H- 1,4- oxazine
Morpholine
Morpholine
It Tri Trichloroethylene
Trichlorobenzenes, liquid 1,2,4-T r ichlorobenzene

Tetrahydro-p-oxazine Morpholine
Tetralin Tetrahydronaphthalene
If- unsym-Trichlorobenzene
1,2,4-Trichlorobenzol
Trichloroethene
1,2,4-T r ichloroben zene
1,2,4-T r ichlorobenzene
Trichloroethylene
Tetraline Tetrahydronaphthalene
Tetramethylene cyanide
Tetramethylene oxide
Adiponitrile
Tetrahydrofuran
It- Trichlorohydrin
Trichloromethane
1,2,3-Trichloropropane
Chloroform
Tetramethyl lead compounds Motor fuel anti-knock
compounds tr Trichloropropane
beta-Trichlorethane
Tricresol
l, 1,2-Trichloroethane
Cresols
Tetramp
Tetranap
Tetrapropylene
Tetrahydronaphthalene
Tetrahydronaphthalene
Dodecene
tr l-Tridecanol
Tridecyl alcohol
Tridecanol
Tridecanol
THF
354
Tetrahydrofuran
rr Trien
355
Triethylenetetramine
-. - -ll . -:::' -
SCANNED BY MKP & BARIS A. 2004 - , b I ! - . . . _ . . . _ _
ll
To Find To Find Look Up
Look Up
1,3,5-Triethylbenzene Triethylbenzene Turpentine

sym-Triethylbenzene Triethylbenzene [r
il U
Triethylene glycol ethyl ether Ethoxy triglycol
UAN-Nitrogen solution Urea-Ammonium nitrdte
Triethylene glycol methyl ether Methoxy triglycol solution
Triethylolamine Triethanolamine UAN solution Urea-Anmonium nitrate
Triglycol Triethylene glycol solution
Triglycol ethyl ether Ethoxy triglycol Ucon Freon
Triglycol monoethyl ether Ethoxy triglycol
Ucon 12 Dichlorodifl uoromethane
Tri(hydroxyethyl)amine
Tri(2-hydrox yethyl)amine
Triethanolamine
Triethanolamine
lf Undecylethylene l-Tridecene
Trihydroxypropane Glycerine f--r*

1,2,3-Trihydroxypropane
Trihydroxytriethylamine
Glycerine
Triethanolamine
II Valeral
Valeraldehyde
n-Valeraldehyde
Valeraldehyde, iso- or n-
isomers
Trimethylaminomethane
Trimethyl carbinol
tert-Butylamine
tert-Butyl alcohol
II Valeric aldehyde
Valerone
n-Valeraldehyde
Diisobutyl ketone
3,5,5-Trimethyl-2-cyclohexene-I - Isophorone
one
Trimethylheptanols iso-Decaldehyde
II VAM
Varnish makers' & painters'
Vinyl acetate
Naphtha: VM & P
naphtha
2,4,4-Trimethyl pentene-I Diisobutylene Vaseline Petrolatum
2,4,4-Trimethyl pentene-2 Diisobutylene VC Vinyl chloride
Trimethyl pentene Diisobutylene
Trimethyltrimethylene glycol Hexylene glycol VCL Vinyl chloride
alpha, alpha, alpha'-Trimethyl- Hexylene glycol VCM Vinyl chloride
trimethylene glycol
Vinamar Vinyl ethyl ether
Vinegar acid Acetic acid
2,4,6-Trimethyl- l, 3,5-trioxane Paraldehyde Vinegar naphtha Ethyl acetate
Tri-o-cresyl phosphate Tricresyl phosphate
Tri-o-tolyl phosphate
l, 3,5-Trioxane, 2,4,6-trimethyl-
Tricresyl phosphate
Paraldehyde
tI Vinyl acetate monomer
Vinyl A monomer
Vinyl acetate
Vinyl acetate
3,6,9-Trioxaundecanol, I l-diol Tetraethylene glycol
Vinylbenzene Styrene monomer
Vinyl carbinol Allyl alcohol
Tris(hydroxyethyl)amine Triethanolamine
Tritolyl phosphate Vinyl chloride monomer Vinyl chloride
Tricresyl phosphate
Trolamine
Turkey-red oil (sulfated caster
Triethanolamine
Caster oil
l- Vinyl C monomer Vinyl chloride
oil) Vinyl cyanide Acrylonitrile
Turpentine substitute Mineral spirits
I Vinyl ethylene Butadiene
357
SCANNED BY MKP & BARIS A. 2004 ttd.,
- _._.,.,,.--,ad.., .dii&'.',. - .",......d{4{&r.ili
r
To Find Look Up t-
tr
Vinyl trichloride 1,1,2-Trichloroethane
Vinyl formic acid Acrylic acid
Vy Ac Vinyl acetate
w lr
Wash oil Creosote, coal tar
Whale sperm oil Sperm oil tr
l l
APPENDIXES
White camphor oil Camphor oil
White fuming nitric acid
White phosphoric acid
Nitric acid (95Vo)
Phosphoric acid r
il
A.
B.
Compatibility Information, 46 CFR 150 - Subpart A......... 360
Medical Kit Information - Cyanide-like cargoes;
Carcinogens listed in the Guide... 408
White phosphorus Phosphorus (white) C. List of Oils - Appendix I, MARPOL 73/78;
White
White
spirits
tar
Naphtha: Stoddard solvent
Naphthalene
il- D.
Composition of Common Petroleum Products.....
Conversion Factors.......
410
412
Wood alcohol Methyl alcohol E. Temperature Conversion.................. 417
Wood spirit Methyl alcohol
il:
Wood turpentine
WP
x
'
Turpentine
Phosphorus (white)
r
meta-Xylene
ortho-Xylene
m-Xylene
o-Xylene
r
ir
para-Xylene p-Xylene
Xylol Xylene
Y
Yellow petrolatum
Yellow phosphorus
Petrolatum
Phosphorus (white)
t1-
Zinc dlhexyldithiophosphate Zinc dialkyldithiophosphate
r
Zinc dihexylphosphorodithioate Zinc dialkyldithiophosphate lf
tl
tr
F 359
35t
r
APPENDIX A
r groups. Products assigned to Cargo groups, however, are much less re-
active and dangerous combinations can be formed only with members
r
COMPATIBILITY INFORMATION of certain Reactive groups. Cargo groups do not react hazardously
with one another. Because of these differences in reactivity, a signifi-
In this seventh edition, chemical compatibility is covered by a gen- cant part of the usual two-dimensional chart has been eliminated.
eral discussion and summary of 46 CFR 150 Subpart A followed by 46
CFR 150 in essentially its entirety. If necessary, current information
may be obtained by calling 202-267-1577or writing to Commandant
r d. Using the Guide-The following procedure explains how the
Guide should be used to find compatibility information:
(l) Determine the group numbers of the two chemicals by refer-

(G-MTH-l), Washington, D.C. 20593-0001.
General Discussion. t- ring to the alphabetical listing of products and their corresponding
groups (Table I of 46 CFR 150). Many chemicals are listed under their
a. Introduction-The accidental mixing of one chemical product
with another inside a cargo tank or pipe may result in a vigorous chem-
ical reaction. Binary combinations that generate significant heat or
r parent names and, unless otherwise indicated, isomers or mixtures of
isomers for a particular product are assigned to the same group. For
example, to frnd the group number for Isobutyl alcohol, look under the
produce gas can be very hazardous to personnel and property. The pur-
pose of the Compatibility Guide is to indicate, in chart form, combina-
tions believed to be dangerous. Based on information provided by the
r parent name Butyl alcohol. Similady, the group number for para-
Xylene is found under the entry Xylene. If a chemical cannot be found
in this listing, contact the Coast Guard for a group determination.
National Academy of Sciences, the Guide represents the latest data
available to the Coast Guard on chemical compatibility. Extensive use
was made of direct experimental evidence obtained under contract to
r (2) If both group numbers do not fall between 30 and 43 inclu-
sive, locate on the chart one of the numbers on the left (Cargo groups)
the NAS and Coast Guard.
b. Definition of a Hazardous Reaction-As a first approximation, a r and the other across the top (Reactive groups). Note that if one of the
group numbers is between 30 and 43 it must be located on the left side.
Proceed across the page until the appropriate Reactive group column is
r
binary mixture is considered hazardous when the products are mixed intersected. The box formed by the intersection will indicate one of the
under specified conditions and the temperature rise exceeds 25"C or a following:
gas is evolved. In rare cases the reaction of two components (even
(a) blank-The two products are considered compatible.
r
though non-hazardous, from temperature or pressure considerations)
may produce a product which is significantly more flammable or toxic (b) "X'-The two products are not considered compatible.
than the original materials. Although no examples of such a reaction
(c) a letter other than an "X"-Differences (deviations) in re-
r
are known at this time, they would be considered hazardous.
activity are present among the group members-refer to the listing fol-
c. Chart Format-In reviewing the binary test results and previous
lowing the chart to hnd whether the products in question are included
charts, it was evident that there were different degrees of reactivity
in the deviations. Unless the combination is specifically covered on this
among the various products. Many of them are relatively non-reactive
(aromatic hydrocarbons, paraffins) while others form hazardous combi-
nations with many groups (inorganic acids).
r page, it may be considered compatible.
Examples:
The compatibility chart (refer to Figure I in 46 CFR 150) is separated
into two sections, group I through group 22 are Reactive groups, and
group 30 through group 43 are Cargo groups. Left unassigned and
r Combination Compatible?
available for future expansion are groups 23 through 29 and those past
43. Reactive groups contain products which are chemically the most re-
active; dangerous combinations may result between members of differ-
r Butyraldehyde/Aceticacid
Allyl alcohol/Toluenediisocyanate
Decene/Ethylbenzene
Ethanolamine/Acetone
lgl 4
215/12
30/32
8/18
yes
no
yes
yes
ent Reactive groups and between members of Reactive and Cargo
360
r Ammonia/Dimethylformamide 6/10 no

r
e. Exceptions to the Guide-The hazard ratings in the chart are
based largely upon direct experimental data using in most casesone of
r The Coast Guard intends that this section comply with the require-
ments of 44 U.S.C. 3507(0 which requires that agencies display a cur-
the most reactive members of the group. Combinations of other group
members may display considerably less reactivity. For this reason, an
experimental procedure (refer to Appendix III,46 CFR 150) has been
r rent control number assigned by the Director of the OMB for each ap-
proved agency information collection requirement.
(b) Display.
developed which allows a shipper to test two particul.:arproducts he be-
lieves non-hazardous although an "X" appears in the chart for their
corresponding groups. A data sheet is also supplied and should be com-
r 46 CFR part or section where
CurrentOMBcontrolNo.
pleted and returned to the Coast Guard for evaluation. If the combina-
tion is not found to be dangerously reactive, an exception will be
issued.
t: identifiedor described
15 0 . 0 1 - 1 5 2115-0016
153.5 2115-0016
46 CFR PART IsO-COMPATIBILITY
Subpart A-Compatibility of Cargoes
OF CARGOES
f- 153.905
153.910
2115-0089
2115-0089
Sec.
150.105 OMB control numbers assignedpursuant to the Paperwork
Reduction Act.
r 153.968
Part 154
't54.12
2115-0089
2115-0113
2115-0016
l50.ll0 Applicability.
l50.ll5 Def,rnitions. {- $150.110 Applicability.
150.120 Definition of incompatible cargoes.
150.130 Loading a aargo on vesselscarrying cargoes with which it is
incompatible.
150.140 Cargoes not listed in Table I or II.
r This subpart prescribes rules for identifying incompatible hazard-
ous materials and rules for carrying these materials in bulk as cargo in
permanently attached tanks or in tanks that are loaded or discharged
150.150 Exceptions to the compatibility chart.

150.160 Carrying a cargo as an exception to the compatibility chart.
150.170 Right of appeal.
r while aboard the vessel. The rules apply to all vessels subject to 46
U.S.C.39la.
S150.115 Definitions.
Frcunp l-CovrpeuBrlrry
Tenrr, I-AlpnenETrcAL
Cnenr
Lrsr oF CARcoEs
l= As used in this subpart: "Hazardous material" means:
(a) A flammable liquid as defined in $ 30.10-22 or a combustible
TesrE, II-GnouprNG oF Cencoes
ApppNorx I-ExcBprroNs ro rHE CHART
AppeNolx II-Expr-eNATroN oF FrcuRE I
AppeNux III-TesrrNc PRocEDUREsFoR Dsrenuntxc ExcEprroNs
r liquid as defined in $ 30.10-15 of this chapter;
(b) A material listed in Table 151.05,Table l of Part 153, or Table
4 of Part 154 of this chapter; or
TO THE CHENT
AppnNorx IV-Dlre Sneer
,
t: (c) A liquid, liquefied gas, or compressed gas listed in 49 CFR
r72.tot.
Subpart A-Compatibility of Cargoes
$150.105 OMB control numbers assignedpursuant to the Paperwork
Reduction Act.
r the
"Person
person
in charge" means the master of a self-propelled vessel, or
in charge of a barge.
(a) Purpose. This section collects and displays the control numbers
assigned to information collection and recordkeeping requirements in
this subchapter by the Ofhce of Management and Budget (OMB) pursu-
r $150.120 Definition of incompatible cargoes
Except as described in $ 150.150, a cargo of hazardous material is
incompatible with another cargo listed in Table I if the chemical groups
ant to the Paperwork Reduction Act of 1980 (44 U.S.C. 3501 et seq.).
l- of the two cargoes have an "X" where their columns intersect in

362 363
. ,\;.jiL.*! ,e'--i.-tu-l
r
Figure I and are not shown as exceptions in Appendix I. (See also
$ 150.1,+0.)
r $150.150 Exceptions to the compatibility chart.
The Commandant (G-MTH) authorizes, on a case by case basisn
$150.130 Loading a cargo on vessels carrying cargoes with which it is

incompatible.
F exceptions to the rules in this subpart under the following conditions:
(a) When two cargoes shown to be incompatible in Figure I meet
the standards for a compatible pair in Appendix III, or
Except as described in $ 150.160,the person in charge of a vessel
shall ensure that the containment system for a cargo that is a hazardous
material meets the following requirements:
tr (b) When two cargoes shown to be compatible in Figure I meet
the standards for an incompatible pair in Appendix III.
(a) The containment system must separate the hazardous material

or its residue from any cargo in table I with which it is incompatible by
F Appendix I contains cargoes which have been found to be excep-
tions to Figure l, the Compatibility Chart.
two barriers such as formed bv a:
(l) Cofferdam;
tr:
tl
$150.160 Carrying a cargo as an exception to the compatibility chart.
The Operator of a vessel having on board a cargo carried as an
exception under $150.150 but not listed in Appendix I, Exceptions to
(2) Empty tank;
(3) Void space;

ti: the Chart. shall make sure that:
(a) The Commandant (G-MTH) has authorized by letter or mes-
(4) Cargo handling space;
(5) Tank containing a compatible cargo; or

r sage the cargo pair as an exception to the compatibility chart; and
(b)Acopyofthe1etterormessageisonthevessel.
(6) Piping tunnel. IT: $150.170 Right of appeal.

il Any person directly affected by a decision or action taken under
(b) In this subpart, isolation across a cruciform joint is equivalent
this part, by or on behalf of the Coast Guard, may appeal therefrom in
to isolation by two barriers.
(c) The containment system for the hazardous material rnust not F accordance with subpart 1.03 of this chapter.
r
have a piping or venting system that connects to a containment system
carrying a aargo with which the hazardous material is incompatible.
Any such piping or venting system must have been separated from the
containment system carrying the incompatible cargo by:
(l) Removing a valve or spool piece and blanking off the exposed
pipe ends, or
F
(2) Installing two spectacle flanges in series with a means of detect-
ing leakage into the pipe between the spectacle flanges.
F
$150.140 Cargoes not listed in Table I or II.
A cargo of hazardous material not listed in Table I or II must be
F
handled as if incompatible with all other cargoes until the Commandant
(G-MTH) (tel. no. (202) 267-1577) assignsthe hazardous material to a
compatibility group. (Table I lists cargoes alphabetically while Table II
F
lists cargoes by compatibility group).
r 365
-.:-. ---:U 'u!t:r. =
3&
-L- SCANNED BY MKP & BARIS A. 2004 :1il ;
r
Figure l--{ompatibility Chart
tt- Chemical name
Table I-Alphabetical
Group
List of Cargoes
CHRIS Related CHRIS codes

No. code
rr
ll
Acetaldehyde.. t9
24
AAD
Acetic acid...... AAC
CABGO GROUPS NEACNVE GROUPS Acetic anhydride.............................. l l ACA
Acetone... 2lg ACT
iT
ll Acetone cyanohydrin.... r'20 ACY
Acetonitrile..... J I ATN
Acetophenone. 18 ACP
it- A c e t y l t r i b u t y l c i t r a t e . . . . . . . . . . . . . . . . . . . . . . 34
Acrolein
Acrylamide solution............
2lg
l0
ARL
AAM 4{
Acrylic acid.................. 24 ACR
It- Acrylonitrile
Acrylonitrile-Styrene copolymer
215 ACN
dispersion in Polyether polyol .... 20 ALE

r- Adiponitrile..... tt ADN
il Alcohols (Cl 3 and above)............... 20 ALY TDN,/TTN,/PDC
Alcoholic beverages......... 20
A l c o h o l p o l y e t h o x y l a t e s . . . . . . . . . . . . . . . . . . 20 APK,/APL
t--
I
Atcohol polyethoxylates,
s e c o n d a r y. . . . . . . . 20 AEA,/AEB
Alkyl acrylate-Vinyl pyridine
rI copolymer in Toluene.............,....
A l k y l ( C 9 - C l 7 ) b e n 2 e n e s . . . . . . . . . . . . . . . . 32
32 AAP
AKB DBZ/UDB/DDBARBADB
t Alkylbenzenesulfonic acid............... 1 ' 2 0 ABS
n
Alkylbenzenesulfonic acid, sodium
t-
o
il
salt solutions... JJ ABT
! A l k y l p h t h a 1 a t e s . . . . . . . . . . . . . . . . . . . . . . . . . . . .34 ...
o 215
C Allyl alcohol... ALA
8
t- Allyl chloride
Aluminium chloride, Hydrochloric
acid solution...
l5
243
0
ALC
AHS
Aluminum sulfate solution ASX
f- 2-(2-Aminoethoxy)ethano|...............
Aminoethyldiethanolamine,
8 AEX
r s o l u t i o n. . . . . . . . . . . .
Aminoethylethanolamine.................
N-Aminoethylpiperazine..................
8
8 AEE
AEP
r
2-Amino-2-hydroxymethyl- 1,3-
p r o p a n e d i o ls o l u t i o n . . . . . . . . . . . . . . . . . . . . . 43 AHL
2-Amino-2-methyl- I -propanol ......... 8 APR
BtLLtNGCODE 4910-14-C X: Incompatible Groups Ammonia, anhydrous........ 6 AMA
r Ammonium bisulfite solution ..........

Ammonium hydrogen phosphate
s o l u t i o n. . . . . . . . . . .
243
0
ABX
r
Ammonium hydroxide (28Vo or
less Ammonia) 6 AMH
167
366
L
SCANNED BY MKP & BARIS A. 2004 " ,J .
Table l-Alphabetical List of Cargoes-Continued Table I-Alphabetical List of Cargoes-Continued
Ctemical narne Group CHRIS RelatedCHRIS codec Chemical name Group CHRIS Related CHRIS codes
No. codc No. code
r0 Butyl alcohol 220 IAL,/BAN,/BAS,/BAT
Ammonium nitrate solution ANR AMN
Ammonium nitrate, Urea solution Butylamine...... 7 BTY IAM,/BAM,/BTL/BUA
(containing Ammonia) 6 UAS Butylbenzene 32 BBE
Ammonium nitrate, Urea solution B u t y l b e n z y l p h t h a l a t e . . . . . . . . . . . . . . . . . . . . . 34 BPH
(not containing Ammonia)........... 43 ANU n - B u t y l b u t y r a t e. . . . . . . . . . . 34 BUB
Ammonium polyphosphate B u t y l e n e. . . . . . . . . . 30 BTN
43 Butylene glycol .............. 220 BUG
solution............ ANS,/APP
Amrnonium sulfate solution 43 AME AMS Butylene oxide................ 16 BTO
Ammonium sulfide solution ............ 5 ASS ASF Butyl ether...... 4I BTE
Ammonium thiocyanate, Butyl formate.. 34 BFI,/BFN
Ammonium thiosulfate solution .. 0 ACS iso-Butyl isobutyrate ...... 34 BIB
Ammonium thiosulfate solution...... 43 ATV ATF B u t y l h e p t y l k e t o n e . . . . . . . . . . . . . . . . . . . . . . . . . . 18 BHK
Amyl acetate... 34 AEC IAT/AI',.IL/AAS,/AYA B u t y l m e t h a c r y l a t e . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 BMH BMI,/BMN
Amyl alcohol.. 20 AAI IAA,/AAN,/ASE/APIN'{ Butyl methacrylate, Decyl
Amylene.......... 30 AMZ PTX,/PTE methacrylate, Cetyl-Eicosyl
Amyl methyl ketone........................ l8 AMK methacrylate mixture 14 DER
Amyl tallate.... 34 Butyl phenol, Formaldehyde resin
Aniline............. 9 ANL in Xylene......... 32
Anthracene oil (Coal tar fraction), Butyl toluene.. 32 BUE
s e eC o a l t a r . . . . . . . . . . . . . . . . . . . . . JJ AHO coR Butyraldehyde l9 BAE BAD,/BTR,/BFA
Asphalt............ 33 ASP ACU Butyric acid 4 BRA IBR
Asphalt blending stocks, roofers g a m m a - B u t y r o l a c t o n e . . . . . . . , . . . , , . . . . . . . . .l ' 2 0 BLA
f lu x . . , . . . , . . . . . . . . . . . . 33 ARF Calcium bromide solution................ 43 CBM
Asphalt blending stocks, straight Calcium bromide, Zinc bromide
run residue 33 ASR solution see Drilling brine
Aviation alkylates........... 33 AVA GAV (containing Zinc salts).................. 43 DZB
Behenyl alcohol............. 20 Calcium chloride solution................ 43 CCS cLc
B e n z e n e. . . . . . . . . . . 32 BNZ Calcium hypochlorite solutions ...... 5 CHZ/CHU/CHY
Benzene hydrocarbon mixtures Calcium naphthenate in Mineral
(having l0Vo Benzene or more).. 32 BHB oil.................... 34 CNM
Benzenesulfonyl chloride................. 20 BSC Calcium nitrate, Magnesium
Benzene, Toluene, Xylene nitrate, Potassium chloride
mixtures...........
Benzene tricarboxylic acid, trioctyl
32 BTX
I- s o l u t i o n. . . . . . . . . . .
Calcium sulfonate, Calcium
carbonate, Hydrocarbon solvent
34
r
e s t e r. . . . . . . . . . . . . . . . . 34
Benzylacetate.. 34 BZE mlxture 33
Benzyl alcohol 2l BAL Camphor oil..................... 18 cPo
Benzyl chloride 36 BCL Caprolactam solution ....................... 22 CLS
Brake fluid base mixtures
Butadiene
Butadiene, Butylene mixtures
( c o n t . A c e t y l e n e s ). . . . . . . . . . . . . . . . . . . . . . . .
20
30
30
BFX
BDI
r Carbolic oil....................
C a r b o n d i s u l f id e . . . . . . . . . . . . . . . .-........ . . . . . .
2r
C a r b o n b l a c k b a s e. . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
38
C a r b o n t e t r a c h l o r i d e . . . . . . . . . . . . . . . . . . . . . . . . 36
cBo
CBB
CBT
r
BBM
Butane,............ 3l BMX IBT,/BUT Cashew nut shell oil (untreated)..... 4 OcN
Butene,............ 30 IBL,/BTN Caustic potashso|ution.................... 2 5 CPS
Caustic soda solution 25
B u t e n eo l i g o m e r . . . . . . . . . . . , . . , . . . , . . , . , . , . , . , . 30 BOL CSS
r
Butyl acetate... 34 BAX IBA,/BCN,/BTA/BYA Cetyl-Eicosyl methacrylate
Butyl acrylate. l4 BAR BAI,/BTC mixture t4 CEM
SCANNED BY I MKP & BARIS A. 2004

36t 369
; . , . ;r!i&iifl'i.;-r* . .:--,- t,. ,;],t.,4j,.,,.,.i ' 'd
fr
Chemical name Group

List of Cargoes-Continued

r Table l-Alphabetical
Chemical name Group

Chlorinated paraffrns (Cl0 - C13)...

Chlorinated paraffins (C14 - C17)...
Chlorine
No.
36
36
r0
code
CLH
cLx
r Cymene...........
Decahydronaphthalene....................
Decaldehyde...
JJ
l9
No.
t2
code
CMP
DHN
IDA,/DAL
Chloroacetic acid solution...............
Chlorobenzene
4
36
CHM
CRB
CHL,/MCA
tr
tl
Decane
Decanoicacid..................
31
4
DDC
DCO
PFN
Chlorodifl uoromethane.................... 36 MCF Decene 30 DCE

Chloroform..... 36 CRF Decyl acrylate................:................. l 4 DAT IAI,/DAR
Chlorohydrins.
4-Chloro-2-methylphenoxyacetic
t7 CHD f|.*
tl
Decyl alcohol . 220 DAX ISA,/DAN
Decylbenzene 32 DBZ AKB
acid, Dimethylamine salt Dextrose solution 43 DTS
solution............ 9 CDM 220
Chloronitrobenzene - see o- Ii*
tl
Diacetone alcohol ............
-
Dialkyl(C 10 C14) benzenes........... JZ
DAA
DAB
Nitrochlorobenzene.........-............ cNo Dialkyl(C7 - Cl3) phthalates .......... t4 DAH DHP/DIE,/DOP /DTF /DTP /
Chloropropionicacid....................... 4 CPM CLA/CLP
ir
DUP
C h l o r o s u l f o n i ca c i d . . . . . . . . . . . . . . . . . . . . . . . . . . r0 CSA Diammoniu.m salt of Zinc EDTA
Chlorotoluene. 36 CHI CTM,/CTO,/CRN s o l u t i o n. . . . . . . . . . . . 43 DSZ
Choline chloride solutions............... 20 cco Dibutylamine 7 DBA
Coal tar
Coal tar pitch.................
Coconut oil, fatty acid.....................
Corn syrup......
JJ
33
34
43
coR
CTP
CFA
CSY
ocT
ir Dibutyl phthalate 34
D i c h l o r o b e n z e n e. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Dichlorodifl uoromethane ................ 36
DPA
DBX
DCF
DBM,/DBO,/DBP
l , l - D i c h 1 o r o e t h a n e . . . . . . . . . . . . . . . . . . . . . . . . .36 .. DCH
Cottonseed oil, fatty acid ................
Creosote..,.,.,...
34
2l
CFY
CCT CCW,/CWD
fr
il
2,2'-Dichloroethyl ether
2,2'-Dichloroisopropyl ether ...........
4I
36
DEE
DCI
CresoIs............. 2l cRs cRL,/CSL,/CSO D i c h l o r o m e t h a n e . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 DCM
Cresylate spent caustic.... 5 csc 2 , 4 - D i c h l o r o p h e n o l. . . . . . . . . . . . . . . . . . . . . . . . . . 2I DCP
csc r
C r e s y l i ca c i d. . . . . . . . . . . . . . . . . . 2l CRY 2,4-Dichlorophenoxyacetic acid,
Cresylic acid, sodium salt solution. l Diethanolamine salt solution....... 43 DDE
Crotonaldehyde................................l 9 CTA 2,4-Dichlorophenoxyacetic acid,
Cumene
Cycloaliphatic resins........................
32
3l
CUM
ll--
tl
Dimethylamine salt solution........
2,4-Dichlorophenoxyacetic acid,
l'20 DAD DDA,/DSX
l, 5,9-Cyclododecatriene 30 CYT Triisopropanolamine salt

Cycloheptane.. 3l CYE so|ution............ 243 DTI
Cyclohexane
Cyclohexane oxidation product
3l
4
cHx
tl: D i c h l o r o p r o p a n e. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 6
l , 3 - D i c h l o r o p r o p e n e. . . . . . . . . . . . . . . . . . . . . . . . l 5
DPX
DPS
DPB/DPP,/DPC/DPL
DPU,/DPF
r
acid water........ Dichloropropene,
Cyclohexanol.. 20 CHN Dichloropropane mixtures........... l5 DMX
Cyclohexanone l8 ccH 2 , 2 - D i c h l o r o p r o p i o n i ca c i d . . . . . . . . . . . . . 4 DCN
Cyclohexanone, Cyclohexanol Dicyclopentadiene............................ 3 0 ' DPT
mixtures........... ,18 cYx Didecyl dimethyl ammonium
Cyclohexyl acetate.............
Cyclohexylamine.............................. 7
1 , 3 - C y c l o p e n t a d i e ndei m e r . . . . . . . . . . . . . .
34
30
CYC
CHA
CPD
F chloride, Ethanol mixture
s o l u t i o n. . . . . . . . . . .
Diethanolamine
43 DDX
DEA
r
8
Cyclopentadiene polymers .............. 30 CPD Diethanolamine salt of 2,4-
Cyclopentadiene, Styrene, Benzene Dichlorophenoxyacetic acid
mrxtures.........,. 30 csB solution............ 43 DDE
Cyclopentane.. 3l CYP Diethylamine DEN
Cyclopentene.. 30 CPE
fl- Diethylaminoethanol........................ 8
370
371
r
Table l-Alphabetical List of Cargoes-Continued
C-hemicd name Group CHRIS Related CHRIS codec
F Tabte I-Alphabetical
Chemicsl name Group


No. No. code
2,GDiethylaniline .............................
Diethylbenzene
I
32
code
DMN
DEB
F Dimethylamine salt of 4-Chloro-2-
methylphenoxyacetic acid
r
so1ution............ 9 CDM
Diethylene glycol............... 40 DEG
Dimethylamine salt of 2,4-
Diethylene glycol butyl ether......... 40 DME
Dichlorophenoxyacetic acid
Diethylene glycol butyl ether
. . .2. .0. . ;
solution..................................L DAD DDA,/DSX
acetate........,..... 34 DEM
tr DMM
2 , 6 - D i m e t h y l a n i l i n e. . . . . . . . . . . . . . . . . . . . . . . . . . 9
Diethylene glycol dibutyl ether...... 40 DIG
Dimethylcyclicsiloxane
Diethylene glycol ethyl ether......... & DGE hydrolyzate..... 34
Diethylene glycol ethyl ether
N,N-Dimethylcy"l"h.rylu-i;;':: :::. DXN
acetate..............
Diethylene glycol methyl ether......
Diethylene glycol methyl ether
acetate..............
34
n
34
DGA
DGM
DGR
tr Dimethylethanolamine.....................
D i m e t h y l f o r m a m i d e. . . . . . . . . . . . . . . . . . . . . . . . .
Dimethyl furan................
8
l0
4l
DMB
DMF
Dimethyl glutarate.......... 34 DGT

Diethylene glycol phenyl ether......
Diethylene glycol phthalate............
n
34
DGP
DGL
Ir:
tl
Dimethyl hydrogen phosphite ........ 234 DPI
Dimethyl naphthalene sulfonic
Diethy|enetriamine........................... 27 DET 234
acid, sodium salt solution............. DNS
Diethylethanolamine........................ 8 DAE
Diethyl ether................ 4l EET
t- Dimethyloctanoicacid..................... 4 DMO
tl Dimethyl phthalate 34 DTL
Di-(2-ethylhexyl)adipate .................. 34 DEH Dimethylpolysiloxane ...................... 34 DMP
Di-(2-ethylhexyl)phosphoric acid... I DEP 2,2-Dimethylpropane- 1,3-diol.......... 20 DDI
Di-(2-ethylhexyl)phthalate...............
Diethyl phthalate..........
Diethyl sulfate..............
34
34
34
DIE
DPH
DSU
DIO,/DOP,/DAH
F Dimethyl succinate
Dinitrotoluene
34
42
DSE
DNM DTT,/DNL,/DNU
Dinonyl phthalate 34 DIF DAH
Diglycidyl ether of Bisphenol A....
Diglycidyl ether of Bisphenol F.....
Diheptyl phthalate
4l
4l
34
BDE
DGF
DHP
BPA
tr Dioctyl phthalate
1,4-Dioxane.....
Dipentene........
34
4l
30
DOP
DOX
DPN
DAH
Di-n-hexyl adipate.............
Diisobutyl carbinol............
Diisobutylene..
34
Diisobutylamine................................ 7
20
30
DHA
DBU
DBC
DBL
tr Diphenyl
Diphenyl, Diphenyl ether mixture.
Diphenyl ether.................
Diphenyl ether, Diphenyl phenyl
32
33
4l
DIL
DDO
DPE
Diisobutyl ketone .....,........

Diisobutyl phthalate...,......
Diisodecyl phthalate .........
l8
34
t4
DIK
DIT
DID
F ether mixture...
Diphenylmethane diisocyanate .......
Diphenylol propane-
4l
12
DOB
DPM
Diisononyl adipate ............. 34 DNY . : Epichlorohydrin resins................. r0 DPR

Diisononyl phthalate..........
Diisooctyl phthalate..........
34
34
DIN
DIO
F D i - n - P r o p y 1 a m i n e . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Dipropylene glycol .......................... 0 ,
.. DNA
DPG
r
Diisopropanolamine ......................... 8 DIP Dipropylene glycol dibenzoate....... 34 DGY
D i i s o p r o p y l a m i n e. . . . . . . . . . . . . . . . . . . . . . . . . . . . . DIA Dipropylene glycol methyl ether... 40 DPY
D i i s o p r o p y l b e n z e n e . . . . . . . . . . . . . . . . . . . . . . . . . . 32 DIX Distillates, flashed feed stocks......... 33 DFF
Diisopropyl naphthalene..... 32 DII Distillates, straight run..................... 33 DSR
N,N-Dimethylacetamide.................. l0 DAC Ditridecyl phthalate......... 34 DTP DAH
N,N-Dimethylacetamide solution ...
Dimethyl adipate.............
l0
34
DLS
DLA
ll- Diundecyl phthalate..........
D o d e c a n e. . . . . . . .
34
3l
DUP
DOC
DAH
PFN
r
Dimethylamine 7 DMA Dodecanol....... 20 DDN LAL
Dimethylamine solution................... 7 DMG,/DMY,/DMC D o d e c e n e. . . . . . . . 30 DOZ DDC,/DOD
SCANNED BY MKP
ir: & BARIS A. 2004
372 373
r
Table l-Alphabetical
Ctemicrl nane Group


tr Tabte I-Alphabetical
Ctemicsl name Group

r
No. code
No. code
Ethylenediaminetetracetic acid,
2-Dodecenylsuccinic acid,
tetrasodium salt solution .............. 43 EDS
dipotassium salt solution. 34
Ethylene dibromide........ 36 EDB
r
Dodecylamine, tetraOecytami'nl 236
27 Ethylene dichloride........ EDC
mixture DTA 220
E t h y l e n eg l y c o l . . . . . . . . . . . . . . EGL
Dodecyl alcohol............. 20 DDN/LAL
Ethylene glycol acetate. 34 EGO
D o d e c y l b e n z e n e. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 DDB AKB
20 Ethylene glycol butyl ether ............ Q EGM
Dodecylbenzenesulfonic acid.......... DSA ,10
Ethylene glycol tert-butyl ether.....
Dodecyl diphenyl ether [:
I Ethylene glycol butyl ether
disulfonate solution....................... 43 DOS
acetate............. 34 EMA
Dodecyl methacrylate l4 DDM
Ethylene glycol diacetate................ 34 EGY
Dodecyl-Pentadecyl methacrylate
m i x t u r e s. . . . . . . . . . .
Dodecyl phenol..............
t4
2l
DDP
DOL
t: Ethylene glycol dibutyl ether.........
Ethylene glycol ethyl ether.............
Ethylene glycol ethyl ether acetate
Q
40
34
EGB
EGE
EGA
Drilling brine (containing Calcium,
Potassiumor Sodium salts).......... 43 DRB r-: Ethylene glycol isopropyl ether..... .lO EGI
Drilling brine (containing Zinc I Ethylene glycol methyl ether .........
Ethylene glycol methyl ether
,10 EME
salts)................. 43 DZB
acetate............. 34 EGT
t:
Drilling mud (low toxicity) (d
Ethylene glycol phenyl ether.......... & EPE
flammable or combustible) ............ 33 DRM
Drilling mud (low toxicity) (if non- Ethylene glycol phenyl ether,
Diethylene glycol phenyl ether
flam mabIe or non-combustible)..... 43 DRM
E p i c h | o r o h y d r i n. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t 7
Epoxy resin.....
E t h a n e. . . . . . . . . . . . .
l8
3l
EPC
ETH
t- mrxture
Ethylene glycol propyl ether..........
Ethylene oxide................
Ethylene oxide, Propylene oxide
40
Q
rO
EDX
EGP
EOX
Ethanolamine.. 8 MEA ....*
2 - E t h o x y e t h a n o.l . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
2 - E t h o x y e t h y l a c e t a t e. . . . . . . . . . . . . . . . . . . . . . 34
EEO
EEA
t- mlxture
Ethylene-Vinyl acetate copolyrner
emulsion
t6
43
EPM
r
Ethoxylated alcohols, C I 1-C15....... 20 EOD,/ENP,/EOP/ F.OT,/ETD
Ethyl ether...... 4I EET
E t h o x y t r i g l y c o l . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,10 ETG
Ethyl-3-ethoxypropionate................ 34 EEP
Ethyl acetate... 34 ETA
2 - E t h y l h e x a l d e h y d e. . . . . . . . . . . . . . . . . . . . . . . . . 19 EHA
E t h y l a c e t o a c e t a t e . . . . . . . . . . . . . . . . . . . . . . . . . . . .34 EAA
r
2 - E t h y l h e x a n o i ca c i d . . . . . . . . . . . . . . . . . . . . . . . 4 EHO
Ethyl acrylate. t4 EAC
220 2-Ethylhexanol 20 EHX
Ethyl alcohol.. EAL
27 2 - E t h y l h e x y l a c r y l a t e . . . . . . . . . . . . . . . . . . . . . . . 14 EAI
Ethylamine...... EAM
Ethylamine solution ...........
2 - E t h y l h e x y l a m i n e. . . . . . . . . . . . . . . . . . . . . . . . . . . 7 EHM
7 EAN
Ethyl hexyl phthalate 34 EHE
Ethyl amyl ketone..............
Ethylbenzene..
Ethyl butanol..
l8
)z
20
EAK
ETB
EBT
ELK
t: Ethyl hexyl tallate...............
Ethylidene norbornene
34
230
E t h y l m e t h a c r y l a t e . . . . . . . . . . . . . . . . . . . . . . . . . . . 14'
EHT
ENB
ETM
N - E t h y l - n - b u t y 1 a m i n .e. . . . . . . . . . . . . . . . . . . . . EBA
Ethyl butyrate
Ethyl chloride.
Ethyl chlorothioformate..................
34
36
2o
EBR
ECL
ECT
t: 2-Ethyl-6-methyl-N-(l'-methyl-2-
methoxyethyl)aniline....................
o-Ethyl phenol..............
9
2I
EEM
EPL
E t h y l p r o p i o n a t e. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 EPR
t:
N-Ethylcyclohexylamine................. ECC 2I9
2-Ethyl-3-propylacrolein.................. EPA
Ethylene.......... 30 ETL
Ethyl toluene.. 32 ETE
Ethylene chlorohydrin... 20 ECH
Fatty acids (saturated, Cl3 and
Ethylene cyanohydrin 20 ETC
above)............. 34
E t h y 1 e n e d i a m i n e . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2. 7 EDA
375
374
- ,jgt::
SCANNED BY MKP & BARIS A. 2004 .u
r
Chemical name Group CHRIS RelatedCHRIS codes
|'r:
ll
Chemical name Group CHRIS Related CHRIS codes

No. code
No. code
F
Fatty acid amides............. 33
Hexameth ylenetetramine 7 HMT
Ferric chloride solution................... I FCS FCL
Hexamethylenetetramine solutions . HTS
Ferric hydroxyethylethylene-
H e x a m e t h y l e n i m i n e . . . . . . . . . . . . . . . . . . . . . . . . .7
. HMI
diaminetriacetic acid, trisodium
231
salt solution.....
Ferric nitrate, Nitric acid solution..
243 FHX
FNN
STA lr
tl
Hexane............,
Hexanoic acid....,............. 4
HXS
HXO
IHA,/HXA
Fish solubles (water basedfsh meal H e x a n o l. . . . . . . . . . . 20 HXN

Hexene............. 30 HEX HXE,/HXT
extractil............
Formaldehyde, Methanol mixtures.
Formaldehyde solution....................
2lg
219
43 FSO
MTM
FMS
tr
il
Hexyl acetate..
Hexylene glycol ..............
34
20
HAE
HXG
HSA
Formamide...... l0 FAM Hydrochloric acid............................ I HCL

24 I HCS
Formic acid.....
Fructose solution............ 43
FMA
II:
(l
Hydrochloric acid, spent.................
Hydrofl uorosilicic acid.................... I HFS
Fumaiic adduct of Rosin, water Hydrogen peroxide solutions .......... 10 HPN,/HPS,/HPO
dispersion 43 FAR 2 - H y d r o x y e t h y l a c r y l a t e . . . . . . . . . . . . . . . . . . r' 20 HAI
F u r f u r a l . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . l. .9
F u r f u r y l a l c o h o l. . . . . . . . . . . . . 220
FFA
FAL
tr
il
N.
(Hydroxyethyl)ethylenediamine-
Gas oil, cracked............ JJ GOC triacetic acid. trisodium salt
Gasoline blending stock, alkylates.. JJ GAK s o l u t i o n. . . . . . . . . . . 4t HET
Gasoline blending stock,
tl 2-Hydroxy-4-(methylthio)butanoic
tl
reformates........ 33 GRF acid ................. 4 HBA
Gasolines: Isophorone ...... 218 IPH
Automotive (not over 4.23 grams ti-
tl
I s o p h o r o n ed i a m i n e . . . . . . . . . . . . 7 IPI
lead per gal.) .... 33 GAT Isophorone diisocyanate.... t2 IPD
Aviation (not over 4.86 grams Isoprene.......,... 30 IPR
Ieadper gal)..... 33 GAV AVA I s o p r o p y l b e n 2 e n e. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 ) CUM
Casinghead (natural) ..,................. GCS
I-
JJ
tl Jet fuels:
PoIymer........... 33 GPL JP-l ................. 33 JPO
Straight run................... 33 GSR JP-3................. JPT
tr:
JJ
Glutaraldehyde solution .................. l9 GTA JP-4................. JJ JPF

Glycerine 220 GCR tl
JP-5................. JJ JPV
Glycerol polyalkoxylate. 34 JP-8................. 33 JPE
Glyceryl triacetate ......... 34 Kaolin clay slurry .............. 43
Gylcidyl ester of tridecylacetic Kerosene 33 KRS
acid .................. 34 GLT Ketone residue l8
r
Glycidyl ester of Versatic acid....... 34 GLT Kraft black liquor............... 5 KPL
G l y c o l d i a c e t a t e. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t1
Kraft pulping liquors (Black,
Glycols, Resins, and Solvents
G r e e n ,o r W i t e ) . . . . . . . . . . . . . . . 5 KPL
mlxture 33 Lactonitrile solution............ J I LNI
Glyoxal solutions........... t9 cos
H e p t a n e. . . . . . . . . . .
n - H e p t a n o i ca c i d . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
3l HMX
HEP
HPI,/HPT
F Latex, liquid synthetic
Lauric acid......
Lignin liquor...
43
34
41
LLS
LRA
r
Heptanol.......... 20 HTX HTN l, 20
Magnesium chloride solution ..........
Heptene........... 30 HPX HTE
Magnesium nonyl phenol sulltde.... JJ
Heptyl acetate. 34 HPE
M a g n e s i u ms u l f o n a t e . . . . . . . . . . 34 MSE MAS
Herbicide (C l5-H22-NO2-Cl) ......... 33 MCO
Maleic anhydride............................., 1 l MLA
Hexamethylenediaminesolution ..... 7 HMC HMD
376
F Maleic anhydride copolymer .......... JJ
377
''
- ' r SCANNED BY MKP & BARIS A. 2004
F
Table l-Alphabetical
Chemicgl name Group

CHRIS RelatedCHRIS codes

F Table I-Alphabetical List of Cargoes-Continued
No. code Chenical nsme Group CHRIS Related CHRIS codes
Mercaptobenzothiazol, sodium salt
solution........,...
Mesityl oxide.. 2lg
)
MSO
SMB F M e t h y l m e t h a c r y | a t e . . . . . . . . . . . . . . . . . . . . . . . . 14
3 - M e t h y l - 3 - m e t h o x y b u t a n o.l. . . . . . . . . . .
No,
20
code
MMM
Metam sodium so|ution....................

Methacrylic acid..................
Methacrylonitrile..............................
Methane...........
7
4
l5
3l
MSS
MAD
MET
MTH
SMD
r 3-Methyl-3-methoxybutyl acetate...
M e t h y l n a p h t h a l e n .e. . . . . . . . . . . . . . . . . . . . . . . . 32
Methylolureas.
2-Methyl pentane............
34
19
3l
MNA
MUS
tr
IHA
3-Methoxy- 1-butanol ........................ 20 2 - M e t h y l - l - p e n t e n e. . . . . . . . . . . . . . . . . . . . . . . . . . 30 MPN
3-Methoxybutyl acetate................... 34 MOA 4 - M e t h y l - l - p e n t e n.e. . . . . . . . . . . . . . . . . . . . . . . . . 30 MTN
I -Methoxy-2-propyl acetate ............ 34 MPO Methylpyridine 9 MPR,/MPE,/MPF
Methoxy triglycol
Methyl acetate
M e t h y l a c e t o a c e t a t .e. . . . . . . . , . . . . . . . . . . , . , . . 34
Methyl acetylene, Propadiene
N
34
MTG
MTT
MAE r N-Methyl-2-pyrrolidone
Methyl salicylate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
.
a l p h a - M e t h y 1 s t y r e n e . . . . . . . . . . . . . . . . . . . . . . . . . 30
Metolachlor 34
9 MPY
MES
MSR
MCO
mlxture
Methyl acrylate
Methyl alcohol 220
30
t4
MAP
MAM
MAL
tr Mineral spirits...............
Molasses
M o l a s s e sr e s i d u e . . . . . . . . . . . . .
33
20
0
MNS
Methylamine...
Methylamine solutions.....................
M e t h y l a m y l a c e t a t e. . . . . . . . . . . . . . . . . . . . . . . . 34
M e t h y l a m y l a l c o h o l . . . . . . . . . . . . . . . . . . . . . . . . 20
7
MTA
MSZ
MAC
MAA
r Monochlorodifl uoromethane........,..
Morpholine
Motor fuel antiknock compounds
containing lead a|kyls............,...... 1 0
36
27
MCF
MPL
r
MFA
M e t h y l a m y l k e t o n e. . . . . . . . . . . . . . . . . . . . . . . . . l 8 MAK Myrcene .......... 30 MRE
M e t h y l b r o m i d e . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 MTB Naphtha:
Methyl butenol 20 MBL C o a l t a r s o | v e n t. . . . . . . . . . . . . 33 NCT
Methyl butyl ketone......................... l 8 MBK Cracking fraction............ 233
Methyl tert-butyl ether....................
Methylbutynol
3-Methyl butyraldehyde .
241
20
l9
MBE
MBY F Petroleum........
Solvent
Stoddard so|vent.............
33
' 333
3
PTN
NSV
NSS
M e t h y l b u t y r a t e . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
M e t h y l c h l o r i d e . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
M e t h y l c y c l o h e x a n e. . . . . . . . . . . . . . . . . . . . . . . . . . 3 l
Methylcyclopentadiene dimer......... 30
MBU
MTC
MCY
MCK
r Varnish Makers' and Painters' ....
Naphthalene....
Naphthalene sulfonic acid-
formaldehyde copolymer,
33
32
NVM
NTM
Methyl diethanolamine ....................

4,4'-Methylene dianiline (43Vo or
less), Polymethylene
8 MDE MAB
ti- sodium salt solulion......................
Naphthalene sulfonic acid, sodium
salt solution
O
34
NFS
NSA
polyphenylamine, o-
tt:
N a p h t h e n i ca c i d . . . . . . . . . . . . . . . . . . 4 NTI
Dichlorobenzene mixtures........,., 9 MDB Naphthenic acid, sodium salt
2-Methyl-6-ethy1ani1ine.................... 9 MEN so1ution........,... 43, NTS
Methyl ethyl ketone......................... 2 1 9 MEK N e o d e c a n o i ca c i d. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 NEA
2-Methyl-5-ethylpyridine.................
Methyl formal.
Methyl formate
9
4l
34
MEP
MTF
MFM
tt: N i t r a t i n ga c i d . . . . . . . . . . . . . . . . . .
N i t r i c a c i d ( l O V ao r l e s s ) . . . . . . . . . . . . . . . . . 3
Nitric acid (greater than TOVo)........
IO
r0
NIA
NCD
NAC
tr
Methyl heptyl ketone....................... l 8 MHK Nitrobenzene... 42 NTB
2-Methyl-2-hydroxy-3-butyne ......... 20 MHB o - N i t r o c h l o r o b e n z e n e. . . . . . . . . . . . . . . . . . . . . . 42 CNO CNP
Methyl isoamyl ketone l8 MAK N i t r o e t h a n e. . . . . 42 NTE
Methyl isobutyl carbinol 20 MIC o-Nitrophenol r'20 NTP NIP,/NPH
Methyl isobutyl ketone.................... 218
378
MIK
ir N itropropane
Nitropropane, Nitroethane mixture
42
42
NPM
NNM
NPN,/NPP
SCANNED BY MKP
ll . & BARIS.i^..4tt,!ih'"'.'.
t-
--,,.^;., A. 2004. 1r,
379
r'
Table l-Alphabetical List of Cargoes-Continued r Table I-Alphabetical
Chemical name
Group
r
Group CHRIS Related CHRIS coder
CHRIS RelatedCHRIS coder
No. code
No. cod€
No. 2-D. JJ OTD
42 NIT NIE/NTI,/NTR
3l NAX NAN
No.4 33 OFR
4
30
220
t4
NNA
NON
NNS
NMA
NAI,/NIN
NNE
NNI,/NNN
r No. 5 33
JJ
JJ
oFv
osx
oAs
33
2l
40
NNP
NPE f- 33
JJ ocF
40
JJ
NPE
NPS
r 33
34
34
ocM
CFY
r
0
30 33 OIL
l0 ODD JJ ODS
JJ
JI OAX IOO,/OAN
4 OAY OAA 33 oLs
30
220
OTX
ocx
OTE
IOA,/OTA t- 33
JJ
33
OLB
OMN
OMS
r
l9 OAL IOC,/OLX
34 ODA JJ OMT
34 OET 33 ONF
234 ONE 34 ooI
r
2l 34 OPE
34 OBB 34 OPE
34 ocA 33 OPT
234
34
34
234
occ
oco
ocs
OFS
r JJ
JJ
JJ
JJ
OPI
ORG
oRs
34
34
234
OLD
ooL
OPM
t- 33
JJ
JJ
ORD
ORN
34
34
34
34
oPo
OPN
ORP
t- 34
40
oIs
EVO
r
34 ORB
JJ OSP
34 osF JJ osD
34 osB JJ osY
34 OSN
34 OTL
234
34
34
oTc
ovG
ooN
r JJ
JJ
34
TOF
OTN
OTF
OTG
r
JJ
JJ ooD JJ OTB
33 oTw 33
SCANNED BY MKP
E & BARIS A. 2004 381
r
Chemical nsme Group

List of Cergoes-Continued
CHRIS RelatedCHRIS codes

r Table l-Alphabetical
Chemical name Group

Olefin mixtures
alpha-Olefins (C6 - Cl8) mixtures..
No.
30
30
code
OAM
OFX,/OFY
r Polyethylene glycol dimethyl
ether..,...,,.........
No.
/t0
code
r
alpha-Olefins (C I 3 and above)........ 30 Polyethylene glycol monoalkyl
Oleic acid........ 34 OLA ether................. 40 PEE
Oleum.............. 1'20 OLM P o l y e t h y l e n ep o l y a m i n e s . . . . . . . . . . . . . . . . . 2 7 PEB
Oxyalkylated alkyl phenol Polyferric sulfate solution 34 PSS
20
t-
formaldehyde.. 33 Polyglycerol GCR
Palm kernel oil, fatty acid............... 34 PNO Polymethylene polyphenyl
Palm kernel oil, fatty acid methyl isocyanate........ t2 PPI
e s t e r. . . . . . . . . . . . . , . . . 34 PNF P o l y m e t h y l s i l o x a n e. . . . . . . . . . . . . . . . . . . . . . . . . . 34
Palm stearin
n-Paraffins (Cl0 - C20).....
Paraldehyde....
34
3l
l9
PMS
PFN
PDH
DCC,/DOC,/TRD t- Poly(20)oxyethylene sorbitan
monooleate......
Polypropylene
34
30
PSM
PLP
P o l y p r o p y l e n eg 1 y c o l . . . . . . . . . . . . . . . . . . . . . . .40 PGC
P e n t a c h l o r o e t h a n e . . . . . . . . . . . . . . . . . . . . . . . . . . . .36
Pentadecanol...
1.3-Pentadiene.
20
30
PCE
PDC
PDE PDN
tr Polypropylene glycol methyl ether
P o l y s i l o x a n e. . . .
Potassium hydroxide solution.........
q
34
25
PGM
cPs
Pentaethylenehexamine,
Tetraethylenepentamine mixture.
Pentane............
Pentene............
3l
30
PEP
PTY
PTX
IPT,/TTTA
PTE
r P o t a s s i u mo l e a t e . . . . . . . . . . . . . . .
P r o p a n e. . . . . . . . . . .
Propanolamine
34
3l
8
POE
PRP
PAX MPA,/PLA
Pentene, Miscellaneous
hydrocarbon mixture....................
3-Pentenenitrile
230
37 PNT
r P r o p i o n a l d e h y d e. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 9
Propionic acid .................
Propionic anhydride.........
Propionitrile....
ll
37
4
PAD
PNA
PAH
PCN
Pentyl aldehyde................................ t 9
P e r c h l o r o e t h y l e n e. . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Petrolatum 33
2l
PER
PTL r n - P r o p o x y p r o p a n o l. . . . . . . . . . . . . . . . . . . . . . . . . . 40
Propyl acetate.
Propyl alcohol
34
220
PXP
IAC,/PAT
IPA,/PAL
r
P h e n o l. . . . . . . . . . . . . PHN Propylamine.... 7 IPP,/PRA,/IPO
I -Phenyl-I -xylyl ethane................... t2 PXE Propylbenzene 32 PBZ
P h o s p h o r i ca c i d . . . . . . . . . . . . . . . . . . I PAC iso-Propylcyclohexane..................... J I rPx
Phosphorus r0 PPW,/PPR,/PPB Propylene........ 30 PPL
Phthalic anhydride........ ll PAN Propylene-butylene copolymer....... 30 PBP
Pinene..,...........
Pine oil............
30
33
PIN
OPI l- P r o p y l e n ed i m e r . . . . . . . . . . . . . . .
Propyleneglycol ..............
30
220
PDR
PPG
r
Polyalkenyl succinic anhydride Propylene glycol monoalkyl ether. 40 PGE PME,/PGY
a m i n e. . . . . . . . . . . . . . . 33 Propyleneglycol ethyl ether .......... 40 PGY PGE
Polyalkylene glycols, Polyalkylene Propyleneglycol methyl ether....... 40 PME PGE
glycol monoalkyl ethers Propyleneoxide................ l6 POX
mixtures...........
Polyalkyl(Cl8 - C22) acrylate in
X y l e n e. . . . . . . . . . . . .
Polyalkylene oxide polyol...............
,|()
t4
20
PPX
PIx
PAO
r Propylene ietramer
Propylenetrimer..............
Propyl ether....
30
30
4l
PTT
PTR
IPE,/PRE
r
Pseudocumene 32 TME,/TRE
Polybutadiene, hydroxyl Pyridine........... 9 PRD
terminated 20 P y r i d i n eb a s e s . . . . . . . . . . . . . . . . 9 PRB
Polybutene ...... 30 PLB R o s i no i | . . . . . . . . . . 33 ORN
P o l y d i m e t h y l s i l o x a n .e. . . . . . . . . . . . . . . . . . . . . .
P o l y e t h y l e n eg l y c o l . . . . . . . . . . . . . . . . . . . . . . . . .
34
n
r Rosin soap (disproportionated)
so1ution............ 43 RSP

382 383
r
Table I-Alphabetical List of Cargoes-Continued r Table I-Alphabetical List of Cargoes-Continued
r
Chemical name Group CHRIS RelatedCHRIS codes Chemical neme Group CHRIS Related CHRIS codes
No. code No, code
Rum.......,......... 20 T a l l o w f a t t y a c i d . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2 3 4 TFD
Salicylaldehyde 19 SAL Tallow fatty alcohol ........................ 20 TFA
S e w a g es l u d g e . . . . . . . . . . . . . .
Sodium acetate solution
Sodium alkyl sulfonate solution......
Sodium aluminate solution
4t
34
43
5
SAN
SSU
SAU
r Tallow nitrile..
1,1,2,2-Tetrachloroethane................
Tetradecanol...
Tetradecene
37
36
20
30
TEC
TTN
TTD
Sodium benzoate so|ution,...............
Sodium borohydride, Sodium
hydroxide solution........................ 5
34 SBN
SBX SBH,/SBI
t- Tetradecylbenzene........................... 12
T e t r a e t h y l e n eg l y c o l . . . . . . . . . . . . . . . . . . . . . . . . , 1 0
Tetraethylenepentamine................... 7
TDB
TTG
TTP
AKB
Sodium carbonate solutions.............
Sodium cyanidesolution..................
Sodium dichromate solution............ r ' 2 0
5
S o d i u m c h l o r a t es o l u t i o n . . . . . . . . . . . . . . . . . I ' 2 0
5
SCE
SDD
SCS
sDL
SDC
scN
SCR
r T e t r a h y d r o f u r a n. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 l
Tetrahydronaphthalene.................... 32
1,2,3,5-Tetramethylbenzene.............
Tetrasodium salt of EDTA
32
THF
THN
TTB
Sodium dimethyl naphthalene

s u l f o n a t es o | u t i o n . . . . . . . . . . . .
Sodium hydrogen sulfide, Sodium
234
20
DNS
t- solution...........
Titanium tetrachloride...
Toluene
43
32
2 TTT
TOL
EDS
carbonate solution SSS T o l u e n e d i a m i n e. . . . . . . . . . . . , . . . . . . . , . . . . . . , . . . . 9 TDA

Sodium hydrogen sulfite solution...
Sodium hydrosulfide solution .........
Sodium hydrosulfide, Ammonium
43
25
SHX
SHR t- Toluene diisocyanate
o-Toluidine......
12
9
T r i a r y l p h o s p h a t e. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 4
TDI
TLI
sulfide solution
Sodium hydroxide solution
Sodium hypochlorite solution.........
25
25
5
SSA
SHP
css
sHc r Tributyl phosphate........
1,2,4-Trichlorobenzene
34
36
I , I , I - T r i c h | o r o e t h a n e . . . . . . . . . . . . . . . . . . . . . . . 23 6
TBP
TCB
TCE
r
Sodium 2-mercaptobenzothiazol 1,1,2-Trichloroethane....................... 36 TCM
s o l u t i o n. . . . . . . . . . . . 5 SMB T r i c h l o r o e t h y l e n e . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2 3 6 TCL
Sodium naphthalene sulfonate 1,2,3-Trichloropropane.................... 36 TCN
solution.,.......... 34 SNS l, 1,2-Trichloro- 1,2,2-
Sodium nitrite solution
Sodium polyacrylate solution..........
Sodium salt of Ferric hydro-
243
5 SNI SNT
r trifluoroethane
Tricresyl phosphate........
Tridecane........
36
34
3l
TTF
TRD
TCO,/TCP
PFN
r
xyethylethylenediaminetriacetic Tridecanol...... 20 TDN
acid solution.... 4T STA FHX Tridecene........ 30 TDC
S o d i u m s i l i c a t es o | u t i o n . . . . . . . . . . . . . . . . . . . 2 4 3 SSN ssc T r i d e c y l b e n z e n e. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 2 TRB AKB
Sodium sulhde, Hydrosulfide T r i e t h a n o I a m i n e . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2 8 TEA
r
s o l u t i o n. . . . . . . . . . . . r.20 SSH/SSL/SSJ Triethylamine 7 TEN
Sodium thiocyanate solution........... 1'20 sTs SCY T r i e t h y | b e n 2 e n e . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 2 TEB
Sorbitol solutions........... 20 SBT Triethylene g1yco1.............. 40, TEG
Stearic acid 34 SRA
r
Triethylene glycol butyl ether........ ,f0
S t y r e n e. . . . . . . . . . . . 30 STY Triethylene glycol butyl ether
Sulfolane 39 SFL mixture N
SuIfur............... 10 sxx Triethylene glycol di-(2-
r
Sulfuric acid................... 22 SFA ethylbutyrate). 34 TGD
Sulfuricacid, spent........ sAc Triethylene glycol ether mixture.... 40
Tall oil............. 34 OTL Triethylene glycol ethyl ether........ & TGE
Tall oil soap (disproportionated) T r i e t h y l e n e t e t r a m i n e . . . . . . . . . . . . . . . . . . . . . . . . 27 TET
s o l u t i o n. . . . . . . . . . . .
Tallow.............
43
234
TOS
TLO
r Triethyl phosphate........
Triethyl phosphite.........
34
234
TPS
TpI
384
SCANNED BY MKP;*i&,{r&t:
, -,.
& BARIS d A. ', *-l"t
-t-,;t ttfiiti:iil
2004 "-l;1* ,-.,i....t
f-
Table I-Alphabetical List of Cargoes-Continued
r Table l-Alphabetical List of Cargoes-Continued
r
Chemical nan Group CHRIS Related CHRIS codeg Chemical name Group CHRIS Related CHRIS codes
No. code No. code
Triisobutylene. 30 TIB Vinyl ethyl ether................ l3 VEE
Triisooctyl trimellitate ....... 34 Vinylidene chloride........... 35 vcI
Triisopropanolamine ........................ E TIP Vinyl neodecanate.,......,.........,.......,. 1 3 VND
Triisopropanolamine salt of 2,4-
s o l u t i o n. . . . . . . . . . . . 43 DTI
t- Vinyltoluene
W a x e s :. . . . . . . . . . , . .
Carnauba ....,....
l3
34
VNT
wAx
wcA
4 TAA P a r a f f i n. . . . . . . . . . . . 3l WPF
f-
Trimethylacetic acid ........................
T r i m e t h y l b e n 2 e n e . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 TRE TME,/TMB,/TMD White spirit (low (15-2OVo)
Trimethylhexamethylenediamine aromatic) ......... JJ wsL wsP
r
( 2 , 2 , 4 -a n d 2 , 4 , 4 - ) . . . . . . . . . . . . . . . . . . . . . . . . . . 7 THA Xylene............. 32 xLx XLI0''/){LO/)KLP
Trimethylhexamethylene Xylenols.......... 2l XYL
diisocyanate (2,2,4- md 2,4,4-).... t2 THI Zinc bromide, Calcium bromide
Trimethylol propane solution see Drilling brine
(containing Zinc salts).................. 43 DZB
polyethoxylate
2,2,4-Trimethyl pentanediol- 1,3-
diisobutyrate....
20
34
TPR
t- r Because of very high reactivity or unusual conditions of carriage or potential compat-
r
2,2,4-Trimethyl- 1,3-pentanediol- 1- ibility problems, this product is not assigned to a specific group in the Compatibility
isobutyrate....... 34 TMP Chart. For additional compatibility information, contact Commandant (G-MTH), U.S.
2,2,4-Trimethyl-3-pentanol- I - Coast Guard, 2100 Second Street, SW., Washington, D.C. 20593-0001. Telephone (202)
isobutyrate....... 34
r
267-1577.
Trimethyl phosphite......... 234 TPP 2See Appendix l-Exceptions to the Chart.
Tripropylene... 30
Tripropylene glycol ......................... & TGC
,m
r
Tripropylene glycol methyl ether .. TGM
Trisodium nitrilotriacetate 34
Trixylenyl phosphate........ 34 TRP
Turpentine....... 30 TPT
U n d e c a n o i ca c i d . . . . . . . . . . . . . . . . . .
Undecanol.......
Undecene
20
30
4 UDA
UDC
UND
r
r
Undecyl alcohol ............ 20 UND
U n d e c y l b e n z e n e. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t z UDB AKB
Urea, Ammonium mono- and di-
hydrogen phosphate, Potassium
chloride solution............
Urea, Ammonium nitrate solution
(containing Ammonia)
0
6
UPX
UAS r
(not containing Ammonia)...........
Urea, Ammonium phosphate
solution............
4l
43
ANU
UAP
r
l9
r
Valeraldehyde. IVA/VAL/VAK
Vanillin black liquor.... l VBL
Vegetable protein solution 43
Vinyl acetate... l3 VAM
Vinyl acetate-Fumarate copolymer
Vinyl chloride
34
35 vcM
r
,;i:Aa"d^.' t;, ...,1,:,
386 SCANNED BY MKP & BARIS A. 2004
- ,.IiiJ:;I.ldt
0. Unassigned Cargoes
Table Il-Grouping of Cargoes
Acetone cyanohydrin 1'2

Urea, Ammonium mono- and di-
r Cresylic acid, sodium salt solution
Kraft black liquor
Hexamethylenetetramine solutions
Hexamethylenimine
t-
hydrogen phosphate, Potassium Kraft pulping liquors Isophorone diamine
Alkylbenzenesulfonic acid L2 chloride solution Mercaptobenzothiazol, sodium salt Metam sodium solution
Aluminium chloride, Hydrochloric 1. Non-Oxidizing Mineral Acids solution Methylamine
acid solution I Di-(2-ethylhexyl)phosphoric aoid Potassium hydroxide solution 2 Methylamine solutions
Ammonium hydrogen phosphate
" solution r
Ammonium nitrate solution I
Ferric chloride solution
Hydrochloric acid
Hydrochloric acid, spent
t- Sodium aluminate solution
Sodium borohydride, Sodium
hydroxide solution
.l
Morpholine 2
Pentaethylenehexamine,
Tetraethylenepentamine mixture
Ammonium thiocyanate, Ammonium
thiosulfate solution t
Benzenesulfonyl chloride L2
gamma-Butyrolactone r'2
Hydrofl uorosilicic acid
Phosphoric acid
2. Sulfuric Acids
Sulfuric acid 2
r Sodium carbonate solutions
Sodium cyanide solution
Sodium hydrosulhde solution 2
Sodium hydrosulfrrde,Ammonium
Polyethylenepolyamines 2
Propylamine
Tetraethylenepentamine
Triethylamine
Chlorine I sulfide solution 2 2
Chlorosulfonic acid I
Sulfuric acid, spent
Titanium tetrachloridc
3. Nitric Acid
I- Sodium hydroxide solution 2
Sodium hypochlorite solution
Triethylenetetramine
Trimethylhexamethylene diamine
(2,2,4- and 2,4,4-)
Dimethylamine salt solution Lt Ferric nitrate, Nitric acid solution Sodium 2-mercaptoben zothiazol t. Alkanolaminec
Dimethylamine salt of 2,4-
solution 1'2
Nitric acid (707o or less)
4. Organic Acids
Acetic acid 2
l- solution
Sodium nitrite solution
Vanillin black liquor
2-(2-Aminoethoxy)ethanol
Aminoethyldiethanolamine,
Aminoethylethanolamine solution
Diphenylol propane-Epichlorohydrin
resins r
Dodecylbenzenesulfonic acid L2
Ethyl chlorothioformate L2
Acrylic acid 2
Butyric acid
Cashew nut shell oil (untreated)
t- 6. Ammonia
Ammonia, anhydrous
Ammonium hydroxide (28Vo or l*s
2-Amino-2-methyl- 1-propanol
Diethanolamine
Chloroacetic acid solution Ammonia) Diethylaminoethanol
Ethylene oxide r
2-Hydroxyethyl acrylate L2
Magnesium chloride solution L2
Chloropropionic acid
Cyclohexane oxidation product acid
water
t- Ammonium nitrate, Urea solution
(containing Ammonia)
Diethylethanolamine
Diisopropanolamine
Dimethylethanolamine
Molasses residue 1
Motor fuel antiknock compounds
containing Lead alkyls I
Naphthalene sulfonic acid-
Decanoic acid
2,2-Dichloropropionic acid
2,2-Dimethyloctanoic acid
2-Ethylhexanoic acid
r (containing Ammonia)
7. Aliphatic Amines
N-Aminoethylpiperazine
Butylamine
Ethanolamine
Propanolamine
Triethanolamine 2
Triisopropanolamine
t-
formaldehyde copolymer, sodium
Formic acid 2 Cyclohexylamine 9. Aromatic Amines
salt solution I
n-Heptanoic acid Dibutylamine Aniline
Nitrating acid 1
Hexanoic acid Diethylamine 2 4-Chloro-2-methylphenoxyacetic
Nitric acid (greater than TOVo) |
o-Nitrophenol 1'2
Noxious Liquid Substance, n.o.s.
(NLS's) r
Oleum ln2
2-Hydroxy-4-(methylthio)butanoic
acid
Methacrylic acid
Naphthenic acid
r Diethylenetriamine
Diisobutylamine
Diisopropylamine
Dimethylamine
acid, Dimethylamine salt solution
2,6-Diethylaniline
Dimethylamine salt of 4-Chloro-2-
methylphenoxyacetic acid solution
Phosphorus I
Sodium chlorate solution L,
Sodium dichromate solution L!
Neodecanoic acid
Nonanoic acid
Octanoic acid
t- Dimethylamine solution
N,N-Dimethylcyclohexylamine
Di-n-propylamine
2,6-Dimethylaniline
2-Ethyl-Gmethyl-N-( l'-methyl-2-
methoxyethyl)aniline
r
Propionic acid Dodecylamine, Tetradecylamine 4,4'-Methylene dianiline (43Vo or
Sodium hydrogen sulfide, Sodium
Trimethylacetic acid mixture 2 less), Polymethylene
carbonate solution r2
Undecanoic acid Ethylamine 2 polyphenylamine, o-
Sodium sulfide, Hydrosulfide
5. Caustics Ethylamine solution Dichlorobenzene mixtures
r
solution L2
Ammonium sulfide solution N-Ethyl-n-butylamine 2-Methyl-6-ethyl aniline
Sodium thiocyanate solution L2
Calcium hypochlorite solutionc N-Ethyl cyclohexylaminc 2-Methyl-5-ethyl pyridine
Sulfur I
Caustic potash solution 2 Ethylenediamine 2 Methyl pyridine
Caustic soda solution 2
r
2-Ethyl hexylamine 3-Methylpyridine
Cresylate spent caustic Hexamethylenediamine solution N-Methyl pyrrolidone
Hexamethylenetetramine Pvridine
388
SCANNED BY MKP & BARIS A. 2004 r'"'' r;'
r
Pyridine bases
Toluenediamine
p-Toluidine
1,3-Dichloropropenc
Dichloropropene, Dichloropropane
mixtures
tr Paraldehyde
Pentyl aldehyde
Propionaldehyde
Polybutadiene, hydroxyl terminated
Polyglycerol
Propyl alcohol 2
Propylene glycol t
10. Amides
Acrylamide solution
N,N-Dimethylacetamide
Methacrylonitrile
Alkylene Oxider
Butylene oxide
ff= Salicylaldehyde
Valeraldehyde
20. Alcohols, Glycols
Rum
Sorbitol solutions
N,N-Dimethylacetamide solution
Dimethylformamide
Formamide
Octadecenoanrrde
Ethylene oxide, Propylene oxide
mtxtures
Propylene oxide
17. Epichlorohydrin
rr Acrylonitrile-Styrene copolymer
dispersion in Polyether polyol
Alcoholic beverages
Alcohol polyethoxylates
Tallow fatty alcohol
Tetradecanol
Tridecanol
Trimethylol propane polyethoxylate
Alcohol polyethoxylates, secondary Undecanol
11. Organic Anhydrider
Acetic anhydride
Chlorohydrins
Epichlorohydrin
tf:
tl
Alcohols (Cl3 and above) Undecyl alcohol
Amyl alcohol 21. Phenols, Cresols
Maleic anhydride 18. Ketones
2 Behenyl alcohol Benzyl alcohol
Phthalic anhydride Acetone
Propionic anhydride
tF Brake fluid base mixtures Carbolic oil
Acetophenone
Isocyanates Amyl methyl ketone
il Butyl alcohol 2 Creosote 2
. Butylene glycol 2 Cresols
Diphenylmethane diisocyanate Butyl heptyl ketone
Choline chloride solutions Cresylic acid
Isophorone diisocyanate
Polymethylene polyphenyl
lsocyanate
Camphor oil
Cyclohexanone
Cyclohexanone, Cyclohexanol
F Cyclohexanol
Decyl alcohol 2
Diacetone alcohol ,
2,4-Dichlorophenol
Dodecyl phenol
o-Ethylphenol
Toluene diisocyanate mixtures 2
Trimethylhexamethylene
diisocyanate (2,2,4- afi, 2,4,+\
Diisobutyl ketone
Ethyl amyl ketone
Ir
tl
Diisobutyl carbinol
2,2-Dimethylpropane- 1,3-diol
Nonyl phenol
Octyl phenol
Dodecanol Phenol
13. Vinyl Acetate Epoxy resin
tr
Dodecyl alcohol Xylenols
Vinyl acetate Ketone residue
Ethoxylated alcohols, Cl l-Cl5 22. Caprolactam Solutions
Vinyl ethyl ether Isophorone 2
2-Ethoxyethanol Caprolactam solution
Vinyl neodecanate Mesityl oxide
Ethyl alcohol 2 23 - 29. Unassigned
Vinyl toluene Methyl amyl ketone
Ethyl butanol
14. Acrylates Methyl butyl ketone II:
tl
Ethylene chlorohydrin
30. Olefins
Amylene
Butyl acrylate Methyl butyl ketone
Ethylene cyanohydrin Butadiene
Butyl methacrylate Methyl diethanolamine
Ethylene glycol 2 Butadiene, Butylene mixtures (cont.
Butyl methacrylate, Decyl Methyl ethyl ketone 2
methacrylate, Cetyl-Eicosyl
methacrylate mixture
Methyl heptyl ketone
Methyl isoamyl ketone
F 2-Ethylhexanol
Furfuryl alcohol 2
Glycerine 2
Acetylenes)
Butene
Butene oligomer
Cetyl-Eicosyl methacrylate mixture Methyl isobutyl ketone 2
Heptanol
F
Decyl acrylate Butylene
19. Aldehydes Hexanol
Dodecyl methacrylate 1,5,9-Cyclododecatriene
Acetaldehyde Hexylene glyco. 1,3-Cyclopentadienedimer
Dodecyl-Pentadecyl methacrylate Acrolein 2 3-Methoxy- l -butanol
mlxture Cyclopentadiene polymers
Butyraldehyde Methyl alcohol '
Ethyl acrylate
2-Ethylhexyl acrylate
Ethyl methacrylate
Crotonaldehyde 2
Decaldehyde
Ethylhexaldehyde
F Methyl amyl alcohol
Methyl butenol
Cyclopentadiene, Styrene, Benzene
mixture
Cyclopentene
Methylbutynol Decene
2-Ethyl-3-propylacrolein 2
F
Methyl acrylate
2-Methyl-2-hydroxy-3-butyne Dicyclopentadiene
Methyl methacrylate Formaldehyde, Methanol mixtures , Methyl isobutyl carbinol Diisobutylene
Nonyl methacrylate Formaldehyde solution 2 3-Methyl-3-methoxybutanol
Polyalkyl(Cl8 - C22) acrylate in Dipentene
Furfural Molasses
Xylene
15. Subctituted Allyls
Acrylonitrile 2
Glyoxal solutions
3-Methyl butyraldehyde
tl- Nonyl alcohol 2
Octyl alcohol 2
Pentadecanol
Dodecene
Ethylene
Ethylidene norbornene 2
l-Heptene
Allyl alcohol 2 Methylolureas
"
Allyl chloride Octyl aldehyde
F Polyalkylene oxide polyol Hexene
SCANNED _-i{
BY MKP .-&
i , a . "BARIS A. 2004
390 391
h
ti x- .- ., -:... e$L
r
Isoprene
Methyl acetylene, Propadiene
mtxture
Propane
iso-Propylcyclohexane
Tridecane
il- Calcuim sulfonate, Calcium
carbonate, Hydrocarbon solvent
mixture
No. 5
No. 6
Oil, misc:
Methylcyclopentadiene dimer
2-Methyl- l -pentene
4-Methyl- 1-pentene
alpha-Methyl styrene
Waxes:
Paraffin
32. Aromatic Hydrocarbons
Alkyl acrylate-Vinyl pyridine
r- Carbon black base
Coal tar
Coal tar pitch
Decahydronaphthalene
Absorption
Aliphatic
Aromatic
Clarified
Myrcene
Nonene
1-Octadecene
copolymer in Toluene
Alkyl(C9 - Cl7) benzenes
Benzene
{t* Diphenyl, Diphenyl ether
Distillates, flashed feed stocks
Distillates, straight run
Coal
Crude
Diesel
Octene Benzene hydrocarbon mixtures Drilling mud (low toxicity) (d Heartcut distillate
Olefin mixtures
alpha-Olehns (C6 - Cl8) mixtures
alpha-Olefins (Cl3 and above)
(having 10Vo Benzene or more)
Benzene, Toluene, Xylene mixtures
Butylbenzene
F JTammable or combustiblel
Fatty acid amides
Gas oil, cracked
Linseed
Lubricating
Mineral
1,3-Pentadiene
Pentene
Pentene, Miscellaneous hydrocarbon
mixture 2
Butyl phenol, Formaldehyde resin in
Xylene
Butyl toluene
Cumene
r Gasoline blending stock, alkylates
Gasoline blending stock, reformates
Gasolines:
Automotive (not over 4.23 grams
Mineral seal
Motor
Neatsfoot
Penetrating
Pinene
Polybutene
Polypropylene
Cymene
Decylbenzene
Dialkyl(ClO - Cl4) benzenes
rI lead per gal.)
Aviation (not over 4.86 grams
lead per gal.)
Pine
Range
Resin
Propylene Diethylbenzene Casinghead (natural) Resinous petroleum
Propylene-butylene copolymer Diisopropylbenzene
ir Polymer Rosin
Propylene dimer Diisopropyl naphthalene ll Straight run Sperm
Propylene tetramer
r-
Diphenyl Glycols, Resins, and Solvents Spindle
Propylene trimer Dodecylbenzene mixture Spray
Styrene Ethylbenzene Herbicide (Cl 5-H22-NO2-CI) Tanner's
Tetradecene Ethyl toluene Jet Fuels: Turbine
Tridecene Isopropylbenzene JP.I White (mineral)
Triisobutylene
Tripropylene
Turpentine
Methyl naphthalene
Naphthalene
l-Phenyl-l-xylyl ethane
il-- JP-3
JP4
JP.5
Residual
Road
Transformer
Undecene
31. Paraffins
Butane
Propylbenzene
Pseudocumene
Tetradecylbenzene
r
tl
JP-8
Kerosene
Magnesium nonyl phenol sulfide
Oxyalkylated alkyl phenol
formaldetryde
Petrolatum
Cycloaliphatic resins Tetrahydronaphthalene Maleic anhydride copolymer Pine oil
Cycloheptane
Cyclohexane
Cyclopentane
1,2,3,5-Tetramethylbenzene
Toluene
Tridecylbenzene
F Mineral spirits
Naphtha:
Coal tar solvent
Polyalkenyl succinic anhydride
amine
White spirit (low (15-2OVo)aromatic)
Decane
Dodecane
Ethane
Heptane
Triethylbenzene
Trimethylbenzene
Undecylbenzene
Xylene
r Cracking fraction I
Petroleum
Solvent
34. Esters
Acetyl tributyl citrate
Alkyl phthalates
r
Stoddard solvent Amyl acetate
Hexane 2 33. Miscellaneous Hydrocarbon Mixtures Varnish Makers' and Painters' Amyl tallate
Methane Alkylbenzenesulfonic acid, sodium Nonyl phenolsulhde solution Benzene tricarboxylic acid trioctyl
Methylcyclohexanc salt solutions Oil, fuel: ester
r
2-Methyl pentane Asphalt blending stocks, roofers flux No. I Benzyl acetate
Nonane Asphalt blending stocks, straight run No. l-D Butyl acetate
Octane residue No. 2 Butyl benzyl phthalate
n-Paraffins (ClO - C20) Aviation alkylates No.2-D n-Butyl butyrate
Pentane No.4 Butyl formate
393
o".u, .-!It --.,.,, SCANNED BY MKP & BARIS A. 2004
iso-Butyl isobutyrate Ethyl hexyl phthalate
Oil, misc: Waxes:
Calcium naphthenate in Mineral oil Ethyl hexyl tallat€
Coconut oil, fatty acid methyl Carnauba
Calcium nitrate, Magnesium nitrate, Ethyl propionate
ester 35. Vinyl Halides
Potassium chloride solution Ethyl propionate
Cotton seed oil, fatty acid Vinyl chloride
Coconut oil, fatty acid Fatty acids (saturated, C13 and
Palm oil, fatty acid methyl ester Vinylidene chloride
Cottonseed oil, fatty acid above)
Palm oil, methyl ester 36. Halogenated Hydrocarbonr
Cyclohexyl acetate Glycerol polyalkoxylate
Soapstock Benzyl chloride
Dialkyl(C7 - Cl3) phthalates Glyceryl triac.etate
Tall Carbon tetrachloride
Dibutyl phthalate Gylcidyl ester of tridecylacetic acid
Tall, fatty acid ' Chlorinated paraffini (C10 - Cl3)
Diethylene glycol butyl ether acetate Glycidyl ester of Versatic acid
Tung Chlorinated paraffins (C14 - Cl?)
Diethylene glycol ethyl ether acetate
acetate
Glycol diacetate
Heptyl acetate
Hexyl acetate
lt- Oleic acid
Palm kernel oil, fatty acid
Palm kernel oil, fatty acid methyl
Chlorobenzene
Lauric acid Chloroform
Diethylene glycol phthalate
Di-(2-ethylhexyl)adipate
Di-(2-ethylhexyl)phthalate
Magnesium sulfonate
3-Methoxybutyl acetate
tr-
t (
ester
Palm stearin
Polydimethylsiloxane
Chlorotoluene
Dichlorobenzene
I -Methoxy-2-propyl acetatc Dichlorodifl uoromethane
Diethyl phthalate
Polyferric sulfate solution
tr
l,l-Dichloroethane
Diethyl sulfate Methyl acetate
Polymethylsiloxane 2,2'-Dichloroisopropyl ether
Diheptyl phthalate Methyl acetoacetate
Poly(20)oxyethylene sorbitan Dichloromethane
Di-n-hexyl adipate Methyl amyl acetate
monooleate Dichloropropane
Diisobutyl phthalate Methyl butyrate
Polysiloxane Ethyl chloride
Diisodecyl phthalate Methyl formate
Potassium oleate Ethylene dibromide
Diisononyl adipate 3-Methyl-3-methoxybutyl acetate
Propyl acetate Ethylene dichloride 2
Diisononyl phthalate Methyl salicylate
Sodium acetate solution Methyl bromide
Diisooctyl phthalate Metolachlor
Sodium benzoate solution Methyl chloride
Dimethyl adipate Naphthalene sulfonic acid, sodium
Sodium dimethyl naphthalene Monochlorodifl uoromethane
Dimethylcyclicsiloxane hydrolyzate salt solution (zlo7o or less)
sulfonate solution 2 Pentachloroethane
Dimethyl glutarate Octyl decyl adipate
Sodium naphthalene sulfonate Perchloroethylene
Dimethyl hydrogen phosphite 2
Dimethyl naphthalene sulfonic acid,
sodium salt solution 2
Octyl epoxytallate
Octyl nitrate 2
Oil, edible:
t- solution
Stearic acid
Tall oil
l, 1,2,2-T etr achloroethane
1.2.4-Trichlorobenzene
I,I,1-Trichloroethane t
Dimethyl phthalate Babassu
Tallow 2 l. 1,2-Trichloroethane
Dimethyl polysiloxane
Dimethyl succinate
Dinonyl phthalate
Castor
Coconut
Corn
I Tallow fatty acid 2
Triarylphosphate
Trichloroethylene
2
Tributyl phosphate l, 1,2-Trichloro- 1,2,2-trifluoroethane

Dioctyl phthalate Cotton seed
Tricresyl phosphate
Dipropylene glycol dibenzoate
Ditridecyl phthalate
Fish'
Lard
l' Triethylene glycol di-(2-
ethylbutyrate)
37. Nitriles
Acetonitrile
Adiponitrile
2-Dodecenylsuccinic acid, Olive
Triethyl phosphate
dipotassium salt solution Palm 2 Lactonitrile solution
Triethyl phosphite 2 3-Pentenenitrile
Diundecyl phthalate Palm kernel
Triisooctyl trimellitate 2 Propionitrile
2-Ethoxyethyl acetate Peanut
2,2,4-T rimethyl pentanediol- 1,3- Tallow nitrile
Ethyl acetate Rapeseed
diisobutyrate
Ethyl acetoacetate Rice bran 38. Carbon Disulfide
2,2,4-T rimethyl- 1,3-pentanediol- I -
Ethyl butyrate Safflower Carbon disulfide
isobutyrate
Ethylene glycol acetate .Soya bean 39. Sulfolane
2,2,4-T rimethyl-3-pentanol- 1-
Ethylene glycol butyl ether acetate Sunflower Sulfolane
isobutyrate
Ethylene glycol diacetate Sunflower seed tl0. Glycol Ethers
Trimethyl phosphite 2
Ethylene glycol ethyl ether acetate Tucum Diethylene glycol
Trisodium nitrilotriacetate
Ethylene glycol methyl ether acetate Vegetable Diethylene glycol butyl ether
Trixylenyl phosphate
Ethyl-.3-ethoxypropionate Diethylene glycol dibutyl ether
Vinyl acetate-Fumarate copolymer
Diethylene glycol ethyl ether
'tjciil4j4ht
-tû;t;t *Mo' -.' "'-t- SCANNED BY MKP & BARIS A. 2004 395 rl
r
Diethylene glycol phenyl ether
Ethyl ether
Methyl-tert-butyl ether I
r Ferric hydroxyethylethylenediamioe
triacetic acid, trisodium salt
Tall oil soap (disproportionated)
solution
Dipropylene glycol
Dipropylene glycol methyl ether
Ethoxy triglycol
Methyl formal
Propyl ether
Tetrahydrofuran
r solution 2
Fish solubles (water basedJish meal
extlacts)
Tetrasodium salt of EDTA solution
Triisopropanolamine salt of 2,4-
solution
r
Ethylene glycol tert-butyl ether Nitrocompounds Fructose solution
Ethylene glycol butyl ether Dinitrotoluene Fumaric adduct of Rosin, water Urea, Ammonium nitrate solution
Ethylene glycol dibutyl ether dispersion (not containing Ammonia)
Nitrobenzene
Ethylene glycol ethyl ether N-(Hydroxyethyl)ethylene diamine Urea, Ammonium phosphate solution
o-Nitrochlorobenzene
Ethylene glycol isopropyl ether triacetic acid, trisodium salt Vegetable protein solution
t*
Nitroethane
Ethylene glycol methyl ether solution (hydrolysed)
Nitropropane
Ethylene glycol phenyl ether Nitropropane, Nitroethane mixture Kaolin clay slurry
Ethylene glycol phenyl ether, Latex, liquid synthetic
r
Nitrotoluene Footnotes to Table II
Diethylene glycol phenyl ether Lignin liquor
43. Miscellrneous Water Solutionr
. Naphthenic acid, sodium salt solution r Because of very high reactivity or un-
mixture Aluminum sulfate solution 2
Ethylene glycol propyl ether Rosin soap (disproportionated) usual conditions of carriage or potential
2-Amino-2-hydroxymethyl- 1,3-
r
Methoxy triglycol solution compatibility problems, this product is not
propanediol solution
Nonyl phenol (ethoxylated) Sewage sludge. treatec assigned to a specific group in the Com-
Ammonium bisulfite solution 2
Nonyl phenol poly(4-12)ethoxylates Sodium alkyl sulfonate solution patibility Chart. For additional compat-
Ammonium nitrate. Urea solution
Oil, misc: (not containing Ammonia) Sodium hydrogen sulfite solution ibility information, contact Commandant
Soybean (epoxidized)
Polyalkylene glycols, Polyalkylene
glycol monoalkyl ethers mixtures
Ammonium polyphosphate solution
Amrnonium sulfate solution
Ammonium thiosulfate solution
r Sodium polyacrylate solution 2
Sodium salt of Ferric
hydroxyethylethylenediamine
triacetic acid solution
(G-MTH) , U.S. Coast Guard, 2100
Second Street, SW., Washington, D.C.
20593-0001. Telephone (2O2) 267 -1577.
2 See Appendix I-Exceptions
r
Polyethylene glycols Calcium bromide solution to the
Polyethylene glycol dimethyl ether Sodium silicate solution 2 Chart.
Calcium chloride solution
Polyethylene glycol monoalkyl ether Corn syrup
Polypropylene glycol methyl ether Dextrose solution Appendix I-Exceptions to the Chart
Polypropylene glycols
n-Propoxypropanol
Propylene glycol monoalkyl ether
Propylene glycol ethyl ether
Diammonium salt of Zinc EDTA
solution
r (a). The binary combinations listed below have been tested as pre-
scribed in Appendix III and found not to be dangerously reactive.
r
Diethanolamine salt solution These combinations are exceptions to the Compatibility Chart (Figure
Propylene glycol methyl ether 2,4-Dichlorophenoxyacetic acid,
Tetraethylene glycol l) and may be stowed in adjacent tanks.
Triisopropanolamine salt solution
Triethylene glycol 2
Triethylene glycol butyl ether Didecyl dimethyl ammonium
Triethylene glycol butyl ether
mixture
Triethylene glycol ether mixture
chloride, Ethanol mixture solution
Diethanolamine salt of 2,4-
ll Member of reactive group Compatiblewith
Triethylene glycol ethyl ether
Tripropylene glycol
Tripropylene glycol methyl ether
solution
Dodecyl diphenyl ether disulfonate
solution
r Acetone (18)
Acetone cyanohydrin(0)
Diethylenetriamine
Acetic acid (4)
(7)
r
41. Ethers Drilling brine (containing Calcium,
Butyl ether Acrylonitrile('l5) Triethanolamine(8)
Potassium, or Sodium salts)
2,2'-Dichloroethyl ether Drilling brine (containing Zinc salts) 1,3-Butyleneglycol (20) Morpholine(7)
Digylcidyl ether of Bisphenol A Drilling mud (low toxictty) (if non- 1,4-Butyleneglycol (20) Ethylamine(7)
Diglycidyl ether of Bisphenol F
Dimethyl furan
1,4-Dioxane
Diphenyl ether
flammable or non-combustible)
Ethylenediaminetetracetic acid,
tetrasodium salt solution
Ethylene-Vinyl acetate copolymer
r Caustic potash, 5Oo/o
ot less (5)
Triethanolamine(8)
Ethyl alcohol (20)
Ethyleneglycol (20)
r
lsopropylalcohol (20)
Diphenyl ether, Diphenyl phenyl emulsion Methylalcohol (20)
ether mixture
iso-Octyl alcohol (20)
tr!'l SCANNED BY MKP &,;4&**.

BARIS.,.=:r',;.,,1..;-.:.
A. 2004
r
Memberof reactivegroup Compatiblewith ir (b). The binary combinations listed below have been determined to
be dangerously reactive, based on either data obtained in the literature
Causticsoda, 50% or less (5) Butylalcohol(20)
tert-Butylalcohol,Methanolmixtures
Decylalcohol(20)
rr or on laboratory testing which has been carried out in accordance with
procedures prescribed in Appendix III. These combinations are excep-
tions to the Compatibility Chart (Figure 1) and may not be stowed in
Diacetonealcohol (20)
Diethyleneglycol(40)
Ethylalcohol(20)
r adjacent tanks.
. Acetone cyanohydrin (0) is not compatible with Groups l-12, 16, 17,
r
Ethylalcohol(40%, whiskey)(20) and 22.
Ethyleneglycol(20)
Ethylene glycol, Diethylene glycol mixturo r Acrolein (19) is not compatible with Group 1, Non-Oxidizing Miner-
(20) al Acids.
Ethyl hexanol(Octylalcohol)(20)
Methylalcohol(20)
Nonylalcohol(20)
r o Acrylic acid (4) is not compatible with Group 9, Aromatic Amines.
r Alkylbenzenesulfonic acid (0) is not compatible with Groups 1-3, 5-9,
r
Propylalcohol(20)
Propyleneglycol(20) 15, 16, 18, 19,30,34, 37,and strongoxidizers.
Sodiumchlorate(0) . Allyl alcohol (15) is not compatible with Group 12, Isocyanates.
iso-Tridecanol(20)
Dodecyl and Tetradecylamine mixture (7) Tall oil, fatty acid (34)
Ethylenediamine (7) Butylalcohol(20)
tert-Butyl alcohol (20)
tr e Aluminum sulfate solution (43) is not compatible with Groups 5-ll.
e Ammonium bisulfite solution (43) is not compatible with Groups l, 3,
4, and 5.
ir
Butyleneglycol (20)
Creosote(21) o Benzenesulfonyl chloride (0) is not compatible with Groups 5-7 and
Diethyleneglycol(40)
43.
Ethylalcohol(20)
Ethyleneglycol (20)
Ethyl hexanol(20)
Glycerine(20)
ir . gamma-Butyrolactone (0) is not compatible with Groups l-9.
o Crotonaldehyde (19) is not compatible with Group l, Non-Oxidizing
lsononylalcohol(20)
lsophorone(18)
Methylbutyl'ketone (18)
Methyliso-butylketone (18)
r Mineral Acids.
o Cyclohexanone, Cyclohexanol mixture (18) is not compatible with
Group 12, Isocyanates.
Methylethyl ketone(18)
Propylalcohol(20)
Propyleneglycol (20)
il- r 2,4-Dichlorophenoxyacetic acid, Dimethylamine
not compatible with Groups l-5, ll, 12, and 16.
salt solution (0) is
Oleum(0) Hexane(31)
Dichloromethane
Perchloroethylene
(36)
(36)
r . 2,4-Dichlorophenoxyacetic acid, Triisopropanolamine salt solution
(43) is not compatible with Group 3, Nitric Acid.
1,2-Propylene glycot(20) Diethylenetriamine (7)
Polyethylenepolyamines(7)
Triethylenetetramine (7) r o Dimethyl
and 4.
hydrogen phosphite (3a) is not compatible with Groups I
o Dimethyl naphthalene sulfonic acid, sodium salt solution (34) is not
r
Sulfuricacid (2) coconut oil (34)
Coconutoil acid (34) compatible with Group 12, Formaldehyde, and strong oxidizing
Palm oil (34) agents.
Tallow (34)
Sulfuricacid, 98% or less (2) Choice white grease tallow (34)
r o Dodecylbenzenesulfonic acid (0) is not compatible with oxidizing
a g e n t sa n d G r o u p s 1 , 2 , 3 , 5 , 6 , 7 , 8 , 9 , 1 5 , 1 6 , 1 8 , 1 9 , 30,34, and 37.
391 SCANNED BY MKP;;'^'s'*,

& BARIS A. 2004 .,_ .!,,,_,,,
r
Ethyl chlorothioformate (0) is not compatible with Groups 5, 6, 7, 8,
and 9.
r . Sodium chlorate solution (5OVo or less) (0) is not compatible with
G r o u p s l - 3 , 5 , 7 , 8 , 1 0 , 1 2 , 1 3 , 1 7 ,a n d 2 0 .
a Ethylenediamine (7) is not compatible with Ethylene dichloride (36).
Ethylene dichloride (36) is not compatible with Ethylenediamine (7).

r r Sodium dichromate solution (7OVoor less) (0) is not compatible with
G r o u p s l - 3 , 5 , 7 , 8 , 1 0 , 1 2 , 1 3 , 1 7 ,a n d 2 0 .
r
a
. Sodium dimethyl naphthalene sulfonate solution (3a) is not compati-
a Ethylidene norbornene (30) is not compatible with Groups l-3 and 5- ble with Group 12, Formaldehyde and strong oxidizing agents.
8.
. Sodium hydrogen sulfide, Sodium carbonate solution (0) is not com-
2-Ethyl-3-propylacrolein (19) is not compatible with Group l, Non-
Oxidizing Mineral Acids. t- patible with Groups 6 (Ammonia) and 7 (Aliphatic amines).
r Sodium hydrosulfide (5) is not compatible with Groups 6 (Ammonia)
o Ferric hydroxyethylethylenediamine triacetic acid, Sodium salt solu-
tion (43) is not compatible with Group 3, Nitric acid.
. Fish oil (34) is not compatible with Sulfuric acid (2).
r and 7 (Aliphatic amines).
. Sodium hydrosulfide, Ammonium sulfide solution (5) is not compati-
r Formaldehyde (over 5O7o)in Methyl alcohol (over 3OVo)(19) is not

compatible with Group 12, Isocyanates.
r: ble with Groups 6 (Ammonia) and 7 (Aliphatic amines).
. Sodium polyacrylate solution (a3) is not compatible with Group 3,
Nitric Acid.
e Formic acid (4) is not compatible with Furfural alcohol (20).
o Furfuryl alcohol (20) is not compatible with Group 1, Non-Oxidizing

r r Sodium salt of Ferric hydroxyethylethylenediamine triacetic acid so-
lution (43) is not compatible with Group 3, Nitric acid.
Mineral Acids and Formic acid (4).
o 2-Hydroxyethyl acrylate is not compatible with Groups 2, 3, 5-8, and r r Sodium silicate solution (a3) is not compatible with Group 3, Nitric
Acid.
r Sodium sulfide, hydrosulfide solution (0) is not compatible with
r
12.
r Isophorone (18) is not compatible with Group 8, Alkanolamines. Groups 6 (Ammonia) and 7 (Aliphatic amines).
o Sodium thiocyanate (56Vo or less) (0) is not compatible with Groups
. Magnesium chloride solution (0) is not compatible with Groups 2, 3,
t-4.
5, 6, and 12.
. Sulfuric acid (2) is not compatible with Fish oil (34), or Oleum (0).
. Mesityl oxide (18) is not compatible with Group 8, Alkanolamines.
o Methyl tert-butyl ether (41) is not compatible with Group 1, Non-

oxidizing Mineral Acids.
r o Tallow fatty acid (34) is not aompatible with Group 5, Caustics.
r l,l,l-Trichloroethane (36) is not compatible with Oleum (0).
o Naphtha, cracking fraction (33) is not compatible with strong acids,
causticsor oxidizing agents. r o Trichloroethylene (36) is not compatible with Group 5, Caustics.
o Triethyl phosphite (3a) is not compatible with Groups I and 4.
r
o o-Nitrophenol (0) is not compatible with Groups 2,3, and 5-lO. e Trimethyl phosphite (3a) is not compatible with Groups I and 4.
. Octyl nitrates (all isomers) (3a) is not compatible with Group 1, Non-
Appendix ll-Explanation of Figure I
oxidizing Mineral Acids.
o Oleum (0) is not compatible with Sulfuric acid (2) and 1,1,1-Trichlor-
oethane (36).
r DeJinition of a hazardous reaction-As a first approximation, a mix-
ture of two cargoes is considered hazardous when, under specified con-
dition, the temperature rise of the mixture exceeds 25'C or a gas is
. Pentene, Miscellaneous hydrocarbon mixtures (30) are not compatible
with strong acids or oxidizing agents. r evolved. It is possible for the reaction of two cargoes to produce a
product that is significantly more flammable or toxic than the original
a(p SCANNED BY MKP & BARIS A. 2004

r
cargoes even though the reaction is non-hazardous from temperature or
pressure considerations, although no examples of such a reaction are
F (b)'X"-The two cargoes are not compatible.
(Note that reactivity may vary among the group members. Refer
known at this time.
Chart format-There are different degrees of reactivity among the

F to Table I or Table II to frnd whether the products in question are ref-
erenced by a footnote which indicates that exceptions exist and are
various cargoes. Many of them are relatively non-reactive: For exam- listed in Appendix I. Unless the combination is specifically mentioned in
ple, aromatic hydrocarbons or paraffins. Others will form hazardous
combinations with many groups: For example, the inorganic acids.
F Appendix I, it is compatible.)
Examples
The cargo groups in the compatibility chart are separated into two I r--
categories: I through 22 are "Reactive Groups" and 30 through 43 are lt Combination Compatible
"Cargo
Groups". Left unassignedand available for future expansion are
groups 23 through 29 and those past 43. Reactive Groups contain prod. r: Butyraldehyde/AceticAcid 19/4 Yes
ucts which are chemically the most reactive; dangerous combinations ll Allyl Alcohol/Toluene Diisocyanate
Decene/EthylBenzene
1 5 /1 2
30/32
No
Yes
may result between members of different Reactive Groups and between Ethanolamine/Acetone 8/18 Yes
members of Reactive Groups and Cargo Groups. Products assignedto
Cargo Groups, however, are much less reactive; dangerous combina-
tions involving these can be formed only with members of certain Re-
F Ammonia/Dimethylf ormamide 6/10 No
Appendix Ill-Testing Procedures for Determining Exceptions to the

active Groups. Cargo Groups do not react hazardously with one an-
other. F Chart
Experimental Procedurefor Evaluating Binory Chemical Reactivity

1
Using the Compatibility Chart-The following procedure explainc

how the compatibility chart should be used to find compatibility info-
mation:
tr General safety precautions-Chemical reactivity tests have, by their
nature, serious potential for injuring the experimenter or destroying
tr
equipment. The experimenter should 1) have knowledge of the magni-
(l) Determine the group numbers of the two cargoes by referring
tude of the reactivity to be expected, 2) use adequate facilities and pro-
to the alphabetical listing of cargoes and the corresponding groups
tective equipment to prevent injury from splatter of materials or release
(Table I). Many cargoes are listed under their parent names; unless oth-'
of fumes, and 3) start on a small scale so that unexpected reactions can
erwise indicated, isomers or mixtures of isomers of a particular cargo
are assignedto the same group. For example, to frnd the group number
for Isobutyl Alcohol, look under the parent name Butyl Alcohol. Simi-
tr be safely contained. All tests should be performed in a well-ventilated
laboratory hood provided with shields.
larly, the group number for para-Xylene is found under the entry
Xylene. If a cargo cannot be found in this listing, contact the Coast
Guard for a group determination (see $ 150.140).
tr Testing chemicals other than liquids-The procedure outlined below
was developed for chemicals which are liquids at ambient temperatures.
If one or both chemicals are normally shipped at elevated temperatures,
(2) If both group numbers are between 30 and 43 inclusive, the
products are compatible and the chart need not be used.
tr the same procedure may be followed except the chemicals are tested at
their respective shipping temperatures and the oil bath in Step 3 is
maintained at a level 25'C above the higher temperature. This informa-
(3) If both group numbers do not fall between 30 and 43 inclusive,
locate one of the numbers on the left of the chart (Cargo Groups) and
the other across the top (Reactive Groups). (Note that if a group
tr tion is then indicated on the data sheet. If one of the chemicals is a gas
at ambient temperatures, consult the Coast Guard for additional instruc-
tions before proceeding with the compatibility test.
number is between 30 and 43, it can only be found on the left side of
the chart.) The box formed by the intersection of the column and row
containing the two numbers will contain one of the following:
F Step I
Objective-To determine if the test chemicals react violently and

(a) Blank-The two cargoes are compatible. F present a safety hazard in further tests.
SCANNED BY MKP--d!;rg&-^.
& BARIS . A. 2004 403
Procedure-Place 0.5 ml of one (A) of the test chemicals in a ri proceed to Step 3. If the observed temperature rise exceeds 25"C or
gasesare evolved, do not proceed to Step 3.
25x150mm test tube. Clamp the test tube to a stand behind a safety
shield (in a hood). Carefully add from a dropper 0.5 ml of the other
substance(B). Shake to induce mixing. If no immediate reaction occurs,
retain the mixture for at least l0 minutes to check for a delaved reac-
r Step 3
Objective-To determine if exothermic reactions occur at tempera-
tion.
Results-If a violent reaction occurs, such as sputtering, boiling of l- tures up to 50'C
Procedure-If a non-hazardous reaction occurred in Step 2, the
ratio of chemicals which resulted in the greatest temperature rise will
reactants or release of fumes, record the results on the Data Sheet (Ap-
pendix IV) and do not proceed to Step 2. If no reaction or a minor
reaction occurs, proceed to Step 2. I be tested. Fresh chemicals will be used with a total volume for this test
of about 10ml (a ratio of I ml:9m1, 5ml: 5ml, or 9ml : I ml). If no
reaction was bbserved in Step 2, use a ratio of 5 ml : 5 ml. Using the
Step 2
Objective-To determine the heat of reaction of two chemicals on

t- thermocouple prepared for Step 2, insert the reference probe into a
25X 150 mm test tube containing l0 ml of water. Place the other probe
into an empty test tube. Start the temperature recorder and add the two
mixing under specified conditions.
Procedure-These separate mixes of the proposed binary combina-
tion will be tested. These are 2 ml : 18 ml, 10 ml : l0 ml, and
t- chemicals of the combination, one at a time, to the empty test tube.
Lower the two test tubes into an oil bath maintained at 50-r2'C. Hold
the samples in the oil bath until the maximum temperature differential is
18 ml : 2 ml, respectively, to result in a flrnal mixture of about 20 ml in
recorded, and in all cases at least 15 minutes. Observe the test mixture
each case. to determine if gases are evolved or if other visible changes occur.
A reference-junctioned thermocouple is prepared by inserting two Follow prescribed safety precautions.
lengths of 20 gauge or finer iron-constantan or chromelalumel duplex
thermocouple wire into glass capilary sheaths. The common wire of
each probe is joined, while the other wire of each is connected to a
r Results-Record the maximum differential temperature measured,
the time required to reach this temperature, and any other observations
in the proper space on the Data Sheet.
strip-chart recorder. The thermocouple probe which produces a nega-
tive pen deflection upon warming is the reference junction and is Send a copy of the Data Sheet for each binary chemical mixture
placed in a test tube of water at ambient laboratory temprature. The tested to: Commandant (G-MTH), U.S. Coast Guard, Washington, DC
other probe is placed near the bottom of a Dewar flask of about 300 ml
capacity, such that the thermocouple will be below the surface of thc
test mixture. The Dewar flask is equipped with a magnetic stirref
r 20593-0001.
having a stirring bar coated with an inert material such as a flourinated

hydrocarbon.
Start the temperature recorder and stirrer. Deliver the test chemi-
t-
cals to the Dewar Flask simultaneously from separate graduated sy-
ringes. If an exothermic reaction occurs, continue the test until the
maximum temperature is reached and begins to subside. If no apparent
r
reaction occurs, continue the test for at least 30 minutes to check for a
delayed reaction. Stop agitation and observe the mixture at frve-minute
intervals to determine if the mixture is miscible, if gasesare evolved, or
r
if other visible changes occur. In the interest of safety, a mirror can be
used for these observations. Repeat the above,test for the other mixture
combinations.
r
Results-Record the results in the appropriate places on the Data
Sheet. If no reaction occurs or if the temperature rise is less than 25'C, t-
.:,1L.', SCANNED
,i;- BY
.giL MKP & BARIS A. 2004
Step Numbsr 3
Appendix IV-Data Sheet
CHEMICAL REACTIVIW TEST DATA r A/B Ratio:
Oil Bath Temp€raturo
Chemi€ls:
Synonyms:
r MaximumA T
Time to reach Max. Tonp.
Gases evolved?
Formuh:
F Other Observations
Descriptionof Producls: A B Date ol Test:

Manulacturor
Samplo Sourco
F Submitting Organization:
Tsst Data Approved By:
Composition (by woight %) BTLLTNG

CODE4910-14-€
Inhibitorsor Slabilizers
Deviationsfrom Prescrib€dMethod
(ircluding sp€cial equipmsnt) [[-'
Ir-
il
St€pNumber1
Products
miscibl6? Gases evolved? lf--
Olher Obseflalions:
tr
St€p Numb€r 2
r
A/B Ralio:
Initial Tomporatur€
Mdimum A T
2t18 1Cyl0 18r2
r
Time to reach Max. Temp.
Producls miscible?
F
Gases evolv€d?
Olher Obseruations '
Size ol Dowar Flask (inside measwement) Wiitth - mm Height - mm

Ir
l1:
407
SCANNED BY MKP &Hfu.,
BARIS A. 2004
406
r
APPENDIX B
r APPENDIX B
r
MEDICAL KIT INFORMATION CARCINOGENS
Cyanide-like cargoes
The following is a list of carcinogens, either known or suspected, for
The kit described below should be readily available for use by a doctor
or other person specially trained in it use when the following cargoes
r which data are given in this Guide:
Acetaldehyde Dioctyl phthalate

handled: r- Acrylamide Epichlorohydrin
Acetone cyanohydrin ll Acrylonitrile Ethyl acrylate

Ethylene dibromide
r-
Acetonitrile Allyl chloride
Acrylonitrile Aniline Ethylene dichloride
Adiponitrile Ethylene oxide
Benzene
r
Ethylene cyanohydrin Ethyl methacrylate (a teratogen)
Benzene, Toluene, Xylene
Methacrylonitrile
Formaldehyde
Propionitrile mixtures
Methyl bromide
Toluene diisocvanate Benzyl chloride
Medical Kit r
ll
ButaCiene
Methyl chloride
2-Nitropropane
Carbon tetrachloride
l2 pearls of amyl nitrite Perchloroethylene
I sterile syringe, 10 cc.
I sterile syringe, 50 cc. ll_- crude Chlorohydrins*
beta-Propiolactone
Propylene oxide
2 ampules of sodium nitrite (10 cc., 37o solution) Chloroform
Styrene
2 ampules of sodium thiosulfate (50 cc., 25Vo solution)
Inhalation - DO NOT DELAY!
il* Coal tar
Coal tar naphtha
l, 1,2,2-Tetr achloroethane
l. 1.2-Trichloroethane
Break an amyl nitrite pearl in a cloth and hold -it lightly under the
nose of the victim (but away from the person giving first aid) for about
15 seconds.Repeat five times at about l5 second intervals.
r Cresols
Crotonaldehyde
2.4-Toluenediamine
r
1,4-Dioxane Trichloroethylene
Follow further instructions found with the kit. Dichloromethane Vinyl chloride
1,3-Dichloropropene Vinvlidene chloride
|r * By analogy to epichlorohydrin.
r This list has been compiled from those published by the Interna-
tional Agency for Research on Cancer (IARC) Supplement 7, the Na-
tional Toxicology Program (NTP) Fifth Annual Report on Carcinogens,
r 1989, and the American Conference of Governmental Industrial Hy-

gienists (ACGIH) Threshold Limit Values for Chemical Substances and
PhysicolAgents in the Work Environment, 1989-1990.
r
,t.,, SCANNED BY MKP & BARIS A. 2004
r
APPENDIX C
MARPOL 73178
r- APPENDIX C
LIST OF OILS I.
():
II
Asphalt solutions
Blending Stocks
Roofers Flux
Gas Oil
Cracked
Gasoline Blending Stocks
r o
9
2
i -
i
3
6
6
9
S
S
t*
! 9 =
Straight Run Residue Alkylates - fuel U - t r
Oils Reformates - - i B F
t e
Clarified Polymer -fuel + l e r
Crude Oil
Mixtures containing crude oil
Gasolines
Casinghead (natural)
I O
s! .
o
e
:
K
R
X
e
t-
L :
Diesel Oil Automotive . 9 u R S
Fuel Oil No.4 Aviation t
L
= -
U
:
d
i l
I
;
Fuel Oil No.5 Straight Run S : € =

Fuel Oil No.6
Residual Fuel Oil
Fuel Oil No.I (Kerosene)
Fuel Oil No.l-D
i- ?
!
E
c
:
U
9
: a
d
{
{
9 +
Road Oil Fuel Oil No.2 t o : 3
Transformer Oil
Aromatic Oil (excluding
vegetable oil)
Lubricating Oils and Blending
Fuel Oil No.2-D
Jet Fuels
JP-l (Kerosene)
JP_3
r
E
-
*
d
E
9
.
e
6
:
s
a
=
6
h
S
8
II
Stocks JP-4 F . : e 3
Mineral Oil
Motor Oil
JP-5 (Kerosene, Heavy) I 9 - 9 s
r
Turbo Fuel -Y
l r o g ?
Penetrating Oil Kerosene e
Spindle Oil Mineral Spirit t r , - . $ $

5 I
Turbine Oil
Distillates
Straight Run
Naphtha
Solvent
Petroleum
r c 5 , i 6 S
-
:
.
N
;
6
f
Flashed Feed Stocks Heartcut Distillate Oil
r 9 F
, . P
r ? - B z -
J a
x 6 !
< F 8 s n 6 s
E Z E I
F
:
:
v
d E : E - a
ze xn *E aE 'X qS f4
r
v c o
* The list of oils shall not necessarily be considered as comprehensive. : 6
! ! o z q i
q g , : ,= e =
, e =
. i d
q ti E ?
F F: =
410
2 3 E 5 5 6 = € i ; 5 : F
4lt
J&*irai'*:,,'-
r
APPENDIX D r APPENDIX D
CONVERSION FACTORS
MetricUnitsUsed In Part153
r CONVERSION FACTORS
MiscellaneousConversionFactors
Parameter Metric(Sl unit)

Abbrevia-
tion
Equivalentto English
or common metric r Given this,
atmosphere (atm)
multiply by this,
760
to get this.
mm Hg (at 0'C)
Nawlnn
ir6t6r
N 0.225 lbs.
39.37in.
t'-
I
29.92 in. Hg (at 0'C)
33.899 ft Hro (at 4'c)
Cenlimeler .3937in.
1.0333 kg/cmz
r
.l0 '4 lbs/in2.
Pressure Pacnal Pa 1.450x
Kilo-Pascal(1,000Pascals) VDa 0. 145 lbs/in2. 14.69 lb/in.z
Kilo-Pasnal kPa 1.02x 10.2kglcm2. 1.0r33 bar
1 x 1 0 3N / m 2 . 101.3 kPa
r
kPa
T a:6lcir rc 5/s ('F-32).
milli-Pascal mPa.sec..... 1.0 centipoise.
second.............-..... bar 0.987 atm
Cr rhin malor . . . gallons(gal).
m 3 . . . . . . . . . . . . 264
750 mm Hg (at 0"C)
..RULE OF THUMB'
do.................. m 3 . . . . . . , . . . . . 35.3
. , . ft3.
r 14.5
100
lb/in.2
kPa
barrel (U.S. liq.) (bbl)

Specific gravity of water:
fresh: 1.00
l: 26.229
31.5
t19.237
gal (Brit)
sal(u.s.)
I
VISCOSITY
salt : 1.025 (approx.)
r barrel, petroleum
4.2109
42
ft3
sal(u.s.)
Centistokes X density (grams per ml.) : centipoises
Kinematic viscosity X density : absolute viscosity r foot, HzO (at 4"C) 0.0295
0.883
atm
in. Hg (at 0'C)
DENSITY
Pound per gal. (U.S.) at 2O"C: specificgravity at 20/20"C X 8.32162

r 2.2419
0.4335
304.79
cm Hg (at 0"C)
lb/in.2
kg/m2
Pound per gal. (U.S.) : 0.119 826 grams per ml. !
r foot3 0.02832
28.3t6
m3
I
r 7.4805
6.2288
gal (u.s.)
gal (Brit)
r gallon, U.S. (gal) 0.8327

128
8
gal (Brit)
oz (U.S. liq.)
pt (U.S. liq.)
r 4 qt (U.S. liq.)
4t2 SCANNED BY MKP & BARIS A. 2004

-4*
4lt .
' ,ii,: '
r
APPENDIX D
CONVERSION FACTORS
r APPENDIX D
CONVERSION FACTORS
Given this. multiply by this, to get this. r Given this, multiply by this, to get this.
gallon, U.S. cont. 3.785

0.1337
I
ftg
r liter cont. 0.001
o.2642
m3
sal(u.s.)
r 0.21998
8.328 lb fresh HzO (fresh gal (Brit)
water at 60"F) 1.0567 qt (U.S. liq.)
8.336 lb fresh HzO (fresh 0.8799 qt (Brit liq.)
0.0317
0.0238
water at 4'C)
bbl (U.S. liq.)
bbl (petroleum)
r liters,/min (l,zmin) 0.035316
o.264179
ft3 /min
gal (U.S.),zmin
gallon, British t.2009

4.546
160
sal(u.s.)
I
oz (Brit liq.)
r meters (m3) 35.315
264.172
219.969
ft3
gal (U.S.)
gal (Brit)'
0.16054
l0
ft3
lb HrO (at 60'F)
t- 1000 I
r
millimeter Hg 0.001316 atm
gallon,/minute (U.S.) 8.0208 fts /hr (at 0"C) 0.001333 bar
0.06309 l/sec 1.3595 g/cm2
r
0.0193 lb/in.2
gram (g) 0.001 kg I torr
0.0353 oz (avoir.)
0.oo22 lb ounce 28.35 g
gramAiter (g/l) I 000 ppm I (avoirdupois)(oz)
ounce (U.S. liq.) 29.5737
r
0.008345 lbleal (U.S.) cc
o.0624 lb/ft3 0.0296 I
0.032 qt
0.07356
r
kilogram,/meter2 mm Hg (at 0'C)
(kg/m2) 0.00142 lb/in.2 ounce (Brit liq.) 28.413 cc
0.000097 atm
pint (U.S. liq.) 473.176
r
0.20482 lb/ftz cc
o.473163 I
kilogram,/meter3 0.06243 lb/ftg 0.5 qt
r
(kglms)
pound (lb) 4s3.s924 o
kilopascal (kPa) 0.t4503774 lb/in.2 0.45359 kg

l6 oz (avdp)
liter (l) 0.035 ftg
r
,.'.J:.
4t4
r,
APPENDIX D r APPENDIX E
Given this,
CONVERSION FACTORS
rnultiply by this, to get this. r TEMPERATURE CONVERSION TABLE
('c x e/i l-32 : "F ("F - 32) x 5/s: "C
pound,/in.2 (lb,zin.2) 51. 7 1 5

703.O7
mm Hg (at 0'C)
kg/m2
r To convert To convert To convert
0.068046
0.06895
70.307
atm
bar
g/cmz
r To'F
-40.0
-38.2
-40
-39
-40.0
-39.4
26.6
28.4
-3
a
-19.4
- 18.9
93.2
95.0
34
35
To'C
'l.l
1.7
pound,/foot3 (lb,/ft3)
6.894757
0.01602
kPa
g/cc
t- -36.4
-34.6
-38
-37
-38.9
-38.3
30.2
32.0
-l
0
- 18.3
-17.8
96.8
98.6
36
31
2.2
2.8
r
-32.8 -36 -37.8 33.8 I -17.2 100.4 38 J.J
16.018 kg/mg
- 31 . 0 -35 -to./
-5t-z 35.6 2 1o2.2 39 3.9
-29.2 -34 -JO. / 37.4 3 -16.1 104.0 40 4.4
quart (liquid) 946.353 cc -27.4 -33 -36.1 39.2 4 -15.6 105.8 4l 5.0
o.94633
o.25
I
sal(u.s.) r -25.6
-23.8
-22.0
-20.2
-32
-31
-30
-29
-35.6
-35.0
-34.4
-33.9
41.0
42.8
44.6
)
6
-15.0
-t4.4
- 13.9
- 13.3
107.6
109.4
lll.2
42
+J
44
5.6
6.1
6.7
ton (short) 907.1847 kg 46.4 8 I13.0 45 7.2
2000
0.89286
lb (avdp)
ton (long)
1- -18.4
- 16.6
-28
-)1
-JJ..t
-32.8
48.2
50.0
9
l0
-12.8
-12.2
I14.8
116.6
46
47
7.8
8.3
ton (long)
0.9072
tot6.o47
tonne (metric)
kg
r -14.8
-13.0
-11.2
-9.4
-26
-)\
-24
-23
-32.2
-31.7
- 3 1 I.
-30.6
51.8
53.6
55.4
ll
t2
t3
-tt.7
-ll.l
-10.6
-10.0
I18.4
120.2
122.0
48
49
50
8.9
9.4
10.0
r
57.2 t4 123.8 5t 10.6
2240 lb (avdp) -7.6 -)', -30.0 -9.4 ll.l
59.0 l5 125.6 52
t.l2 ton (short) -5.8 -21 -29.4 -8.9 53 tt.7
60.8 l6 127.4
1.01605 ton (metric) -4.0 -20 -28.9 62.6 t7 -8.3 129.2 54 12.2
tonne (metric) 1000

2204.62
kg
lb (avdp)
r 1 1
-o.4
1.4
-19
-18
-17
-28.3
-27.8
-)1 )
64.4
66.2
68.0
l8
t9
20
-7.8
1 -
-6.7
l 31 . 0
132.8
134.6
))
56
57
12.8
13.3
13.9
l.Lo23
0.98421
ton (short)
ton (long) r J.Z
5.0
6.8
-16
-15
-14
-26.7
-26.1
-25.6
69.8
71.6
73.4
2l
22
ZJ
-6. I
-5.6
-5.0
136.4
138.2
140.0
58
59
60
14.4
15.0
15.6
r 8.6 -13 -25.0 75.2 1A -4.4 141.8 6l l6.l

torr 0.001316 atm
10.4 -12 -24.4 77.0 25 -3.9 r43.6 62 t6.7
1.0 mm Hg (at 0"C)
-l I -23.9 -3.3
12.2 78.8 26 145.4 63 t7.2
14.0 -10 -23.3 80.6 27 -2.8 147.2 64 17.8
r 15.8
17.6
19.4
-9
-8
-6
1
-22.8
a1 a
-21.7
-21.1
82.4
84.2
86.0
28
29
30
-,, )
-t.7
-1.1
-0.6
149.0
150.8
t52.6
65
66
67
18.3
18.9
19.4
20.0
2l.2 3l 68
t_
87.8 t54.4
23.O -5 -20.6 89.6 32 0.0 156.2 69 20.6
24.8 -4 -20.0 9t.4 JJ 0.6 158.0 70 2t.l
'll5
ji''
417
ir-
APPENDIX E r APPENDIX E
TEMPERATURE CONVERSION TABLE
(C
TEMPERATURE CONVERSION TABLE
/5)*32:
'F ("F-32)X5/s:"C
t* (Cxs/) * 32:'F ( ' F - 3 2 )X 5 / s : " C
To convert To convert To convert F To convert To convert To convert
r-
To'F To'C To'F
159.8 7l 21.7 226.4 108 42.2 293.O 145 62.8 359.6 182 83.3 410.0 2to 98.9 460.4 238 114.4
462.2 239 115.0
r
161.6 72 22.2 228.2 109 42.8 294.8 t46 63.3 351.4 183 83.9 4l1.8 2tl 99.4
163.4 73 22.8 230.0 ll0 43.3 296.6 147 63.9 363.2 184 84.4 413.6 2t2 100.0 464.0 2Q I 15.6
165.2 74 23.3 2 31 . 8 lu 43.9 298.4 148 64.4 365.0 185 85.0 415.4 2t3 100.6 465.8 241 I 16.1
167.0 75 23.9 233.6 tt2 44.4 300.2 149 65.0 366.8 186 85.6 417.2 214 1 0 1I . 467.6 242 116.7
168.8
170.6
172.4
76
77
78
24.4
25.0
25.6
235.4
237.2
239.0
113
il4
It5
45.0
45.6
46.1
302.0
303.8
305.6
150
l5l
t52
65.6
66.1
66.7
r 368.6
370.4
372.2
187
188
189
86.I
86.7
87.2
419.0
420.8
422.6
2t5
216
2t7
101.7
102.2
102.8
469.4
411.2
473.0
243
244
245
tt7.2
17.8
18.3
174.2
176.0
177.8
179.6
79
80
8t
82
26.1
26.7
27.2
27.8
240.8
242.6
244.4
246.2
l16
tl7
ll8
l19
46.7
47.2
47.8
48.3
307.4
309.2
311.0
3t2.8
153
154
155
156
67.2
67.8
68.3
68.9
n 374.0
375.8
377.6
379.4
190
l9l
192
193
87.8
88.3
88.9
89.4
424.4
426.2
428.O
429.8
218
219
220
221
103.3
103.9
1o4.4
105.0
474.8
476.6
478.4
480.2
246
247
248
249
t8.9
t9.4
120.0
t20.6
482.0 250 tzt.l
181.4
183.2
83
84
28.3
28.9
248.0
249.8
120
121
48.9
49.4
314.6
316.4
t57
158
69.4
70.0 li*! 38t.2
383.0
194
r95
90.0
90.6
431.6
433.4
222
223
105.6
106.I
483.8
485.6
251
252
tzr.7
122.2
r
185.0 85 29.4 251.6 122 50.0 318.2 159 70.6 38 4 . 8 196 9l.l 435.2 224 106.7
186.8 86 30.0 253.4 123 50.6 320.0 160 7t . r 487.4 253 t22.8
386.6 197 91.7 437.0 225 1o7.2 489.2 254 123.3
188.6 87 30.6 255.2 124 51.1 321.8 l6l 71.7 388.4 198 92.2 4 38 . 8 226 107.8
190.4 88 3 1I. 257.0 125 51.7 323.6 162 72.2 491.O 255 123.9
r
390.2 199 92.8 440.6 227 108.3 492.8 256 124.4
192.2 89 3t.7 258.8 t26 52.2 32s.4 163 72.8 392.O 200 93.3 442.4 228 108.9
194.0 90 260.6 127 52.8 327.2 164 494.6 257 125.O
12.2 /J.J
393.8 201 93.9 444.2 229 109.4
195.8 91 32.8 262.4 128 53.3 329.O 165 73.9 496.4 258 t25.6
395.6 202 94.4 446.0 230 I10.0
r
197.6 92 264.2 330.8 166 74.4 498.2 259 t26.1
JJ.J t29 53.9
397.4 203 95.0 447.8 231 110.6 500.0 260 126.7
r99.4 93 33.9 266.0 130 54.4 332.6 t67 75.0
399.2 204 95.6 449.6 232 lll.l 501.8 261 127.2
201.2 94 34.4 267.8 l3t 55.0 334.4 168 75.6
401.0 205 96.1 45t.4 233 ttl.7 503.6 262 127.8
r
203.0 95 35.0 269.6 132 55.6 336.2 169 76.1
402.8 206 96.7 453.2 234 t12.2 505.4 263 128.3
204.8 96 35.6 2'n.4 133 56.l 338.0 170 76.7
404.6 207 97.2 455.0 235 112.8 507.2 264 128.9
206.6 97 36.l 273.2 134 56.7 339.8 t7l 77.2
406.4 208 97.8 456.8 236 113.3 509.0 265 t29.4
208.4 98 36.7 275.O 135 57.2 341.6 t72 77.8
2t0.2
212.0
213.8
99
100
l0l
37.2
37.8
38.3
276.8
278.6
280.4
136
t37
r38
57.8
58.3
58.9
343.4
345.2
347.0
173
174
175
78.3
78.9
79.4
r 408.2 zo9 98.3 458.6 237 I13.9
215.6
217.4
219.2
t02
103
104
38.9
39.4
40.0
282.2
284.O
285.8
139
t40
l4l
59.4
60.0
60.6
348.8
350.6
352.4
176
177
178
80.0
80.6
8 1 t.
r
221.O
222.8
224.6
105
106
107
40.6
4l.l
41.7
287.6
289.4
29t.2
t42
t43
144
6 1 l.
6t.7
62.2
354.2
356.0
357.8
179
180
l8l
81.7
82.2
82.8 r
4t8 SCANNED BY MKP & BARIS A. 2004

Chemical Data Guide For Bulk Shipment by Water

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SCANNED BY MKP & BARIS A.

rl COMI'IANDANT INSTRUCTION M16616. 6A

PURPOSE. This manual has

2. DIRECTIVES AFFECTED. The Chemical Data cuide for Bulk

rw Securlty and Envlronmental Protectlon

For d. by th. 8uFrinbnd6s! ol freumGtrb, U.8. Oovcmncnt Printi{ Ofiaa

SCANNED BY MKP & BARIS A. 2004

The U.S. Coast Guard is vitally concerned with safety at sea. In

t* The number and variety of unconventional liquid cargoes being

r and foam incompatibility in addition to other hazards such as toxicity

f i of these concerns was this Chemical Data Guide.

This manual was prepared by the Marine Technical and Hazardous

A standard form is used for each product to permit rapid reference

ty is greater than 1, the product will sink, and if the specific

Grade A Flammable liquid with a Reid vapor pressure of 14

2 Chemicals that cause smarting of the skin and first-degree burns

Stability: ' '

MANUAL 2 COMDTINST M16465.12A HAZARDOUS CHEMICAI t-l

NOTE: Coast Guard offices can obtain CHRIS manuals at no cos

f--r U.S. Coast Guard Headquarters, Washington, D.C. 20593.

n Continential U.S. (In Washington, D.C. area call (202) 426-

ri Continuously manned Communications Center.

Access to environmental and safety information on chemicals.

n Contact points with other Government Agencies for access to

Fornula-Simolitied structural lormula

FIRE & EXPLOSION HAZARD DATA

ExposurePreedures-First aid measures to be taken immediately.THIS DOES NOT REPLACEMEDICAL

Comprtibility-Msterial: In general,the substanceswith which the product could react dangerously.This

SPILL OR LEAK PROCEDURE

If a spill mcurs, call the National ResDons C€nter, E00-424-8t02.

Heilth H.ed Rraings

of skin in contacl with liquid. lrilation of eyes and respiratorysystam.

victim to fresh air; if breathing stops, apply artificial respiration.Skin or

Crrgo: Group 4 ot compaiibilitychart. S€€ also Appendix l.Exceptionsto the Chart.

SPILL OR LEAX PROCEDURE

B o l f l n g P o i n t . . . . . . . . . . . - - . . . , - . . .5. 7. .' .C. ' 1 3 4 " F

c'hcmlql Fmlly-Add anhydrid€

Vrtor Prsure 20"C (5S'F) (nnHS)..........

Reid Vapor Pressure(pdr).........

H6lth Hr8d RatirS.

Gcrenl-Vapor extrsmev iritating. Liquidcauses *vere bums.

Short EtDosureTolerucFLes than 40 ppm lor 5 minutes.

victim to tresh air; il breathing stops, apply artificialrespiration.Skin ol

REACTIVITY DATA REACTIVITY DATA

SPILL OR LEAK PROCEDURE

SCANNED BY MKP & BARIS A. 2004

F l s h P o i n tC F ) . . . . . . . . . . . . . . . . . . . . . . . . .(. c. .c. ')1 6 5

Fbi Potrt CD.............................

Health H@rd Rstirgr

REACTIVITY DATA REACTIVITY DATA

Cugo: Group O of compatibilitychart. See also App€ndix l-Exc€ption to ih€ Chatt

SPILL OR LEAK PROCEDURE

Flsh Point('F)...... Non-tlammable

Flsb Poirt CF).............................

H6lth H.ed Rrting

ErDqure Toleme-Unavailable Short ErpGure Toleruce-o.s ppm

REACTIVITY DATA REACTIVITY DATA

SPILL OR LEAK PROCEDURE

SCANNED BY MKP & BARIS A. 2004 jli J;-d -,&r;*;r$ll&r.

CfiRIS cod............ .,.. -6!il-

Grrdec: Flammabls lkrui,

Fluh Potrt CD.............................

Fluh Point Cn.............................