36

Lampiran 1
Perhitungan Berat Jenis (BJ = ρ) Larutan HCl 32%
Diketahui :
BERAT REPLIKASI PERLAKUAN
I II III
A 43,9304 gram 43,9376 gram 43,9392 gram
B 14,4288 gram 14,4288 gram 14,4288 gram
A–B 29,5016 gram 29,5088 gram 29,5104 gram
Keterangan : A = Berat Piknometer + isi
B = Berat Piknometer kosong
A – B = Berat HCl = m
Volume piknometer = 25 ml
Ditanya : Berat Jenis (ρ) HCl = ….. ?
Jawab :
m1
ρ HCl I =
V
piknometer

29,5016
=
25

= 1,1801 gram/ml
m2
ρ HCl II =
V
piknometer

29,5088
=
25

= 1,1803 gram/ml
 37

m3
ρ HCl III =
V
piknometer

29,5104
=
25

= 1,1804 gram/ml

ρ I + ρ II + ρ III
ρ HCl =
3

1,1801 + 1,1803 + 1,1804

=
3

= 1,1802 gram/ml ≈ 1,18 gram/ml

 38

Lampiran 2
Perhitungan Pembuatan Larutan HCl Baku 0,1 N

Diketahui : Kadar HCl persediaan = 32 %

BJ (ρ) HCl = 1,18 gram/ml
BM HCl = 36,5
Valensi HCl =1

Ditanya : Volume HCl dalam persediaan yang diperlukan untuk pembuatan HCl
0,1 N (V2) = ….. ?

kadar x BJ x 1000
Jawab : N HCl persediaan = X valensi
BM
32
100 x 1,18 x 1000
= X1
36,5
377,6
=
36,5
= 10,34 N

V1 X N1 = V2 X N2

1000 ml X 0,1 N = V2 X 10,34 N

100 = 10,34 V2

100
V2 =
10,34
V2 = 9,67 ml ∼ 9,7 ml
 39

Lampiran 3
Perhitungan Pembuatan Indikator Metil Orange 0,1% sebanyak 100 ml

0,1 % = 0,1 gram/100 ml

Gram = 0,1 gram x 100 ml
100 ml
= 0,1 gram
 40

Lampiran 4
Perhitungan Pembakuan Larutan HCl dengan Na2B4O7.10H2O

Diketahui : Reaksi kimia =

Na2B4O7.10H2O + 2 HCl 2 NaCl + 4 H3BO3 + 5 H2O
Berat Na2B4O7.10H2O = 100 mg
Valensi Na2B4O7.10H2O = 2
Mr Na2B4O7.10H2O = 381,37
Volume titran (HCl) I = 5,0 ml
Volume titran (HCl) II = 4,9 ml
Volume titran (HCl) III = 5,0 ml

Ditanya : Normalitas (N) HCl = ….. ?

Jawab :
mg penimbangan Na 2 B 4 O 7 .10H 2 O
N1 = X valensi Na 2 B 4 O 7 .10H 2 O
Mr Na 2 B 4 O 7 .10H 2 O X V titran I

100 X 2
=
381,37 X 5

200
=
1906,85
= 0,1049 N

mg penimbangan Na 2 B 4 O 7 .10H 2 O
N2 = X valensi Na 2 B 4 O 7 .10H 2 O
Mr Na 2 B 4 O 7 .10H 2 O X V titran II

100 X 2
=
381,37 X 4,9
200
=
1868,713
= 0,1070 N
 41

mg penimbanga n Na 2 B 4 O 7 .10H 2 O
N3 = X valensi Na 2 B 4 O 7 .10H 2 O
Mr Na 2 B 4 O 7 .10H 2 O X V titran III

100 X 2
=
381,37 X 5

200
=
1906,85
= 0,1049 N

N1 + N 2 + N 3
N =
3

0,1049 + 0,1070 + 0,1049

=
3

= 0,1056 N
 42

Lampiran 5
Perhitungan Penetapan Kadar Boraks pada Bakso

Diketahui :
Reaksi kimia = Na2B4O7.10H2O + 2 HCl 2 NaCl + 4 H3BO3 + 5 H2O

Volume titran SAMPEL BAKSO

(HCl) A B C D
I 3,5 ml 3,8 ml 4,1 ml 3,9 ml
II 3,4 ml 3,9 ml 4,1 ml 4,0 ml
III 3,7 ml 3,8 ml 4,2 ml 4,0 ml

Mr Na2B4O7.10H2O = 381,37
Valensi Na2B4O7.10H2O = 2
Mr
BE =
valensi
381,37
=
2
= 190,685

N titran (HCl) = 0,1056 N

Berat sampel (bakso) = 20 gram = 20000 mg

 43

Kadar boraks pada sampel bakso :

a) Sampel A

( N X V ) HCl X BE
I. Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O = X 100%
Berat sampel (mg)
0,1056 N X 3,5 ml X 190,685
= X 100%
20000
7047,7176
=
20000
= 0,3524 % b/b

( N X V ) HCl X BE
II. Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O = X 100%
Berat sampel (mg)
0,1056 N X 3,4 ml X 190,685
= X 100%
20000
6846,3542
=
20000
= 0,3423 % b/b

( N X V ) HCl X BE
III. Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O = X 100%
Berat sampel (mg)
0,1056 N X 3,7 ml X 190,685
= X 100%
20000
7450,4443
=
20000
= 0,3725 % b/b
 44

I + II + III
Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O sampel A =
3
0,3524 % + 0,3423 % + 0,3725 %
=
3
1,0672
=
3
= 0,3557 % b/b ∼ 0,36 % b/b
 45

b) Sampel B
( N X V ) HCl X BE
I. Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O = X 100%
Berat sampel (mg)

0,1056 N X 3,8 ml X 190,685

= X 100%
20000
7651,8077
=
20000
= 0,3826 % b/b
( N X V ) HCl X BE
II. Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O = X 100%
Berat sampel (mg)
0,1056 N X 3,9 ml X 190,685
= X 100%
20000
7853,1710
=
20000
= 0,3927 % b/b

( N X V ) HCl X BE
III. Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O = X 100%
Berat sampel (mg)
0,1056 N X 3,8 ml X 190,685
= X 100%
20000
7651,8077
=
20000
= 0,3826 % b/b
I + II + III
Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O sampel B =
3
0,3826 % + 0,3927 % + 0,3826 %
=
3
1,1579
=
3
= 0,3860 % b/b ∼ 0,39 % b/b
 46

c) Sampel C
( N X V ) HCl X BE
I. Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O = X 100%
Berat sampel (mg)

0,1056 N X 4,1 ml X 190,685

= X 100%
20000
8255,8978
=
20000
= 0,4128 % b/b
( N X V ) HCl X BE
II. Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O = X 100%
Berat sampel (mg)
0,1056 N X 4,1 ml X 190,685
= X 100%
20000
8255,8978
=
20000
= 0,4128 % b/b
( N X V ) HCl X BE
III. Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O = X 100%
Berat sampel (mg)
0,1056 N X 4,2 ml X 190,685
= X 100%
20000
8457,2611
=
20000
= 0,4229 % b/b
I + II + III
Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O sampel C =
3
0,4128 % + 0,4128 % + 0,4229 %
=
3
1,2485
=
3
= 0,4162 % b/b ∼ 0,42 % b/b
 47

d) Sampel D
( N X V ) HCl X BE
I. Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O = X 100%
Berat sampel (mg)

0,1056 N X 3,9ml X 190,685

= X 100%
20000
7853,1710
=
20000
= 0,3927 % b/b
( N X V ) HCl X BE
II. Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O = X 100%
Berat sampel (mg)
0,1056 N X 4,0 ml X 190,685
= X 100%
20000
8054,5344
=
20000
= 0,4027 % b/b
( N X V ) HCl X BE
III. Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O = X 100%
Berat sampel (mg)
0,1056 N X 4,0 ml X 190,685
= X 100%
20000
8054,5344
=
20000
= 0,4027 % b/b
I + II + III
Kadar(% b/b) Na 2 B 4 O 7 .10H 2 O sampel D =
3
0,3927 % + 0,4027 % + 0,4027 %
=
3
1,1981
=
3
= 0,3994 % b/b ∼ 0,4 % b/b