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Connectivity in a Karst System Using Electrical

Resistivity Tomography and Network Theory


by Mariana Gómez-Nicolás1 , Mario Rebolledo-Vieyra2,3 , Efrain Canto-Lugo4 , Rodrigo Huerta-Quintanilla5 , and
Pablo Ochoa-Sandoval6

Abstract
The Ring of Cenotes (RC) is an alignment of numerous cenotes (sinkholes) in a semicircular form (with a radius of 100 km)
located in northwestern Yucatán, México. The formation roughly coincides with a concentric ring that corresponds to a buried
structure, which has been identified as the product of a meteor impact, known as the Chicxulub crater. Secondary permeability
generated by the fracturing and faulting of the sedimentary sequence in the Chicxulub crater has favored the karstification process
and therefore the development of underground rivers that transport water from the mainland to the sea.
This study implements the network theory to study the hydrological connectivity between a group of 11 cenotes within the
RC. Eight electrical resistivity tomography transects were used as an empirical basis. Each transect was acquired directly in the
field using the SuperSting R1/IP equipment with a dipole-dipole configuration. An adapted version of the reliability algorithm for
communication networks was used as a theoretical model.
We found evidence of the existence of water cavities in the study area. We made a network from the data and assigned
connection probabilities among cenotes as a function of the separation length and the number of water cavities, as well as their size.

Introduction out the southern boundary of the Chicxulub crater’s outer


The Yucatán Peninsula contains one of the most rim (Pope et al. 1991). Although the RC is clearly associ-
extensive karst aquifer systems on the planet. The region ated with the Chicxulub crater basin, several hypotheses
hosts the world’s longest underwater cave system and the have been proposed to explain the formation of this
65-million-year-old multi-ring Chicxulub impact crater surface. Furthermore, new discussions could emerge in
(Gondwe et al. 2010; Bauer-Gottwein et al. 2011). coming years in the light of the findings derived from
Using Landsat Thematic Mapper imagery, Pope iden- the 364 drilling Expedition (Morgan et al. 2016).
tified in 1991 the Ring of Cenotes (RC), a semicircular Despite its uncertain origin, the RC plays a key role
feature which extends over an arc of about 90 km tracing in the regional hydrology of the Yucatán Peninsula; it
was a focus for Mayan settlements (Gilli et al. 2009)
1
Laboratorio de Ingeniería y Procesos Costeros, Instituto de and now, individual cenotes continue to be exploited
Ingeniería, Universidad Nacional Autónoma de México, Puerto de for human consumption or for tourism. As a result of
Abrigo S/N, Sisal, Yucatán, 97355, México. their importance, cenotes have become the subject of
2 Centro de Investigación Científica de Yucatán, Unidad de
an extensive variety of hydrogeological, chemical, and
Ciencias del Agua, Mérida, Yucatán, México.
3 Currently at Independent Consultant, SM 312, Mza 7, Chipre geophysical studies (Pérez-Ceballos et al. 2012). These
5, Cancún, Quintana Roo, 77500, México. studies have allowed large-scale patterns to be established
4 Departamento de Física Aplicada, Centro de Investigación y across the RC and have played a decisive role in the
de Estudios Avanzados del Instituto Politécnico Nacional, Mérida, formulation of laws to delimit protection zones such as
Yucatán, México. the geohydrological reserve (Decree117 2016). Despite
5
Corresponding author: Departamento de Física Aplicada,
Centro de Investigación y de Estudios Avanzados del
these efforts, there is a lack of integral management to
Instituto Politécnico Nacional, Mérida, Yucatán 97310, México; preserve the quality of their waters.
52+(999)9429431; rhuerta@cinvestav.mx In cenotes which have a good hydraulic connection
6
Facultad de Ingeniería y Ciencias, Universidad Autónoma de with the rest of the aquifer, the water remains clear
Tamaulipas, Ciudad Victoria, Tamaulipas, 87149, México. during most of the year. These cenotes are primarily
Article impact statement: Novel method combining electrical
resistivity tomography and network reliability theory to infer fed by groundwater through fractures and dissolution
preferential connectivity in a karst system. cavities (Schmitter-Soto et al. 2002). These conduits
Received March 2017, accepted October 2017. serve as major pathways for groundwater flow in karst
© 2017, National Ground Water Association. aquifers and since a water-filled underground void has
doi: 10.1111/gwat.12618 lower resistivity than most of the surrounding rocks, in

NGWA.org Groundwater 1
principle it can be detect using the geophysical method of 14 km from drill site U2, into the archeological site of
electrical resistivity tomography (ERT) (Zhu et al. 2011). Mayapán (Figure 2), the last Maya capital of the Yucatán.
Electrical resistivity is based on the injection of an electric Bedrock samples, around Mayapán, show it as an impor-
current into the ground through electrodes. Bulk electrical tant geological boundary with contrasting 87 Sr/86 Sr sig-
resistivities in the shallow subsurface are controlled natures on either side (Gilli et al. 2009).
largely by electrolytic conduction in aqueous fluids that In hydrogeological terms, the aquifer consists of a
are either distributed across grain boundaries or contained mature karstic system with a low hydraulic gradient on
in pores, fractures, and faults (Stummer et al. 2004). the order of 7 to 10 mm/km, suggesting very high perme-
We are interested in studying the connection between abilities (Steinich and Marín 1996, 1997). Dissolution of
sinkholes across conduits found by ERT. Since each the carbonate rocks has resulted in a lack of aquitards. The
electrical resisitivity image is limited to a few meters in aquifer is unconfined except for a narrow band parallel to
depth and length, here we propose a new approach based the coast, possesses a thin lens of fresh water (45 m at
on a modified network reliability algorithm to integrate Mérida) underlaid by salt-water intrusion that penetrates
the information provided by several ERT measurements more than 40-km inland, with measured water depths of
and characterize the connection between sinkholes. up to 60 m (Perry et al. 1989, 1995). The aquifer is highly
By network, we refer to a collection of small circles vulnerable to contamination, as shown by previous studies
(nodes) interconnected by lines (links). For example, in that reported that groundwater within the top 15 to 20 m
transportation, the circles might represent delivery points of the aquifer does not meet the standards for human con-
of goods and the lines are the roads between them. The sumption (Marín et al. 2000; Pacheco-Castro et al. 2017).
study of reliability models starts from the knowledge of Six kilometers to the east of our study site, Pérez-Ceballos
the failure probabilities of the links and seeks to determine characterized a group of seven cenotes with low pH val-
an index that corresponds to the probability that the ues, high NO− + −
3 , and high Ca2 and HCO3 and concluded
network is operational; in other words, it determines the that these cenotes in the center of the RC are in an aquifer
probability that there is at least one path that connects recharge zone (Pérez-Ceballos et al. 2012).
a pair of nodes. In this study, sinkholes comprising 11 At the end of the Cretaceous, a large asteroid
cenotes within the RC in an area of 0.5 km2 and cavities impacted the Yucatán Peninsula. The center of the
found by ERT are the nodes of the network. We establish approximately 200 km impact crater, named the Chicxulub
links between the nodes and then calculate the probability impact crater, is located off the present Yucatán Peninsula
that one cenote is connected to another by a specific Gulf of México coastline, at approximately 21.4◦ N and
trajectory. 89.5◦ W. The outline of the impact crater is marked by
the RC, a fracture zone with a high density of sinkholes.
This zone plays an important role in the distribution of
Site Description water in the peninsula because of its high permeability
This is a summary of the relevant geological features and subterranean-river behavior concentrates, transports,
of the Yucatán Peninsula as presented by Bauer-Gottwein and discharges groundwater where the ring intersects the
et al. (2011)). The current conceptual geological under- coast near Celestún and Dzilam de Bravo (Marín 1990;
standing of the Yucatán Peninsula was established by the Perry et al. 1995). In addition, due to its great biodiversity
Pemex Exploration Drilling Program from the 1940s to and its hydrogeological properties, in 2016, the RC was
1960s, along with regional gravity and magnetic surveys, declared a Ramsar site and in the southwestern portion
and the Chicxulub Scientific Drilling Program carried the first hydrogeological State Reserve in the country was
out by the National Autonomous University of México created (Decree117 2016).
(UNAM) in 2000 (Figure 1). Mayapán was the largest Mayan political capital of
The Yucatán Peninsula is a low-lying platform con- the Post-classic Period (A.D. 1150 to 1450). It has been
sisting of limestone, dolomites, and evaporates, reaching the subject of a comprehensive archeological study that
thicknesses of greater than 1500 m. The Cretaceous, and began in 1948 with the arrival of a team of researchers
most of the Tertiary, lies upon a basement of red beds from the Carnegie Institution (Hare et al. 2014). Nowa-
from the Triassic-Jurassic and igneous rocks from the Tri- days, researchers focus their efforts on long-term studies
assic and Paleozoic. The surface sedimentary rocks span at the ancient city by documenting the regional system of
from the Upper Cretaceous to the Holocene, and are gen- settlement and the environment in which it was developed.
erally almost horizontally layered and off-lapping, with As a result, they have created a bare earth digital eleva-
gradually younger carbonates deposited toward the Penin- tion model of a 40 km2 area centered on the walled city
sula margins. Lithological columns from the site UNAM- of Mayapán using LiDAR-generated data, ground survey,
2 (U2) drill site present this sequence from surface to surface collection, test excavations, artifact analysis, and
bottom: 1.7 m of soil and caliche followed by 85 m of Geographic Information System–aided spatial analysis.
dolomitized crystalline limestone with 14 m of intercalated Underwater archeology presents some interesting
dolomitized calcarenite, 95 m of fossiliferous dolomitized results 2 km far from our study site. Detailed underwater
crystalline limestone, 10 m of argillaceous limestone and mapping, photography, and video of the cenote Sac
finally another 10 m of dolomitized crystalline limestone Uayum shows two 15-m-deep chambers connected by a
(Rebolledo-Vieyra et al. 2000). Our study zone is located narrow passage about 10 m long. The remains of human

2 M. Gómez-Nicolás et al. Groundwater NGWA.org


Figure 1. Compiled geologic map of Yucatán. The map shows the location of PEMEX exploratory boreholes (C1, S1, T1, Y1,
Y2, Y5A, and Y6) and UNAM scientific shallow-drilling program boreholes (U1 to U8). Q, Calcarenite and coquina; PCP,
Argillaceous limestone and coquinoide limestone; O, Marly calcarenite and coquinoide; EChCh, Fossilliferous crystalline
limestone; EChP, Crystalline limestone and argillaceous; Pal-E, Crystalline limestone, dolomitized with anhydritic facies. No
scale (modified from Rebolledo-Vieyra et al. 2010).

crania, bones, and ceramic fragments were clustered in coordinates for the 11 cenotes of interest (Figure 2). Table
the southwest end of the first chamber (Russell 2017). S1, supporting information, shows the cenote labels and
With all of the aforementioned, our main working their coordinates.
hypothesis is that the RC is originated and structurally
controlled by the faults and joints generated by the ERT Measurements
gravitational accommodation of the Chicxulub Crater rim In this particular case, we used ERT to identify
(Gulick et al. 2008). Based on this, we developed a macroscale porosities (> 3 m diameter). Our main goal
conceptual model for the conduits and connections. The was to identify conduits larger than 3 m with a high
model assumes that the vertical faults and joints are likelihood of connecting sinkholes. For this task, ERT is
continuous structures, no larger than 3 × 3 km. We also a very effective tool. The spatial set up of the transects
hypothesize that this is a fault and joint system, where (labeled T1, T2,...,T8) was designed considering the
the surface expression of them are nearly parallel. The accessibility to the field, using trails already available
latter accounts for the connection along the RC, and, in and patches free of vegetation. The next consideration
a lesser degree, to the connections perpendicular to the was to position the transect in a way that would intercept
main trace of the RC. the imaginary line connecting one cenote to another. For
example, T7 intercepts an imaginary line from cenote
nine to cenote one and from cenote nine to cenote
Research Method seven. Transects: T1, T2, T5, T6, and T7 were laid
out on existing trails, while for T3, T4, and T8, it was
Cenote Selection necessary to clear the vegetation. There was an overlap
We selected the study zone based on the database among transects T1, T2, and T3 with the purpose of
provided by the Yucatán Government (SEDUMA 2016) reducing the edge effects. In Table S2, we show the
which satisfies the conditions of being in the RC and geographic coordinates for the first and the last electrodes
presenting a high density of cenotes. The zone chosen of each transect. The final setup of the transects and
is 40 km southeast from Mérida, in the ancient city cenotes is shown in Figure 3. The area in which the
of Mayapán. The original Carnegie map of Mayapán transects and cenotes are located has an approximate size
(Jones 1962) and a map shared by Dr. Russell (Russell of 600 m × 800 m. ERT imaging surveys were conducted
®
2017) played an important role in our specific selection using the AGI SuperSting R1/IP (Advanced Geosciences
of sinkholes. We used a Global Positioning System Inc., Austin, Texas) acquisition system. The 345-m
®
Trimble (Sunnyvale, California) Recon 400X to aquire stationary cable consisted of 71 electrodes spaced 5 m

NGWA.org M. Gómez-Nicolás et al. Groundwater 3


Figure 2. Map of the Yucatán Peninsula. An aerial view of the RC, with Chicxulub Port at its center and two water discharge
locations (Celestún and Dzilam de Bravo). Study zone comprising a group of 11 cenotes, located in the Post-classic Mayan
political capital of Mayapán, within the only geohydrological Reserve of México. Cenote No. 11 (Chen Carro) belongs to the
Ramsar Site list no. 2043.

where V is the potential difference and K is the


geometric factor of the dipole-dipole array (Loke 2013).
Prior to further processing, the data were filtered. We
discarded data with voltages lower than 0.2 mV and
resistivities smaller than 0.01 ohm-m and larger than
105 ohm-m. For the forward solution, we solved the
following two-dimensional partial differential equation in
the Fourier transform domain by the finite difference
method:
   
∂ ∂V ∂ ∂V
σ + σ − k 2 σ V = −I · δ (x) · δ (z)
∂x ∂x ∂z ∂z
(2)

where V is the potential, I is the electric current,


k is the wavenumber in the transform domain, and
Figure 3. Array of the eight ERT transects (T1, T2, ..., T8) σ is the electrical conductivity as a function of (x ,
located between the 11 cenotes. The geographical coordinates z ) (Advanced Geosciences Inc. 2005). The results in
of the cenotes and transects are given in Tables S1 and S2, this study were produced using the finite difference
respectively. method solving Equation 2 (Dey and Morrison 1979).
For inversion, we used a smooth model inversion algo-
rithm (Constable et al. 1987) to minimize the objective
apart along multi-node cable. A dipole-dipole array was
function
used because of its good lateral resolution (Stummer et al.
2004). A total number of 2175 measurements per transect
were collected. S (m) = (dobs − g (m))T Wd (dobs − g (m)) + α· mT Rm
(3)
Inversion Process
The apparent resistivity ρ a value is calculated from where dobs is the measured data and g(m) is the calculated
the current (I ) and voltage (V ) values: data. Wd is a data weighting matrix, α is a Lagrange
multiplier, and R is a roughness operator (Advanced
V Geosciences Inc. 2005). All these processes were carried
ρa = K (1) ®
I out using the software AGI EarthImager 2D v2.4.0

4 M. Gómez-Nicolás et al. Groundwater NGWA.org


Calculation of Probabilities
To calculate the connection probability between the
studied cenotes, we used an adapted version of the
network reliability algorithm (Fishman 1996, p. 55). This
algorithm provides us with the probability of any two
cenotes in a network, called s and t, being connected. To
frame the problem in terms of that algorithm we define
nodes, links and the reliability vector q as follows.
The nodes considered for the calculation consisted
of the 11 cenotes (Figure 3) and the 23 water cavities
identified by ERT analysis (Figure 5). In total, we obtain
a set of V = {1, ..., 34} nodes. For the other hand, there
is a link between two nodes s and t if there is a straight
line joining s and t and this line does not cross an ERT
transect. It is important to note that s and t cannot both be
cenotes, because we establish that the connection between
them is only across the cavities found by the ERT. With
this criteria we obtained a set of m = 138 links. Figure 6
shows the network with 34 nodes and 138 links. For
each link, we calculated q i with i ∈ 1, ..., m, where
1−q i means the probability that link q i “fails.” For the
calculation, we used the exponential functions D(X ) and
A(Z ), both with a range of (0, 1). The first one given in
Figure 4. Color scale associated with resistivity. The label terms of the nodes distance X = X (s, t) and expressed as
color is used to calculate the weighted area for the water
cavity in Equation 4.
D (X) = e−αX (s,t) (5)

(Advanced Geosciences Inc.). We applied a common scale with α = γ /λ, where λ = 181.05 m is the average distance
of colors to the eight inverted resistivity sections. In between the nodes in the network; by assumption
Figure 4, the color scale and the corresponding resistivity D(3000 m) = 0.01, then, solving for γ we get γ = 0.277.
are displayed. This assumption is based on geophysical observations:
Gulick et al. (2008), reported faults within the Chicxulub
Water Cavity Determination crater rim, where the study area is located, up to 3 km
The ERTs were performed to obtain information deep, from ground surface. From this, we assigned a
on possible underground water cavities which connect square shape to the fault’s geometry, with a 3 × 3 km side.
cenotes. The water in the region studied has a resistivity In Pope et al. (1991), we also found that the cenote density
between 6 and 12 ohm-m (Pérez-Ceballos et al. 2012) and width of the ring vary from about three cenotes per
but since the inversion process introduces a degree of km2 along a 3 km-wide portion in the southwest, to a chain
uncertainty, we consider a larger range for the resistivity: of single cenotes 3 km apart in the southeast.
1 to 47 ohm-m. Later in the paper, we will see evidence The second function is in terms of the weighted area
for 23 water cavities. The cross-sectional area for each of the cavities Z = Z (t),
cavity was calculated as:
A (Z) = 1 − e−βZ (t) (6)

5
Z= Wi Ai (4) with β = η/τ , where τ = 81.34 m2 is the average weighted
i=1 area for all the cavities; by assumption A(56 m2 ) = 0.5,
then, solving for η we get η = 1. This assumption is based
where Ai is the area of the cavity with color ai (Figure 4)
on personal observations in the field that show the radius
and W i is the weight that represents the percentage of
of cenotes in this study area is approximately 4 m.
water contained in a material with resistivity ai. We
In this way, when we considered cenote (s)—water
use previous studies as a reference (Telford et al. 1990;
cavity (t), q i = q(s, t) is calculated as
Bauer-Gottwein et al. 2011) to assign the following values
for W : W 1 = 0.8, since this is typical for saline water;  
q (s, t) = e−αX (s,t) 1 − e−βZ (t) (7)
W 2 = 0.9, because in this resistivity range (3 to 6 ohm-
m), most of water is saturated with salt; W 3 = 1.0,
this is the resistivity for free water in the cenotes In the case water cavity (s)—water cavity (t). The
(Pérez-Ceballos et al. 2012); W 4 = 0.5 and W 5 = 0.3, equation takes the form
correspond to water trapped in rocks with different   
densities. q (s, t) = e−αX (s,t) 1 − e−βZ (s) 1 − e−βZ (t) (8)

NGWA.org M. Gómez-Nicolás et al. Groundwater 5


Figure 5. Electrical Resistivity Tomography Profiles. The eight transects with the 23 water cavities found, with resistivities
between 1 and 47 ohm-m and numbered from 12 to 34.

The 138 tuple of values of q i conform the compo- of uncertainties. Figure 5 shows the eight transects and
nents of the reliability vector q. Once we obtain q, the net- the positions of the 23 cavities that were found. The
work is divided into six clusters or subnetworks (Figure 6) comparison between the color hues (Figure 4) allowed us
and we applied the reliability algorithm to each of them to to identify the non-saturation zone (red-yellow with resis-
calculate the final probability g(q) of connection. In sum- tivities of 1529 to 100,000 ohm-m) and the saturated zone
mary, the network reliability algorithm indicates that the (1 to 47 ohm-m). The range between 47 and 1529 ohm-m
probability of connection between two network nodes s is associated with fractured limestone (Telford et al.
and t over one specific path is the product of the probabil- 1990). The water level was 14 m deep with respect to
ities that each node is connected with the next one in that the terrain level. This was based on measurements made
path. Afterward, it is necessary to sum these probabilities on cenotes with wide surface openings, using a portable
over every possible path between s and t. electronic water level meter. However, it was not possible
The two adjusted parameters γ and η can be to do this with every cenote. With the others, we had to
updated once more information is obtained from the substitute indirect estimates from ERT, uncorrected for
system. Figures S1 and S2 illustrate the variability of topography. Figure 5 shows that most of the underground
the Euclidean norm of the reliability vector, as measured water lies at a depth range of 12 to 20 m.

by the difference ||q− q ||, under changes in our geological The transects T1, T2, T3, T4, T5, and T7 indicate
suppositions. possible water flux in the east to west direction (Figure 3);
this observation gives strength to the hypothesis of
circulation flux in the RC direction (Bauer-Gottwein et al.
Results 2011).
We perform a contact resistance test prior to each To use Equation 5, coordinates of the cenotes were
ERT survey. Transects T1, T2, T3, T5, T7, and T8 passed used, as in Table S1. The coordinates of the geometrical
the test (<2000 ohm-m). However, 20% of the contact center of each water cavity was calculated from the
resistance values in T4 and T6 were high. These two transect to which it belongs, using the first electrode of
transects were installed on exposed limestone bedrock. the transect as a spatial reference. The results are given in
We kept the data since they contribute significantly to the Table S3. For Equation 6, we calculated the weighted area
analysis, but keeping in mind the possible introduction Z (Equation 4) of each water cavity (Table 1). Finally,

6 M. Gómez-Nicolás et al. Groundwater NGWA.org


Figure 6. The complex network with 34 nodes and 138 links. The colors show the six clusters analyzed. The nodes are labeled
in red from 1 to 11 for cenotes and in blue from 12 to 34 for water cavities. Black lines represent links between the nodes.

Table 1 Table 2
Weighted Area (Z ) of the Water Cavities Connecting Probabilities Between Cenotes that
Belong to Clusters 1, 2, and 3.
Water Cavity Z (m2 ) Water Cavity Z (m2 )
Cluster Cenotes g(q)
12 7 24 19
13 52 25 12 1 {1, 7} 0.875
14 92 26 125 {1, 8} 0.877
15 131 27 106 {1, 9} 0.878
16 7 28 61 {7, 8} 0.861
17 36 29 68 {7, 9} 0.873
18 50 30 9 {8, 9} 0.870
19 23 31 310 2 {2, 4} 0.594
20 62 32 28 {2, 5} 0.575
21 157 33 96 {2, 7} 0.003
22 296 34 107 {4, 5} 0.672
23 15 {4, 7} 0.004
{5, 7} 0.003
3 {2, 3} 0.581
{2, 6} 0.669
we used Equations 7 and 8 (depending on the case) to {2, 11} 0.615
determine the q values. {3, 6} 0.661
The 34 nodes, 138 links, and 6 clusters are presented {3, 11} 0.537
in Figure 6. Cenotes are the nodes in red (1 to 11) {6, 11} 0.688
and, water cavities are the nodes in blue (12 to 34).
Cluster 1 is composed of nine nodes of which nodes 1, 7, 8, and 9 are cenotes.
To reduce computational effort, and according to our Cluster 2 is composed of 10 nodes of which nodes 2, 4, 5, and 7 are cenotes.
principal interest, the network was divided into six clusters Cluster 3 is composed of 11 nodes of which nodes 2, 3, 6, and 11 are cenotes
(subgraphs); this does not modified our findings. (Figure 6).

In Tables 2 and 3, we applied network reliability


algorithm (Fishman 1996, p. 55) and we show the g(q) part of the RC is in that direction. Cluster 6 oriented west-
probabilities of cenote-cenote connections. In particular, east has 36% more connecting probability than cluster
we see a preferential pattern of connection in the west to 5 (oriented north-south). Further analysis is needed to
east orientation. As previous studies suggest, this could be confirm these findings. Another point that should be noted
related to the fact that the preferential flux direction in this is that for a pair of cenotes, these tables do not give equal

NGWA.org M. Gómez-Nicolás et al. Groundwater 7


Table 3 flow; this variable was not measured. Nevertheless, we
Connecting Probabilities Between Cenotes that can infer the preferential direction of flow from the
Belong to Clusters 4, 5, and 6. conduits found and their connections. This methodology
can complement archeological underwater studies such
Cluster Cenotes g(q) as those of Dr. Bradley Russell’s group. Despite the
arbitrariness of the scale factors γ and η, we have found
4 {6, 8} 0.230 that the connectivity hierarchy is preserved even when the
{6, 10} 0.728 factors are modified. If, for instance, in cluster 6 the two
{8, 10} 0.182
most connected cenotes are {1,8} and the least connected
5 {1, 4} 0.004
{1, 8} 0.278 are {3,9}, this would remain true even if the parameters
{1, 10} 0.095 are modified.
{4, 8} 0.004 We hope that future work in this area could support
{4, 10} 0.001 our findings. For instance, we expect cenotes 1, 7, 8, and
{8, 10} 0.097 9 in cluster 1, which are the most connected, to share
6 {1, 3} 0.005 geochemical characteristics, for example, clear waters,
{1, 6} 0.098
clean, sandy or rocky bottoms, and a homogeneous, well-
{1, 8} 0.670
{1, 9} 0.625 oxygenated water column. In any case, in cenote 1, a great
{3, 6} 0.035 sound of flowing water was detected that was big enough
{3, 8} 0.005 to generate an air column which was expelled from the
{3, 9} 0.004 cenote.
{6, 8} 0.097 Cenote 11 is very probably connected to cenotes 6, 2,
{6, 9} 0.077 and 3, and because of this, any action to preserve cenote
{8, 9} 0.609 11 as a RAMSAR site, would require this connection to
Cluster 4 is composed of 10 nodes of which nodes 6, 8, 10 are cenotes. be considered in the preservation scheme. With regards
Cluster 5 is composed of 11 nodes of which nodes 1, 4, 8 and 10 are cenotes. to cenotes 4 and 10, which in the calculations appear to
Cluster 6 is composed of 8 nodes of which nodes 1, 3, 6, 8 and 9 are cenotes be poorly connected, possibly due to the collapse of a
(Figure. 6).
roof or wall and sedimentation, we expect turbid water,
and a thermally stratified, alkaline surface water layer
values, that is, the probability of 3 and 6 being connected which is oversaturated with oxygen, while water near the
is 0.661 in cluster 3 and is not the same as the probability bottom is likely to be acidic, devoid of O2 , and contain
that 3 being connected to 6 in cluster 6: 0.035. These H2 S. It is beyond the scope of this paper to corroborate
probabilities need not to be the same since they depend the aforementioned, however, we are sure that it would
on the transects that have been included in the calculation. be easy for the community to test it.
Even though we have split the network into clusters to
calculate the connecting probabilities, we also calculated
them using the entire network. As an example we obtain Conclusion
0.662 for the connecting probability between cenotes {2, The methodology proposed in this study is poten-
11}. Inside cluster 3, this probability is 0.615. tially a very powerful tool for investigating aquifers where
traditional hydrogeological methods (e.g., pumping tests)
are not available or difficult to perform. The combina-
Discussion tion of a proved geophysical technique to investigate
Many attempts have been made to describe the the underground geological structure, with a powerful,
network structure of underground karstic cavities (Borghi yet flexible mathematical algorithm such as the network
et al. 2012). Geophysical methods have been successfully theory, allows us to assign a number to the connection
used to locate preferential flow paths and structures probability between different cenotes based on the dis-
in karst aquifers (Gondwe et al. 2010). In the Yucatán tance between them and the empirical evidence obtained
Peninsula, electrical resistivity methods have never been using ERT. In this particular case, we applied our pro-
applied to the study of connectivity between sinkholes, posed methodology to an area where we have very reliable
the only antecedent is the work of (Steinich and Marín macroscale geological information, such as information
1996). These authors detected the main azimuth angles of on the RC, where extensive, regional, geophysical studies
subsurface high-permeability structures at a regional scale have been performed (Gulick et al. 2008). These provide
using vertical electrical sounding. us with regional information, predicting connectivity in
In the present study, we are not aiming to determine the southern portion of the RC, roughly oriented W-E,
the complete structure of a karstic aquifer, such as the one which concurs with our results.
we have in the Yucatán Peninsula, since the representation These probabilities depend on the setup we used to
of sinkholes and conduits in terms of nodes and links measure the resistivities, which means they are sensitive
lacks important information. However, we have gained to the trajectory. The uncertainties can only be reduced
an insight into the system’s pattern of connections. Our by increasing the number of transects. With regards to
method does not provide quantitative information on water computation, it was possible to program in parallel to

8 M. Gómez-Nicolás et al. Groundwater NGWA.org


reduce the time taken to perform the analyses, which Bauer-Gottwein, P., B. Gondwe, G. Charvet, L.E. Marín, M.
allowed for more possible links in the network. We Rebolledo-Vieyra, and G. Merediz-Alonso. 2011. Review:
are sure that other teams that have been working in The Yucatán Peninsula karst aquifer, México. Hydrogeol-
ogy Journal 19, no. 3: 507–524.
Mayapán for many years have something to say about Borghi, A., P. Renard, and S. Jenni. 2012. A pseudo-genetic
our results, and with their collaboration the results of this stochastic model to generate karstic networks. Journal of
study could provide valuable information. We hope that Hydrology 414–415: 516–529.
people working in underwater anthropology or isotopic Constable, S.C., R.L. Parker, and C.G. Constable. 1987.
techniques can verify our results, since it could be a Occam’s inversion: A practical algorithm for generating
smooth models from electromagnetic sounding data. Geo-
technique to help make conservation decisions such as physics 52, no. 3: 289–300.
the restriction of human activities, the selection of waste Decree117. 2016. Decreto 117, decreto que establece el
disposal areas, and the protection of recharge areas to área natural protegida denominada reserva estatal geo-
promote the sustainable use of the water resources in this hidrológica del anillo de cenotes. Gobierno del estado
geographical area. de Yucatán (spanish) [decree 117, decree establishing the
protected natural area called the geohydrological state
reserve of the ring of cenotes. Government of the state
of Yucatán]. http://www.yucatan.gob.mx/gobierno/diario_
Acknowledgments oficial.php?f=2013-10-28 (accessed March 2016).
M.G.N. acknowledges a master grant from CONA- Dey, A., and H.F. Morrison. 1979. Resistivity modelling for
CyT, under which this contribution first started. Also we arbitrarily shaped two-dimensional structures. Geophysical
thank Acrelio Pacheco, Archeologists Carlos Peraza and Prospecting 27, no. 1: 106–136.
Fishman, G.S. 1996. Monte Carlo: Concepts, Algorithms, and
Eunice Uc, for providing free access to the lands where Applications. New York: Springer.
we carried out the survey. The authors wish to thank Gilli, A., D.A. Hodell, G.D. Kamenov, and M. Brenner. 2009.
CICY for providing the vehicles and field equipment for Geological and archaeological implications of strontium
conducting ERT surveys. We also thank the project “Geo- isotope analysis of exposed bedrock in the Chicxulub crater
physical survey of the Yucatán Aquifer,” where M.R.V. basin, northwestern Yucatán, México. Geology 37, no. 8:
723–726.
is responsible. Also would like to thank three anonymous Gondwe, B.R., S. Lerer, S. Stisen, L. Marín, M. Rebolledo-
reviewers for their insightful comments, which greatly Vieyra, G. Merediz-Alonso, and P. Bauer-Gottwein. 2010.
improved this manuscript. To Dr. Adrián Flores-Orozco Hydrogeology of the south-eastern Yucatán Peninsula: New
for the useful suggestions in the ERT inversion process. insights from water level measurements, geochemistry,
To Dr. Bradley Russell for sharing geographic locations geophysics and remote sensing. Journal of Hydrology 389,
no. 1: 1–17.
of Mayapan cenotes. To Daniel P.B. Smith for editorial
Gulick, S.P., P.J. Barton, G.L. Christeson, J.V. Morgan,
assistance. M. McDonald, K. Mendoza-Cervantes, Z.F. Pearson, A.
Surendra, J. Urrutia-Fucugauchi, P.M. Vermeesch, et al.
2008. Importance of pre-impact crustal structure for
Supporting Information the asymmetry of the Chicxulub impact crater. Nature
Additional Supporting Information may be found in the Geoscience 1, no. 2: 131–135.
Hare, T., M. Masson, and B. Russell. 2014. High-density lidar
online version of this article. Supporting Information is mapping of the ancient city of Mayapán. Remote Sensing
generally not peer reviewed. 6, no. 9: 9064–9085.
Jones, M. 1962. Map of Mayapán. In Mayapán, Yucatán,
Table S1. Cenote labels and their locations. México, ed. H.E. Pollock, R.L. Roys, T. Proskouriakoff,
Table S2. Location of each of the transects. In this table, and A.L. Smith, 619. Washington, DC: Carnegie Institute
we give the position of the first (E1) and last (E71) of Washington.
electrodes. Loke, M.H. 2013. Tutorial: 2-D and 3-D Electrical Imaging
Table S3. Location of the geometrical center of each water Surveys. Copyright (1996–2004). Malaysia: Geotomo Soft-
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cavity. Marín, L.E., 1990. Field Investigations and Numerical Simula-
Figure S1. Variability of the reliability vector q under tion of Groundwater Flow in the Karstic Aquifer of North-
changes in the geological suppositions in Equation 5. western Yucatán, México. DeKalb, Illinois: Northern Illi-
Here, q is the reliability vector when we assume D(X *) nois University.
= 0.01 with X * = 3000m, and q is the reliability vector Marín, L.E., B. Steinich, J. Pacheco, and O.A. Escolero. 2000.
Hydrogeology of a contaminated sole-source karst aquifer,
obtained when X* is perturbed.
Mérida, Yucatán, México. Geofísica Internacional 39, no.
Figure S2. Variability of the reliability vector q under 4: 359–365.
changes in the geological suppositions in Equation 6. Morgan, J.V., S.P.S. Gulick, T. Bralower, E. Chenot, G.
Here, q is the reliability vector when we assume A(Z *) Christeson, P. Claeys, C. Cockell, G.S. Collins, M.J.L.
= 0.5 with Z* = 56 m2 , and q is the reliability vector Coolen, L. Ferrière, C. Gebhardt, K. Goto, H. Jones,
obtained when Z* is perturbed. D.A. Kring, E. Le Ber, J. Lofi, X. Long, C. Lowery, C.
Mellett, R. Ocampo-Torres, G.R. Osinski, L. Perez-Cruz,
A. Pickersgill, M. Poelchau, A. Rae, C. Rasmussen, M.
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