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Abstract
The Ring of Cenotes (RC) is an alignment of numerous cenotes (sinkholes) in a semicircular form (with a radius of 100 km)
located in northwestern Yucatán, México. The formation roughly coincides with a concentric ring that corresponds to a buried
structure, which has been identified as the product of a meteor impact, known as the Chicxulub crater. Secondary permeability
generated by the fracturing and faulting of the sedimentary sequence in the Chicxulub crater has favored the karstification process
and therefore the development of underground rivers that transport water from the mainland to the sea.
This study implements the network theory to study the hydrological connectivity between a group of 11 cenotes within the
RC. Eight electrical resistivity tomography transects were used as an empirical basis. Each transect was acquired directly in the
field using the SuperSting R1/IP equipment with a dipole-dipole configuration. An adapted version of the reliability algorithm for
communication networks was used as a theoretical model.
We found evidence of the existence of water cavities in the study area. We made a network from the data and assigned
connection probabilities among cenotes as a function of the separation length and the number of water cavities, as well as their size.
NGWA.org Groundwater 1
principle it can be detect using the geophysical method of 14 km from drill site U2, into the archeological site of
electrical resistivity tomography (ERT) (Zhu et al. 2011). Mayapán (Figure 2), the last Maya capital of the Yucatán.
Electrical resistivity is based on the injection of an electric Bedrock samples, around Mayapán, show it as an impor-
current into the ground through electrodes. Bulk electrical tant geological boundary with contrasting 87 Sr/86 Sr sig-
resistivities in the shallow subsurface are controlled natures on either side (Gilli et al. 2009).
largely by electrolytic conduction in aqueous fluids that In hydrogeological terms, the aquifer consists of a
are either distributed across grain boundaries or contained mature karstic system with a low hydraulic gradient on
in pores, fractures, and faults (Stummer et al. 2004). the order of 7 to 10 mm/km, suggesting very high perme-
We are interested in studying the connection between abilities (Steinich and Marín 1996, 1997). Dissolution of
sinkholes across conduits found by ERT. Since each the carbonate rocks has resulted in a lack of aquitards. The
electrical resisitivity image is limited to a few meters in aquifer is unconfined except for a narrow band parallel to
depth and length, here we propose a new approach based the coast, possesses a thin lens of fresh water (45 m at
on a modified network reliability algorithm to integrate Mérida) underlaid by salt-water intrusion that penetrates
the information provided by several ERT measurements more than 40-km inland, with measured water depths of
and characterize the connection between sinkholes. up to 60 m (Perry et al. 1989, 1995). The aquifer is highly
By network, we refer to a collection of small circles vulnerable to contamination, as shown by previous studies
(nodes) interconnected by lines (links). For example, in that reported that groundwater within the top 15 to 20 m
transportation, the circles might represent delivery points of the aquifer does not meet the standards for human con-
of goods and the lines are the roads between them. The sumption (Marín et al. 2000; Pacheco-Castro et al. 2017).
study of reliability models starts from the knowledge of Six kilometers to the east of our study site, Pérez-Ceballos
the failure probabilities of the links and seeks to determine characterized a group of seven cenotes with low pH val-
an index that corresponds to the probability that the ues, high NO− + −
3 , and high Ca2 and HCO3 and concluded
network is operational; in other words, it determines the that these cenotes in the center of the RC are in an aquifer
probability that there is at least one path that connects recharge zone (Pérez-Ceballos et al. 2012).
a pair of nodes. In this study, sinkholes comprising 11 At the end of the Cretaceous, a large asteroid
cenotes within the RC in an area of 0.5 km2 and cavities impacted the Yucatán Peninsula. The center of the
found by ERT are the nodes of the network. We establish approximately 200 km impact crater, named the Chicxulub
links between the nodes and then calculate the probability impact crater, is located off the present Yucatán Peninsula
that one cenote is connected to another by a specific Gulf of México coastline, at approximately 21.4◦ N and
trajectory. 89.5◦ W. The outline of the impact crater is marked by
the RC, a fracture zone with a high density of sinkholes.
This zone plays an important role in the distribution of
Site Description water in the peninsula because of its high permeability
This is a summary of the relevant geological features and subterranean-river behavior concentrates, transports,
of the Yucatán Peninsula as presented by Bauer-Gottwein and discharges groundwater where the ring intersects the
et al. (2011)). The current conceptual geological under- coast near Celestún and Dzilam de Bravo (Marín 1990;
standing of the Yucatán Peninsula was established by the Perry et al. 1995). In addition, due to its great biodiversity
Pemex Exploration Drilling Program from the 1940s to and its hydrogeological properties, in 2016, the RC was
1960s, along with regional gravity and magnetic surveys, declared a Ramsar site and in the southwestern portion
and the Chicxulub Scientific Drilling Program carried the first hydrogeological State Reserve in the country was
out by the National Autonomous University of México created (Decree117 2016).
(UNAM) in 2000 (Figure 1). Mayapán was the largest Mayan political capital of
The Yucatán Peninsula is a low-lying platform con- the Post-classic Period (A.D. 1150 to 1450). It has been
sisting of limestone, dolomites, and evaporates, reaching the subject of a comprehensive archeological study that
thicknesses of greater than 1500 m. The Cretaceous, and began in 1948 with the arrival of a team of researchers
most of the Tertiary, lies upon a basement of red beds from the Carnegie Institution (Hare et al. 2014). Nowa-
from the Triassic-Jurassic and igneous rocks from the Tri- days, researchers focus their efforts on long-term studies
assic and Paleozoic. The surface sedimentary rocks span at the ancient city by documenting the regional system of
from the Upper Cretaceous to the Holocene, and are gen- settlement and the environment in which it was developed.
erally almost horizontally layered and off-lapping, with As a result, they have created a bare earth digital eleva-
gradually younger carbonates deposited toward the Penin- tion model of a 40 km2 area centered on the walled city
sula margins. Lithological columns from the site UNAM- of Mayapán using LiDAR-generated data, ground survey,
2 (U2) drill site present this sequence from surface to surface collection, test excavations, artifact analysis, and
bottom: 1.7 m of soil and caliche followed by 85 m of Geographic Information System–aided spatial analysis.
dolomitized crystalline limestone with 14 m of intercalated Underwater archeology presents some interesting
dolomitized calcarenite, 95 m of fossiliferous dolomitized results 2 km far from our study site. Detailed underwater
crystalline limestone, 10 m of argillaceous limestone and mapping, photography, and video of the cenote Sac
finally another 10 m of dolomitized crystalline limestone Uayum shows two 15-m-deep chambers connected by a
(Rebolledo-Vieyra et al. 2000). Our study zone is located narrow passage about 10 m long. The remains of human
crania, bones, and ceramic fragments were clustered in coordinates for the 11 cenotes of interest (Figure 2). Table
the southwest end of the first chamber (Russell 2017). S1, supporting information, shows the cenote labels and
With all of the aforementioned, our main working their coordinates.
hypothesis is that the RC is originated and structurally
controlled by the faults and joints generated by the ERT Measurements
gravitational accommodation of the Chicxulub Crater rim In this particular case, we used ERT to identify
(Gulick et al. 2008). Based on this, we developed a macroscale porosities (> 3 m diameter). Our main goal
conceptual model for the conduits and connections. The was to identify conduits larger than 3 m with a high
model assumes that the vertical faults and joints are likelihood of connecting sinkholes. For this task, ERT is
continuous structures, no larger than 3 × 3 km. We also a very effective tool. The spatial set up of the transects
hypothesize that this is a fault and joint system, where (labeled T1, T2,...,T8) was designed considering the
the surface expression of them are nearly parallel. The accessibility to the field, using trails already available
latter accounts for the connection along the RC, and, in and patches free of vegetation. The next consideration
a lesser degree, to the connections perpendicular to the was to position the transect in a way that would intercept
main trace of the RC. the imaginary line connecting one cenote to another. For
example, T7 intercepts an imaginary line from cenote
nine to cenote one and from cenote nine to cenote
Research Method seven. Transects: T1, T2, T5, T6, and T7 were laid
out on existing trails, while for T3, T4, and T8, it was
Cenote Selection necessary to clear the vegetation. There was an overlap
We selected the study zone based on the database among transects T1, T2, and T3 with the purpose of
provided by the Yucatán Government (SEDUMA 2016) reducing the edge effects. In Table S2, we show the
which satisfies the conditions of being in the RC and geographic coordinates for the first and the last electrodes
presenting a high density of cenotes. The zone chosen of each transect. The final setup of the transects and
is 40 km southeast from Mérida, in the ancient city cenotes is shown in Figure 3. The area in which the
of Mayapán. The original Carnegie map of Mayapán transects and cenotes are located has an approximate size
(Jones 1962) and a map shared by Dr. Russell (Russell of 600 m × 800 m. ERT imaging surveys were conducted
®
2017) played an important role in our specific selection using the AGI SuperSting R1/IP (Advanced Geosciences
of sinkholes. We used a Global Positioning System Inc., Austin, Texas) acquisition system. The 345-m
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Trimble (Sunnyvale, California) Recon 400X to aquire stationary cable consisted of 71 electrodes spaced 5 m
(Advanced Geosciences Inc.). We applied a common scale with α = γ /λ, where λ = 181.05 m is the average distance
of colors to the eight inverted resistivity sections. In between the nodes in the network; by assumption
Figure 4, the color scale and the corresponding resistivity D(3000 m) = 0.01, then, solving for γ we get γ = 0.277.
are displayed. This assumption is based on geophysical observations:
Gulick et al. (2008), reported faults within the Chicxulub
Water Cavity Determination crater rim, where the study area is located, up to 3 km
The ERTs were performed to obtain information deep, from ground surface. From this, we assigned a
on possible underground water cavities which connect square shape to the fault’s geometry, with a 3 × 3 km side.
cenotes. The water in the region studied has a resistivity In Pope et al. (1991), we also found that the cenote density
between 6 and 12 ohm-m (Pérez-Ceballos et al. 2012) and width of the ring vary from about three cenotes per
but since the inversion process introduces a degree of km2 along a 3 km-wide portion in the southwest, to a chain
uncertainty, we consider a larger range for the resistivity: of single cenotes 3 km apart in the southeast.
1 to 47 ohm-m. Later in the paper, we will see evidence The second function is in terms of the weighted area
for 23 water cavities. The cross-sectional area for each of the cavities Z = Z (t),
cavity was calculated as:
A (Z) = 1 − e−βZ (t) (6)
5
Z= Wi Ai (4) with β = η/τ , where τ = 81.34 m2 is the average weighted
i=1 area for all the cavities; by assumption A(56 m2 ) = 0.5,
then, solving for η we get η = 1. This assumption is based
where Ai is the area of the cavity with color ai (Figure 4)
on personal observations in the field that show the radius
and W i is the weight that represents the percentage of
of cenotes in this study area is approximately 4 m.
water contained in a material with resistivity ai. We
In this way, when we considered cenote (s)—water
use previous studies as a reference (Telford et al. 1990;
cavity (t), q i = q(s, t) is calculated as
Bauer-Gottwein et al. 2011) to assign the following values
for W : W 1 = 0.8, since this is typical for saline water;
q (s, t) = e−αX (s,t) 1 − e−βZ (t) (7)
W 2 = 0.9, because in this resistivity range (3 to 6 ohm-
m), most of water is saturated with salt; W 3 = 1.0,
this is the resistivity for free water in the cenotes In the case water cavity (s)—water cavity (t). The
(Pérez-Ceballos et al. 2012); W 4 = 0.5 and W 5 = 0.3, equation takes the form
correspond to water trapped in rocks with different
densities. q (s, t) = e−αX (s,t) 1 − e−βZ (s) 1 − e−βZ (t) (8)
The 138 tuple of values of q i conform the compo- of uncertainties. Figure 5 shows the eight transects and
nents of the reliability vector q. Once we obtain q, the net- the positions of the 23 cavities that were found. The
work is divided into six clusters or subnetworks (Figure 6) comparison between the color hues (Figure 4) allowed us
and we applied the reliability algorithm to each of them to to identify the non-saturation zone (red-yellow with resis-
calculate the final probability g(q) of connection. In sum- tivities of 1529 to 100,000 ohm-m) and the saturated zone
mary, the network reliability algorithm indicates that the (1 to 47 ohm-m). The range between 47 and 1529 ohm-m
probability of connection between two network nodes s is associated with fractured limestone (Telford et al.
and t over one specific path is the product of the probabil- 1990). The water level was 14 m deep with respect to
ities that each node is connected with the next one in that the terrain level. This was based on measurements made
path. Afterward, it is necessary to sum these probabilities on cenotes with wide surface openings, using a portable
over every possible path between s and t. electronic water level meter. However, it was not possible
The two adjusted parameters γ and η can be to do this with every cenote. With the others, we had to
updated once more information is obtained from the substitute indirect estimates from ERT, uncorrected for
system. Figures S1 and S2 illustrate the variability of topography. Figure 5 shows that most of the underground
the Euclidean norm of the reliability vector, as measured water lies at a depth range of 12 to 20 m.
by the difference ||q− q ||, under changes in our geological The transects T1, T2, T3, T4, T5, and T7 indicate
suppositions. possible water flux in the east to west direction (Figure 3);
this observation gives strength to the hypothesis of
circulation flux in the RC direction (Bauer-Gottwein et al.
Results 2011).
We perform a contact resistance test prior to each To use Equation 5, coordinates of the cenotes were
ERT survey. Transects T1, T2, T3, T5, T7, and T8 passed used, as in Table S1. The coordinates of the geometrical
the test (<2000 ohm-m). However, 20% of the contact center of each water cavity was calculated from the
resistance values in T4 and T6 were high. These two transect to which it belongs, using the first electrode of
transects were installed on exposed limestone bedrock. the transect as a spatial reference. The results are given in
We kept the data since they contribute significantly to the Table S3. For Equation 6, we calculated the weighted area
analysis, but keeping in mind the possible introduction Z (Equation 4) of each water cavity (Table 1). Finally,
Table 1 Table 2
Weighted Area (Z ) of the Water Cavities Connecting Probabilities Between Cenotes that
Belong to Clusters 1, 2, and 3.
Water Cavity Z (m2 ) Water Cavity Z (m2 )
Cluster Cenotes g(q)
12 7 24 19
13 52 25 12 1 {1, 7} 0.875
14 92 26 125 {1, 8} 0.877
15 131 27 106 {1, 9} 0.878
16 7 28 61 {7, 8} 0.861
17 36 29 68 {7, 9} 0.873
18 50 30 9 {8, 9} 0.870
19 23 31 310 2 {2, 4} 0.594
20 62 32 28 {2, 5} 0.575
21 157 33 96 {2, 7} 0.003
22 296 34 107 {4, 5} 0.672
23 15 {4, 7} 0.004
{5, 7} 0.003
3 {2, 3} 0.581
{2, 6} 0.669
we used Equations 7 and 8 (depending on the case) to {2, 11} 0.615
determine the q values. {3, 6} 0.661
The 34 nodes, 138 links, and 6 clusters are presented {3, 11} 0.537
in Figure 6. Cenotes are the nodes in red (1 to 11) {6, 11} 0.688
and, water cavities are the nodes in blue (12 to 34).
Cluster 1 is composed of nine nodes of which nodes 1, 7, 8, and 9 are cenotes.
To reduce computational effort, and according to our Cluster 2 is composed of 10 nodes of which nodes 2, 4, 5, and 7 are cenotes.
principal interest, the network was divided into six clusters Cluster 3 is composed of 11 nodes of which nodes 2, 3, 6, and 11 are cenotes
(subgraphs); this does not modified our findings. (Figure 6).