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MODULE 1: DENTAL MATERIALS • 1976 – Glass-Ionomer cements are invented by

A. Wilson.
❖ is the study of the physical and chemical
properties of the metallic and non-metallic • 1978 – light activated composites appear on the
materials used in Dentistry. market.
SCOPE • 1983 – Horn introduces the resin – bonded
ceramic veneer.
❖ Restorative
• 1985 – development of dentine bonding agents.
❖ Operative DENTISTRY
• 1988 – introduction of resin – modified glass
❖ PROSTHODONTIC DENTISTRY
ionomer cements.
Milestones in the history of Dental Materials • 1994 – first compomer apears on market.
• 600 BC – Etruscan gold bridge work.
SPECIFICATION
• AD 148 – First authentic records of gold
❖ Specific requirements including the test method
• filling in human teeth by Johannes Arculanus, for controlling the quality of the various types of
University of Bologna. dental materials

• 1500s – Ivory dentures begin to be covered from IMPORTANCE:


wax models. ❖ help to ensure the health and safety of both the
• 1729 – Fauchard proposes the used of porcelain. dental patient and dental professional by setting
the requirements that will deliver consistent
• 744 - Duchateau makes the first recorded quality and effectiveness.
porcelain denture.
Specification centers:
• 1826 – Taveau of Paris suggest the use of silver
and mercury to make a paste of filling teeth. • NBS (Dr. wilmer Souder, 1927)

• 1839 – the first dental journal, called the • FDI (1st international, 1953)
American journal of dental science. • ADA
• 1840s – ‘ Amalgam War’ the used of silver • PDA
amalgam is forbidden.
• ISO (Int’l Organization for
• 1850 – Charles Goodyear invents vulcanite Standardization,1963)
(sulfur hardened rubber).
• JIS
• 1879 – the first cement to set in the BSS
mouth, zinc phosphate, is introduced. AS
• 1880’s – silicate cements are developed. Etc.....

• 1895 – G.V. Black publishes the first detailed Dr. wilmer Souder, 1935
study of the properties of amalgam. HARDNESS TEST
• 1907 – W.H. Taggart of Chicago invent a ❖ A number on a calibrated scale indicating the
practical method of casting gold alloys. relative hardness as determined by a particular
• 1950s – introduction of acrylic resin for fillings system of testing
and dentures. ❖ BHN – BRINELL’S HARDNESS NUMBER
• 1955 – Buonocore discovers the acid etch TEST
technique for bonding to enamel. VHN – VICKER’S HARDNESS NUMBER
TEST
• 1970 – composite begin top replace silicate
cements. ❖ KNOOP’S HARDNESS TEST
❖ MOH
❖ ROCKWELL
PROPERTIES OF DENTAL MATERIALS

• PhysIcal
• Chemical
• Thermal
• BioloGIcal
• Optical
• Mechanical
• Electrical
MECHANICAL PROPERTIES

• STRENGTH
• TOUGHNESS
• HARDNESS
• PLASTICITY
• ELASTICITY
MP– Behavior of a material under the action of external
forces called LOAD.
LOAD - The force applied that tends to produce an
effect, deformation or displacement of a structure.
STRESS - An internal force that resist the load.
STRAIN - A change in dimension. The ratio of a change
in dimension to its original body or size.
HARDNESS TEST

• A number on a calibrated scale indicating the


relative hardness as determined by a particular
system of testing

• BHN – BRINELL’S HARDNESS NUMBER


TEST
VHN – VICKER’S HARDNESS NUMBER
TEST

• KNOOP’S HARDNESS TEST

• MOHs hardness test

• ROCKWELL hardness test


MODULE 2: GYPSUM PRODUCTS. 12. WATER/RATIO - refers to the quotient
obtained when the volume of water is divided by
• A mineral mined found in various parts of the world, the weight of the powder.
the mineral used for dental purposes is pure calcium 13. WORKING TIME- the time available to use a
sulfate dihydrate (CaSO4.2H2O) workable mix, one that maintains a uniform
• Gypsum products used in dentistry are formed by consistency to perform one or more tasks. It is
driving off part of the water of crystallization from measured from the start of mixing to the point
gypsum to form calcium sulfate hemihydrate. 14. WORKING TIME- the time available to use a
• As the temp. further raised, it becomes anhydrite. The workable mix, one that maintains a uniform
process is known as calcination consistency to perform one or more tasks. It is
measured from the start of mixing to the point
where the consistency is no longer acceptable for
the product’s intended purpose.

DEFINITION OF TERMS: DENTAL GYPSUM

1. CAST- a reproduction of the shape of a structure


made in an impression of the surface
2. MODEL- a positive likeness of an object CALCINATION
3. DIE- A reproduction of a prepared tooth made
from a gypsum product, epoxy resin, a metal, or • It is the process of heating gypsum to remove
refractory material. parts of the water of crystallization
4. DENTAL PLASTER - (Plaster of Paris)- the
beta form of calcium hemihydrate Gypsum PHYSICAL CHARACTERISTIC
5. DENTAL STONE- the alpha form of calcium
sulfate hemihydrate • Color is usually white, colorless or gray,
6. SETTING EXPANSION- increase in volume
accompanying the hardening of a material. can also be shades of red, brown and yellow
7. CALCIUM SULFATE DIHYDRATE-
composition of a gypsum product such as • Luster is vitreous to pearly
plaster, once it has been mixed with water.
8. CALCIUM SULFATE HEMIHYDRATE - • Crystal System is monoclinic
composition of unreacted particles of gypsum.
9. ACCELERATOR- the chemical that increases • Crystal habits include the tabular, bladed
the rate of a chemical reaction so that reaction or blocky crystals with a slanted
can occur within a particular period of time parallelogram outline
10. RETARDER- the chemical that decreases the
rate of chemical reaction to allow for a longer • Fracture is uneven but rarely seen.
working time
11. SPATULATION- a term used to describe the by • Hardness - can be scratched by a fingernail.
hand or mechanically of a material.
• Specific Gravity is approximately 2.3+
• Hardens by chemical reaction ❖ Type V – Die stone (high strength; high
expansion
• Associated Minerals: halite, calcite,
sulfur, pyrite, borax and many others.
- Densite or modified hemihydrate
• low thermal conductivity - Dehydrated in a boiling solution of 30%
calcium chloride in a kettle
• Notable Occurances include Naica, Mexico;
• Sicily; Utah and Colorado, USA; and many
other locallities throughout the world.
DENTAL PLASTER
• also called Beta Hemihydrate
• Obtained by heating it in a kettle in open air at a
temperature of 110 – 1200C.
• Irregular shaped crystals
• has a Bigger particle size
• Spongy or porous in character Setting Time
• Needs more water during mixing • The powder is mixed with the water, the time
elapsing from the beginning of mixing until the
• Weaker
material hardens.
DENTAL STONE
• the length of time it takes for the materials to
• Alpha hemihydrate harden from the beginning of mixing.

• Obtained by heating gypsum under a steam- • Initial setting time – “starts”


pressure in an autoclave at a temperature of 120
• Final setting – “completely”
- 1300C
Initial setting time:
• Prismatic shaped crystals
• It refers to the start of mixing until it starts to harden
• Compact or dense
• - 5 to 10mins. for plaster
• Smaller particle size
• - plaster loses its glossy appearance
• Needs less water
• and is hard enough to hold for carving.
• Stronger
• - 8-10 mins. for stone
GYPSUM PRODUCTS
Final setting time:
❖ Type I - Impression Plaster - Contain potato starch to
render them soluble • It refers to the time when the dental plaster has
❖ Type II - Dental plaster - (beta hemihydrate) completely hardened.
- 110-120C (230-250F) To drive off part of the
water of crystallization • - approximately 25-45 mins.
❖ Type III – Dental Stone
- Calcined under steam pressure in an autoclave at • - achieves a dry, hard condition.
a temp. of 120-130 C (250-265 F) 3 Methods of determining the Setting Time
- Dehydrated in an autoclave in the presence of
sodium succinate 1. Use of Vicat Needle
❖ Type IV – Die stone (high strength; low expansion)
2. Use of Gillmore Needle
3. Loss of Gloss Method
Factors Affecting Setting Time CHEMICAL PROPERTIES

• Fineness  A chemical property is a characteristic of a


particular substance that can be observed in a
• Impurities chemical reaction.
• Water-powder ratio E.g. Some major chemical properties include
• Mixing flammability, toxicity, heat of combustion, pH value,
rate of radioactive decay, and chemical stability.
• Temperature
Chemical Properties: Sorption
• Use of chemical modifiers
• Adsorption
• Accelerators
- process in which atoms, ions or molecules from
• Retarders a substance (it could be gas, liquid or dissolved solid)
SETTING EXPANSION
adhere to a surface of the adsorbent.

• Expansion occurs by the growth of crystals during the • Absorption


crystallization process
- substances enter the bulk phase of a liquid or
Types of setting expansion solid.
1. Thermal BIOLOGICAL PROPERTIES
2. Normal
3. Hygroscopic  The ability of a biomaterial to elicit or modulate
a favorable response (“activity”) from any part
Spatulating Gypsum of a biological organism.
• Hand Spatulation:  The degree to which a material may permanently
destroy or impair of any part of a biological
• One Direction at 90 revs/min.
organism.
• Mechanical spatulation
e.g. Toxicity
• Air bubbles may be eliminated by:
MECHANICAL PROPERTIES
• Allowing the plaster to dissolve in water before
 physical properties that a material exhibits upon
mixing
the application of forces. Examples of
• Tapping or vibrating the mixture. mechanical properties are the modulus of
elasticity, tensile strength, elongation, hardness
• Using a mechanical vibrator or spatula. and fatigue limit.
PROPERTIES OF DENTAL MATERIALS
e.g.
 PHYSICAL
Load
 CHEMICAL
• Force applied that tends to produce an effect,
 BIOLOGICAL deformation or displacement of a structure.
• Force tending to cause deformation of a material
 MECHANICAL by slippage along a plane or planes parallel to
 ELECTRICAL the imposed stress.

PHYSICAL Stress

 a characteristic of matter that is not associated • An internal force that resist the load
with a change in its chemical composition.
Strain
 Density, color, hardness, melting and boiling
• a change in dimension. The ratio of a change in
points, and electrical conductivity
dimension to its original body or size
MECHANICAL PROPERTIES 2. Insulator- a substance or device which does not
readily conduct electricity
Stress:
3. Electrical conductivity- the degree to which a
• Tensile specified material conducts electricity.
• Compressive 4. Galvanism- effect of electric potentials in the
• Shear mouth as a result of the use of dissimilar metals
as restorative materials.
Strain: 5. Melting point- the temperature at which a given
• Tensile solid will melt
• Compressive 6. Freezing point- the temperature at which a liquid
• Shear turns into a solid when cooled.
7. Dew point- the temperature (varying according
Flexural Strength to pressure and humidity) below which water
droplets begin to condense and dew can form.
- the ability of the material to withstand bending
8. Heat of fusion- measures the amount of energy
forces applied perpendicular to its longitudinal
needed to melt a given mass of a solid at its
axis. E.g. composites Measured in MR (Modulus
melting point temperature.
of rupture) in MPa
9. Heat of vaporization-heat absorbed when a
Impact Strength liquid vaporizes.
10. Thermal conductivity- quantity of heat
- also called impact toughness – is the amount of transferred per second across a unit area (cm3)
energy that a material can withstand when the and a unit length (cm) when a temperature
said load is suddenly applied to it. difference along the length is 1◦ C/cm.
Hardness 11. Coefficient of thermal expansion- thermal
property of a material that quantifies how much
- surface property. a material will expand when it is heated and
- e.q. Scratches, abrasion, erosion contract when it cools.
12. Thermal diffusivity- a measure of the speed with
Toughness
which a temperature change will proceed
• bulkiness through an object when one surface is heated.
• e.q. Fracture, Elongation, Compression 13. Colour-sensation is induced by lights of varying
wavelengths reaching the eye.
Ductility 14. Value- the lightness of, or relative amount of
• a metal's ability to withstand stress without light reflected from, a colour
rupturing, but opposite in terms of the type of 15. Hue- the dominant colour of an object.
stress being applied 16. Chroma- relative intensity of the colour of an
• tensile stress object.
17. Rheology- the study of the deformation and flow
Malleability characteristics of matter.
18. Transparency- the extent to which light passes
• a metal's ability to withstand stress without
through a material and to which an undistorted
rupturing, but opposite in terms of the type of
image can be seen through it.
stress being applied
19. Translucency- relative amount of light
• Compressive stress
transmitted through an object.
CANVAS/CEU LEAPS 20. Creep – the gradual dimensional change of a
material under a load or stress. In some materials
M1 L2: PROPERTIES OF DENTAL MATERIALS (like amalgams) as a result of the occlusal load
• PHYSICAL PROPERTY: over a long period of time.
1. Conductor- is a substance in which electric 21. Flow- to describe the rheology of amorphous
charge carriers, usually electrons, move easily materials
from atom to atom with the application of 22. Dilatant- liquids show an increase in viscosity as
voltage. the shear rate goes up.
23. Viscosity- the resistance of a liquid to flow 6. Mutagen- physical, chemical or biological agent
24. Viscoelasticity- materials show behaviour that is that causes mutation by altering the genetic
intermediate between that of a viscous liquid and material possibly results in the disease condition.
that of an elastic solid
25. Thixotropic- the property of a material that MECHANICAL PROPERTY
results in low flow under low load but flows 1. Force- push or pull of an object
readily when placed under load. 2. Stress- force per unit area
3. Strain- deformation per unit length
CHEMICAL PROPERTY
4. Tensile- capable of being drawn or stretched
1. Sorption- is a physical and chemical process to 5. Compressive- the act of compressing or being
which one substance becomes attached. compressed
2. Adsorption- concentration of molecules at a 6. Shear- the ratio of a shear force to the original
surface of a solid or liquid cross-sectional area parallel to the direction of
3. Absorption- the extent to which light is absorbed the applied force
by the material in an object. 7. Flexural- the act or an instance of bending or
4. 5. Diffusion- is the net movement of anything flexing
from a region of higher concentration to 8. Elastic deformation- the material returns to its
a region of lower concentration. original shape when the force is removed.
5. 6. Osmosis- a process by which molecules of a 9. Plastic deformation- the material does not return
solvent tend to pass through to its original shape when the force is removed.
a semipermeable membrane from a less 10. Young’s modulus- called elastic modulus or
concentrated solution, into a more concentrated modulus of elasticity, measures the elastic strain
one. or plastic strain behaviour of dental materials.
6. Solubility- the ability to be dissolved 11. Dynamic Young’s modulus- determined by the
7. Erosion- irreversible loss of dental hard tissue measurement of ultrasonic wave velocity
from acids, without the involvement of bacteria. 12. Shear modulus- also called as modulus of
8. Adhesion- A molecular or atomic attraction rigidity
between two contacting surfaces promoted by 13. Flexibility- the quality of bending easily without
interfacial force of attraction between the breaking
molecules or atoms of different species. 14. Resilience- the amount of elastic energy per unit
9. Cohesion- the force of molecular attraction volume that is sustained on loading and released
between molecules or atoms of the same species. upon uploading a test specimen.
10. Surface Energy is a term used to describe the 15. Poisson’s ratio- describes the expansion or
surface of a given substrate. contraction of material in a direction
11. Wetting- spreading of a liquid over a solid perpendicular to the direction of loading
surface. 16. Flexural strength- also called bending strength or
modulus of rupture; force per unit area of a
BIOLOGICAL PROPERTY
material that is subjected to flexural loading
1. Biomaterials-any matter, surface or construct 17. Impact strength-defined as its capability to resist
that interacts with biological systems a sudden applied load or force.
2. Biomechanics- the study of the mechanical laws 18. Toughness- the ability of a material to absorb
relating to the movement or structure of living elastic energy and deform plastically before
organisms fracturing.
3. Biocompatibility- the appropriate biologic 19. Resilience-associated with springiness
response of the body to a material used in a 20. Fracture toughness- the critical stress intensity
specific application. factor at the point of rapid crack propagation in a
4. Toxicity- the quality of being toxic or poisonous solid containing a crack of known shape and
5. In vitro test- refers to the technique of size.
performing a given procedure in a controlled 21. Ductility- relative ability of a material to
environment outside of a living organism. elongate plastically under tensile stress.
22. Malleability- ability to be hammered or
compressed plastically into thin sheets without
fracture.
23. Brittleness- the relative inability of a material to
deform plastically before it fractures.
24. Proportional limit-magnitude of elastic stress
above which plastic deformation occurs
25. Elastic limit- the maximum extent to which a
solid may be stretched without permanent
alteration of size or shape.
III. Biological Property
26. Ultimate tensile strength- the maximum stress
that a material can withstand while being • The ability of a material to elicit an appropriate
stretched or pulled before breaking. biological response in a given application in the
body.
SCOPE OF THE COURSE
• The science of dental materials is generally
considered to comprise those materials which
are employed in the mechanical procedures
included in restorative dentistry, such as
prosthetics, crowns and bridges.
ADA SPECIFICATION
• It contains requirements for mechanical, IV. Mechanical Property
physical, biological and chemical properties of
the materials which will ensure their quality • A physical science that deals with energy and
and usefulness to the dentist. forces and their effects on bodies.

I. Physical Property

• Physical properties are based on the laws of


mechanics, acoustics, optics, thermodynamics,
elasticity, magnetism, radiation, atomic structure
or nuclear phenomena.

• Contents:

II. Chemical property


• A characteristic of a substance that may be
observed when it participates in a chemical
reaction.
MODULE 3 – WAXES Mineral origin

• Waxes are thermoplastic materials that are solids at ➢ Paraffin – obtained from high boiling point fractions
room temperature and soften or become low viscosity of petroleum; melting temperature generally increases
liquid when subjected to moderate temperatures. In with increasing molecular weight;
dentistry, waxes are versatile materials that are used ➢ Microcrystalline - similar to paraffin, except they
are obtained from the heavier oil fractions in the
both in clinics and laboratories. Certain procedures
petroleum industry, as a result, have higher melting
cannot be completed without the use of wax in one of
points
its many forms. Dental waxes are used for specific ➢ Ceresin – used to increase the melting range of
and well-defined applications. paraffin waxes; higher molecular weight

Plant origin

➢ Carnauba – occurs as a fine powder on the leaves of


certain tropical palms; this wax is very hard, and high
melting point; contributes greater glossiness to the
wax surface
➢ Candelilla – can be added partially or entirely to
replace carnauba wax; provides the same general
quali3es as carnauba but its melting point is lower
and not as hard
• Dental wax is a mixture of two or more waxes with
➢ Cocoa butter – not a true wax; chiefly fats; brittle at
other additives, used in dentistry for casts,
room temperature; used to protect the soft tissues
construction of nonmetallic denture bases, registering
against dehydration and to protect the glass ionomer
of jaw relations, and laboratory work.
from moisture during setting or protect them from
COMPOSITION: dehydrating after setting

• Dental waxes may be composed of natural and Animal origin- Spermaceti wax
synthetic waxes, gums, fats, fatty acids, oils, natural ➢ obtained from sperm whale, used as coa6ng in the
and synthetic resins, and pigments. manufacture of dental floss
• The particular working characteristics of each wax
are achieved by blending the appropriate natural and Insect origin – Beeswax
synthetic waxes, resins, and other additives.
➢ brittle at room temperature but Becomes plastic at
NATURAL WAXES: body temperature; modifies properties of paraffin
wax; Main component of sticky wax
• Natural waxes are distributed in nature, derived from
mineral, vegetable/plant, and animal (insect) Synthetic Waxes
origins. Whereas synthetic waxes are produced by a
➢ Complex organic compounds of varied chemical
combination of various chemicals in
composition
the laboratory, from natural wax molecules and are
➢ High degree of refinement in contrast to
typically composed of hydrogen, carbon, oxygen, and
contamination seen in natural waxes
chlorine.
➢ Include:
• The additives may be natural mineral and synthe3c
- Polyethylene waxes
products.
• A.) Natural - Mineral, Plant, Animal/Insect - Polyoxyethylene glycol waxes
• B.) Synthetic - Halogenated hydrocarbon
- Hydrogenated waxes
Coloring agents are added for the contrast of wax patterns
against the tooth, die, and model surfaces. Other Substances Related to Wax

• Gums - Many plants produce a variety of gums


that are viscous, amorphous exudates that harden
on exposure to air
• Fats – used to increase the melting range and
hardness of compounded wax
• Resins – are obtained from trees and plants;
shellac, however, is from insects. Natural resins
are blended with waxes to develop waxes for
dental applications.
Properties of Dental Waxes

Melting range - Waxes consist of several types of molecules,


each having a range of molecular weight, hence they have
melting ranges rather than melting points

Flow

➢ Change of shape or dimension in response to the


applied force
➢ Caused by slippage of chained wax molecules over
each other Pattern Waxes- Inlay wax

Thermal expansion  Inlay waxes are used to prepare patterns


 Classification:
➢ The coefficient thermal expansion of inlay waxes is ✓ Type I (medium) - used for direct technique
high. Waxes expand when subjected to a rise in ✓ Type II (soft) - used for indirect technique
temperature and contract as the temperature is ✓ Available as: blue, green, purple sticks
decreased ✓ 7.5 cm long, 6 mm diameter
Thermal conductivity Desirable properties
➢ The thermal conductivity of waxes is low, which ➢ should soften uniformly
implies that these materials gain, and lose, heat very ➢ colour should contrast the die material
slowly. Sufficient time must be allowed both to heat
➢ no flakiness / rough surface
them uniformly throughout and to cool them to body
➢ melts completely without residue
or room temperature
➢ rigid, and dimensionally stable
(To know more about dental waxes, read the chapter on Dental
Waxes, from Phillip's Science of Dental Materials.12th ed. Kenneth J.  Inlay waxes may be softened over a flame or in water
Anusavice,2013.) 54 to 60 degrees celsius to enable their flow in the
liquid state and their adaptation to the prepared tooth
➢ The wide variety of dental waxes is classified into
or die.
two groups, those used primarily in the clinic and
those used in commercial laboratories.  Type I inlay wax must soften at a temperature that is
not hazardous to the pulp tissue, and it must harden at
a temperature above mouth temperature
 Direct wax technique: A wax pattern made in the
mouth for producing wax inlay patterns within the
prepared teeth
 Indirect technique: The cavity is prepared in the
tooth and the wax pattern is carved directly on a die
that is a reproduction of the prepared tooth and dental
TYPES / CLASSIFICATION tissues
➢ Pattern wax - used to form the general Wax Distortion
predetermined size and contour of artifial dental
restoration, which is to be constructed of a durable ➢ Wax distortion is probably the most serious problem
material. that can occur during forming and removal of the
- Inlay wax pattern from the mouth or die.
- Casting wax ➢ Distortion results from thermal changes and the
- Baseplate wax relaxation of stresses that are caused by contraction
➢ Processing wax - used primarily as auxillary aid in on cooling, molding, carving, removal and the time
the construction of variety of restorations and and temperature of storage.
appliances either clinically or in the laboratory ➢ Waxes tend to return partially to their original shape
➢ Impression wax – used to obtain impressions of after manipulation. The property responsible for this
phenomenon is known as “elastic memory”
oral structures
- Corrective impression wax Pattern Waxes – Casting wax
- Bite registration wax
➢ The patterns for metalic framework of RPD’s asr
fabricated from casting waxes.
➢ Ready made shapes - round, halfround, half pear IMPRESSION WAXES
shaped rods and wires of various gauges.
➢ Highly ductile and posses a slight degree of tackiness
which helps to maintain the position on the cast as
well as on earther during assembling the patterns.

Pattern Waxes- Baseplate wax

➢ Baseplate wax is used to establish the vertical


dimension, plane of occlusion, and initial arch form
in the technique for complete denture
➢ Patterns for orthodontic appliances and prostheses
other than complete dentures, which are to be
constructed of acrylic resin also are made of
baseplate wax
➢ normally pink or red in color IMPRESSION WAXES – Corrective wax

PROCESSING WAXES ➢ wax in combination with resins of low melting point


can be used in corrective impression technique in
partial and complete denture prosthesis
➢ the peculiarity of impression wax is that they flow at
mouth temperature
➢ available in sheets or cakes
➢ uses: as a veneer over an original impression to
contact and register the details of the soft tissues

IMPRESSION WAXES – Bite (occlusal) wax

➢ It is used to record the relationship of the upper and


lower teeth in dentulous patients
➢ wax is softened under hot water

Manipulation of Waxes

Processing Waxes – Boxing wax

➢ Usually consists of, narrow stick or strip of wax


around the impression below its peripheral height,
followed by a wide strip of wax, producing a form
aroung the entire impression
➢ Slightly tacky and have sufficient strength and
toughness for convenient manipulation

Processing Waxes – Utility wax

➢ Supplied as stick and sheet form in dark red or


orange.
➢ It’s is pliable which makes it workable and adaptable
at room temperature
➢ It used for extending borders of impression trays

Processing Waxes – Sticky wax

➢ This material is sticky when melted and adheres


closely to the surfaces on which it is applied. At room
temperature, the wax is firm, free from tackiness, and
brittle
➢ It is used to assemble metallic or resin pieces in a
fixed temporary position, used primarily on dental
stones and plaster
➢ used to join pieces in case of repair of dentures
MODULE 4: Six IMPRESSION MATERIALS ❖ Stearin and Kauri resin

1. Impression Plaster ❖ French Chalk


2. Impression Compound
❖ Coloring ingredient
3. Reversible Hydrocolloid
4. Irreversible Hydrocolloid Properties
5. Zinc Oxide Eugenol Impression paste
6. Elastomeric Rubber Impression Flow

CLASSIFICATION: - Flows easily

❖ According to the manner in which they harden Thermal Conductivity


✓ Physical
- Low
✓ Chemical
✓ Thermoplastic Distortion

❖ According to their use in Dentistry - relaxation occurs


✓ For Edentulous mouth Viscosity:
✓ For non-edentulous mouth
- most viscous of impression material
❖ According to the state and condition
✓ Rigid Requisites of Impression Compound
✓ Flexible ➢ It should be free of poisonous or irritating
IMPRESSION PLASTER ingredients.

COMPOSITION: ➢ Harden completely at, or slightly above, mouth


temperature
❖ Plaster of Paris
❖ Chemical Modifiers ➢ It should be plastic at a temperature which will not
- regulates setting time cause undue discomfort to the patient
- controls setting expansion ➢ Should harden uniformly when it is cooled without
Potato starch warpage or distortion

❖ renders the impression plaster soluble in warm water ➢ When it is soft, the material should have a
❖ facilitates easy removal of cast from the impression consistency which will allow it to reproduce all
details of crevices and other small markings, and to
Flavoring retain such detail after solidification.

❖ makes the impression plaster palatable ➢ It will not be deformed or fractured and reproduce all
undercuts completely when impression is withdrawn
Coloring from the mouth
❖ for easy identification of the impression from the cast ➢ Should exhibit a smooth, glossy appearance surface
❖ color: pink after being passed through a flame
Scent ➢ After solidification, must withstand trimming with a
Properties: sharp knife without flaking or chipping

❖ W/P ratio: 0.6 - 0.7 ➢ It should not change dimension during or after
❖ Setting time: 3-5 minutes removal from the mouth.
❖ Setting expansion: Lowest – 0.06% Types
IMPRESSSION COMPOUND • Type I - True Compound
❖ A thermoplastic material usually composed of gum Lower fusing
dammar and prepared chalk
• Type II - Tray Compound
Composition
Higher fusing
❖ Beeswax

❖ Burgundy Pitch, Shellac, Gutta Percha


Type 1

➢ Available as sheets, sticks, cylinders, cones.

➢ Sheets: for recording of edentulous ridge.

➢ Flow readily above mouth temperature

➢ Should be capable of recording sharp grooves

➢ Most viscous (mucocompressive)

TYPE 1: STICK

❖ Soften with flame; tempered in a water bath before


placing in the pt.’s mouth

❖ Used to refine or modify peripheral extent of special


tray for CD or edentulous region of RPD.

❖ For securing rubber dam retainer and occlusal


registration plate.

❖ Recording single crown preparation

TYPE II: TRAY COMPOUND

❖ For making impression tray


❖ Not distorted at mouth temperature
❖ Lacks dimensional stability and strength
❖ Thus, replaced by acrylics and plastics

Manipulation

1. Direct Flame - sticks

2. Use of Dry Heat – sheets, sticks

3. Use of Warm water bath – sheets, sticks

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