Professional Documents
Culture Documents
A. Wilson.
❖ is the study of the physical and chemical
properties of the metallic and non-metallic • 1978 – light activated composites appear on the
materials used in Dentistry. market.
SCOPE • 1983 – Horn introduces the resin – bonded
ceramic veneer.
❖ Restorative
• 1985 – development of dentine bonding agents.
❖ Operative DENTISTRY
• 1988 – introduction of resin – modified glass
❖ PROSTHODONTIC DENTISTRY
ionomer cements.
Milestones in the history of Dental Materials • 1994 – first compomer apears on market.
• 600 BC – Etruscan gold bridge work.
SPECIFICATION
• AD 148 – First authentic records of gold
❖ Specific requirements including the test method
• filling in human teeth by Johannes Arculanus, for controlling the quality of the various types of
University of Bologna. dental materials
• 1839 – the first dental journal, called the • FDI (1st international, 1953)
American journal of dental science. • ADA
• 1840s – ‘ Amalgam War’ the used of silver • PDA
amalgam is forbidden.
• ISO (Int’l Organization for
• 1850 – Charles Goodyear invents vulcanite Standardization,1963)
(sulfur hardened rubber).
• JIS
• 1879 – the first cement to set in the BSS
mouth, zinc phosphate, is introduced. AS
• 1880’s – silicate cements are developed. Etc.....
• 1895 – G.V. Black publishes the first detailed Dr. wilmer Souder, 1935
study of the properties of amalgam. HARDNESS TEST
• 1907 – W.H. Taggart of Chicago invent a ❖ A number on a calibrated scale indicating the
practical method of casting gold alloys. relative hardness as determined by a particular
• 1950s – introduction of acrylic resin for fillings system of testing
and dentures. ❖ BHN – BRINELL’S HARDNESS NUMBER
• 1955 – Buonocore discovers the acid etch TEST
technique for bonding to enamel. VHN – VICKER’S HARDNESS NUMBER
TEST
• 1970 – composite begin top replace silicate
cements. ❖ KNOOP’S HARDNESS TEST
❖ MOH
❖ ROCKWELL
PROPERTIES OF DENTAL MATERIALS
• PhysIcal
• Chemical
• Thermal
• BioloGIcal
• Optical
• Mechanical
• Electrical
MECHANICAL PROPERTIES
• STRENGTH
• TOUGHNESS
• HARDNESS
• PLASTICITY
• ELASTICITY
MP– Behavior of a material under the action of external
forces called LOAD.
LOAD - The force applied that tends to produce an
effect, deformation or displacement of a structure.
STRESS - An internal force that resist the load.
STRAIN - A change in dimension. The ratio of a change
in dimension to its original body or size.
HARDNESS TEST
PHYSICAL Stress
a characteristic of matter that is not associated • An internal force that resist the load
with a change in its chemical composition.
Strain
Density, color, hardness, melting and boiling
• a change in dimension. The ratio of a change in
points, and electrical conductivity
dimension to its original body or size
MECHANICAL PROPERTIES 2. Insulator- a substance or device which does not
readily conduct electricity
Stress:
3. Electrical conductivity- the degree to which a
• Tensile specified material conducts electricity.
• Compressive 4. Galvanism- effect of electric potentials in the
• Shear mouth as a result of the use of dissimilar metals
as restorative materials.
Strain: 5. Melting point- the temperature at which a given
• Tensile solid will melt
• Compressive 6. Freezing point- the temperature at which a liquid
• Shear turns into a solid when cooled.
7. Dew point- the temperature (varying according
Flexural Strength to pressure and humidity) below which water
droplets begin to condense and dew can form.
- the ability of the material to withstand bending
8. Heat of fusion- measures the amount of energy
forces applied perpendicular to its longitudinal
needed to melt a given mass of a solid at its
axis. E.g. composites Measured in MR (Modulus
melting point temperature.
of rupture) in MPa
9. Heat of vaporization-heat absorbed when a
Impact Strength liquid vaporizes.
10. Thermal conductivity- quantity of heat
- also called impact toughness – is the amount of transferred per second across a unit area (cm3)
energy that a material can withstand when the and a unit length (cm) when a temperature
said load is suddenly applied to it. difference along the length is 1◦ C/cm.
Hardness 11. Coefficient of thermal expansion- thermal
property of a material that quantifies how much
- surface property. a material will expand when it is heated and
- e.q. Scratches, abrasion, erosion contract when it cools.
12. Thermal diffusivity- a measure of the speed with
Toughness
which a temperature change will proceed
• bulkiness through an object when one surface is heated.
• e.q. Fracture, Elongation, Compression 13. Colour-sensation is induced by lights of varying
wavelengths reaching the eye.
Ductility 14. Value- the lightness of, or relative amount of
• a metal's ability to withstand stress without light reflected from, a colour
rupturing, but opposite in terms of the type of 15. Hue- the dominant colour of an object.
stress being applied 16. Chroma- relative intensity of the colour of an
• tensile stress object.
17. Rheology- the study of the deformation and flow
Malleability characteristics of matter.
18. Transparency- the extent to which light passes
• a metal's ability to withstand stress without
through a material and to which an undistorted
rupturing, but opposite in terms of the type of
image can be seen through it.
stress being applied
19. Translucency- relative amount of light
• Compressive stress
transmitted through an object.
CANVAS/CEU LEAPS 20. Creep – the gradual dimensional change of a
material under a load or stress. In some materials
M1 L2: PROPERTIES OF DENTAL MATERIALS (like amalgams) as a result of the occlusal load
• PHYSICAL PROPERTY: over a long period of time.
1. Conductor- is a substance in which electric 21. Flow- to describe the rheology of amorphous
charge carriers, usually electrons, move easily materials
from atom to atom with the application of 22. Dilatant- liquids show an increase in viscosity as
voltage. the shear rate goes up.
23. Viscosity- the resistance of a liquid to flow 6. Mutagen- physical, chemical or biological agent
24. Viscoelasticity- materials show behaviour that is that causes mutation by altering the genetic
intermediate between that of a viscous liquid and material possibly results in the disease condition.
that of an elastic solid
25. Thixotropic- the property of a material that MECHANICAL PROPERTY
results in low flow under low load but flows 1. Force- push or pull of an object
readily when placed under load. 2. Stress- force per unit area
3. Strain- deformation per unit length
CHEMICAL PROPERTY
4. Tensile- capable of being drawn or stretched
1. Sorption- is a physical and chemical process to 5. Compressive- the act of compressing or being
which one substance becomes attached. compressed
2. Adsorption- concentration of molecules at a 6. Shear- the ratio of a shear force to the original
surface of a solid or liquid cross-sectional area parallel to the direction of
3. Absorption- the extent to which light is absorbed the applied force
by the material in an object. 7. Flexural- the act or an instance of bending or
4. 5. Diffusion- is the net movement of anything flexing
from a region of higher concentration to 8. Elastic deformation- the material returns to its
a region of lower concentration. original shape when the force is removed.
5. 6. Osmosis- a process by which molecules of a 9. Plastic deformation- the material does not return
solvent tend to pass through to its original shape when the force is removed.
a semipermeable membrane from a less 10. Young’s modulus- called elastic modulus or
concentrated solution, into a more concentrated modulus of elasticity, measures the elastic strain
one. or plastic strain behaviour of dental materials.
6. Solubility- the ability to be dissolved 11. Dynamic Young’s modulus- determined by the
7. Erosion- irreversible loss of dental hard tissue measurement of ultrasonic wave velocity
from acids, without the involvement of bacteria. 12. Shear modulus- also called as modulus of
8. Adhesion- A molecular or atomic attraction rigidity
between two contacting surfaces promoted by 13. Flexibility- the quality of bending easily without
interfacial force of attraction between the breaking
molecules or atoms of different species. 14. Resilience- the amount of elastic energy per unit
9. Cohesion- the force of molecular attraction volume that is sustained on loading and released
between molecules or atoms of the same species. upon uploading a test specimen.
10. Surface Energy is a term used to describe the 15. Poisson’s ratio- describes the expansion or
surface of a given substrate. contraction of material in a direction
11. Wetting- spreading of a liquid over a solid perpendicular to the direction of loading
surface. 16. Flexural strength- also called bending strength or
modulus of rupture; force per unit area of a
BIOLOGICAL PROPERTY
material that is subjected to flexural loading
1. Biomaterials-any matter, surface or construct 17. Impact strength-defined as its capability to resist
that interacts with biological systems a sudden applied load or force.
2. Biomechanics- the study of the mechanical laws 18. Toughness- the ability of a material to absorb
relating to the movement or structure of living elastic energy and deform plastically before
organisms fracturing.
3. Biocompatibility- the appropriate biologic 19. Resilience-associated with springiness
response of the body to a material used in a 20. Fracture toughness- the critical stress intensity
specific application. factor at the point of rapid crack propagation in a
4. Toxicity- the quality of being toxic or poisonous solid containing a crack of known shape and
5. In vitro test- refers to the technique of size.
performing a given procedure in a controlled 21. Ductility- relative ability of a material to
environment outside of a living organism. elongate plastically under tensile stress.
22. Malleability- ability to be hammered or
compressed plastically into thin sheets without
fracture.
23. Brittleness- the relative inability of a material to
deform plastically before it fractures.
24. Proportional limit-magnitude of elastic stress
above which plastic deformation occurs
25. Elastic limit- the maximum extent to which a
solid may be stretched without permanent
alteration of size or shape.
III. Biological Property
26. Ultimate tensile strength- the maximum stress
that a material can withstand while being • The ability of a material to elicit an appropriate
stretched or pulled before breaking. biological response in a given application in the
body.
SCOPE OF THE COURSE
• The science of dental materials is generally
considered to comprise those materials which
are employed in the mechanical procedures
included in restorative dentistry, such as
prosthetics, crowns and bridges.
ADA SPECIFICATION
• It contains requirements for mechanical, IV. Mechanical Property
physical, biological and chemical properties of
the materials which will ensure their quality • A physical science that deals with energy and
and usefulness to the dentist. forces and their effects on bodies.
I. Physical Property
• Contents:
• Waxes are thermoplastic materials that are solids at ➢ Paraffin – obtained from high boiling point fractions
room temperature and soften or become low viscosity of petroleum; melting temperature generally increases
liquid when subjected to moderate temperatures. In with increasing molecular weight;
dentistry, waxes are versatile materials that are used ➢ Microcrystalline - similar to paraffin, except they
are obtained from the heavier oil fractions in the
both in clinics and laboratories. Certain procedures
petroleum industry, as a result, have higher melting
cannot be completed without the use of wax in one of
points
its many forms. Dental waxes are used for specific ➢ Ceresin – used to increase the melting range of
and well-defined applications. paraffin waxes; higher molecular weight
Plant origin
• Dental waxes may be composed of natural and Animal origin- Spermaceti wax
synthetic waxes, gums, fats, fatty acids, oils, natural ➢ obtained from sperm whale, used as coa6ng in the
and synthetic resins, and pigments. manufacture of dental floss
• The particular working characteristics of each wax
are achieved by blending the appropriate natural and Insect origin – Beeswax
synthetic waxes, resins, and other additives.
➢ brittle at room temperature but Becomes plastic at
NATURAL WAXES: body temperature; modifies properties of paraffin
wax; Main component of sticky wax
• Natural waxes are distributed in nature, derived from
mineral, vegetable/plant, and animal (insect) Synthetic Waxes
origins. Whereas synthetic waxes are produced by a
➢ Complex organic compounds of varied chemical
combination of various chemicals in
composition
the laboratory, from natural wax molecules and are
➢ High degree of refinement in contrast to
typically composed of hydrogen, carbon, oxygen, and
contamination seen in natural waxes
chlorine.
➢ Include:
• The additives may be natural mineral and synthe3c
- Polyethylene waxes
products.
• A.) Natural - Mineral, Plant, Animal/Insect - Polyoxyethylene glycol waxes
• B.) Synthetic - Halogenated hydrocarbon
- Hydrogenated waxes
Coloring agents are added for the contrast of wax patterns
against the tooth, die, and model surfaces. Other Substances Related to Wax
Flow
Manipulation of Waxes
❖ renders the impression plaster soluble in warm water ➢ When it is soft, the material should have a
❖ facilitates easy removal of cast from the impression consistency which will allow it to reproduce all
details of crevices and other small markings, and to
Flavoring retain such detail after solidification.
❖ makes the impression plaster palatable ➢ It will not be deformed or fractured and reproduce all
undercuts completely when impression is withdrawn
Coloring from the mouth
❖ for easy identification of the impression from the cast ➢ Should exhibit a smooth, glossy appearance surface
❖ color: pink after being passed through a flame
Scent ➢ After solidification, must withstand trimming with a
Properties: sharp knife without flaking or chipping
❖ W/P ratio: 0.6 - 0.7 ➢ It should not change dimension during or after
❖ Setting time: 3-5 minutes removal from the mouth.
❖ Setting expansion: Lowest – 0.06% Types
IMPRESSSION COMPOUND • Type I - True Compound
❖ A thermoplastic material usually composed of gum Lower fusing
dammar and prepared chalk
• Type II - Tray Compound
Composition
Higher fusing
❖ Beeswax
TYPE 1: STICK
Manipulation