Hyperconjugation also called as

1
NO Bond Resonance

2 Baker nathaneffect

3 Co P conjugation

4

For

o plempty conjugation

For alkene

5

o
empty conjugation radical
for free

6

O P Half filled conjugation

7

In Hyperconjugation consider sp a carbon of

following

a
ing

p

H H

9 THz 2 H

Enz 8h2

Enz

c
Chacha alkene Allylic H

dEnz Benzene Benzylic H

e THz CECH

For Hyperconjugation sp3

x c must have a H

Hyperconjugation in carbocation
gaz Ie

I Iq

No Bond
Hb ca
during
q

Hyperconj

dsp37x.c

N
so called
no Bond Reso


tis
Ifc's

of

delocalisation
called
iconjugation
C

é cha

r
Hb

hyper HE

is c

BR'D

Ig

Bondlength Bond length 1 2

going

going 1 o

ie TT

Hyperconjugation in is called as o pcomply

conjugation

More the number of L H more stable

the carbocation

number of L H number structure

of Hyperconj
involving C H bonds

Que

find the number of Hyperconjugative structure

of following

TX 641h
6 Hyperconj Structure

Cuz CH CH3

I Tructures

3 K H

structures

due compare stability of following Ct

CHz 2 cuz 043 CH3 43

BL H
g

GL H GL H

stability 1

2631

A A
77 B e
777 DJ

Ez

yet g

É Et

LI EE CE

C Hz Hz D C
Dz z th I

as C H CC D Bond

energy

so Extent of Hyperconjugation is C H C D

But

3 C ED no d
Hydrogen so no

Hyperconjugation only

Inductive eff

I D H

Ez 142

IE IE

CH3 143 EH CH3

Sp3 32 H show Hyperconj

2 142

t.EE eEi d

at meta

by Hyper
O


ÉÉ

Not 2

IF

a B

I 43

100

Eres
Es Es

143 245 I

to

2 CH3

Hyperconjugation with free radical cuz its

sp3 x c with L H

millions mis
Ger
Hc

Sp3 C

with L H b CHz

Ya CHz

Hb C

HE
number c

more the of 2 Hydrogen more

stabilityof

Ed

D
I A B c

É a

yes sesame a
Y

Reso

A B C D E

B D A C

stability E
Bondevik

Bond a a D e B
energy

origin

NOTE R D H I
ne Ld

Hyperconjugation in alkene Eng chacha

sp34 C
with 2 Hydrogen

Fa

fjÉÉÉ

Hb on E

Hii gna anion

O Tty

o empty I

Skytbphasemo
th

Ifan

it j

I
i

e
q

in

inphase MO

HE

ÉÉqA


Fbi
ch Iz

he

B o ca g Begg

B 0 1 2 B L did

B0 1 0 B L.TT

This is called o
empty conjugation

more number of 2 Hydrogen more stable alkene

one

compare stability of following

Bonds in
foitpmcongfat.ve
CI CE

I É É

2 cha ch ch

42 42 cuz ca cha

nd

iso butene cis 2 butene Trans 2 butene

KEEN EPI Éhers

64 H 62 H 62 H

BC

I I I

Ken 41143

cuz

fanion Fanion Fanion



when number decide

of 2 Hydrogen are same

by anion

Fanion 7 Zanion

Trans cis

so

D 4 6 stability

Que

compare stability of meta para xylene

CH3 both have

943

y 64 H

Caz

43

P xylene m
xylene

And

HE 1 H H H

JaninOLI
EE cuz

I anion

3 anion Fanion

stability p xylene m
xylene

Cue

Compare stability

H h h

A B C

Out

compare the rate of Et attack

943 245
Y 1
y

E ET
A B C D

É
f E
yet
845
943 E Y
ITE

FEE ELE

32 H 24 H 14 H 02 H

stabilise

the Ave

charge

A B C D

Sacrificial Hyperconjugation If the contributing

structure has 1 Bond less than normal lewis

formula

of the original compound or ion

1

II

ÉÉ
n
I t In
to

go

2 F
II g

H cha H c cuz

I g


Isovalent Hyperconjugation If the contributing

structure has same number of bonds as the

normal lewis formula of the original compound

or ion

H
Elif H e ti I H

te g

Negative or Reverse Hyperconjugation

The donation of E density from a filled

p orbital to orbital

non
bonding É

or

N F overlap

f IF F É cha

Heat of combustion

D DH combustion number of Carbon atoms

more the number of C atom more heat combustion

of

2 for isomeric

AH combustion
stility

T compare Heat of combustion

272 374

8
0

I II y

IT

A MI

3
D H

Y
gy

gy

Que Consider the DH combustion

following
energy profile diagram for Isomeric alkene

of molecular formula 05h10

th
oncolb

Im

on

sp

Yo

aid in in an a man

on the basis of given energy profile match the following

column I column II 7

1 position isomers A P Q

2 Chain isomers B OT

3 G I C OR

4 Out of two only D TU

one show G I E PS


Heat of Hydrogenation

DH

Hz PF Hydrogenation

for isomeric as well as non isomeric alkene

DHHydrogenation provided the number

stagey

of double bonds across the molecule are same

X A A

stability 3 2
I 2 73

DHHyd

DHcomb I 7 2 73

Compound DH theoritical DH Experimental Resonance Energy

II Hz 120 120 o

240 232

212

3k 360 208 152

all Energy are in KJ

DHHyd ED

R E D

DHuyd per T

2080

12 23212 3

Exception
I I Id

DHHyde cis 2 butene isobutene Frans 2 butene

Q compare DH
Hydrogenation

1 AL NV 1

ud ti 2am
EE EE

stability A B C D

DHHyd D C B A

Ii

LF

Hint more T bonds more DHhyd

3 At

AA

Ay Y 82 T a

5
A A
M