LABORATORY REPORT EVALUATION SHEET

Laboratory Course: ENSC 111b Schedule: Tuesday, 2:00 – 3:30 PM

Experiment Number: 3
Experiment Title: The Reaction of Iron with Copper (II) Sulfate

Group Number: 3 Date Performed: September 20, 2022

Group Members: Glenn Boado Date Submitted: October 18, 2022
John Bryan Dave Bumatay
Norma Grace Maliwat
Jerome Mori
Cassandra Mosuela
Alejandro Luis Olarte
Sanrio Reyes
Angela Rivera

CONTENTS TOTAL REMARKS SCORE

POINTS
I. Chapter 1: Introduction 15
II. Chapter 2: Design and
15
Methodology
III. Chapter 3: Results and
25
Discussion
IV. Chapter 4: Conclusions 10
V. References 5
VI. Appendices
a. Definition of terms
b. List and Uses of
Apparatus
c. Documentation 25
d. Computations
e. Problems
f. Material Safety Data
Sheet
Format/ Neatness 5

TOTAL POINTS: 100 SCORE: _________

 TABLE OF CONTENTS Page

CHAPTER I: BACKGROUND

Research Context and Aims. . . . . . . . . . . . . . . 1

. . .

CHAPTER II: DESIGN AND METHODOLOGY

Procedure. . . . . . . . . . . . . 3
. . .
CHAPTER III: RESULTS AND DISCUSSION
Results and Discussion. . . . . . . . . . . . . . . . . 4
. . .
CHAPTER IV: CONCLUSIONS
Conclusions. . . . . . . . . . . . . . . . . . . . . . . 6
. . .
CHAPTER V: REFERENCES

References. . . . . . . . . . . . . . . . . . . . . . . . 7

CHAPTER VI: APPENDICES

A Definition of Terms. . . . . . . . . . . . . . . . . . . . . 9
. . .
B List and Uses of Apparatus. . . . . . . . . . . . . . . . . 10
. . .
C Documentation. . . . . . . . . . . . . . . . . . . . . . . 11
. . .
D Computations. . . . . . . . . . . . . . . . . . . . . . . . 16
. . .
E Problems. . . . . . . . . . . . . . . . . . . . . . . . . . 18
. . .
F Material Safety Data Sheet. . . . . . . . . . . . . . . . . 19
. . .
 CHAPTER I

BACKGROUND

RESEARCH CONTEXT

Stoichiometry is the study of the quantitative relationships or ratios between

two or more substances undergoing a physical change or chemical change or a

chemical reaction (Helmenstine A.M., 2019). Experiments involving stoichiometric

principles is done to analyze the amounts of reactants, leftover reactants, products,

and by-products in a chemical equation. Often, stoichiometry calculations deal with

the mass or volumes of products and reactants. Moreover, stoichiometry is used for

balancing chemical equation, which is an important aspect of chemistry (Gudzuadze

M., 2022).

The use of stoichiometric principles results in determining which ions is

formed in the reaction between the two samples used. Hence, it is used in this

experiment to determine the ions formed in the reaction of iron and copper (II)

sulfate solution. In the reaction, iron will be the limiting reagent which means that it

will all be used up in the reaction. While the copper (II) sulfate will be in the excess,

therefore not all of it will be used up in the reaction.

RESEARCH AIMS

The experiment will start with the heated copper (II) sulfate solution being added to

the iron powder. Copper (II) sulfate solution is warm, making the reaction occur

almost instantaneously. This experiment aims to know if there will be occurrence of

 2

reaction once copper (II) sulfate solution is added to iron powder. Additionally, it also

aims to know if there is a 1:1 ratio between the iron and the copper by calculating

the number of moles of iron that reacts and the number of moles of the copper

produced.
 CHAPTER II

METHODOLOGY

In this experiment, stoichiometric principles will be used to obtain the

appropriate equation between the reaction of iron metal and copper II sulfate

solution. And it is used to determine which reaction is more dominant compared to

another one by examining the reaction between iron copper II sulfate solution.

PROCEDURE

First, weigh the empty beaker, then add 1.00 gram of iron powder, and weigh

it again. On the other empty beaker, put 30 milliliters of copper sulfate (COSu4)

solution using the graduated cylinder and heat gently until it gives off fume. After

that, gently pour the heated copper sulfate solution into the beaker containing iron

powder. Stir it until the iron powder submerged and turns to copper. Then, wash the

copper with distilled water and decant it, do this three times and for the fourth time,

wash it with acetone and decant afterwards. After draining, the copper’s color turned

into reddish brown. After which, dry the copper; gently heat the beaker containing

the copper. And let it cool down, then weigh it.

 CHAPTER III

RESULTS AND DISCUSSION

We observed that some of the powder immediately sank, while some moved

on or near the surface of a liquid without sinking. However, swirling the mixture

made the remaining floating iron powder sink. Due to that, the sediments begin to

create a pile of iron powder that is now copper. Below is the table that shows the

given and calculated data of the reaction of iron with copper (II) sulfate.

Data Sheet of Reaction of Iron

with Copper (II) Sulfate

Data

Mass of empty beaker 66.657 g

Mass of iron used 1.036 g
Moles of iron used 0.0186 mol

Mass of beaker plus copper 67.693 g

Mass of copper formed 1.122 g

Moles of copper formed 0.0177 mol

Moles of Cu divided by 0.9459
moles of Fe

Reaction Equation: Fe + CuSO₄ = FeSO₄ + Cu

Limiting Reagent: Fe

Theoretical and Percentage 1.184 g CuSO4

Yield: 94.7365 %

The empty beaker weighs 66.657 grams. The iron powder used weighs 1.036

grams. By dividing the amount of iron used, which is 1.036 grams, by the molecular
 5

weight of iron, which is 55.845 grams per mole, the number of moles of iron was

computed. The mass of the empty beaker, which is 66.657 grams, and the mass of

the iron, which is 1.036 grams, were added to get the mass of the beaker including

copper. 1.122 grams of copper were produced and weighed. By dividing the quantity

of copper created, which is 1.122 grams, by copper's molecular weight, which is

63.546 grams per mole, the moles of copper were determined. Moles of copper

divided by moles of iron was calculated to be 0.9459 moles. Copper sulfate has 0.3

moles while iron has 0.0185 moles. Iron is the limiting reactant since it has a lower

value than copper sulfate. Theoretically, 1.184 grams of copper sulfate were

produced, while the actual yield was 94.7365 percent.

 CHAPTER IV

CONCLUSIONS

In conclusion, one instance of a single substitution reaction, in which one

element "displaces" another from a compound, is the reaction between iron and

copper (ii) sulfate. To be "more active" than the displaced metal is to be able to

remove another element from a complex. Additionally, this single displacement

reaction between copper sulfate (CuSO4) and iron (Fe) let us learn more about how

stoichiometric principles operate to produce the correct equation between the

forenamed elements. Additionally, the state of the solution added has the potential to

completely alter an element's physical appearance in addition to other factors, such

as its physical look.

A 1:1 ratio between the mass of iron consumed and the mass of copper made

is acquired and displayed in the "Data Sheet of Reaction of Iron with Copper (II)

Sulfate," which was derived by calculating the number of moles of iron that reacts

and the number of moles of copper produced. The physical properties of a given

element may change, but the condition of the solution added may also entirely

convert the element to another element.

 CHAPTER V

REFERENCES

chemical element | Definition, Origins, Distribution, & Facts. (2022, September 20).

Encyclopedia Britannica. Retrieved October 2, 2022, from

https://www.britannica.com/science/chemical-element

chemical reaction | Definition, Equations, Examples, & Types. (n.d.). Encyclopedia

Britannica. Retrieved October 2, 2022, from

https://www.britannica.com/science/chemical-reaction

General Data Protection Regulation (GDPR) Guidelines BYJU’S. (2021, March 22).

BYJUS. Retrieved October 2, 2022, from

https://byjus.com/chemistry/decantation/

Gudzuadze, M. (2022, July 3). 10 Reasons Why Stoichiometry Is Important. The

Important Site. Retrieved September 29, 2022, from

https://theimportantsite.com/reasons-why-stoichiometry-is-important/

https://thermofishervn.com/images/products/MSDS/I0850.pdf

https://westliberty.edu/health-and-safety/files/2010/02/Distilled-Water.pdf

https://www.fishersci.com/msds?productName=AC422870050

https://www.labchem.com/tools/msds/msds/LC10420.pdf

Libretexts. (2022, August 20). Stoichiometry and Balancing Reactions. Chemistry

LibreTexts. Retrieved October 2, 2022, from

 8

https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/

Supplemental_Modules_and_Websites_(Inorganic_Chemistry)/

Chemical_Reactions/Stoichiometry_and_Balancing_Reactions#:

%7E:text=Stoichiometry%20is%20a%20section%20of,means%20the

%20measure%20of%20elements.

What Is a Limiting Reactant? Review Your Chemistry Concepts. (2018, December

23). ThoughtCo. Retrieved October 2, 2022, from

https://www.thoughtco.com/definition-of-limiting-reactant-605310

What is stoichiometry? (2019, January 6). ThoughtCo. Retrieved September 29,

2022, from https://www.thoughtco.com/definition-of-stoichiometry-605926

 CHAPTER VI

APPENDICES

DEFINITION OF TERMS

Compound. It is a substance composed of two or more elements united

chemically in definite proportions. It can be decomposed into two or more different

pure substances by chemical means.

Decantation. Refers to the process of separation of liquid from solid and

other immiscible or non-mixing liquids, by removing the liquid layer at the top from

the layer of solid or liquid below.

Element. Elements are the fundamental materials of which all matter is

composed. It cannot be decomposed into simpler substances by ordinary chemical

processes.

Limiting reagent. It is a reactant in a chemical reaction that determines the

amount of product that is formed.

Reaction. Refers to a process in which one or more substances, also called

reactants, are converted to one or more different substances.

Stoichiometry. It is a section of chemistry that involves using relationships

between reactants and/or products in a chemical reaction to determine desired

quantitative data.
 10

LIST AND USES OF APPARATUS

Alcohol lamp. It was used to heat up the copper sulfate solution.

Analytical balance. It was used to weigh the precise measurement of small

samples.

Beaker. It was used as a reaction container and to hold the liquid samples.

Brush. It was used to clean apparatus like the beakers.

Bulb syringe. It was used to get any solution inside the pipette and was used

to push the solution outside the pipette.

Laboratory tripod stand. It was used to hold the beaker with copper sulfate

solution to get it into heating.

Pipette. It was used to get solution like the copper sulfate solution and the

acetone.

Spatula. It was used to scoop chemicals like the iron powder out of its

original container.

Wire gauze. It was placed on top of the tripod stand to hold the beaker with

copper sulfate solution in heating up.

Wood block. It was used for the alcohol lamp to make the fire higher and

heat up the solution faster.

 11

DOCUMENTATION

Apparatus

Alcohol lamp Beaker

 12

Laboratory tripod stand Wire gauze

 12

Weighing the dry beaker Putting the iron powder

Weighing the beaker with iron powder

13
 12

Putting copper sulfate solution Boiling the copper sulfate

to the beaker solution

Pouring the heated copper sulfate solution

to the beaker that contains iron powder
 14

Unswirled mixture of a hot copper, Swirled mixture of a hot copper,

and an iron powder and an iron powder

Decanting the copper sulfate solution

 15

Putting acetone in the beaker Resting mixture of acetone

that has an iron powder and copper

Copper after decanting the acetone

 17

COMPUTATIONS

Equations

actual yield
% yield= × 100 %
theoretical yield

Solutions

Moles of iron used.

1 mol Fe
1.036 g Fe × =0.0185 mol Fe
56 g Fe

Mass of beaker plus copper.

Mass of empty beaker = 66.657 g

Mass of copper = 1.122 g

66.657 g+1.122 g=67.693 g

Moles of copper formed.

1mol Cu
1.122 g Cu × =0.0175 mol Cu
64 g Cu

Moles of Cu divided by moles of Fe.

Moles of Cu = 0.0175 mol

Moles of Fe = 0.0185 mol

0.0175 mol
=0.9459
0.0185 mol
 17

Reaction Equation.

Fe + CuSO₄ = FeSO₄ + Cu

Limiting Reactant.

1L 1.0 mol
mol Cu So 4=30 mL × × =0.03 mol Cu So 4
1000 mL 1L

0.0185 mol Fe
=0.0185 mol Fe( Limiting Reactant )
1

0.03 mol Cu SO 4
=0.03 mol Cu SO 4 ( Excess Reactant)
1

Theoretical Yield.

1 mol Fe 1 mol Cu 64 g Cu
1.036 g Fe × × × =1.184 g Cu
56 g Fe 1 mol Fe 1 mol Cu

% Yield.
 18
1.122 g Cu
% yield= × 100 %=94.7635 %PROBLEMS
1.184 g Cu

Questions

1. What is the purpose of using excess solution?

- The purpose of using the excess solution is to compensate for impurities and ensure

that one reactant fully reacts. This is financially efficient when one of the reactants is

very cheap. When one reactant is in excess, there will always be some left over.

2. In the experiment, which is the more active element or compound?

- Iron can displace copper from its salt solution. Therefore, iron is more reactive when

compared to copper.

3. What is the role of the acetone in the experiment?

- Acetone removes impurities without dissolving the copper sulfate.

Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 11/12/1998 Revision date: 04/24/2018 Supersedes: 04/24/2018 Version: 1.3

SECTION 1: Identification
1. . Identificatio
Product
1 n : Substanc
Substance
form : Aceton
e
name name
Chemical e
: 2-Propanone
CAS-No. : 67-64-1
Product code : LC10420, LC10425
Formula : C3H6O
Synonyms : 2-propanone / beta-ketopropane / dimethyl formaldehyde / dimethyl
ketone / dimethylketal /
DMK (=dimethyl ketone) / keto propane / methyl ketone / pyroacetic acid / pyroacetic ether /

pyroacetic spirit

1.2. Recommended use and restrictions on use

Use of the substance/mixture : Solvent

Cleaning product

Chemical raw material

Recommended use : Laboratory chemicals

Restrictions on use : Not for food, drug or household use

1. . Supplie
3 r Inc.
LabChem,

Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court

Zelienople, PA 16063 - USA

T 412-826-5230 - F 724-473-0647

04/23/2019 EN (English US) 3/83

Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

1. . Emergency telephone
4 number
Emergency number : CHEMTREC: 1-800-424-9300 or +1-703-741-5970

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture

Flammable liquids H225 Highly flammable liquid and vapour
Category 2
Serious eye H319 Causes serious eye irritation
damage/eye
irritation Category
2A
Specific target H336 May cause drowsiness or dizziness
organ toxicity
(single exposure)
Category 3

GHS-US classification

Full text of H statements : see section 16

2. . GHS Label elements, including precautionary

GHS
2 USstatements
Hazard
labelingpictograms (GHS :
US)
Hazard statements (GHS US) : H225 - Highly flammable liquid
and vapour H319 - Causes
serious
GHS02
eye irritation
GHS07

Signal word (GHS : Dang

H336 - May cause drowsiness or dizziness
US) er
Precautionary statements (GHS : P210 - Keep away from heat, hot surfaces, open
US) flames, sparks. - No smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving
equipment.
P241 - Use explosion-proof electrical, lighting,
ventilating equipment P242 - Use only non-
04/23/2019 EN (English US) 4/83
sparking tools.
P243 - Take precautionary measures against static
discharge.
P261 - Avoid breathing mist, spray, vapors.
Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

04/23/2019 EN (English US) Page 1

P264 - Wash exposed skin thoroughly after handling.

P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear eye protection, face protection, protective clothing, protective gloves. P303+P361+P353

- IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with

water/shower.

P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing

P312 - Call a POISON CENTER or doctor/physician if you feel unwell.

P337+P313 - If eye irritation persists: Get medical advice/attention.

P370+P378 - In case of fire: Use dry chemical powder, alcohol-resistant foam, carbon dioxide

(CO2) to extinguish

P403+P233 - Store in a well-ventilated place. Keep container tightly closed.

P405 - Store locked up.

P501 - Dispose of contents/container to comply with local, state and federal regulations P235 -

Keep cool.

2.3. Other hazards which do not result in

classification Other hazards not contributing to

the : None. classification

04/23/2019 EN (English US) 5/83

Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

2. . Unknown acute toxicity

4
(GHS US) Not applicable
SECTION 3: Composition/Information on ingredients
3. . Substance
1 s type
Substance : Mono-constituent

Name Product % GHS-US

identifier classification
Acetone (CAS-No.) 67-64-1 100 Flam. Liq. 2, H225 Eye
( Main constituent) Irrit. 2A, H319
STOT SE 3, H336

3. . Mixture
2 s

Full text of hazard classes and H-statements :

see section 16 Not applicable

SECTION 4: First-aid measures

4. . Description of first aid
First-aid measures
1 measures general
First-aid measures after
inhalation
First-aid measures after skin
contact
First-aid measures after eye
04/23/2019
: Check the vital functions. Unconscious: maintain adequate
airway and respiration. Respiratory arrest: artificial respiration
or oxygen. Cardiac arrest: perform resuscitation. Victim
conscious with labored breathing: half-seated. Victim in shock:
on his back with legs slightly raised. Vomiting: prevent
asphyxia/aspiration pneumonia. Prevent cooling by covering
the victim (no warming up). Keep watching the victim. Give
psychological aid. Keep the victim calm, avoid physical strain.
Depending on the victim's condition: doctor/hospital.
: Remove the victim into fresh air. Respiratory problems: consult
a doctor/medical service.
: Wash immediately with lots of water. Soap may be used. Do not
apply (chemical) neutralizing agents. Remove clothing before
washing. Take victim to a doctor if irritation persists.
: Rinse immediately with plenty of water. Remove contact lenses,
EN (English US) 6/83
Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

contact if present and easy to do. Continue rinsing. Do not apply

neutralizing agents. Take victim to an ophthalmologist if
irritation persists.
First-aid measures after : Rinse mouth with water. Immediately after ingestion: give lots of
ingestion water to drink. Do not give
milk/oil to drink. Do not induce vomiting. Give activated charcoal. Call Poison Information Centre

(www.big.be/antigif.htm). Consult a doctor/medical service if you feel unwell. Ingestion of large

quantities: immediately to hospital. Doctor: gastric lavage.

4.2. Most important symptoms and effects (acute and delayed)

Symptoms/effects : Not expected to present a significant hazard under anticipated
conditions of normal use.
Symptoms/effects after inhalation: EXPOSURE TO HIGH CONCENTRATIONS: Feeling of
weakness. Irritation of the respiratory tract. Nausea. Vomiting.
Headache. Central nervous system depression. Dizziness.
Narcosis. Excited/restless. Drunkenness. Disturbed motor
response. Respiratory difficulties. Disturbances of
consciousness.
Symptoms/effects after skin : ON CONTINUOUS EXPOSURE/CONTACT: Dry skin. Cracking
contact of the skin.
Symptoms/effects after eye : Irritation of the eye tissue.
contact
Symptoms/effects after ingestion : Dry/sore throat. Risk of aspiration pneumonia. Symptoms
similar to those listed under inhalation. AFTER ABSORPTION
OF LARGE QUANTITIES: Irritation of the gastric/intestinal
mucosa. Change in the blood composition. Change in urine
output. Renal disease. Enlargement/disease of the liver.
Symptoms/effects upon : Not available.
intravenous administration
Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red
skin. Skin rash/inflammation.
Dry/sore throat. Headache. Nausea. Feeling of weakness. Loss of weight. Possible inflammation of

the respiratory tract.

4.3. Immediate medical attention and special

treatment, if necessary Obtain medical assistance.
04/23/2019 EN (English US) 7/83
Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media

Suitable extinguishing media : Quick-acting ABC powder extinguisher. Quick-acting BC powder

extinguisher. Quick-acting class B foam extinguisher. Quick-acting

CO2 extinguisher. Class B foam (alcohol-resistant). Water spray if

puddle cannot expand.

Unsuitable extinguishing media : Water (quick-acting extinguisher, reel); risk of puddle expansion.

Water; risk of puddle expansion.

5.2. Specific hazards arising from the chemical

Fire hazard : DIRECT FIRE HAZARD. Highly flammable liquid and vapour.
Gas/vapor flammable with air within explosion limits.
INDIRECT FIRE HAZARD. May be ignited by sparks.
Gas/vapor spreads at floor level: ignition hazard. Reactions
involving a fire hazard: see "Reactivity Hazard".
Explosion hazard : DIRECT EXPLOSION HAZARD. Gas/vapour explosive with
air within explosion limits. INDIRECT EXPLOSION HAZARD.
Heat may cause pressure rise in tanks/drums: explosion risk.
may be ignited by sparks. Reactions with explosion hazards:
see "Reactivity Hazard".
Reactivity : Violent to explosive reaction with many compounds.
Prolonged storage: on exposure to light:
release of harmful gases/vapours.

5.3. Special protective equipment and precautions for fire-fighters

Firefighting instructions : Cool tanks/drums with water spray/remove them into safety.

Physical explosion risk: extinguish/cool from behind cover. Do not

move the load if exposed to heat. After cooling: persistant risk of

physical explosion.

04/23/2019 EN (English US) 8/83

Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Protection during firefighting : Heat/fire exposure: compressed air/oxygen

apparatus. SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and

emergency procedures 6.1.1. For non-emergency
personnel
Protective equipment : Gloves. Protective goggles. Protective clothing. Large spills/in
enclosed spaces: compressed air apparatus.
Emergency procedures : Keep upwind. Mark the danger area. Consider evacuation. Seal
off low-lying areas. Close doors and windows of adjacent
premises. Stop engines and no smoking. No naked flames or
6.1.2. For emergency sparks. Spark- and explosion-proof appliances and lighting
responders equipment. Keep containers closed. Wash contaminated
clothes.
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
For containment : Contain released substance, pump into suitable containers.
6. . Environmental
2 precautions Plug the leak, cut off the supply. Dam up the liquid spill. Try to
reduce evaporation. Measure the concentration of the explosive
gas-air mixture. Dilute/disperse combustible gas/vapour with
water curtain. Provide equipment/receptacles with earthing. Do
not use compressed air for pumping over spills.
Methods for cleaning up : Take up liquid spill into inert absorbent material, e.g.: sand,
earth, vermiculite. Scoop absorbed substance into closing
containers. Spill must not return in its original container.
Carefully collect the spill/leftovers. Damaged/cooled tanks must
be emptied. Do not use compressed air for pumping over spills.
Clean contaminated surfaces with an excess of water. Take
collected spill to manufacturer/competent authority. Wash
clothing and equipment after handling.

04/23/2019 EN (English US) 9/83

Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

6.4. Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7. . Precautions for safe
1 handling

Precautions for safe handling : Use spark-/explosionproof appliances and lighting system. Take

precautions against

electrostatic charges. Keep away from naked flames/heat. Keep away from ignition

sources/sparks. Measure the concentration in the air regularly. Work under local

exhaust/ventilation. Comply with the legal requirements. Remove contaminated clothing

immediately. Clean contaminated clothing. Handle uncleaned empty containers as full ones.

Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Do not

use compressed air for pumping over. Keep container tightly closed.

Hygiene measures : Do not eat, drink or smoke when using this product. Wash contaminated

clothing before reuse.

Wash hands and other exposed areas with mild soap and water before eating, drinking or

smoking and when leaving work.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions
Incompatible products
Incompatible materials
Storage temperature
Heat-ignition
04/23/2019
: Keep only in the original container in a cool, well ventilated
place away from : Heat sources, Direct sunlight, incompatible
materials. Keep container closed when not in use.
: Strong bases. Strong acids.
: Sources of ignition. Direct sunlight.
: 15 - 20 °C
: KEEP SUBSTANCE AWAY FROM: heat sources. ignition
EN (English US) 10/83
Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

sources.
Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. reducing
agents. strong acids. (strong) bases. halogens. amines.
Storage area : Store in a cool area. Keep out of direct sunlight. Store in a dry
area. Store in a dark area.
Ventilation at floor level. Fireproof storeroom. Provide for an
automatic sprinkler system.
Provide for a tub to collect spills. Provide the tank with
earthing. Meet the legal requirements.
Special rules on packaging : SPECIAL REQUIREMENTS: closing. with pressure relief
valve. clean. opaque. correctly labelled. meet the legal
requirements. Secure fragile packagings in solid containers.
Packaging materials : SUITABLE MATERIAL: steel. stainless steel. carbon steel.
aluminium. iron. copper. nickel.
bronze. glass. MATERIAL TO AVOID: synthetic material.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Acetone (67-64-1)
ACGIH ACGIH TWA (ppm) 250 ppm
ACGIH ACGIH STEL (ppm) 500 ppm
NIOSH NIOSH REL (TWA) (mg/m³) 590 mg/m³
NIOSH NIOSH REL (TWA) (ppm) 250 ppm

8. . Appropriate engineering controls

2
Appropriate engineering controls : Emergency eye wash fountains should be available in the

immediate vicinity of any potential exposure.

8.3. Individual protection measures/Personal

protective equipment Personal protective equipment:
04/23/2019 EN (English US) 11/83
Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Safety glasses. Gloves. Protective clothing. Face shield. High gas/vapor concentration: gas mask

with filter type A.

Materials for protective clothing:

GIVE GOOD RESISTANCE: butyl rubber. tetrafluoroethylene. GIVE LESS RESISTANCE:

chlorosulfonated polyethylene. natural rubber. neoprene.

polyurethane. PVA. styrene-butadiene rubber. GIVE POOR RESISTANCE: nitrile rubber.

polyethylene. PVC. viton. nitrile rubber/PVC

Hand protection:
Gloves

Eye protection:
Safety glasses

Skin and body protection:

Head/neck protection. Protective

clothing Respiratory

protection:

Full face mask with filter type

AX at conc. in air > exposure
limit

Other information:
04/23/2019 EN (English US) 12/83
Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Appearance : Liquid.
: Colourless

: Aromatic odour Sweet odour Fruity odour

Odor threshold : No data available

pH : 7 (10 g/l)

Melting point : -95 °C

Freezing point : No data available

Boiling point : 56 °C

Critical temperature : 235 °C

Critical pressure : 47010 hPa
Flash point : -17 °C (Closed cup)

Relative evaporation rate (butyl : 6

acetate=1)
Relative evaporation rate :2
(ether=1)
Flammability (solid, gas) : Non flammable.

Vapor pressure : 247 hPa (20 °C)

Vapor pressure at 50 °C : 828 hPa

Relative vapor density at 20 °C :2

Relative density : 0.79

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Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Relative density of saturated : 1.2

gas/air mixture
Specific gravity / density : 786 kg/m³
Molecular mass : 58.08 g/mol
Solubility : Soluble in water. Soluble in ethanol. Soluble in ether.
Soluble in dimethyl ether. Soluble in petroleum spirit.
Soluble in chloroform. Soluble in dimethylformamide.
Soluble in oils/fats. Water: complete
Ethanol:
complete Ether:
complete

Log Pow : -0.24 (Test data)

Auto-ignition temperature : 465 °C

Decomposition temperature : No data available

Viscosity, kinematic : 0.417 mm²/s

Viscosity, dynamic : 0.32 mPa·s (20 °C)

Explosion limits : 2 - 12.8 vol

% 60 - 310
g/m³
Lower explosive limit
(LEL): 2 vol % UEL: 12.8
vol %

Explosive properties : No data available.

Oxidizing properties : None.

9.2. Other information

Minimum ignition energy : 1.15 mJ
Specific conductivity : 6000000 pS/m (25 °C)
Saturation concentration : 589 g/m³
VOC content : 100 %
Other properties : Gas/vapour heavier than air at 20°C. Clear. Highly
volatile. Neutral reaction.
SECTION 10: Stability and reactivity
10.. Reactivit
1
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Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Violent to explosive reaction with many compounds. Prolonged storage: on exposure to light:

release of harmful gases/vapours.

10..
2 Chemical stability

Unstable on exposure to light.

10.. Possibility of hazardous

3
Reacts reactions
with (strong) oxidizers.

10..
4Conditions to avoid

Direct sunlight. Extremely high or low temperatures.

10.Incompatible
. materials
5
Strong acids. Strong bases. Strong oxidizers.

10.. Hazardous decomposition

6
products fume. Carbon monoxide.

Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Likely routes of exposure : Inhalation; Skin and eye contact

Acute toxicity : Not classified

Acetone (67-64-1)
LD50 oral rat 5800 mg/kg (Equivalent or similar to OECD 401, Rat, Female,
Experimental value, Oral)
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Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

LD50 dermal rabbit 20000 mg/kg (Equivalent or similar to OECD 402, Rabbit,
Male, Experimental value, Dermal)
LC50 inhalation rat (mg/l) 76 mg/l (Other, 4 h, Rat, Female, Experimental value,
Inhalation (vapours))
ATE US (oral) 5800 mg/kg body weight
ATE US (dermal) 20000 mg/kg body weight
ATE US (gases) 30000 ppmV/4h
ATE US (vapors) 71 mg/l/4h
ATE US (dust, mist) 71 mg/l/4h

Skin corrosion/irritation : Not

classified
pH: 7 (10
g/l)
Serious eye : Causes serious eye irritation.
damage/irritation pH: 7 (10 g/l)
Respiratory or skin : Not classified
sensitization
Germ cell mutagenicity : Not classified
Based on available data, the
classification criteria are not met
Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Based on available data, the
classification criteria are not met
Specific target organ : May cause drowsiness or dizziness.
toxicity – single
exposure

Specific target organ : Not classified

toxicity – repeated
exposure

Aspiration hazard : Not classified

Potential Adverse : Based on available data, the

human health effects classification criteria are not met.
and symptoms
Symptoms/effects after : EXPOSURE TO HIGH CONCENTRATIONS:
inhalation Feeling of weakness. Irritation of the respiratory
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Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

tract. Nausea. Vomiting. Headache. Central

nervous system depression. Dizziness. Narcosis.
Excited/restless. Drunkenness. Disturbed motor
response. Respiratory difficulties. Disturbances of
consciousness.
Symptoms/effects after : ON CONTINUOUS EXPOSURE/CONTACT: Dry
skin contact skin. Cracking of the skin.
Symptoms/effects after : Irritation of the eye tissue.
eye contact
Symptoms/effects after : Dry/sore throat. Risk of aspiration pneumonia.
ingestion Symptoms similar to those listed under inhalation.
AFTER ABSORPTION OF LARGE QUANTITIES:
Irritation of the gastric/intestinal mucosa. Change
in the blood composition. Change in urine output.
Renal disease. Enlargement/disease of the liver.
Symptoms/effects upon : Not available.
intravenous
administration
Chronic symptoms : ON CONTINUOUS/REPEATED
EXPOSURE/CONTACT: Red skin. Skin
rash/inflammation. Dry/sore throat. Headache.
Nausea. Feeling of weakness. Loss of weight.
Possible inflammation of the respiratory tract.
SECTION 12: Ecological information
12.. Toxicit
1
Ecology y- general : Not classified as dangerous for the environment according to

the criteria of Regulation (EC) No 1272/2008.

Ecology - air : Not included in the list of substances which may contribute to the greenhouse effect

(IPCC).

Not included in the list of fluorinated greenhouse gases (Regulation (EU) No 517/2014). Not

classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009).

Ecology - water : Not harmful to crustacea. Not harmful to fishes. Inhibition of

activated sludge. Not harmful to algae. Not harmful to plankton.

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Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Acetone (67-64-1)
LC50 fish 1 5540 mg/l (EU Method C.1, 96 h, Salmo gairdneri, Static
system, Fresh water, Experimental value, Nominal
concentration)

12.. Persistence and

2
Acetonedegradability
(67-64-1)
Persistence and degradability Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Readily biodegradable in water.
Biochemical oxygen demand 1.43 g O₂/g substance
(BOD)
Chemical oxygen demand 1.92 g O₂/g substance
(COD)
ThOD 2.2 g O₂/g substance
BOD (% of ThOD) 0.872 (20 day(s), Literature study)

12.. Bioaccumulative
3
Acetonepotential
(67-64-1)
BCF fish 1 0.69 (Pisces)
BCF other aquatic organisms 1 3 (BCFWIN, Calculated value)
Log Pow -0.24 (Test data)
Bioaccumulative potential Not bioaccumulative.

12.. Mobility in
4
Acetonesoil
(67-64-1)
Surface tension 0.0237 N/m
Ecology - soil No (test)data on mobility of the substance available.

12.. Other adverse

5 effects

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Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

Waste disposal : Do not discharge into drains or the environment. Remove waste
recommendations in accordance with local and/or national regulations. Hazardous
waste shall not be mixed together with other waste. Different
types of hazardous waste shall not be mixed together if this
may entail a risk of pollution or create problems for the further
management of the waste. Hazardous waste shall be managed
responsibly. All entities that store, transport or handle
hazardous waste shall take the necessary measures to prevent
risks of pollution or damage to people or animals. Recycle by
distillation. Incinerate under surveillance with energy recovery.
Additional information : Hazardous waste according to Directive 2008/98/EC, as
amended by Regulation (EU) No 1357/2014 and Regulation
(EU) No 2017/997.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation
(DOT)
In accordance with DOT
Transport document description : UN1090 Acetone, 3, II

UN-No.(DOT) : UN1090
Proper Shipping Name (DOT) : Acetone
Transport hazard class(es) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
(DOT)
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
13..
1
Disposal methods

DOT Packaging Non Bulk (49 CFR 173.xxx) : 202

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Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

DOT Packaging Bulk (49 CFR 173.xxx) : 242

DOT Special Provisions (49 CFR 172.102) : IB2 - Authorized IBCs: Metal (31A, 31B and

31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).

Additional Requirement: Only liquids with a vapor pressure less

than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa

at 55 C (1.3 bar at 131 F) are authorized.

T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)

TP1 - The maximum degree of filling must not exceed the
degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the
maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of
the liquid during filling. DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Quantity Limitations Passenger

aircraft/rail : 5 L (49 CFR 173.27)

DOT Quantity Limitations Cargo aircraft only (49 : 60 L

CFR 175.75)

DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on

a cargo vessel and on a

passenger vessel carrying a number of passengers limited to not more than the larger of 25

passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on

passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this

section is exceeded.

Other information : No supplementary information available.

Transportation of Dangerous Goods

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Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Transport document description : UN1090 ACETONE, 3, II

UN-No. (TDG) : UN1090

Proper Shipping Name (Transportation of : ACETONE

Dangerous Goods)

TDG Primary Hazard Classes : 3 - Class 3 - Flammable Liquids

Packing group : II - Medium Danger

Explosive Limit and Limited Quantity Index :1L

Passenger Carrying Road Vehicle or Passenger : 5 L

Carrying Railway Vehicle Index

Passenger Carrying Ship Index : Forbidden

Transport by sea
Transport document description : UN 1090 acetone, 3, II
(IMDG)
UN-No. (IMDG) : 1090
Proper Shipping Name (IMDG) : acetone
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting
medium danger
EmS-No. (1) : F-E
EmS-No. (2) : S-D

Air transport
Transport document description : UN 1090 Acetone, 3, II
(IATA)
UN-No. (IATA) : 1090
Proper Shipping Name (IATA) : Acetone
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
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Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 15: Regulatory information

15.. US Federal
1 regulations
Acetone (67-64-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
RQ (Reportable quantity, section 304 of 5000 lb
EPA's List of Lists)
SARA Section 311/312 Hazard Classes Immediate (acute)
health hazard Fire
hazard
All components of this product are listed, or excluded from listing, on the United States
Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory

15.. International
2 regulations
CANADA
Acetone (67-64-1)
Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations
No additional information available

National regulations
Acetone (67-64-1)
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Acetone
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Listed on the Canadian IDL (Ingredient Disclosure List)

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the
state of California to cause cancer, developmental and/or reproductive harm

SECTION 16: Other information

Revision date : 04/24/2018 Other

information : None.

Full text of H-phrases: see section 16:

H225 Highly flammable liquid and vapour

H319 Causes serious eye irritation
H336 May cause drowsiness or dizziness
-----
-----
-----

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NFPA health hazard : 1 - Materials that, under emergency conditions, can cause

significant irritation.

NFPA fire hazard : 3 - Liquids and solids (including finely divided

suspended

solids) that can be ignited under almost all ambient

temperature conditions.

NFPA reactivity : 0 - Material that in themselves are normally stable, even

under fire conditions.

Hazard Rating
Health : 1 Slight Hazard - Irritation or minor reversible injury possible
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all
normal temperature conditions. Includes flammable liquids with
flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100
F. (Classes IB & IC)
Physical : 0 Minimal Hazard - Materials that are normally stable, even
under fire conditions, and will NOT react with water, polymerize,
decompose, condense, or self-react. Non-Explosives.
Personal protection :C
C - Safety glasses, Gloves, Synthetic apron

SDS US LabChem

Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.

04/23/2019 EN (English US) 2/83


Effective date : 01.08.2015
Creation Date 09-Apr-2010
Product Name
Cat No. :
CAS No
Synonyms
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Company
Fisher Scientific Company
One Reagent Lane
Fair Lawn, NJ 07410
Tel: (201) 796-7100
Emergency Telephone
Number
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR
1910.1200)
Acute oral toxicity
Skin Corrosion/Irritation
Safety Data Sheet
Page 3 of 83
Distilled Water
SAFETY DATA SHEET
Revision Date 26-Dec-2021 Revision
Number 5
1. Identification
Copper(II) sulfate
AC422870000; AC422870025; AC422870050;
AC422870100; AC422871000; AC422875000
7758-98-7
Cupric sulfate anhydrous; Cupric sulfate; Copper
monosulfate
Laboratory chemicals.
Food, drug, pesticide or biocidal product use.
Acros Organics
One Reagent Lane
Fair Lawn, NJ 07410
For information US call: 001-800-ACROS-01 / Europe
call: +32 14 57 52 11
Emergency Number US:001-201-796-7100 / Europe:
+32 14 57 52 99
CHEMTREC Tel. No.US:001-800-424-9300 /
Europe:001-703-527-3887
2. Hazard(s) identification
Category 4
Category 2
 Safety Data Sheet
Serious Eye Damage/Eye Irritation Category 2
Effective date : 01.08.2015 Page 4 of 83
Label Elements Distilled Water
Signal Word

Warning

Hazard Statements
Harmful if swallowed

Causes skin irritation

Causes serious eye irritation

Precautionary Statements Prevention

Wash face, hands and any exposed skin thoroughly after handling

Do not eat, drink or smoke when using this product

Wear protective gloves/protective clothing/eye

protection/face protection Skin

IF ON SKIN: Wash with plenty of soap and water

If skin irritation occurs: Get medical advice/attention

Take off contaminated clothing and wash before reuse

Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention

Ingestion
IF SWALLOWED: Call a POISON CENTER or doctor/physician if

you feel unwell Rinse mouth

 Safety Data Sheet
Disposal
Effective date : 01.08.2015 Page 5 of 83

Dispose of contents/container to an approved waste

Distilled disposal plant
Water

Hazards not otherwise classified (HNOC)

Very toxic to aquatic life with long lasting effects

3. Composition/Information on Ingredients

Component CAS No Weight %

Cupric sulfate 7758-98-7 98

4. First-aid measures

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for
at least 15 minutes. Get medical attention.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes.
Get medical attention if symptoms occur.
Inhalation Remove to fresh air. Do not use mouth-to-mouth method if victim
ingested or inhaled the substance; give artificial respiration with the
aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device. Get medical attention. If not
breathing, give artificial respiration.
Do NOT induce vomiting. Call a physician or poison control center
Ingestion
immediately.
Most important symptoms No information available.
and effects
Notes to Physician Treat symptomatically
5. Fire-fighting measures
Suitable Extinguishing Substance is nonflammable; use agent most appropriate to
Media extinguish surrounding fire.
Unsuitable Extinguishing
No information available
Media
No information available
Flash Point
Method - No information available

Autoignition Temperature No information available

Explosion Limits
Upper No data available
 Safety Data Sheet
Lower No data available
Effective date : 01.08.2015 Page 6 of 83

Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge

Distilled Water

No information available

Specific Hazards Arising from the Chemical

Non-combustible, substance itself does not burn but may decompose upon heating to produce

corrosive and/or toxic fumes. Do not allow run-off from fire-fighting to enter drains or water courses.

Hazardous Combustion Products

Toxic fumes. Sulfur oxides. Copper oxides.

Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH

(approved or equivalent) and full protective gear. NFPA

Health Flammability Instability Physical

2 0 1 hazards
N/A
6. Accidental release measures
Personal Precautions Use personal protective equipment as required. Ensure adequate
ventilation. Avoid dust formation. Avoid contact with skin, eyes or
clothing.
Environmental Do not flush into surface water or sanitary sewer system. Do not
Precautions allow material to contaminate ground water system. Prevent
product from entering drains. Local authorities should be advised
if significant spillages cannot be contained. Should not be
released into the environment.
Methods for Containment and Clean Sweep up and shovel into suitable containers for disposal.

Avoid dust formation.

Up
7. Handling and storage

Handling Wear personal protective equipment/face protection. Ensure

adequate ventilation. Avoid dust formation. Avoid contact with skin,
eyes or clothing. Avoid ingestion and inhalation.
Storage. Keep containers tightly closed in a dry, cool and well-ventilated
place. Store under an inert atmosphere. Incompatible Materials.
Strong bases. Metals. Alkali metals. Finely powdered metals.
 Safety Data Sheet
8. Exposure controls / personal protection
Effective date : 01.08.2015 Page 7 of 83

Exposure Distilled Water

Guidelines
Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA)
Cupric sulfate TWA: 1 mg/m3 IDLH: 100 mg/m3
TWA: 1 mg/m3
Legend

ACGIH - American Conference of Governmental Industrial Hygienists

NIOSH IDLH: NIOSH - National Institute for Occupational Safety and Health
Engineering Measures Ensure adequate ventilation, especially in confined areas.
Ensure that eyewash stations and safety showers are close to
Personal Protective the workstation location.
Equipment
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety
goggles as described by OSHA's eye and face protection
regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body Wear appropriate protective gloves and clothing to prevent skin
protection exposure.
Respiratory Follow the OSHA respirator regulations found in 29 CFR
Protection 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if exposure
limits are exceeded or if irritation or other symptoms are
experienced.
Handle in accordance with good industrial hygiene and safety
Hygiene Measures practice.
9. Physical and chemical properties
Physical State Powder Solid
Appearance Grey
Odor Odorless
Odor Threshold No information available
pH 3.5-4.5
Melting Point/Range 200 °C / 392 °F
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive
limits Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity 3.6
Solubility 203 g/L (20°C)
Partition coefficient; n- No data available
octanol/water
Autoignition Temperature No information available
 Safety Data Sheet
Decomposition Temperature No information available
Effective date : 01.08.2015 Page 8 of 83
Viscosity Not applicable
Molecular Formula Distilled
CuWater
O4 S
Molecular Weight 159.6
10. Stability and reactivity
Reactive Hazard None known, based on information available

Stability Stable under normal conditions. Hygroscopic.

Avoid dust formation. Incompatible products. Excess heat.
Conditions to Avoid
Exposure to moisture.
Strong bases, Metals, Alkali metals, Finely powdered
Incompatible Materials metals
Hazardous Decomposition ProductsToxic fumes, Sulfur oxides, Copper oxides

Hazardous Hazardous
Polymerization polymerization does
not occur.
Hazardous None under normal
Reactions processing.
11. Toxicological information
Acute Toxicity

Product
Information
Component
Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
Cupric sulfate LD50 = 481 mg/kg ( LD50 > 1000 Not listed
Rat ) mg/kg ( Rabbit )
Toxicologically SynergisticNo information available
Products
Delayed and immediate effects as well as chronic effects
from short and long-term exposure

Irritation Irritating to eyes and skin

Sensitization No information available

The table below indicates whether
Carcinogenicity each agency has listed any ingredient
as a carcinogen.
Component CAS IARC NTP ACGIH OSHA Mexico
No
Cupric sulfate 7758- Not listed Not Not Not Not listed
98-7 listed listed listed
 Safety Data Sheet
Mutagenic Effects No information
Effective date : 01.08.2015 Page 9 of 83
available
Reproductive No information Distilled Water

Effects available.
Developmental No information
Effects available.
No information
Teratogenicity
available.
STOT - single None known
exposure
STOT - repeated None known
exposure
No information
Aspiration hazard
available
Symptoms / No information
effects,both acute available
and delayed
Endocrine Disruptor No information
Information available
The toxicological properties
Other Adverse
have not been fully
Effects
investigated.
12. Ecological
information
Ecotoxicity
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do

not allow material to contaminate ground water system. The product contains following substances

which are hazardous for the environment.

Component Freshwater Algae Freshwater Fish Microtox Water Flea

Cupric sulfate Not listed LC50: = 0.1 mg/L, 96h Not listed EC50 = 0.024 mg/L/48h
(Oncorhynchus mykiss)

Persistence and May persist based on information available.

Degradability
Bioaccumulation/
No information available.
Accumulation
Will likely be mobile in the environment due to its
Mobility
water solubility.
13. Disposal considerations
Waste Disposal Methods Chemical waste generators must determine whether a discarded

chemical is classified as a hazardous waste. Chemical waste

 Safety Data Sheet
generators must also consult local, regional, and national hazardous
Effective date : 01.08.2015 Page 10 of 83

waste regulations to ensure

Distilled Water complete and accurate classification.

14. Transport information

DOT
UN-
No UN3077
Proper Shipping Environmentally hazardous substances, solid,
Name n.o.s.
Technical Name Cupric sulfate
Hazard Class 9
Packing Group III
TDG
UN-No UN3077
Proper Shipping Environmentally hazardous substances, solid,
Name n.o.s.
Hazard Class 9
Packing Group III
IATA
UN-No UN3077
Proper Shipping Environmentally hazardous substances, solid,
Name n.o.s.
Hazard Class 9
Packing Group III
IMDG/IMO
UN-No UN3077
Proper Shipping Environmentally hazardous substances, solid,
Name n.o.s.
Hazard Class 9
Packing Group III
15. Regulatory information

United States of America

Inventory
Component CAS No TSCA TSCA Inventory notification Active- TSCA - EPA Regulatory
Inactive Flags
Cupric sulfate 7758-98-7 X ACTIVE -
Legend:
TSCA US EPA (TSCA) - Toxic Substances Control Act, (40 CFR Part 710) X -

Listed

'-' - Not Listed

 Safety Data Sheet
TSCA 12(b) - Notices of ExportNot applicable
Effective date : 01.08.2015 Page 11 of 83

Distilled Water

International Inventories
Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), China (IECSC), Korea

(KECL).

Component CAS No DSL NDSL EINECS PICCS ENCS ISHL AICS IECSC KECL
Cupric sulfate 7758-98-7 X - 231-847- X X X X X KE-08956
6
KECL - NIER number or KE number (http://ncis.nier.go.kr/en/main.do)

U.S. Federal Regulations

SARA 313
Component CAS No Weight % SARA 313 - Threshold
Values %

Cupric sulfate 7758-98-7 98 1.0

SARA 311/312 Hazard See section 2 for more

Categories information

CWA (Clean Water Act)

Component CWA - Hazardous CWA - Reportable CWA - Toxic Pollutants CWA - Priority
Substances Quantities Pollutants

Cupric sulfate X 10 lb X -

Clean Air Act Not applicable

OSHA - Occupational Safety andNot applicable

Health Administration

CERCLA This material, as supplied, contains one or more substances regulated

as a hazardous substance under the Comprehensive Environmental

Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Component Hazardous Substances RQs CERCLA EHS RQs

Cupric sulfate 10 lb -

California Proposition 65 This product does not contain any emicals.

Proposition 65 ch

U.S. State Right-to-Know

Regulations
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
 Safety Data Sheet
Cupric sulfate X X X - -
Effective date : 01.08.2015 Page 12 of 83
U.S. Department of Transportation Distilled Water
Reportable Quantity (RQ): Y

DOT Marine Pollutant N DOT

Severe Marine Pollutant Y

U.S. Department of HomelandThis product does not contain any DHS chemicals.

Security

Other International Regulations

Mexico - Grade No information available

Authorisation/Restrictions according to EU REACH

Component REACH (1907/2006) - Annex XIV - REACH (1907/2006) - Annex XVII - REACH Regulation (EC
Substances Subject to Restrictions on Certain 1907/2006) article 59 - Candidate
Authorization Dangerous Substances List of Substances of Very High
Concern (SVHC)
Cupric sulfate - Use restricted. See item 75. -
(see link for restriction details)
https://echa.europa.eu/substances-restricted-under-reach

Safety, health and environmental regulations/legislation specific for the substance or mixture
Component CAS No OECD HPV Persistent Organic Ozone Depletion Restriction of
Pollutant Potential Hazardous
Substances (RoHS)
Cupric sulfate 7758-98-7 Listed Not applicable Not applicable Not applicable
Component CAS No Seveso III Directive Seveso III Directive Rotterdam Basel Convention
(2012/18/EC) - (2012/18/EC) - Convention (PIC) (Hazardous Waste)
Qualifying Qualifying
Quantities for Major Quantities for Safety
Accident Report
Notification Requirements
Cupric sulfate 7758-98-7 Not applicable Not applicable Not applicable Annex I - Y22
16. Other information

Prepared By Regulatory Affairs

Thermo Fisher Scientific

Email: EMSDS.RA@thermofisher.com

Creation Date 09-Apr-2010

Revision Date 26-Dec-2021
Print Date 26-Dec-2021
Revision Summary This document has been updated to comply with the US OSHA
HazCom 2012 Standard replacing the current legislation under 29
 Safety Data Sheet
CFR 1910.1200 to align with the Globally Harmonized System of
Effective date : 01.08.2015 Page 13 of 83
Classification and Labeling of Chemicals (GHS).
Disclaimer Distilled Water
The information provided in this Safety Data Sheet is correct to the best of our knowledge,

information and belief at the date of its publication. The information given is designed only as

a guidance for safe handling, use, processing, storage, transportation, disposal and release

and is not to be considered a warranty or quality specification. The information relates only to

the specific material designated and may not be valid for such material used in combination

with any other materials or in any process, unless specified in the text

End of SDS
 Safety Data Sheet
SECTION 1 : Identification of the substance/mixture and of the supplier
Effective date : 01.08.2015 Page 14 of 83
Product name : Distilled Water
Distilled Water

Manufacturer/Supplier Trade name:

Manufacturer/Supplier Article number: S25868

Recommended uses of the product and uses restrictions on use:
Manufacturer Details:

AquaPhoenix Scientific
9 Barnhart Drive, Hanover, PA 17331

Supplier Details:

Fisher Science Education

15 Jet View Drive, Rochester, NY 14624

Emergency telephone number:

Fisher Science Education Emergency Telephone No.: 800-535-5053

SECTION 2 : Hazards identification

Classification of the substance or mixture:

Not classified for physical or health hazards under GHS.

Hazard statements:
Precautionary statements:

Other Non-GHS Classification:

WHMIS
NFPA/HMIS

NFPA SCALE (0-4) HMIS RATINGS (0-4)

SECTION 3 : Composition/information on ingredients

 Safety Data Sheet

Effective date : 01.08.2015

Ingredients:
Page 15 of 83

Distilled Water
CAS 7732-18-5 Deionized Water 100 %

Percentages are by weight

 Safety Data Sheet

Effective date : 01.08.2015 Page 16 of 83

Distilled Water

SECTION 4 : First aid measures

Description of first aid measures
After inhalation: Move exposed individual to fresh air.

After skin contact: Wash affected area with soap and water.

After eye contact: Protect unexposed eye. Rinse/flush exposed eye(s) gently using water for 15-20 minutes. Remove contact lens(es) if able to do
so during rinsing. Seek medical attention if irritation persists or if concerned.
After swallowing: Rinse mouth thoroughly. Do not induce vomiting. Have exposed individual drink sips of water. Seek medical attention if
irritation, discomfort or vomiting persists.

Most important symptoms and effects, both acute and delayed:

Irritation, Nausea,Headache, Shortness of breath.;

Indication of any immediate medical attention and special treatment needed:

If seeking medical attention, provide SDS document to physician.

SECTION 5 : Firefighting measures

Extinguishing media

Suitable extinguishing agents: If in laboratory setting, follow laboratory fire suppression procedures.

For safety reasons unsuitable extinguishing agents:

Special hazards arising from the substance or mixture:

Advice for firefighters:

Protective equipment:

Additional information (precautions): Move product containers away from fire or keep cool with water spray
as a protective measure, where feasible.

SECTION 6 : Accidental release measures

Personal precautions, protective equipment and emergency procedures:

Stop the spill, if possible. Contain spilled material by diking or using inert absorbent.

Environmental precautions:

Prevent from reaching drains, sewer or waterway. Collect contaminated soil for characterization per Section 13

Methods and material for containment and cleaning up:

If in a laboratory setting, follow Chemical Hygiene Plan procedures.Collect liquids using vacuum or by use of absorbents. Place into properly labeled
containers for recovery or disposal. If necessary, use trained response staff/contractor.

Reference to other sections:

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 Safety Data Sheet

Effective date : 01.08.2015 Page 17 of 83

Distilled Water

SECTION 7 : Handling and storage

Precautions for safe handling:

Follow good hygiene procedures when handling chemical materials. Avoid splashes or spray in enclosed areas.

Conditions for safe storage, including any incompatibilities:

Store in cool, dry conditions in well sealed containers.

SECTION 8 : Exposure controls/personal protection

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 Safety Data Sheet

Effective date : 01.08.2015 Page 18 of 83

Distilled Water

Control Parameters: No applicable occupational exposure limits

Appropriate Engineering controls: Emergency eye wash fountains and safety showers should be available in

the immediate vicinity of use/handling.

Respiratory protection: Not required under normal conditions of use. Use suitable respiratory

protective device when aerosol or mist is formed.

Protection of skin: The glove material has to be impermeable and resistant to the product/

the substance/ the preparation being used/handled.Selection of the glove material on consideration
of the penetration times, rates of diffusion and the degradation.
Eye protection: Safety glasses with side shields or goggles.

General hygienic measures: The usual precautionary measures are to be adhered to when handling

chemicals. Keep away from food, beverages and feed sources. Wash hands before breaks and at
the end of work. Do not inhale gases/fumes/dust/mist/vapor/aerosols. Avoid contact with the eyes
and skin.

SECTION 9 : Physical and chemical properties

Appearance (physical Explosion limit lower: Not Determined Not

state,color): Clear, colorless liquid. Explosion limit upper: Determined

Odor: Odorless Vapor pressure: 17.5 mmHg @20C

Odor threshold: Not Determined Vapor density: Not Determined

pH-value: Not Determined Relative density: 1.000

Melting/Freezing point: 0C Solubilities:

Boiling point/Boiling Partition coefficient (n-

range: 100C octanol/water): Not Determined

Flash point (closed Auto/Self-ignition

cup): Not Determined temperature: Not Determined

Decomposition
Evaporation rate: Not Determined temperature: Not Determined

Flammability a. Kinematic:Not Determined

(solid,gaseous): Not Determined Viscosity:
b. Dynamic: Not Determined

Density: Not Determined

SECTION 10 : Stability and reactivity

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 Safety Data Sheet

Effective date : 01.08.2015 Page 19 of 83

Distilled Water

Reactivity:

Chemical stability:No decomposition if used and stored according to specifications.

Possible hazardous reactions:

Conditions to avoid:Store away from oxidizing agents, strong acids or bases.

Incompatible materials:Strong acids.Strong bases.

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 Safety Data Sheet

Effective date : 01.08.2015 Page 20 of 83

Distilled Water

Hazardous decomposition products:Carbon oxides (CO, CO2).

SECTION 11 : Toxicological information

Acute Toxicity: No additional information.

Chronic Toxicity: No additional information.

Corrosion Irritation: No additional information.

Sensitization: No additional information.

Single Target Organ (STOT): No additional information.

Numerical Measures: No additional information.

Carcinogenicity: No additional information.

Mutagenicity: No additional information.

Reproductive Toxicity: No additional information.

SECTION 12 : Ecological information

Ecotoxicity Persistence and degradability: Readily degradable in the environment.

Bioaccumulative potential:

Mobility in soil: Aqueous solution has high mobility in soil.

Other adverse effects:

SECTION 13 : Disposal considerations

Waste disposal recommendations:

Product/containers must not be disposed together with household garbage. Do not allow product to reach sewage system or open water.It is the
responsibility of the waste generator to properly characterize all waste materials according to applicable regulatory entities (US 40CFR262.11).
Consult federal state/ provincial and local regulations regarding the proper disposal of waste material that may incorporate some amount of this
product.

SECTION 14 : Transport information

UN-Number

Not Dangerous Goods

UN proper shipping

name

Not Dangerous Goods

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 Safety Data Sheet

Effective date : 01.08.2015 Page 21 of 83

Distilled Water

Transport hazard class(es)

Packing group:Not Dangerous
Goods Environmental hazard:

Transport in bulk:

Special precautions for user:

SECTION 15 : Regulatory information

United States (USA)

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 Safety Data Sheet

Effective date : 01.08.2015 Page 22 of 83

Distilled Water

SARA Section 311/312 (Specific toxic chemical listings):

None of the ingredients is listed

SARA Section 313 (Specific toxic chemical listings):

None of the ingredients is listed

RCRA (hazardous waste code):

None of the ingredients is listed

TSCA (Toxic Substances Control Act):

All ingredients are listed.

CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act):

None of the ingredients is listed

Proposition 65 (California):

Chemicals known to cause cancer:

None of the ingredients is listed

Chemicals known to cause reproductive toxicity for females:

None of the ingredients is listed

Chemicals known to cause reproductive toxicity for males:

None of the ingredients is listed

Chemicals known to cause developmental toxicity:

None of the ingredients is listed

Canada

Canadian Domestic Substances List (DSL):

All ingredients are listed.

Canadian NPRI Ingredient Disclosure list (limit 0.1%):

None of the ingredients is listed

Canadian NPRI Ingredient Disclosure list (limit 1%):

None of the ingredients is listed

SECTION 16 : Other information

This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the SDS contains all the information
required by the Controlled Products Regulations.Note:. The responsibility to provide a safe workplace remains with the user.The user should consider the
health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct
employees and develop work practice procedures for a safe work environment.The information contained herein is, to the best of our knowledge and
belief, accurate.However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for
damages incurred by the use of this material.It is the responsibility of the user to comply with all applicable laws and regulations applicable to this material.
GHS Full Text Phrases:

Abbreviations and acronyms:

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 Safety Data Sheet

Effective date : 01.08.2015 Page 23 of 83

Distilled Water

IMDG: International Maritime Code for Dangerous Goods PNEC: Predicted No-
Effect Concentration (REACH)
CFR: Code of Federal Regulations (USA)

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SARA: Superfund Amendments and Reauthorization Act (USA) RCRA: Resource
Conservation and Recovery Act (USA)
TSCA: Toxic Substances Control Act (USA)
NPRI: National Pollutant Release Inventory (Canada) DOT: US Department of
Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals ACGIH: American
Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection
Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada) DNEL: Derived No-Effect
Level (REACH)

Effective date : 01.08.2015

Last updated : 03.23.2015

SECTION 1 : Identification of the substance/mixture and of the supplier

Product name : Iron Powder
 Safety Data Sheet
Manufacturer/Supplier Trade name:
Effective date : 01.23.2015 Page 3 of 83

Manufacturer/Supplier Article number: Iron Powder S25370A

Recommended uses of the product and uses restrictions on use:
Manufacturer Details:

AquaPhoenix Scientific
9 Barnhart Drive, Hanover, PA 17331

Supplier Details:

Fisher Science Education

15 Jet View Drive, Rochester, NY 14624

Emergency telephone number:

Fisher Science Education Emergency Telephone No.: 800-535-5053

SECTION 2 : Hazards identification

Classification of the substance or mixture:

Flammable

Flammable solids, category 1

Self-heating substances and mixtures, category 1

Flam. Sol. 1
Self-heat. 1
Hazards Not Otherwise Classified - Combustible Dust

Signal word :Danger

Hazard statements:

Flammable solid
Self-heating; may catch fire
Precautionary statements:

If medical advice is needed, have product container or label at hand Keep out of reach of children
Read label before use
Keep away from heat/sparks/open flames/hot surfaces. No smoking Ground/bond container and
receiving equipment
Use explosion-proof electrical/ventilating/light/equipment
Wear protective gloves/protective clothing/eye protection/face protection Do not eat, drink or smoke when
using this product

Combustible Dust Hazard: :

May form combustible dust concentrations in air (during processing).

 Safety Data Sheet

Effective date : 01.23.2015 Page 4 of 83

Other Non-GHS Classification:
Iron Powder
WHMIS
 Safety Data Sheet

Effective date : 01.23.2015 Page 5 of 83

Iron Powder

B4 D2B

NFPA/HMIS

NFPA SCALE (0-4) HMIS RATINGS (0-4)

SECTION 3 : Composition/information on ingredients

Ingredients:

CAS 7439-89-6 Iron >97 %

Percentages are by weight

SECTION 4 : First aid measures

Description of first aid measures

After inhalation: Move exposed individual to fresh air. Loosen clothing as necessary and position individual in a comfortable position.Seek
medical advice if discomfort or irritation persists.If breathing difficult, give oxygen.
After skin contact: Wash affected area with soap and water. Rinse/flush exposed skin gently using water for 15-20 minutes. Seek medical
advice if discomfort or irritation persists.
After eye contact: Protect unexposed eye. Rinse/flush exposed eye(s) gently using water for 15-20 minutes. Remove contact lens(es) if able to
do so during rinsing. Seek medical attention if irritation persists or if concerned.
After swallowing: Rinse mouth thoroughly. Do not induce vomiting. Have exposed individual drink sips of water. Seek medical attention if
irritation, discomfort or vomiting persists.

Most important symptoms and effects, both acute and delayed:

Irritation, Nausea,Headache, Shortness of breath.;

Indication of any immediate medical attention and special treatment needed:

If seeking medical attention, provide SDS document to physician.

SECTION 5 : Firefighting measures

Extinguishing media

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 Safety Data Sheet

Effective date : 01.23.2015 Page 6 of 83

Iron Powder

Suitable extinguishing agents: If in laboratory setting, follow laboratory fire suppression procedures. Use appropriate fire suppression agents for
adjacent combustible materials or sources of ignition

For safety reasons unsuitable

extinguishing agents: Special hazards arising
from the substance or mixture:

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 Safety Data Sheet

Effective date : 01.23.2015 Page 7 of 83

Iron Powder

Combustion products may include carbon oxides or other toxic vapors.Thermal decomposition can lead to release of irritating gases and
vapors.Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust
explosion hazard.

Advice for firefighters:

Protective equipment: Use NIOSH-approved respiratory protection/breathing apparatus.

Additional information (precautions): Move product containers away from fire or keep cool with water spray as a protective measure, where
feasible.Use spark-proof tools and explosion-proof equipment.

SECTION 6 : Accidental release measures

Personal precautions, protective equipment and emergency procedures:

Wear protective equipment. Transfer to a disposal or recovery container.Use spark-proof tools and explosion-proof equipment.Use respiratory
protective device against the effects of fumes/dust/aerosol. Keep unprotected persons away. Ensure adequate ventilation.Keep away from ignition
sources. Protect from heat.Stop the spill, if possible. Contain spilled material by diking or using inert absorbent.

Environmental precautions:

Prevent from reaching drains, sewer or waterway. Collect contaminated soil for characterization per Section 13

Methods and material for containment and cleaning up:

If in a laboratory setting, follow Chemical Hygiene Plan procedures.Place into properly labeled containers for recovery or disposal. If necessary, use trained
response staff/contractor.Dust deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are released into
the atmosphere in sufficient concentration. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air).
Collect solids in powder form using vacuum with (HEPA filter)

Reference to other sections:

SECTION 7 : Handling and storage

Precautions for safe handling:

Minimize dust generation and accumulation. Wash hands after handling. Routine housekeeping should be instituted to ensure that dusts do not
accumulate on surfaces. Dry powders can build static electricity charges when subjected to the friction of transfer and mixing operations. Follow
good hygiene procedures when handling chemical materials. Use only in well ventilated areas.Avoid contact with eyes, skin, and clothing.

Conditions for safe storage, including any incompatibilities:

Provide ventilation for containers. Avoid storage near extreme heat, ignition sources or open flame. Store away from foodstuffs. Store away from
oxidizing agents.Store in cool, dry conditions in well sealed containers. Store with like hazards

SECTION 8 : Exposure controls/personal protection

Control Parameters: , , OSHA PEL TWA (Total Dust) 15 mg/m3 (50 mppcf*)

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 Safety Data Sheet

Effective date : 01.23.2015 Page 8 of 83

Iron Powder

, , ACGIH TLV TWA (inhalable particles) 10 mg/m3

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 Safety Data Sheet

Effective date : 01.23.2015 Page 9 of 83

Iron Powder

Appropriate Engineering controls: Emergency eye wash fountains and safety showers should be available in

the immediate vicinity of use/handling.Provide exhaust ventilation or other engineering controls to

Respiratory protection:
keep the airborne concentrations of vapor or dusts (total/respirable) below the applicable
workplace exposure limits (Occupational Exposure Limits-OELs) indicated above.Use under a fume
hood. It is recommended that all dust control equipment such as local exhaust ventilation and
material transport systems involved in handling of this product contain explosion relief vents or
an explosion suppression system or an oxygen deficient environment.Ensure that dust-handling
systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in
a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the
equipment).
Not required under normal conditions of use. Use suitable respiratory

protective device when high concentrations are present. Use suitable respiratory protective device
when aerosol or mist is formed. For spills, respiratory protection may be advisable.
Protection of skin: The glove material has to be impermeable and resistant to the product/

the substance/ the preparation being used/handled.Selection of the glove material on consideration of
the penetration times, rates of diffusion and the degradation.
Eye protection: Safety glasses with side shields or goggles.

General hygienic measures: The usual precautionary measures are to be adhered to when handling

chemicals. Immediately remove all soiled and contaminated clothing. Wash hands before breaks
and at the end of work. Do not inhale gases/fumes/dust/mist/vapor/aerosols. Avoid contact with
the eyes and skin.

SECTION 9 : Physical and chemical properties

Appearance (physical Explosion limit lower: Not Determined Not

state,color): Black to gray solid Explosion limit upper: Determined

Odor: Odorless Vapor pressure: 1 mm Hg @ 1787C

Odor threshold: Not Determined Vapor density: Not Determined

pH-value: Not Determined Relative density: 7.86 @ 20C

Melting/Freezing point: 1535C Solubilities: Insoluble in water.

Boiling point/Boiling Partition coefficient (n-

range: 2750C octanol/water): Not Determined

Flash point (closed Auto/Self-ignition

cup): Not Determined temperature: Not Determined

Decomposition
Evaporation rate: Not Determined temperature: Not Determined

Flammability a. Kinematic:Not Determined

(solid,gaseous): Not Determined Viscosity:
b. Dynamic: Not Determined

Density: Not Determined

Iron:Molecular Weight: 55.847

SECTION 10 : Stability and reactivity

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 Safety Data Sheet

Effective date : 01.23.2015 Page 10 of 83

Iron Powder

Reactivity:

Chemical stability:Decomposes when heated. Oxidizes when exposed to air.

Possible hazardous reactions:

Conditions to avoid:Store away from oxidizing agents, strong acids or bases.Incompatible materials, moisture, exposure to air, excess heat.
Incompatible materials:Strong acids.Strong bases.

Hazardous decomposition products:Oxides of iron

SECTION 11 : Toxicological information

Acute Toxicity:

Oral: 30 mg/kg LD50 orl - rat

Chronic Toxicity: No additional information.

Corrosion Irritation: No additional information.

Sensitization: No additional information.

Single Target Organ (STOT): No additional information.

Numerical Measures: No additional information.

Carcinogenicity: No additional information.

Mutagenicity: No additional information.

Reproductive Toxicity: No additional information.

SECTION 12 : Ecological information

Ecotoxicity Persistence and degradability: Readily degradable in the environment.

Bioaccumulative potential:
Mobility in soil:

Other adverse effects:

SECTION 13 : Disposal considerations

Waste disposal recommendations:

Product/containers must not be disposed together with household garbage. Do not allow product to reach sewage system or open water.It is the
responsibility of the waste generator to properly characterize all waste materials according to applicable regulatory entities (US 40CFR262.11).
Consult federal state/ provincial and local regulations regarding the proper disposal of waste material that may incorporate some amount of this
product.

SECTION 14 : Transport information

UN-Number

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 Safety Data Sheet

Effective date : 01.23.2015 Page 11 of 83

Iron Powder

3089

UN proper shipping name

METAL POWDERS, FLAMM ABLE, N.O.S.

Transport hazard class(es)

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 Safety Data Sheet

Effective date : 01.23.2015 Page 12 of 83

Iron Powder

Class:

4.1 Flammable solids, self-reactive substances and solid desensitized explosives

Packing group:II
Environmental hazard:
Transport in bulk:

Special precautions for user:

SECTION 15 : Regulatory information

United States (USA)

SARA Section 311/312 (Specific toxic chemical listings):

None of the ingredients is listed

SARA Section 313 (Specific toxic chemical listings):

None of the ingredients is listed

RCRA (hazardous waste code):

None of the ingredients is listed

TSCA (Toxic Substances Control Act):

All ingredients are listed.

CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act):

None of the ingredients is listed

Proposition 65 (California):

Chemicals known to cause cancer:

None of the ingredients is listed

Chemicals known to cause reproductive toxicity for females:

None of the ingredients is listed

Chemicals known to cause reproductive toxicity for males:

None of the ingredients is listed

Chemicals known to cause developmental toxicity:

None of the ingredients is listed

Canada

Canadian Domestic Substances List (DSL):

All ingredients are listed.

Canadian NPRI Ingredient Disclosure list (limit 0.1%):

None of the ingredients is listed

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 Safety Data Sheet

Effective date : 01.23.2015 Page 13 of 83

Iron Powder

Canadian NPRI Ingredient Disclosure list (limit 1%):

None of the ingredients is listed

SECTION 16 : Other information

This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the SDS contains all the information
required by the Controlled Products Regulations.Note:. The responsibility to provide a safe workplace remains with the user.The user should consider the
health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct

Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 -

www.gsmsds.com
employees and develop work practice procedures for a safe work environment.The information contained herein is, to the best of our knowledge and belief,
accurate.However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred
by the use of this material.It is the responsibility of the user to comply with all applicable laws and regulations applicable to this material.
GHS Full Text Phrases:

Abbreviations and acronyms:

IMDG: International Maritime Code for Dangerous Goods PNEC: Predicted No-
Effect Concentration (REACH)
CFR: Code of Federal Regulations (USA)
SARA: Superfund Amendments and Reauthorization Act (USA) RCRA: Resource
Conservation and Recovery Act (USA)
TSCA: Toxic Substances Control Act (USA)
NPRI: National Pollutant Release Inventory (Canada) DOT: US Department of
Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals ACGIH: American
Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire
Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada) DNEL: Derived No-Effect
Level (REACH)

Effective date : 01.23.2015

Last updated : 03.19.2015