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1. Cathode rays are deflected away from a negatively charged plate because : [30 sec]
(A) they are not particles (B) they are positively charged particles
(C) they are neutral (D) they are negatively charged particles
3. The energies of the 3s, 3p and 3d orbitals in a multielectron atom increase in that order. To which factor(s)
can this order be attributed ? [45 sec]
I. the relative penetrations of these orbitals near the nucleus
II. the relative average distance of the electron from the nucleus
(A) I only (B) II only (C) Both I and II (D) Neither I nor II
6. Which gas-phase atom in its ground state could have an electron with the quantum numbers
n 3, 2, m 0, ms 1 / 2 ? (Given atomic number Na 11, Mg 12, P 15, Ti 22) [60 sec]
(A) Na (B) Mg (C) P (D) Ti
7. Which orbital possesses one angular node and one radial node ? [60 sec]
(A) 2s (B) 2p (C) 3p (D) 3d
8. The first ionization energy of Na is 495.9 kJ mol 1. What is the longest wavelength of light that could
remove an electron from a Na atom ? [120 sec]
7 4 3
(A) 2.41 10 m (B) 2.41 10 m (C) 4.14 m (D) 4.14 10 m
9. What is the ratio of frequencies between the first lines of Lyman, Balmer and Paschen series ? [120 sec]
(A) 1 / 2 : 1 / 6 : 1 / 12 (B) 1/ 2 :1/ 3 :1/ 4
(C) 3 / 4 : 5 / 36 : 7 / 144 (D) 2 / 3 : 8 / 56 : 3 / 88
10. Which set of orbitals is listed in the sequential order of filling in a many-electron atom ? [60 sec]
(A) 3s, 3p, 3d (B) 3d, 4s, 4p (C) 3d, 4p, 5s (D) 4p, 4d, 5s
11. Which quantum number is associated with the shape of an atomic orbital ? [60 sec]
(A) n (B) (C) m1 (D) ms
12. What is the electron configuration for a gas phase 3 ion of iron (Z 26) ? [120 sec]
(A) [Ar]3d 5 (B) [Ar]4s2 3d 3 (C) [Ar]4s1 3d 4 (D) [Ar]4s2 3d 6
13. Wave length of particular transition for H atom is 400 nm. What can be wavelength of He for same
transition : 120 sec]
(A) 400 nm (B) 100 nm (C) 1600 nm (D) 200 nm
14. The correct sequence of frequency of the electromagnetic radiations in electromagnetic spectrum is :
(A) X-rays > UV rays > Microwaves > Radio waves [60 sec]
(B) Radio waves > Microwaves > UV rays > X-rays
(C) UV rays > X-rays > Radio waves > Microwaves
(D) Radio waves > Microwaves > X-rays > UV rays
15. The work function for a metal is 4eV. To emit a photo-electron of zero velocity from the surface of the
metal, the wavelength of incident light should be : [Given: h = 6.626 1034 Js, c = 3 108m/s] [120 sec]
(A) 2700 Å (B) 1700 Å (C) 5900 Å (D) 3100 Å