+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + +
+ + ASPEN PLUS CALCULATION REPORT + +
+ + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +

ASPEN PLUS IS A TRADEMARK OF HOTLINE:

ASPEN TECHNOLOGY, INC. U.S.A. 888/996-7100
781/221-6400 EUROPE (44) 1189-226555

PLATFORM: WIN-X64 SEPTEMBER 4, 2022

VERSION: 37.0 Build 395 SUNDAY
INSTALLATION: 9:47:52 P.M.

  ASPEN PLUS PLAT: WIN-X64 VER: 37.0 09/04/2022 PAGE I

ASPEN PLUS (R) IS A PROPRIETARY PRODUCT OF ASPEN TECHNOLOGY, INC.

(ASPENTECH), AND MAY BE USED ONLY UNDER AGREEMENT WITH ASPENTECH.
RESTRICTED RIGHTS LEGEND: USE, REPRODUCTION, OR DISCLOSURE BY THE
U.S. GOVERNMENT IS SUBJECT TO RESTRICTIONS SET FORTH IN
(i) FAR 52.227-14, Alt. III, (ii) FAR 52.227-19, (iii) DFARS
252.227-7013(c)(1)(ii), or (iv) THE ACCOMPANYING LICENSE AGREEMENT,
AS APPLICABLE. FOR PURPOSES OF THE FAR, THIS SOFTWARE SHALL BE DEEMED
TO BE "UNPUBLISHED" AND LICENSED WITH DISCLOSURE PROHIBITIONS.
CONTRACTOR/SUBCONTRACTOR: ASPEN TECHNOLOGY, INC. 20 CROSBY DRIVE,
BEDFORD, MA 01730.
TABLE OF CONTENTS

RUN CONTROL SECTION.................................... 1

RUN CONTROL INFORMATION........................... 1
DESCRIPTION....................................... 1

FLOWSHEET SECTION...................................... 2
FLOWSHEET CONNECTIVITY BY STREAMS................. 2
FLOWSHEET CONNECTIVITY BY BLOCKS.................. 2
COMPUTATIONAL SEQUENCE............................ 2
OVERALL FLOWSHEET BALANCE......................... 2

PHYSICAL PROPERTIES SECTION............................ 3

COMPONENTS........................................ 3

U-O-S BLOCK SECTION.................................... 4

BLOCK: B1 MODEL: DSTWU..................... 4

STREAM SECTION......................................... 7
B D F............................................. 7
 PROBLEM STATUS SECTION................................. 8
BLOCK STATUS...................................... 8
  ASPEN PLUS PLAT: WIN-X64 VER: 37.0 09/04/2022 PAGE 1

RUN CONTROL SECTION

RUN CONTROL INFORMATION

-----------------------

THIS COPY OF ASPEN PLUS LICENSED TO

TYPE OF RUN: EDIT

INPUT FILE NAME: _2313amp.inm

INPUT PROBLEM DATA FILE NAME : _2313amp

OUTPUT PROBLEM DATA FILE NAME: _4743mhh
LOCATED IN:

PDF SIZE USED FOR INPUT TRANSLATION:

NUMBER OF FILE RECORDS (PSIZE) = 0
NUMBER OF IN-CORE RECORDS = 256
PSIZE NEEDED FOR SIMULATION = 1

CALLING PROGRAM NAME: apmain

LOCATED IN: C:\Program Files\AspenTech\Aspen Plus V11.0\Engine\\xeq

SIMULATION REQUESTED FOR ENTIRE FLOWSHEET

DESCRIPTION
-----------

Specialty Chemicals Simulation with Metric Units : C, atm, kg/hr,

kmol/hr, kcal/hr, l/hr. Property Method: NRTL Flow basis for
input: Mass Stream report composition: Mass flow
  ASPEN PLUS PLAT: WIN-X64 VER: 37.0 09/04/2022 PAGE 2

FLOWSHEET SECTION

FLOWSHEET CONNECTIVITY BY STREAMS

---------------------------------

STREAM SOURCE DEST STREAM SOURCE DEST

F ---- B1 D B1 ----
B B1 ----

FLOWSHEET CONNECTIVITY BY BLOCKS

--------------------------------

BLOCK INLETS OUTLETS

 B1 F D B

COMPUTATIONAL SEQUENCE
----------------------

SEQUENCE USED WAS:

B1

OVERALL FLOWSHEET BALANCE

-------------------------

*** MASS AND ENERGY BALANCE ***

IN OUT RELATIVE DIFF.
CONVENTIONAL COMPONENTS (KMOL/HR )
METHA-01 3.00000 3.00000 0.00000
ETHAN-01 7.00000 7.00000 0.00000
PROPA-01 15.0000 15.0000 0.00000
N-BUT-01 33.0000 33.0000 0.00000
N-PEN-02 30.0000 30.0000 0.00000
N-HEX-01 12.0000 12.0000 0.00000
TOTAL BALANCE
MOLE(KMOL/HR ) 100.000 100.000 0.142109E-15
MASS(KG/HR ) 6036.77 6036.77 0.301318E-15
ENTHALPY(KCAL/HR ) -0.323714E+07 -0.343154E+07 0.566511E-01

*** CO2 EQUIVALENT SUMMARY ***

FEED STREAMS CO2E 1203.21 KG/HR
PRODUCT STREAMS CO2E 1203.21 KG/HR
NET STREAMS CO2E PRODUCTION 0.00000 KG/HR
UTILITIES CO2E PRODUCTION 0.00000 KG/HR
TOTAL CO2E PRODUCTION 0.00000 KG/HR
  ASPEN PLUS PLAT: WIN-X64 VER: 37.0 09/04/2022 PAGE 3

PHYSICAL PROPERTIES SECTION

COMPONENTS
----------

ID TYPE ALIAS NAME

METHA-01 C CH4 METHANE
ETHAN-01 C C2H6 ETHANE
PROPA-01 C C3H8 PROPANE
N-BUT-01 C C4H10-1 N-BUTANE
N-PEN-02 C C5H12-1 N-PENTANE
N-HEX-01 C C6H14-1 N-HEXANE
  ASPEN PLUS PLAT: WIN-X64 VER: 37.0 09/04/2022 PAGE 4

U-O-S BLOCK SECTION

BLOCK: B1 MODEL: DSTWU

-----------------------------
INLET STREAM: F
 CONDENSER OUTLET: D
REBOILER OUTLET: B
PROPERTY OPTION SET: NRTL RENON (NRTL) / IDEAL GAS

*** MASS AND ENERGY BALANCE ***

IN OUT RELATIVE DIFF.
TOTAL BALANCE
MOLE(KMOL/HR ) 100.000 100.000 0.00000
MASS(KG/HR ) 6036.77 6036.77 0.00000
ENTHALPY(KCAL/HR ) -0.323714E+07 -0.343154E+07 0.566511E-01

*** CO2 EQUIVALENT SUMMARY ***

FEED STREAMS CO2E 1203.21 KG/HR
PRODUCT STREAMS CO2E 1203.21 KG/HR
NET STREAMS CO2E PRODUCTION 0.00000 KG/HR
UTILITIES CO2E PRODUCTION 0.00000 KG/HR
TOTAL CO2E PRODUCTION 0.00000 KG/HR

*** INPUT DATA ***

HEAVY KEY COMPONENT N-PEN-02
RECOVERY FOR HEAVY KEY 0.0100000
LIGHT KEY COMPONENT PROPA-01
RECOVERY FOR LIGHT KEY 0.98000
TOP STAGE PRESSURE (ATM ) 10.2147
BOTTOM STAGE PRESSURE (ATM ) 10.2147
NO. OF EQUILIBRIUM STAGES 5.00000
DISTILLATE VAPOR FRACTION 0.0

*** RESULTS ***

DISTILLATE TEMP. (C ) -47.1010
BOTTOM TEMP. (C ) 108.874
MINIMUM REFLUX RATIO 0.25059
ACTUAL REFLUX RATIO 2.23914
MINIMUM STAGES 3.98608
ACTUAL EQUILIBRIUM STAGES 5.00000
NUMBER OF ACTUAL STAGES ABOVE FEED 2.89963
DIST. VS FEED 0.38341
CONDENSER COOLING REQUIRED (KCAL/HR ) 625,127.
NET CONDENSER DUTY (KCAL/HR ) -625,127.
REBOILER HEATING REQUIRED (KCAL/HR ) 430,727.
NET REBOILER DUTY (KCAL/HR ) 430,727.
  ASPEN PLUS PLAT: WIN-X64 VER: 37.0 09/04/2022 PAGE 5

U-O-S BLOCK SECTION

BLOCK: B1 MODEL: DSTWU (CONTINUED)

++++++++++++++++++++++++++++++++++
+ REFLUX RATIO VS. NO. OF STAGES +
++++++++++++++++++++++++++++++++++

---------------------------
! NSTAGE ! RR !
 !============!============!
! 4 ! 148.2759 !
! 5 ! 2.2390 !
! 6 ! 0.9819 !
! 7 ! 0.7120 !
! 8 ! 0.4914 !
! 9 ! 0.3883 !
! 10 ! 0.3537 !
! 11 ! 0.3346 !
---------------------------
  ASPEN PLUS PLAT: WIN-X64 VER: 37.0 09/04/2022 PAGE 6

U-O-S BLOCK SECTION

BLOCK: B1 MODEL: DSTWU (CONTINUED)

********************************************************
ACTUAL REFLUX RATIO VS. ACTUAL NO. OF EQUILIBRIUM STAGES
********************************************************

150.0A--------+--------+--------+--------+--------+--------+--------+
* ! ! ! ! ! ! !
* ! ! ! ! ! ! !
* ! ! ! ! ! ! !
* ! ! ! ! ! ! !
!* ! ! ! ! ! ! !
!* ! ! ! ! ! ! !
125.0+*-------+--------+--------+--------+--------+--------+--------+
!* ! ! ! ! ! ! !
!* ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
100.0+--*-----+--------+--------+--------+--------+--------+--------+
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
R ! * ! ! ! ! ! ! !
R 75.00+---*----+--------+--------+--------+--------+--------+--------+
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
50.00+-----*--+--------+--------+--------+--------+--------+--------+
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
 ! * ! ! ! ! ! ! !
! * ! ! ! ! ! ! !
25.00+------*-+--------+--------+--------+--------+--------+--------+
! * ! ! ! ! ! ! !
! *! ! ! ! ! ! !
! *! ! ! ! ! ! !
! *! ! ! ! ! ! !
! *! ! ! ! ! ! !
! A ! ! ! ! ! !
0.00+--------+********A********A********A********A********A********A
4 5 6 7 8 9 10 11

NSTAGE

  ASPEN PLUS PLAT: WIN-X64 VER: 37.0 09/04/2022 PAGE 7

STREAM SECTION

B D F
-----

STREAM ID B D F
FROM : B1 B1 ----
TO : ---- ---- B1

SUBSTREAM: MIXED
PHASE: LIQUID LIQUID MIXED
COMPONENTS: KMOL/HR
METHA-01 3.6793-07 3.0000 3.0000
ETHAN-01 9.0136-04 6.9991 7.0000
PROPA-01 0.3000 14.7000 15.0000
N-BUT-01 19.6596 13.3404 33.0000
N-PEN-02 29.7000 0.3000 30.0000
N-HEX-01 11.9981 1.8607-03 12.0000
COMPONENTS: KG/HR
METHA-01 5.9026-06 48.1283 48.1283
ETHAN-01 2.7104-02 210.4604 210.4875
PROPA-01 13.2290 648.2188 661.4478
N-BUT-01 1142.6848 775.3874 1918.0722
N-PEN-02 2142.8633 21.6451 2164.5084
N-HEX-01 1033.9656 0.1603 1034.1259
TOTAL FLOW:
KMOL/HR 61.6587 38.3413 100.0000
KG/HR 4332.7697 1704.0003 6036.7701
L/HR 8396.7831 2900.2484 1.1920+05
STATE VARIABLES:
TEMP C 108.8739 -47.1010 82.0000
PRES ATM 10.2147 10.2147 10.2147
VFRAC 0.0 0.0 0.3912
LFRAC 1.0000 1.0000 0.6088
SFRAC 0.0 0.0 0.0
ENTHALPY:
 CAL/MOL -3.6392+04 -3.0975+04 -3.2371+04
CAL/GM -517.8924 -696.9650 -536.2366
KCAL/HR -2.2439+06 -1.1876+06 -3.2371+06
ENTROPY:
CAL/MOL-K -114.0135 -86.2162 -96.0241
CAL/GM-K -1.6225 -1.9399 -1.5907
DENSITY:
MOL/CC 7.3431-03 1.3220-02 8.3893-04
GM/CC 0.5160 0.5875 5.0644-02
AVG MW 70.2702 44.4429 60.3677
  ASPEN PLUS PLAT: WIN-X64 VER: 37.0 09/04/2022 PAGE 8

PROBLEM STATUS SECTION

BLOCK STATUS
------------

****************************************************************************
* *
* Calculations were completed normally *
* *
* All Unit Operation blocks were completed normally *
* *
* All streams were flashed normally *
* *
****************************************************************************