AMALEAKS.BLOGSPOT.

COM
CHEM2122 WEEK 1-9

Which kinds of substances are held together by intermolecular forces?

- Molecules (covalent) in solid and liquid phases

Does CH4 have hydrogen bonding?

- No

Van der Waals forces include

- Both London and dipole-dipole attractions

Dipole-dipole attraction occurs when molecules are polar. Which of these molecules contains a
polar bond?
- HCl

Does H2O have hydrogen bonding?

- Yes

Which is the second strongest intermolecular force, after hydrogen bonding?

- Dipole-dipole attraction

All molecules have London forces between them, but dipole-dipole and hydrogen bonding are
so much stronger that when they are present we can ignore London forces. Which of these has
ONLY London forces?
- I2

A substance capable of hydrogen bonding has a _______________ boiling point than a similar
substance that doesn’t hydrogen bond.
- Higher

Does NH3 have hydrogen bonding?

- Yes

London forces are stronger in heavier atoms or molecules, and weaker in lighter atoms or
molecules. Which of these has the strongest London forces?
- I2

Which of these molecules could have dipole-dipole attraction?

- PCl3

Does NO2 have

hydrogen bonding?
- No
Which of these molecules could
have dipole-dipole attractions?
- HCl (electronegativity
difference = 1.1)

Does HF have hydrogen bonding?

- Yes

Does H2S have hydrogen bonding?

- No

Hydrogen bonding occurs when hydrogen is bonded to N, O, or F. Which of the following has
hydrogen bonding?
- NH3

Which kind of intermolecular force is strongest?

- Hydrogen bonding

Which of the following is NOT a kind of intermolecular force?

- Covalent bond

Which is stronger?
- Intermolecular forces

Does HCl have hydrogen bonding?

- No

1 20/20
Define the term “mass”
- The amount of matter in an object

What is the measuring unit for mass?

- Grams

It is an indication of the escape of molecules from the surface of the liquid.

- Evaporation

The following liquids are poured in a beaker: alcohol (density=0.79), corn syrup (density=1.38),
water (density=1.0), and cooking oil (density= 0.93). which of theses liquids will sink to the
bottom of the beaker?
- Corn syrup

Fluids with very low viscosity very ______________.

- Fast

Which unit of measurement is used for volume?

- Milliliter

The piece of copper has a mass of 89g and a volume of 10cm3. What would be the density of
the
copper?
- 8.9g/cm3

Put the liquids in order from most dense to least

dense?
- 4, 3, 2,
1

Which property of matter is determined by dividing its mass by its volume?

- Density
As temperature increases viscosity ___________.
- Decreases

Fluids with very high viscosity flow very

____________.
- Slow

Which lab tool might you use to measure the volume of a liquid?
- Graduated cylinder

A piece of copper has a mass of 89g and a volume of 10cm3. What would be the density of the
copper?
- 8.9g/cm3

Why do some substances float on water?

- They are less dense than water

A block has a mass of 54g and a volume of 20cm3. What is the density of the block?
- 2.7g/cm3

Which box has a higher density?

- Box A

What is the mass if the volume of the object is 75 cm3 and the density is
1.56g/cm3?
- 117
grams

What units are used to measure Density?

- g/cm3

What is viscosity?
- A liquid’s resistance to flow

A brick sinks in water while a wooden block of the same size floats. This is because the brick has
a
____________.
- Higher density than the wooden block

2 15/15
Water droplets take a spherical shape (as pictured) because of __________

- Cohesion

What word describes when water is attracted to other substances?

- Adhesion

Because of surface tension, you can put things into a full of water and…
- The water will never spill

Refer to the picture of water sticking to a leaf; this is occurring because of:

- Adhesion

Water droplets take a spherical shape (as pictured) because of __________

- Cohesion

Force of attraction between similar molecules is called

- Cohesive force

Describe
COHESION.
- Water molecules attracted to other water molecules

What is adhesion?
- Water’s ability to stick to other substances

Surface tension of water can be reduced by

- Heating

Rain drops are spherical in shape because of

- Surface tension

Which characteristic of water will allow a paperclip to remain floating on water when the
paperclip is gently placed on top of the water?
- Solvent properties

Surface tension is the property of water in which…

- Water molecules at the surface tend to stick together

Water beads up on the surface of a penny because of this property

- High surface tension

Tendency of molecules of the same kind to stick to one another

- Cohesion

Water’s ability to stick to glass is

- Adhesion
 3 15/15
How many moles of NaCl are present in a solution with a molarity of 8.59M and a volume of
125mL?
- 1.07mol

How many moles are needed to make 2.5L of a 3.8M

solution?
-
9.5mol

What volume of 1.50 M KBr can be made from a 15.6 mL

concentrated
of KBr with a molarity of
9.65 M?
- 100mL

Which sweet tea would you expect to taste the sweetest?

-
3.1M

What is the molarity of 4 g of NaCl (MM=58.45) in 3,800 mL of

solution?
- 0.018
M

How many mL of 10.8M HCl are required to make 100.0mL of 3.00M

acid?
-
27.8mL

What is the molarity of a solution made by adding 1.565 moles of PbNO3 to 500
mL?
-
3.13M

Calculate the molarity of the following solution: 1.0mole of KCl in 750.0mL of solution.
-
1.3M

Find the molarity of 186.55 g of sucrose, C12H22011 (MM=342) in 250mL of

water.
-
2.18M

True or False? The higher the concentration of a solution the less solutes it has in it.
- False

How many liters would you need to make 1M solution if you have 6mol of sodium hydroxide?
-6

Which of the following has the most NaCl (MM=58.44)?

- 1mole

How many grams of solute are dissolved in 125.0mL of 5.00M NaCl

(MM=58.45)?
- 36.5g
NaCl
How many grams of AgNO3 (MM=169.87) are needed to prepare 0.125M
solution in 250mL of
water?
- 5.3g

What is the molarity of a solution made by diluting 26.5 mL of 6.00M HNO3 to a volume of 250
mL?
- 0.636M

Week 5 Quiz | 20/20

Intermolecular forces for: CO2

- Dispersion Force

Does H2O have hydrogen bonding?

- Yes
What is the basis of a metallic bond?
- The attraction between positive metal ions and free-floating electrons.

Does HCl have hydrogen bonding?

- Yes

All molecules have London forces between them, but dipole-dipole and hydrogen bonding are
so much stronger that when they are present we can ignore London forces. Which of these has
ONLY London forces?
- I2

Intermolecular forces for3NH

- Hydrogen bondin
g

Intermolecular force present HCl?

- Dipole dipole
Which is the second strongest intermolecular force, after hydrogen bonding?
- Dipole-dipole attraction

Does HF have hydrogen bonding?

- Yes

___________________________________________ have the strongest intermolecular forces of attraction.

- Hydrogen bonds

Determine the type of intermolecular force present in SiO2.

- Covalent network

This picture most likely depicts the arrangement of atoms in a ________________.

- Metal

Hydrogen bonding occurs when hydrogen is bonded to N, O , or F. Which of the following has
hydrogen bonding?
- NH3

Does NH3 have hydrogen bonding?

- No

Which is the strongest intermolecular force below?

- Ionic

What explains the very high melting and boiling point of water.
- Strong hydrogen bonds between water and
molecules

Ionic Bonding involves…

- The transfer of electrons

The model used to describe and explain the bonding and arrangement of atoms in a solid metal
is the
- Electron sea model

Which substance would have the weakest intermolecular forces of attraction?

- CH4

Does CH4 have hydrogen bonding?

- No

Week 6 Quiz | 15/15

Which of the following colligative properties is associated with a semipermeable membrane?
- Osmotic pressure /

Which of the following solutions has the highest boiling point? Assume that all solutes in
solution are nonvolatile.
- 1m magnesium chloride /

The basic law governing the colligative properties of solutions is Raoult’s law. Raoult’s law
explains the relationship between the vapor pressure of the solution, mole fraction, and vapour
pressure of the solvent. This can be given as:
- P1= x1p1° /

What is the name for a substance that dissolves in water but does not form ions or conduct an
electric current?
- Nonelectrolyte /

Examples of colligative properties include vapor pressure lowering, freezing point depression,
osmotic pressure, molarity, molality and boiling point elevation.
- False /

The change in the vapor pressure that occurs when a solute is added to a solvent is therefore a
colligative property.
- True /

Antifreeze works because the freezing and boiling points of liquids are “colligative” properties.
This means they depend on the concentrations of “solutes”, or dissolved substances, in the
solution.
- True/

Colligative properties are not dependent only on the number of particles in a solution, and their
identity. - False /
Molality, also called molal concentration, is a measure of the concentration of a solute, in a
solution in terms of amount of substance in a specified amount of mass of the solvent.
- True /

Osmotic pressure is the minimum pressure which needs to be applied to a solution to prevent
the inward flow of its pure solvent across a semipermeable membrane
- True /

What is the boiling point of a solution created when four moles of glucose are dissolved in two
kg of water? Assume that glucose isa nonvolatile solute. Kb water= 0.515℃.kg/mol
- 101.03℃ /

What is the osmotic pressure (atm) of a 0.30 M solution of glucose in water that is used for
intravenous infusion at body temperature, 37℃? R=0.082 L.atm/mol.k
- 0.76 atm

Colligative properties are dependent only on the number of particles in a solution, and not their
identity.
- True /

If 4.27 g sucrose (C12H22O11) are dissolved in 15.2 g water, what is the boiling point of the
resulting solution? Kb for water= 0.51℃/m. ΔTb= I x Kb x m.
- 10.42°C/

Colligative properties are dependent only on the number of particles in a solution, and not their
identity. (select all that apply)
Week 7 Quiz | 10/10

Is the combustion of gasoline endothermic or exothermic?

- Exothermic

As someone is running on the track they begin to perspire. If the runner is our system, are they
endothermic or
exothermic?
- Exothermic process

A reaction is performed in a beaker with a temperature probe recording the temperature

changes of the reaction. If the temperature began at 15.0 degrees Celsius and ended at 27.5
degrees Celsius. If the reaction is our system, is the system endothermic or exothermic? -
Endothermic

Refer the following question: 2n2 + 3H2 →→ 2NH3 +46 kJ. How much energy would be
produced if only 1 mol of nitrogen was reacted?
- 23kJ

How much energy must be used to produce 4.75 mol of gaseous water?: H20 (l) + 44.0 kJ -
→→ H2O (g)
- 207kJ

What mass of P4 must be reacted to produce 5905 kJ of energy?: P4 + 6Cl2 - →→ 4PCl3 + 2439
kJ -
300.0g

Do reactants in an endothermic reaction have a higher or lower energy than the products? -
Lower

Do the reactants in an exothermic reaction have a higher or lower energy than the products? -
Higher

In an exothermic process the surrounding loses heat

- False

In an endothermic reaction the system is releasing energy.

- False

Week 8-9 Quiz | 10/10

How does a catalyst work in speeding up a reaction?

- By lowering the activation energy or reaction

Why does a higher concentration increase the rate of reaction?

- It increases the frequency of particle collisions

Why does a higher temperature increase the rate of a reaction?

- It only increases the frequency of particle collisions

What factors can affect the value of the activation energy of a reaction?
- The presence of a catalyst

Catalysts are thought to increase the rate of a chemical reaction by

- Providing an alternative reaction pathway with a lower activation energy

Increasing the temperature of a chemical reaction

- Increases the energy of the reactant and product particles

What is the rate of reaction?

- How fast a reaction is

Grinding a effervescent tablet into powder increases the rate of reaction due to increased -
Surface area

The _____________ is required to break the bonds of the reactants.

- Activation energy

List four factors that affects the rate of a reaction