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• With this expression the chemical formulas for three groups of glass as classified above
3. Potash-Lead Glass • For the purpose of classification the glass may be grouped into the following five main categories:
2. It is cheap
4. It is possible to blow or to weld articles made from this glass with the help of simple sources of heat
USES – Used in the manufacture of glass tubes and other laboratory apparatus, Plate glass, window glass etc.,
GLASS GLASS COMPOSITION
COMPOSITION OF GLASS CLASSIFICATION OF GLASS
CLASSIFICATION OF GLASS POTASH-LIME GLASS OR BOHEMIAN GLASS OR HARD GLASS
1. Soda-Lime Glass • A mixture of potassium silicate and Calcium silicate
2. Potash-Lime Glass
PROPERTIES
3. Potash-Lead Glass
1. It fuses at high temperatures
4. Common Glass
2. It is not easily affected by water and other solvents
5. Borosilicate Glass
3. It does not melt so easily
PROPERTIES OF GLASS
USES – Used in the manufacture of glass articles which have to withstand high temperatures such as
TREATMENT OF GLASS combustion tubes etc.
1. Cutting and Grinding POTASH-LEAD GLASS OR FLINT GLASS
2. Bending • A mixture of potassium silicate and lead silicate
3. Opaque Making
PROPERTIES
4. Silvering
1. It fuses very easily
2. It is easily attacked by aqueous solutions
3. It possesses bright lustre and great refractive power
4. It specific gravity is about 3 to 3.30
5. It turns black and opaque, if it comes into contact with reducing gases of the furnace during heating
USES – Used in the manufacture of artificial gems, electric bulbs, lenses, prisms etc
GLASS COMMON GLASS OR BOTTLE GLASS
COMPOSITION OF GLASS • A mixture of sodium silicate, iron silicate and Calcium silicate. It is prepared from cheap raw
materials
CLASSIFICATION OF GLASS
PROPERTIES
1. Soda-Lime Glass
2. Potash-Lime Glass 1. It fuses with difficulty
USES – Used in the chemical industry, for laboratory apparatus, for ampoules and other pharmaceutical
containers, for various high intensity lighting applications and as glass fibres used in the reinforced
BOROSILICATE plastics to make protective helmets, boats, piping, car chassis, ropes, care exhausts and many other
GLASS items and also in textile industry.
GLASS COMPOSITION
PROPERTIES OF GLASS
• Properties of glass – factors such as composition of the constituents, state of surface, thermal treatment conditions, dimension of
specimen, etc.
1. It absorbs, refracts or transmits light. It can take up a high polish and may be used as substitute for very costly gems
3. It is affected by alkalies
4. It is an excellent electrical insulator at elevated temperatures due to the fact that glass can be considered as an ionic liquid. The
ions are not easily moved at room temperature because of the high viscosity. But when the temperature rises, the ions are permitted
to flow and thus they will sustain an electric current
6. It behaves more as a solid than most solids in the sense that it is elastic. But when the elastic limit is exceeded it fractures
instead of deforming.
7. It is capable of being worked in many ways. It can be blown, drawn or pressed. But it is strange to note that is difficult to cast
in large pieces.
9. It is not easily attacked by ordinary chemical reagents. It is possible to intentionally alter some of its properties such as
fusibility, hardness, refractive power etc. to suit different purposes
PROPERTIES OF GLASS
14. It is possible to obtain glasses with diversified properties. The glasses may be clear, colourless, diffused and stained
15. It is possible to weld pieces of glass by fusion.
16. It is transparent and translucent. The transparency is the most used characteristic of glass and it is due to the absence of free
electrons. For the same reason, it also works as a good insulator.
17. When it is heated, it becomes soft and soft with the rise in temperature. It is ultimately transformed into a mobile liquid. The
liquid, when allowed to cool, passes to all the degrees of viscosity. This property of glass has made its manufacturing process
easy. It can also be formed into articles of desired shape. Thus the amorphousness of glass permits it t be blown, drawn from
furnaces and continuously worked
18. Due to advancement made in the science of glass production, it is possible to make glass lighter than cork or softer than cotton
or stronger than steel. The strength of glass however is considerably affected by foreign inclusions, internal defects and cords
or chemically heterogeneous areas.
19. The glass panes can be cleaned easily by any one of the following methods:
a) Applying methylated spirit;
b) Painting the glass panes with lime-wash and leaving it to dry and then washing with clean water;
c) Rubbing damp salt for cleaning paint spots; and
d) Rubbing finely powdered chalk
COLOURED GLASS
• To make coloured glass, the colouring pigment is added to the raw materials while preparing the batch for its manufacture.
• The whole mass is heated till it becomes homogeneous.
• The colouring pigment may consist of metallic oxides, finely divided metals, carbon, salts of metal, sulphur etc
• Different substances which are used to produce different shades of colour.
• Different quantities of the same substance may also impart different colour to the glass
• The coloured glass is used for various purposes such as artificial precious stones, window panels, fancy articles, decorative tile etc.
CLASSIFICATION OF GLASS 1. CUTTING AND GRINDING – The glass is cut to the required size and shape by either a diamond
cutter or small wheel of hardened steel. The edges of cut glass can be ground and rounded by
1. Soda-Lime Glass suitable grinding stone or wheel
2. Potash-Lime Glass 2. BENDING – The glass may be bent into desired shape by placing it in ovens in which the
3. Potash-Lead Glass temperature can be regulated. The glass in the form of rods, sheets or tubes is placed in such
4. Common Glass ovens and heated. It is then bent when it is suitably heated
5. Borosilicate Glass 3. OPAQUE MAKING – The glass can also be made opaque or impervious to light. IT is done by
grinding the glass surface with emery. It can also be achieved chemically by the application of
PROPERTIES OF GLASS hydrofluoric acid.
TREATMENT OF GLASS 4. SILVERING – This can be archieved by application of a very thin coat of a tin or its surface
1. Cutting and Grinding followed by layer of silver coating. This silvered surface needs to be protected against weather
effects by application of suitable paint over it.
2. Bending
3. Opaque Making
4. Silvering
TYPES OF GLASS
TYPES OF GLASS
TYPES OF GLASS
1. FOAM GLASS
1. FOAM GLASS
The foam glass is prepared in the form of rectangular blocks. The finely ground glass and carbon are thoroughly
2. GLASS BLOCKS mixed and the mixture is then melted in a furnace. At the time of melting, the mixture expands and assumes the form
3. FLOAT GLASS of a black foam. The resulting glass material contains more than 350 million inert air cells per m3. The foam glass
floats in water and it can be cut like wood. It is fire-proof, rigid and an excellent heat insulator. It can be used as
4. WIRED GLASS a substitute for cork for use in air-conditioning and refrigeration industries
6. SAFETY GLASS These are partially evacuated and completely sealed hollow units which are formed by fusing together two-halves
of pressed glass. The edges are coated with a grit bearing plastic material so that permanent and effective bond
7. HEAT EXCLUDING with the mortar is ensured. The glass blocks are available in square sizes with dimension as 150 mm, 200 mm and
300 mm with the approximate thickness of 100 mm. One or both the faces of the blocks are suitably treated to
GLASS obscure the glass and to diffuse light. These blocks possess high insulating value and they are set in cement
mortar.
8. LAMINATED GLASS
The glass blocks possess the following advantages
9. SHIELDING GLASS
i. They are easy to clean and hence they can be well maintained
10. FIBRE GLASS
ii. They are excellent in light transmission
11. SOLAR CONTROL
FOAM GLASS iii. They provide very good insulation against cold, heat and noise.
The glass blocks are not intended to carry superimposed loads. But they possess adequate strength to carry their
own weight up to a maximum height of 6m. They are also able to resist the effect of lateral wind pressure for
individual panels not exceeding 11 m2 in area.
GLASS BLOCKS
3. FLOAT GLASS OR PLATE GLASS
TYPES OF GLASS
1. FOAM GLASS Float glass is a sheet of glass made by floating molten glass on a bed of molten metal, typically tin, although lead
and various low melting point alloys were used in the past. This method gives the sheet uniform thickness and very flat
2. GLASS BLOCKS surfaces. Modern windows are made from float glass.
3. FLOAT GLASS The molten glass coming out of the furnace is allowed to flat on the molten tin. The glass thus formed is known as the
float glass and it is then further annealed to remove all the stresses. It is widely used for residential buildings,
4. WIRED GLASS commercial complexes furniture articles. It is superior to ordinary sheet glass and grants the following advantages:
5. STRUCTURAL GLASS 1. It consumes 30 to 40 % less energy and is thus environment friendly.
6. SAFETY GLASS
2. It is aesthetic in appearance and its use has opened unlimited possibilities of innovation in architectural design
7. HEAT EXCLUDING
3. It is available in larger sizes and various thicknesses
GLASS
4. It is cost-effective as compared to the corresponding cost of brick wall, finishing material, paint, maintenance, etc.
8. LAMINATED GLASS
5. It is ideally suitable for solar applications due to high light transmission and it results in higher efficiency.
9. SHIELDING GLASS
10. FIBRE GLASS 6. It is tougher and more scratch-resistant
11. SOLAR CONTROL 7. It makes the windows that transmit more natural light and the mirrors that give true images
9. There is no refraction defect due to uniform thickness and superior optical clarity and thus there is less strain
4. WIRED GLASS
TYPES OF GLASS
• In this type of glass, the steel wire mesh is placed in glass during rolling
1. FOAM GLASS operation.
2. GLASS BLOCKS • The mesh may have hexagonal or square units.
3. FLOAT GLASS • If this glass breaks, the pieces of glass are held by wire in position.
• The glass is also fire-resistant.
4. WIRED GLASS • The wired glass is used for roofs, skylights, fire-resisting doors and
5. STRUCTURAL windows etc.
GLASS 5. STRUCTURAL GLASS
6. SAFETY • These are in the form of glass-crete square or lenses which are set in
cement concrete and reinforced with steel frames. They are known as
GLASS/TOUGHENED the glass bricks.
GLASS • The semi-prism formed on the underside of these bricks collect light
and project it on the other dark side. These bricks can be used as light
7. HEAT EXCLUDING structural members also.
GLASS • They are widely used for pavement lights, partitions, lantern lights etc.
8. LAMINATED GLASS 6. SAFETY GLASS OR TOUGHENED GLASS OR SHATTER PROOF GLASS
9. SHIELDING GLASS • This glass is formed by placing celluloid between two sheets of the
plate glass and then applying glue to make a single unit.
10. FIBRE GLASS • If glass breaks, the flying of splinters does not occur.
11. SOLAR CONTROL 7. HEAT-EXCLUDING GLASS
• This glass allows light to pass through it, but it eliminates heat.
• Used for windows of coaches of higher class in railways, in window
panels of important buildings etc
TYPES OF GLASS 8. LAMINATED GLASS
• Laminated glass is a type of safety glass that holds together when
1. FOAM GLASS shattered. In the event of breaking, it is held in place by an interlayer,
typically of polyvinyl butyral (PVB) or ethylene-vinyl acetate (EVA),
2. GLASS BLOCKS between its two or more layers of glass.
3. FLOAT GLASS 9. SHIELDING GLASS
4. WIRED GLASS • This is a special variety of glass and it contains heavy elements like lead
oxide (PbO) etc. LAMINATED
5. STRUCTURAL GLASS • Used for windows through which high radiation is observed. GLASS
• Depending upon the type of radiation, the quality od shielding glass is
6. SAFETY GLASS determined.
7. HEAT EXCLUDING 10. FIBRE GLASS
GLASS • The fibre glass is composed of minute glass rods and each glass rod
resembles the parent material in all respects.
FIBRE GLASS
8. LAMINATED GLASS • It is soft to the touch and it is flexible in nature.
9. SHIELDING GLASS • It does not absorb water and it is proof against fire, vermins, water and
acids.
10. FIBRE GLASS • It can be prepared either in the form of continuous strands just like silk or
in the staple form just like wool.
11. SOLAR CONTROL • For making this type of glass, the molten glass is spun at a very high speed
to produce continuous fine glass fibres. This is special type of glass and it
is used for thermal insulations sheets, fibres glass reinforced plastics,
etc.
• Making optical fibres which can guide light and thus transmit images round
SHIELDING GLASS corners. These fibres are used in endoscopes for examination of internal
human organs, changeable traffic message signs now on motorways for
speed restriction warnings and communications technology without which
telephones and internet would not be possible.
• Glass fibre used in roof insulation to medical equipment and its
compositions varies depending on its application.
TYPES OF GLASS 11. SOLAR CONTROL
1. FOAM GLASS • Clear glass transmits incident short wave solar radiation. This is absorbed by the surfaces like
walls, ceiling furnishes inside the building which heats them up. This in turn emits long wave
2. GLASS BLOCKS radiation which does not pass out through glass.
3. FLOAT GLASS • The radiation admitted by the glass gets trapped in the rooms resulting in rise in temperature.
4. WIRED GLASS This is called “GREEN HOUSE EFFECT”.
• In air-conditioned rooms this affects the efficiency of the system very badly. Such solar gain can
5. STRUCTURAL GLASS be reduced by external shading devices such as screens, blinds, canopies etc or internal
6. SAFETY GLASS shading.
7. HEAT EXCLUDING • External shading is more effective than internal shading. The position of the windows with respect
to the sun in summer is also important. These factors are important in air conditioning of
GLASS buildings.
8. LAMINATED GLASS • Another method to reduce this heat is by using solar control glasses which are of two types the
9. SHIELDING GLASS solar reflecting and solar absorbing. In general, the reflecting type is more efficient than the
absorbing ones.
10. FIBRE GLASS • The performance can be improved by double glazing using clear glass as the inside leaf.
11. SOLAR CONTROL ENERGY EFFICIENT GLASS – Float glass with a special thin coating on one side which allows
the sun’s energy to pass through in one direction while reducing the thermal transfer the other
way. The principle behind this is the difference in thermal wavelength of energy transmitted from
the sun and that transmitted from the heat within a room.
PHOTO CATALYTIC EFFECT – Float glass with a special thin photo catalytic coating on one side. This
coating uses the ultraviolet rays from the sun to steadily break down any organic dirt on the surface using
the photo catalytic effect and thus loosen the dirt from the glass. This type of float glass is known as self-
cleaning glass. Self-cleaning glass also has hydrophilic properties which means that when rain runs down
SOLAR CONTROL
the pane of glass, it will wash away the dirt
USES OF GLASS
2 Alumino silicate Used in Combustion tubes, gauge glasses for high-pressure steam
Glass boilers and in halogen-tungsten lamps capable of operating at
temperature as high as 750oC.
3 Bullet Proof It will not allow bullet to pierce through it.
Glass
4 Fibre Glass • Used for thermal insulation, sheets, fibre glass reinforced
plastics etc.
• Optical fibres are used in endoscopes for examination of
internal human organs, changeable traffic message sign now
on motorways for speed restriction warnings and
communications technology without which telephones and the
internet would not be possible
USES OF GLASS
Double-glazing units are equipped with coating, such as Low-Emissivity Triple-glazing is even more efficient and helps achieve extra energy
coatings and / or Solar-control coatings. These coatings increase savings. The ‘U value' of coated triple glazing units usually reaches
considerably the insulation performance of the double-glazed units but 0.7, which is over 8 times more efficient than single glazing (U value
they also allow free solar-heat gains. of 5.8) and nearly 4 times more efficient than early basic double
glazing; (the lower the U value, the better the insulation).
Gas-filled windows can be combined with low-e coatings, highly insulating frames and double or triple glazing to
provide 'super windows', which provide a very high level of resistance to heat transfer.
Dynamic Glazing System or Responsive Glazing – They change in response to light, heat, or
electricity. The sunglasses that darken when exposed to sunlight.
Responsive Glazing – either active and passive.
• Passive glazing responds directly to environmental conditions such as light level or
temperature(Photochromics or thermochromics). Passive glazing is controlled by the
external conditions to which a building is exposed. Photochromic glazing is that in
which resistance to light transmission across the pane is increased as the intensity of
light falling on the pane increases. Thermotropic glazing increases its resistance to heat
(or long wavelength radiation) transmission as the intensity of the heat falling on the
pane increases.
• Active glazing - controlled as per needed and can include such devices as liquid crystal,
dispersed particle and electrochromics. Active glazing known as electrochromic glazing,
is controlled by a current passing through the material to alter the amount of heat and
light transfer. The state of the glazing is controlled by building occupants, who set the
current passing through the glazing and thus set the working environment to suit their
needs.
PHOTOCHROMICS – These materials change their transparency in response to light
intensity. They are ideal for automatically controlling the quantity of daylight allowed into a
building. Enough light to eliminate the need for electric lighting but not so much that the
cooling load would increase
THERMOCHROMICS – These materials change transparency in response to temperature.
They are transparent when cold and reflective white when hot. They can be used in skylights
where the loss of transparency on a hot day is not a problem as it would be in a view window.
These materials could also be used to prevent passive solar heating systems for overheating in
the summer.
LIQUID CRYSTAL GLAZING
LIQUID CRYSTAL GLAZING– When electric power is applied, the transparent liquid crystals
align and become translucent liquid crystals align and become translucent. Thus liquid-crystal glazing
has little application for shading but its real potential is in privacy control.
DISPERSED-PARTICLES GLAZING – Similar to liquid-crystal glazing, this material is more
promising for solar control because the applied power can change the transmittance of the material in
a range between clear and dark state, thereby preserving the view.
ELECTROCHROMIC GLAZING – This is the most promising material for shading because it can
change transparency – not translucency – continuously over a wide ( about 10 to 70 %) and can be
easily controlled.
ELECTROCHROMIC GLAZING
DISPERSED-PARTICLES
GLAZING
ENERGY CONSERVATION MEASURES
• Glass plays an important role in the generation of solar power by way of two
technologies: solar thermal and photovoltaic.
• Photovoltaic technologies are used to convert solar energy directly into
electricity. There are many different technologies available to suit various
requirements and they can come in various shapes and colours offering
flexibility for design integration and building integrated applications (BIPV).
The most common photovoltaic technology is based on crystalline silicon
solar cells. In this application glass acts as a protective outer layer, while
transmitting the solar light to the photovoltaic cells interconnected
underneath. In another technology called ‘thin films’, transparent conductive
coated glass not only allows light through to the photoactive films, but also
conducts the generated electricity out of the modules.
ENERGY CONSERVATION MEASURES
• Glass plays an important role in the generation of solar power by way of two technologies: solar thermal and photovoltaic.
• Solar thermal collectors are intended to collect heat which is then used to supply hot water or heat exchangers, for domestic or
industrial applications.
• There are various kinds of solar thermal collectors but most require a flat glass cover, or glazing, which serves not only to protect
the panel while letting the sunlight through, but also to prevent cooling of the panel from exposure to cold air.
• High-tech glass, the properties of solar-energy technologies are optimised. Indeed, extra-clear glass and mirrored glass can also be
used to produce electricity from the sun at utility scale in Concentrated Solar Power systems (CSPs).