I. 3 MARKS QUESTIONS 1. Derive the packing efficiency FCC, BCC and simple cubic lattice. 2. Construct SHE and write cathodic and anodic reactions 3. Construct Daniel cell and write cathodic and anodic reactions 4. Explain Led – storage battery and it’s charging and recharging reaction. 5. Explain Dry cell, H2-O2 fuel cell 6. Write the postulates of Werner theory 7. Explain the hybridization, geometry and magnetic properties of [CoF6]-3,[Co(NH3)6]+3 8. Explain the mechanism of ter.butyl bromide to ter.butyl alcohol and name the reaction. 9. Explain the mechanism of SN2 reaction. 10.Explain Sand-Mayer’s reaction of preparation of haloarenes II.2 MARKS QUESTIONS 1.write the difference between Frenkel and Schottky defect 2.write the difference between n-type and p-type semiconductor. 3.Write the difference between ideal and non-ideal solut 4.Write the mechanism of rusting of iron and anodic and cathodic reaction. 5.state Kohlrausch lawand write its one application. 6.State Faraday I and II law. 7.Explain homoleptic and heteroleptic complex with an example. 8.Explain types of ligands and give an example. 9.Preparation of haloalkanes by Darzen, Grooves, Finkelstein, Swartz reaction. 10.Explain Wurtz , Wurtz-fittig , Fittig reaction with an example. 11.Why haloarenes are less reactive than haloalkanes. Give reason. 12.Explain Friedel – Craft acylation and alkylation reaction. 13.Write the structure of DDT. 14.Explain Dow’s process of phenol preparation from haloarenes. III.PROBLEMS BASED ON FORMULAE 1.Based on density d =zm/a3NA 2.Based on Nernst equation equilibrium and Gibb’s energy. 3.Based on Elevation of boiling point, Depression in freezing point, Osmotic pressure.