𝒓+

Calcul du rapport 𝒓−

a 𝟑 a 𝐚 𝟑
Contact cation-anion : 𝒓+ + 𝒓− = Contact cation-anion : 𝒓+ + 𝒓− = Contact cation-anion : 𝒓+ + 𝒓− =
𝟐 𝟐 𝟒

Contact anion-anion : a = 2 𝒓− Contact anion-anion : a 𝟐 = 4 𝒓− Contact anion-anion : a 𝟐 = 4 𝒓−

𝒓+ 𝒓+ 𝒓+ 𝟑
𝒓− = 𝟑 - 1 = 0,732 𝒓−
= 𝟐 - 1 = 0,414
𝒓−
= 𝟐
- 1 = 0,225

Coordinence [4/4] Coordinence [6/6] Coordinence [8/8] 𝒓+

Type ZnS Type NaCl Type CsCl 𝒓−
0,225 0,414 0,732
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